适用于SCR的固体储氨材料开发研究
详细信息 查看官网全文
- 英文论文题名：Research and Development of Solid Materials as Ammonia Sources for DeNO_x SCR System
- 论文作者：张克金 ; 崔龙 ; 王丹 ; 张喆 ; 张苡铭
- 英文论文作者：Zhang Kejin Cui Long Wang Dan Zhang Zhe Zhang Yiming Research and Development Center of China FAW Co. ; Ltd. ; Changchun ; 130011
- 年：2013
- 作者机构：中国第一汽车股份有限公司技术中心;
- 论文关键词：SCR ; 氨合氯化锶 ; 氨气
- 英文论文关键词：SCR ; Strontium ammine chloride ; Ammonia
- 会议召开时间：2013-11-26
- 会议录名称：2013中国汽车工程学会年会论文集
- 英文会议录名称：Proceedings of 2013 SAE-China Congress
- 语种：中文
- 分类号：U464.134.4
- 学会代码：QCGC
- 会议名称：2013中国汽车工程学会年会
- 会议地点：中国北京
- 主办单位：中国汽车工程学会
- 学会名称：中国汽车工程学会
- 页数：5
- 文件大小：2263k
- 原文格式：O
- 会议级别：全国
摘要
适用于SCR的先进固体储氨材料开发研究,开发固态形式的SCR尾气后处理用车载氨源,使用碱土金属氯化物氯化锶材料与2%～10%比例的膨胀石墨均匀混合,形成氯化锶-膨胀石墨复合材料。在氨气压力不低于4 bar的条件下发生氨合反应,形成氨合氯化锶复合材料,该材料有效氨含量高46%,是现有液体尿素还原剂的2.5倍以上。通过热重分析、导热系数测定、模拟分析以及充放氨试验,得出氨合氯化锶材料的相关特性,确定该材料的使用条件。氨合氯化锶材料在SCR车载氨源技术中应用具有使用成本低、氨有效含量高、储存运输安全方便等特点。
Research and development of solid materials as ammonia sources for deNO_x SCR system,development of solid state form of SCR exhaust aftertreatment with on-board ammonia source,the use of chlorides strontium materials mixed with 2%～10%proportion of expanded graphite evenly,formation of strontium chloride/expanded graphite composite materials.Under the condition of not less than 4 bar ammonia pressure,ammonia reaction formation of ammine chloride strontium composite material,the material effective high ammonia content 46%,2.5 times more that of the existing liquid urea reductant.By thermogravimetric analysis,thermal conductivity test, simulation analysis and adsorption/desorption properties tests,the materials data of properties can be got.Ammine chloride strontium material application in SCR on-board ammonia source technology has Characteristics of the low cost,high ammonia content of effective component and storage convenient transportation safety,etc.
Research and development of solid materials as ammonia sources for deNO_x SCR system,development of solid state form of SCR exhaust aftertreatment with on-board ammonia source,the use of chlorides strontium materials mixed with 2%～10%proportion of expanded graphite evenly,formation of strontium chloride/expanded graphite composite materials.Under the condition of not less than 4 bar ammonia pressure,ammonia reaction formation of ammine chloride strontium composite material,the material effective high ammonia content 46%,2.5 times more that of the existing liquid urea reductant.By thermogravimetric analysis,thermal conductivity test, simulation analysis and adsorption/desorption properties tests,the materials data of properties can be got.Ammine chloride strontium material application in SCR on-board ammonia source technology has Characteristics of the low cost,high ammonia content of effective component and storage convenient transportation safety,etc.
引文
[1]京华时报2013年2月17日第003版.
[2]http://www.fev.com.
[3]一汽技术中心内部研究资料,2010.
[4]陈砺,董鹏飞,符文瑜,等.氯化锶复合吸附剂制冷性能的实验研究[J].流体机械,2003,1.
[5]江龙,金哲权,王丽伟,等.氯化锶/膨胀石墨固化混合吸附剂导热和渗透性能测试[C].中国工程热物理学会传热传质学术会议P-001,113002,2011.
[6]陈恒,低温位驱动的固气热化学吸附制冷工质对及变压解吸特性研究[D].上海:上海交通大学,2011.
[7]T D Elmoe,R Z Sorensen,U Quaade,et al.Ahigh-density ammonia storage/delivery system based on Mg(NH_3) 6Cl_2 for SCR - DeNO,in vehicles[J].Chem.Eng.Sci.,2006 (61):2618 -2625.
[8]Gary Fulks,Galen B Fisher,Julian Tan.A Review of Solid Materials as Alternative Ammonia Sources for Lean NO,_x Reduction with SCR[C].SAE 2009-01-0907,8.
[9]Patnaik P.Handbook of Inorganic Chemicals PradyotPatnaik [M].Mc,Graw-Hill,2002.
[2]http://www.fev.com.
[3]一汽技术中心内部研究资料,2010.
[4]陈砺,董鹏飞,符文瑜,等.氯化锶复合吸附剂制冷性能的实验研究[J].流体机械,2003,1.
[5]江龙,金哲权,王丽伟,等.氯化锶/膨胀石墨固化混合吸附剂导热和渗透性能测试[C].中国工程热物理学会传热传质学术会议P-001,113002,2011.
[6]陈恒,低温位驱动的固气热化学吸附制冷工质对及变压解吸特性研究[D].上海:上海交通大学,2011.
[7]T D Elmoe,R Z Sorensen,U Quaade,et al.Ahigh-density ammonia storage/delivery system based on Mg(NH_3) 6Cl_2 for SCR - DeNO,in vehicles[J].Chem.Eng.Sci.,2006 (61):2618 -2625.
[8]Gary Fulks,Galen B Fisher,Julian Tan.A Review of Solid Materials as Alternative Ammonia Sources for Lean NO,_x Reduction with SCR[C].SAE 2009-01-0907,8.
[9]Patnaik P.Handbook of Inorganic Chemicals PradyotPatnaik [M].Mc,Graw-Hill,2002.