内蒙古东北地区上古生界粘土矿物组合的成因意义
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摘要
极低级变质作用是指变质作用最低级部分,与石油、天然气和煤等能源矿产的形成有着紧密的关系,是目前地质学研究的重要课题之一。东北地区(佳蒙地块)晚古生代地层主要是由一套海相沉积层和部分陆相沉积层组成,蕴藏着十分丰富的油气资源。前人研究了晚古生代泥质岩石中伊利石的成因标志,得到了区内晚古生代地层主体属于晚期成岩带和低级近变质带的认识。
作者通过研究不同成岩-极低级变质强度带内伊利石、绿泥石、高岭石、蒙皂石、伊/蒙混层、绿/蒙混层等粘土矿物的相对含量、伊/蒙混层混层比、绿/蒙混层混层比等混层粘土矿物的混层比(蒙皂石在混层粘土矿物中所占比例)的成因标志,表征研究区内的成岩-极低级变质作用;研究不同时代(D、C、P)地层的粘土矿物组合、粘土矿物混层比等与伊利石结晶度的相互关系,从而讨论粘土矿物组合的成因意义。
Northeastern Inner Mongolia lies in eastern East Asia orogenic zone, geotectonic unit consists of EErGuNa and Xingan massif、SongNeng massif and JiaMuSi massif typically. Neopaleozoic formation makes up of a battery of marine deposit formation and partial continental deposit formation, rock are argillaceous rock(mudstone、silty mudstone、argillaceous siltstoue etc.)and carbonate etc., and it contains abundant hydrocarbon resources, which is the most promising area for finding marine exploration activity new area and new territory. The structure in this religion has NE structure and EW structure mainly. By means of XRD and TEM technique, predecessors analyzed and studied illite genesis sign among Neopaleozoic argillaceous rock, researched Neopaleozoic very low-grade metamorphism in Northeastern Inner Mongolia by illite crystallinity index and b0 value etc. and obtained the result that Neopaleozoic main layer in this religion was late diagenetic zone and low anchizone.
This thesis studies varied feature of clay mineral content during different diagenic-very low-grade metamorphism intensity band in the upper Paleozoic, in Northeastern Inner Mongolia, according to illite crystallinity < 0.25( epimetamorphism band )、illite crystallinity 0.25-0.42 (low anchizone) illite crystallinity>0.42 ( late diagenetic zone),discusses varied tendency of clay mineral relative content、mixed layer clay mineral ratio、clay mineral assemblage etc. respectively,and probes into genesis significance of clay mineral assemblage.
Our research demonstrate that clay mineral of argillaceous rock in the upper Paleozoic, in this area are illite、kaolinite、smectite、chlorite、illite / smectite mixed layer、chlorite/ smectite mixed layer etc.. Clay mineral distribution present feature in different time stratigraphic unit and diagenic-very low-grade metamorphism intensity belt as follows:①In Devonian anchizone, average illite crystallinity is 0.35, illite and chlorite are dominant among these clay mineral, content of kaolinite is very low, rate mixed-layer of smectite in mixed-layer mineral (illite / smectite mixed layer and chlorite/ smectite mixed layer) is lower relatively(25%);in diagenetic zone, average illite crystallinity is 0.48, illite and chlorite are dominant among these clay mineral, but content of kaolinite is higher relatively(6%), rate mixed-layer of smectite in mixed-layer mineral is higher relatively(34%).②In Carboniferous anchizone, average illite crystallinity is 0.37, relative content of illite is 66.50%, relative content of illite / smectite mixed layer is 16.00%;in diagenetic zone, average illite crystallinity is 0.58, relative content of illite is 62.00%, relative content of illite / smectite mixed layer is 26.17%.③In Permian anchizone, average illite crystallinity is 0.31, relative content of illite is 65.84%, relative content of illite / smectite mixed layer is 8.74%, rate mixed-layer of smectite in illite / smectite mixed layer and chlorite/ smectite mixed layer is 31.67% and 23.67%,the sum of them is 55.34%; in diagenetic zone, average illite crystallinity is 0.61, relative content of illite is 56.75%, relative content of illite / smectite mixed layer is 37.00%, rate mixed-layer of smectite in illite / smectite mixed layer and chlorite/ smectite mixed layer is 28.75% and 42.50%,the sum of them is 71.25%.④In region of interest, relative content of illite is negative related with illite crystallinity, coefficient of correlation is -0.206;relative content of chlorite is negative related with illite crystallinity, coefficient of correlation is -0.170; relative content of illite / smectite mixed layer is positive related with illite crystallinity, coefficient of correlation is 0.479.⑤There are correlation among these clay mineral,presenting positive correlation are kaolinite and chlorite/ smectite mixed layer、rate of illite / smectite mixed layer、rate of chlorite/ smectite mixed layer,chlorite/ smectite mixed layer and rate of illite / smectite mixed layer、rate of chlorite/ smectite mixed layer,rate of illite / smectite mixed layer and rate of chlorite/ smectite mixed layer; presenting negative correlation are illite / smectite mixed layer and illite, kaolinite and chlorite, chlorite and illite / smectite mixed layer、chlorite/ smectite mixed layer、rate of illite / smectite mixed layer、rate of chlorite/ smectite mixed layer.
作者通过研究不同成岩-极低级变质强度带内伊利石、绿泥石、高岭石、蒙皂石、伊/蒙混层、绿/蒙混层等粘土矿物的相对含量、伊/蒙混层混层比、绿/蒙混层混层比等混层粘土矿物的混层比(蒙皂石在混层粘土矿物中所占比例)的成因标志,表征研究区内的成岩-极低级变质作用;研究不同时代(D、C、P)地层的粘土矿物组合、粘土矿物混层比等与伊利石结晶度的相互关系,从而讨论粘土矿物组合的成因意义。
Northeastern Inner Mongolia lies in eastern East Asia orogenic zone, geotectonic unit consists of EErGuNa and Xingan massif、SongNeng massif and JiaMuSi massif typically. Neopaleozoic formation makes up of a battery of marine deposit formation and partial continental deposit formation, rock are argillaceous rock(mudstone、silty mudstone、argillaceous siltstoue etc.)and carbonate etc., and it contains abundant hydrocarbon resources, which is the most promising area for finding marine exploration activity new area and new territory. The structure in this religion has NE structure and EW structure mainly. By means of XRD and TEM technique, predecessors analyzed and studied illite genesis sign among Neopaleozoic argillaceous rock, researched Neopaleozoic very low-grade metamorphism in Northeastern Inner Mongolia by illite crystallinity index and b0 value etc. and obtained the result that Neopaleozoic main layer in this religion was late diagenetic zone and low anchizone.
This thesis studies varied feature of clay mineral content during different diagenic-very low-grade metamorphism intensity band in the upper Paleozoic, in Northeastern Inner Mongolia, according to illite crystallinity < 0.25( epimetamorphism band )、illite crystallinity 0.25-0.42 (low anchizone) illite crystallinity>0.42 ( late diagenetic zone),discusses varied tendency of clay mineral relative content、mixed layer clay mineral ratio、clay mineral assemblage etc. respectively,and probes into genesis significance of clay mineral assemblage.
Our research demonstrate that clay mineral of argillaceous rock in the upper Paleozoic, in this area are illite、kaolinite、smectite、chlorite、illite / smectite mixed layer、chlorite/ smectite mixed layer etc.. Clay mineral distribution present feature in different time stratigraphic unit and diagenic-very low-grade metamorphism intensity belt as follows:①In Devonian anchizone, average illite crystallinity is 0.35, illite and chlorite are dominant among these clay mineral, content of kaolinite is very low, rate mixed-layer of smectite in mixed-layer mineral (illite / smectite mixed layer and chlorite/ smectite mixed layer) is lower relatively(25%);in diagenetic zone, average illite crystallinity is 0.48, illite and chlorite are dominant among these clay mineral, but content of kaolinite is higher relatively(6%), rate mixed-layer of smectite in mixed-layer mineral is higher relatively(34%).②In Carboniferous anchizone, average illite crystallinity is 0.37, relative content of illite is 66.50%, relative content of illite / smectite mixed layer is 16.00%;in diagenetic zone, average illite crystallinity is 0.58, relative content of illite is 62.00%, relative content of illite / smectite mixed layer is 26.17%.③In Permian anchizone, average illite crystallinity is 0.31, relative content of illite is 65.84%, relative content of illite / smectite mixed layer is 8.74%, rate mixed-layer of smectite in illite / smectite mixed layer and chlorite/ smectite mixed layer is 31.67% and 23.67%,the sum of them is 55.34%; in diagenetic zone, average illite crystallinity is 0.61, relative content of illite is 56.75%, relative content of illite / smectite mixed layer is 37.00%, rate mixed-layer of smectite in illite / smectite mixed layer and chlorite/ smectite mixed layer is 28.75% and 42.50%,the sum of them is 71.25%.④In region of interest, relative content of illite is negative related with illite crystallinity, coefficient of correlation is -0.206;relative content of chlorite is negative related with illite crystallinity, coefficient of correlation is -0.170; relative content of illite / smectite mixed layer is positive related with illite crystallinity, coefficient of correlation is 0.479.⑤There are correlation among these clay mineral,presenting positive correlation are kaolinite and chlorite/ smectite mixed layer、rate of illite / smectite mixed layer、rate of chlorite/ smectite mixed layer,chlorite/ smectite mixed layer and rate of illite / smectite mixed layer、rate of chlorite/ smectite mixed layer,rate of illite / smectite mixed layer and rate of chlorite/ smectite mixed layer; presenting negative correlation are illite / smectite mixed layer and illite, kaolinite and chlorite, chlorite and illite / smectite mixed layer、chlorite/ smectite mixed layer、rate of illite / smectite mixed layer、rate of chlorite/ smectite mixed layer.
引文
[1]Coombs D S Some recent work on the low grades of metamor-phism Austranlian Journal of Scieace,1961
[2]焦玉国,李景坤,乔建华等.伊利石结晶度指数在岩石变质程度研究中的应用.大庆石油地质与开发,2005.1
[3]燕守勋,田庆久,吴昀昭.极低级变质作用及其研究方法.现代地质,2002.3
[4]Frey M,Robinson D Low Grade Metamorphism【M.Ox.ford:B】ackweⅡScience 1998
[5]Bi Xianmei.Zhang Jijun.Mo Jun MioerMngi indlaator of very low-grade metanorphasm;examples from china[A] Abstracts Volume of the 31st Intemational Geological Congress,2000
[6]燕守勋,王志刚,黄永权.由伊利石结晶度研究桂西右江地区区域极低级变质作用.地质科学,2003
[7]燕守勋.广西右江盆地利周-河口剖面极低级变质带的伊利石结晶度与粘土矿物光谱标志对比研究.中国科学,2003
[8]李景坤,宋兰斌,刘伟.松辽盆地北部石炭-二叠系古镜质体反射率恢复.大庆石油地质与开发.2007
[9]毕先梅,莫宣学.成岩-极低级变质-低级变质作用及有关矿产.地学前缘,2004.3
[10]王成文,金巍,张兴洲等.东北及邻区晚古生代大地构造属性新认识.地层学杂志,2008
[11]胡大千,于介江.内蒙古东北地区上古生界的伊利石研究.岩石学报,2009
[12]Winkler H G F.Petrogenesis of Metamorphic Rocks.5th.edition,New York:Sringer Verlag,1979
[13] Frey M·Very low-grade metamorphism of clastic sedimentary rock[A]·In: FreyM·ed·Low TemperatureMetamorphism [C]·Glas-gow: Blackie and Son ltd, 1987·1-33·
[14] Frey M, Robinson D·Low-Grade Metamorphism [M ]·London:Blackwel,l 1999·29-31·
[15] KischH J·Calibration of the anchizone: a critical comparison of illite’crystallinity’scales used for definition [J]·Journal of Metamorphic Geology, 1990, 8: 31-46·
[16]The 31st International Geological Congress Abstracts Volume[C].2000,Session 10—1:1—23.
[17]RAHN M ,P0TEL S(Conveners).Quantifying diagenesiso low-grade metamorphism:Old shoes and new paths[A].EGS-AGU-EUG Joint Assembly Abstracts[C]. 2003.VGP33,EAE03一A.
[18]DAY H W.Very low grade metamorphism in the Sierra Ne—vada.California:An overview and new resultsr [A].EGSAGU-EUG Joint Assembly Abstracts[C].2003.VGP33.EAE03一A—07112.
[19]周希云.贵州奥陶-三叠系牙形石颜色变化指标(CAI)及油气评价.贵州地质,1990
[20]赵孟为.划分成岩作用于埋藏变质作用的指标及其界限.地质论评,1995.5
[21]沈其韩.80年工以来我国变质岩研究的若干进展.地学研究,1992
[22]索书田,游振东,周汉文.极低级变质作用和极低级变质作用带综述.地质科技情报,1995
[23]索书田,毕先梅,赵文霞等.右江盆地三叠纪岩层极低级变质作用及地球动力学意义. SCIENTIA GEOLOGICA SINICA,1998.10
[24]梁斌,何文劲,谢启兴等.川西北壤塘地区三叠纪西康群极低级变质作用.矿物岩石,2003.5
[25]陈明,何文劲,梁斌等.川西高原西康群极低级变质岩特征.四川地质学报,2001.6
[26]朱明新王河锦.长沙-澧陵-浏阳一带冷家溪群及板溪群的甚低级变质作用.岩石学报,2000.9
[27]段菁春,庄新国,何谋春.不同变质程度煤的激光拉曼光谱特征.地质科技情报,2002.6
[28]何谋春,吕新彪,王群英.有机包裹体的拉曼光谱测定.石油实验地质,2002.4
[29]郭少斌,刘玉梅.松辽盆地德惠凹陷深层含油气系统划分.石油实验地质,2002.8
[30]谭靖,刘嵘.低温绿泥石成分温度计Fe/(Fe+Mg)校正的必要性问题.矿物学报,2007.6
[31]董申保.中国变质作用及其与地壳演化的关系.地质出版社,1986
[32]Bruno L, Gerard B . Characterization of the end of smectite-to-illitetransformation: decomposition of X-ray patterns. Clay and Clay Minerals, 1992
[33]Hoffman J,Hower J.Clay mineral assemblages as low grade metamorphic geothermometers:Application to the thrust faulted disturbed belt of Montana,U.S.A.Aspect of Diageness,SPEM Spec.Pub.,1979.
[34]孔详,赵中英,杨子荣.鹤岗煤田泥质岩粘土矿物类型及其他意义.辽宁工程技术大学工程学报,2006.11
[35]Richard M P. Considerations and applications of the illite/ smectite geothermometer in hydrocarbon-bearing rocks of Miocene to Mississip-pian age. Clay and Clay Minerals, 1993
[36]中华人民共和国能源部.碎屑岩成岩阶段划分规范.中华人民共和国石油天然气行业标准1993.2
[37]冯启,冯庆来,于吉顺.广西东攀剖面二叠系顶部粘土矿物特征及古气候意义.沉积学报,2007.6
[38]张慧.西北中生代煤系粘土矿物与煤变质关系.中国煤田地质,1994.12
[39]王河锦,周健.关于伊利石结晶度诸指数的评价.岩石学报,1998.8
[40]张秉良,刘桂芬,方仲景.云南小湾断层泥中伊利石矿物特征及其意义.地震地质,1994.3
[41]索书田,毕先梅,周汉文.极低级变质作用-以右江中生代构造带为例.地质出版社,1999.6
[42]王河锦,陶晓风.伊利石结晶度及其在低温变质研究中若干问题的讨论.地学前缘,2007
[43]王河锦,陶晓风,Rahn Meinert.伊利石结晶度Kubler,Weaver和Weber指数关系式常数的确定与应用.高校地质学报,2007
[44]燕守勋.广西右江盆地利周-河口剖面极低级变质带的伊利石结晶度与粘土矿物光谱标志对比研究.中国科学,2003
[45]王成文,金巍,张兴洲等.佳蒙地块(古陆)的建立.中国古生物学会古生态会古生物专业委员会第三次学术年会论文摘要集,2006
[46]内蒙古自治区区勘查局.内蒙古自治区区域地质志.地质出版社,1991
[47]Arkai,P.,1991,Chlorite crystallinity:an empirical approach and correlation with illite crystallinity,coal rank and mineral facies as exemplified by Palaeozoic and Mesozoic rocks of northeast Hungary.J.metamorphic Geol.,9,723-734
[48]Coobs,D.,1961,Some recent work on the lower grades of metamorphism.Australian Journal of Science,24,203-215.13、
[49]Eslinger,E.and Glasmann,J.R,1993,Geothermometry and Geochronology using clay minerals-An introduction.Clays and Cley Minerals,41(2):117-118
[50]Frey,M.,1978,Progressive low-grade metamorphism of a black shale formation,central Swiss Alps,with special reference to pyrophyllite and margarite bearing assemblages.Journal of Petrology,19(Part):95-135.
[51]Frey,M.,1988,Very-low-grade-metamorphism of clastic sedimntaruy rocks.In: (Frey,M.,ed.)Low Temperature Metamorphism .Blackie,Glasgow,9-57.
[52]汤艳杰,贾建页,谢先德.黏土矿物的环境意义.地学前缘,2002,9
[53]张乃娴.黏土矿物与风化作用.建材地质,1992
[54]WEAVER C E.Clays,Mud sand Shales ,Developments in Sedimentology.Amsterdam: Elsevier, 1989
[55]陈涛,王欢.黏土矿物对古气候指示作用浅析.岩石矿物学杂志,2003
[56]Robinson,D.and Bevins,R.E.,1986,Incipient metamorphism in the Lower Palaezoic marginal basin of Wales.J.metamorphic Geol,4(1):101-113
[57]Sassi,F.P.and Scolari,A.,The b0 value of the potassic white as a barometric indicator in low-grade metamorphism of politic schists.Contr.Mineral.and Petol,1974
[58]Wang,H.Frey,M.and Stern.W.B.Diagenesis and metamorphism of clay minerals in the Helvetic Alps of eastern Switzerland.Clays and Clay Minerals, 1996
[58]杨献忠,叶念军.蒙脱石伊利石化过程中伊-蒙混层形成的Gibbs自由能.地质地球化学,2003
[59]赵杏媛,张有瑜.粘土矿物与粘土矿物分析[M].北京:海洋出版社,1990
[60]贾建业,汤艳杰.环境演变的矿物标识研究新进展[J].岩石矿物学杂志,2001
[61]任磊夫.试论粘土矿物转化过渡结构[J].沉积学报,1988.9
[62]于开平等.浙江长兴煤山剖面P/T界线附近粘土矿物研究.沉积学报,2005.3
[2]焦玉国,李景坤,乔建华等.伊利石结晶度指数在岩石变质程度研究中的应用.大庆石油地质与开发,2005.1
[3]燕守勋,田庆久,吴昀昭.极低级变质作用及其研究方法.现代地质,2002.3
[4]Frey M,Robinson D Low Grade Metamorphism【M.Ox.ford:B】ackweⅡScience 1998
[5]Bi Xianmei.Zhang Jijun.Mo Jun MioerMngi indlaator of very low-grade metanorphasm;examples from china[A] Abstracts Volume of the 31st Intemational Geological Congress,2000
[6]燕守勋,王志刚,黄永权.由伊利石结晶度研究桂西右江地区区域极低级变质作用.地质科学,2003
[7]燕守勋.广西右江盆地利周-河口剖面极低级变质带的伊利石结晶度与粘土矿物光谱标志对比研究.中国科学,2003
[8]李景坤,宋兰斌,刘伟.松辽盆地北部石炭-二叠系古镜质体反射率恢复.大庆石油地质与开发.2007
[9]毕先梅,莫宣学.成岩-极低级变质-低级变质作用及有关矿产.地学前缘,2004.3
[10]王成文,金巍,张兴洲等.东北及邻区晚古生代大地构造属性新认识.地层学杂志,2008
[11]胡大千,于介江.内蒙古东北地区上古生界的伊利石研究.岩石学报,2009
[12]Winkler H G F.Petrogenesis of Metamorphic Rocks.5th.edition,New York:Sringer Verlag,1979
[13] Frey M·Very low-grade metamorphism of clastic sedimentary rock[A]·In: FreyM·ed·Low TemperatureMetamorphism [C]·Glas-gow: Blackie and Son ltd, 1987·1-33·
[14] Frey M, Robinson D·Low-Grade Metamorphism [M ]·London:Blackwel,l 1999·29-31·
[15] KischH J·Calibration of the anchizone: a critical comparison of illite’crystallinity’scales used for definition [J]·Journal of Metamorphic Geology, 1990, 8: 31-46·
[16]The 31st International Geological Congress Abstracts Volume[C].2000,Session 10—1:1—23.
[17]RAHN M ,P0TEL S(Conveners).Quantifying diagenesiso low-grade metamorphism:Old shoes and new paths[A].EGS-AGU-EUG Joint Assembly Abstracts[C]. 2003.VGP33,EAE03一A.
[18]DAY H W.Very low grade metamorphism in the Sierra Ne—vada.California:An overview and new resultsr [A].EGSAGU-EUG Joint Assembly Abstracts[C].2003.VGP33.EAE03一A—07112.
[19]周希云.贵州奥陶-三叠系牙形石颜色变化指标(CAI)及油气评价.贵州地质,1990
[20]赵孟为.划分成岩作用于埋藏变质作用的指标及其界限.地质论评,1995.5
[21]沈其韩.80年工以来我国变质岩研究的若干进展.地学研究,1992
[22]索书田,游振东,周汉文.极低级变质作用和极低级变质作用带综述.地质科技情报,1995
[23]索书田,毕先梅,赵文霞等.右江盆地三叠纪岩层极低级变质作用及地球动力学意义. SCIENTIA GEOLOGICA SINICA,1998.10
[24]梁斌,何文劲,谢启兴等.川西北壤塘地区三叠纪西康群极低级变质作用.矿物岩石,2003.5
[25]陈明,何文劲,梁斌等.川西高原西康群极低级变质岩特征.四川地质学报,2001.6
[26]朱明新王河锦.长沙-澧陵-浏阳一带冷家溪群及板溪群的甚低级变质作用.岩石学报,2000.9
[27]段菁春,庄新国,何谋春.不同变质程度煤的激光拉曼光谱特征.地质科技情报,2002.6
[28]何谋春,吕新彪,王群英.有机包裹体的拉曼光谱测定.石油实验地质,2002.4
[29]郭少斌,刘玉梅.松辽盆地德惠凹陷深层含油气系统划分.石油实验地质,2002.8
[30]谭靖,刘嵘.低温绿泥石成分温度计Fe/(Fe+Mg)校正的必要性问题.矿物学报,2007.6
[31]董申保.中国变质作用及其与地壳演化的关系.地质出版社,1986
[32]Bruno L, Gerard B . Characterization of the end of smectite-to-illitetransformation: decomposition of X-ray patterns. Clay and Clay Minerals, 1992
[33]Hoffman J,Hower J.Clay mineral assemblages as low grade metamorphic geothermometers:Application to the thrust faulted disturbed belt of Montana,U.S.A.Aspect of Diageness,SPEM Spec.Pub.,1979.
[34]孔详,赵中英,杨子荣.鹤岗煤田泥质岩粘土矿物类型及其他意义.辽宁工程技术大学工程学报,2006.11
[35]Richard M P. Considerations and applications of the illite/ smectite geothermometer in hydrocarbon-bearing rocks of Miocene to Mississip-pian age. Clay and Clay Minerals, 1993
[36]中华人民共和国能源部.碎屑岩成岩阶段划分规范.中华人民共和国石油天然气行业标准1993.2
[37]冯启,冯庆来,于吉顺.广西东攀剖面二叠系顶部粘土矿物特征及古气候意义.沉积学报,2007.6
[38]张慧.西北中生代煤系粘土矿物与煤变质关系.中国煤田地质,1994.12
[39]王河锦,周健.关于伊利石结晶度诸指数的评价.岩石学报,1998.8
[40]张秉良,刘桂芬,方仲景.云南小湾断层泥中伊利石矿物特征及其意义.地震地质,1994.3
[41]索书田,毕先梅,周汉文.极低级变质作用-以右江中生代构造带为例.地质出版社,1999.6
[42]王河锦,陶晓风.伊利石结晶度及其在低温变质研究中若干问题的讨论.地学前缘,2007
[43]王河锦,陶晓风,Rahn Meinert.伊利石结晶度Kubler,Weaver和Weber指数关系式常数的确定与应用.高校地质学报,2007
[44]燕守勋.广西右江盆地利周-河口剖面极低级变质带的伊利石结晶度与粘土矿物光谱标志对比研究.中国科学,2003
[45]王成文,金巍,张兴洲等.佳蒙地块(古陆)的建立.中国古生物学会古生态会古生物专业委员会第三次学术年会论文摘要集,2006
[46]内蒙古自治区区勘查局.内蒙古自治区区域地质志.地质出版社,1991
[47]Arkai,P.,1991,Chlorite crystallinity:an empirical approach and correlation with illite crystallinity,coal rank and mineral facies as exemplified by Palaeozoic and Mesozoic rocks of northeast Hungary.J.metamorphic Geol.,9,723-734
[48]Coobs,D.,1961,Some recent work on the lower grades of metamorphism.Australian Journal of Science,24,203-215.13、
[49]Eslinger,E.and Glasmann,J.R,1993,Geothermometry and Geochronology using clay minerals-An introduction.Clays and Cley Minerals,41(2):117-118
[50]Frey,M.,1978,Progressive low-grade metamorphism of a black shale formation,central Swiss Alps,with special reference to pyrophyllite and margarite bearing assemblages.Journal of Petrology,19(Part):95-135.
[51]Frey,M.,1988,Very-low-grade-metamorphism of clastic sedimntaruy rocks.In: (Frey,M.,ed.)Low Temperature Metamorphism .Blackie,Glasgow,9-57.
[52]汤艳杰,贾建页,谢先德.黏土矿物的环境意义.地学前缘,2002,9
[53]张乃娴.黏土矿物与风化作用.建材地质,1992
[54]WEAVER C E.Clays,Mud sand Shales ,Developments in Sedimentology.Amsterdam: Elsevier, 1989
[55]陈涛,王欢.黏土矿物对古气候指示作用浅析.岩石矿物学杂志,2003
[56]Robinson,D.and Bevins,R.E.,1986,Incipient metamorphism in the Lower Palaezoic marginal basin of Wales.J.metamorphic Geol,4(1):101-113
[57]Sassi,F.P.and Scolari,A.,The b0 value of the potassic white as a barometric indicator in low-grade metamorphism of politic schists.Contr.Mineral.and Petol,1974
[58]Wang,H.Frey,M.and Stern.W.B.Diagenesis and metamorphism of clay minerals in the Helvetic Alps of eastern Switzerland.Clays and Clay Minerals, 1996
[58]杨献忠,叶念军.蒙脱石伊利石化过程中伊-蒙混层形成的Gibbs自由能.地质地球化学,2003
[59]赵杏媛,张有瑜.粘土矿物与粘土矿物分析[M].北京:海洋出版社,1990
[60]贾建业,汤艳杰.环境演变的矿物标识研究新进展[J].岩石矿物学杂志,2001
[61]任磊夫.试论粘土矿物转化过渡结构[J].沉积学报,1988.9
[62]于开平等.浙江长兴煤山剖面P/T界线附近粘土矿物研究.沉积学报,2005.3