Synthesis of [1]rotaxanes based on pillar[5]arene mono-thiourea derivatives

详细信息    查看官网全文

• 英文论文题名：Synthesis of [1]rotaxanes based on pillar[5]arene mono-thiourea derivatives
• 论文作者：Gui-Fei Huo ; Ying Han ; Jing Sun ; Chao-Guo Yan
• 英文论文作者：Gui-Fei Huo ; Ying Han ; Jing Sun ; Chao-Guo Yan ; College of Chemistry & Chemical Engineering ; Yangzhou University
• 年：2016
• 作者机构：College of Chemistry & Chemical Engineering, Yangzhou University;
• 英文论文关键词：pillar[5]arene ; thiourea ; [1]rotaxane ; crystal structure
• 会议召开时间：2016-08-25
• 会议录名称：全国第十八届大环化学暨第十届超分子化学学术讨论会会议论文集（上）
• 语种：英文
• 分类号：O621.3
• 学会代码：ZGHY
• 会议名称：全国第十八届大环化学暨第十届超分子化学学术讨论会
• 会议地点：中国湖南长沙
• 主办单位：中国化学会
• 学会名称：中国化学会
• 页数：1
• 文件大小：831k
• 原文格式：D
• 会议级别：全国

摘要

<正>A series of pillar[5]arene mono-thiourea derivatives with different alkylene chain bridge were conveniently synthesized by reaction of alkyl(aryl)isocyanide with pillar[5]arene monooxyacetoamide in refluxing ethanol.1H NMR spectra of pillar[5]arene thiourea derivatives in DMSO-d6 showed the characteristic signs of the bridging ethylene,propylene or butylene unit at the normal range of 1.00-4.00 ppm.This absorption pattern indicats that the alkylthopureadoalkylene scaffolds is in the cavity of pillar[5]arene.However,pillar[5]arene thiourea derivatives

引文

[1]Xue,M.;Yang,Y.;Chi,X.;Zhang,Z.;Huang,F.Acc.Chem.Res.,2012,45,1294.
    [2]Clavel,P.W.C.;Fournel-Marotte,K;Coutrot,F.Chem.Sci.,2015,6,4828.
    [3]Han,Y.;Huo,G.F.;Sun,J.;Xie,J.;Yan,C.G.;Zhao,Y.;Wu,X.;Lin,C.;Wang,L.Y.Sci.Rep.2016,6,28748.