二茂铁基含硫席夫碱及其配合物的合成与表征
|
摘要
过渡金属与席夫碱配体所形成的配合物以其多样的结构和广泛的用途愈来愈受到人们的重视。该类配合物在催化、生物活性及功能材料等领域都有广泛的应用前景。肼基二硫代甲酸酯衍生的席夫碱及其配合物具有很强的抗癌、抗病毒性能,而二茂铁具有改善药物的功能,一些二茂铁类的衍生物由于其强给电子性和电子桥联作用而显示出良好的非线性光学特性。基于它们的结构特性及其应用的广泛性,将肼基二硫代甲酸酯衍生的席夫碱与二茂铁类的衍生物联系起来研究引起了许多研究者的兴趣。
本文合成了六种含硫席夫碱: (反)-间硝基肉桂酰基二茂铁缩-(S)-甲基二硫代碳酰腙(L~1),(反)-间硝基肉桂酰基二茂铁-(S)-苄基二硫代碳酰腙(L~2),(反)-呋喃亚甲基乙酰基二茂铁-(S)-甲基二硫代碳酰腙(L~3),(反)-对甲基肉桂酰基二茂铁-(S)-甲基二硫代碳酰腙(L~4),(反)-对溴(氯)肉桂酰基二茂铁-(S)-甲基二硫代碳酰腙(L~5、L~6)。并且得到了配体(HL~1)和配合物(Zn(L~1)_2, Zn(L~6)_2)的单晶结构。另外还利用这些配体与过渡金属(Ni2+, Cd2+, Pb2+, Hg2+, Zn2+)共合成配合物24种。分别是: Ni(L~1)_2、Cd(L~1)_2、Pb(L~1)_2、Hg(L~1)_2、Zn(L~1)_2、Hg(L~2)_2、Zn(L~2)_2、Ni(L~3)_2、Cd(L~3)_2、Pb(L~3)_2、Hg(L~3)_2、Zn(L~3)_2、Ni(L~4)_2、Cd(L~4)_2、Pb(L~4)_2、Hg(L~4)_2、Zn(L~4)_2、Ni(L~5)_2、Cd(L~5)_2、Pb(L~5)_2、Hg(L~5)_2、Zn(L~5)_2、Cd(L~6)_2、Zn(L~6)_2。对上述配合物均进行了元素分析、红外光谱、紫外光谱、氢谱、摩尔电导率、循环伏安等表征。
根据实验事实,本文推测了配合物的配位形式。实验证明了配体HL~是反式构型的二齿配体,是以亚胺中的N原子和烯硫醇式中的S原子为配位原子的。这些化合物的生理活性尚在测试中,将在以后报道。
The complexes, synthesized with transition metal and Schiff’s bases, are more and more important for their various structures and extensive uses. The applied foreground of these complexes will be extensive in the field of catalysis, bioactivity and material etc. The Schiff’s bases from S-methyl(or benzyl)dithiocarbazate and their complexes have strongly antitumour and antivirus activities, while the ferrocenyl group can improve medicinal properties. Some ferrocene derivatives are excellent nonlinear optical materials, because they are strong electron donors and contain electron-flowing bridge. Due to their interesting structural character and wide-ranging uses, the studies of the Schiff base and ferrocene derivatives attracted many investigators' attention.
In this paper, six sulf-schiff bases, (E)-m-nitrocinnamoylferrocene condensed with S-methyldithiocarbazate (L~l), (E)-m-nitrocinnamoylferrocene condensed with S-benzyl dithiocarbazate (L~2), (E)-3-(furan-2-yl)-1-ferrocenylprop-2-en-1-one condensed with S-methyldithiocarbazate (L~3), (E)-p-methylcinnamoylferrocene condensed with S-meth- yldithiocarbazate (L~4), (E)-p-bromo(or chloro)cinnamoylferrocene condensed with S-methyldithiocarbazate (L~5, L~6), had been synthesized and characterized. The crystal structure of the ligand (HL~1) and complexes [Zn(L~1)_2, Zn(L~6)_2] had been determined by X-ray. These six Sulf-Schiff bases were used to synthesize the complexes with transition metal ions(Ni~(2+), Cd~(2+), Pb~(2+), Hg~(2+), Zn~(2+)), and twenty-four complexes obtained. Zn(L~1)_2, Ni(L~1)_2, Cd(L~1)_2, Pb(L~1)_2, Hg(L~1)_2, Zn(L~2)_2, Hg(L~2)_2, Ni(L~3)_2, Cd(L~3)_2, Pb(L~3)_2, Hg(L~3)_2, Zn(L~3)_2, Ni(L~4)_2, Cd(L~4)_2, Pb(L~4)_2, Hg(L~4)_2, Zn(L~4)_2, Ni(L~5)_2, Cd(L~5)_2, Pb(L~5)_2, Hg(L~5)_2, Zn(L~5)_2, Cd(L~6)_2, Zn(L~6)_2. All of these complexes were characterized by elemental analysis, IR spectra, UV spectra, 1HNMR, molar conductance and cyclic voltammetry.
The synthesis reaction mechanisms of the ligand and complexes were presumed by experiment facts. It is shown that HL~ appears to be a bidentate ligand with trans configuration to coordinate the metal through the azomethine nitrogen and thioenolic sulfur atom.The physiological activities of every compound are being tested and their results will be reported in the future.
本文合成了六种含硫席夫碱: (反)-间硝基肉桂酰基二茂铁缩-(S)-甲基二硫代碳酰腙(L~1),(反)-间硝基肉桂酰基二茂铁-(S)-苄基二硫代碳酰腙(L~2),(反)-呋喃亚甲基乙酰基二茂铁-(S)-甲基二硫代碳酰腙(L~3),(反)-对甲基肉桂酰基二茂铁-(S)-甲基二硫代碳酰腙(L~4),(反)-对溴(氯)肉桂酰基二茂铁-(S)-甲基二硫代碳酰腙(L~5、L~6)。并且得到了配体(HL~1)和配合物(Zn(L~1)_2, Zn(L~6)_2)的单晶结构。另外还利用这些配体与过渡金属(Ni2+, Cd2+, Pb2+, Hg2+, Zn2+)共合成配合物24种。分别是: Ni(L~1)_2、Cd(L~1)_2、Pb(L~1)_2、Hg(L~1)_2、Zn(L~1)_2、Hg(L~2)_2、Zn(L~2)_2、Ni(L~3)_2、Cd(L~3)_2、Pb(L~3)_2、Hg(L~3)_2、Zn(L~3)_2、Ni(L~4)_2、Cd(L~4)_2、Pb(L~4)_2、Hg(L~4)_2、Zn(L~4)_2、Ni(L~5)_2、Cd(L~5)_2、Pb(L~5)_2、Hg(L~5)_2、Zn(L~5)_2、Cd(L~6)_2、Zn(L~6)_2。对上述配合物均进行了元素分析、红外光谱、紫外光谱、氢谱、摩尔电导率、循环伏安等表征。
根据实验事实,本文推测了配合物的配位形式。实验证明了配体HL~是反式构型的二齿配体,是以亚胺中的N原子和烯硫醇式中的S原子为配位原子的。这些化合物的生理活性尚在测试中,将在以后报道。
The complexes, synthesized with transition metal and Schiff’s bases, are more and more important for their various structures and extensive uses. The applied foreground of these complexes will be extensive in the field of catalysis, bioactivity and material etc. The Schiff’s bases from S-methyl(or benzyl)dithiocarbazate and their complexes have strongly antitumour and antivirus activities, while the ferrocenyl group can improve medicinal properties. Some ferrocene derivatives are excellent nonlinear optical materials, because they are strong electron donors and contain electron-flowing bridge. Due to their interesting structural character and wide-ranging uses, the studies of the Schiff base and ferrocene derivatives attracted many investigators' attention.
In this paper, six sulf-schiff bases, (E)-m-nitrocinnamoylferrocene condensed with S-methyldithiocarbazate (L~l), (E)-m-nitrocinnamoylferrocene condensed with S-benzyl dithiocarbazate (L~2), (E)-3-(furan-2-yl)-1-ferrocenylprop-2-en-1-one condensed with S-methyldithiocarbazate (L~3), (E)-p-methylcinnamoylferrocene condensed with S-meth- yldithiocarbazate (L~4), (E)-p-bromo(or chloro)cinnamoylferrocene condensed with S-methyldithiocarbazate (L~5, L~6), had been synthesized and characterized. The crystal structure of the ligand (HL~1) and complexes [Zn(L~1)_2, Zn(L~6)_2] had been determined by X-ray. These six Sulf-Schiff bases were used to synthesize the complexes with transition metal ions(Ni~(2+), Cd~(2+), Pb~(2+), Hg~(2+), Zn~(2+)), and twenty-four complexes obtained. Zn(L~1)_2, Ni(L~1)_2, Cd(L~1)_2, Pb(L~1)_2, Hg(L~1)_2, Zn(L~2)_2, Hg(L~2)_2, Ni(L~3)_2, Cd(L~3)_2, Pb(L~3)_2, Hg(L~3)_2, Zn(L~3)_2, Ni(L~4)_2, Cd(L~4)_2, Pb(L~4)_2, Hg(L~4)_2, Zn(L~4)_2, Ni(L~5)_2, Cd(L~5)_2, Pb(L~5)_2, Hg(L~5)_2, Zn(L~5)_2, Cd(L~6)_2, Zn(L~6)_2. All of these complexes were characterized by elemental analysis, IR spectra, UV spectra, 1HNMR, molar conductance and cyclic voltammetry.
The synthesis reaction mechanisms of the ligand and complexes were presumed by experiment facts. It is shown that HL~ appears to be a bidentate ligand with trans configuration to coordinate the metal through the azomethine nitrogen and thioenolic sulfur atom.The physiological activities of every compound are being tested and their results will be reported in the future.
引文
1. P. Pfeiffer, Synthesis and Character of Some Metal Comlex of Schiff Base Ligand, J. Parkt. Chem., 1931, 129, 163-167.
2. Robert D. Jones, David A. Summerville, and Fred Basolo, Synthetic oxygen carriers related to biological systems, Chem. Rev., 1979, 79, 139.
3. E. G. Samsel, K. Srinivasan, and Jay K. Kochi, Mechanism of the chromium catalyzed epoxidati-文 on of olefins. Role of oxochromium (V) cations, J. Am. Chem. Soc., 1985, 107, 7606.
4. Pascal G. Lacroix and Jean-Claude Daran, Synthesis, crystal structure, conductivity and magnetic properties of trifluoromethylated dinuclear copper(II) complexes with tetracyanoquinodimethane, J. Chem. Soc., Dalton Trans., 1997, 8, 1369.
5. 钟超凡, 邓建成, 桶任, 双安息香缩三乙四胺双核过渡金属配合物的合成、表征与载氧性质, 高等学校学报, 1998, 19(2), 174.
6. 陈新斌, 桂明德, 朱中杰, 双[N, N'-亚乙基-2, 2'-(苯基亚甲基)-(3, 4-二甲基吡咯-5-醛缩亚胺)]合锰(II)的合成、光谱特征及拟酶催化性能研究, 高等学校学报, 1998, 3, 1065.
7. Russel C. Long, David N. Hendrickson, Intra molecular electron transfer in a series of mixed- valence copper(II)-copper(I) complexes, J. Am. Chem. Soc., 1983, 105, 1513.
8. Charles J, O.Connor, Dale Firmin, Binuclear molecules incorporating small molecules as bridg- ing ligands, Inorg. Chem., 1986, 25, 2300.
9. P. Guerriero, S. Tamburini, P. A. Vigato, M?ssbauer and magnetic properties of mononuclear, homo-and hetero-dinuclear complexes, Inorg. Chim. Acta, 1993, 213, 279.
10. Pascal G. Lacroix, Jean Claude Daran, Synthesis, crystal structure, conductivity and magnetic properties of trifluoromethylated dinuclear copper(II) complexes with tetracyanoquinodimethane, J. Chem. Soc., Dalton Trans., 1997, (8), 1369.
11. Rita H. Molina, Alfredo Mederos, Dimer species in dimethyl sulfoxide/water(80:20w/w) solution of N, N'-bis(salicylicdene)-m-phenylenediamine(H2sal-m-phen) and similar Schiff bases with Cu(II), Ni(II), Co(II) and Zn(II), J. Chem. Soc., Dalton Trans., 1997, (22), 4327.
12. Xiaoyan Chen, Shuzhong Zhan, Synthesis, electrochemical and magnetic properties of Cu complexes of a series of new compartmental trinucleating ligands H4L, J. Chem. Soc., Dalton Trans., 1997, (2), 245.
13. Jonathan D. Crane, David E. Feton, Unsymmetric dicopper(II) complexes of dinucleating ligands bearing chemically distinct coordination environments, J. Chem. Soc., Dalton Trans., 1991, (11), 2979.
14. Chikako Higrchi, Hiroshi Sakiyanma, Dinuclear manganese(II) complexes of unsymmetric phenol-based dinucleating ligands with amino and imino chelating arms: synthesis, structure and catalase-like activity, J. Chem. Soc., Dalton Trans., 1994, (7), 1097.
15. M. Marappan, V. Narayan, Synthesis, spectral and electrochemical properties of a new series of unsymmetrical bis(phenoxo) bridged macrocyclic binuclear manganese (III) complexes, J. Chem. Soc., Dalton Trans., 1998, 3405.
16. D. Black, A. J. Blake, Metallosupramolecular silver complexes of bis- and tetra-kis-(2-pyridyl sulfanylmethyl)benzenes, J. Chem. Soc., Dalton Trans., 1998, (23), 3935.
17. N. Brianese, U. Casellato, S. Tamburini, Functionalized acyclic Schiff bases and related compl- exes with d- and f-metalions, Inorg. Chim. Acta, 1998, 272, 235.
18. David E. Feton, Metallobiosites and their synthetic analogs a belief in synergism, Chem. Soc. Rev., 1999, 28(3), 159.
19. K. Dey, J Scient, Schiff bases and their uses, Ind. Res., 1974, 33(2), 76.
20. 明阳福, 黄震年, 许宝安, 双席夫碱-N, N'-二(2-羟基-1-萘甲醛)缩-1, 4-苯二胺的电子光谱和光致变色机理研究, 中国科学, 1997, 27(2), 120.
21. 李清寒, 陈淑华, 缩氨基硫脲类化合物的设计合成和生物活性研究, 有机化学, 2006, 26(4), 528-532.
22. Qinlu, Chengyu Shen, Qinhui Luo, A study on the Schiff base Cu2Zn2SOD model complexes- The relationship between structure and activity, Polyhedron., 1993, 12 (16), 2005.
23. 唐波, 刘阳, 梁芳珍, 陈德展, 孙天麟, β-CD-Shiff 碱铜(II)配合物模拟酶催化光度法的研究, 化学学报, 2000, 58(8), 1031-1036.
24. 唐波, 刘阳, 唐晓玲, SDS-Schif 碱铜(II)配合物模拟酶催化光度法研究, 高等学校化学学报, 2001, 22(6), 919-921.
25. Cai L. S., Mahmound H. Han Y., Binuclear versus mononuclear copper complexes as catalysts for asymmetric cyclopropanation of styrene, Tetrahedron Asymmetry, 1999, 10(3), 411.
26. Evans D. A, Woerpel K. A, Hinman M. M, Bis(oxazolines) as chiral ligands in metal-catalyzed asymmetric reactions, J. Am. Chem. Soc., 1991, 113(2), 726.
27. Doyle M. P, Forbes D. C, Recent Advances in Asymmetric Catalytic Metal Carbene Transformati- ons, Chem. Rev., 1998, 98 (2), 911.
28. Aratani T, Catalytic asymmetric synthesis of cyclopropanecarboxylic acids: an application of chiral copper carbenoid reaction, Pure. Appl. Chem., 1985, 57(12), 1839.
29. Desai S. B., Desai P. B., Desai K. R., Synthesis of some Schiff bases, thiazolidinones and azeti- dinones derived from 2, 6-diaminobenzo[1, 2-d-4, 5-d'] bisthiazole and their anticancer activities, Heterocycl Commun., 2001, 7(1), 83.
30. 张恭孝, 杨荣华席夫碱金属配合物的研究进展, 山东化工, 2004, 33, 14-17.
31. Bastos M. B. R., Moreira J. C., Farias P. A. M., Adsorptive stripping voltammetric behavior of UO2(II) complex with Schiff base N, N'-ethylenebis(salicylidenimine) in aqueous medium containing 4-(2-hydroxyethyl)-1-piperazine ethanesulfonic acid, Analytica Chimica. Acta, 2000, 408(1-2), 83.
32. Ma H., Chen S. H., Niu L, Studies on electrochemical behavior of copper in aerated NaBr solutions with Schiff base, N, N'-o-phenylenebis(3-methoxysalicylidenimine), J. Electrochemical文 Society, 2001, 148(5), 208.
33. 赵建章, 赵冰, 徐蔚青, Schiff 碱 N, N'-双水杨醛缩-1, 6-己二胺的光致变色光谱研究, 高等学校化学学报, 2001, 22(6), 971.
34. 陈德余, 封子先, 胡小莉, 冯亚非, 某些过渡金属氨基酸席夫碱配合物的合成、表征及其对O2-的清除作用, 浙江大学学报, 1996, 30(5), 498-502.
35. 叶勇, 2-氯代苯甲醛丙氨酸席夫碱及其 3d-过渡金属配合物的合成与表征, 湖北大学学报, 2001, 23(1), 57.
36. 陈德余, 张义建, 张平, 甲硫氨酸席夫碱铜、锌、钴配合物合成及抗 O2-性能, 应用化学, 2000, 17(6), 607-610.
37. 叶勇, 胡继明, 曾云鹗, N-β-萘酚醛-D-氨基葡萄糖席夫碱甘氨酸金属络合物与 DNA 作用的谱学研究, 分析化学, 2001, 7.
38. 叶勇, 胡继明, 曾云鹗, N-β-萘酚醛-D-氨基葡萄糖席夫碱金属配合物与 DNA 作用的谱学研究, 无机化学学报, 2000, 16(6), 951-958.
39. 鲁桂, 姚克敏, 张肇英, 镧系与直链系-组氨酸Schiff碱配合物合成、波谱与生物活性, 应用化学, 2001, 18(1), 1-4.
40. Hodnett E. M, Dunn W, Structure-antitumor activity correlation of some Schiff bases, J. Med. Chem., 1970, 13, 768.
41. 张建民, 李瑞芳, 刘树祥, 过渡金属配合物的稳定性及其杀菌活性, 无机化学学报, 1999, 15(4), 493-496.
42. Nyarkusk, Mavusoe, Preparation, characterisation and biological evaluation of a chromium(Ⅲ) Schiff bases complex derived from o-nitrobenzaldehyde and p-amino phenol, South African J. Chem., 1998, 51(4), 168-172.
43. 柳翠英, 李忠, 刘培漫, 5-硝基水杨醛亚胺合铜(II)类鳌合物的合成与抑菌活性, 华西药学杂志, 1996, 11(2), 69-71.
44. 柳翠英,赵全芹, 郭秀英, 5-N-(2-2羟基乙基)水杨醛亚胺Shiff碱的合成与表征, 化学试剂, 1998, 20(1), 42-43.
45. 卢冰熙, 李淑贤, 叶文法, 含四唑环Schiff碱的合成及植物激素活性, 湖南化学, 2000, 30(5), 42-43.
46. 唐婷, 席夫碱的研究新进展, 杭州医学高等专科学校学报, 2000, 21(4), 204-210.
47. 魏丹毅, 李冬成, 姚克敏, 稀土元素与α-丙氨酸席夫碱双核配合物的合成与表征及催化活性, 无机化学学报, 1998, 14(2), 209-213.
48. 鲁桂, 姚克敏, 张肇英, 镧系与直链系-组氨酸Schiff碱配合物合成、波谱与生物活性, 应用化学, 2001, 18(1), 1-4.
49. Yong L, Huang J. L, Lian B, Synthesis of titanium(Ⅳ) complexes with Schiff bases ligand and their catalytic activities for polymerisation of ethylene and etyrene, Chinese Journal of Chemistry., 2001, 19(4), 429-432.
50. Cai L. S., Mahmound H., Han Y., Binuclear versus mononuclear copper complexes as catalysts for asymmetric cyclopropanation of styrene, Tetrahedron Asymmetry, 1999, 10(3), 411.
51. 仇敏, 刘国生, 姚小泉, 催化学报, 2001, 22(1), 77.
52. 杜向东, 俞贤达, 非对称Schiff碱过渡金属配合物模拟酶催化烯烃环氧化, 高等学校化学学报, 1997, 18(4), 67.
53. 杜向东, 俞贤达, 非对称希夫碱过渡金属配合物模拟催化烯烃环氧化, 分子催化, 1997, 12(1), 26-30.
54. 王积涛, 陈蓉, 冯霄, 手性过渡金属(Mn, Co, Ni)Salen配合物催化NaOCl不对称氧化苯乙烯的反应研究, 有机化学, 1998, 18, 228-234.
55. 何星存, 蔡沛祥, 莫金垣, 一氧化氮在聚钴-席夫碱修饰电极上的电催化氧化, 分析实验室, 2000, 19(1), 9.
56. 何星存, 邓锐, 李平, 用修饰电极导数伏安法同时测定多巴胺和肾上腺素, 分析测试学报, 2000, 19(1), 35.
57. Khuhawar. M Y, Lanjwani S. N, High-performance liquid Chromatographic determination of uranium using solvent extraction and bis(alicyladehyde)tetramethylene diimine as complexing reagent , Talanta., 1995, 42, 1925-1929.
58. 李锦州, 安郁美, 于文锦, 新席夫碱萃取剂(HPMaFP )TEN的合成及其在反相纸色谱中的研究, 化学试剂, 1996, 18 (6), 327-329.
59. 孔淑青, 徐曲, 赫莱安, 用桑色素甲硫氨酸席夫碱荧光法测定锡青铜中痕量铝的研究, 江西冶金, 1999, 19(6), 48
60. Li S. L., Chen S. H., Lei S. B., Investigation on some Schiff bases as HCl corrosion inhibitors for copper, Corrosion Science, 1999, 41(7), 1273.
61. Quan Z., Wu X., Chen S., Self-assembled monolayers of Schiff bases on copper surfaces, Corrosion, 2001, 57(3), 195.
62. Kuzentsov Y. I., Vagapov R. K., On the inhibition of hydrogen sulfide corrosion of steel with Schiff bases, Rrot Met., 2001, 37(3), 210.
63. Desai M.N, Chauhan P.O, Shah N, Schiff bases derived form chloroanilines as corrosion inhibitors of zinc in sulfuric acid solutions, European Symposium on Corrision Inhibitors., 1995, 27, 891-902.文
64. Bansiwal A. Anthonyp, Mathurs Y, Inhabitive effect of some Schiff bases on corrosion of aluminum in hydrochloric acidsolution, Corros, 2000, 35(4), 301-303.
65. Ma H, Chen S. H., Niu L, Studies on electrochemical behavior of copper in aerated NaBr solutions with Schiff base, N,N'-o-phenylenebis(3-methoxysalicylidenimine), J. Electrochemical. Society, 2001, 148(5), 208.
66. Grabowaka A, Kownacki K, Karpiuk J, Photcxhromism and proton transfer reaction cycle of new internalty H-bonded Schiff bases, Chemical Physics Letters, 1997, 267, 132-140.
67. 朱传方, 席夫碱及其络合物的可逆热致变色材料, 化学通报, 2000, 8, 15-20.
68. 吴爱斌, 朱传方, 5-(4'-磺胺苯基偶氮)水杨醛席夫碱的合成及其热色性研究, 华中师范大学学报, 2002, 36(2).
69. 陈玉红, 丁克强, 王庆飞, 席夫碱应用研究新进展, 河北师范大学学报, 2003, 27 (1), 71-73.
70. Ahmed M Donia, EI-Zxiny M Ebid, Thermochromism in nickel(II) complexes with Schiff base derivatives of 4-aminoantipyrine, Thermochimica Acta, 1988, 131, 1-6.
71. Naohide Matsumoto, Synthesis and characterization of iron(III) complexes with unsymmetrical quadridentate Schiff bases, and spin equilibrium behavior in solution, Kazuhiro Kimoto, Bull Chem. Soc., Jpn, 1984, 57(11), 3307-3311.
72. 黄发宏, 王彬, 液晶热变色印刷油墨, CN 1062744A., 1992.
73. Masaru H, Junko T, Koichi N, Laminated fabrics having temperature controlling function, JP0 2234980, 1990.
74. 任红霞, 雷自强, 张海涛, π共轭席夫碱聚合物的合成及其荧光性能, 西北师范大学学报, 2000, 36(3), 36-38.
75. 吕绪良, 许卫东, 崔传安, 席夫碱的合成及其在热红外伪装涂料中的应用, 解放军理工大学学报, 2000, 1(6), 54-57.
76. 毕思玮, 余海滨, 一个含有端基双键的席夫碱型液晶化合物的合成与表征, 曲阜师范大学学报, 1999, 25(6), 93-95.
77. Zhu Xinde, Wang Chenggang, Le Zhifeng, Mei Shangyun, Yen Zhenhuan, WuZishen, Synthesis, characterization and scavenger effect on superoxide of copper(II)and zinc(II) complexes derived from thiosemicarbazide, Synth. React. Inorg. Met.-0rg. Chem., 1991, 21(9), 1365.
78. M. AkbarAli, A. H. Mirza, M. HanitiS. A. Hamid, P. V. Bernhardt, Diphenyltin(IV) complexes of the 2-quinolinecarboxaldehyde Schiff bases of S-methyl- and S-benzyl- dithiocarbazate (Hqaldsme and Hqaldsbz): X-ray crystal structures of Hqaldsme and two conformers of its diphenyltin(IV) complex, Polyhedron, 2005, 24(3), 383–390.
79. 杨锦明, 张猛, 曹建国, 含硫双Schiff碱型配体的合成与表征, 光谱实验室, 2003, 20(4).
80. 陈良壁, 郑细鸣, 李碧婵, 肼基双硫代甲酸苄酯类席夫碱的合成, 南平师专学报, 2003, 22(4).
81. 张霞, 刘万毅, 田大年, 新试剂4-氯查尔酮缩氨基硫脲与铜(II)的显色反应研究, 分析试验室, 2006, 25(6).
82. 孙楠, 杨忠愚, 胡惟孝, 杂环基缩胺硫脲的合成及其抗癌活性的研究(含氟哌酸基的缩胺硫脲), 合成化学, 2001, 9(2).
83. T. J. Kealy, P. L. Paulson, A new type of organo-iron compound, Nature, 1951, 168, 1039.
84. 孙红随, 马永祥, 殷元骐, 含二茂铁基席夫碱及其配合物的研究, 无机化学学报, 1992, 8(2), 203.
85. Yao-Cheng Shi, Synthesis and crystal structure of a nickel complex with the bidentate ligand derived from condensation of acetylferrocene and S-benzyldithiocarbazate, Journal of Coordination Chemistry., 2004, 57(11), 961-966.
86. 胡培植, 季立才, 王亚夫, 张伦, 二茂铁甲酰丙酮缩氨基硫脲金属配合物研究, 无机化学学报, 1996, 12(1), 11-17.
87. 孟祥茹, 李爱梅, 阴春枝, 田孟超, 双乙酰基二茂铁缩氨基硫脲与Cu(Ⅱ )、Zn(Ⅱ )烯夫碱配合物的合成与表征, 河南科学, 1998, 16(3), 287-290.
88. G. S. Huang, Y. H. Liu, B. H. Chen, and Y. X. Ma, (E)-cinnamoylferrocene S-Benzylcarbodithioyl hydrazone and its chelates, Chem. Papers., 1999, 53(1), 65.
89. G.S. Huang, B.H. Chen, C.M. Liu, and Y.X. M, Transition metal(II) complexes of (E)- cinnamoyl ferrocene (S)-methylcarbodithioylhydrazone, Transition Met. Chem., 1998, 23, 589.
90. A.G. Hu, L.Y. Zhang, N.Y. Fu, Y.F. Yuan, T. Z. Ding, Synthesis, characterization and scavenger effect on superoxide of copper(II) and zinc(II) complexes derived from thiosemicarbazide, Synth. React. Inorg. Met.-Org. Chem., 1998, 28, 809.
91. (反)-肉桂酰基二茂铁缩二硫代碳酰腙及其Cu(II)、Zn(II)配合物的合成与表征, 刘永红, 刘晓岚, 杨声, 马永祥, 有机化学, 2001, 21(3), 218-222.
92. 硫、氮双齿配体与Cd(II)和Hg(II)配合物的合成与表征, 刘晓岚, 刘永红, 袁冬梅,景淆壁, 石尧成, 有机化学, 2005, 25(11), 1427-1430.
1. 李清寒, 陈淑华, 缩氨基硫脲类化合物的设计合成和生物活性研究, 有机化学, 2006, 26(4), 528-532.
2. Offiong O.E., Martelli S., Antibacterial activity of metal complexes of benzil and benzoin thiosemicarbazones, Farmaco, 1994, 49, 513-518.
3. Bharti N., Maurya mannar R., Palladium(II) complexes of NS donor ligandsderived from S-methyl-dithiocarbazate, S-benzyldithiocarbazateand thiosemicarbazide as antiamoebic agents, Naqvi, Eur. J. Med. Chem., 2000(35), 481.
4. Quiroga A. G., Perez J. M., Lopez-Solcra, Novel Tetranuclear Orthometalated Comp lexes of Pd(II) and Pt(II) Derived from p-Isopropylbenzaldehyde Thiosemicarba- zone with Cytotoxic Activity in cis-DDP Resistant Tumor Cell Lines. Interaction of These Complexes with DNA, J. Med. Chem, 1998, 41, 1399-1408.
5. Hadjipavlou-Litina D., QSAR of thiosemicarbazones derived from formyl- and acyl- diazines designed as antiviral agents, Pharmazie, 1996, 51, 468-470.
6. Ali M. A., Livingstone S. E., Phillips, D. J., Antiferromagnetic and ferromagnetic interacttions in some copper(II) complexes of salicylaldehyde and acetylacetone Schiff bases derived from S-methyldithiocarbazate, Inorg. Chim. Acta, 1973, 7, 179.
7. Ali M. A., Metal complexes of sulfur-nitrogen chelating agents, Livingstone S. E, Coord. Chem. Rev., 1974, 13, 101.
8. 胡惟孝, 孙楠, 杨忠愚, 缩胺硫脲化合物的合成及其抗癌活性的研究, 高等学校化学学报, 2001, 22(12), 2014-2017.
9. Ali M. A., Tarafdar M. H, Metal complexes of sulfur and nitrogen-containing ligands: complexes of S-benzyldithiocarbazate and a Schiff base formed by its condensation with pyridine- 2-carboxaldehyde, J. Inorg. Nucl. Chem., 1977, 39, 1785.
10. Edwards E. I., Epto R. M., Marr G. J., Ligand substitution reactions of metal and organometalcarb- onyls with group V and VI donor ligands, Organomet .Chem., 1976, 5, 205.
11. P. J. Graham, R. V. Lindsey, G. W. Parshall, M. L. Peterson, and G. M. Whitman, Some acyl ferrocenes and their reactions, J. Am. Chem. Soc., 1957, 79, 3416.
12. Charles R. Hauser and Jacque K. Lindsay, Certain acylations of ferrocene and some condensations involving the α-hydrogen of acetylferrocene, J. Org. Chem., 1957, 22 (13), 482.
13. Roberts R. M., Rodewald L. B., Wingrovw A. S.Comp., Cao X. G., Hu C. Q.Transl., An Introduc -tion to Modern Experimental Organic Chemitry, Shanghai Science and Technology Press., 1981, 245.
14. Uber Lactame, Chem. Ber., Lactams and cyclic peptides, 1968, (101), 1979.
15. Aggarwal R. C., Narrang K. K., Diacetylhydrazine complexes of cobalt(II), nickel(II), and copper (II), Indian J. Chem., 1971, 9, 1413.
16. Datil S. R., Kantak U. N., Sen D. N., Some ferrocenyl aroyl hydrazones and their copper(II) comp- lexes, Inorg. Chim.Acta, 1982, 63, 261.
17. Abu G. M., Taha F. I., Shallaby A. M., Some ferrocenyl aroyl hydrazones and their copper(II) complexes,Synth. React. Inorg. Met. Org. Chem., 1990, 20, 887.
18. Nakamota K, Infrared Spectra of Inorganic and Coordination Compounds, and End, Wiley Inter Science., New York, 1970, 68.
1. 李清寒, 陈淑华, 缩氨基硫脲类化合物的设计合成和生物活性研究, 有机化学, 2006, 26(4), 528-532.
2. Offiong O.E., Martelli S., Antibacterial activity of metal complexes of benzil and benzoin thio- semicarbazones, Farmaco, 1994, 49, 513-518.
3. Bharti N., Maurya mannar R., Palladium(II) complexes of NS donor ligandsderived from S-methyl-dithiocarbazate, S-benzyldithiocarbazateand thiosemicarbazide as antiamoebic agents, Naqvi, Eur. J. Med. Chem., 2000(35), 481.
4. Quiroga A. G., Perez J. M., Lopez-Solcra, Novel Tetranuclear Orthometalated Comp lexes of Pd(II) and Pt(II) Derived from p-Isopropylbenzaldehyde Thiosemicarba- zone with Cytotoxic Activity in cis-DDP Resistant Tumor Cell Lines. Interaction of These Complexes with DNA, J. Med. Chem, 1998, 41, 1399-1408.
5. Hadjipavlou-Litina D., QSAR of thiosemicarbazones derived from formyl- and acyl- diazines designed as antiviral agents, Pharmazie, 1996, 51, 468-470.
6. Das M., Livingstone S. E, Metal chelates of dithiocarbazic acid and its derivatives. IX. Metal chelates of ten new Schiff bases derived from S-methyldithiocarbazate, Inorg. Chim. Acta, 1976, 19, 5.
7. Ali M. A., Livingstone S. E., Phillips, D. J., Antiferromagnetic and ferromagnetic interacttions in some copper(II) complexes of salicylaldehyde and acetylacetone Schiff bases derived from S-methyldithiocarbazate, Inorg. Chim. Acta, 1973, 7, 179.
8. Ali M. A., Metal complexes of sulfur-nitrogen chelating agents, Livingstone S. E, Coord. Chem. Rev., 1974, 13, 101.
9. 胡惟孝, 孙楠, 杨忠愚, 缩胺硫脲化合物的合成及其抗癌活性的研究, 高等学校化学学报, 2001, 22(12), 2014-2017.
10. Ali M. A., Tarafdar M. H, Metal complexes of sulfur and nitrogen-containing ligands: complexes of S-benzyldithiocarbazate and a Schiff base formed by its condensation with pyridine-2-carboxaldehyde, J. Inorg. Nucl. Chem., 1977, 39, 1785.
11. P. J. Graham, R. V. Lindsey, G. W. Parshall, M. L. Peterson, and G. M. Whitman, Some acyl ferrocenes and their reactions, J. Am. Chem. Soc., 1957, 79, 3416.
12. Charles R. Hauser and Jacque K. Lindsay, Certain acylations of ferrocene and some condensations involving the α-hydrogen of acetylferrocene, J. Org. Chem., 1957, 22 (13), 482.
13. Roberts R. M., Rodewald L. B., Wingrovw A. S. Comp., Cao X. G., Hu C. Q. Transl. An Introdu -ction to Modern Experimental Organic Chemitry, Shanghai Science and Technology Press, 1981, 245.
14. Aggarwal R. C., Narrang K. K., Diacetylhydrazine complexes of cobalt(II), nickel(II), and copper (II), Indian J. Chem., 1971, 9, 1413.
15. Datil S. R., Kantak U. N., Sen D. N., Some ferrocenyl aroyl hydrazones and their copper(II) comp- lexes, Inorg. Chim. Acta, 1982, 63, 261.
16. Abu G. M., Taha F. I., Shallaby A. M., Metal complexes of a Schiff base formed by condensation of S-benzyldithiocarbazate with biacetylmonoxime(H2BTC), Synth. Re-act .Inorg. Met. Org. Chem., 1990, 20, 887.
17. Nakamota K, Infrared Spectra of Inorganic and Coordination Compounds, and End, Wiley Inter Science, New York, 1970, 68.
1. Das M., Livingstone S. E, Metal chelates of dithiocarbazic acid and its derivatives. IX. Metal chelates of ten new Schiff bases derived from S-methyldithiocarbazate, Inorg. Chim. Acta, 1976, 19, 5.
2. Ali M. A., Livingstone S. E., Phillips, D. J., Antiferromagnetic and ferromagnetic interacttions in some copper(II) complexes of salicylaldehyde and acetylacetone Schiff bases derived from S-methyldithiocarbazate, Inorg. Chim. Acta, 1973, 7, 179.
3. Ali M. A., Metal complexes of sulfur-nitrogen chelating agents, Livingstone S. E, Coord. Chem. Rev., 1974, 13, 101.
4. 胡惟孝, 孙楠, 杨忠愚, 缩胺硫脲化合物的合成及其抗癌活性的研究, 高等学校化学学报, 2001, 22(12), 2014-2017.
5. Ali M. A., Tarafdar M. H, Metal complexes of sulfur and nitrogen-containing ligands: complexes of S-benzyldithiocarbazate and a Schiff base formed by its condensation with pyridine-2- carboxaldehyde, J. Inorg. Nucl. Chem., 1977, 39, 1785.
6. G. S. Huang, Y. H. Liu, B. H. Chen, and Y. X. Ma, (E)-cinnamoylferrocene S-Benzylcarbodi thio- ylhydrazone and its chelates, Chem. Papers., 1999, 53(1), 65.
7. G.S. Huang, B.H. Chen, C.M. Liu, and Y.X. M, Transition metal(II) complexes of (E)-cinnamoyl ferrocene (S)-methylcarbodithioylhydrazone, Transition Met. Chem., 1998, 23, 589.
8. A.G. Hu, L.Y. Zhang, N.Y. Fu, Y.F. Yuan, T. Z. Ding, Synthesis, characterization and scavenger effect on superoxide of copper(II) and zinc(II) complexes derived from thiosemicarbazide, Synth. React. Inorg. Met.-Org. Chem., 1998, 28, 809.
9. (反)-肉桂酰基二茂铁缩二硫代碳酰腙及其Cu(II)、Zn(II)配合物的合成与表征, 刘永红, 刘晓岚, 杨声, 马永祥, 有机化学, 2001, 21(3), 218-222.
10. 硫、氮双齿配体与Cd(II)和Hg(II)配合物的合成与表征, 刘晓岚, 刘永红, 袁冬梅, 景淆壁, 石尧成, 有机化学, 2005, 25(11), 1427-1430.
11. P. J. Graham, R. V. Lindsey, G. W. Parshall, M. L. Peterson, and G. M. Whitman, Some acyl ferrocenes and their reactions, J. Am. Chem. Soc., 1957, 79, 3416.
12. Charles R. Hauser and Jacque K. Lindsay, Certain acylations of ferrocene and some condensations involving the α-hydrogen of acetylferrocene, J. Org. Chem., 1957, 22 (13), 482.
13. Roberts R. M., Rodewald L. B., Wingrovw A. S. Comp., Cao X. G., Hu C. Q. Transl. An Introduc -tion to Modern Experimental Organic Chemitry, Shanghai Science and Technology Press, 1981, 245.
14. Aggarwal R. C., Narrang, K. K., Diacetylhydrazine complexes of cobalt(II), nickel(II), and copper (II), Indian J. Chem., 1971, 9, 1413.
15. Datil S. R., Kantak U. N., Sen D. N., Some ferrocenyl aroyl hydrazones and their copper(II) comp- lexes, Inorg. Chim. Acta, 1982, 63, 261.
16. Abu G. M., Taha F. I., Shallaby A. M., Metal complexes of a Schiff base formed by condensation of S-benzyldithiocarbazate with biacetylmonoxime(H2BTC), Synth. Re-act. Inorg. Met. Org. Chem., 1990, 20, 887.
17. Nakamota K, Infrared Spectra of Inorganic and Coordination Compounds, and End, Wiley Inter Science, New Yor, 1970, 68.
2. Robert D. Jones, David A. Summerville, and Fred Basolo, Synthetic oxygen carriers related to biological systems, Chem. Rev., 1979, 79, 139.
3. E. G. Samsel, K. Srinivasan, and Jay K. Kochi, Mechanism of the chromium catalyzed epoxidati-文 on of olefins. Role of oxochromium (V) cations, J. Am. Chem. Soc., 1985, 107, 7606.
4. Pascal G. Lacroix and Jean-Claude Daran, Synthesis, crystal structure, conductivity and magnetic properties of trifluoromethylated dinuclear copper(II) complexes with tetracyanoquinodimethane, J. Chem. Soc., Dalton Trans., 1997, 8, 1369.
5. 钟超凡, 邓建成, 桶任, 双安息香缩三乙四胺双核过渡金属配合物的合成、表征与载氧性质, 高等学校学报, 1998, 19(2), 174.
6. 陈新斌, 桂明德, 朱中杰, 双[N, N'-亚乙基-2, 2'-(苯基亚甲基)-(3, 4-二甲基吡咯-5-醛缩亚胺)]合锰(II)的合成、光谱特征及拟酶催化性能研究, 高等学校学报, 1998, 3, 1065.
7. Russel C. Long, David N. Hendrickson, Intra molecular electron transfer in a series of mixed- valence copper(II)-copper(I) complexes, J. Am. Chem. Soc., 1983, 105, 1513.
8. Charles J, O.Connor, Dale Firmin, Binuclear molecules incorporating small molecules as bridg- ing ligands, Inorg. Chem., 1986, 25, 2300.
9. P. Guerriero, S. Tamburini, P. A. Vigato, M?ssbauer and magnetic properties of mononuclear, homo-and hetero-dinuclear complexes, Inorg. Chim. Acta, 1993, 213, 279.
10. Pascal G. Lacroix, Jean Claude Daran, Synthesis, crystal structure, conductivity and magnetic properties of trifluoromethylated dinuclear copper(II) complexes with tetracyanoquinodimethane, J. Chem. Soc., Dalton Trans., 1997, (8), 1369.
11. Rita H. Molina, Alfredo Mederos, Dimer species in dimethyl sulfoxide/water(80:20w/w) solution of N, N'-bis(salicylicdene)-m-phenylenediamine(H2sal-m-phen) and similar Schiff bases with Cu(II), Ni(II), Co(II) and Zn(II), J. Chem. Soc., Dalton Trans., 1997, (22), 4327.
12. Xiaoyan Chen, Shuzhong Zhan, Synthesis, electrochemical and magnetic properties of Cu complexes of a series of new compartmental trinucleating ligands H4L, J. Chem. Soc., Dalton Trans., 1997, (2), 245.
13. Jonathan D. Crane, David E. Feton, Unsymmetric dicopper(II) complexes of dinucleating ligands bearing chemically distinct coordination environments, J. Chem. Soc., Dalton Trans., 1991, (11), 2979.
14. Chikako Higrchi, Hiroshi Sakiyanma, Dinuclear manganese(II) complexes of unsymmetric phenol-based dinucleating ligands with amino and imino chelating arms: synthesis, structure and catalase-like activity, J. Chem. Soc., Dalton Trans., 1994, (7), 1097.
15. M. Marappan, V. Narayan, Synthesis, spectral and electrochemical properties of a new series of unsymmetrical bis(phenoxo) bridged macrocyclic binuclear manganese (III) complexes, J. Chem. Soc., Dalton Trans., 1998, 3405.
16. D. Black, A. J. Blake, Metallosupramolecular silver complexes of bis- and tetra-kis-(2-pyridyl sulfanylmethyl)benzenes, J. Chem. Soc., Dalton Trans., 1998, (23), 3935.
17. N. Brianese, U. Casellato, S. Tamburini, Functionalized acyclic Schiff bases and related compl- exes with d- and f-metalions, Inorg. Chim. Acta, 1998, 272, 235.
18. David E. Feton, Metallobiosites and their synthetic analogs a belief in synergism, Chem. Soc. Rev., 1999, 28(3), 159.
19. K. Dey, J Scient, Schiff bases and their uses, Ind. Res., 1974, 33(2), 76.
20. 明阳福, 黄震年, 许宝安, 双席夫碱-N, N'-二(2-羟基-1-萘甲醛)缩-1, 4-苯二胺的电子光谱和光致变色机理研究, 中国科学, 1997, 27(2), 120.
21. 李清寒, 陈淑华, 缩氨基硫脲类化合物的设计合成和生物活性研究, 有机化学, 2006, 26(4), 528-532.
22. Qinlu, Chengyu Shen, Qinhui Luo, A study on the Schiff base Cu2Zn2SOD model complexes- The relationship between structure and activity, Polyhedron., 1993, 12 (16), 2005.
23. 唐波, 刘阳, 梁芳珍, 陈德展, 孙天麟, β-CD-Shiff 碱铜(II)配合物模拟酶催化光度法的研究, 化学学报, 2000, 58(8), 1031-1036.
24. 唐波, 刘阳, 唐晓玲, SDS-Schif 碱铜(II)配合物模拟酶催化光度法研究, 高等学校化学学报, 2001, 22(6), 919-921.
25. Cai L. S., Mahmound H. Han Y., Binuclear versus mononuclear copper complexes as catalysts for asymmetric cyclopropanation of styrene, Tetrahedron Asymmetry, 1999, 10(3), 411.
26. Evans D. A, Woerpel K. A, Hinman M. M, Bis(oxazolines) as chiral ligands in metal-catalyzed asymmetric reactions, J. Am. Chem. Soc., 1991, 113(2), 726.
27. Doyle M. P, Forbes D. C, Recent Advances in Asymmetric Catalytic Metal Carbene Transformati- ons, Chem. Rev., 1998, 98 (2), 911.
28. Aratani T, Catalytic asymmetric synthesis of cyclopropanecarboxylic acids: an application of chiral copper carbenoid reaction, Pure. Appl. Chem., 1985, 57(12), 1839.
29. Desai S. B., Desai P. B., Desai K. R., Synthesis of some Schiff bases, thiazolidinones and azeti- dinones derived from 2, 6-diaminobenzo[1, 2-d-4, 5-d'] bisthiazole and their anticancer activities, Heterocycl Commun., 2001, 7(1), 83.
30. 张恭孝, 杨荣华席夫碱金属配合物的研究进展, 山东化工, 2004, 33, 14-17.
31. Bastos M. B. R., Moreira J. C., Farias P. A. M., Adsorptive stripping voltammetric behavior of UO2(II) complex with Schiff base N, N'-ethylenebis(salicylidenimine) in aqueous medium containing 4-(2-hydroxyethyl)-1-piperazine ethanesulfonic acid, Analytica Chimica. Acta, 2000, 408(1-2), 83.
32. Ma H., Chen S. H., Niu L, Studies on electrochemical behavior of copper in aerated NaBr solutions with Schiff base, N, N'-o-phenylenebis(3-methoxysalicylidenimine), J. Electrochemical文 Society, 2001, 148(5), 208.
33. 赵建章, 赵冰, 徐蔚青, Schiff 碱 N, N'-双水杨醛缩-1, 6-己二胺的光致变色光谱研究, 高等学校化学学报, 2001, 22(6), 971.
34. 陈德余, 封子先, 胡小莉, 冯亚非, 某些过渡金属氨基酸席夫碱配合物的合成、表征及其对O2-的清除作用, 浙江大学学报, 1996, 30(5), 498-502.
35. 叶勇, 2-氯代苯甲醛丙氨酸席夫碱及其 3d-过渡金属配合物的合成与表征, 湖北大学学报, 2001, 23(1), 57.
36. 陈德余, 张义建, 张平, 甲硫氨酸席夫碱铜、锌、钴配合物合成及抗 O2-性能, 应用化学, 2000, 17(6), 607-610.
37. 叶勇, 胡继明, 曾云鹗, N-β-萘酚醛-D-氨基葡萄糖席夫碱甘氨酸金属络合物与 DNA 作用的谱学研究, 分析化学, 2001, 7.
38. 叶勇, 胡继明, 曾云鹗, N-β-萘酚醛-D-氨基葡萄糖席夫碱金属配合物与 DNA 作用的谱学研究, 无机化学学报, 2000, 16(6), 951-958.
39. 鲁桂, 姚克敏, 张肇英, 镧系与直链系-组氨酸Schiff碱配合物合成、波谱与生物活性, 应用化学, 2001, 18(1), 1-4.
40. Hodnett E. M, Dunn W, Structure-antitumor activity correlation of some Schiff bases, J. Med. Chem., 1970, 13, 768.
41. 张建民, 李瑞芳, 刘树祥, 过渡金属配合物的稳定性及其杀菌活性, 无机化学学报, 1999, 15(4), 493-496.
42. Nyarkusk, Mavusoe, Preparation, characterisation and biological evaluation of a chromium(Ⅲ) Schiff bases complex derived from o-nitrobenzaldehyde and p-amino phenol, South African J. Chem., 1998, 51(4), 168-172.
43. 柳翠英, 李忠, 刘培漫, 5-硝基水杨醛亚胺合铜(II)类鳌合物的合成与抑菌活性, 华西药学杂志, 1996, 11(2), 69-71.
44. 柳翠英,赵全芹, 郭秀英, 5-N-(2-2羟基乙基)水杨醛亚胺Shiff碱的合成与表征, 化学试剂, 1998, 20(1), 42-43.
45. 卢冰熙, 李淑贤, 叶文法, 含四唑环Schiff碱的合成及植物激素活性, 湖南化学, 2000, 30(5), 42-43.
46. 唐婷, 席夫碱的研究新进展, 杭州医学高等专科学校学报, 2000, 21(4), 204-210.
47. 魏丹毅, 李冬成, 姚克敏, 稀土元素与α-丙氨酸席夫碱双核配合物的合成与表征及催化活性, 无机化学学报, 1998, 14(2), 209-213.
48. 鲁桂, 姚克敏, 张肇英, 镧系与直链系-组氨酸Schiff碱配合物合成、波谱与生物活性, 应用化学, 2001, 18(1), 1-4.
49. Yong L, Huang J. L, Lian B, Synthesis of titanium(Ⅳ) complexes with Schiff bases ligand and their catalytic activities for polymerisation of ethylene and etyrene, Chinese Journal of Chemistry., 2001, 19(4), 429-432.
50. Cai L. S., Mahmound H., Han Y., Binuclear versus mononuclear copper complexes as catalysts for asymmetric cyclopropanation of styrene, Tetrahedron Asymmetry, 1999, 10(3), 411.
51. 仇敏, 刘国生, 姚小泉, 催化学报, 2001, 22(1), 77.
52. 杜向东, 俞贤达, 非对称Schiff碱过渡金属配合物模拟酶催化烯烃环氧化, 高等学校化学学报, 1997, 18(4), 67.
53. 杜向东, 俞贤达, 非对称希夫碱过渡金属配合物模拟催化烯烃环氧化, 分子催化, 1997, 12(1), 26-30.
54. 王积涛, 陈蓉, 冯霄, 手性过渡金属(Mn, Co, Ni)Salen配合物催化NaOCl不对称氧化苯乙烯的反应研究, 有机化学, 1998, 18, 228-234.
55. 何星存, 蔡沛祥, 莫金垣, 一氧化氮在聚钴-席夫碱修饰电极上的电催化氧化, 分析实验室, 2000, 19(1), 9.
56. 何星存, 邓锐, 李平, 用修饰电极导数伏安法同时测定多巴胺和肾上腺素, 分析测试学报, 2000, 19(1), 35.
57. Khuhawar. M Y, Lanjwani S. N, High-performance liquid Chromatographic determination of uranium using solvent extraction and bis(alicyladehyde)tetramethylene diimine as complexing reagent , Talanta., 1995, 42, 1925-1929.
58. 李锦州, 安郁美, 于文锦, 新席夫碱萃取剂(HPMaFP )TEN的合成及其在反相纸色谱中的研究, 化学试剂, 1996, 18 (6), 327-329.
59. 孔淑青, 徐曲, 赫莱安, 用桑色素甲硫氨酸席夫碱荧光法测定锡青铜中痕量铝的研究, 江西冶金, 1999, 19(6), 48
60. Li S. L., Chen S. H., Lei S. B., Investigation on some Schiff bases as HCl corrosion inhibitors for copper, Corrosion Science, 1999, 41(7), 1273.
61. Quan Z., Wu X., Chen S., Self-assembled monolayers of Schiff bases on copper surfaces, Corrosion, 2001, 57(3), 195.
62. Kuzentsov Y. I., Vagapov R. K., On the inhibition of hydrogen sulfide corrosion of steel with Schiff bases, Rrot Met., 2001, 37(3), 210.
63. Desai M.N, Chauhan P.O, Shah N, Schiff bases derived form chloroanilines as corrosion inhibitors of zinc in sulfuric acid solutions, European Symposium on Corrision Inhibitors., 1995, 27, 891-902.文
64. Bansiwal A. Anthonyp, Mathurs Y, Inhabitive effect of some Schiff bases on corrosion of aluminum in hydrochloric acidsolution, Corros, 2000, 35(4), 301-303.
65. Ma H, Chen S. H., Niu L, Studies on electrochemical behavior of copper in aerated NaBr solutions with Schiff base, N,N'-o-phenylenebis(3-methoxysalicylidenimine), J. Electrochemical. Society, 2001, 148(5), 208.
66. Grabowaka A, Kownacki K, Karpiuk J, Photcxhromism and proton transfer reaction cycle of new internalty H-bonded Schiff bases, Chemical Physics Letters, 1997, 267, 132-140.
67. 朱传方, 席夫碱及其络合物的可逆热致变色材料, 化学通报, 2000, 8, 15-20.
68. 吴爱斌, 朱传方, 5-(4'-磺胺苯基偶氮)水杨醛席夫碱的合成及其热色性研究, 华中师范大学学报, 2002, 36(2).
69. 陈玉红, 丁克强, 王庆飞, 席夫碱应用研究新进展, 河北师范大学学报, 2003, 27 (1), 71-73.
70. Ahmed M Donia, EI-Zxiny M Ebid, Thermochromism in nickel(II) complexes with Schiff base derivatives of 4-aminoantipyrine, Thermochimica Acta, 1988, 131, 1-6.
71. Naohide Matsumoto, Synthesis and characterization of iron(III) complexes with unsymmetrical quadridentate Schiff bases, and spin equilibrium behavior in solution, Kazuhiro Kimoto, Bull Chem. Soc., Jpn, 1984, 57(11), 3307-3311.
72. 黄发宏, 王彬, 液晶热变色印刷油墨, CN 1062744A., 1992.
73. Masaru H, Junko T, Koichi N, Laminated fabrics having temperature controlling function, JP0 2234980, 1990.
74. 任红霞, 雷自强, 张海涛, π共轭席夫碱聚合物的合成及其荧光性能, 西北师范大学学报, 2000, 36(3), 36-38.
75. 吕绪良, 许卫东, 崔传安, 席夫碱的合成及其在热红外伪装涂料中的应用, 解放军理工大学学报, 2000, 1(6), 54-57.
76. 毕思玮, 余海滨, 一个含有端基双键的席夫碱型液晶化合物的合成与表征, 曲阜师范大学学报, 1999, 25(6), 93-95.
77. Zhu Xinde, Wang Chenggang, Le Zhifeng, Mei Shangyun, Yen Zhenhuan, WuZishen, Synthesis, characterization and scavenger effect on superoxide of copper(II)and zinc(II) complexes derived from thiosemicarbazide, Synth. React. Inorg. Met.-0rg. Chem., 1991, 21(9), 1365.
78. M. AkbarAli, A. H. Mirza, M. HanitiS. A. Hamid, P. V. Bernhardt, Diphenyltin(IV) complexes of the 2-quinolinecarboxaldehyde Schiff bases of S-methyl- and S-benzyl- dithiocarbazate (Hqaldsme and Hqaldsbz): X-ray crystal structures of Hqaldsme and two conformers of its diphenyltin(IV) complex, Polyhedron, 2005, 24(3), 383–390.
79. 杨锦明, 张猛, 曹建国, 含硫双Schiff碱型配体的合成与表征, 光谱实验室, 2003, 20(4).
80. 陈良壁, 郑细鸣, 李碧婵, 肼基双硫代甲酸苄酯类席夫碱的合成, 南平师专学报, 2003, 22(4).
81. 张霞, 刘万毅, 田大年, 新试剂4-氯查尔酮缩氨基硫脲与铜(II)的显色反应研究, 分析试验室, 2006, 25(6).
82. 孙楠, 杨忠愚, 胡惟孝, 杂环基缩胺硫脲的合成及其抗癌活性的研究(含氟哌酸基的缩胺硫脲), 合成化学, 2001, 9(2).
83. T. J. Kealy, P. L. Paulson, A new type of organo-iron compound, Nature, 1951, 168, 1039.
84. 孙红随, 马永祥, 殷元骐, 含二茂铁基席夫碱及其配合物的研究, 无机化学学报, 1992, 8(2), 203.
85. Yao-Cheng Shi, Synthesis and crystal structure of a nickel complex with the bidentate ligand derived from condensation of acetylferrocene and S-benzyldithiocarbazate, Journal of Coordination Chemistry., 2004, 57(11), 961-966.
86. 胡培植, 季立才, 王亚夫, 张伦, 二茂铁甲酰丙酮缩氨基硫脲金属配合物研究, 无机化学学报, 1996, 12(1), 11-17.
87. 孟祥茹, 李爱梅, 阴春枝, 田孟超, 双乙酰基二茂铁缩氨基硫脲与Cu(Ⅱ )、Zn(Ⅱ )烯夫碱配合物的合成与表征, 河南科学, 1998, 16(3), 287-290.
88. G. S. Huang, Y. H. Liu, B. H. Chen, and Y. X. Ma, (E)-cinnamoylferrocene S-Benzylcarbodithioyl hydrazone and its chelates, Chem. Papers., 1999, 53(1), 65.
89. G.S. Huang, B.H. Chen, C.M. Liu, and Y.X. M, Transition metal(II) complexes of (E)- cinnamoyl ferrocene (S)-methylcarbodithioylhydrazone, Transition Met. Chem., 1998, 23, 589.
90. A.G. Hu, L.Y. Zhang, N.Y. Fu, Y.F. Yuan, T. Z. Ding, Synthesis, characterization and scavenger effect on superoxide of copper(II) and zinc(II) complexes derived from thiosemicarbazide, Synth. React. Inorg. Met.-Org. Chem., 1998, 28, 809.
91. (反)-肉桂酰基二茂铁缩二硫代碳酰腙及其Cu(II)、Zn(II)配合物的合成与表征, 刘永红, 刘晓岚, 杨声, 马永祥, 有机化学, 2001, 21(3), 218-222.
92. 硫、氮双齿配体与Cd(II)和Hg(II)配合物的合成与表征, 刘晓岚, 刘永红, 袁冬梅,景淆壁, 石尧成, 有机化学, 2005, 25(11), 1427-1430.
1. 李清寒, 陈淑华, 缩氨基硫脲类化合物的设计合成和生物活性研究, 有机化学, 2006, 26(4), 528-532.
2. Offiong O.E., Martelli S., Antibacterial activity of metal complexes of benzil and benzoin thiosemicarbazones, Farmaco, 1994, 49, 513-518.
3. Bharti N., Maurya mannar R., Palladium(II) complexes of NS donor ligandsderived from S-methyl-dithiocarbazate, S-benzyldithiocarbazateand thiosemicarbazide as antiamoebic agents, Naqvi, Eur. J. Med. Chem., 2000(35), 481.
4. Quiroga A. G., Perez J. M., Lopez-Solcra, Novel Tetranuclear Orthometalated Comp lexes of Pd(II) and Pt(II) Derived from p-Isopropylbenzaldehyde Thiosemicarba- zone with Cytotoxic Activity in cis-DDP Resistant Tumor Cell Lines. Interaction of These Complexes with DNA, J. Med. Chem, 1998, 41, 1399-1408.
5. Hadjipavlou-Litina D., QSAR of thiosemicarbazones derived from formyl- and acyl- diazines designed as antiviral agents, Pharmazie, 1996, 51, 468-470.
6. Ali M. A., Livingstone S. E., Phillips, D. J., Antiferromagnetic and ferromagnetic interacttions in some copper(II) complexes of salicylaldehyde and acetylacetone Schiff bases derived from S-methyldithiocarbazate, Inorg. Chim. Acta, 1973, 7, 179.
7. Ali M. A., Metal complexes of sulfur-nitrogen chelating agents, Livingstone S. E, Coord. Chem. Rev., 1974, 13, 101.
8. 胡惟孝, 孙楠, 杨忠愚, 缩胺硫脲化合物的合成及其抗癌活性的研究, 高等学校化学学报, 2001, 22(12), 2014-2017.
9. Ali M. A., Tarafdar M. H, Metal complexes of sulfur and nitrogen-containing ligands: complexes of S-benzyldithiocarbazate and a Schiff base formed by its condensation with pyridine- 2-carboxaldehyde, J. Inorg. Nucl. Chem., 1977, 39, 1785.
10. Edwards E. I., Epto R. M., Marr G. J., Ligand substitution reactions of metal and organometalcarb- onyls with group V and VI donor ligands, Organomet .Chem., 1976, 5, 205.
11. P. J. Graham, R. V. Lindsey, G. W. Parshall, M. L. Peterson, and G. M. Whitman, Some acyl ferrocenes and their reactions, J. Am. Chem. Soc., 1957, 79, 3416.
12. Charles R. Hauser and Jacque K. Lindsay, Certain acylations of ferrocene and some condensations involving the α-hydrogen of acetylferrocene, J. Org. Chem., 1957, 22 (13), 482.
13. Roberts R. M., Rodewald L. B., Wingrovw A. S.Comp., Cao X. G., Hu C. Q.Transl., An Introduc -tion to Modern Experimental Organic Chemitry, Shanghai Science and Technology Press., 1981, 245.
14. Uber Lactame, Chem. Ber., Lactams and cyclic peptides, 1968, (101), 1979.
15. Aggarwal R. C., Narrang K. K., Diacetylhydrazine complexes of cobalt(II), nickel(II), and copper (II), Indian J. Chem., 1971, 9, 1413.
16. Datil S. R., Kantak U. N., Sen D. N., Some ferrocenyl aroyl hydrazones and their copper(II) comp- lexes, Inorg. Chim.Acta, 1982, 63, 261.
17. Abu G. M., Taha F. I., Shallaby A. M., Some ferrocenyl aroyl hydrazones and their copper(II) complexes,Synth. React. Inorg. Met. Org. Chem., 1990, 20, 887.
18. Nakamota K, Infrared Spectra of Inorganic and Coordination Compounds, and End, Wiley Inter Science., New York, 1970, 68.
1. 李清寒, 陈淑华, 缩氨基硫脲类化合物的设计合成和生物活性研究, 有机化学, 2006, 26(4), 528-532.
2. Offiong O.E., Martelli S., Antibacterial activity of metal complexes of benzil and benzoin thio- semicarbazones, Farmaco, 1994, 49, 513-518.
3. Bharti N., Maurya mannar R., Palladium(II) complexes of NS donor ligandsderived from S-methyl-dithiocarbazate, S-benzyldithiocarbazateand thiosemicarbazide as antiamoebic agents, Naqvi, Eur. J. Med. Chem., 2000(35), 481.
4. Quiroga A. G., Perez J. M., Lopez-Solcra, Novel Tetranuclear Orthometalated Comp lexes of Pd(II) and Pt(II) Derived from p-Isopropylbenzaldehyde Thiosemicarba- zone with Cytotoxic Activity in cis-DDP Resistant Tumor Cell Lines. Interaction of These Complexes with DNA, J. Med. Chem, 1998, 41, 1399-1408.
5. Hadjipavlou-Litina D., QSAR of thiosemicarbazones derived from formyl- and acyl- diazines designed as antiviral agents, Pharmazie, 1996, 51, 468-470.
6. Das M., Livingstone S. E, Metal chelates of dithiocarbazic acid and its derivatives. IX. Metal chelates of ten new Schiff bases derived from S-methyldithiocarbazate, Inorg. Chim. Acta, 1976, 19, 5.
7. Ali M. A., Livingstone S. E., Phillips, D. J., Antiferromagnetic and ferromagnetic interacttions in some copper(II) complexes of salicylaldehyde and acetylacetone Schiff bases derived from S-methyldithiocarbazate, Inorg. Chim. Acta, 1973, 7, 179.
8. Ali M. A., Metal complexes of sulfur-nitrogen chelating agents, Livingstone S. E, Coord. Chem. Rev., 1974, 13, 101.
9. 胡惟孝, 孙楠, 杨忠愚, 缩胺硫脲化合物的合成及其抗癌活性的研究, 高等学校化学学报, 2001, 22(12), 2014-2017.
10. Ali M. A., Tarafdar M. H, Metal complexes of sulfur and nitrogen-containing ligands: complexes of S-benzyldithiocarbazate and a Schiff base formed by its condensation with pyridine-2-carboxaldehyde, J. Inorg. Nucl. Chem., 1977, 39, 1785.
11. P. J. Graham, R. V. Lindsey, G. W. Parshall, M. L. Peterson, and G. M. Whitman, Some acyl ferrocenes and their reactions, J. Am. Chem. Soc., 1957, 79, 3416.
12. Charles R. Hauser and Jacque K. Lindsay, Certain acylations of ferrocene and some condensations involving the α-hydrogen of acetylferrocene, J. Org. Chem., 1957, 22 (13), 482.
13. Roberts R. M., Rodewald L. B., Wingrovw A. S. Comp., Cao X. G., Hu C. Q. Transl. An Introdu -ction to Modern Experimental Organic Chemitry, Shanghai Science and Technology Press, 1981, 245.
14. Aggarwal R. C., Narrang K. K., Diacetylhydrazine complexes of cobalt(II), nickel(II), and copper (II), Indian J. Chem., 1971, 9, 1413.
15. Datil S. R., Kantak U. N., Sen D. N., Some ferrocenyl aroyl hydrazones and their copper(II) comp- lexes, Inorg. Chim. Acta, 1982, 63, 261.
16. Abu G. M., Taha F. I., Shallaby A. M., Metal complexes of a Schiff base formed by condensation of S-benzyldithiocarbazate with biacetylmonoxime(H2BTC), Synth. Re-act .Inorg. Met. Org. Chem., 1990, 20, 887.
17. Nakamota K, Infrared Spectra of Inorganic and Coordination Compounds, and End, Wiley Inter Science, New York, 1970, 68.
1. Das M., Livingstone S. E, Metal chelates of dithiocarbazic acid and its derivatives. IX. Metal chelates of ten new Schiff bases derived from S-methyldithiocarbazate, Inorg. Chim. Acta, 1976, 19, 5.
2. Ali M. A., Livingstone S. E., Phillips, D. J., Antiferromagnetic and ferromagnetic interacttions in some copper(II) complexes of salicylaldehyde and acetylacetone Schiff bases derived from S-methyldithiocarbazate, Inorg. Chim. Acta, 1973, 7, 179.
3. Ali M. A., Metal complexes of sulfur-nitrogen chelating agents, Livingstone S. E, Coord. Chem. Rev., 1974, 13, 101.
4. 胡惟孝, 孙楠, 杨忠愚, 缩胺硫脲化合物的合成及其抗癌活性的研究, 高等学校化学学报, 2001, 22(12), 2014-2017.
5. Ali M. A., Tarafdar M. H, Metal complexes of sulfur and nitrogen-containing ligands: complexes of S-benzyldithiocarbazate and a Schiff base formed by its condensation with pyridine-2- carboxaldehyde, J. Inorg. Nucl. Chem., 1977, 39, 1785.
6. G. S. Huang, Y. H. Liu, B. H. Chen, and Y. X. Ma, (E)-cinnamoylferrocene S-Benzylcarbodi thio- ylhydrazone and its chelates, Chem. Papers., 1999, 53(1), 65.
7. G.S. Huang, B.H. Chen, C.M. Liu, and Y.X. M, Transition metal(II) complexes of (E)-cinnamoyl ferrocene (S)-methylcarbodithioylhydrazone, Transition Met. Chem., 1998, 23, 589.
8. A.G. Hu, L.Y. Zhang, N.Y. Fu, Y.F. Yuan, T. Z. Ding, Synthesis, characterization and scavenger effect on superoxide of copper(II) and zinc(II) complexes derived from thiosemicarbazide, Synth. React. Inorg. Met.-Org. Chem., 1998, 28, 809.
9. (反)-肉桂酰基二茂铁缩二硫代碳酰腙及其Cu(II)、Zn(II)配合物的合成与表征, 刘永红, 刘晓岚, 杨声, 马永祥, 有机化学, 2001, 21(3), 218-222.
10. 硫、氮双齿配体与Cd(II)和Hg(II)配合物的合成与表征, 刘晓岚, 刘永红, 袁冬梅, 景淆壁, 石尧成, 有机化学, 2005, 25(11), 1427-1430.
11. P. J. Graham, R. V. Lindsey, G. W. Parshall, M. L. Peterson, and G. M. Whitman, Some acyl ferrocenes and their reactions, J. Am. Chem. Soc., 1957, 79, 3416.
12. Charles R. Hauser and Jacque K. Lindsay, Certain acylations of ferrocene and some condensations involving the α-hydrogen of acetylferrocene, J. Org. Chem., 1957, 22 (13), 482.
13. Roberts R. M., Rodewald L. B., Wingrovw A. S. Comp., Cao X. G., Hu C. Q. Transl. An Introduc -tion to Modern Experimental Organic Chemitry, Shanghai Science and Technology Press, 1981, 245.
14. Aggarwal R. C., Narrang, K. K., Diacetylhydrazine complexes of cobalt(II), nickel(II), and copper (II), Indian J. Chem., 1971, 9, 1413.
15. Datil S. R., Kantak U. N., Sen D. N., Some ferrocenyl aroyl hydrazones and their copper(II) comp- lexes, Inorg. Chim. Acta, 1982, 63, 261.
16. Abu G. M., Taha F. I., Shallaby A. M., Metal complexes of a Schiff base formed by condensation of S-benzyldithiocarbazate with biacetylmonoxime(H2BTC), Synth. Re-act. Inorg. Met. Org. Chem., 1990, 20, 887.
17. Nakamota K, Infrared Spectra of Inorganic and Coordination Compounds, and End, Wiley Inter Science, New Yor, 1970, 68.