The Room Temperature Synthesis and Performance Study of Cationic Polycarboxylate Superplasticizer
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摘要
In this paper,cationic polycarboxylate superplasticizer has been synthesized by using room temperature process with HPEG,AA,DAC and 3-S as the main raw materials.We investigated the effect of the dosage of different raw materials on the dispersing property of polycarboxylate superplasticizer,and we knew that AA:DAC HPEG:3-S=4.5:0.05:1:0.12 was the best molar ratio,the synthesized cationic polycarboxylate superplasticizer had excellent dispersity and mud resistance,and it was superior to commercially available ordinary polycarboxylate superplasticizer
In this paper,cationic polycarboxylate superplasticizer has been synthesized by using room temperature process with HPEG,AA,DAC and 3-S as the main raw materials.We investigated the effect of the dosage of different raw materials on the dispersing property of polycarboxylate superplasticizer,and we knew that AA:DAC:HPEG:3-S = 4.5:0.05:1:0.12 was the best molar ratio,the synthesized cationic polycarboxylate superplasticizer had excellent dispersity and mud resistance,and it was superior to commercially available ordinary polycarboxylate superplasticizer.
引文
[1]Li Chongzhi,Li Yongde,Feng Naiqian.Development and properties of polycarbosylic type high performance water-reducer[J].China Concrete and Cement Products,2002(2):3~6.
    [2]Hulusi Ozkul M.The utilization of beet molasses as a retarding and water-reducing admixture for concrete[J].Cement and Concrete Research,2005(5):8741~882.
    [3]Kavas T,Olgun A,Erdogan Y.Setting and hardening of borogypsum-Portland cement clinkerfly ash blends.Studies on effects of molasses on properties of mortar containing borogypsum[J].Cement and Concrete Research,2005(4):711~718.
    [4]Liu X,Wang Z,Zhu J,et al.Synthesis,characterization and performance of a polycarboxylate superplasticizer with amide structure[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2014,448:1191~129.
    [5]Liao Guosheng,Pan Hui,Xiao Yu.Research on synthesis and performances of control-released polycarboxylic water reducer[J].New Building Materials,2013(4):541~58.
    [6]Wang Hao,Pang Jianjun,Ye Ranran,et al.Theoretical research on room temperature synthesis process of polycarboxylate superplasticizer[J].Ready-mixed Concrete,2014(5).
    [7]Duan Zhouyu,Huang Xue,Wang Tao,et al.Development research on control-released polycarboxylic water reducer synthesized at room temperature[J].Guangdong Building Materials,2015(8):231-26.
    [8]Chen Xiaolu.Synthesis and performance research of polycarboxylate superplasticizer at normal temperature[J].New Building Materials,2014,41(12):801~83.
    [9]Zhu Lizan,Fu Xinjian,Xia Zongyan,et al.Study on synthesis of polycarboxylic acid water-reducing agent under normal atmospheric temperature[J].Concrete,2013(7):591~61.
    [10]Guan Mengqin.The conventional temperature synthesis of high performance polycarboxylates superplasticizer by the oxidation-reduction composite system[J].New Building Materials,2014(8):641~67.
    [11]Jiang Jiayun,Gai Guangqing,Kong Lingwei,et al.Research progress of compatibility between raw materials composed of concrete and polycarboxylate superpiasticizers[J].Concrete,2015(11):691~74.
    [12]Li Chongzhi,Liu Junchao,Wang Qin,et al.Influence of acid/ether-ratio on composition and dispersive property of polycarboxylic type water reducers[J].New Building Materials,2013(12):801~83+87.

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