废弃贝壳高附加值资源化利用
|
摘要
本研究着力解决固体废弃物贝壳资源化利用难题及评估我国贝类养殖对海洋碳循环的贡献。以废弃贝壳为原料制备了生物填料,并对其表介面特性进行了研究。将制备的生物填料填充到聚丙烯和聚氯乙烯中,对贝壳填料聚丙烯复合材料力学性能和结晶性能以及贝壳填料聚氯乙烯复合材料力学性能进行了考察。对厚壳贻贝壳粉体的抗霉性能进行了研究。主要研究内容和结果如下：
(1)以2001年到2010年的年平均产量计算、评估了贝类捕获和养殖的碳沉积能力,并评估了其碳沉积潜力。我国近十年贝类年产量稳定在1100万吨以上,其中海水养殖贝类约占87.34%。贝类养殖和捕获总产量的碳沉积和海水养殖产量的碳沉积量分别为58.57、51.15万吨／年,碳沉积能力分别相当于122.28、106.78万公顷的造林,可分别减少大气C02增加量的0.0125%、0.0109%。
(2)以废弃珍珠贝壳为原料,经去除角质层、分离棱柱层,得到珍珠层。然后采用机械研磨得到生物填料(ZZB),对其表介面特性研究表明,其主要成分为文石型碳酸钙,成片状,粒径大小约为100～500nm,有机物含量约为3.87%,热稳定性良好。表面元素平均原子含量(%)为Ca(14.43)、C(33.54)、O(50.40)、N(1.62),其中有机物中各元素实际含量原子比(%)为：C(68.64)、O(25.54)、N(5.82)；表面含有(CH2)n-、MeCH2NH2、MeCOOH等有机基团。ZZB粉体具有亲水、亲油的双亲性,对正庚烷浸润,对水的接触角约为23.40。
(3)以废弃河蚌壳为原料,去除角质层,分离棱柱层和珍珠层,分别机械研磨得到珍珠层生物填料(HBZZC)和棱柱层生物填料(HBLZC)。它们的主要成分都为文石型碳酸钙,热稳定性良好,但HBZZC粉体成片状,粒径大小为40-1000nm,有机物含量约为4.34%,而HBLZC粉体成柱状、长条状,粒径分布范围为1～10μm,有机物含量约为2.20%。HBZZC粉体表面元素平均原子含量(%)为Ca(8.71),C(45.17),O(43.79),N(2.33),其中有机物中各元素实际含量原子比(%)约为：C(64.59),O(31.28),N(4.13)；HBLZC粉体表面元素平均原子含量(%)为Ca(12.10),C(33.63),O(51.35),N(2.93),其中有机物中各元素实际含量原子比(%)约为：C(54.49),O(38.09),N(7.42)。二者都具有亲水、亲油双亲性,都对正庚烷浸润,对水的接触角分别为24.5°和32°。
(4)以废弃厚壳贻贝壳、紫贻贝壳为原料分别制备的生物填料YBCC和ZYBCC粉体,其主要成分都为文石型碳酸钙,成片状,有机物含量分别约为2.04%、2.68%,热稳定性良好。YBCC、ZYBCC粉体对mm/YBCC、mm/ZYBCC复合材料具有增强作用,当YBCC、ZYBCC填充比例为3%时,mm/YBCC、 mm/ZYBCC复合材料的屈服强度达最大,分别比mm高了11.1%、6.8%。YBCC、 ZYBCC对mm具有异相成核作用,对mm结晶度与熔点影响较小,可诱导mm形成p-晶,提高mm/YBCC、mm/ZYBCC复合材料结晶度。YBCC对mVC/YBCC复合材料力学性能的影响与无机改性碳酸钙(方解石型碳酸钙)类似,无显著差异。
(5)将厚壳贻贝壳粉体添加到聚乙烯醇(mVA)中制成涂料试板,研究其抗霉性能,只在涂料试板表面边缘上有少量的霉菌生长,生霉面积为1%,长霉等级0<1级,具有较好的抗霉作用。
This study was aimed to settle the resource utilization problem of the waste shellfish shell and evaluate the contribution of shellfish culture in china on the ocean carbon cycle. Several kinds of bio-fillers were prepared from the waste shellfish shell and their surface properties were characterized. The mechanical properties and crystallization properties of molypropylene/calcium carbonate composite materials and polyvinyl chloride/calcium carbonate composite materials were researched. The anti-fungi performance of the shellfish shell powder was studied too. The main contents and results were as follows:
(1) motential ability of carbon deposition of shellfish of China was calculated and evaluated by the10year average yield of fishing shellfish and culturing shellfish production from2001year to2010year based on China Fishery Statistics Yearbook. Analysis shows that the total yield of shellfish is stable and more than110million tons with an increasing trend and the mariculture shellfish is account for about87.34%. The total carbon deposition of shellfish aquaculture and capture and the amount of carbon deposition of the mariculture shellfish are approximately585.7,511.5thousand tons per year which are equivalent to about1222.8and1067.8thousand hectares afforestation for carbon deposition and can reduce the increasing amount of CO2in the atmosphere by approximately0.0125%and0.0109%respectively. Carbon deposition rates of oyster, clam, scallop and mussel are1.573,0.388,0.301and1.039tons C ha-1yr-1separately. The carbon deposition rates of oyster and mussel with consumption of economic value are higher than the forest (0.479tons C ha-1yr-1), but lower than the coral reefs (1.8tons C ha-1yr-1). The effect of using the shellfish for carbon deposition is superior to capture and archive CO2directly into deep sea though carbon capture and storage engineering. Freshwater culture shellfish and mariculture shellfish can create carbon credit opportunities by2.684million yuan and127.112million yuan separately per year in China.
(2) Granule of pearl oyster shell bio-filler (ZZB) was prepared from waste pearl oyster shell by removing cuticle, separating prismatic layer and the left nacreous layer was grinded. The characterization results of ZZB show that the mainly composition of ZZB is aragonite (CaCO3) platelets and the particle size distribution range of ZZB powder is from100nm to500nm, the proportion of organic components of ZZB is about3.87%and with a good thermal stability. Calcium, carbon, oxygen and nitrogen contents on the surface of ZZB determined by XmS are14.43%,33.54%,50.40%and1.62%respectively, while the actual contents of carbon, oxygen and nitrogen of the organic matter within the ZZB powder are approximately68.64%,25.54%and5.82%separately; organic groups of (CH2)n-, MeCH2NH2and MeCOOH may be existing on its surface. Both lipophilic and hydrophilic properties of ZZB powder are significantly. N-heptane spreads out on the ZZB powder and the water contact angle is about23.4°.
(3) Removing cuticle, separating nacreous layer and prismatic layer of freshwater mussel shell, then the bio-filler HBZZC and HBLZC were prepared by mechanical grinding from the nacreous layer and prismatic layer of thick shell mussel (mytilus coruscus gould) shell respectively. The characterization results of HBZZC and HBLZC show that the mainly compositions of both of the HBZZC and HBLZC filler are aragonite (CaCO3) platelets and the particle size distribution ranges of HBZZC and HBLZC powder are40-1000nm and1～10μm VHSDUDHOY, thH proportions of organic components of HBZZC and HBLZC particles are about4.34%and2.20%respectively and both of them are being with a good thermal stability. Calcium, carbon, oxygen and nitrogen contents on the surface of HBZZC determined by XmS are8.71%,45.17%,43.79%and2.33%respectively, while the actual contents of carbon, oxygen and nitrogen of the organic matter within the HBZZC powder are approximately64.59%,31.28%and4.13%separately. Calcium, carbon, oxygen and nitrogen contents on the surface of HBLZC determined by XmS are12.10%,33.63%,51.35%and2.93%respectively, while the actual contents of carbon, oxygen and nitrogen of the organic matter within the HBLZC powder are approximately54.49%,38.09%and7.42%separately. Both of hydrophilic property and lipophilic property of HBZZC and HBLZC powder are significantly. N-heptane spreads out on the HBZZC and HBLZC powder and the water contact angles are about24.5°and32°respectively.
(4) Bio-filler YBCC and ZYBCC were prepared from waste thick shell mussel (mytilus coruscus gould) shell and mytilus edulis shell by removing cuticle, crushing, grinding and shearing emulsification and was introduced as a filler to reinforce polypropylene (PP) and Polyvinyl chloride (PVC). The characterization results of YBCC and ZYBCC show that the mainly compositions of both YBCC and ZYBCC are aragonite (CaCO3) platelets, the proportion of organic components of YBCC and ZYBCC are about2.04%and2.68%respectively and being with a good thermal stability. The mechanical behavior of PP/YBCC and PP/ZYBCC composites show a higher yield strain, yield strength, tensile strength and elongation at break than traditional commercial calcium carbonate (CMCC) filled PP. The yield strength of PP/YBCC and PP/ZYBCC composites with3%YBCC and ZYBCC are improved by about11.1%and6.8%respectly. YBCC and ZYBCC can promote the heterogeneous nucleation for PP crystallization and the formation β-crystalline PP. The mechanical behavior of PP/PVC composites show no significant differences with the traditional commercial calcium carbonate (CMCC) filled PP.
(5) The YBCC powder was added into the Polyvinyl alcohol (PVA) for preparing the coating test plate for researching its anti-mold properties. The experimental results show that the anti-mold properties of the YBCC powder are well, the mildew area of the coating test plate surface is1%and the fungi-growth grade is0<1.
(1)以2001年到2010年的年平均产量计算、评估了贝类捕获和养殖的碳沉积能力,并评估了其碳沉积潜力。我国近十年贝类年产量稳定在1100万吨以上,其中海水养殖贝类约占87.34%。贝类养殖和捕获总产量的碳沉积和海水养殖产量的碳沉积量分别为58.57、51.15万吨／年,碳沉积能力分别相当于122.28、106.78万公顷的造林,可分别减少大气C02增加量的0.0125%、0.0109%。
(2)以废弃珍珠贝壳为原料,经去除角质层、分离棱柱层,得到珍珠层。然后采用机械研磨得到生物填料(ZZB),对其表介面特性研究表明,其主要成分为文石型碳酸钙,成片状,粒径大小约为100～500nm,有机物含量约为3.87%,热稳定性良好。表面元素平均原子含量(%)为Ca(14.43)、C(33.54)、O(50.40)、N(1.62),其中有机物中各元素实际含量原子比(%)为：C(68.64)、O(25.54)、N(5.82)；表面含有(CH2)n-、MeCH2NH2、MeCOOH等有机基团。ZZB粉体具有亲水、亲油的双亲性,对正庚烷浸润,对水的接触角约为23.40。
(3)以废弃河蚌壳为原料,去除角质层,分离棱柱层和珍珠层,分别机械研磨得到珍珠层生物填料(HBZZC)和棱柱层生物填料(HBLZC)。它们的主要成分都为文石型碳酸钙,热稳定性良好,但HBZZC粉体成片状,粒径大小为40-1000nm,有机物含量约为4.34%,而HBLZC粉体成柱状、长条状,粒径分布范围为1～10μm,有机物含量约为2.20%。HBZZC粉体表面元素平均原子含量(%)为Ca(8.71),C(45.17),O(43.79),N(2.33),其中有机物中各元素实际含量原子比(%)约为：C(64.59),O(31.28),N(4.13)；HBLZC粉体表面元素平均原子含量(%)为Ca(12.10),C(33.63),O(51.35),N(2.93),其中有机物中各元素实际含量原子比(%)约为：C(54.49),O(38.09),N(7.42)。二者都具有亲水、亲油双亲性,都对正庚烷浸润,对水的接触角分别为24.5°和32°。
(4)以废弃厚壳贻贝壳、紫贻贝壳为原料分别制备的生物填料YBCC和ZYBCC粉体,其主要成分都为文石型碳酸钙,成片状,有机物含量分别约为2.04%、2.68%,热稳定性良好。YBCC、ZYBCC粉体对mm/YBCC、mm/ZYBCC复合材料具有增强作用,当YBCC、ZYBCC填充比例为3%时,mm/YBCC、 mm/ZYBCC复合材料的屈服强度达最大,分别比mm高了11.1%、6.8%。YBCC、 ZYBCC对mm具有异相成核作用,对mm结晶度与熔点影响较小,可诱导mm形成p-晶,提高mm/YBCC、mm/ZYBCC复合材料结晶度。YBCC对mVC/YBCC复合材料力学性能的影响与无机改性碳酸钙(方解石型碳酸钙)类似,无显著差异。
(5)将厚壳贻贝壳粉体添加到聚乙烯醇(mVA)中制成涂料试板,研究其抗霉性能,只在涂料试板表面边缘上有少量的霉菌生长,生霉面积为1%,长霉等级0<1级,具有较好的抗霉作用。
This study was aimed to settle the resource utilization problem of the waste shellfish shell and evaluate the contribution of shellfish culture in china on the ocean carbon cycle. Several kinds of bio-fillers were prepared from the waste shellfish shell and their surface properties were characterized. The mechanical properties and crystallization properties of molypropylene/calcium carbonate composite materials and polyvinyl chloride/calcium carbonate composite materials were researched. The anti-fungi performance of the shellfish shell powder was studied too. The main contents and results were as follows:
(1) motential ability of carbon deposition of shellfish of China was calculated and evaluated by the10year average yield of fishing shellfish and culturing shellfish production from2001year to2010year based on China Fishery Statistics Yearbook. Analysis shows that the total yield of shellfish is stable and more than110million tons with an increasing trend and the mariculture shellfish is account for about87.34%. The total carbon deposition of shellfish aquaculture and capture and the amount of carbon deposition of the mariculture shellfish are approximately585.7,511.5thousand tons per year which are equivalent to about1222.8and1067.8thousand hectares afforestation for carbon deposition and can reduce the increasing amount of CO2in the atmosphere by approximately0.0125%and0.0109%respectively. Carbon deposition rates of oyster, clam, scallop and mussel are1.573,0.388,0.301and1.039tons C ha-1yr-1separately. The carbon deposition rates of oyster and mussel with consumption of economic value are higher than the forest (0.479tons C ha-1yr-1), but lower than the coral reefs (1.8tons C ha-1yr-1). The effect of using the shellfish for carbon deposition is superior to capture and archive CO2directly into deep sea though carbon capture and storage engineering. Freshwater culture shellfish and mariculture shellfish can create carbon credit opportunities by2.684million yuan and127.112million yuan separately per year in China.
(2) Granule of pearl oyster shell bio-filler (ZZB) was prepared from waste pearl oyster shell by removing cuticle, separating prismatic layer and the left nacreous layer was grinded. The characterization results of ZZB show that the mainly composition of ZZB is aragonite (CaCO3) platelets and the particle size distribution range of ZZB powder is from100nm to500nm, the proportion of organic components of ZZB is about3.87%and with a good thermal stability. Calcium, carbon, oxygen and nitrogen contents on the surface of ZZB determined by XmS are14.43%,33.54%,50.40%and1.62%respectively, while the actual contents of carbon, oxygen and nitrogen of the organic matter within the ZZB powder are approximately68.64%,25.54%and5.82%separately; organic groups of (CH2)n-, MeCH2NH2and MeCOOH may be existing on its surface. Both lipophilic and hydrophilic properties of ZZB powder are significantly. N-heptane spreads out on the ZZB powder and the water contact angle is about23.4°.
(3) Removing cuticle, separating nacreous layer and prismatic layer of freshwater mussel shell, then the bio-filler HBZZC and HBLZC were prepared by mechanical grinding from the nacreous layer and prismatic layer of thick shell mussel (mytilus coruscus gould) shell respectively. The characterization results of HBZZC and HBLZC show that the mainly compositions of both of the HBZZC and HBLZC filler are aragonite (CaCO3) platelets and the particle size distribution ranges of HBZZC and HBLZC powder are40-1000nm and1～10μm VHSDUDHOY, thH proportions of organic components of HBZZC and HBLZC particles are about4.34%and2.20%respectively and both of them are being with a good thermal stability. Calcium, carbon, oxygen and nitrogen contents on the surface of HBZZC determined by XmS are8.71%,45.17%,43.79%and2.33%respectively, while the actual contents of carbon, oxygen and nitrogen of the organic matter within the HBZZC powder are approximately64.59%,31.28%and4.13%separately. Calcium, carbon, oxygen and nitrogen contents on the surface of HBLZC determined by XmS are12.10%,33.63%,51.35%and2.93%respectively, while the actual contents of carbon, oxygen and nitrogen of the organic matter within the HBLZC powder are approximately54.49%,38.09%and7.42%separately. Both of hydrophilic property and lipophilic property of HBZZC and HBLZC powder are significantly. N-heptane spreads out on the HBZZC and HBLZC powder and the water contact angles are about24.5°and32°respectively.
(4) Bio-filler YBCC and ZYBCC were prepared from waste thick shell mussel (mytilus coruscus gould) shell and mytilus edulis shell by removing cuticle, crushing, grinding and shearing emulsification and was introduced as a filler to reinforce polypropylene (PP) and Polyvinyl chloride (PVC). The characterization results of YBCC and ZYBCC show that the mainly compositions of both YBCC and ZYBCC are aragonite (CaCO3) platelets, the proportion of organic components of YBCC and ZYBCC are about2.04%and2.68%respectively and being with a good thermal stability. The mechanical behavior of PP/YBCC and PP/ZYBCC composites show a higher yield strain, yield strength, tensile strength and elongation at break than traditional commercial calcium carbonate (CMCC) filled PP. The yield strength of PP/YBCC and PP/ZYBCC composites with3%YBCC and ZYBCC are improved by about11.1%and6.8%respectly. YBCC and ZYBCC can promote the heterogeneous nucleation for PP crystallization and the formation β-crystalline PP. The mechanical behavior of PP/PVC composites show no significant differences with the traditional commercial calcium carbonate (CMCC) filled PP.
(5) The YBCC powder was added into the Polyvinyl alcohol (PVA) for preparing the coating test plate for researching its anti-mold properties. The experimental results show that the anti-mold properties of the YBCC powder are well, the mildew area of the coating test plate surface is1%and the fungi-growth grade is0<1.
引文
Addadi L, Weiner S, Geva M. On how proteins interact with crystals and their effect on crystal formation[J]. Zeitschrift fur Kardiologie,2001,90(15):92-98.
Addadi L, Weiner S. Biomineralization:a pavement of pearl[J]. Nature,1997, 389(6654):912-915.
Addadi L, Weiner S. Control and design principles in biological mineralization[J]. Angewandte Chemie International Edition in English,1992,31(2):153-169.
Arias J L, Neira-Carrillo A, Arias J I, et al. Sulfated polymers in biological mineralization:a plausible source for bio-inspired engineering[J]. Journal of Materials Chemistry,2004,14(14):2154-2160.
Atlan G, Delattre O, Berland S, et al. Interface between bone and nacre implants in sheep[J]. Biomaterials,1999,20(11):1017-1022.
Azizi H, Faghihi J. An investigation on the mechanical and dynamic rheological properties of single and hybrid filler/polypropylene composites based on talc and calcium carbonate[J]. Polymer Composites,2009,30(12):1743-1748.
Balmain J, Hannoyer B, Lopez E. Fourier transform infrared spectroscopy (ftir) and x-ray diffraction analyses of mineral and organic matrix during heating of mother of pearl (nacre) from the shell of the mollusc pinctada maxima[J]. Journal of Biomedical Materials Research,1999,48(5):749-754.
Barthelat F, Li C M, Comi C, et al. Mechanical properties of nacre constituents and their impact on mechanical performance [J]. Journal of Materials Research,2006, 21(8):1977-1986.
Barthelat F, Tang H, Zavattieri P D, et al. On the mechanics of mother-of-pearl:a key feature in the material hierarchical structure [J]. Journal of the Mechanics and Physics of Solids,2007,55(2):306-337.
Baumer A, Ganteaume M, Bernat M. Variations de la teneur en eau des coraux lors de la transformation aragonite→calcite:included water in corals for the transition aragonite→calcite[J]. Thermochimica Acta,1993,221(2):255-262.
Belcher A M, Wu X H, Christensen R J, et al. Control of crystal phase switching and orientation by soluble mollusc-shell proteins[J]. Nature,1996,381(6577):56-58.
Bin-Yang Z, Qiang Z, Chang-Feng C, et al. Structure and property characterization of oyster shell cementing material[J]. Chinese Journal of Structural Chemistry,2012, 31(1):85-92.
Blakemore R. Magnetotacticbacteria[J]. Science,1975,190(4212):377.
Brinker C J, Lu Y, Sellinger A, et al. Evaporation-induced self-assembly: nanostructures made easy[J]. Advanced Materials,1999,11(7):579-585.
Butler M F, Glaser N, Weaver A C, et al. Calcium carbonate crystallization in the presence of biopolymers[J]. Crystal Growth & Design,2006,6(3):781-794.
Campbell-Lendrum D, Corvalan C. Climate change and developing-country cities: implications for environmental health and equity [J]. Journal of Urban Health, 2007,84(1):109-117.
Castaneda C, Eeckhout S G, Costa G M, et al. Effect of heat treatment on tourmaline from brazil[J]. Physics and Chemistry of Minerals,2006,33(3):207-216.
Chan C M, Wu J, Li J X, et al. Polypropylene/calcium carbonate nanocomposites[J]. Polymer,2002,43(10):2981-2992.
Chan C, Wu J, Li J, et al. Polypropylene/calcium carbonate nanocomposites[J]. Polymer,2002,43(10):2981-2992.
Chen C H, Teng C C, Su S F, et al. Effects of microscale calcium carbonate and nanoscale calcium carbonate on the fusion, thermal, and mechanical characterizations of rigid poly (vinyl chloride)/calcium carbonate composites[J]. Journal of Polymer Science Part B:Polymer Physics,2006,44(2):451-460.
Chen P Y, Lin A, Lin Y S, et al. Structure and mechanical properties of selected biological materials[J]. Journal of the Mechanical Behavior of Biomedical Materials,2008,1(3):208-226.
Chen T Y, Li W F, Jun J D, et al. Modification of nanometre calcium carbonate and its application on pvc composites in situ suspension polymerisation[J]. Materials Science and Technology,2010,26(7):871-874.
Chowdhury S, Saha P. Sea shell powder as a new adsorbent to remove basic green 4 (malachite green) from aqueous solutions:equilibrium, kinetic and thermodynamic studies[J]. Chemical Engineering Journal,2010,164(1): 168-177.
Cobabe E A, Pratt L M. Molecular and isotopic compositions of lipids in bivalve shells:a new prospect for molecular paleontology[J]. Geochimica et Cosmochimica Acta,1995,59(1):87-95.
Cornwell D W, Rodary G. Modification of rigid pvc properties through effective use of synthetic calcium carbonates of controlled morphology and surface character[J]. Plastics, Rubber and Composites,2005,34(3):105-110.
Currey J D, Taylor J D. The mechanical behaviour of some molluscan hard tissues[JJ. Journal of Zoology,1974,173(3):395-406.
Currey J D, Zioupos P, Peter D, et al. Mechanical properties of nacre and highly mineralized bone[J]. Proceedings of the Royal Society of London. Series B: Biological Sciences,2001,268(1462):107-111.
Currey J D. Mechanical properties of mother of pearl in tension[J]. Proceedings of the Royal Society of London. Series B. Biological Sciences,1977,196(1125):443.
Dasgupta S, Laplante B, Meisner C, et al. The impact of sea level rise on developing countries:a comparative analysis[J]. Climatic Change,2007,93(3):379-388.
Dauphin Y, Denis A. Structure and composition of the aragonitic crossed lamellar layers in six species of bivalvia and gastropoda[J]. Comparative Biochemistry and Physiology-Part A:Molecular & Integrative Physiology,2000,126(3): 367-377.
Dauphin Y, Guzman N, Denis A, et al. Microstructure, nanostructure and composition of the shell of concholepas concholepas (gastropoda, muricidae)[J]. Aquatic Living Resources,2003,16(2):95-103.
Doney, S C, Fabry V J, Feely R A, et al. Ocean acidification:the other co2 problem[J]. Marine Science,2009,1:169-192.
Durner G M, Douglas D C, Nielson R M, et al. Predicting 21st-century polar bear habitat distribution from global climate models [J]. Ecological Monographs,2009, 79(1):25-58.
Eliel E L, Wilen S H. Stereochemistry of organic compounds[M]. Wiley-India.2008.
Engin B, Demirtas H, Eken M. Temperature effects on egg shells investigated by xrd, ir and esr techniques[J]. Radiation Physics and Chemistry,2006,75(2):268-277.
Etelaaho P, Haveri S, Jarvela P. Comparison of the morphology and mechanical properties of unmodified and surface-modified nanosized calcium carbonate in a polypropylene matrix[J]. Polymer Composites,2011,32(3):464-471.
Etelaaho P, Haveri S, Jarvela P. Comparison of the morphology and mechanical properties of unmodified and surface-modified nanosized calcium carbonate in a polypropylene matrix[J]. Polymer Composites,2011,32(3):464-471.
Falini G, Albeck S, Weiner S, et al. Control of aragonite or calcite polymorphism by mollusk shell macromolecules[J]. Science,1996,271(5245):67-69.
Falkowski P, Scholes R J, Boyle E, et al. The global carbon cycle:a test of our knowledge of earth as a system[J]. Science,2000,290(5490):291-296.
Fuad M, Hanim H, Zarina R, et al. Polypropylene/calcium carbonate nanocomposites-effects of processing techniques and maleated polypropylene compatibiliser[J]. Express Polymer Letters,2010.
Gao H, Chen H, Chen W, et al. Effect of nanometer pearl powder on calcium absorption and utilization in rats[J]. Food Chemistry,2008,109(3):493-498.
Gotliv B A, Addadi L, Weiner S. Mollusk shell acidic proteins:in search of individual functions[J]. ChemBioChem,2003,4(6):522-529.
Gotliv B A, Kessler N, Sumerel J L, et al. Asprich:a novel aspartic acid-rich protein family from the prismatic shell matrix of the bivalve atrina rigida[J]. ChemBioChem,2005,6(2):304-314.
Hansen J, Sato M, Ruedy R, et al. Global temperature change [J]. Proceedings of the National Academy of Sciences,2006,103(39):14288-14293.
Havenhand J N, Schlegel P. Near-future levels of ocean acidification do not affect sperm motility and fertilization kinetics in the oyster crassostrea gigas [J]. Biogeosciences,2009,6:3009-3015.
Herzog H J. What future for carbon capture and sequestration?[J]. Environmental Science & Technology,2001,35(7):148-153.
Heuer A H, Fink D J, Laraia V J, et al. Innovative materials processing strategies:a biomimetic approach[J]. Science,1992,255(5048):1098-1105.
Heywood B R, Mann S. Molecular construction of oriented inorganic materials: controlled nucleation of calcite and aragonite under compressed langmuir monolayers[J]. Chemistry of Materials,1994,6(3):311-318.
Hoegh-Guldberg O, Mumby P J, Hooten A J, et al. Coral reefs under rapid climate change and ocean acidification[J]. Science,2007,318(5857):1737-1742.
Houghton J. Global warming [J]. Reports on Progress in Physics,2005,68(6): 1343-1403.
Huang H, Han B, Wang L, et al. Crystallization kinetics of polypropylene composites filled with nano calcium carbonate modified with maleic anhydride[J]. Journal of Applied Polymer Science,2011,119(3):1516-1527.
Jackson A P, Vincent J, Turner R M. The mechanical design of nacre[J]. Proceedings of the Royal Society of London. Series B. Biological Sciences,1988,234(1277): 415-440.
Jacob D E, Soldati A L, Wirth R, et al. Nanostructure, composition and mechanisms of bivalve shell growth[J]. Geochimica et Cosmochimica Acta,2008,72(22): 5401-5415.
Jipa S, Zaharescu T, Supaphol P. Thermal stability of isotactic polypropylene modified with calcium carbonate nanoparticles[J]. Polymer Bulletin,2010,64(8): 783-790.
Jones G P, Mccormick M I, Srinivasan M, et al. Coral decline threatens fish biodiversity in marine reserves [J]. Proceedings of the National Academy of Sciences of the United States of America,2004,101(21):8251-8253.
Kamat S, Su X, Ballarini R, et al. Structural basis for the fracture toughness of the shell of the conch strombus gigas[J]. Nature,2000,405(6790):1036-1040.
Katti K S, Katti D R. Why is nacre so tough and strong[J]. Materials Science and Engineering:C,2006,26(8):1317-1324.
Khatiwala S, Primeau F, Hall T. Reconstruction of the history of anthropogenic co2 concentrations in the ocean[J]. Nature,2009,462(7271):346-349.
Kinderman G E, Obersteiner M, Sohngen B, et al. Global cost estimates of reducing carbon emissions through avoided deforestation[J] Proceedings of the National Academy of Sciences,2008,105(30):10302-10307.
Kleypas J A, Yates K K. Coral reefs and ocean acidification[J]. Oceanography,2009, 22(4):108-117.
Kobayashi I, Samata T. Bivalve shell structure and organic matrix[J]. Materials Science and Engineering:C,2006,26(4):692-698.
Kwon H B, Lee C W, Jun B S, et al. Recycling waste oyster shells for eutrophication control[J]. Resources, Conservation and Recycling,2004,41(1):75-82.
Lee C H, Lee D K, Ali M A, et al. Effects of oyster shell on soil chemical and biological properties and cabbage productivity as a liming materials [J]. Waste Management,2008,28(12):2702-2708.
Levi Y, Albeck S, Weiner S, et al. Control over aragonite crystal nucleation and growth:an in vitro study of biomineralization[J]. Chemistry-a European Journal, 1998,4(3):389-396.
Levi-Kalisman Y, Falini G, Addadi L, et al. Structure of the nacreous organic matrix of a bivalve mollusk shell examined in the hydrated state using cryo-tem[J]. Journal of Structural Biology,2001,135(1):8-17.
Li C, Botsaris G D, Kaplan D L. Selective in vitro effect of peptides on calcium carbonate crystallization[J]. Crystal Growth & Design,2002,2(5):387-393.
Li C, Champagne P. Fixed-bed column study for the removal of cadmium (ii) and nickel (ii) ions from aqueous solutions using peat and mollusk shells [J]. Journal of Hazardous Materials,2009,171(1):872-878.
Li X, Xu Z H, Wang R. In situ observation of nanograin rotation and deformation in nacre[J]. Nano Letters,2006,6(10):2301-2304.
Liang J Z. Evaluation of dispersion of nano-CaCO3 particles in polypropylene matrix based on fractal method[J]. Composites Part A:Applied Science and Manufacturing,2007,38(6):1502-1506.
Liao H, Brandsten C, Lundmark C, et al. Responses of bone to titania-hydroxyapatite composite and nacreous implants:a preliminary comparison by in situ hybridization[J]. Journal of Materials Science:Materials in Medicine,1997, 8(12):823-827.
Lin Y, Chen H, Chan C M, et al. The toughening mechanism of polypropylene/calcium carbonate nanocomposites[J]. Polymer,2010,51(14): 3277-3284.
Lorens R B, Bender M L. The impact of solution chemistry on mytilus edulis calcite and aragonite[J]. Geochimica et Cosmochimica Acta,1980,44(9):1265-1278.
Lowenstam H A, Weiner S. On biomineralization[M]. Oxford University Press, USA. 1989.
Ma X, Wei Q, Zhang S, et al. Isolation and bioactivities of organic acids and phenols from walnut shell pyroligneous acid[J]. Journal of Analytical and Applied Pyrolysis,2011,91(2):338-343.
Mai K, Zhang W, Tan B, et al. Effects of dietary zinc on the shell biomineralization in abalone haliotis discus hannai ino[J]. Journal of Experimental Marine Biology and Ecology,2003,283(1-2):51-62.
Mann S. Biomineralization:principles and concepts in bioinorganic materials chemistry[M]. Oxford University Press, USA.2001.
Mann S. Molecular recognition in biomineralization[J]. Nature,1988,332(6160): 119-124.
Manne S, Zaremba C M, Giles R, et al. Atomic force microscopy of the nacreous layer in mollusc shells[J]. Proceedings:Biological Sciences,1994,256(1345): 17-23.
Marin F, Luquet G, Marie B, et al. Molluscan shell proteins:primary structure, origin, and evolution[J]. Current Topics in Developmental Biology,2007,80:209-276.
Marin F, Luquet G. Molluscan biomineralization:the proteinaceous shell constituents of pinna nobilis 1.[J]. Materials Science and Engineering:C,2005,25(2): 105-111.
Marin F, Luquet G Molluscan shell proteins[J]. Comptes Rendus Palevol,2004, 3(6-7):469-492.
Marxen J C, Hammer M, Gehrke T, et al. Carbohydrates of the organic shell matrix and the shell-forming tissue of the snail biomphalaria glabrata (say)[J]. The Biological Bulletin,1998,194(2):231.
Mckibben B. Carbon's new math[J]. National Geographic,2007,212(4):33-34.
Meyers M A, Lin A Y M, Chen P Y, et al. Mechanical strength of abalone nacre:role of the soft organic layer[J]. Journal of the Mechanical Behavior of Biomedical Materials,2008,1(1):76-85.
Mihara Y, Takada T, Uno N. Antibacterial and antifungal effects of fired scallop shell-glass composites fabricated by a simple process [J]. Journal of the Ceramic Society of Japan,2008,6(116):1-4.
Miller A W, Reynolds A C, Sobrino C, et al. Shellfish face uncertain future in high co2 world:influence of acidification on oyster larvae calcification and growth in estuaries[J]. PLoS One,2009,4(5):e5661.
Miyamoto H, Miyashita T, Okushima M, et al. A carbonic anhydrase from the nacreous layer in oyster pearls [J]. Proceedings of the National academy of Sciences of the United States of America,1996,93(18):9657.
Naemchan K, Meejoo S, Onreabroy W, et al. Temperature effect on chicken egg shell investigated by xrd, tga and ftir[J]. Advanced Materials Research,2008,55: 333-336.
Nakahara H, Kakei M, Bevelander G Electron microscopic and amino acid studies on the outer and inner shell layers of haliotis rufescens[J]. Venus (Japan),1982, 41(1):33-46.
Nakamura Y, Fukuoka Y, Iida T. Tensile test of poly (vinyl chloride) filled with ground calcium carbonate particles[J]. Journal of Applied Polymer Science,1998, 70(2):311-316.
Njoyim-Tamungang E, Laminsi S, Ghogomu P, et al. Pollution control of surface waters by coupling gliding discharge treatment with incorporated oyster shell powder[J]. Chemical Engineering Journal,2011,173(2):303-308.
Nudelman F, Gotliv B A, Addadi L, et al. Mollusk shell formation:mapping the distribution of organic matrix components underlying a single aragonitic tablet in nacre[J]. Journal of Structural Biology,2006,153(2):176-187.
Oikawa K, Asada T, Yamamoto K, et al. Antibacterial activity of calcined shell calcium prepared from wild surf clam[J]. Journal of Health Science,2000,46(2): 98-103.
Oladoja N A, Aliu Y D. Snail shell as coagulant aid in the alum precipitation of malachite green from aqua system[J]. Journal of Hazardous Materials,2009, 164(2-3):1496-1502.
Ren F, Wan X, Liu P, et al. Microstructure and infra-red spectra analysis of mussel shell[J]. Journal of Henan University of Science & Technology (Natural Science), 2007,28(1):1-5.
Ren F, Wan X, Ma Z, et al. Study on microstructure and thermodynamics of nacre in mussel shell[J]. Materials Chemistry and Physics,2009,114(1):367-370.
Rodhe H. A comparison of the contribution of various gases to the greenhouse effect[J]. Science,1990,248(4960):1217-1219.
Rousseau M, Lopez E, Stempfle P, et al. Multiscale structure of sheet nacre[J]. Biomaterials,2005,26(31):6254-6262.
Sarikaya M. An introduction to biomimetics:a structural viewpoint[J]. Microscopy Research and Technique,1994,27(5):360-375.
Sarmiento J L, Gruber N. Sinks for anthropogenic carbon[J]. Physics Today,2002, 55(8):30-36.
Shono M, Shimizu I, Aoyagi E, et al. Reducing effect of feeding powdered nacre of pinctada maxima on the visceral fat of rats[J]. Bioscience, Biotechnology, and Biochemistry,2008,72(10):2761-2763.
Sikes C S, Wheeler A P. Control of crystallization by polyanionic hydrophobic polypeptides[J]. Chemical aspects of regulation of mineralization. University of South Alabama Publication Service, Mobile, Alabama,1988,194:15-20.
Smith B L, Sch Ffer T E, Viani M, et al. Molecular mechanistic origin of the toughness of natural adhesives, fibres and composites[J]. Nature,1999, 399(6738):761-763.
Song F, Soh A K, Bai Y L. Structural and mechanical properties of the organic matrix layers of nacre[J]. Biomaterials,2003,24(20):3623-3631.
Song F, Zhou J, Xu X, et al. Effect of a negative poisson ratio in the tension of ceramics[J]. Physical Review Letters,2008,100(24):1-4.
Stickle W F, Sobol P E, Bomben K D. Handbook of x-ray photoelectron spectroscopy: a reference book of standard spectra for identification and interpretation of xps data[M]. Eden Prairie Minnesota:Perkin-Elmer Corporation.1992.1-261.
Sudo S, Fujikawa T, Nagakura T, et al. Structures of mollusc shell framework proteins[J]. Nature,1997,387(6633):563-564.
Takada T, Furusaki A, Tanaka Y. Formaldehyde reduction with scallop shell powders fired at high temperatures:identification of the effective ingredient[J]. Bio-Medical Materials and Engineering,2009,19(2):187-192.
Tanner L H, Hubert J F, Coffey B P, et al. Stability of atmospheric co2 levels across the triassic/jurassic boundary[J]. Nature,2001,411(6838):675-677.
Tong H, Hu J M, Ma W T, et al. In situ analysis of the organic framework in the prismatic layer of mollusc shell[J]. Biomaterials,2002,23(12):2593-2598.
Toro P, Quijada R, Yazdani-Pedram M, et al. Eggshell, a new bio-filler for polypropylene composites [J]. Materials Letters,2007,61(22):4347-4350.
Trenberth K. Uncertainty in hurricanes and global warming[J]. Science,2005, 308(5729):1753-1754.
Tyrrell T. Calcium carbonate cycling in future oceans and its influence on future climates[J]. Journal of Plankton Research,2008,30(2):141-156.
Vijayaraghavan K, Balasubramanian R. Single and binary biosorption of cerium and europium onto crab shell particles[J]. Chemical Engineering Journal,2010, 163(3):337-343.
Mayes W, Davis J, Silva V, et al. Treatment of zinc-rich acid mine water in low residence time bioreactors incorporating waste shells and methanol dosing[J]. Journal of Hazardous Materials,2011,193:279-287.
Wagner C D. Handbook of x-ray photoelectron spectroscopy[M]. Eden Prairie Minnesota:Perkin-Elmer Corporation.1981.25-69.
Waldbusser G G, Voigt E P, Bergschneider H, et al. Biocalcification in the eastern oyster (crassostrea virginica) in relation to long-term trends in chesapeake bay ph[J]. Estuaries and Coasts,2010,34:221-231.
Wang R Z, Suo Z,-Evans A G, et al. Deformation mechanisms in nacre [J]. Journal of Materials Research,2001,16(9):2485-2493.
Webster T J, Ergun C, Doremus R H, et al. Enhanced functions of osteoblasts on nanophase ceramics[J]. Biomaterials,2000,21(17):1803-1810.
Weiner S, Hood L. Soluble protein of the organic matrix of mollusk shells:a potential template for shell formation[J]. Science,1975,190(4218):987-989.
Weiner S, Traub W, Parker S B. Macromolecules in mollusc shells and their functions in biomineralization[J]. Philosophical Transactions of the Royal Society of London. B, Biological Sciences,1984,304(1121):425-434.
Weiner S. Separation of acidic proteins from mineralized tissues by reversed-phase high-performance liquid chromatography.[J]. Journal of Chromatography,1982, 245(1):148-152.
Wheeler A P, George J W, Evans C A. Control of calcium carbonate nucleation and crystal growth by soluble matrx of oyster shell[J]. Science,1981,212(4501): 1397-1398.
Wierzbicki A, Sikes C S, Madura J D, et al. Atomic force microscopy and molecular modeling of protein and peptide binding to calcite[J]. Calcified Tissue International,1994,54(2):133-141.
Worms D, Weiner S. Mollusk shell organic matrix:fourier transform infrared study of the acidic macromolecules [J]. Journal of Experimental Zoology,1986,237(1): 11-20.
Wu D, Wang X, Song Y, et al. Nanocomposites of poly (vinyl chloride) and nanometric calcium carbonate particles:effects of chlorinated polyethylene on mechanical properties, morphology, and rheology[J]. Journal of Applied Polymer Science,2004,92(4):2714-2723.
Xie L, Wang X X, Li J. The sem and tem study on the laminated structure of individual aragonitic nacre tablet in freshwater bivalve h. Cumingii lea shell[J]. Journal of Structural Biology,2010,169(1):89-94.
Yang L, Zhang X, Liao Z, et al. Interfacial molecular recognition between polysaccharides and calcium carbonate during crystallization[J]. Journal of Inorganic Biochemistry,2003,97(4):377-383.
Yoon G L, Kim B T, Kim B O, et al. Chemical-mechanical characteristics of crushed oyster-shell[J]. Waste Management,2003,23(9):825-834.
Yu Z, Xie L, Lee S, et al. A novel carbonic anhydrase from the mantle of the pearl oyster (pinctada fucata)[J]. Comparative Biochemistry and Physiology Part B: Biochemistry and Molecular Biology,2006,143(2):190-194.
Zhang J, Han B, Zhou N, et al. Preparation and characterization of nano/micro-calcium carbonate particles/polypropylene composites[J]. Journal of Applied Polymer Science,2011,119(6):3560-3565.
Zhang Q X, Yu Z Z, Xie X L, et al. Crystallization and impact energy of polypropylene/CaCO3 nanocomposites with nonionic modifier[J]. Polymer,2004, 45(17):5985-5994.
Zhang S, Zhang J, Zhang Z, et al. Preparation and characterization of self-assembled organic-inorganic nacre-like nanocomposite thin films[J]. Materials Letters,2004, 58(17-18):2266-2269.
Zhao Q, Liu Y, Abel E W. Effect of temperature on the surface free energy of amorphous carbon films[J]. Journal of Colloid and Interface Science,2004, 280(1):174-183.
Zhao Q, Liu Y, Abel E W. Surface free energies of electroless ni-p based composite coatings [J]. Applied Surface Science,2005,240(1):441-451.
Zuiderduin W C J, Westzaan C, Huetink J, et al. Toughening of polypropylene with calcium carbonate particles[J]. Polymer,2003,44(1):261-275.
蔡英亚.贝类学概论[M].上海科学技术出版社.1995.
曹光明,罗廉明.一种评价塑料填料粉体改性效果的新方法[J].化工矿物与加工,2002,31(4)：5-7.
曾敏莉,周远大.钙制剂的现状及发展趋势[J].儿科药学杂志,2004,10(3)：16-18.
曾名勇,陈胜军.海洋生物抗菌剂的研究进展[J].精细与专用化学品,2002,10(19)：3-6.
曾名勇,林洪,刘树青,等.海洋生物保鲜剂OP-Ca抗菌特性的研究[J].中国海 洋药物,2002,21(4)：27-31.‘
陈忱,赵杰,梁艳,等.鲍鱼壳的结构和力学性能[J].材料导报：纳米与新材料专辑,2009,23(14)：457-459.
陈忱.头足纲与腹足纲贝壳材料的结构和性能[D].大连：大连理工大学硕士学位论文,2009.
陈俊宏.二枚贝养殖的钙化作用与其碳隔离能力的评估[D].基隆：国立台湾海洋大学硕士学位论文,2010.
陈琪,邹胜祥.可溶性海洋生物钙强化食品开发[J].农村实用技术与信息,1999(11)：11-12.
陈士勇,王令充,嵇晶,等.双壳类贝壳的应用研究进展[J].中国海洋药物,2011,30(1)：58-64.
陈玉枝,林舒.牡蛎壳与龙骨成分的分析[J].福建医科大学学报,1999,33(4)：432-434.
董瑞娜,麦康森,张文兵,等.皱纹盘鲍贝壳沉积过程的研究[J].中国海洋大学学报(自然科学版),2006(S1)：63-70.
段杉,陈海梅,林秋峰,等.贝壳煅烧物的防腐作用研究[J].中国食品添加剂,2007(6)：74-78.
范昌福,王宏,裴艳东,等.牡蛎壳体的同位素贝壳年轮研究[J].地球科学进展,2010,25(2)：163-173.
范克雷维伦D.W.聚合物的性质-性质的估算及其与化学结构的关系[M].北京：科学出版社.1981.127.
非金属化工网.世界重质碳酸钙10大著名生产企业[EB/OL].(2009-09-26)[2012-04-19].http://www.fj198.com/newsfile/2009-09-26/20092026092053.aspx.
冯庆玲,侯文涛.碳酸钙生物矿化的体外研究进展[J].清华大学学报(自然科学版),2006(12)：2019-2023.
高长云,齐军.聚丙烯/纳米碳酸钙复合材料性能的研究[J].橡塑技术与装备,2010,36(12)：1-5.
国家统计局,环境保护部.中国环境统计年鉴2010[M].中国统计出版社.2010.47.
韩琛,汪家宝,沈玉海,等.纳米CaCO3/PP复合材料的制备与性能研究[J].塑料工业,2008,36(5)：22-24.
韩启成.仿生叠层复合材料研究[D].镇江：江苏大学硕士学位论文,2002.
韩玉香,韩平,王永富,等.固体表面自由能及其分量的计算方法(Ⅰ)——接触角法[J].辽宁师范大学学报(自然科学版),1995,18(3)：214-216.
洪鹏志,章超桦.牡蛎壳制备活性钙[J].湛江海洋大学学报,2000,20(4)：46-49.
侯东芳,周根树,郑茂盛.贝壳珍珠层层间断口及死亡期的XPS研究[J].材料科学与工程学报,2004,22(6)：838-841.
侯东芳,周根树,郑茂盛.贝壳珍珠层断裂过程的原位观察及其增韧机制分析[J].材料科学与工程学报,2007,25(3)：388-391.
胡庆福,刘祝增,刘树文.碳酸钙产品分类与命名建议[J].无机盐工业,2008,40(3)：1-3.
胡学寅,周丽丽,齐兴义.贝壳吸附材料的制备与表征[J].应用科技,2008,35(3)：70-72.
黄广民,黄必春,肖红,等.双烧法从贝壳中制备葡萄糖酸钙[J].食品工业,2002,23(3)：24-26.
黄玉松,郑威,辛培训,等.贝壳珍珠层结构仿生复合材料研究[J].工程塑料应用,2008,36(10)：21-25.
江敏,李鉴,梁洁玲,等.牡蛎壳合成L-乳酸钙的工艺研究[J].食品科技,2008,33(3)：123-141.
蒋学文.贝壳微粉改性环氧树脂复合材料的制备及性能研究[D].兰州：兰州大学硕士学位论文,2007.
焦其帅,胡永琪,陈瑞珍,等.改性针形纳米碳酸钙在PVC中的应用研究[J].中国塑料,2011,25(9)：79-84.
郎萌萌.有机基质调控碳酸钙的仿生合成及其改性PVC研究[D].保定：河北大学硕士学位论文,2011.
李晶,黄丽.防腐阻燃型玻璃鳞片/环氧树脂涂料的性能[J].北京化工大学学报(自然科学版),2009(S1)：37-41.
李茂春,刘程.碳酸钙表面改性研究进展[J].聚氯乙烯,2010,38(8)：5-8.
李耐刚,生瑜,朱德钦,等.大分子键合处理CaCO3的表面性质及其与PVC的界面特性[J].聚氯乙烯,2006(5)：15-17.
李泳,张兆霞.以牡蛎壳粉作载体对维生素C和维生素E的抗氧化包合作用研究[J].云南化工,2009,36(1)：18-20.
梁金生,孟军平,朱东彬,等.热处理对电气石矿物粉体表面自由能的影响[J].硅酸盐学报,2008,36(2)：257-260.
梁艳,赵杰,王来,等.贝壳的力学性能和增韧机制[J].机械强度,2007,29(3)：507-511.
梁艳,赵杰,王来,等.贝壳的有机质及生物矿化机制分析[J].生物学杂志,2006,23(6)：19-23.
梁艳,赵杰,吴承伟.贝壳中交错纹状的结构对力学性能的影响[J].功能材料,2010,3(41)：459-465.
林秀玲.贝壳热分解行为的研究及对聚合物热降解的影响[D].安徽淮南：安徽理工大学硕士学位论文,2006.
刘必林,陈新军.头足类贝壳研究进展[J].海洋渔业,2010,32(3)：332-339.
刘方斌.碳酸钙产业结构矛盾突出[EB/OL]. (2011-07-29) [2012-04-19]. http://www.baogao.com/freereport/47100.html.
刘克松,江雷.仿生结构及其功能材料研究进展[J].科学通报,2009,54(18)：2667-2681.
刘小风,钟宏.不同形态纳米碳酸钙的研究进展[J].上海涂料,2009,47(4)：22-25.
刘晓军,闫振广,郑桂兰,等.一个有关双壳贝类贝壳年轮纹可能的形成机理[J].中国科学：生命科学,2011,41(1)：46-52.
刘亚雄.纳米碳酸钙填充PVC的分散研究[J].广东化工,2010,37(9)：51-52.
柳华,薄伟.纳米碳酸钙在填充PVC中的应用分散性研究[J].中国西部科技,2011,10(6)：39-40.
陆现彩,侯庆锋,尹琳,等.几种常见矿物的接触角测定及其讨论[J].岩石矿物学杂志,2003,22(4)：397-400.
马强,刘宇,李小静,等.贝壳填料曝气生物滤池处理污水试验研究[J].大连民族学院学报,2010,12(3)：287.
马文涛,沈亦平,曹连欣.贝壳有机质对CaCO3晶型形成的控制作用[J].武汉大学学报(自然科学版),1996,42(4)：469-474.
马治军,杨景辉,吴秋芳.聚丙烯酸酯/纳米碳酸钙复合增韧PVC的研究[J].塑料工业,2011,39(3)：67-70.
苗艳丽,洪鹏志,宋文东,等.以牡蛎壳粉-CMC为载体制备阿司匹林胃漂浮片的研究[J].药学实践杂志,2008,26(4)：264-266.
农业部渔业局.中国渔业统计年鉴2011[M].北京：中国农业出版社.2011.1-120.
欧秀芹,梁广川,梁金生,等.碳粉表面自由能对空气电极成膜的影响[J].电池,2006,36(1)：21-23.
欧阳健明.生物矿物及其矿化过程[J].化学进展,2005,17(4)：749-756.
彭金花.环氧玻璃鳞片涂料在重防腐领域中的应用[J].全面腐蚀控制,2009,23(3)：32-34.
施佳炜,刘术佳,彭刚,等.利用分形理论对PE/贝壳粉复合材料中粒子分布及力学性能的研究[J].合成纤维,2011,40(2)：14-17.
宋德宏,丁永生,庞艳华,等.贝壳棱柱层和珍珠层的傅里叶变化红外光谱[J].大连海事大学学报,2006,32(4)：110-112.
宋华杰,董海山,郝莹.计算固体表面能的Young-Good-Girifalco-Fowkes方程的理论基础[J].粘接,2000,21(5)：1-5.
宋丽英,胡晓湘,胡庆福.中国纳米级碳酸钙生产现状与发展建议[J].无机盐工业,2010,42(6)：1-4.
孙晋美,郭万林.贝壳珍珠母多级结构的化学-力学稳定性[J].中国科学(G辑：物理学力学天文学),2009,39(11)：1654-1663.
孙晋美,郭万林.珍珠母堆垛微结构的力学性能和热稳定性[J].中国科学：物理学力学天文学,2010,40(8)：1044-1053.
谭晓梅,王新雨,张明明,等.5种贝壳类动物药及其煎出物中微量元素含量测定[J].中国实验方剂学杂志,2011,17(1)：61-63.
唐焕章,陈建庭,金大地,等.珍珠层聚乳酸人工骨复合成骨细胞体内异位成骨研究[J].中国修复重建外科杂志,2005,19(2)：114-117.
陶靖,徐怡庄,翁诗甫,等.珍珠和贝壳珍珠层的傅里叶变换红外光谱研究[J]. 光谱学与光谱分析,1998,18(3)：307-310.
涂料原料网.国内碳酸钙产业发展的格局分析[EB/OL]. (2012-1-10) [2012-04-19]. http://www.ccgz4.cn/Html/?3070.html.
万欣娣,任凤章,刘平,等.贝壳珍珠层的研究现状[J].材料导报,2006,20(10)：21-24.
王家明,魏玉西,殷邦忠,等.以牡蛎壳为钙源的谷氨酸螯合钙制备工艺研究[J].中国海洋药物,2010,2(29)：22-26.
王凯雄,姚铭.全球变化研究热点——碳循环[J].浙江大学学报：农业与生命科学版,2001,27(5)：473-478.
王丽丹.两种季铵盐对蒙脱石的插层改性及其抗生性能试验[D].杭州：浙江大学硕士学位论文,2007.
王森,毛二林.片状碳酸钙的制备及其在造纸涂布中的应用[J].中华纸业,2009,30(20)：59-61.
王玮,陈莹,钦维民.偶联剂处理贝壳粉及其在增强聚乙烯中的应用[J].东华大学学报(自然科学版),2011,37(3)：278-281.
王旭,黄锐,金春烘.PP/弹性体/纳米CaC03复合材料的研究[J].中国塑料,2000,14(6):34-38.
韦钦胜,孙丕喜,徐宗军,等.贝类养殖环境安全评价及其监控体系技术研究的探讨[J].海洋开发与管理,2010,27(3)：48-51.
温变英.自然界中的梯度材料及其仿生研究[J].材料导报,2008(S2)：351-356.
吴培培.张仲景应用牡蛎的规律研究[D].北京：北京中医药大学硕士学位论文,2010.
吴晓京,杨大宇,李方华,等.珍珠和珍珠贝壳的显微结构[J].无机材料学报,1990,5(3)：272-277.
夏静芬,钱国英,陈亮,等.傅里叶变换红外光谱法对珍珠粉和贝壳粉的研究[J].光谱实验室,2010,27(2)：524-528.
夏静芬,钱国英,陈亮,等.珍珠粉和贝壳粉的化学成分和结构特征分析[J].化学研究与应用,2010,22(11)：1467-1471.
夏枚生,叶瑛,李海晏,等.一种以贝壳为原料制备多肽的方法[P]. CN102115487A.中国：浙江大学.2011.
向天夏,靳向煜,吴海波,等.无机粉体碳酸钙改性聚丙烯流变性能的研究[J].产业用纺织品,2011(1)：18-21.
谢益东.无定形碳酸钙的相转化[D].杭州：浙江大学硕士学位论文,2011.
谢忠东,丁晓非,黄光烨.贝壳——天然复合材料仿生学研究的发展状况[J].水产科学,2006,25(6)：317-320.
熊涛,乐易林.生物保鲜技术的研究进展[J].食品与发酵工业,2004,30(2)：111-114.
熊小京,黄智贤,景有海,等.牡蛎壳填料浸没式生物滤池的除磷特性[J].环境污染与防治,2003,25(6)：329-331.
徐永祥,李运德,师华,等.低收缩耐热冲击重防腐鳞片涂料的研究[J].中国涂料,2009,24(6)：53-56.
许艺,周俊兵,宋凡.珍珠母的微结构与力学行为研究进展[J].力学进展,2008,38(3)：283-302.
鄢晓晖,王胜男,博杜,等.淡水三角帆蚌贝壳珍珠质的同步辐射XRD研究[J].无机材料学报,2012,27(5)：524-528.
严立文,黄海军,陈纪涛,等.我国近海藻类养殖的碳汇强度估算[J].海洋科学进展,2011,29(4)：537-545.
杨春露,陈建庭,王建钧,等.珍珠层人工骨与入骨髓基质细胞的生物相容性[J].中国组织工程研究与临床康复,2007,11(1)：37-40.
杨海林,谢元彦,阮建明,等.机械化学法制备纳米碳酸钙[J].粉末冶金材料科学与工程,2010,15(5)：538-542.
杨金鑫,文秀芳,皮丕辉,等.CaCO3/SiO2复合粒子涂层的表面结构及其疏水性能研究[J].无机材料学报,2009,24(1)：91-96.
杨文.层状生物贝壳材料的结构表征与断裂行为研究[D].沈阳：东北大学硕士学位论文硕士学位论文,2008.
尹德胜,林得鹏.从牡蛎壳中提取生物糖蛋白的分析研究[J].广州化工,2009,37(9)：143-144.
袁金芳,刘学军,翟翠萍,等.两水亲性嵌段共聚物对CaCO3粒子形貌的调控[J]. 功能材料,20-11,42(3)：455-458.
张岑.合浦珠母贝贝壳形成相关蛋白及基因的研究[D].北京：清华大学博士学位论文,2006.
张恩,彭明生,胡林玉,等.珍珠层有机质特点及其药用探讨[J].矿物学报,2010(S1)：22-23.
张刚生,童银洪.软体动物贝壳中的有机质研究进展[J].湛江海洋大学学报,2000,20(1)：74-78.
张刚生,谢先德,戚绍祺,等.贝壳珍珠层的X射线衍射研究[J].矿物岩石,2002,22(4)：8-11.
张刚生,谢先德.贝壳的显微激光拉曼光谱研究[J].分析科学学报,2003,19(1)：27-29.
张刚生.生物矿物材料及仿生材料工程[J].矿产与地质,2002,16(89)：98-102.
张继红,方建光,唐启升.中国浅海贝藻养殖对海洋碳循环的贡献[J].地球科学进展,2005,20(3)：359-365.
张明亮,邹健,毛玉泽,等.养殖栉孔扇贝对桑沟湾碳循环的贡献[J].渔业现代化,2011,38(4)：13-16.
张明亮.栉孔扇贝生理活动对近海碳循环的影响[D].青岛：中国科学院研究生院(海洋研究所),2011.
张宁.CPE与CaCO3协同增韧PVC力学性能的研究[J].塑料科技,2012,40(2)：40-44.
张晟卯,高永建,张治军,等.仿贝壳自组装纳米复合薄膜的制备及结构表征[J].物理化学学报,2002,18(5)：451-454.
张伟钢,汪港,唐建,等.贝壳珍珠层动态的文石板片厚度及其新结构模型[J].广西大学学报(自然科学版),2009,34(4)：509-512.
张炜,洪尉,夏晋程,等.UHMWPE/PP/PP基无机填料母粒复合材料的制备及表征[J].工程塑料应用,2010,38(6)：5-8.
张文兵,姚春凤,麦康森.贝壳生物矿化的研究进展[J].海洋科学,2008,32(2)：74-79.
张学骜,王建方,吴文健,等.贝壳珍珠层生物矿化及其对仿生材料的启示[J]. 无机材料学报,2006,21(2)：257-266.
张学骜,吴文健,刘长利,等.自组装制备有机/无机层状复合材料[J].功能材料,2005,36(11)：1645-1650.
张亚涛,姜俊青,张延武,等.环氧树脂/层状无机物纳米复合材料[J].高分子通报,2006(4)：47-51.
张振凌.中医专业应当开设《临床中药炮制学》[J].中医药学刊,2006,24(2)：346-347.
章峻,包富荣,戴冬萍,等.马来酸酐(MAH)表面改性纳米碳酸钙粉体的制备及表面性能[J].无机化学学报,2007,23(5)：822-826.
赵丽娜,赵旭,任素霞,等.碳酸钙的原位合成及表面改性[J].物理化学学报,2009,25(1)：47-52.
赵松江.多种贝壳混合烧制而成的抗菌剂、表面剥离剂及其应用[P].101116449A.中国：赵松江.2008.
甄健,丁艳芬.聚丙烯/纳米碳酸钙复合材料性能的研究[J].塑料加工应用,2001,23(1)：5-8.
郑清,王玉琴.利用文蛤壳制备复合氨基酸螯合钙[J].安徽化工,2009,35(1)：25-28.
中国无机盐工业协会.2011年全国碳酸钙行业年会会议纪要[EB/OL]. (2011-06-09) [2012-04-19]. http://www.cisia.org/Html/4/20116977995842.html.
中华人民共和国国家统计局.中国统计年鉴2011[M].北京：中国统计出版社.2011.1-120.
钟洁雯,陈建伟,李祥,等.牡蛎炮制与临床应用进展[J].中国药房,2009,20(21)：1673-1674.
周红波,王苓,王正有.纳米碳酸钙改性弹性体/聚丙烯的研究进展[J].四川化工,2011,14(1)：18-20.
周佩玲.贝壳的宝石学特征[J].桂林工学院学报,1998,18(1)：45-52.
周淑芬,杨其,朱红,等.填料对PP结晶行为的影响[J].塑料科技,2008,21(3)：46-50.
邹燕,纪彬彬,温变英.滑石粉、碳酸钙填充聚丙烯复合材料等温结晶行为的研 究[J],中国塑料,2010,24(2)：26-29.
Addadi L, Weiner S. Biomineralization:a pavement of pearl[J]. Nature,1997, 389(6654):912-915.
Addadi L, Weiner S. Control and design principles in biological mineralization[J]. Angewandte Chemie International Edition in English,1992,31(2):153-169.
Arias J L, Neira-Carrillo A, Arias J I, et al. Sulfated polymers in biological mineralization:a plausible source for bio-inspired engineering[J]. Journal of Materials Chemistry,2004,14(14):2154-2160.
Atlan G, Delattre O, Berland S, et al. Interface between bone and nacre implants in sheep[J]. Biomaterials,1999,20(11):1017-1022.
Azizi H, Faghihi J. An investigation on the mechanical and dynamic rheological properties of single and hybrid filler/polypropylene composites based on talc and calcium carbonate[J]. Polymer Composites,2009,30(12):1743-1748.
Balmain J, Hannoyer B, Lopez E. Fourier transform infrared spectroscopy (ftir) and x-ray diffraction analyses of mineral and organic matrix during heating of mother of pearl (nacre) from the shell of the mollusc pinctada maxima[J]. Journal of Biomedical Materials Research,1999,48(5):749-754.
Barthelat F, Li C M, Comi C, et al. Mechanical properties of nacre constituents and their impact on mechanical performance [J]. Journal of Materials Research,2006, 21(8):1977-1986.
Barthelat F, Tang H, Zavattieri P D, et al. On the mechanics of mother-of-pearl:a key feature in the material hierarchical structure [J]. Journal of the Mechanics and Physics of Solids,2007,55(2):306-337.
Baumer A, Ganteaume M, Bernat M. Variations de la teneur en eau des coraux lors de la transformation aragonite→calcite:included water in corals for the transition aragonite→calcite[J]. Thermochimica Acta,1993,221(2):255-262.
Belcher A M, Wu X H, Christensen R J, et al. Control of crystal phase switching and orientation by soluble mollusc-shell proteins[J]. Nature,1996,381(6577):56-58.
Bin-Yang Z, Qiang Z, Chang-Feng C, et al. Structure and property characterization of oyster shell cementing material[J]. Chinese Journal of Structural Chemistry,2012, 31(1):85-92.
Blakemore R. Magnetotacticbacteria[J]. Science,1975,190(4212):377.
Brinker C J, Lu Y, Sellinger A, et al. Evaporation-induced self-assembly: nanostructures made easy[J]. Advanced Materials,1999,11(7):579-585.
Butler M F, Glaser N, Weaver A C, et al. Calcium carbonate crystallization in the presence of biopolymers[J]. Crystal Growth & Design,2006,6(3):781-794.
Campbell-Lendrum D, Corvalan C. Climate change and developing-country cities: implications for environmental health and equity [J]. Journal of Urban Health, 2007,84(1):109-117.
Castaneda C, Eeckhout S G, Costa G M, et al. Effect of heat treatment on tourmaline from brazil[J]. Physics and Chemistry of Minerals,2006,33(3):207-216.
Chan C M, Wu J, Li J X, et al. Polypropylene/calcium carbonate nanocomposites[J]. Polymer,2002,43(10):2981-2992.
Chan C, Wu J, Li J, et al. Polypropylene/calcium carbonate nanocomposites[J]. Polymer,2002,43(10):2981-2992.
Chen C H, Teng C C, Su S F, et al. Effects of microscale calcium carbonate and nanoscale calcium carbonate on the fusion, thermal, and mechanical characterizations of rigid poly (vinyl chloride)/calcium carbonate composites[J]. Journal of Polymer Science Part B:Polymer Physics,2006,44(2):451-460.
Chen P Y, Lin A, Lin Y S, et al. Structure and mechanical properties of selected biological materials[J]. Journal of the Mechanical Behavior of Biomedical Materials,2008,1(3):208-226.
Chen T Y, Li W F, Jun J D, et al. Modification of nanometre calcium carbonate and its application on pvc composites in situ suspension polymerisation[J]. Materials Science and Technology,2010,26(7):871-874.
Chowdhury S, Saha P. Sea shell powder as a new adsorbent to remove basic green 4 (malachite green) from aqueous solutions:equilibrium, kinetic and thermodynamic studies[J]. Chemical Engineering Journal,2010,164(1): 168-177.
Cobabe E A, Pratt L M. Molecular and isotopic compositions of lipids in bivalve shells:a new prospect for molecular paleontology[J]. Geochimica et Cosmochimica Acta,1995,59(1):87-95.
Cornwell D W, Rodary G. Modification of rigid pvc properties through effective use of synthetic calcium carbonates of controlled morphology and surface character[J]. Plastics, Rubber and Composites,2005,34(3):105-110.
Currey J D, Taylor J D. The mechanical behaviour of some molluscan hard tissues[JJ. Journal of Zoology,1974,173(3):395-406.
Currey J D, Zioupos P, Peter D, et al. Mechanical properties of nacre and highly mineralized bone[J]. Proceedings of the Royal Society of London. Series B: Biological Sciences,2001,268(1462):107-111.
Currey J D. Mechanical properties of mother of pearl in tension[J]. Proceedings of the Royal Society of London. Series B. Biological Sciences,1977,196(1125):443.
Dasgupta S, Laplante B, Meisner C, et al. The impact of sea level rise on developing countries:a comparative analysis[J]. Climatic Change,2007,93(3):379-388.
Dauphin Y, Denis A. Structure and composition of the aragonitic crossed lamellar layers in six species of bivalvia and gastropoda[J]. Comparative Biochemistry and Physiology-Part A:Molecular & Integrative Physiology,2000,126(3): 367-377.
Dauphin Y, Guzman N, Denis A, et al. Microstructure, nanostructure and composition of the shell of concholepas concholepas (gastropoda, muricidae)[J]. Aquatic Living Resources,2003,16(2):95-103.
Doney, S C, Fabry V J, Feely R A, et al. Ocean acidification:the other co2 problem[J]. Marine Science,2009,1:169-192.
Durner G M, Douglas D C, Nielson R M, et al. Predicting 21st-century polar bear habitat distribution from global climate models [J]. Ecological Monographs,2009, 79(1):25-58.
Eliel E L, Wilen S H. Stereochemistry of organic compounds[M]. Wiley-India.2008.
Engin B, Demirtas H, Eken M. Temperature effects on egg shells investigated by xrd, ir and esr techniques[J]. Radiation Physics and Chemistry,2006,75(2):268-277.
Etelaaho P, Haveri S, Jarvela P. Comparison of the morphology and mechanical properties of unmodified and surface-modified nanosized calcium carbonate in a polypropylene matrix[J]. Polymer Composites,2011,32(3):464-471.
Etelaaho P, Haveri S, Jarvela P. Comparison of the morphology and mechanical properties of unmodified and surface-modified nanosized calcium carbonate in a polypropylene matrix[J]. Polymer Composites,2011,32(3):464-471.
Falini G, Albeck S, Weiner S, et al. Control of aragonite or calcite polymorphism by mollusk shell macromolecules[J]. Science,1996,271(5245):67-69.
Falkowski P, Scholes R J, Boyle E, et al. The global carbon cycle:a test of our knowledge of earth as a system[J]. Science,2000,290(5490):291-296.
Fuad M, Hanim H, Zarina R, et al. Polypropylene/calcium carbonate nanocomposites-effects of processing techniques and maleated polypropylene compatibiliser[J]. Express Polymer Letters,2010.
Gao H, Chen H, Chen W, et al. Effect of nanometer pearl powder on calcium absorption and utilization in rats[J]. Food Chemistry,2008,109(3):493-498.
Gotliv B A, Addadi L, Weiner S. Mollusk shell acidic proteins:in search of individual functions[J]. ChemBioChem,2003,4(6):522-529.
Gotliv B A, Kessler N, Sumerel J L, et al. Asprich:a novel aspartic acid-rich protein family from the prismatic shell matrix of the bivalve atrina rigida[J]. ChemBioChem,2005,6(2):304-314.
Hansen J, Sato M, Ruedy R, et al. Global temperature change [J]. Proceedings of the National Academy of Sciences,2006,103(39):14288-14293.
Havenhand J N, Schlegel P. Near-future levels of ocean acidification do not affect sperm motility and fertilization kinetics in the oyster crassostrea gigas [J]. Biogeosciences,2009,6:3009-3015.
Herzog H J. What future for carbon capture and sequestration?[J]. Environmental Science & Technology,2001,35(7):148-153.
Heuer A H, Fink D J, Laraia V J, et al. Innovative materials processing strategies:a biomimetic approach[J]. Science,1992,255(5048):1098-1105.
Heywood B R, Mann S. Molecular construction of oriented inorganic materials: controlled nucleation of calcite and aragonite under compressed langmuir monolayers[J]. Chemistry of Materials,1994,6(3):311-318.
Hoegh-Guldberg O, Mumby P J, Hooten A J, et al. Coral reefs under rapid climate change and ocean acidification[J]. Science,2007,318(5857):1737-1742.
Houghton J. Global warming [J]. Reports on Progress in Physics,2005,68(6): 1343-1403.
Huang H, Han B, Wang L, et al. Crystallization kinetics of polypropylene composites filled with nano calcium carbonate modified with maleic anhydride[J]. Journal of Applied Polymer Science,2011,119(3):1516-1527.
Jackson A P, Vincent J, Turner R M. The mechanical design of nacre[J]. Proceedings of the Royal Society of London. Series B. Biological Sciences,1988,234(1277): 415-440.
Jacob D E, Soldati A L, Wirth R, et al. Nanostructure, composition and mechanisms of bivalve shell growth[J]. Geochimica et Cosmochimica Acta,2008,72(22): 5401-5415.
Jipa S, Zaharescu T, Supaphol P. Thermal stability of isotactic polypropylene modified with calcium carbonate nanoparticles[J]. Polymer Bulletin,2010,64(8): 783-790.
Jones G P, Mccormick M I, Srinivasan M, et al. Coral decline threatens fish biodiversity in marine reserves [J]. Proceedings of the National Academy of Sciences of the United States of America,2004,101(21):8251-8253.
Kamat S, Su X, Ballarini R, et al. Structural basis for the fracture toughness of the shell of the conch strombus gigas[J]. Nature,2000,405(6790):1036-1040.
Katti K S, Katti D R. Why is nacre so tough and strong[J]. Materials Science and Engineering:C,2006,26(8):1317-1324.
Khatiwala S, Primeau F, Hall T. Reconstruction of the history of anthropogenic co2 concentrations in the ocean[J]. Nature,2009,462(7271):346-349.
Kinderman G E, Obersteiner M, Sohngen B, et al. Global cost estimates of reducing carbon emissions through avoided deforestation[J] Proceedings of the National Academy of Sciences,2008,105(30):10302-10307.
Kleypas J A, Yates K K. Coral reefs and ocean acidification[J]. Oceanography,2009, 22(4):108-117.
Kobayashi I, Samata T. Bivalve shell structure and organic matrix[J]. Materials Science and Engineering:C,2006,26(4):692-698.
Kwon H B, Lee C W, Jun B S, et al. Recycling waste oyster shells for eutrophication control[J]. Resources, Conservation and Recycling,2004,41(1):75-82.
Lee C H, Lee D K, Ali M A, et al. Effects of oyster shell on soil chemical and biological properties and cabbage productivity as a liming materials [J]. Waste Management,2008,28(12):2702-2708.
Levi Y, Albeck S, Weiner S, et al. Control over aragonite crystal nucleation and growth:an in vitro study of biomineralization[J]. Chemistry-a European Journal, 1998,4(3):389-396.
Levi-Kalisman Y, Falini G, Addadi L, et al. Structure of the nacreous organic matrix of a bivalve mollusk shell examined in the hydrated state using cryo-tem[J]. Journal of Structural Biology,2001,135(1):8-17.
Li C, Botsaris G D, Kaplan D L. Selective in vitro effect of peptides on calcium carbonate crystallization[J]. Crystal Growth & Design,2002,2(5):387-393.
Li C, Champagne P. Fixed-bed column study for the removal of cadmium (ii) and nickel (ii) ions from aqueous solutions using peat and mollusk shells [J]. Journal of Hazardous Materials,2009,171(1):872-878.
Li X, Xu Z H, Wang R. In situ observation of nanograin rotation and deformation in nacre[J]. Nano Letters,2006,6(10):2301-2304.
Liang J Z. Evaluation of dispersion of nano-CaCO3 particles in polypropylene matrix based on fractal method[J]. Composites Part A:Applied Science and Manufacturing,2007,38(6):1502-1506.
Liao H, Brandsten C, Lundmark C, et al. Responses of bone to titania-hydroxyapatite composite and nacreous implants:a preliminary comparison by in situ hybridization[J]. Journal of Materials Science:Materials in Medicine,1997, 8(12):823-827.
Lin Y, Chen H, Chan C M, et al. The toughening mechanism of polypropylene/calcium carbonate nanocomposites[J]. Polymer,2010,51(14): 3277-3284.
Lorens R B, Bender M L. The impact of solution chemistry on mytilus edulis calcite and aragonite[J]. Geochimica et Cosmochimica Acta,1980,44(9):1265-1278.
Lowenstam H A, Weiner S. On biomineralization[M]. Oxford University Press, USA. 1989.
Ma X, Wei Q, Zhang S, et al. Isolation and bioactivities of organic acids and phenols from walnut shell pyroligneous acid[J]. Journal of Analytical and Applied Pyrolysis,2011,91(2):338-343.
Mai K, Zhang W, Tan B, et al. Effects of dietary zinc on the shell biomineralization in abalone haliotis discus hannai ino[J]. Journal of Experimental Marine Biology and Ecology,2003,283(1-2):51-62.
Mann S. Biomineralization:principles and concepts in bioinorganic materials chemistry[M]. Oxford University Press, USA.2001.
Mann S. Molecular recognition in biomineralization[J]. Nature,1988,332(6160): 119-124.
Manne S, Zaremba C M, Giles R, et al. Atomic force microscopy of the nacreous layer in mollusc shells[J]. Proceedings:Biological Sciences,1994,256(1345): 17-23.
Marin F, Luquet G, Marie B, et al. Molluscan shell proteins:primary structure, origin, and evolution[J]. Current Topics in Developmental Biology,2007,80:209-276.
Marin F, Luquet G. Molluscan biomineralization:the proteinaceous shell constituents of pinna nobilis 1.[J]. Materials Science and Engineering:C,2005,25(2): 105-111.
Marin F, Luquet G Molluscan shell proteins[J]. Comptes Rendus Palevol,2004, 3(6-7):469-492.
Marxen J C, Hammer M, Gehrke T, et al. Carbohydrates of the organic shell matrix and the shell-forming tissue of the snail biomphalaria glabrata (say)[J]. The Biological Bulletin,1998,194(2):231.
Mckibben B. Carbon's new math[J]. National Geographic,2007,212(4):33-34.
Meyers M A, Lin A Y M, Chen P Y, et al. Mechanical strength of abalone nacre:role of the soft organic layer[J]. Journal of the Mechanical Behavior of Biomedical Materials,2008,1(1):76-85.
Mihara Y, Takada T, Uno N. Antibacterial and antifungal effects of fired scallop shell-glass composites fabricated by a simple process [J]. Journal of the Ceramic Society of Japan,2008,6(116):1-4.
Miller A W, Reynolds A C, Sobrino C, et al. Shellfish face uncertain future in high co2 world:influence of acidification on oyster larvae calcification and growth in estuaries[J]. PLoS One,2009,4(5):e5661.
Miyamoto H, Miyashita T, Okushima M, et al. A carbonic anhydrase from the nacreous layer in oyster pearls [J]. Proceedings of the National academy of Sciences of the United States of America,1996,93(18):9657.
Naemchan K, Meejoo S, Onreabroy W, et al. Temperature effect on chicken egg shell investigated by xrd, tga and ftir[J]. Advanced Materials Research,2008,55: 333-336.
Nakahara H, Kakei M, Bevelander G Electron microscopic and amino acid studies on the outer and inner shell layers of haliotis rufescens[J]. Venus (Japan),1982, 41(1):33-46.
Nakamura Y, Fukuoka Y, Iida T. Tensile test of poly (vinyl chloride) filled with ground calcium carbonate particles[J]. Journal of Applied Polymer Science,1998, 70(2):311-316.
Njoyim-Tamungang E, Laminsi S, Ghogomu P, et al. Pollution control of surface waters by coupling gliding discharge treatment with incorporated oyster shell powder[J]. Chemical Engineering Journal,2011,173(2):303-308.
Nudelman F, Gotliv B A, Addadi L, et al. Mollusk shell formation:mapping the distribution of organic matrix components underlying a single aragonitic tablet in nacre[J]. Journal of Structural Biology,2006,153(2):176-187.
Oikawa K, Asada T, Yamamoto K, et al. Antibacterial activity of calcined shell calcium prepared from wild surf clam[J]. Journal of Health Science,2000,46(2): 98-103.
Oladoja N A, Aliu Y D. Snail shell as coagulant aid in the alum precipitation of malachite green from aqua system[J]. Journal of Hazardous Materials,2009, 164(2-3):1496-1502.
Ren F, Wan X, Liu P, et al. Microstructure and infra-red spectra analysis of mussel shell[J]. Journal of Henan University of Science & Technology (Natural Science), 2007,28(1):1-5.
Ren F, Wan X, Ma Z, et al. Study on microstructure and thermodynamics of nacre in mussel shell[J]. Materials Chemistry and Physics,2009,114(1):367-370.
Rodhe H. A comparison of the contribution of various gases to the greenhouse effect[J]. Science,1990,248(4960):1217-1219.
Rousseau M, Lopez E, Stempfle P, et al. Multiscale structure of sheet nacre[J]. Biomaterials,2005,26(31):6254-6262.
Sarikaya M. An introduction to biomimetics:a structural viewpoint[J]. Microscopy Research and Technique,1994,27(5):360-375.
Sarmiento J L, Gruber N. Sinks for anthropogenic carbon[J]. Physics Today,2002, 55(8):30-36.
Shono M, Shimizu I, Aoyagi E, et al. Reducing effect of feeding powdered nacre of pinctada maxima on the visceral fat of rats[J]. Bioscience, Biotechnology, and Biochemistry,2008,72(10):2761-2763.
Sikes C S, Wheeler A P. Control of crystallization by polyanionic hydrophobic polypeptides[J]. Chemical aspects of regulation of mineralization. University of South Alabama Publication Service, Mobile, Alabama,1988,194:15-20.
Smith B L, Sch Ffer T E, Viani M, et al. Molecular mechanistic origin of the toughness of natural adhesives, fibres and composites[J]. Nature,1999, 399(6738):761-763.
Song F, Soh A K, Bai Y L. Structural and mechanical properties of the organic matrix layers of nacre[J]. Biomaterials,2003,24(20):3623-3631.
Song F, Zhou J, Xu X, et al. Effect of a negative poisson ratio in the tension of ceramics[J]. Physical Review Letters,2008,100(24):1-4.
Stickle W F, Sobol P E, Bomben K D. Handbook of x-ray photoelectron spectroscopy: a reference book of standard spectra for identification and interpretation of xps data[M]. Eden Prairie Minnesota:Perkin-Elmer Corporation.1992.1-261.
Sudo S, Fujikawa T, Nagakura T, et al. Structures of mollusc shell framework proteins[J]. Nature,1997,387(6633):563-564.
Takada T, Furusaki A, Tanaka Y. Formaldehyde reduction with scallop shell powders fired at high temperatures:identification of the effective ingredient[J]. Bio-Medical Materials and Engineering,2009,19(2):187-192.
Tanner L H, Hubert J F, Coffey B P, et al. Stability of atmospheric co2 levels across the triassic/jurassic boundary[J]. Nature,2001,411(6838):675-677.
Tong H, Hu J M, Ma W T, et al. In situ analysis of the organic framework in the prismatic layer of mollusc shell[J]. Biomaterials,2002,23(12):2593-2598.
Toro P, Quijada R, Yazdani-Pedram M, et al. Eggshell, a new bio-filler for polypropylene composites [J]. Materials Letters,2007,61(22):4347-4350.
Trenberth K. Uncertainty in hurricanes and global warming[J]. Science,2005, 308(5729):1753-1754.
Tyrrell T. Calcium carbonate cycling in future oceans and its influence on future climates[J]. Journal of Plankton Research,2008,30(2):141-156.
Vijayaraghavan K, Balasubramanian R. Single and binary biosorption of cerium and europium onto crab shell particles[J]. Chemical Engineering Journal,2010, 163(3):337-343.
Mayes W, Davis J, Silva V, et al. Treatment of zinc-rich acid mine water in low residence time bioreactors incorporating waste shells and methanol dosing[J]. Journal of Hazardous Materials,2011,193:279-287.
Wagner C D. Handbook of x-ray photoelectron spectroscopy[M]. Eden Prairie Minnesota:Perkin-Elmer Corporation.1981.25-69.
Waldbusser G G, Voigt E P, Bergschneider H, et al. Biocalcification in the eastern oyster (crassostrea virginica) in relation to long-term trends in chesapeake bay ph[J]. Estuaries and Coasts,2010,34:221-231.
Wang R Z, Suo Z,-Evans A G, et al. Deformation mechanisms in nacre [J]. Journal of Materials Research,2001,16(9):2485-2493.
Webster T J, Ergun C, Doremus R H, et al. Enhanced functions of osteoblasts on nanophase ceramics[J]. Biomaterials,2000,21(17):1803-1810.
Weiner S, Hood L. Soluble protein of the organic matrix of mollusk shells:a potential template for shell formation[J]. Science,1975,190(4218):987-989.
Weiner S, Traub W, Parker S B. Macromolecules in mollusc shells and their functions in biomineralization[J]. Philosophical Transactions of the Royal Society of London. B, Biological Sciences,1984,304(1121):425-434.
Weiner S. Separation of acidic proteins from mineralized tissues by reversed-phase high-performance liquid chromatography.[J]. Journal of Chromatography,1982, 245(1):148-152.
Wheeler A P, George J W, Evans C A. Control of calcium carbonate nucleation and crystal growth by soluble matrx of oyster shell[J]. Science,1981,212(4501): 1397-1398.
Wierzbicki A, Sikes C S, Madura J D, et al. Atomic force microscopy and molecular modeling of protein and peptide binding to calcite[J]. Calcified Tissue International,1994,54(2):133-141.
Worms D, Weiner S. Mollusk shell organic matrix:fourier transform infrared study of the acidic macromolecules [J]. Journal of Experimental Zoology,1986,237(1): 11-20.
Wu D, Wang X, Song Y, et al. Nanocomposites of poly (vinyl chloride) and nanometric calcium carbonate particles:effects of chlorinated polyethylene on mechanical properties, morphology, and rheology[J]. Journal of Applied Polymer Science,2004,92(4):2714-2723.
Xie L, Wang X X, Li J. The sem and tem study on the laminated structure of individual aragonitic nacre tablet in freshwater bivalve h. Cumingii lea shell[J]. Journal of Structural Biology,2010,169(1):89-94.
Yang L, Zhang X, Liao Z, et al. Interfacial molecular recognition between polysaccharides and calcium carbonate during crystallization[J]. Journal of Inorganic Biochemistry,2003,97(4):377-383.
Yoon G L, Kim B T, Kim B O, et al. Chemical-mechanical characteristics of crushed oyster-shell[J]. Waste Management,2003,23(9):825-834.
Yu Z, Xie L, Lee S, et al. A novel carbonic anhydrase from the mantle of the pearl oyster (pinctada fucata)[J]. Comparative Biochemistry and Physiology Part B: Biochemistry and Molecular Biology,2006,143(2):190-194.
Zhang J, Han B, Zhou N, et al. Preparation and characterization of nano/micro-calcium carbonate particles/polypropylene composites[J]. Journal of Applied Polymer Science,2011,119(6):3560-3565.
Zhang Q X, Yu Z Z, Xie X L, et al. Crystallization and impact energy of polypropylene/CaCO3 nanocomposites with nonionic modifier[J]. Polymer,2004, 45(17):5985-5994.
Zhang S, Zhang J, Zhang Z, et al. Preparation and characterization of self-assembled organic-inorganic nacre-like nanocomposite thin films[J]. Materials Letters,2004, 58(17-18):2266-2269.
Zhao Q, Liu Y, Abel E W. Effect of temperature on the surface free energy of amorphous carbon films[J]. Journal of Colloid and Interface Science,2004, 280(1):174-183.
Zhao Q, Liu Y, Abel E W. Surface free energies of electroless ni-p based composite coatings [J]. Applied Surface Science,2005,240(1):441-451.
Zuiderduin W C J, Westzaan C, Huetink J, et al. Toughening of polypropylene with calcium carbonate particles[J]. Polymer,2003,44(1):261-275.
蔡英亚.贝类学概论[M].上海科学技术出版社.1995.
曹光明,罗廉明.一种评价塑料填料粉体改性效果的新方法[J].化工矿物与加工,2002,31(4)：5-7.
曾敏莉,周远大.钙制剂的现状及发展趋势[J].儿科药学杂志,2004,10(3)：16-18.
曾名勇,陈胜军.海洋生物抗菌剂的研究进展[J].精细与专用化学品,2002,10(19)：3-6.
曾名勇,林洪,刘树青,等.海洋生物保鲜剂OP-Ca抗菌特性的研究[J].中国海 洋药物,2002,21(4)：27-31.‘
陈忱,赵杰,梁艳,等.鲍鱼壳的结构和力学性能[J].材料导报：纳米与新材料专辑,2009,23(14)：457-459.
陈忱.头足纲与腹足纲贝壳材料的结构和性能[D].大连：大连理工大学硕士学位论文,2009.
陈俊宏.二枚贝养殖的钙化作用与其碳隔离能力的评估[D].基隆：国立台湾海洋大学硕士学位论文,2010.
陈琪,邹胜祥.可溶性海洋生物钙强化食品开发[J].农村实用技术与信息,1999(11)：11-12.
陈士勇,王令充,嵇晶,等.双壳类贝壳的应用研究进展[J].中国海洋药物,2011,30(1)：58-64.
陈玉枝,林舒.牡蛎壳与龙骨成分的分析[J].福建医科大学学报,1999,33(4)：432-434.
董瑞娜,麦康森,张文兵,等.皱纹盘鲍贝壳沉积过程的研究[J].中国海洋大学学报(自然科学版),2006(S1)：63-70.
段杉,陈海梅,林秋峰,等.贝壳煅烧物的防腐作用研究[J].中国食品添加剂,2007(6)：74-78.
范昌福,王宏,裴艳东,等.牡蛎壳体的同位素贝壳年轮研究[J].地球科学进展,2010,25(2)：163-173.
范克雷维伦D.W.聚合物的性质-性质的估算及其与化学结构的关系[M].北京：科学出版社.1981.127.
非金属化工网.世界重质碳酸钙10大著名生产企业[EB/OL].(2009-09-26)[2012-04-19].http://www.fj198.com/newsfile/2009-09-26/20092026092053.aspx.
冯庆玲,侯文涛.碳酸钙生物矿化的体外研究进展[J].清华大学学报(自然科学版),2006(12)：2019-2023.
高长云,齐军.聚丙烯/纳米碳酸钙复合材料性能的研究[J].橡塑技术与装备,2010,36(12)：1-5.
国家统计局,环境保护部.中国环境统计年鉴2010[M].中国统计出版社.2010.47.
韩琛,汪家宝,沈玉海,等.纳米CaCO3/PP复合材料的制备与性能研究[J].塑料工业,2008,36(5)：22-24.
韩启成.仿生叠层复合材料研究[D].镇江：江苏大学硕士学位论文,2002.
韩玉香,韩平,王永富,等.固体表面自由能及其分量的计算方法(Ⅰ)——接触角法[J].辽宁师范大学学报(自然科学版),1995,18(3)：214-216.
洪鹏志,章超桦.牡蛎壳制备活性钙[J].湛江海洋大学学报,2000,20(4)：46-49.
侯东芳,周根树,郑茂盛.贝壳珍珠层层间断口及死亡期的XPS研究[J].材料科学与工程学报,2004,22(6)：838-841.
侯东芳,周根树,郑茂盛.贝壳珍珠层断裂过程的原位观察及其增韧机制分析[J].材料科学与工程学报,2007,25(3)：388-391.
胡庆福,刘祝增,刘树文.碳酸钙产品分类与命名建议[J].无机盐工业,2008,40(3)：1-3.
胡学寅,周丽丽,齐兴义.贝壳吸附材料的制备与表征[J].应用科技,2008,35(3)：70-72.
黄广民,黄必春,肖红,等.双烧法从贝壳中制备葡萄糖酸钙[J].食品工业,2002,23(3)：24-26.
黄玉松,郑威,辛培训,等.贝壳珍珠层结构仿生复合材料研究[J].工程塑料应用,2008,36(10)：21-25.
江敏,李鉴,梁洁玲,等.牡蛎壳合成L-乳酸钙的工艺研究[J].食品科技,2008,33(3)：123-141.
蒋学文.贝壳微粉改性环氧树脂复合材料的制备及性能研究[D].兰州：兰州大学硕士学位论文,2007.
焦其帅,胡永琪,陈瑞珍,等.改性针形纳米碳酸钙在PVC中的应用研究[J].中国塑料,2011,25(9)：79-84.
郎萌萌.有机基质调控碳酸钙的仿生合成及其改性PVC研究[D].保定：河北大学硕士学位论文,2011.
李晶,黄丽.防腐阻燃型玻璃鳞片/环氧树脂涂料的性能[J].北京化工大学学报(自然科学版),2009(S1)：37-41.
李茂春,刘程.碳酸钙表面改性研究进展[J].聚氯乙烯,2010,38(8)：5-8.
李耐刚,生瑜,朱德钦,等.大分子键合处理CaCO3的表面性质及其与PVC的界面特性[J].聚氯乙烯,2006(5)：15-17.
李泳,张兆霞.以牡蛎壳粉作载体对维生素C和维生素E的抗氧化包合作用研究[J].云南化工,2009,36(1)：18-20.
梁金生,孟军平,朱东彬,等.热处理对电气石矿物粉体表面自由能的影响[J].硅酸盐学报,2008,36(2)：257-260.
梁艳,赵杰,王来,等.贝壳的力学性能和增韧机制[J].机械强度,2007,29(3)：507-511.
梁艳,赵杰,王来,等.贝壳的有机质及生物矿化机制分析[J].生物学杂志,2006,23(6)：19-23.
梁艳,赵杰,吴承伟.贝壳中交错纹状的结构对力学性能的影响[J].功能材料,2010,3(41)：459-465.
林秀玲.贝壳热分解行为的研究及对聚合物热降解的影响[D].安徽淮南：安徽理工大学硕士学位论文,2006.
刘必林,陈新军.头足类贝壳研究进展[J].海洋渔业,2010,32(3)：332-339.
刘方斌.碳酸钙产业结构矛盾突出[EB/OL]. (2011-07-29) [2012-04-19]. http://www.baogao.com/freereport/47100.html.
刘克松,江雷.仿生结构及其功能材料研究进展[J].科学通报,2009,54(18)：2667-2681.
刘小风,钟宏.不同形态纳米碳酸钙的研究进展[J].上海涂料,2009,47(4)：22-25.
刘晓军,闫振广,郑桂兰,等.一个有关双壳贝类贝壳年轮纹可能的形成机理[J].中国科学：生命科学,2011,41(1)：46-52.
刘亚雄.纳米碳酸钙填充PVC的分散研究[J].广东化工,2010,37(9)：51-52.
柳华,薄伟.纳米碳酸钙在填充PVC中的应用分散性研究[J].中国西部科技,2011,10(6)：39-40.
陆现彩,侯庆锋,尹琳,等.几种常见矿物的接触角测定及其讨论[J].岩石矿物学杂志,2003,22(4)：397-400.
马强,刘宇,李小静,等.贝壳填料曝气生物滤池处理污水试验研究[J].大连民族学院学报,2010,12(3)：287.
马文涛,沈亦平,曹连欣.贝壳有机质对CaCO3晶型形成的控制作用[J].武汉大学学报(自然科学版),1996,42(4)：469-474.
马治军,杨景辉,吴秋芳.聚丙烯酸酯/纳米碳酸钙复合增韧PVC的研究[J].塑料工业,2011,39(3)：67-70.
苗艳丽,洪鹏志,宋文东,等.以牡蛎壳粉-CMC为载体制备阿司匹林胃漂浮片的研究[J].药学实践杂志,2008,26(4)：264-266.
农业部渔业局.中国渔业统计年鉴2011[M].北京：中国农业出版社.2011.1-120.
欧秀芹,梁广川,梁金生,等.碳粉表面自由能对空气电极成膜的影响[J].电池,2006,36(1)：21-23.
欧阳健明.生物矿物及其矿化过程[J].化学进展,2005,17(4)：749-756.
彭金花.环氧玻璃鳞片涂料在重防腐领域中的应用[J].全面腐蚀控制,2009,23(3)：32-34.
施佳炜,刘术佳,彭刚,等.利用分形理论对PE/贝壳粉复合材料中粒子分布及力学性能的研究[J].合成纤维,2011,40(2)：14-17.
宋德宏,丁永生,庞艳华,等.贝壳棱柱层和珍珠层的傅里叶变化红外光谱[J].大连海事大学学报,2006,32(4)：110-112.
宋华杰,董海山,郝莹.计算固体表面能的Young-Good-Girifalco-Fowkes方程的理论基础[J].粘接,2000,21(5)：1-5.
宋丽英,胡晓湘,胡庆福.中国纳米级碳酸钙生产现状与发展建议[J].无机盐工业,2010,42(6)：1-4.
孙晋美,郭万林.贝壳珍珠母多级结构的化学-力学稳定性[J].中国科学(G辑：物理学力学天文学),2009,39(11)：1654-1663.
孙晋美,郭万林.珍珠母堆垛微结构的力学性能和热稳定性[J].中国科学：物理学力学天文学,2010,40(8)：1044-1053.
谭晓梅,王新雨,张明明,等.5种贝壳类动物药及其煎出物中微量元素含量测定[J].中国实验方剂学杂志,2011,17(1)：61-63.
唐焕章,陈建庭,金大地,等.珍珠层聚乳酸人工骨复合成骨细胞体内异位成骨研究[J].中国修复重建外科杂志,2005,19(2)：114-117.
陶靖,徐怡庄,翁诗甫,等.珍珠和贝壳珍珠层的傅里叶变换红外光谱研究[J]. 光谱学与光谱分析,1998,18(3)：307-310.
涂料原料网.国内碳酸钙产业发展的格局分析[EB/OL]. (2012-1-10) [2012-04-19]. http://www.ccgz4.cn/Html/?3070.html.
万欣娣,任凤章,刘平,等.贝壳珍珠层的研究现状[J].材料导报,2006,20(10)：21-24.
王家明,魏玉西,殷邦忠,等.以牡蛎壳为钙源的谷氨酸螯合钙制备工艺研究[J].中国海洋药物,2010,2(29)：22-26.
王凯雄,姚铭.全球变化研究热点——碳循环[J].浙江大学学报：农业与生命科学版,2001,27(5)：473-478.
王丽丹.两种季铵盐对蒙脱石的插层改性及其抗生性能试验[D].杭州：浙江大学硕士学位论文,2007.
王森,毛二林.片状碳酸钙的制备及其在造纸涂布中的应用[J].中华纸业,2009,30(20)：59-61.
王玮,陈莹,钦维民.偶联剂处理贝壳粉及其在增强聚乙烯中的应用[J].东华大学学报(自然科学版),2011,37(3)：278-281.
王旭,黄锐,金春烘.PP/弹性体/纳米CaC03复合材料的研究[J].中国塑料,2000,14(6):34-38.
韦钦胜,孙丕喜,徐宗军,等.贝类养殖环境安全评价及其监控体系技术研究的探讨[J].海洋开发与管理,2010,27(3)：48-51.
温变英.自然界中的梯度材料及其仿生研究[J].材料导报,2008(S2)：351-356.
吴培培.张仲景应用牡蛎的规律研究[D].北京：北京中医药大学硕士学位论文,2010.
吴晓京,杨大宇,李方华,等.珍珠和珍珠贝壳的显微结构[J].无机材料学报,1990,5(3)：272-277.
夏静芬,钱国英,陈亮,等.傅里叶变换红外光谱法对珍珠粉和贝壳粉的研究[J].光谱实验室,2010,27(2)：524-528.
夏静芬,钱国英,陈亮,等.珍珠粉和贝壳粉的化学成分和结构特征分析[J].化学研究与应用,2010,22(11)：1467-1471.
夏枚生,叶瑛,李海晏,等.一种以贝壳为原料制备多肽的方法[P]. CN102115487A.中国：浙江大学.2011.
向天夏,靳向煜,吴海波,等.无机粉体碳酸钙改性聚丙烯流变性能的研究[J].产业用纺织品,2011(1)：18-21.
谢益东.无定形碳酸钙的相转化[D].杭州：浙江大学硕士学位论文,2011.
谢忠东,丁晓非,黄光烨.贝壳——天然复合材料仿生学研究的发展状况[J].水产科学,2006,25(6)：317-320.
熊涛,乐易林.生物保鲜技术的研究进展[J].食品与发酵工业,2004,30(2)：111-114.
熊小京,黄智贤,景有海,等.牡蛎壳填料浸没式生物滤池的除磷特性[J].环境污染与防治,2003,25(6)：329-331.
徐永祥,李运德,师华,等.低收缩耐热冲击重防腐鳞片涂料的研究[J].中国涂料,2009,24(6)：53-56.
许艺,周俊兵,宋凡.珍珠母的微结构与力学行为研究进展[J].力学进展,2008,38(3)：283-302.
鄢晓晖,王胜男,博杜,等.淡水三角帆蚌贝壳珍珠质的同步辐射XRD研究[J].无机材料学报,2012,27(5)：524-528.
严立文,黄海军,陈纪涛,等.我国近海藻类养殖的碳汇强度估算[J].海洋科学进展,2011,29(4)：537-545.
杨春露,陈建庭,王建钧,等.珍珠层人工骨与入骨髓基质细胞的生物相容性[J].中国组织工程研究与临床康复,2007,11(1)：37-40.
杨海林,谢元彦,阮建明,等.机械化学法制备纳米碳酸钙[J].粉末冶金材料科学与工程,2010,15(5)：538-542.
杨金鑫,文秀芳,皮丕辉,等.CaCO3/SiO2复合粒子涂层的表面结构及其疏水性能研究[J].无机材料学报,2009,24(1)：91-96.
杨文.层状生物贝壳材料的结构表征与断裂行为研究[D].沈阳：东北大学硕士学位论文硕士学位论文,2008.
尹德胜,林得鹏.从牡蛎壳中提取生物糖蛋白的分析研究[J].广州化工,2009,37(9)：143-144.
袁金芳,刘学军,翟翠萍,等.两水亲性嵌段共聚物对CaCO3粒子形貌的调控[J]. 功能材料,20-11,42(3)：455-458.
张岑.合浦珠母贝贝壳形成相关蛋白及基因的研究[D].北京：清华大学博士学位论文,2006.
张恩,彭明生,胡林玉,等.珍珠层有机质特点及其药用探讨[J].矿物学报,2010(S1)：22-23.
张刚生,童银洪.软体动物贝壳中的有机质研究进展[J].湛江海洋大学学报,2000,20(1)：74-78.
张刚生,谢先德,戚绍祺,等.贝壳珍珠层的X射线衍射研究[J].矿物岩石,2002,22(4)：8-11.
张刚生,谢先德.贝壳的显微激光拉曼光谱研究[J].分析科学学报,2003,19(1)：27-29.
张刚生.生物矿物材料及仿生材料工程[J].矿产与地质,2002,16(89)：98-102.
张继红,方建光,唐启升.中国浅海贝藻养殖对海洋碳循环的贡献[J].地球科学进展,2005,20(3)：359-365.
张明亮,邹健,毛玉泽,等.养殖栉孔扇贝对桑沟湾碳循环的贡献[J].渔业现代化,2011,38(4)：13-16.
张明亮.栉孔扇贝生理活动对近海碳循环的影响[D].青岛：中国科学院研究生院(海洋研究所),2011.
张宁.CPE与CaCO3协同增韧PVC力学性能的研究[J].塑料科技,2012,40(2)：40-44.
张晟卯,高永建,张治军,等.仿贝壳自组装纳米复合薄膜的制备及结构表征[J].物理化学学报,2002,18(5)：451-454.
张伟钢,汪港,唐建,等.贝壳珍珠层动态的文石板片厚度及其新结构模型[J].广西大学学报(自然科学版),2009,34(4)：509-512.
张炜,洪尉,夏晋程,等.UHMWPE/PP/PP基无机填料母粒复合材料的制备及表征[J].工程塑料应用,2010,38(6)：5-8.
张文兵,姚春凤,麦康森.贝壳生物矿化的研究进展[J].海洋科学,2008,32(2)：74-79.
张学骜,王建方,吴文健,等.贝壳珍珠层生物矿化及其对仿生材料的启示[J]. 无机材料学报,2006,21(2)：257-266.
张学骜,吴文健,刘长利,等.自组装制备有机/无机层状复合材料[J].功能材料,2005,36(11)：1645-1650.
张亚涛,姜俊青,张延武,等.环氧树脂/层状无机物纳米复合材料[J].高分子通报,2006(4)：47-51.
张振凌.中医专业应当开设《临床中药炮制学》[J].中医药学刊,2006,24(2)：346-347.
章峻,包富荣,戴冬萍,等.马来酸酐(MAH)表面改性纳米碳酸钙粉体的制备及表面性能[J].无机化学学报,2007,23(5)：822-826.
赵丽娜,赵旭,任素霞,等.碳酸钙的原位合成及表面改性[J].物理化学学报,2009,25(1)：47-52.
赵松江.多种贝壳混合烧制而成的抗菌剂、表面剥离剂及其应用[P].101116449A.中国：赵松江.2008.
甄健,丁艳芬.聚丙烯/纳米碳酸钙复合材料性能的研究[J].塑料加工应用,2001,23(1)：5-8.
郑清,王玉琴.利用文蛤壳制备复合氨基酸螯合钙[J].安徽化工,2009,35(1)：25-28.
中国无机盐工业协会.2011年全国碳酸钙行业年会会议纪要[EB/OL]. (2011-06-09) [2012-04-19]. http://www.cisia.org/Html/4/20116977995842.html.
中华人民共和国国家统计局.中国统计年鉴2011[M].北京：中国统计出版社.2011.1-120.
钟洁雯,陈建伟,李祥,等.牡蛎炮制与临床应用进展[J].中国药房,2009,20(21)：1673-1674.
周红波,王苓,王正有.纳米碳酸钙改性弹性体/聚丙烯的研究进展[J].四川化工,2011,14(1)：18-20.
周佩玲.贝壳的宝石学特征[J].桂林工学院学报,1998,18(1)：45-52.
周淑芬,杨其,朱红,等.填料对PP结晶行为的影响[J].塑料科技,2008,21(3)：46-50.
邹燕,纪彬彬,温变英.滑石粉、碳酸钙填充聚丙烯复合材料等温结晶行为的研 究[J],中国塑料,2010,24(2)：26-29.