摘要
近红外光是近年来备受瞩目的一类新型远程刺激手段,具有清洁、生物穿透能力强等诸多优点。发展近红外光响应的聚合物体系在生物医疗、电子器件、能源转换等领域具有重要的价值。然而,对近红外光直接产生响应的聚合物材料较少。基于光热转换的概念,我们将能吸收近红外光的"黑材料"与聚合物基材相结合,成功地将有限的近红外光响应材料范畴拓展到多类聚合物体系。例如,我们以聚乳酸作为模板基材,在合适的乳化条件下,实现了聚乳酸与近红外响应基元的结合,成功发展了一系列具有治疗失控炎症、酶催化或气体吸附及分离功能的体系。
Owing to its outstanding performance, near infrared(NIR) light is rising an attractive actuator for exploiting smart materials and functional devices. Yet polymers with ability of NIR light absorption are sparse because few chemical bonds can be directly triggered by NIR light photons. Herein, we combined traditional biocompatible polymers, e.g. PLA, with photothermal agents for expanding the use of NIR light in polymer areas. Several controllable emulsion systems involving PLA and special photothermal agents were developed, aiming to fabricate polymer particles with function of inhibiting uncontrolled inflammation, enzyme catalysis, or gas separation.
引文
[1]Wang,J.;Zhao,J.;Li,Y.;Yang,M.;Zhang,Y.-Q.;Zhang,J.-P.;Sun,Z.;Wang,Y.ACS Macro Lett.2015,4:392.
[2]Cao,Y.;Wang,Z.;Liao,S.;Wang,J.;Wang,Y.Chem.Eur.J.2016,22:1152.