Al含量对高锰TWIP钢中夹杂物的影响
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- 英文论文题名：Effects of Al Content on Inclusions in High Mn TWIP Steel
- 论文作者：杨健 ; 辛修令 ; 王毓男 ; 王睿之 ; 徐龙云
- 英文论文作者：YANG Jian ; XIN Xiuling ; WANG Yunan ; WANG Ruizhi ; XU Longyun ; Steelmaking Technology Department ; Research Institute ; Baosteel Group Corporation
- 年：2016
- 作者机构：宝钢集团有限公司中央研究院炼钢技术研究所;
- 论文关键词：高锰TWIP钢 ; 夹杂物 ; Al含量 ; FactSage
- 英文论文关键词：high Mn TWIP steel ; non-metallic inclusions ; Al ; FactSage
- 会议召开时间：2016-05-19
- 会议录名称：第十九届（2016年）全国炼钢学术会议大会报告及论文摘要集
- 语种：中文
- 分类号：TF771.2
- 学会代码：ZGJS
- 会议名称：第十九届（2016年）全国炼钢学术会议
- 会议地点：中国湖南长沙
- 主办单位：中国金属学会炼钢分会
- 学会名称：中国金属学会
- 页数：6
- 文件大小：614k
- 原文格式：O
- 会议级别：全国
摘要
本文通过实验并结合FactSage热力学计算研究了不同Al含量下Fe-16Mn-xAl-0.6C高锰TWIP钢中夹杂物的演变规律。结果表明,随着钢中Al含量从0.002wt%增加到2.1wt%,氧化物夹杂演变规律为MnO→Al_2O_3→MgO/Al_2O_3→MgO,硫化物夹杂从MnS转变为MgS,另外钢中主要夹杂物演变规律为MnO→Al_2O_3/MnS→MnS→AlN。FactSage热力学计算结果与实验结果相吻合。
In the present study,the effects of Al content on the evolution of inclusions formed in high Mn TWIP steels were investigated experimentally and discussed based on the thermodynamic calculation with FactSage.The results show that with the increase of Al content from 0.002 wt-%to 2.1 wt-%in the steels,the evolution route of main oxide inclusions is MnO→Al_2O_3→MgAl_2O_4→MgO;the main sulfide inclusion is changed from MnS to MgS;and the dominant stable inclusion changes along the path of MnO→Al_2O_3/MnS→MnS→AIN.The main inclusion types in thermodynamic calculation results are consistent with the observed results in the present experimental steels.
In the present study,the effects of Al content on the evolution of inclusions formed in high Mn TWIP steels were investigated experimentally and discussed based on the thermodynamic calculation with FactSage.The results show that with the increase of Al content from 0.002 wt-%to 2.1 wt-%in the steels,the evolution route of main oxide inclusions is MnO→Al_2O_3→MgAl_2O_4→MgO;the main sulfide inclusion is changed from MnS to MgS;and the dominant stable inclusion changes along the path of MnO→Al_2O_3/MnS→MnS→AIN.The main inclusion types in thermodynamic calculation results are consistent with the observed results in the present experimental steels.
引文
[1]P.Von Schweinichen,Z.Chen,D.Senk and A.Lob:'Effect of different casting parameters on the cleanliness of high manganese steel ingots compared to high carbon steel',Metall.Mater.Trans.A,2013,44A,(12),5416-5423.
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[3]S.W.Hwang,J.H.Ji and K.T.Park:'Effects of Al addition on high strain rate deformation of fully austenitic high Mn steels',Mater.Sci.Eng.A,2011,528,(24),7267-7275.
[4]M.Koyama,T.Sawaguchi,K.Ogawa,T.Kikuchi and M.Murakami:"The effects of thermomechanical training treatment on the deformation characteristics of Fe-Mn-Si-Al alloys',Mater.Sci.Eng.A,2008,497,(1),353-357.
[5]ts of high manganese twinning-induced plasticity(TWIP)steel,a review',Acta Metall.Sin.,2013,26,(1),1-15.
[6]J.Kim and B.C.De Cooman:'On the stacking fault energy of Fe-18Pct Mn-0.6Pct C-1.5Pct Al twinning-induced plasticity steel',Metall.Mater.Trans.A,2011,42A,(4),932-936.
[7]K.T.Park,G.Kim,S.K.Kim,S.W.Lee,S.W.Hwang and C.S.Lee:'On the transitions of deformation modes of fully austenitic steels at room temperature',Met.Mater.Int.,2010,16,(1),1-6.
[8]O.Bouaziz,S.Allain,C.P.Scott,P.Cugy and D.Barbier:'High manganese austenitic twinning induced plasticity steels:a review of the microstructure properties relationships',Curr.Opin.Solid St.M.,2011,15,(4),141-168.
[9]I.Gutierrez-Urrutia and D.Raabe:'Dislocation and twin substructure evolution during strain hardening of an Fe-22wt.%Mn-0.6 wt.%C TWIP steel observed by electron channeling contrast imaging',Acta Mater.,2011,59,(16),6449-6462.
[10]G.Gigacher,W.Krieger,P.R.Scheller and C.Thomser:'Non-metallic inclusions in high-manganese-alloy steels',Steel Res.Int.,2005,76,(9),644-649.
[11]A.Grajcar,U.Galisz,L.Bulkowski:'Non-metallic inclusions in high manganese austenitic alloys',Arch.Mater.Sci.Eng.,2011,50,(1),21-30.
[12]J.H.Park,D.J.Kim and D.J.Min:'Characterization of nonmetallic inclusions in high-manganese and aluminum-alloyed austenitic steels',Mater.Sci.Eng.A,2012,43,(7),2316-2324.
[13]I.H.Jung,S.A.Decterov and A.D.Pelton:'A thermodynamic model for deoxidation equilibria in steel',Metall.Mater.Trans.B,2004,35B,(3),493-507.
[2]O.Grassel,L.Kruger,G.Frommeyer and L.W.Meyer:'High strength Fe-Mn-(A1,Si)TRTP/TWIP steels development properties application',Int.J.Plast,2000,16,(10),1391-1409.
[3]S.W.Hwang,J.H.Ji and K.T.Park:'Effects of Al addition on high strain rate deformation of fully austenitic high Mn steels',Mater.Sci.Eng.A,2011,528,(24),7267-7275.
[4]M.Koyama,T.Sawaguchi,K.Ogawa,T.Kikuchi and M.Murakami:"The effects of thermomechanical training treatment on the deformation characteristics of Fe-Mn-Si-Al alloys',Mater.Sci.Eng.A,2008,497,(1),353-357.
[5]ts of high manganese twinning-induced plasticity(TWIP)steel,a review',Acta Metall.Sin.,2013,26,(1),1-15.
[6]J.Kim and B.C.De Cooman:'On the stacking fault energy of Fe-18Pct Mn-0.6Pct C-1.5Pct Al twinning-induced plasticity steel',Metall.Mater.Trans.A,2011,42A,(4),932-936.
[7]K.T.Park,G.Kim,S.K.Kim,S.W.Lee,S.W.Hwang and C.S.Lee:'On the transitions of deformation modes of fully austenitic steels at room temperature',Met.Mater.Int.,2010,16,(1),1-6.
[8]O.Bouaziz,S.Allain,C.P.Scott,P.Cugy and D.Barbier:'High manganese austenitic twinning induced plasticity steels:a review of the microstructure properties relationships',Curr.Opin.Solid St.M.,2011,15,(4),141-168.
[9]I.Gutierrez-Urrutia and D.Raabe:'Dislocation and twin substructure evolution during strain hardening of an Fe-22wt.%Mn-0.6 wt.%C TWIP steel observed by electron channeling contrast imaging',Acta Mater.,2011,59,(16),6449-6462.
[10]G.Gigacher,W.Krieger,P.R.Scheller and C.Thomser:'Non-metallic inclusions in high-manganese-alloy steels',Steel Res.Int.,2005,76,(9),644-649.
[11]A.Grajcar,U.Galisz,L.Bulkowski:'Non-metallic inclusions in high manganese austenitic alloys',Arch.Mater.Sci.Eng.,2011,50,(1),21-30.
[12]J.H.Park,D.J.Kim and D.J.Min:'Characterization of nonmetallic inclusions in high-manganese and aluminum-alloyed austenitic steels',Mater.Sci.Eng.A,2012,43,(7),2316-2324.
[13]I.H.Jung,S.A.Decterov and A.D.Pelton:'A thermodynamic model for deoxidation equilibria in steel',Metall.Mater.Trans.B,2004,35B,(3),493-507.