Na_2MnGe_2Se_6: A New Mn-based Antiferromagnetic Chalcogenide with Large Mn···Mn Separation
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摘要
<正>A new one-dimensional(1D)Mn-based chalcogenide Na_2MnGe_2Se_6 has been obtained by solid-state reaction.It crystallizes in the tetragonal space group I4/mcm with unit cell parameters a=7.7718(16)?,b=7.7718(16)?,c=19.077(7)?and Z=2.In the structure,MnSe_4 and GeSe_4 tetrahedra are linked alternately via edge-sharing with the ratio 1:2 to form 1D infinite
引文
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