摘要
本文在Al-Mg-Sn合金基础上,开发出一种高性能的Al-Mg-Sn-In合金阳极。Tafel曲线和P-t曲线测试结果表明,该合金作为铝空气电池阳极比Al-Mg-Sn合金和高纯铝具有更高的电化学溶解活性和更低的自腐蚀速率。其比能量可达到2428.5W·h kg-1。
On the basis of Al-Mg-Sn alloy,a kind of Al-Mg-Sn-In alloy anode with high performance was developed.The results of Tafel curves and P-t curves show that this alloy has a higher electrochemical dissolution activity and a lower self- corrosion rate than Al- Mg- Sn alloy and high purity aluminum when used as the anode of aluminum air battery.Its specific energy can reach to 2428.5W · h kg~1.
引文
[1]Zhang X,Yang S H,Knickle H.Novel operation and control of anelectric vehicle aluminum/air battery system[J],Journal of Power Sources,128(2004)331-342.
[2]D.R.Egan,C.Ponce de Leon,R.J.K.Wood.Developments in electrode materials and electrolytes for aluminumair batteries[J],Journal of Power Sources,236(2013)293-310.
[3]J.A.Hunter,G.M.Scamans,W.B.O'Callaghan,P.A.Wycliffe.Aluminium batteries[P].United States Patent 5,004,654,2 April 1991.
[4]MokhtarMarliyana,TalibMeorZainalMeor,MajlanEdyHerianto.Recent developments in materials for aluminum-air batteries:A review[J].Journal of Industrial and Engineering Chemistry,32(2015)1-20.
[5]E.J.Rudd,D.W.Gibbons.High Energy Density aluminum/oxygen cell[J],Journal of Power Sources,47(1994)329-340.
[6]蔡年生.电池用铝合金的开发应用[J].铝加工,19%,19(4):44-46.