Molecular doping enhances the performance of solid-state dye-sensitized solar cells based on P3HT as a hole-transporting material
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- 英文论文题名：Molecular doping enhances the performance of solid-state dye-sensitized solar cells based on P3HT as a hole-transporting material
- 论文作者：Jianbo Lai ; Ze Yu ; Xiaoqing Jiang ; Licheng Sun
- 英文论文作者：Jianbo Lai ; Ze Yu ; Xiaoqing Jiang ; Licheng Sun ; State Key Laboratory of Fine Chemicals ; Institute of Artificial Photosynthesis ; DUT-KTH Joint Education and Research Center on Molecular Devices ; Dalian University of Technology(DUT) ; Department of Chemistry ; School of Chemical Science and Engineering ; KTH Royal Institute of Technology
- 年：2017
- 作者机构：State Key Laboratory of Fine Chemicals,Institute of Artificial Photosynthesis,DUT-KTH Joint Education and Research Center on Molecular Devices,Dalian University of Technology(DUT);Department of Chemistry,School of Chemical Science and Engineering,KTH Royal Institute of Technology;
- 英文论文关键词：Solid-state dye-sensitized solar cells ; Hole-transporting materials ; P3HT ; Molecularly p-doping
- 会议召开时间：2017-05-27
- 会议录名称：第四届新型太阳能电池学术研讨会论文集
- 英文会议录名称：Abstract Book of the 4th Conference on New Generation Solar Cells
- 语种：英文
- 分类号：TM914.4
- 学会代码：ZKYQ
- 会议名称：第四届新型太阳能电池学术研讨会
- 会议地点：中国北京
- 主办单位：中国可再生能源学会光化学专业委员会
- 学会名称：中国科学院物理研究所清洁能源实验室
- 页数：1
- 文件大小：790k
- 原文格式：D
- 会议级别：全国
摘要
Conducting polymer poly(3-hexylthiophene-2,5-diyl)(P3HT) has attracted intense research interest as hole-transporting materials(HTMs) in solid-state dye-sensitized solar cells(ss-DSCs).Nevertheless, pristine P3HT-based devices typically exhibit relatively poor overall performance, mainly due to its relatively low conductivity.Herein, we have successfully incorporated tetrafluoro-tetracyano-quinodimethane(F4TCNQ) as an efficient p-type dopant for P3HT as a HTM in ss-DSCs.The introduction of F4TCNQ(1.0%, w/w) into P3HT film results in a significant increase of the bulk conductivity(more than 20 times), which dramatically improves the photovoltaic parameters, in particular, for the short-circuit current density and fill factor, leading to impressive power conversion efficiency(PCE) of 5.0%.This is the highest reported value for P3HT-based HTMs in ss-DSCs.Thus, molecualrly p-doping has been demonstrated to be an effective strategy for improving the electrical property and thereby the overall performance of ss-DSCs based on P3HT as a HTM.
Conducting polymer poly(3-hexylthiophene-2,5-diyl)(P3HT) has attracted intense research interest as hole-transporting materials(HTMs) in solid-state dye-sensitized solar cells(ss-DSCs).Nevertheless, pristine P3HT-based devices typically exhibit relatively poor overall performance, mainly due to its relatively low conductivity.Herein, we have successfully incorporated tetrafluoro-tetracyano-quinodimethane(F4TCNQ) as an efficient p-type dopant for P3HT as a HTM in ss-DSCs.The introduction of F4TCNQ(1.0%, w/w) into P3HT film results in a significant increase of the bulk conductivity(more than 20 times), which dramatically improves the photovoltaic parameters, in particular, for the short-circuit current density and fill factor, leading to impressive power conversion efficiency(PCE) of 5.0%.This is the highest reported value for P3HT-based HTMs in ss-DSCs.Thus, molecualrly p-doping has been demonstrated to be an effective strategy for improving the electrical property and thereby the overall performance of ss-DSCs based on P3HT as a HTM.
Conducting polymer poly(3-hexylthiophene-2,5-diyl)(P3HT) has attracted intense research interest as hole-transporting materials(HTMs) in solid-state dye-sensitized solar cells(ss-DSCs).Nevertheless, pristine P3HT-based devices typically exhibit relatively poor overall performance, mainly due to its relatively low conductivity.Herein, we have successfully incorporated tetrafluoro-tetracyano-quinodimethane(F4TCNQ) as an efficient p-type dopant for P3HT as a HTM in ss-DSCs.The introduction of F4TCNQ(1.0%, w/w) into P3HT film results in a significant increase of the bulk conductivity(more than 20 times), which dramatically improves the photovoltaic parameters, in particular, for the short-circuit current density and fill factor, leading to impressive power conversion efficiency(PCE) of 5.0%.This is the highest reported value for P3HT-based HTMs in ss-DSCs.Thus, molecualrly p-doping has been demonstrated to be an effective strategy for improving the electrical property and thereby the overall performance of ss-DSCs based on P3HT as a HTM.
引文
[1]G.K.Mor,S.Kim,Nano Lett,2009,9,4250.
[2]P.Pingel,D.Neher,Phys.Rev.B,2013,87,269.
[2]P.Pingel,D.Neher,Phys.Rev.B,2013,87,269.