片状无机富锌涂料的制备和性能研究
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摘要
本文通过对硅酸钾、硅溶胶、烷氧基硅烷性能的研究，反应温度的影响，确定了以硅酸钾、硅溶胶、烷氧基硅烷及水为原料，在一定温度范围内通过正交实验合成了高模数硅酸钾溶液作为片状无机富锌涂料用基料，与适量锌粉混合后配制成片状无机富锌涂料。通过机械性能检测、浸泡试验及盐雾实验表明片状无机富锌涂料性能优良。
经过对市售球状无机富锌涂料进行同样的性能测试，与片状无机富锌涂料进行对比，表明片状无机富锌涂料性能比市售球状无机富锌涂料有所提高。
无机富锌涂料通常作为底漆使用，上面需涂中间漆及面漆，以提高耐蚀性。实验选用环氧云铁作为中间漆，氯化橡胶作为面漆与片状无机富锌涂料复合，配制成底／中／面三涂层体系及底／面两涂层体系进行性能测试，同时将市售球状无机富锌涂料与中间漆及面漆配成三涂层体系及两涂层体系浸泡在3.5％NaCl溶液中进行交流阻抗测试，结果表明片状无机富锌涂料与中间漆及面漆的配套性良好。
Based on the study of potassium silicate, silica sol, Trialkoxysilane performance, the reaction temperature, determined potassium silicate. sol, alkoxy silane and water as raw material, in a certain temperature range through orthogonal experimental, synthesis of a high modulus potassium silicate solutions as inorganic flake zinc-rich coating with the base material. With the proper preparation flake zinc mixed into inorganic flake zinc-rich coating. Through mechanical properties testing, salt spray and immersion test results show inorganic flake zinc-rich coating has good performance.
Through the commercial inorganic spherical zinc-rich coating for the same performance test, comparison with inorganic flake zinc-rich coating, showed inorganic flake zinc-rich coating has better properties than commercial inorganic spherical zinc-rich coating.
Inorganic zinc-rich coating is usually used as primer, above it needs to cover middle section and top section, to improve corrosion resistance. Experimental use MIO epoxy primer as an intermediary coating, chlorinated rubber as top section as composite coating of inorganic flake zinc-rich coating. And prepared the primer /intermediary /top tir-layer system and primer /top double layer system performance testing, while use commercial inorganic spherical zinc-rich coating, middle section and top section prepared double layer system and tir-layer system and immersion into 3.5% NaCl solution for electrochemical impedance spectroscopy test (EIS). The results showed inorganic flake zinc-rich coating matched with the middle section and the top section well.
经过对市售球状无机富锌涂料进行同样的性能测试，与片状无机富锌涂料进行对比，表明片状无机富锌涂料性能比市售球状无机富锌涂料有所提高。
无机富锌涂料通常作为底漆使用，上面需涂中间漆及面漆，以提高耐蚀性。实验选用环氧云铁作为中间漆，氯化橡胶作为面漆与片状无机富锌涂料复合，配制成底／中／面三涂层体系及底／面两涂层体系进行性能测试，同时将市售球状无机富锌涂料与中间漆及面漆配成三涂层体系及两涂层体系浸泡在3.5％NaCl溶液中进行交流阻抗测试，结果表明片状无机富锌涂料与中间漆及面漆的配套性良好。
Based on the study of potassium silicate, silica sol, Trialkoxysilane performance, the reaction temperature, determined potassium silicate. sol, alkoxy silane and water as raw material, in a certain temperature range through orthogonal experimental, synthesis of a high modulus potassium silicate solutions as inorganic flake zinc-rich coating with the base material. With the proper preparation flake zinc mixed into inorganic flake zinc-rich coating. Through mechanical properties testing, salt spray and immersion test results show inorganic flake zinc-rich coating has good performance.
Through the commercial inorganic spherical zinc-rich coating for the same performance test, comparison with inorganic flake zinc-rich coating, showed inorganic flake zinc-rich coating has better properties than commercial inorganic spherical zinc-rich coating.
Inorganic zinc-rich coating is usually used as primer, above it needs to cover middle section and top section, to improve corrosion resistance. Experimental use MIO epoxy primer as an intermediary coating, chlorinated rubber as top section as composite coating of inorganic flake zinc-rich coating. And prepared the primer /intermediary /top tir-layer system and primer /top double layer system performance testing, while use commercial inorganic spherical zinc-rich coating, middle section and top section prepared double layer system and tir-layer system and immersion into 3.5% NaCl solution for electrochemical impedance spectroscopy test (EIS). The results showed inorganic flake zinc-rich coating matched with the middle section and the top section well.
引文
[1] 宣兆龙，易建政，杜仕国．金属防腐涂料的研究进展[J]．现代化工，1999，19(4)：21-24
[2] 于晓辉，朱晓云，郭忠诚，龙晋明．鳞片状锌基环氧富锌重防腐涂料的研制[J]．表面技术，2005，34(1)：53～55
[3] 李金桂．钢铁构件表面上的无机富锌涂层[J]．中国表面工程，2003，(5)：1～4
[4] 张祖文，王军．提高环氧富锌涂料耐盐雾性和稳定性[J]．中国涂料，2003增刊：29～32
[5] 周文涛，李晓勤．无机富锌涂料性能及其应用[J]．湖北化工，2002(5)；26～27
[6] Feliu S, Barajas R, Bastidas J M, et al. Mechanism of cathodic protection of zinc-rich paints by electrochemical impedance spectroscopy: Ⅱ. barrier stage[J]. J. Coatings Technology, 1989, 61 (775): 71-76
[7] Feliu S, Barajas R, Bastidas J M, et al. Mechanism of cathodic protection of zinc-rich paints by electrochemica limpedance spectroscopy. Ⅰ. galvanicstage[J]. J. Coatings Technology, 1989,61 (775): 63-69
[8] Lindquist S A, Meszaros L, Svenson L. Aspects of galvanic action of zinc rich paints [J]. J. Oil Color Chem. Association, 1985, 1: 10
[9] Vomagnolt R, Vetere V F. The mechanism of anticorrosive action of zinc ethyl silicate paints [J]. J. Oil Color Chem. Association, 1993, 5: 208
[10] Morcillo M, Barajas R, Feliu S, et al. SEM study on the galvanic protection of zinc-rich paints [J]. J. MaterialsScience, 1990, 25(5): 2441-2446
[11] 张曙贤，海峰．水性无机富锌涂料[J]．上海建材，2001，(4)；32～33
[12] Malgorzata Zubielewicz a, Witold Gnot. Mechanisms of non-toxic anticorrosive pigments in organic waterborne coatings[J]. Progress in Organic Coatings, 2004, (49): 358-371
[13] Veleva L, Chin J, Del Amo B. corrosion electrochemical behavior of epoxy anticorrosive paints based on zinc molybdenum phosphate and zinc oxide[J]. Progress in Organic Coatings, 1999, 36; 211～216.
[14] 季瑞峰，钱叶苗，刘登良．水性无机富锌涂料．涂料工业，1999，(9)；7～10
[15] 翁永基．锌基防护涂层的保护机理及其使用特性．腐蚀科学与技术．1993，5(1)；70～73，78
[16] H. Marchebois, S. Joiret, C. Savall, J. Bemard, S. Touzain. Characterization of zinc-rich powder coatings by EIS and Raman spectroscopy. Surface and Coatings Technology, 2002, (157): 151～161
[17] 秦国治，王顺．富锌涂料综述．化工设备与防腐蚀，2001，(5)；55～58
[18] 徐峰，邹侯招，储健．环保型无机涂料．北京：化学工业出版社，2004：291～292
[19] 何丽芳，郭忠诚．水性无机富锌涂料的应用研究．表面技术，2006，35(1)：55～59
[20] 张利，吴庆余，魏铭，何松林，李淑柱．醇溶性无机富锌涂料及其电化学行为的研究．涂料：工业，2002，(8)：6～9
[21] 谢德明，胡吉明，童少平，王建明，张鉴清．富锌漆研究进展．中国腐蚀与防护学报．2004，24(5)；314～320
[22] Hare, Clive H. Zinc-rich primers I: design principles[J].J.Protective Coatings & Linings, 1998, 15(7): 17-38
[23] Brevoort, Gordon H. Inorganic zinc-rich coatings and galvanizing: a comparison. J. Protective Coatings & Linings, 1996, 13(9): 66-74
[24] 屠德容，李健，刘红伟，邵国环．关于水性无机富锌涂料的若干问题[J]．涂料技术与文摘，2003，(1)；13～16
[25] C G Munger. The chemistry of zinc silicate coatings [J]. Corrosion Prevention & Control, 1994, 12: 140.
[26] G Parashar, D Srivastava, P Kumar. Ethyl silicate binders for high performance coatings[J]. Progress in Organic Coatings, 2001, 42: 1.
[27] 王亦工，陈华辉，裴嵩峰，张婷．水性无机硅酸锌防腐涂料的研究进展[J]．腐蚀科学与防护技术，2006，18(1)；41～45
[28] 杨振波，杨忠林，郭万生，宋广成．鳞片状富锌涂层耐蚀机理的研究．中国涂料，2006，21(1)：19～22
[29] 江国庆，汪庆锋，胡晶．一种水性双组分无机锌涂料及其制造方法．CN1526780．2004-09．
[30] 林左峰．混合型砗溶胶水性无机富锌涂料CN1552771．2004-12
[31] 屠德容，刘红伟，邵国环．性价比卓越的无机水性涂料．涂料工业，2001，(5)：32～34
[32] 李金桂．无机富锌涂层的诞生和应用．防腐保温技术，2005，14(1)：22～26
[33] 赵力，曾燕．涂料用高模数砖酸钾溶液的制备方法．CN1676551，2005-10
[34] 于良民，董磊，姜晓辉，徐焕志．高模数硅酸钾及其富锌涂料的制备．涂料工业，2004，34(3)：9～13
[35] 黄鑫泉，陈东光．水溶性富锌防腐涂料CN1676550，2005-10
[36] Abreu C M, Izquierdo M, Merino P, et al. A new approach to the determination of the cathodic protection period in zinc-rich paints[J]. Corrosion, 1999, 55(12): 1173-1181
[37] Gervasi C A, Sarli A R Di, Cavalcanti E, et al. The corrosion protection of steel in sea-water using zinc-rich alkyd paints-an assessment of the pigment-content effect by EIS [J]. Corros. Sci., 1994,36(12): 1963-1972
[38] Abreu C M, Izquierdo M, Keddam M, et al. Electrochemical behaviour of zinc-rich epoxy paints in 3% NaCl solution[J]. Electrochim. Acta, 1996,41(15):2405-2415
[39] Real S G, Elias A C, Vilche J R, et al. electrochemical impedance spectroscopy study of zinc rich paints on steels in artificial sea-water by a transmission-line model[J]. Electrochim. Acta, 1993,38( 14):2029-2035
[40] Armas R A, Gervasi C A, Sarli A Di, et al.Zinc-rich paints on steels in artificial sea water by EIS [J]. Corrosion, 1992,48(5):379-383
[41] Vilche J R, Bucharsky E C, Giudice C A. Application of EIS and SEM to evaluate the influence of pigment shape and content in ZRP formulations on the corrosion prevention of naval steel[J].Corros. Sci.,2002,44(6): 1287-1309
[42] Feliu S, Barajas R, Bastidas J M, Morcillo M. Mechanism of cathodic protection of zinc-rich paints by electrochemical impedance spectroscopy. I . Galvanic stage[J].J.Coat.Technol., 1989,61(775):63-69
[43] Feliu S, Barajas R, Bastidas J M, Morcillo M. Mechanism of cathodic protection of zinc-rich paints by electrochemical impedance spectroscopy. I I . Galvanic stage[J].J.Coat.Technol., 1989,61(775):71-76
[44] Faidi S E, Scantlebury J D, Bullivant P, Whittle N T, Savin R. An electrochemical study of zinc-containing epoxy coatings on mild-steel[J].Corros.Sci.,1993,35(5-8):1319-1328
[45] Pereira D, Scantlebury J D, Ferreira M G S, Almeida E. The pplication of electrochemical measurements to the study and behavior of zinc-rich coatings[J]. Corros.Sci., 1990,30(11): 1135-1147
[46] Novoa X R, Izquierdo M, Merino P, Espada L. Electrochemical impedance spectroscopy and zero resistance ammeters (ZRA) as tools for studying the behavior of zinc-rich inorganic coatings [J].Mater.Sci.Forum,1989,44-45:223
[47] Izquierdo M, Novoa X R, Pena G, Espada L. The mechanism of protection of zinc-rich inorganic coatings, a study based on electrochemical impedance spectroscopy (EIS) [J].Mater.Sci.Forum, 1992,111-112:257
[48] J. D. Scantlebury and K. Gali.The application of AC impedance to study the performance of lacquered aluminium specimens in acetic acid solution[J]. Progress in Organic Coatings, 1997,31 (3):201-207
[49] C. G Oliveira and M. G. S. Ferreira.Ranking high-quality paint systems using EIS. Part I: intact coatings[J]. Corrosion Science, 2003,45(1): 123-138
[50] C. G Oliveira and M. G. S. Ferreira.Ranking high-quality paint systems using EIS. Part II: defective coatings[J]．Corrosion Science，2003，45(1)：139-147
[51] 杨建桥，杨军，刘艳．牺牲阳极涂料新进展．陕西科技大学学报：自然科学版，2004，22(5)：171～174
[52] 付文静．国内外防腐蚀涂料的技术现状与发展[J]．全面腐蚀控制，1998，12(1)；24～27，36
[53] Di Sarli A R, Cavalcanti E, Ferraz O. Use of EIS to characterize the performance of naval steel/organic coating systems in NaCl solution [J]. Corrosion Prevention & Control, 1993, 40(3): 66-70
[54] Cavalcanti E, Ferraz O, Di Sarli A R. Use of electrochemical impedance measurements to assess the performance of organic coating systems on naval steel [J]. Progress in Organic Coatings, 1993, 23(2): 185-200
[55] Cavalcanti E, Ferraz O, Di Sarli A R. Use of electrochemical impedance measurements to assess the performance of organic coating systems on naval steel. Progress in Organic Coatings, 1993, 23(2): 185-200
[56] Kweon Y G, Coddet C. Behavior in sea water of zinc-base coatings on aluminum alloy 5086. Corrosion, 1992, 48(2): 97-102
[57] Kweon Y G, Coddet C. Behavior in sea water of zinc-base coatings on aluminum alloy 5086 [J]. Corrosion, 1992, 48(2): 97-102
[58] Di Sarli A R, Cavalcanti E, Ferraz O. Use of EIS to characterize the performance of naval steel/organic coating systems in NaCl solution. Corrosion Prevention & Control, 1993, 40 (3): 66-70
[59] Vliet C H van. Reduction of zinc and volatile organic solvents in two-pack anti-corrosive primers-a pilot study[J]. Progress in Organic Coatings, 1998, 34: 220-226
[60] 周锡荣，唐绍裘，周武艺．新型无机涂料的制备及其应用．山东陶瓷．2004，27(1)；17～20
[61] 杨立红，刘福春，韩恩厚．纳米氧化锌改性聚氨醋复合涂层的防腐性能[J]．材料研究学报．2006，20(4)：355-361
[62] Andrea Kalendova. Effects of particle sizes and shapes of zinc metal on the properties of anticorrosive coatings[J]. Progress in Organic coatings, 2003, 46(4): 324～332
[63] 韩风俊，周钰明，汪小舟．鳞片状锌粉防腐蚀涂料的研制．腐蚀与防护．2006，27(3)；109～112，117
[64] 张东亚，孙祖信．水性无机富锌涂料施工工艺探究[J]．上海涂料，2004，(2)：36～38
[65] 杜存山，吴绍利．水性自固型无机富锌涂料的研究[J]．铁道建筑，2003，(10)；15～17
[66] 于晓辉，朱晓云，郭忠诚，龙晋明．鳞片状锌基环氧富锌重防腐涂料的研制[J]．表面技术，2005，34(1)；53～55
[67] 张文渊．水下金属构件的水性无机富锌涂料防腐处理[J]．涂料工业，2003，33(6)；30～33
[68] 张鉴清，孙国庆，曹楚南．评价有机涂层防护性能的EIS数据处理[J]．腐蚀科学与防护技 术，1994，6(4)：318-325．
[69] 吴丽蓉，胡学文，许崇武．用EIS快速评估有机涂层防护性能的方法．腐蚀科学与防护技术，2000，12(3)：182-184
[70] J.R. Scully. Electrochemical impedance of polymer-coated steel correlation of impedance parameters with long-term coatings deterioration[J].J. Electrochem.Soc., 1989, 136(4): 979-989.
[71] 杨立红，刘福春，韩恩厚．纳米氧化锌改性聚氨醋复合涂层的防腐性能[J]．材料研究学报．2006，20(4)：355-361
[2] 于晓辉，朱晓云，郭忠诚，龙晋明．鳞片状锌基环氧富锌重防腐涂料的研制[J]．表面技术，2005，34(1)：53～55
[3] 李金桂．钢铁构件表面上的无机富锌涂层[J]．中国表面工程，2003，(5)：1～4
[4] 张祖文，王军．提高环氧富锌涂料耐盐雾性和稳定性[J]．中国涂料，2003增刊：29～32
[5] 周文涛，李晓勤．无机富锌涂料性能及其应用[J]．湖北化工，2002(5)；26～27
[6] Feliu S, Barajas R, Bastidas J M, et al. Mechanism of cathodic protection of zinc-rich paints by electrochemical impedance spectroscopy: Ⅱ. barrier stage[J]. J. Coatings Technology, 1989, 61 (775): 71-76
[7] Feliu S, Barajas R, Bastidas J M, et al. Mechanism of cathodic protection of zinc-rich paints by electrochemica limpedance spectroscopy. Ⅰ. galvanicstage[J]. J. Coatings Technology, 1989,61 (775): 63-69
[8] Lindquist S A, Meszaros L, Svenson L. Aspects of galvanic action of zinc rich paints [J]. J. Oil Color Chem. Association, 1985, 1: 10
[9] Vomagnolt R, Vetere V F. The mechanism of anticorrosive action of zinc ethyl silicate paints [J]. J. Oil Color Chem. Association, 1993, 5: 208
[10] Morcillo M, Barajas R, Feliu S, et al. SEM study on the galvanic protection of zinc-rich paints [J]. J. MaterialsScience, 1990, 25(5): 2441-2446
[11] 张曙贤，海峰．水性无机富锌涂料[J]．上海建材，2001，(4)；32～33
[12] Malgorzata Zubielewicz a, Witold Gnot. Mechanisms of non-toxic anticorrosive pigments in organic waterborne coatings[J]. Progress in Organic Coatings, 2004, (49): 358-371
[13] Veleva L, Chin J, Del Amo B. corrosion electrochemical behavior of epoxy anticorrosive paints based on zinc molybdenum phosphate and zinc oxide[J]. Progress in Organic Coatings, 1999, 36; 211～216.
[14] 季瑞峰，钱叶苗，刘登良．水性无机富锌涂料．涂料工业，1999，(9)；7～10
[15] 翁永基．锌基防护涂层的保护机理及其使用特性．腐蚀科学与技术．1993，5(1)；70～73，78
[16] H. Marchebois, S. Joiret, C. Savall, J. Bemard, S. Touzain. Characterization of zinc-rich powder coatings by EIS and Raman spectroscopy. Surface and Coatings Technology, 2002, (157): 151～161
[17] 秦国治，王顺．富锌涂料综述．化工设备与防腐蚀，2001，(5)；55～58
[18] 徐峰，邹侯招，储健．环保型无机涂料．北京：化学工业出版社，2004：291～292
[19] 何丽芳，郭忠诚．水性无机富锌涂料的应用研究．表面技术，2006，35(1)：55～59
[20] 张利，吴庆余，魏铭，何松林，李淑柱．醇溶性无机富锌涂料及其电化学行为的研究．涂料：工业，2002，(8)：6～9
[21] 谢德明，胡吉明，童少平，王建明，张鉴清．富锌漆研究进展．中国腐蚀与防护学报．2004，24(5)；314～320
[22] Hare, Clive H. Zinc-rich primers I: design principles[J].J.Protective Coatings & Linings, 1998, 15(7): 17-38
[23] Brevoort, Gordon H. Inorganic zinc-rich coatings and galvanizing: a comparison. J. Protective Coatings & Linings, 1996, 13(9): 66-74
[24] 屠德容，李健，刘红伟，邵国环．关于水性无机富锌涂料的若干问题[J]．涂料技术与文摘，2003，(1)；13～16
[25] C G Munger. The chemistry of zinc silicate coatings [J]. Corrosion Prevention & Control, 1994, 12: 140.
[26] G Parashar, D Srivastava, P Kumar. Ethyl silicate binders for high performance coatings[J]. Progress in Organic Coatings, 2001, 42: 1.
[27] 王亦工，陈华辉，裴嵩峰，张婷．水性无机硅酸锌防腐涂料的研究进展[J]．腐蚀科学与防护技术，2006，18(1)；41～45
[28] 杨振波，杨忠林，郭万生，宋广成．鳞片状富锌涂层耐蚀机理的研究．中国涂料，2006，21(1)：19～22
[29] 江国庆，汪庆锋，胡晶．一种水性双组分无机锌涂料及其制造方法．CN1526780．2004-09．
[30] 林左峰．混合型砗溶胶水性无机富锌涂料CN1552771．2004-12
[31] 屠德容，刘红伟，邵国环．性价比卓越的无机水性涂料．涂料工业，2001，(5)：32～34
[32] 李金桂．无机富锌涂层的诞生和应用．防腐保温技术，2005，14(1)：22～26
[33] 赵力，曾燕．涂料用高模数砖酸钾溶液的制备方法．CN1676551，2005-10
[34] 于良民，董磊，姜晓辉，徐焕志．高模数硅酸钾及其富锌涂料的制备．涂料工业，2004，34(3)：9～13
[35] 黄鑫泉，陈东光．水溶性富锌防腐涂料CN1676550，2005-10
[36] Abreu C M, Izquierdo M, Merino P, et al. A new approach to the determination of the cathodic protection period in zinc-rich paints[J]. Corrosion, 1999, 55(12): 1173-1181
[37] Gervasi C A, Sarli A R Di, Cavalcanti E, et al. The corrosion protection of steel in sea-water using zinc-rich alkyd paints-an assessment of the pigment-content effect by EIS [J]. Corros. Sci., 1994,36(12): 1963-1972
[38] Abreu C M, Izquierdo M, Keddam M, et al. Electrochemical behaviour of zinc-rich epoxy paints in 3% NaCl solution[J]. Electrochim. Acta, 1996,41(15):2405-2415
[39] Real S G, Elias A C, Vilche J R, et al. electrochemical impedance spectroscopy study of zinc rich paints on steels in artificial sea-water by a transmission-line model[J]. Electrochim. Acta, 1993,38( 14):2029-2035
[40] Armas R A, Gervasi C A, Sarli A Di, et al.Zinc-rich paints on steels in artificial sea water by EIS [J]. Corrosion, 1992,48(5):379-383
[41] Vilche J R, Bucharsky E C, Giudice C A. Application of EIS and SEM to evaluate the influence of pigment shape and content in ZRP formulations on the corrosion prevention of naval steel[J].Corros. Sci.,2002,44(6): 1287-1309
[42] Feliu S, Barajas R, Bastidas J M, Morcillo M. Mechanism of cathodic protection of zinc-rich paints by electrochemical impedance spectroscopy. I . Galvanic stage[J].J.Coat.Technol., 1989,61(775):63-69
[43] Feliu S, Barajas R, Bastidas J M, Morcillo M. Mechanism of cathodic protection of zinc-rich paints by electrochemical impedance spectroscopy. I I . Galvanic stage[J].J.Coat.Technol., 1989,61(775):71-76
[44] Faidi S E, Scantlebury J D, Bullivant P, Whittle N T, Savin R. An electrochemical study of zinc-containing epoxy coatings on mild-steel[J].Corros.Sci.,1993,35(5-8):1319-1328
[45] Pereira D, Scantlebury J D, Ferreira M G S, Almeida E. The pplication of electrochemical measurements to the study and behavior of zinc-rich coatings[J]. Corros.Sci., 1990,30(11): 1135-1147
[46] Novoa X R, Izquierdo M, Merino P, Espada L. Electrochemical impedance spectroscopy and zero resistance ammeters (ZRA) as tools for studying the behavior of zinc-rich inorganic coatings [J].Mater.Sci.Forum,1989,44-45:223
[47] Izquierdo M, Novoa X R, Pena G, Espada L. The mechanism of protection of zinc-rich inorganic coatings, a study based on electrochemical impedance spectroscopy (EIS) [J].Mater.Sci.Forum, 1992,111-112:257
[48] J. D. Scantlebury and K. Gali.The application of AC impedance to study the performance of lacquered aluminium specimens in acetic acid solution[J]. Progress in Organic Coatings, 1997,31 (3):201-207
[49] C. G Oliveira and M. G. S. Ferreira.Ranking high-quality paint systems using EIS. Part I: intact coatings[J]. Corrosion Science, 2003,45(1): 123-138
[50] C. G Oliveira and M. G. S. Ferreira.Ranking high-quality paint systems using EIS. Part II: defective coatings[J]．Corrosion Science，2003，45(1)：139-147
[51] 杨建桥，杨军，刘艳．牺牲阳极涂料新进展．陕西科技大学学报：自然科学版，2004，22(5)：171～174
[52] 付文静．国内外防腐蚀涂料的技术现状与发展[J]．全面腐蚀控制，1998，12(1)；24～27，36
[53] Di Sarli A R, Cavalcanti E, Ferraz O. Use of EIS to characterize the performance of naval steel/organic coating systems in NaCl solution [J]. Corrosion Prevention & Control, 1993, 40(3): 66-70
[54] Cavalcanti E, Ferraz O, Di Sarli A R. Use of electrochemical impedance measurements to assess the performance of organic coating systems on naval steel [J]. Progress in Organic Coatings, 1993, 23(2): 185-200
[55] Cavalcanti E, Ferraz O, Di Sarli A R. Use of electrochemical impedance measurements to assess the performance of organic coating systems on naval steel. Progress in Organic Coatings, 1993, 23(2): 185-200
[56] Kweon Y G, Coddet C. Behavior in sea water of zinc-base coatings on aluminum alloy 5086. Corrosion, 1992, 48(2): 97-102
[57] Kweon Y G, Coddet C. Behavior in sea water of zinc-base coatings on aluminum alloy 5086 [J]. Corrosion, 1992, 48(2): 97-102
[58] Di Sarli A R, Cavalcanti E, Ferraz O. Use of EIS to characterize the performance of naval steel/organic coating systems in NaCl solution. Corrosion Prevention & Control, 1993, 40 (3): 66-70
[59] Vliet C H van. Reduction of zinc and volatile organic solvents in two-pack anti-corrosive primers-a pilot study[J]. Progress in Organic Coatings, 1998, 34: 220-226
[60] 周锡荣，唐绍裘，周武艺．新型无机涂料的制备及其应用．山东陶瓷．2004，27(1)；17～20
[61] 杨立红，刘福春，韩恩厚．纳米氧化锌改性聚氨醋复合涂层的防腐性能[J]．材料研究学报．2006，20(4)：355-361
[62] Andrea Kalendova. Effects of particle sizes and shapes of zinc metal on the properties of anticorrosive coatings[J]. Progress in Organic coatings, 2003, 46(4): 324～332
[63] 韩风俊，周钰明，汪小舟．鳞片状锌粉防腐蚀涂料的研制．腐蚀与防护．2006，27(3)；109～112，117
[64] 张东亚，孙祖信．水性无机富锌涂料施工工艺探究[J]．上海涂料，2004，(2)：36～38
[65] 杜存山，吴绍利．水性自固型无机富锌涂料的研究[J]．铁道建筑，2003，(10)；15～17
[66] 于晓辉，朱晓云，郭忠诚，龙晋明．鳞片状锌基环氧富锌重防腐涂料的研制[J]．表面技术，2005，34(1)；53～55
[67] 张文渊．水下金属构件的水性无机富锌涂料防腐处理[J]．涂料工业，2003，33(6)；30～33
[68] 张鉴清，孙国庆，曹楚南．评价有机涂层防护性能的EIS数据处理[J]．腐蚀科学与防护技 术，1994，6(4)：318-325．
[69] 吴丽蓉，胡学文，许崇武．用EIS快速评估有机涂层防护性能的方法．腐蚀科学与防护技术，2000，12(3)：182-184
[70] J.R. Scully. Electrochemical impedance of polymer-coated steel correlation of impedance parameters with long-term coatings deterioration[J].J. Electrochem.Soc., 1989, 136(4): 979-989.
[71] 杨立红，刘福春，韩恩厚．纳米氧化锌改性聚氨醋复合涂层的防腐性能[J]．材料研究学报．2006，20(4)：355-361