基于环氧甲萘醌的乳液型防污涂料的研究
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摘要
本文针对现有舰船防污涂料的VOC排放和有毒防污剂渗出对大气及海洋环境的污染问题,设计合成了一类新型的有机硅改性丙烯酸酯自乳化乳液,应用于防污涂料的成膜物,并对新型防污剂环氧甲萘醌(ME)在防污涂料中的应用进行了研究,得到一种新型的零VOC排放的乳液型舰船防污涂料。
为了克服传统的由非反应型乳化剂制备的乳液漆膜耐水性差的缺点,本文采用反应型乳化剂烯丙基丙基磺基琥珀酸双酯钠盐(M-10S)和烯丙基辛基酚聚氧乙烯醚(AE-200)制备了新型有机硅改性丙烯酸酯自乳化乳液。采用红外光谱、差热分析、透射电镜和纳米粒度仪分别对有机硅改性丙烯酸酯的结构、玻璃化转变温度、乳液粒子形貌及大小进行分析表征。当甲基丙烯酸甲酯(MMA)的添加量为13.0wt%(物料总量)、丙烯酸丁酯(BA)添加量为13.0wt%(物料总量)、乙烯基三乙氧基硅烷(VTES)添加量为5.0wt%(物料总量)、质量比为1：1的M-10S和AE-200复合乳化剂添加量为0.7wt%(物料总量)、引发剂过硫酸铵(APS)添加量为0.3wt%(物料总量)、反应温度为80℃、反应时间为3h时,所制备的有机硅改性丙烯酸酯自乳化乳液最小数均粒径达到62.4nm。乳液漆膜性能优异,可以满足防污涂料成膜物使用要求。
论文对维生素K3系列产品的防污效果进行了研究,确定了采用无毒、价廉的环氧甲萘醌(ME)作为主防污剂,并对与其匹配的防污助剂进行了研究。同时,为了使防污涂料中主防污剂ME释放可控,采用聚丙烯酸酯为囊壁对防污剂环氧甲萘醌(ME)进行微胶囊包覆,从而控制ME的释放速率,延长涂料使用寿命。研究了囊壁材最优组成、制备工艺对微胶囊平均粒径的影响；采用透射电镜(TEM)对微胶囊形貌进行表征。结果表明,所有的ME都被微胶囊化,ME微胶囊囊壁材最优组成为MMAwt％:BAwt％:AA(丙烯酸)wt%=26：45：29；采用分步加料法和复合乳化剂体系(OP-10wt％:SDS wt％=1:1)制备的微胶囊平均粒径为338.4nm。当囊芯材和囊壁材的质量比1：7时,涂料中ME渗出最平稳。
论文以制备的新型有机硅改性丙烯酸酯自乳化乳液作为成膜物,以微胶囊化的环氧甲萘醌(ME)为主防污剂制备了新型水性防污涂料,对涂料漆膜的机械性能和防污性能进行了详细研究。结果表明,漆膜附着力为1级,抗冲击超过50cm·kg；当囊芯材和囊壁材的质量比为1：7的ME微胶囊的添加量为36.6wt%、吡啶硫酮锌的添加量为0.5wt%、纳米ZnO的添加量为2.0wt%、纳米TiO2的添加量为0.5wt%时,涂料的防污效果最佳。涂膜防污期可达3-4年。该涂料以水为分散介质,使用无毒高效的防污剂,达到无毒和零VOC排放的效果。
另外,本文针对网箱养殖用防污涂料使用期短,及网绳的特殊柔韧性,设计合成了一类新型养殖网箱用防污涂料。该涂料以松香为成膜物,VOC豁免溶剂丙酮为溶剂,通过添加环保型防污剂ME和壬酸香草酰胺(PAV)以及增塑剂,制备了海水养殖用网箱防污涂料,讨论了增塑剂的选择和防污剂ME和PAV用量对漆膜防污效果的影响,检测了漆膜的急性毒性。防污效果海上对比实验结果表明,以邻苯二甲酸二辛酯和氯化石蜡复合物为增塑剂(邻苯二甲酸二辛酯：氯化石蜡=1：1)、PAV用量5.0wt%(物料总量)、ME用量2.5wt%(物料总量)时,3个月后海上挂样网片基本无增重,防污期可达10个月以上。急性毒性检测结果表明,制备的网箱防污涂料实际无毒。
Now, most antifouling coatings still suffered from many problems, especially the atmospheric and marine pollution caused by VOCs emission and toxic biocides release. As concerning such disadvantages of antifouling coating, a novel silicone-acrylate self-emulsifying emulsion which can be used as film former of antifouling coating was designed and investigated, and the application of novel biocide-2,3-epoxy-2-methyl-1,4-naphthoquinone (ME) in the anfiouling coating was also studied. A high efficient, novel antifouling coating without VOCs emission was successfully formulated.
Generally, the unpolymerizable emulsifiers in traditional emulsion show very poor water resistance property which is fatal to the antifouling coating. To conquer such problem, in this paper, a novel silicone-acrylate emulsion was synthesized using polymerizable emulsifiers4-propyl-1-(1-propenyl) sulfosuccinate (M-10S) and allyl octylphenyl polyoxyethylene glycol ether (AE-200). The emulsion was characterized by Fourier transform infrared spectroscopy (FT-IR), differential scanning calorimetry (DSC) and transmission electron microscopy micrograph (TEM). The optimal polymerization condition is13.0wt%MMA,13.0wt%BA,5.0wt%VTES,0.7wt%compound emulsifier-M-10S:AE-200=1:1(wt/wt),0.3wt%ammonium persulfate (APS),80℃of polymerization temperature,3h of reaction time. The Z-average particle size of the emulsion is62.4nm. The performances of the film prepared from the emulsion were excellent. This novel silicone-acrylate emulision met the commercial standards of film-forming polymer for antifouling coating.
Antifouling performances of Vitamin K3products were studied in this paper, and ME was employed as main antifoulant. In the mean time, the antifouling additives matching with ME were also studied. In order to control the release of main antifoulant-ME from the coating film, and prepare the antifouling coating with long service life, polyacrylate emulsion was applied as wall material to microcapsulate ME. Shell material component and the effect of the preparation procedure on the microcapsule particle size were studied. TEM was used to characterize ME microcapsules. The results showed that ME was successfully microencapsulated and the average particle size was only338.4nm by multistep feeding in the presence of emulsifiers-OP-10:SDS=1:1(wt/wt). The optimal shell material component is MMA:BA:AA=26:45:29(wt:wt:wt). When the core/shell mass ratio of microcapsules was1:7, the release rate of ME from the coating was steady.
In this paper, a waterborne antifouling coating for ship hull protection was prepared by employing novel synthesized silicone-acrylate emulsion as film former and ME microcapsules as main antifoulant. Physical and mechanical properties, antifouling performance were tested. The adhesion of the coating film reaches1grade and the impact resistance is over50cm·kg, The optimal recipe of the waterborne antifouling coating is36.6wt%ME microcapsules,0.5wt%Zinc pyrithione,2.0wt%nano-sized ZnO and0.5wt%nano-sized TiO2. The antifouling activity of the coating film is excellent. The service life of the coating film can last for3-4years. By the application of water as dispersion medium and environmental friendly antifouling agents, there is no VOCs emission from the environmental friendly coating.
Based on the short service life of the antifouling coating used on marine cage, and the special flexibility of the netting, a novel antifouling coating was studied and prepared with rosin, acetone, ME, pelargonic acid vanillyamide (PAV) and plasticizer. The observation on treated netting hung up for3months in the sea showed that the antifouling efficiency of the coating made with plasticizers-dinormal octyl phthalate:chlorcosane=1:1(wt/wt) in the presence of5.0wt%PAV and2.5wt%ME was excellent, and there was no weight gain of the netting. The service life of the coatin film can last at least10months. Meanwhile the coating film was environmental friendly.
为了克服传统的由非反应型乳化剂制备的乳液漆膜耐水性差的缺点,本文采用反应型乳化剂烯丙基丙基磺基琥珀酸双酯钠盐(M-10S)和烯丙基辛基酚聚氧乙烯醚(AE-200)制备了新型有机硅改性丙烯酸酯自乳化乳液。采用红外光谱、差热分析、透射电镜和纳米粒度仪分别对有机硅改性丙烯酸酯的结构、玻璃化转变温度、乳液粒子形貌及大小进行分析表征。当甲基丙烯酸甲酯(MMA)的添加量为13.0wt%(物料总量)、丙烯酸丁酯(BA)添加量为13.0wt%(物料总量)、乙烯基三乙氧基硅烷(VTES)添加量为5.0wt%(物料总量)、质量比为1：1的M-10S和AE-200复合乳化剂添加量为0.7wt%(物料总量)、引发剂过硫酸铵(APS)添加量为0.3wt%(物料总量)、反应温度为80℃、反应时间为3h时,所制备的有机硅改性丙烯酸酯自乳化乳液最小数均粒径达到62.4nm。乳液漆膜性能优异,可以满足防污涂料成膜物使用要求。
论文对维生素K3系列产品的防污效果进行了研究,确定了采用无毒、价廉的环氧甲萘醌(ME)作为主防污剂,并对与其匹配的防污助剂进行了研究。同时,为了使防污涂料中主防污剂ME释放可控,采用聚丙烯酸酯为囊壁对防污剂环氧甲萘醌(ME)进行微胶囊包覆,从而控制ME的释放速率,延长涂料使用寿命。研究了囊壁材最优组成、制备工艺对微胶囊平均粒径的影响；采用透射电镜(TEM)对微胶囊形貌进行表征。结果表明,所有的ME都被微胶囊化,ME微胶囊囊壁材最优组成为MMAwt％:BAwt％:AA(丙烯酸)wt%=26：45：29；采用分步加料法和复合乳化剂体系(OP-10wt％:SDS wt％=1:1)制备的微胶囊平均粒径为338.4nm。当囊芯材和囊壁材的质量比1：7时,涂料中ME渗出最平稳。
论文以制备的新型有机硅改性丙烯酸酯自乳化乳液作为成膜物,以微胶囊化的环氧甲萘醌(ME)为主防污剂制备了新型水性防污涂料,对涂料漆膜的机械性能和防污性能进行了详细研究。结果表明,漆膜附着力为1级,抗冲击超过50cm·kg；当囊芯材和囊壁材的质量比为1：7的ME微胶囊的添加量为36.6wt%、吡啶硫酮锌的添加量为0.5wt%、纳米ZnO的添加量为2.0wt%、纳米TiO2的添加量为0.5wt%时,涂料的防污效果最佳。涂膜防污期可达3-4年。该涂料以水为分散介质,使用无毒高效的防污剂,达到无毒和零VOC排放的效果。
另外,本文针对网箱养殖用防污涂料使用期短,及网绳的特殊柔韧性,设计合成了一类新型养殖网箱用防污涂料。该涂料以松香为成膜物,VOC豁免溶剂丙酮为溶剂,通过添加环保型防污剂ME和壬酸香草酰胺(PAV)以及增塑剂,制备了海水养殖用网箱防污涂料,讨论了增塑剂的选择和防污剂ME和PAV用量对漆膜防污效果的影响,检测了漆膜的急性毒性。防污效果海上对比实验结果表明,以邻苯二甲酸二辛酯和氯化石蜡复合物为增塑剂(邻苯二甲酸二辛酯：氯化石蜡=1：1)、PAV用量5.0wt%(物料总量)、ME用量2.5wt%(物料总量)时,3个月后海上挂样网片基本无增重,防污期可达10个月以上。急性毒性检测结果表明,制备的网箱防污涂料实际无毒。
Now, most antifouling coatings still suffered from many problems, especially the atmospheric and marine pollution caused by VOCs emission and toxic biocides release. As concerning such disadvantages of antifouling coating, a novel silicone-acrylate self-emulsifying emulsion which can be used as film former of antifouling coating was designed and investigated, and the application of novel biocide-2,3-epoxy-2-methyl-1,4-naphthoquinone (ME) in the anfiouling coating was also studied. A high efficient, novel antifouling coating without VOCs emission was successfully formulated.
Generally, the unpolymerizable emulsifiers in traditional emulsion show very poor water resistance property which is fatal to the antifouling coating. To conquer such problem, in this paper, a novel silicone-acrylate emulsion was synthesized using polymerizable emulsifiers4-propyl-1-(1-propenyl) sulfosuccinate (M-10S) and allyl octylphenyl polyoxyethylene glycol ether (AE-200). The emulsion was characterized by Fourier transform infrared spectroscopy (FT-IR), differential scanning calorimetry (DSC) and transmission electron microscopy micrograph (TEM). The optimal polymerization condition is13.0wt%MMA,13.0wt%BA,5.0wt%VTES,0.7wt%compound emulsifier-M-10S:AE-200=1:1(wt/wt),0.3wt%ammonium persulfate (APS),80℃of polymerization temperature,3h of reaction time. The Z-average particle size of the emulsion is62.4nm. The performances of the film prepared from the emulsion were excellent. This novel silicone-acrylate emulision met the commercial standards of film-forming polymer for antifouling coating.
Antifouling performances of Vitamin K3products were studied in this paper, and ME was employed as main antifoulant. In the mean time, the antifouling additives matching with ME were also studied. In order to control the release of main antifoulant-ME from the coating film, and prepare the antifouling coating with long service life, polyacrylate emulsion was applied as wall material to microcapsulate ME. Shell material component and the effect of the preparation procedure on the microcapsule particle size were studied. TEM was used to characterize ME microcapsules. The results showed that ME was successfully microencapsulated and the average particle size was only338.4nm by multistep feeding in the presence of emulsifiers-OP-10:SDS=1:1(wt/wt). The optimal shell material component is MMA:BA:AA=26:45:29(wt:wt:wt). When the core/shell mass ratio of microcapsules was1:7, the release rate of ME from the coating was steady.
In this paper, a waterborne antifouling coating for ship hull protection was prepared by employing novel synthesized silicone-acrylate emulsion as film former and ME microcapsules as main antifoulant. Physical and mechanical properties, antifouling performance were tested. The adhesion of the coating film reaches1grade and the impact resistance is over50cm·kg, The optimal recipe of the waterborne antifouling coating is36.6wt%ME microcapsules,0.5wt%Zinc pyrithione,2.0wt%nano-sized ZnO and0.5wt%nano-sized TiO2. The antifouling activity of the coating film is excellent. The service life of the coating film can last for3-4years. By the application of water as dispersion medium and environmental friendly antifouling agents, there is no VOCs emission from the environmental friendly coating.
Based on the short service life of the antifouling coating used on marine cage, and the special flexibility of the netting, a novel antifouling coating was studied and prepared with rosin, acetone, ME, pelargonic acid vanillyamide (PAV) and plasticizer. The observation on treated netting hung up for3months in the sea showed that the antifouling efficiency of the coating made with plasticizers-dinormal octyl phthalate:chlorcosane=1:1(wt/wt) in the presence of5.0wt%PAV and2.5wt%ME was excellent, and there was no weight gain of the netting. The service life of the coatin film can last at least10months. Meanwhile the coating film was environmental friendly.
引文
[1]Chambers L D, Stokes K R,Walsh F C, et al. Modern approaches to marine antifouling coatings [J]. Surface & Coatings Technology,2006,201(6):3642-3652.
[2]史航,石建高,陈晓蕾,等.包埋苯甲酸钠微球的制备及在海洋防污涂料中的抑菌研究[J].高分子通报,2011,(1)：65-70.
[3]Brady R F. A fracture mechanical analysis of fouling release from nontoxic antifouling coatings [J]. Progress in Organic Coatings,2001,43:188-192.
[4]Stupak M E, Garcia M T, Perez M C. Non-toxic alternative compounds for marine antifouling paints [J]. International Biodeterioration Biodegradation,2003,52:49-52.
[5]石建高,史航,王鲁民,等.新型环保渔网防污剂的研究[J].现代渔业信息,2011,26(9)：7-12.
[6]Field, B. Marine Biofouling and its Control:History and State-of-the-Art Review. The Ocean and International workplace Oceans 81 Conference Record Boston [C], Massachusetts,1981.
[7]Alexander I Railkin. Marine Biofouling-colonization processes and defense [M]. Florida: CRC Press,2003.
[8]Lamb T J, Engelhard M. Marine fouling control by electrolytic hypochlorite generation. Proceeding of the 3rd International Congress on Marine Corrosion and Fouling [C], East Newark USA,1972.
[9]孙祖信.聚苯胺及其防污涂料[J].舰船科学技术,1997,(3)：62-65.
[10]金光羊,金钟成,韩相秀.海水电解型偏二氯乙烯-氯乙烯共聚树脂系列无公害防污涂料及其涂覆体系：中国,1385480[P].2002.
[11]Claude A. Case Study of a Chronic Contaminant in the Coastal Environment [J]. Ocean Coastal Management,1998, (40):23-36.
[12]Thomas Kevin V, Blake Sylvia J, Waldock Michael J. Antifouling paint booster biocide contamination in UK marine sediments [J]. Marine Pollution Bulletin,2000,40(9): 739-745.
[13]Blanck H, Dahl B. Recovery of marine periphyton communities around a Swedish marina after the ban of TBT use in antifouling paint [J]. Marine Pollution Bulletin,1998, 36(6):437-442.
[14]全燮,薛大明,赵雅芝,等.有机锡的生物富集作用于生物效应[J].海洋化境科学2003,16(4)：64-70.
[15]Champ M A. A review of organotin regulatory strategies, pending actions, related coats and benefits [J]. The Science of the Total Environment,2000,258:21-71.
[16]Yebra D M, Kiil S, Dam-Johansen K. Reaction rate estimation of controlled-release antifouling paint binders:Rosin- based systems [J]. Progress in Organic Coatings.2005, 53(4):256-275.
[17]Crisp D. The role of the biologist in anti-fouling research. Proceeding of the 3rd International Congress on Marine Corrosion and Fouling [C], East Newark USA,1972.
[18]Ghosh Tirthankar, Oreland P A. Polymeric controlled release compositions:US,6610282 [P].2003.
[19]Ryu Jae Hyeok, Lee Mun Yong. Method for producing controlled release, composite antifouling resin comprising amine salt and metal salt of organic acids antifouling coating composition comprising the same: KR,100417350 [P].2004.
[20]Yonehara Y, Yamashita H, Kawamura C, Itoh K. A new antifouling paint based on a zinc acrylate copolymer [J]. Progress in Organic Coatings,2001,42(3-4):150-158.
[21]Samui A B, Chavan J G, Hande V R. Study on film forming orgno-copper polymer [J]. Progress in Organic Coatings,2006,57(4):310-316.
[22]赵金榜.无锡防污涂料的现状和发展(Ⅱ)[J].现代涂料与涂装,2005,3：36-39.
[23]Ishikura Shiniehi, Higo Kiyoaki, Yamaori Naoki, Matsuda Masayuki. A Proeess for Preparing a metal containing resin composition and the use of the composition thus prepared as a resinous vehicle in antifouling Paint: JP,63128008 [P].1989.
[24]Yamamori Naoki, Ohsugi Hiroharu, Eguchi Yoshio,Yokoi Junji. Hydrolyzable resin composition and an antifouling coating composition containing the same: US,5080892[P].1992.
[25]Almeida Elisabete, Diamantino Teresa C, De Sousa Orlando. Marine paints:The particular case of antifouling paints [J]. Progress in Organic Coatings,2007,59(1),2-20.
[26]Vallee-Rehel Karine, Langlois Valerie, Guerin Philippe. Contribution of Pendant Ester Group Hydrolysis to the Erosion of Acrylic Polymers in Binders Aimed at Organotin-Free Antifouling Paints [J]. Journal of Environmental Polymers Degradation,1998,6 (4): 175-186.
[27]张祖文,徐德增,由继业.有机硅改性氟碳防污涂料表面接触角和防污效果的研[J].中国涂料,2010,25(8)：21-23.
[28]Brady R F, Singer I L. Mechanical factors favoring release from fouling release coatings [J]. Biofouling,2000,15 (1-3):73-81.
[29]Kohl J G, Burke A J, Landas Enrico L L, et al. The release behavior of silicone coatings with a thickness gradient [J]. Progress in Organic Coatings,2007,59 (4):278-283.
[30]Adkins James D, Mera Ann E, Roe-Short Mary Ann, et al. Novel non-toxic coatings designed to resist marine fouling [J]. Progress in O rganic Coatings,1996,29(1-4):1-5.
[31]Webster Dean C, Chisholm Bret J, Stafslien Shane J. Mini-review:Combinatorial approaches for the design of novel coating systems [J]. Biofouling,2007,23 (3):179-192.
[32]Kawakami Y. Influence of modification of fine silica by organosilicon compounds on particle-particle interaction in aqueous suspensions [J]. Journal of coatings Technology, 2000,172(9):45-50.
[33]Durand P, Margaillan A, Camail M, et al. Trioganosilyl methacrylates:kinetic studies of radical homopolymerization and radical copolymerization with methyl methacrylate [J]. Polymer,1994,35(20):4392-4396.
[34]Chen M J, Osterholtz F D, Pohi E R, et al. Silane in high Solids and waterborne coatings [J]. Journal of coatings Technology,1997,69(870):43-51.
[35]James D, Askins, Ann E, et al. Novel non-toxic coatings designed to resist marine fouling [J]. Progress in Organic Coatings,1996, (29):1-5.
[36]Schmidt D L, Dekoven B M, Coburn C E, et al. Characterization of a new family of nonwettable, nonstick surfaces [J]. Langmuir,1996,12(2):518-529.
[37]Griffith J R. Epoxy resins containing fluorine [J]. Chemtech,1982 (12):290-293.
[38]Tsibouklis J, Stone M, Thorpe Adrian A, et al. Surface energy characteristics of polymer film structures:a further insight into the molecular design requirements [J]. Langmuir, 1999,15(20):7076-7079.
[39]赵金榜.无锡防污涂料的现状和发展(Ⅲ)[J],现代涂料与涂装,2005,4：27-29.
[40]Shtykova Liubov S, Ostrovskii Denis, Handa Paul, et al. NMR diffusometry and FTIR in the study of the interaction between antifouling agent and binder in marine paints [J]. Progress in Organic Coatings,2004,51(2):125-133.
[41]Handa Paul, Fant Camilla, Nyden, Magnus. Antifouling agent release from marine coatings-ion pair formation/dissolution for controlled release [J]. Progress in Organic Coatings,2006,57(4):376-382.
[42]Nakamura Toshiki, Banno Tadashi, Umeno Masayuki. Ammonium-tetraarylborate polymer, its production, and underwater antifouling agent containing it:JP,200029037 [P].2000.
[43]Hugues C, Bressy C, Bartolomeo P, Margaillan A. Complexation of an acrylic resin by tertiary amines:synthesis and characterization of new binders for antifouling paints [J]. Eurpoean Polymer Journal,2003 (39):319-326.
[44]Nakamura Toshiki, Banno Tadashi, Umeno Masayuki, et al. Trial borane-heterocyclic amine compound, triaryl borane-heterocyclic amine-based (co) polymer, manufacture and application thereof: JP,2000297118 [P].2000.
[45]Gudipati Chakravarthy S, Finlay John A, Callow James A, et al. The antifouling and fouling - release performance of hyperbranched fluoropolymer (HBFP)-poly(ethylene glycol) (PEG) composite coatings evaluated by adsorption of biomacromolecules and the green fouling alga ulva [J]. Langmuir,2005,21 (7):3044-3053.
[46]Karen L W. New nanoparticle coating mimics dolphin skin Prevents'biofouling' of ship hulls [J/OL]. Science Blog [2002,10,29]. http://www.innovations-report.com/html/reports/materials_science/report-14022.html.
[47]Hamamoto Yasuo, Takeuchi Akihiro. Video signal recording and reproducing device:JP, 6197374 [P].1994.
[48]Yamamori N, Harada A, Yokoi J, et al. Antifouling resin composition:EP,0801117 [P]. 1997.
[49]Xie Q D, Xu J, Feng L, et al. Facile creation of a super - amphiphobic coating surface with bionicmicro structure [J]. Advanced Materials,2004,16(4):302-305.
[50]Sun T, Feng L, Gao X F, et al. Bioinspired surfaces with pecial wettability [J]. Accounts of Chemical Research,2005,38(8):644-652.
[51]Gao X F, Jiang L. Water-repellent legs of water striders [J]. Nature,2004,432:36.
[52]Mecerreyes D, Alvarol V, Cantero I, et al. Low surface energy conducting polypyrrole doped with a fluorinated counterion [J]. Advanced Materials,2002 (14):749-752.
[53]王献,孙祖信,耿延候,等.导电聚苯胺防污防腐涂料的制备方法：中国,1215744[P].2001.
[54]李慧娟,王国建.船舶防污涂料的研究与发展[J].上海涂料,2005,43(1)：14-19.
[55]李浩明,高蓝.辣椒素的提取与纯化[J].广西植物,2001,3：284-286.
[56]陈光宇.辣椒碱自抛光防污涂料及其制备方法：中国,1296044A[P].2004.
[57]Bullat David M, Vasishtha niraj. Biorepellent marix coating:US,5925370 [P].1999.
[58], Fischer Kenneth J. Marine organism repellent covering for protection of underwater objects and method of applying same: US,5226380 [P].1993.
[59]Watts James L. Anti-fouling coating composition containging capaicin:US,5397385 [P]. 1995.
[60]Stupak M E, Garcra M T, Perez M C. Non-toxic Alternative compounds for marine antifouling paints [J]. International Biodeteriortion & Biodegradation,2003(52):49-52.
[61]Sachiko T, Haruko K, Hiroshi H, et al. Antifouling Kalihinenes from the Marine Sponge Acathella Cavemosa [J]. Tetrahedron Letter,1995,36(47):8637-8640.
[62]Tsukamoto Sachiko, Kato Haruko, Hirota Hiroshi, et al. Pseudoceratidine:A new antifouling spermidine derivative from the marine sponge pseudoceratina purpurea [J]. Tetrahedron Letter,1996,37(9):1439-1440.
[63]王钧宇.仿生无毒舰船防污涂料及其制法：中国,1392208A[P].2003.
[64]Targett N M, Bishop S S, McConnell O J, et al. Antifouling agent against the marine diatom, Navicula salinicola homarine from the gorgonians leptogorgia virgulata and L. setacea and analogs [J]. Journal of Chemical Ecolog,1983,9(7):817-829.
[65]Standing J D, Hooper I R., Costlow J D. Inhibition and induction of barnacle settlement by natural products present in octocorals [J]. Journal of Chemical Ecology,1984,10: 823-834.
[66]Rittschof D, Hooper Irving R, Costlow John D. Barnacle settlement inhibitors from sea pansies, renilla reniformis [J]. Bulletin in Marine Science,1986,39(2):376-782.
[67]Geraci Sebastiano, Faimali Marco, Piovetti Louis, et al. Antifouling from nature: laboratory test with Balanus amphitrite darwin on algae and sponges [J]. Defence Science and Technology Organisation,2001:88-97
[68]Elwing H, Martenssson L, Holmberg K. Enzymes acting as antifouling non - toxic agents in coatings [C]. New Perspectives in Marine Biofouling and Biofouling Control. Fiskebackskil:International workshop,2003.
[69]Todd J, Zimmerman R, Crews P. The antifouling activity of natural and synthetic phenolic acid sulphate eaters [J]. Phytochemistry,1993,34(2): 401-404.
[70]Phillip M. Biologically inspired materials synthesis for anti-fouling purpose [M]. Fiskebackskil:International workshop,2003.
[71]Itoh Masayasu, Fukuda Shigeo, Kawakami Yoshihisa, et al. Antifouling coating composition based on rosin blends:EP,0802243 [P].1997.
[72]Greenfield Stanley A, Dupond John A. Formaldehyde-stabilized coating compositions: US,4129448 [P].1978.
[73]王华进,王贤明,管朝祥,等.海洋防污涂料的发展[J].涂料工业,2000,(3)：35-38.
[74]边蕴静.新型海洋涂料技术[J].化工新型材料,2002,30(6)：25-28.
[75]王华进,王贤明,管朝祥,等.硅酸盐复合防污涂料：中国,98119956[P].1998.
[76]Marcheselli Marco, Rustichelli Cecilia, Mauri Marina. Novel antifouling agent zinc pyrithione:determination, acute toxicity, and bioaccumulation in marine mussels (mylilus galloprovincialis) [J]. Enviromental toxicology and chemistry,2010,29 (11): 2583-2592.
[77]Hani Rahim, Craig Waldron, Waterbury, Fanner Jr Douglas A. Process for stabilizing zinc pyrithione plus cuprous oxide in paint:US,5098473 [P].1992.
[78]杨健,周思辰,聂静,等.生物杀生剂灭杀四龄红虫的实验研究[J].中国给水排水,2005,21(10)：55-57.
[79]Bonati S, Monteleone F. Biocidal-antifouling agents with low ecotoxicity index:WO, 0128328 [P]. (2001).
[80]Kou Yan, Wang Jin Yan, Jian Xi Gao. A novel epoxy methacrylate resin containing phthalazinone moiety for UV coatings [J]. Chinese Chemical Letters, 2007,18 (5): 598-600.
[81]Moayed S H, Fatemi S, Pourmahdian S. Synthesis of a latex with bimodal particle size distribution for coating applications using acrylic monomers [J]. Progress in Organic Coatings,2007,60(4):312-319.
[82]马世宁,张占平.舰船防污涂层技术的发展现状与趋势[J].中国表面工程,2009,22,(6)：19-35.
[83]Lee J R., Jin F L, Park S J, et al. Study of new fluorine-containing epoxy resin for low dielectric constant [J]. Surface and Coatings Technology,2004,180-181:650-654.
[84]Zhang C C, Hu L, Hu Y Y. Preparation and characterization of silicone acrylate copolymer emulsion by the emulsifier-free polymerization method [J]. Polymer Preprints (American Chemical Society,Division of Polymer Chemistry),2009,50(2):599-600.
[85]Chen M J, Osterholtz F D, Pohl E R, et al. Silanes in high-solid and waterborne coatings [J]. Journal of Coatings Technology,1997,69 (870):43-51.
[86]Guyot A, Tauer K. Reactive surfactants in emulsion polymerization [J]. Advances in Polymer Science,1994,111:45-65.
[87]Cochin D, Laschewsky A, Nallet F. Emulsion polymerization of styrene using conventional, polymerizable, and polymeric surfactants. a comparative study [J]. Macromolecules,1997,30(8):2278-2287.
[88]Miale John B, Miale J R August, Porter Raymond. Anti-fouling marine paints containing microencapsulated anti-fouling agents and the process of microencapsulation:US, 4253877 [P].1981.
[89]Ma Y J, Dong W F, Hempenius M A, et al. Redox-controlled molecular permeability of composite-wall microcapsules [J]. Nature Materials,2006,5(9):724-729.
[90]Wang K W, He Q, Yan X H, et al. Encapsulated photosensitive drugs by biodegradable microcapsules to incapacitate cancer cells [J]. Journal of Materials Chemistry,2007, 17(38):4018-4021.
[91]Wang X Y, Xie X L, Cai C F, et al. Biodegradable branched polyesters poly(vinyl sulfonate-covinyl alcohol)-graft Poly(D,L-lactic-coglycolic acid) as a negatively charged polyelectrolyte platform for drug delivery: synthesis and characterization [J]. Macromolecules,2008,41(8):2791-2799.
[92]Desai K G H, Park H J. Encapsulation of vitamin C in tripolyphosphate cross-linked chitosan microspheres by spray drying [J]. Journal of Microencapsulation,2005,22(2): 179-192.
[93]Yow H N, Routh A F. Formation of liquid core-polymer shell microcapsules [J]. Soft Matter,2006,2(11):940-949.
[94]Haefliger O P, Jeckelmann N, Ouali L, et al. Real-time monitoring of fragrance release from cotton towels by low thermal mass gas chromatography using a longitudinally modulating cryogenic system for headspace sampling and injection [J]. Analytical Chemistry,2010,82(2):729-737.
[95]Coehet F, Claverie J P, Graillat C, et al. Emulsion polymerization of chloroprene in the presence of a maleic polymerizable surfactant: control of gel formation at low conversion [J]. Macromolecules,2004,37:4081-4086.
[96]崔学军.高性能含氟乳液的合成及水性含氟涂料耐沾污性建模[D].吉林长春,吉林大学,2008.
[97]潘祖仁.高分子化学[M].北京：化学工业出版社,2007.
[98]刘国杰.有机硅改性涂料的开发现状[J].有机硅材料,2003,17(2)：25-28.
[99]章基凯,赵陈超.有机硅整理剂及其在纺织工业上的应用[J].纺织学报,1990(6)：283-285.
[100]许飞,张兴元,戴家兵,等.硅氧烷改性水性聚氨酯的交联机理及成膜性能研究[J].涂料技术,2010,12：28-32.
[101]黄雪青.有机硅改性丙烯酸乳液的研究[D].湖北武汉,武汉理工大学,2007.
[102]胡金生,曹同玉,刘庆普.乳液聚合[M].北京：化学工业出版社,1987.
[103]Yagi Toru, Saito Koichi, Sho Katsuhiko. Curable one-liquid silicone-modified acrylic emulsion coating compositions: JP,10298495 [P].1998.
[104]王耀.改性聚氨酯乳液的合成[D].辽宁大连,大连海事大学,2009.
[105]Paul B K, Moulik S P. Uses and applications of microemulsions [J]. Current Science, 2001,80(8):990-1001.
[106]Liu Y Y, Yang M J. Preparation of MMA-BA-DMAEMA Nanosized Latex [J]. Chinese Chemical Letter,2003,14(8):863-865.
[107]Srivastava P. Structure, wettablility, and barrier properties of self-assembled monolayers on metallic surfaces [D]. Houston Texas, Rice university,2006.
[108]王华进,王贤明.94-01无毒防污涂料的研制[J].涂料工业,1998,28(2)：11-13.
[109]刘继华,钱士强.海洋生物附着及其防护技术[J].腐蚀与防护,2010,1(31)：78-84.
[110]Li G J, Shen J R, Zhu Y L. Study of pyridinium-type functional polymers. Ⅱ. Antibacterial activity of soluble pyridinium-type polymers [J]. Journal of Applied Polymer Science,1998,67 (10):1761-1768.
[111]魏刚,黄海燕,熊蓉春.纳米二氧化钛的光催化性能及其在有机污染物降解中的应用[J].现代化工,2003,23(1)：20-23.
[112]巴雄军.氟乐灵微胶囊的研制[J].中国农药,2008,3：42-43.
[113]杨学习.氯化石蜡增塑作用的探讨和作用[J].中国氯碱,2003,3(3)：18-19.
[114]Wang B, Yang F, Qiu W W, et al. Highly efficient synthesis of capsaicin analogues by condensation of vanillylamine and acyl chlorides in a biphase H2O/CHCl3 system [J]. Tetrahedron,2009,65(27):5409-5412.
[115]Gannett P M, Nagel D L, Reilly P J, et al. Capsaicinoids:their separation, synthesis and mutagenicity [J]. Journal of organic chemistry,1988,53 (5):1064-1071.
[116]张开.高分子界面科学[M].北京：中国石化出版社,1997：297-300.
[117]Karst D, Yang Y Y. Using the solubility parameter to explain disperse dye sorption on polylactide [J]. Journal of Applied Polymer Science,2005,96(2):416-422.
[2]史航,石建高,陈晓蕾,等.包埋苯甲酸钠微球的制备及在海洋防污涂料中的抑菌研究[J].高分子通报,2011,(1)：65-70.
[3]Brady R F. A fracture mechanical analysis of fouling release from nontoxic antifouling coatings [J]. Progress in Organic Coatings,2001,43:188-192.
[4]Stupak M E, Garcia M T, Perez M C. Non-toxic alternative compounds for marine antifouling paints [J]. International Biodeterioration Biodegradation,2003,52:49-52.
[5]石建高,史航,王鲁民,等.新型环保渔网防污剂的研究[J].现代渔业信息,2011,26(9)：7-12.
[6]Field, B. Marine Biofouling and its Control:History and State-of-the-Art Review. The Ocean and International workplace Oceans 81 Conference Record Boston [C], Massachusetts,1981.
[7]Alexander I Railkin. Marine Biofouling-colonization processes and defense [M]. Florida: CRC Press,2003.
[8]Lamb T J, Engelhard M. Marine fouling control by electrolytic hypochlorite generation. Proceeding of the 3rd International Congress on Marine Corrosion and Fouling [C], East Newark USA,1972.
[9]孙祖信.聚苯胺及其防污涂料[J].舰船科学技术,1997,(3)：62-65.
[10]金光羊,金钟成,韩相秀.海水电解型偏二氯乙烯-氯乙烯共聚树脂系列无公害防污涂料及其涂覆体系：中国,1385480[P].2002.
[11]Claude A. Case Study of a Chronic Contaminant in the Coastal Environment [J]. Ocean Coastal Management,1998, (40):23-36.
[12]Thomas Kevin V, Blake Sylvia J, Waldock Michael J. Antifouling paint booster biocide contamination in UK marine sediments [J]. Marine Pollution Bulletin,2000,40(9): 739-745.
[13]Blanck H, Dahl B. Recovery of marine periphyton communities around a Swedish marina after the ban of TBT use in antifouling paint [J]. Marine Pollution Bulletin,1998, 36(6):437-442.
[14]全燮,薛大明,赵雅芝,等.有机锡的生物富集作用于生物效应[J].海洋化境科学2003,16(4)：64-70.
[15]Champ M A. A review of organotin regulatory strategies, pending actions, related coats and benefits [J]. The Science of the Total Environment,2000,258:21-71.
[16]Yebra D M, Kiil S, Dam-Johansen K. Reaction rate estimation of controlled-release antifouling paint binders:Rosin- based systems [J]. Progress in Organic Coatings.2005, 53(4):256-275.
[17]Crisp D. The role of the biologist in anti-fouling research. Proceeding of the 3rd International Congress on Marine Corrosion and Fouling [C], East Newark USA,1972.
[18]Ghosh Tirthankar, Oreland P A. Polymeric controlled release compositions:US,6610282 [P].2003.
[19]Ryu Jae Hyeok, Lee Mun Yong. Method for producing controlled release, composite antifouling resin comprising amine salt and metal salt of organic acids antifouling coating composition comprising the same: KR,100417350 [P].2004.
[20]Yonehara Y, Yamashita H, Kawamura C, Itoh K. A new antifouling paint based on a zinc acrylate copolymer [J]. Progress in Organic Coatings,2001,42(3-4):150-158.
[21]Samui A B, Chavan J G, Hande V R. Study on film forming orgno-copper polymer [J]. Progress in Organic Coatings,2006,57(4):310-316.
[22]赵金榜.无锡防污涂料的现状和发展(Ⅱ)[J].现代涂料与涂装,2005,3：36-39.
[23]Ishikura Shiniehi, Higo Kiyoaki, Yamaori Naoki, Matsuda Masayuki. A Proeess for Preparing a metal containing resin composition and the use of the composition thus prepared as a resinous vehicle in antifouling Paint: JP,63128008 [P].1989.
[24]Yamamori Naoki, Ohsugi Hiroharu, Eguchi Yoshio,Yokoi Junji. Hydrolyzable resin composition and an antifouling coating composition containing the same: US,5080892[P].1992.
[25]Almeida Elisabete, Diamantino Teresa C, De Sousa Orlando. Marine paints:The particular case of antifouling paints [J]. Progress in Organic Coatings,2007,59(1),2-20.
[26]Vallee-Rehel Karine, Langlois Valerie, Guerin Philippe. Contribution of Pendant Ester Group Hydrolysis to the Erosion of Acrylic Polymers in Binders Aimed at Organotin-Free Antifouling Paints [J]. Journal of Environmental Polymers Degradation,1998,6 (4): 175-186.
[27]张祖文,徐德增,由继业.有机硅改性氟碳防污涂料表面接触角和防污效果的研[J].中国涂料,2010,25(8)：21-23.
[28]Brady R F, Singer I L. Mechanical factors favoring release from fouling release coatings [J]. Biofouling,2000,15 (1-3):73-81.
[29]Kohl J G, Burke A J, Landas Enrico L L, et al. The release behavior of silicone coatings with a thickness gradient [J]. Progress in Organic Coatings,2007,59 (4):278-283.
[30]Adkins James D, Mera Ann E, Roe-Short Mary Ann, et al. Novel non-toxic coatings designed to resist marine fouling [J]. Progress in O rganic Coatings,1996,29(1-4):1-5.
[31]Webster Dean C, Chisholm Bret J, Stafslien Shane J. Mini-review:Combinatorial approaches for the design of novel coating systems [J]. Biofouling,2007,23 (3):179-192.
[32]Kawakami Y. Influence of modification of fine silica by organosilicon compounds on particle-particle interaction in aqueous suspensions [J]. Journal of coatings Technology, 2000,172(9):45-50.
[33]Durand P, Margaillan A, Camail M, et al. Trioganosilyl methacrylates:kinetic studies of radical homopolymerization and radical copolymerization with methyl methacrylate [J]. Polymer,1994,35(20):4392-4396.
[34]Chen M J, Osterholtz F D, Pohi E R, et al. Silane in high Solids and waterborne coatings [J]. Journal of coatings Technology,1997,69(870):43-51.
[35]James D, Askins, Ann E, et al. Novel non-toxic coatings designed to resist marine fouling [J]. Progress in Organic Coatings,1996, (29):1-5.
[36]Schmidt D L, Dekoven B M, Coburn C E, et al. Characterization of a new family of nonwettable, nonstick surfaces [J]. Langmuir,1996,12(2):518-529.
[37]Griffith J R. Epoxy resins containing fluorine [J]. Chemtech,1982 (12):290-293.
[38]Tsibouklis J, Stone M, Thorpe Adrian A, et al. Surface energy characteristics of polymer film structures:a further insight into the molecular design requirements [J]. Langmuir, 1999,15(20):7076-7079.
[39]赵金榜.无锡防污涂料的现状和发展(Ⅲ)[J],现代涂料与涂装,2005,4：27-29.
[40]Shtykova Liubov S, Ostrovskii Denis, Handa Paul, et al. NMR diffusometry and FTIR in the study of the interaction between antifouling agent and binder in marine paints [J]. Progress in Organic Coatings,2004,51(2):125-133.
[41]Handa Paul, Fant Camilla, Nyden, Magnus. Antifouling agent release from marine coatings-ion pair formation/dissolution for controlled release [J]. Progress in Organic Coatings,2006,57(4):376-382.
[42]Nakamura Toshiki, Banno Tadashi, Umeno Masayuki. Ammonium-tetraarylborate polymer, its production, and underwater antifouling agent containing it:JP,200029037 [P].2000.
[43]Hugues C, Bressy C, Bartolomeo P, Margaillan A. Complexation of an acrylic resin by tertiary amines:synthesis and characterization of new binders for antifouling paints [J]. Eurpoean Polymer Journal,2003 (39):319-326.
[44]Nakamura Toshiki, Banno Tadashi, Umeno Masayuki, et al. Trial borane-heterocyclic amine compound, triaryl borane-heterocyclic amine-based (co) polymer, manufacture and application thereof: JP,2000297118 [P].2000.
[45]Gudipati Chakravarthy S, Finlay John A, Callow James A, et al. The antifouling and fouling - release performance of hyperbranched fluoropolymer (HBFP)-poly(ethylene glycol) (PEG) composite coatings evaluated by adsorption of biomacromolecules and the green fouling alga ulva [J]. Langmuir,2005,21 (7):3044-3053.
[46]Karen L W. New nanoparticle coating mimics dolphin skin Prevents'biofouling' of ship hulls [J/OL]. Science Blog [2002,10,29]. http://www.innovations-report.com/html/reports/materials_science/report-14022.html.
[47]Hamamoto Yasuo, Takeuchi Akihiro. Video signal recording and reproducing device:JP, 6197374 [P].1994.
[48]Yamamori N, Harada A, Yokoi J, et al. Antifouling resin composition:EP,0801117 [P]. 1997.
[49]Xie Q D, Xu J, Feng L, et al. Facile creation of a super - amphiphobic coating surface with bionicmicro structure [J]. Advanced Materials,2004,16(4):302-305.
[50]Sun T, Feng L, Gao X F, et al. Bioinspired surfaces with pecial wettability [J]. Accounts of Chemical Research,2005,38(8):644-652.
[51]Gao X F, Jiang L. Water-repellent legs of water striders [J]. Nature,2004,432:36.
[52]Mecerreyes D, Alvarol V, Cantero I, et al. Low surface energy conducting polypyrrole doped with a fluorinated counterion [J]. Advanced Materials,2002 (14):749-752.
[53]王献,孙祖信,耿延候,等.导电聚苯胺防污防腐涂料的制备方法：中国,1215744[P].2001.
[54]李慧娟,王国建.船舶防污涂料的研究与发展[J].上海涂料,2005,43(1)：14-19.
[55]李浩明,高蓝.辣椒素的提取与纯化[J].广西植物,2001,3：284-286.
[56]陈光宇.辣椒碱自抛光防污涂料及其制备方法：中国,1296044A[P].2004.
[57]Bullat David M, Vasishtha niraj. Biorepellent marix coating:US,5925370 [P].1999.
[58], Fischer Kenneth J. Marine organism repellent covering for protection of underwater objects and method of applying same: US,5226380 [P].1993.
[59]Watts James L. Anti-fouling coating composition containging capaicin:US,5397385 [P]. 1995.
[60]Stupak M E, Garcra M T, Perez M C. Non-toxic Alternative compounds for marine antifouling paints [J]. International Biodeteriortion & Biodegradation,2003(52):49-52.
[61]Sachiko T, Haruko K, Hiroshi H, et al. Antifouling Kalihinenes from the Marine Sponge Acathella Cavemosa [J]. Tetrahedron Letter,1995,36(47):8637-8640.
[62]Tsukamoto Sachiko, Kato Haruko, Hirota Hiroshi, et al. Pseudoceratidine:A new antifouling spermidine derivative from the marine sponge pseudoceratina purpurea [J]. Tetrahedron Letter,1996,37(9):1439-1440.
[63]王钧宇.仿生无毒舰船防污涂料及其制法：中国,1392208A[P].2003.
[64]Targett N M, Bishop S S, McConnell O J, et al. Antifouling agent against the marine diatom, Navicula salinicola homarine from the gorgonians leptogorgia virgulata and L. setacea and analogs [J]. Journal of Chemical Ecolog,1983,9(7):817-829.
[65]Standing J D, Hooper I R., Costlow J D. Inhibition and induction of barnacle settlement by natural products present in octocorals [J]. Journal of Chemical Ecology,1984,10: 823-834.
[66]Rittschof D, Hooper Irving R, Costlow John D. Barnacle settlement inhibitors from sea pansies, renilla reniformis [J]. Bulletin in Marine Science,1986,39(2):376-782.
[67]Geraci Sebastiano, Faimali Marco, Piovetti Louis, et al. Antifouling from nature: laboratory test with Balanus amphitrite darwin on algae and sponges [J]. Defence Science and Technology Organisation,2001:88-97
[68]Elwing H, Martenssson L, Holmberg K. Enzymes acting as antifouling non - toxic agents in coatings [C]. New Perspectives in Marine Biofouling and Biofouling Control. Fiskebackskil:International workshop,2003.
[69]Todd J, Zimmerman R, Crews P. The antifouling activity of natural and synthetic phenolic acid sulphate eaters [J]. Phytochemistry,1993,34(2): 401-404.
[70]Phillip M. Biologically inspired materials synthesis for anti-fouling purpose [M]. Fiskebackskil:International workshop,2003.
[71]Itoh Masayasu, Fukuda Shigeo, Kawakami Yoshihisa, et al. Antifouling coating composition based on rosin blends:EP,0802243 [P].1997.
[72]Greenfield Stanley A, Dupond John A. Formaldehyde-stabilized coating compositions: US,4129448 [P].1978.
[73]王华进,王贤明,管朝祥,等.海洋防污涂料的发展[J].涂料工业,2000,(3)：35-38.
[74]边蕴静.新型海洋涂料技术[J].化工新型材料,2002,30(6)：25-28.
[75]王华进,王贤明,管朝祥,等.硅酸盐复合防污涂料：中国,98119956[P].1998.
[76]Marcheselli Marco, Rustichelli Cecilia, Mauri Marina. Novel antifouling agent zinc pyrithione:determination, acute toxicity, and bioaccumulation in marine mussels (mylilus galloprovincialis) [J]. Enviromental toxicology and chemistry,2010,29 (11): 2583-2592.
[77]Hani Rahim, Craig Waldron, Waterbury, Fanner Jr Douglas A. Process for stabilizing zinc pyrithione plus cuprous oxide in paint:US,5098473 [P].1992.
[78]杨健,周思辰,聂静,等.生物杀生剂灭杀四龄红虫的实验研究[J].中国给水排水,2005,21(10)：55-57.
[79]Bonati S, Monteleone F. Biocidal-antifouling agents with low ecotoxicity index:WO, 0128328 [P]. (2001).
[80]Kou Yan, Wang Jin Yan, Jian Xi Gao. A novel epoxy methacrylate resin containing phthalazinone moiety for UV coatings [J]. Chinese Chemical Letters, 2007,18 (5): 598-600.
[81]Moayed S H, Fatemi S, Pourmahdian S. Synthesis of a latex with bimodal particle size distribution for coating applications using acrylic monomers [J]. Progress in Organic Coatings,2007,60(4):312-319.
[82]马世宁,张占平.舰船防污涂层技术的发展现状与趋势[J].中国表面工程,2009,22,(6)：19-35.
[83]Lee J R., Jin F L, Park S J, et al. Study of new fluorine-containing epoxy resin for low dielectric constant [J]. Surface and Coatings Technology,2004,180-181:650-654.
[84]Zhang C C, Hu L, Hu Y Y. Preparation and characterization of silicone acrylate copolymer emulsion by the emulsifier-free polymerization method [J]. Polymer Preprints (American Chemical Society,Division of Polymer Chemistry),2009,50(2):599-600.
[85]Chen M J, Osterholtz F D, Pohl E R, et al. Silanes in high-solid and waterborne coatings [J]. Journal of Coatings Technology,1997,69 (870):43-51.
[86]Guyot A, Tauer K. Reactive surfactants in emulsion polymerization [J]. Advances in Polymer Science,1994,111:45-65.
[87]Cochin D, Laschewsky A, Nallet F. Emulsion polymerization of styrene using conventional, polymerizable, and polymeric surfactants. a comparative study [J]. Macromolecules,1997,30(8):2278-2287.
[88]Miale John B, Miale J R August, Porter Raymond. Anti-fouling marine paints containing microencapsulated anti-fouling agents and the process of microencapsulation:US, 4253877 [P].1981.
[89]Ma Y J, Dong W F, Hempenius M A, et al. Redox-controlled molecular permeability of composite-wall microcapsules [J]. Nature Materials,2006,5(9):724-729.
[90]Wang K W, He Q, Yan X H, et al. Encapsulated photosensitive drugs by biodegradable microcapsules to incapacitate cancer cells [J]. Journal of Materials Chemistry,2007, 17(38):4018-4021.
[91]Wang X Y, Xie X L, Cai C F, et al. Biodegradable branched polyesters poly(vinyl sulfonate-covinyl alcohol)-graft Poly(D,L-lactic-coglycolic acid) as a negatively charged polyelectrolyte platform for drug delivery: synthesis and characterization [J]. Macromolecules,2008,41(8):2791-2799.
[92]Desai K G H, Park H J. Encapsulation of vitamin C in tripolyphosphate cross-linked chitosan microspheres by spray drying [J]. Journal of Microencapsulation,2005,22(2): 179-192.
[93]Yow H N, Routh A F. Formation of liquid core-polymer shell microcapsules [J]. Soft Matter,2006,2(11):940-949.
[94]Haefliger O P, Jeckelmann N, Ouali L, et al. Real-time monitoring of fragrance release from cotton towels by low thermal mass gas chromatography using a longitudinally modulating cryogenic system for headspace sampling and injection [J]. Analytical Chemistry,2010,82(2):729-737.
[95]Coehet F, Claverie J P, Graillat C, et al. Emulsion polymerization of chloroprene in the presence of a maleic polymerizable surfactant: control of gel formation at low conversion [J]. Macromolecules,2004,37:4081-4086.
[96]崔学军.高性能含氟乳液的合成及水性含氟涂料耐沾污性建模[D].吉林长春,吉林大学,2008.
[97]潘祖仁.高分子化学[M].北京：化学工业出版社,2007.
[98]刘国杰.有机硅改性涂料的开发现状[J].有机硅材料,2003,17(2)：25-28.
[99]章基凯,赵陈超.有机硅整理剂及其在纺织工业上的应用[J].纺织学报,1990(6)：283-285.
[100]许飞,张兴元,戴家兵,等.硅氧烷改性水性聚氨酯的交联机理及成膜性能研究[J].涂料技术,2010,12：28-32.
[101]黄雪青.有机硅改性丙烯酸乳液的研究[D].湖北武汉,武汉理工大学,2007.
[102]胡金生,曹同玉,刘庆普.乳液聚合[M].北京：化学工业出版社,1987.
[103]Yagi Toru, Saito Koichi, Sho Katsuhiko. Curable one-liquid silicone-modified acrylic emulsion coating compositions: JP,10298495 [P].1998.
[104]王耀.改性聚氨酯乳液的合成[D].辽宁大连,大连海事大学,2009.
[105]Paul B K, Moulik S P. Uses and applications of microemulsions [J]. Current Science, 2001,80(8):990-1001.
[106]Liu Y Y, Yang M J. Preparation of MMA-BA-DMAEMA Nanosized Latex [J]. Chinese Chemical Letter,2003,14(8):863-865.
[107]Srivastava P. Structure, wettablility, and barrier properties of self-assembled monolayers on metallic surfaces [D]. Houston Texas, Rice university,2006.
[108]王华进,王贤明.94-01无毒防污涂料的研制[J].涂料工业,1998,28(2)：11-13.
[109]刘继华,钱士强.海洋生物附着及其防护技术[J].腐蚀与防护,2010,1(31)：78-84.
[110]Li G J, Shen J R, Zhu Y L. Study of pyridinium-type functional polymers. Ⅱ. Antibacterial activity of soluble pyridinium-type polymers [J]. Journal of Applied Polymer Science,1998,67 (10):1761-1768.
[111]魏刚,黄海燕,熊蓉春.纳米二氧化钛的光催化性能及其在有机污染物降解中的应用[J].现代化工,2003,23(1)：20-23.
[112]巴雄军.氟乐灵微胶囊的研制[J].中国农药,2008,3：42-43.
[113]杨学习.氯化石蜡增塑作用的探讨和作用[J].中国氯碱,2003,3(3)：18-19.
[114]Wang B, Yang F, Qiu W W, et al. Highly efficient synthesis of capsaicin analogues by condensation of vanillylamine and acyl chlorides in a biphase H2O/CHCl3 system [J]. Tetrahedron,2009,65(27):5409-5412.
[115]Gannett P M, Nagel D L, Reilly P J, et al. Capsaicinoids:their separation, synthesis and mutagenicity [J]. Journal of organic chemistry,1988,53 (5):1064-1071.
[116]张开.高分子界面科学[M].北京：中国石化出版社,1997：297-300.
[117]Karst D, Yang Y Y. Using the solubility parameter to explain disperse dye sorption on polylactide [J]. Journal of Applied Polymer Science,2005,96(2):416-422.