基于金属氧化物与聚合物的可印刷复合界面层的制备及在有机能电池和钙钛矿电池中的应用
详细信息 查看官网全文
- 英文论文题名：Composite Interfacial Layer Based on Metal Oxides and Polymer for Organic and Perovskite Solar Cells
- 论文作者：武娜 ; 王宜玲 ; 贾晓瑞 ; 魏俊峰 ; 张连萍 ; 马昌期 ; 骆群
- 英文论文作者：Na Wu ; Yiling Wang ; Xiaorui Jia ; Junfeng Wei ; Lianping Zhang ; Chang-Qi Ma ; Qun Luo ; Printable Electronic Research Center ; Suzhou Institute of Nano-Tech and Nano-Bionics ; Chinese Academy of Sciences
- 年：2016
- 作者机构：中国科学院苏州纳米技术与纳米仿生研究所印刷电子研究中心;
- 论文关键词：有机太阳能电池 ; 钙钛矿电池 ; 复合界面层 ; 可印刷 ; 厚度依赖性
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第二十二分会：有机光伏的机遇和挑战
- 语种：中文
- 分类号：TM910
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第二十二分会 ; 有机光伏的机遇和挑战
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：187k
- 原文格式：D
- 会议级别：全国
摘要
在可印刷有机太阳能电池和平面型钙钛矿电池中,界面层起到表面填平、电极功函数修饰、电荷选择性注入和传输等作用。界面层薄膜的宏观和微观性质对器件制备工艺,获得的器件性能,以及器件长时间工作中的稳定性都有很大的影响。针对目前对高成膜质量以及低厚度依赖性可印刷界面层的开发需求,我们研制了一类基于金属氧化物纳米粒子-聚合物的复合物。~(1-4)这类复合物材料结合了金属氧化物导电性能好和聚合物成膜性好的优势;用于有机光伏和钙钛矿电池器件中,表现出表面缺陷少、电荷输运能力强、厚度敏感性低、可印刷性强、器件稳定性提高的特点。本报告将介绍我们在开发可印刷界面层及大面积光伏器件制备方面的一些工作,包括材料合成、材料光电性能、在器件上的效应及相关机制。
In the organic or perovskite solar cells, interfacial layer plays an important role with the functions of work function modification, substrates smoothening, carrier selectively extraction. In general, the commonly used interfacial layers both for cathode buffer layer and anode buffer layer include metal oxides, conjugated or non-conjugated polymer, fullerene and non-fullerene small molecular. Nowadays, composite combining inorganic nanoparticles and polymer is emerging to improve the film formation quality of inorganic nanoparticles and lower the thickness sensitivity of polymer materials. In this respect, we have developed a series of nano-composites based on metal oxides and polymer for application in organic and perovskite solar cells, including cathode ~([1-2]) and anode buffer layers. ~([3-4]) The results demonstrate these composite interfacial layer based organic and perovskite solar cells show prominent properties of high conversion efficiency, low thickness dependence and improved device stability. These results show the attraction of organic –inorganic nano-composite as potential interfacial layer for high efficiency and stable organic optoelectric devices.
In the organic or perovskite solar cells, interfacial layer plays an important role with the functions of work function modification, substrates smoothening, carrier selectively extraction. In general, the commonly used interfacial layers both for cathode buffer layer and anode buffer layer include metal oxides, conjugated or non-conjugated polymer, fullerene and non-fullerene small molecular. Nowadays, composite combining inorganic nanoparticles and polymer is emerging to improve the film formation quality of inorganic nanoparticles and lower the thickness sensitivity of polymer materials. In this respect, we have developed a series of nano-composites based on metal oxides and polymer for application in organic and perovskite solar cells, including cathode ~([1-2]) and anode buffer layers. ~([3-4]) The results demonstrate these composite interfacial layer based organic and perovskite solar cells show prominent properties of high conversion efficiency, low thickness dependence and improved device stability. These results show the attraction of organic –inorganic nano-composite as potential interfacial layer for high efficiency and stable organic optoelectric devices.
引文
[1]Wu,N.;Luo,Q.;Bao,Z.M.;Lin,J.;Li,Y.-Q.;Ma,C.-Q.Sol.Energy Mat.Sol.Cells,2015,141:248-259.
[2]Jia,X.R.;Wu,N.;Wei,J.F.;Luo,Q.;Zhang,L.P.;Bao,Z.M.;Li,Y.-Q.;Ma,C.-Q.Unpublished.
[3]Wang,Y.L.;Luo Q.;Wu N.;Wang,Q.K.;Zhu,H.F.;Chen,L.W.;Li,Y.-Q.;Luo,L.Q.;Ma,C.-Q.ACS Appl.Mater.Interface 2015,7:7170-7179.
[4]Wang,Y.L.;Luo,Q.;Wu,N.;Bao,Z.M.;Li,Y.-Q.;Luo,L.Q.;Ma,C.-Q.Unpublished.
[2]Jia,X.R.;Wu,N.;Wei,J.F.;Luo,Q.;Zhang,L.P.;Bao,Z.M.;Li,Y.-Q.;Ma,C.-Q.Unpublished.
[3]Wang,Y.L.;Luo Q.;Wu N.;Wang,Q.K.;Zhu,H.F.;Chen,L.W.;Li,Y.-Q.;Luo,L.Q.;Ma,C.-Q.ACS Appl.Mater.Interface 2015,7:7170-7179.
[4]Wang,Y.L.;Luo,Q.;Wu,N.;Bao,Z.M.;Li,Y.-Q.;Luo,L.Q.;Ma,C.-Q.Unpublished.