一步法制备网状聚氨酯软泡及性能研究
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- 英文论文题名：Performance Study on Preparation of Reticulated Flexible Polyurethane Foam by One-Step
- 论文作者：叶丞 ; 俞中锋 ; 宗红亮 ; 张丽君 ; 申宝兵
- 英文论文作者：YE Cheng ; YU Zhongfeng ; ZONG Hongliang ; ZHANG Lijun ; SHEN Baobing ; JiangSu ZhongShan chemical Co.Ltd
- 年：2016
- 作者机构：江苏钟山化工有限公司;
- 论文关键词：混合起始剂 ; 网状 ; 聚氨酯泡沫
- 英文论文关键词：mixed initiator ; reticulated ; polyurethane foam
- 会议召开时间：2016-07-30
- 会议录名称：中国聚氨酯工业协会第十八次年会论文集
- 语种：中文
- 分类号：TQ328.3
- 学会代码：JAZG
- 会议名称：中国聚氨酯工业协会第十八次年会
- 会议地点：中国上海
- 主办单位：中国聚氨酯工业协会
- 学会名称：中国聚氨酯工业协会
- 页数：4
- 文件大小：955k
- 原文格式：D
- 会议级别：全国
摘要
本研究采用"一步法"制备网状聚氨酯软泡,使用由季戊四醇和乙二醇作为混合起始剂制备的聚醚多元醇ZS-315(羟值39.5~41.0 mg KOH/g,官能度f=3~3.5)配合普通聚醚三醇ZS-2802及助剂直接发泡得到网状的聚氨酯软泡。其中采用自制的开孔剂K-80(用量为1.2份)来增加"一步法"制备的网状聚氨酯软泡的开孔率,增大孔隙体积。通过改变泡沫稳定剂L-580的用量来调节泡孔的粗细满足不同的需求,提升了配方调节的灵活性。该方法具有灵活的配方调节度,所制得的泡沫物理性能优良,且优于"两步法"制备的网状聚氨酯软泡。
Reticulated flexible polyurethane foam was prepared by one-step method in this paper.Mixed pentaerythritol and ethylene glycol were used as initiators to prepare polyether polyol ZS-315(hydroxyl value39.5~41.0 mgKOH/g,functionality f=3-3.5),which then was employed with ordinary polyether polyol ZS-2802 and other additives as co-substrates to produce reticulated flexible polyurethane foam.Self-made cell opener K-80(1.2 parts)was used to increase reticulated opening ratio and pore volume of flexible polyurethane foam.The cell thickness could be adjusted by changing the foam stabilizer L-580 amount to meet different needs,resulting in more flexible formula.This one-step method had a flexible formula,and the resulting foam has excellent physical properties even better than two-step method.
Reticulated flexible polyurethane foam was prepared by one-step method in this paper.Mixed pentaerythritol and ethylene glycol were used as initiators to prepare polyether polyol ZS-315(hydroxyl value39.5~41.0 mgKOH/g,functionality f=3-3.5),which then was employed with ordinary polyether polyol ZS-2802 and other additives as co-substrates to produce reticulated flexible polyurethane foam.Self-made cell opener K-80(1.2 parts)was used to increase reticulated opening ratio and pore volume of flexible polyurethane foam.The cell thickness could be adjusted by changing the foam stabilizer L-580 amount to meet different needs,resulting in more flexible formula.This one-step method had a flexible formula,and the resulting foam has excellent physical properties even better than two-step method.
引文
[1]沈海琴.网状聚氨酯软泡的应用前景[J].黎明化工,1996(6):1-7.
[2]邹开良.网化聚氨酯泡沫塑料的研制[J].聚氨酯工业,2001,16(3):31-33.
[3]刘德春.聚醚型网状聚氨酯软泡的制备[J].聚氨酯工业,1993(4):29-43.
[4]王翔,王钧,杨小利,等.网状聚氨酯软泡材料的研究状况及发展方向[J].国外建材科技,2002,23(1):10-12.
[5]张仕飚,田宝勇,张志强,等.网状聚氨酯软泡塑料的制备及应用[J].河北科技大学学报,2004,25(4):15-20.
[6]朱吕民,刘益军.聚氨酯泡沫塑料[M].3版.北京:化学工业出版社,2005:239-240.
[7]武琴,李绍雄.网状聚氨酯软泡的制造与应用[J].现代化工,1991(6):49-52.
[2]邹开良.网化聚氨酯泡沫塑料的研制[J].聚氨酯工业,2001,16(3):31-33.
[3]刘德春.聚醚型网状聚氨酯软泡的制备[J].聚氨酯工业,1993(4):29-43.
[4]王翔,王钧,杨小利,等.网状聚氨酯软泡材料的研究状况及发展方向[J].国外建材科技,2002,23(1):10-12.
[5]张仕飚,田宝勇,张志强,等.网状聚氨酯软泡塑料的制备及应用[J].河北科技大学学报,2004,25(4):15-20.
[6]朱吕民,刘益军.聚氨酯泡沫塑料[M].3版.北京:化学工业出版社,2005:239-240.
[7]武琴,李绍雄.网状聚氨酯软泡的制造与应用[J].现代化工,1991(6):49-52.