有毒微量元素铊的催化动力学法测定研究
|
摘要
铊由于其毒性已经被认为是一种对环境有重要影响的元素。但是在自然界中铊的含量低于μg·g~(-1)的水平,各种对铊元素的选择、分离、富集、净化和检测方法研究已成为一个有挑战性的课题。在分析和环境化学中对痕量铊元素的高灵敏度和可靠的检测方法具有重要意义。动力学分析法是利用化学反应速率和反应物浓度、催化剂之间的关系而进行定量分析的方法。而催化动力学法具有灵敏度高、选择性好、设备简单、操作简单的特点,是测定微量金属元素的有效方法之一。本论文研究了铊对几种化学发光反应的影响,建立了一系列测定铊的新方法,并对其可能的反应机理进行了探讨。主要的研究内容如下:
(1)基于铊对鲁米诺-H_2O_2体系的催化作用,据此建立了催化动力学光度法测定痕量铊(Ⅰ)的新方法。系统地考察鲁米诺反应体系随温度、时间的变化、共存离子等因素对测定结果的影响,确定了测定的最佳条件。测定铊(Ⅰ)的线性范围为0.05～0.2μg·mL~(-1),工作曲线的线性方程为ΔA=0.365+0.088C(μg·mL~(-1))(相关系数r=0.9989),检出限为0.0078μg·mL~(-1)。用于矿石中痕量铊的测定,其RSD为1.34%,加标回收率在98%～102%之间。
(2)在第一部分的基础上,利用配备了紫外检测器的高效液相色谱仪来测定痕量铊,建立了一种测定痕量铊的新方法。这种新的方法不仅结合了高效液相色谱的分离性能和化学发光反应的高灵敏度,而且条件简单。三种不同种类的表面活性剂被加入到鲁米诺-H_2O_2体系中,分别为溴化十六烷基三甲基铵(CTMAB)(阳离子型表面活性剂)、十二烷基磺酸钠(SDS)(阴离子型表面活性剂)、吐温80(非离子型表面活性剂)。在最佳条件下,测定铊(Ⅰ)的检测限为0.0073μg·mL~(-1),6次测定0.04μg·m~(-1)铊的标准偏差为低于4.0%,检测的线性范围为0.02～0.1μg·mL~(-1)。
(3)研究了紫外光对铊-光泽精-H_2O_2体系的光化学催化作用,建立了测定痕量铊的新方法。系统地考察光泽精反应体系光化学催化作用、光照时间的变化、共存离子等因素对测定结果的影响,并探讨了该体系光化学催化作用可能的机理,确定了测定的最佳条件。测定铊(Ⅰ)的线性范围为0.05～0.31μg·mL~(-1),工作曲线的线性方程为ΔA=0.0854+0.0892C(μg·mL~(-1))(相关系数r=0.996),检出限为0.0081μg·mL~(-1)。用于矿石中痕量铊的测定,其RSD为3.27%,回收率在97%～103%之间。
Thallium has been identified to be an environmentally significant element because of its toxic effects.But as the concentration of Thallium in the nature is belowμg·g~(-1) level,the development of new methods for selective separation, preconcentration,purification and determination of this metal continues to be a challenging problem.The need for highly sensitive and reliable method for the determination of ultratrace level Thallium has been recognized in analytical and environmental chemistry.The kinetic analytical methods are made using the relations among chemical reaction rates,reactant concentrations and catalysts.The catalytic kinetics has high sensitivity,excellent selectivity,inexpensiye instruments and simple operation.It is one of the effective methods for detecting trace metals.In this thesis, the measurements of trace Thallium(Ⅰ) were established based on its catalytic effect on the chemiluminescence reaction and their reaction mechanisms were also discussed.The main contents of the present work are as follows:
(1) A new catalytic kinetic spectrophotometric method was developed for the determination of Thallium(Ⅰ) based on its catalytic effect on the system of Luminol and hydrogen peroxide.The temperature and reaction time of the system and its effect of coexisting ions were also investigated in detailed.The linear range of the method was 0.05～0.2μg·mL~(-1) for Thallium(Ⅰ).The linear equation wasΔA=0.365+0.088C(μg·mL~(-1))(r=0.9989) and the detection limit was 0.0078μg·mL~(-1).It has been applide to the determination of trace Thallium(Ⅰ) in mineral sample with RSD of 1.34%and recovery of 98%～102%.
(2) At the first part of the foundation up,using a high-performance liquid chromatography equipped with the UV detector to the determination of trace thallium, set up a new determination of trace thallium Ways.This new method not only combines high-performance liquid chromatography separation performance and the chemiluminescence reaction of high sensitivity,and easy conditions.Three different kinds of surfactants,cetrimonium bromide(CTMAB),sodium dodecyl sulphate (SDS),and Tween-80,are also investigated to improve the detection sensitivity.In optimum conditions,a highly selective and sensitive method for detecting trace Thallium(Ⅰ) has been established.The detection limit is 0.0073μg·mL~(-1),the relative standard deviation for six determinations of 0.04μg·mL~(-1) Thallium(Ⅰ) is less than 4.0%, and the linear range of determination is 0.02～0.1μg·mL~(-1).
(3) A new method for the determination of trace element thallium was proposed based on the catalysis of Thallium(Ⅰ) on the photochemical reaction of lucigenin and hydrogen peroxide whit UV radiation.The light sources,radiation time of the system, a possible mechanism and its effect of coexisting ions were also investigated in detailed.The linear range of the method was 0.05～0.3μg·mL~(-1) for Thallium(Ⅰ).The linear equation wasΔA=0.0854+0.0892C(μg·mL~(-1))(r=0.996) and the detection limit was 0.0081μg·mL~(-1).By using the method in the determination of trace Tl(Ⅰ) in mineral sample,the RSD and recovery were 3.27%and 97%～103%,respectively, the results had shown that the method was satisfactory.
(1)基于铊对鲁米诺-H_2O_2体系的催化作用,据此建立了催化动力学光度法测定痕量铊(Ⅰ)的新方法。系统地考察鲁米诺反应体系随温度、时间的变化、共存离子等因素对测定结果的影响,确定了测定的最佳条件。测定铊(Ⅰ)的线性范围为0.05～0.2μg·mL~(-1),工作曲线的线性方程为ΔA=0.365+0.088C(μg·mL~(-1))(相关系数r=0.9989),检出限为0.0078μg·mL~(-1)。用于矿石中痕量铊的测定,其RSD为1.34%,加标回收率在98%～102%之间。
(2)在第一部分的基础上,利用配备了紫外检测器的高效液相色谱仪来测定痕量铊,建立了一种测定痕量铊的新方法。这种新的方法不仅结合了高效液相色谱的分离性能和化学发光反应的高灵敏度,而且条件简单。三种不同种类的表面活性剂被加入到鲁米诺-H_2O_2体系中,分别为溴化十六烷基三甲基铵(CTMAB)(阳离子型表面活性剂)、十二烷基磺酸钠(SDS)(阴离子型表面活性剂)、吐温80(非离子型表面活性剂)。在最佳条件下,测定铊(Ⅰ)的检测限为0.0073μg·mL~(-1),6次测定0.04μg·m~(-1)铊的标准偏差为低于4.0%,检测的线性范围为0.02～0.1μg·mL~(-1)。
(3)研究了紫外光对铊-光泽精-H_2O_2体系的光化学催化作用,建立了测定痕量铊的新方法。系统地考察光泽精反应体系光化学催化作用、光照时间的变化、共存离子等因素对测定结果的影响,并探讨了该体系光化学催化作用可能的机理,确定了测定的最佳条件。测定铊(Ⅰ)的线性范围为0.05～0.31μg·mL~(-1),工作曲线的线性方程为ΔA=0.0854+0.0892C(μg·mL~(-1))(相关系数r=0.996),检出限为0.0081μg·mL~(-1)。用于矿石中痕量铊的测定,其RSD为3.27%,回收率在97%～103%之间。
Thallium has been identified to be an environmentally significant element because of its toxic effects.But as the concentration of Thallium in the nature is belowμg·g~(-1) level,the development of new methods for selective separation, preconcentration,purification and determination of this metal continues to be a challenging problem.The need for highly sensitive and reliable method for the determination of ultratrace level Thallium has been recognized in analytical and environmental chemistry.The kinetic analytical methods are made using the relations among chemical reaction rates,reactant concentrations and catalysts.The catalytic kinetics has high sensitivity,excellent selectivity,inexpensiye instruments and simple operation.It is one of the effective methods for detecting trace metals.In this thesis, the measurements of trace Thallium(Ⅰ) were established based on its catalytic effect on the chemiluminescence reaction and their reaction mechanisms were also discussed.The main contents of the present work are as follows:
(1) A new catalytic kinetic spectrophotometric method was developed for the determination of Thallium(Ⅰ) based on its catalytic effect on the system of Luminol and hydrogen peroxide.The temperature and reaction time of the system and its effect of coexisting ions were also investigated in detailed.The linear range of the method was 0.05～0.2μg·mL~(-1) for Thallium(Ⅰ).The linear equation wasΔA=0.365+0.088C(μg·mL~(-1))(r=0.9989) and the detection limit was 0.0078μg·mL~(-1).It has been applide to the determination of trace Thallium(Ⅰ) in mineral sample with RSD of 1.34%and recovery of 98%～102%.
(2) At the first part of the foundation up,using a high-performance liquid chromatography equipped with the UV detector to the determination of trace thallium, set up a new determination of trace thallium Ways.This new method not only combines high-performance liquid chromatography separation performance and the chemiluminescence reaction of high sensitivity,and easy conditions.Three different kinds of surfactants,cetrimonium bromide(CTMAB),sodium dodecyl sulphate (SDS),and Tween-80,are also investigated to improve the detection sensitivity.In optimum conditions,a highly selective and sensitive method for detecting trace Thallium(Ⅰ) has been established.The detection limit is 0.0073μg·mL~(-1),the relative standard deviation for six determinations of 0.04μg·mL~(-1) Thallium(Ⅰ) is less than 4.0%, and the linear range of determination is 0.02～0.1μg·mL~(-1).
(3) A new method for the determination of trace element thallium was proposed based on the catalysis of Thallium(Ⅰ) on the photochemical reaction of lucigenin and hydrogen peroxide whit UV radiation.The light sources,radiation time of the system, a possible mechanism and its effect of coexisting ions were also investigated in detailed.The linear range of the method was 0.05～0.3μg·mL~(-1) for Thallium(Ⅰ).The linear equation wasΔA=0.0854+0.0892C(μg·mL~(-1))(r=0.996) and the detection limit was 0.0081μg·mL~(-1).By using the method in the determination of trace Tl(Ⅰ) in mineral sample,the RSD and recovery were 3.27%and 97%～103%,respectively, the results had shown that the method was satisfactory.
引文
[1]A.L.John Peter,T.Viraraghavan.Thallium:A review of public health and environmental concerns[J].Environ.Int.2005,31:493-501.
[2]陈红兵,高金燕.铊——人体的杀手[J].化学世界,2005,12:763-766.
[3]Arzate SG,Santarrmria A.Thallium toxicity[J].Toxicol Lett,1998,99(1):1-13.
[4]Heim M,Wappelhorst O,Markert B.Thallium in terrestrial environments-Occurrence and effects[J].Ecotoxieology,2002,11(5):369-377.
[5]J.E.Fergusson,The Heavy Elements:Chemistry,Environmental Impact and Health Effects,Pergamon Press,Oxford,1990.
[6]崔明珍,等.铊的致突效应及细胞转化研究[J].北京市劳动卫生职业病防治研究所年报,1989,36.
[7]张冬生,等.碳酸铊对微核率和精子畸形的影响[J].卫生研究,1987,16(1).
[8]Villaverde M S,Verstraeten S V.Effects of thallium(Ⅰ) and thallium(Ⅲ) on lipos0me membrane physical properties[J].Arch Bioehem Biophy,2003,417(2):235-243.
[9]Hanzel CE,Verstraeten SV.Thallium induces hydrogen peroxide generation by impairing mitochondrial function[J].Toxicol Appl Pharmacol,2006,216(3):485-492.
[10]崔明珍,等.铊的特殊毒性研究[J].卫生毒理学杂志,1990,4(2).
[11]E.Berman,Toxic Metals and their Analysis,Heyden,New York,1980.
[12]罗红群,刘绍璞,刘忠芳,李念兵.碘化物-乙基紫-阿拉伯胶体系高灵敏分光光度法测定铊[J].广东工业大学学报(增刊),1997,14(11):158-159.
[13]郑国祥,郭忠先,邵勇,张淑云.2,3-二羧基-5-磺酸基苯基重氮氨基偶氮苯与铊反应的分光光度法研究[J].分析试验室,1997,16(2):21-24.
[14]曹小安,陈永亨,周怀伟,方德新.邻羟基苯基重氮氨基偶氮苯与铊(Ⅲ)的显色反应及其应用[J].光谱学与光谱分析,2001,21(3):350-352.
[15]王余华,译.盐酸氯丙嗪分光光度法测定铊(Ⅲ)[J].预防医学情报杂志,1989,5(4):244-246.
[16]曹小安,陈永亨,张诠,谢长生.测定痕量铊的泡沫塑料吸附分离.镉试剂2B分光光度法[J].分析测试学报,2000,19(3):11-14.
[17]李锦文,吴惠明,陈永亨,邝杰辉,苏雅琴.八-羟基喹啉紫外分光光度法测定铊的研究[J].广州大学学报(自然科学版),2005,4(3):234-236.
[18]艾军,汤志勇,金泽祥.流动注射.在线萃取-火焰原子吸收法测定化探样品中痕量铊[J].分析化学,1997,25(8):988-991.
[19]杨春霞,陈永亨,彭平安,常向阳,谢长生.活性炭吸附-火焰原子吸收光 谱法测定环境样品中微量铊[J].理化检验.化学分册,2004,40(2):66-68.
[20]孙晓玲,胡瑞莲,张勤,周丽沂.泡沫塑料吸附石墨炉原子吸收测定地质物料中痕量铊[J].光谱实验室,1997,14(2):71-75.
[21]熊昭春.泡沫塑料对分散金属的吸附及其分析应用[J].地质实验室,1990,6(5):277-280.
[22]董云会,张少全.痕量铊的液膜分离富集与测定[J].分析科学学报,2005,21(2):191-193.
[23]Otruba V,Stepankova J,Sommer L.Selective preconcentration of T1 on modified silica gel for its determination by flame emission and absorption spectrometry[J].Talanta,1994,41(7):1185-1190.
[24]Wengener S,Pohl B.Determination of thallium environmental materials with GFAAS[J].Fresenius' J.Anal.Chem.,1992,243(1):153-167.
[25]李海涛,马冰洁.石墨炉原子吸收测定水中铊[J].光谱学与光谱分析,1993,13(1):127-134.
[26]程信良,鲍长利,郭旭明.涂钼石墨管石墨炉原子吸收法测定镓、铟、铊热蒸发行为的探讨[J].分析化学,1994,22(5):512-515.
[27]Welz B,Schlemmer G,Mudakavi J R.Investigation and elimination of chloride interference on thallium in graphite furnace atomic absorption spectrometry[J].Analytical Chemistry,1988,60:2567-2572.
[28]Matsusaki K.Matrix modification for the determination of thallium by graphite furnace atomic absorption spectrometry[J].Bunseki Kagaku,1991,40(8):413-417.
[29]Chen G,Jackson K W.Low-temperature migration of lead,thallium and selenium onto a palladium modifier during the analysis of solutions and slurries by electrothermal atomic absorption spectrometry[J].Spectrochim Acta Part B,1996,51(12):1505-1515.
[30]Arabinda K Das,Milli Dutta,Luisa Cervera M,Miguel de Guardia.Determination of thallium in water samples[J].Microchemical Journal,2007,86:2-8.
[31]Tser-Sheng Lin,Jerome O N.Thallium speciation in river waters with Chelex-100 resin[J].Analytica Chimica Acta,1999,395:301-307.
[32]罗津新.TBP萃淋树脂分离GFAAS测定水与废水中的铊[J].现代科学仪器,2000,4:39-41.
[33]Suzuki S,Katsuragi H.Determination of trace amounts of thallium in some sediments by graphite furnace AAS after preconcentration as xanthogenae complex on activated carbon[J].Bunseki Kagaka,1991,40(5):251-256.
[34]Ivanova E,Yan XP,Van Mol W.Determination of thallium in river sediment by flow injection on line sorption preconcentration in a knotted reactor coupled with ETAAS[J].Analyst(Cambridge,U.K),1997,122(7):667-670.
[35]Liao Yiping,Chen Guang,Du Yan,Li Anmo,Ni Zheming.Investigation of thallium hydride generation using in situ trapping in graphite tube by atomic absorption spectrometry[J].Anal.Chim.Acta,1998,360(123):209-214.
[36]Bjern Frengstad,Aase Kjersti Midtgard Skrede,David Banks,Jan Reidar Krog,Ulrich Siewers.The chemistry of Norwegian groundwater:Ⅲ.The distribution of trace elements in 476 crystalline bedrock groundwater,as analysed by ICP-MS techniques[J].The Science of the Total Environment,2000,246:21-40.
[37]王耐芬,解清,刘雅琼,王小燕,刘虎生,赵金垣.ICP-MS检测铊中毒事件中的痕量[J].质谱学报,2001,21(3):43-46.
[38]Wei Ming-Tsai,Jiang Shiuh-Jen.Determination of thallium in sea-water by flow injection hydride generation isotope dilution ICP-MS[J].Journal of Analytical Atomic Spectrometry,1999,14(8):1177-1181.
[39]Liu Hung wei.Determination of mercury and thallium in sea-water by electrothermal vaporization ICP-MS[J].Journal the Chinese Chemical Society,2000,47(3):481-488.
[40]陈中道,王洪恩,朱军,孙勤枢.电位溶出法测定环境水中的痕量铊[J].济宁医学院学报,1998,21(2):18-20.
[41]曹小安,陈永亨,黄橄荣,吴颖娟.差示脉冲阳极溶出伏安法测定痕量铊的研究[J].广州大学学报(自然科学版),2002,1(4):20-22.
[42]张月霞,刘杰民,朱腾.混合表面活性剂对铊(Ⅰ)的示波极谱电流的增敏效应[J].分析化学,1996,24(12):1391-1395.
[43]Tsai-Hwa Lu,Hao-Yun Yang,Sun Wen I.Square-wave anodic stripping voltammetric determination of thallium(Ⅰ) at a nafion-/mercury film modified electrode[J].Talanta,1999,49(1):59-68.
[44]Rounaghi C,Eshagi Z,Ghiamati E.Study of the complex formation between 18C6 Crown either and T1~+,Pb~(2+) and Cd~(2+) in binary non-aqueous solvents using differential pulse polarography[J].Talanta,1996,43:1043-1048.
[45]Perez-Ruiz T,Mart nez-Lozano C,Tom as V.Simple flow injection spectrofluorinetril method for speciation of thallium[J].Analyst,1996,121:813-816.
[46]Vassileva E,Furuta N.Application of iminodiacetate chelating resin muromac A-1 in on-line preconcentration and inductively couple dplasma optical emission spectroscopy determination of trace elements in natural waters[J].Spectrochimica Acta Part B,2003,58:1541-1552.
[47]Maia S M,Vale M G R,Welz B,Curtius A J.Feasibility of isotope dilution calibration for the determination of thallium in sediment using slurry sampling electrothermal vaporization inductively coupled plasma mass spectrometry[J].Spectrochim Acta Part B:Atomic Spectroscopy,2001,56(7):1263-1275.
[48]Zenon Lukaszewski,Wlodzimierz Zembrzuski,Anna Piela.Direct determination of ultratraces of thallium in water by flowinjection-differential-pulse anodic stripping voltammetry[J].Anal.Chim.Acta,1996,318:159-165.
[49]Sudarshan M,Dutta R K,Vijayan V,Chintalapudi S N.PIXE measurements of drinking water of Salt Lake,Calcutta,India[J].Nuclear Instruments and Methods in Physics Research B,2000,168:553-558.
[50]Oliver F Schedlbauer.Development of an isotope dilution mass spectrometric method for dimethylthallium speciation and first evidence of its existence in the ocean[J].Analytical.Chemistry,1999,71(18):5459-5464.
[51]赵锦瑞,何应律,钱徐根,赵中一,王茀鹏.8-羟基喹啉-5-磺酸-溴化十六烷基三甲胺荧光光度法痕量铊[J].分析化学,1994,22(10):1057-1060.
[52]王献科,李玉萍,李莉芬.释放螯合滴定法测定铊[J].上海有色金属,2000,21(1):25-27.
[53]Bontchev,P.R.,Mikrochinm.Acta,1964,(1).
[54]Budarin,L.I.,and K.E.Prik,Determination of ruthenium by a kinetic method based on the oxidation of p-anisidine with manganese(Ⅲ) sulfate[J].Zavod.Lab.,1960,26(8).
[55]G..G..吉尔鲍特,动力学和催化在分析中的应用,钱君贤译.
[56]Albrecht H O.Z Phys Chem,1928,136:321
[57]Dyke K van,McCapra F,Behesti I.Bioluminescence and Chemiluminescence:Instruments and Applications.CRC Press,West Palm Beach.1985.
[58]李德英,汪芸,汪敬武.盐酸倍他司汀对鲁米诺-高碘酸钾体系后发光作用机理的探讨及其快速测定[J].分析科学学报,2008,24(6):697-700.
[59]刘丽珍,赵守苗,赵鹏祥,等.流动注射化学发光法测定黄藤素[J].分析科学学报,2008,24(6):693-696.
[60]石杰,陈桂娟,吴拥军,等.流动注射化学发光法测定那格列奈[J].分析试验室,2008,27(12):69-71.
[61]白浩,吕九如.流动注射化学发光法测定哈西奈德[J].理化检验(化学分册),2008,44(10):927-929.
[62]任世奇,王栩,唐宝军,等.微板式化学发光酶免疫分析法临床测定人血清中孕酮[J].分析化学,2008,36(6):729-734.
[63]石文兵,流动注射微乳液化学发光法测定福尔可定[J].分析试验室,2008,27(6):35-38.
[64]史犇,石杰,吴拥军,等.流动注射化学发光法测定佐米曲谱坦[J].分析试验室,2008,27(2):62-64.
[65]刘晓宇,李爱芳,陈明,等.蔬菜中有机磷农药辛硫磷的化学发光分析研究[J].分析化学,2007,35(12):1809-1812.
[66]周园,何建波.毛细管电泳—电致化学发光法检测儿茶素[J].传感器世界,2007,(12):11-14.
[67]屈颖娟,段淑娥,王少英.鲁米诺-铁氰化钾化学发光体系测定利福平[J].光谱实验室,2007,24(5):798-781.
[68]唐玉海,姚宏,孙媛媛,流动注射抑制化学发光法测定盐酸环丙沙星[J].理化检验(化学分册),2007,43(8):639-641.
[69]王学锋,崔英,崔倩,等.流动注射化学发光法测定Mn(Ⅱ)[J].分析试验室,2007,26(9):110-113.
[70]杨玲娟,杜建修,李建军,等.流动注射电化学还原-化学发光法测定铀[J].理化检验(化学分册),2007,43(5):348-353.
[71]何树华,流动注射化学发光法测定盐酸仑氨西林[J].分析测试学报,2006,25(6):115-116.
[72]王术皓,庄惠生,姚型军,等.流动注射阻抑化学发光法测定己烯雌酚[J].分析试验室,2006,25(8):10-12.
[73]裴翠锦,章竹君,刘伟,微流动注射芯片化学发光法检测鱼虾中的四环素[J].分析测试学报,2006,25(3):83-85.
[74]余宇燕,沙玫,张淑玲,等.流动注射化学发光法测定茶饮料中的茶多酚[J].分析试验室,2006,25(4):101-103.
[75]李卫华,王雅珍,流动注射化学发光法测定硫脲[J].理化检验.化学分册,2006,42(2):111-112.
[76]陈福南,张迎雪,章竹君,等.高效液相色谱化学发光检测人体血清及尿样中的盐酸肾上腺素[J].分析化学,2005,33(12):1771-1774.
[77]杜凌云,季宁宁,王术皓,等.N-溴代丁二酰亚胺氧化体系流动注射化学发光法测定水中苯酚[J].光谱学与光谱分析,2005,25(12):1943-1946.
[78]冯娜,何云华,杜建修,等.铁氰化钾-鲁米诺体系后化学发光行为的研究-流动注射后化学发光法测定可待因[J].分析试验室,2005,24(5):1-3.
[79]李卫华,无机偶合流动注射化学发光测定钛的研究[J].分析试验室,2005,24(2):32-34.
[80]高新,张小燕,范晓东,等.谷氨酸流动注射化学发光法测定[J].理化检验.化学分册,2004,40(11):635-637.
[81]徐红,赖春泽,廉玫,等.流动注射化学发光法测定丁香酚[J].发光学报,2004,25(4):429-434.
[82]马红燕,郑行望,章竹君.流动注射电化学发光分析法测定诺氟沙星的研究[J].分析化学,2004,32(7):857-860.
[83]Song Z,Zhang N.In vitro detecting ultra-trace novalgin in medicine and human urine by chemiluminescence[J].Talanta,2003,60(1):161-170.
[84]Song Z,Hou S.Sub-picogram determination of Vitamin B12 in pharmaceuticals and human serum using flow injection with chemiluminescence detection[J].Anal Chim Acta,2003,488(1):71-79.
[85]Du J,Shen L,Lu J.Flow injection chemiluminescence determination of epinephrine using epinephrine-imprinted polymer as recognition material[J].Anal Chim Acta,2003,489(2):183-189.
[86]Song Z,Zhang N.In vitro detecting ultra-trace novalgin in medicine and human urine by chemiluminescence[J].Talanta,2003,60:161-170.
[87]Li N,Chi Y,Wang J,et al.Determination of procaine hydrochloride using flow injection inhibitory chemiluminescence[J],Luminescence,2003,18(3):125-130.
[88]Kiba N,Tlkizawa T,Kato S,et al.Flow-through micro sensor using immobilized peroxidase with chemiluminometric FIA system for determining hydrogen peroxide[J].Anal Sci,2003,19(6):823-827.
[89]Lv Y,Zhang Z,He D,Hu Y.Flow-injection determination of ornidazole by chemiluminescence detection based on a luminol-ferricyanide reaction[J].Anal Sci,2003,19(4):625-627.
[90]Yao D,Vlessidis A G,Evmiridis N P,et al.Luminol chemiluminescense reaction:a new method for monitoring nitric oxide in vivo[J].Anal Chim Acta,2002,485(2):281-289.
[91]Safavi A,Karimi M A.Flow injection determination of cationic surfactants by using N-bromosuccinimide and N-chlorosuccinimide as new oxidizing agents for luminol chemiluminescence[J].Anal Chim Acta,2002,486(1):53-63.
[92]Yao D,Vlessidis A G,Evmiridis N P.Development of an interference-free chemiluminescence method for monitoring acetylcholine and choline based on immobilized enzymes[J].Anal Chim Acta,2002,462(2):199-208.
[93]Croot P L,Laan P.Continuous shipboard determination of Fe(Ⅱ) in polar waters using flow injection analysis with chemiluminescence detection[J].Anal Chim Acta, 2002,466(2): 261-273.
[94] Anastasios E, Demetrius G. T., Georgios T., Paraskevas D. Sensitive determination of captopril by flow injection analysis with chemiluminescence detection based on the enhancement of the luminol reaction[J]. Anal Chim Acta,2002, 463(2): 249-255.
[95] Lau C, Lu J, Yagisawa S, et al, Simple chemiluminescence method for the determination of mercaptopurine[J]. Anal Sci, 2002,18(9): 1043-1045.
[96] Campins P, Tortajada-Genaro L A, Meseguer-Lloret S, Bosch-Reig F.Multivariate calibration applied to simultaneous chemiluminescence determination of cobalt and chromium[J]. Anal Bioanal Chem, 2002,374:1223-1229.
[97] Li B, Zhang Z, Jin Y. Chemiluminescence flow sensor for in vivo on-line monitoring of glucose in awake rabbit by microdialysis sampling[J]. Anal Chim Acta, 2001, 432(1):95-100.
[98] Li B, Zhang Z, Jin Y. Plant tissue-based chemiluminescence flow biosensor for glycolic acid[J]. Anal. Chem, 2001, 73(6): 1203-1206.
[99] Song Z, Wang L, Zhao T. Chemiluminescence flow sensor for hydrazine with immobilized reagents[J]. Anal Lett, 2001,34(3): 399-413.
[100] Du J, Li Y, Lu J. Flow injection chemiluminescence determination of rutin based on its enhancing effect on the luminol-ferricyanide/ferrocyanide system[J]. Anal Lett, 2001,34(10): 1741-1748.
[101] Sekiguchi Y, Nishikawa A, Makita H, et al. Flow-through chemiluminescence sensor using immobilized histamine oxidase from Arthrobacter crystallopoietes KAIT-B007 and peroxidase for selective determination of histamine[J]. Anal Sci, 2001,17: 1161-1164.
[102] Danet A F, Badea M, Aboul-Enein H Y, Flow injection system with chemiluminometric detection for enzymatic determination of ascorbic acid[J].Luminescence, 2000, 15: 305-309.
[103] Marquette C A, Ravaud S, Blum L J. Luminol Electrochemiluminescence-Based Biosensor for Total Cholesterol Determination in Natural Samples[J]. Anal Lett, 2000, 33(9): 1779-1796.
[104] Li Z, Li K, Tong S. Study of the Catalytic Effect of Copper(Ⅱ)-Protein Complexes on Luminol-H2O2 Chemiluminescence Reaction and its Analytical Application[J]. Anal Lett, 1999, 32(5): 901-913.
[105] Barnett N W, Francis P S, Lewis S W. Determination of α,4-dihydroxy-3-methoxybenzeneacetic acid (vanilmandelic acid) by flow injection analysis coupled with luminol-hexacyano ferrate(Ⅲ)chemiluminescence detection[J].Anal Commun,1999,36:131-134.
[106]Zheng X,Zheng Z.Flow-injection chemiluminescence determination of isoniazid using on-line electrogenerated BrO-as an oxidant[J].Analyst,1999,124:763-766.
[107]Qin W,Zhang Z,Peng Y,Li B.Plant tissue-based chemiluminescence flow biosensor for oxalate[J].Anal Commun,1999,36:337-339.
[108]Qin W,Zhang Z,Peng Y,Li B,Peng Y.Chemiluminescence flow system for the determination of ammonium ion[J].Talanta,1999,48:225-229.
[109]Perez-Ruiz T,Martinez-Lozano C,Tomas V.J Martin,Flow injection determination of lactate based on a photochemical reaction using photometric and chemiluminescence detection[J].Analyst,1999,124:1512-1517.
[110]Li J,Wang K-M,Yang X,Xiao D.Sol-gel horseradish peroxidase biosensor for the chemiluminescent flow determination of hydrogen peroxide[J].Anal Commun,1999,36:195-197.
[111]朱智甲,周清泽.液相色谱化学发光检测法的进展[J].河北师范太学学报(自然科学版),1997,21(4):402-406.
[112]Jianxiu Du,Jiuru Lu.Flow injection chemiluminescence determination of isoniazid using the lucigenin-periodate system[J].Luminescence,2006,21:26-30.
[113]庄惠生,陈国南,黄金陵.9,9-双吖啶衍生物的化学发光反应新机理[J].福州大学学报(自然科学版),1999,27:54-55.
[114]庄惠生,陈国南,王琼娥,等.9-羧基吖啶-DNA-H_2O_2-KOH化学发光分析新体系的研究[J].福州大学学报(自然科学版),1999,27:52-53.
[115]石明娟,Aung Myint,董永平,等.苯酚和苯胺类化合物对光泽精化学发光的增强和抑制作用[J].光谱学与光谱分析,2007,27(10):1945-1950.
[116]Takeyoshi O,Takeo O.Electrogenerated chemiluminescence of lucigenin enhanced by the modifications of electrodes with self-assembled monolayers and of solutions with surfactants[J].Journal of Electroanalytical Chemistry,2002,534(2):181-187.
[2]陈红兵,高金燕.铊——人体的杀手[J].化学世界,2005,12:763-766.
[3]Arzate SG,Santarrmria A.Thallium toxicity[J].Toxicol Lett,1998,99(1):1-13.
[4]Heim M,Wappelhorst O,Markert B.Thallium in terrestrial environments-Occurrence and effects[J].Ecotoxieology,2002,11(5):369-377.
[5]J.E.Fergusson,The Heavy Elements:Chemistry,Environmental Impact and Health Effects,Pergamon Press,Oxford,1990.
[6]崔明珍,等.铊的致突效应及细胞转化研究[J].北京市劳动卫生职业病防治研究所年报,1989,36.
[7]张冬生,等.碳酸铊对微核率和精子畸形的影响[J].卫生研究,1987,16(1).
[8]Villaverde M S,Verstraeten S V.Effects of thallium(Ⅰ) and thallium(Ⅲ) on lipos0me membrane physical properties[J].Arch Bioehem Biophy,2003,417(2):235-243.
[9]Hanzel CE,Verstraeten SV.Thallium induces hydrogen peroxide generation by impairing mitochondrial function[J].Toxicol Appl Pharmacol,2006,216(3):485-492.
[10]崔明珍,等.铊的特殊毒性研究[J].卫生毒理学杂志,1990,4(2).
[11]E.Berman,Toxic Metals and their Analysis,Heyden,New York,1980.
[12]罗红群,刘绍璞,刘忠芳,李念兵.碘化物-乙基紫-阿拉伯胶体系高灵敏分光光度法测定铊[J].广东工业大学学报(增刊),1997,14(11):158-159.
[13]郑国祥,郭忠先,邵勇,张淑云.2,3-二羧基-5-磺酸基苯基重氮氨基偶氮苯与铊反应的分光光度法研究[J].分析试验室,1997,16(2):21-24.
[14]曹小安,陈永亨,周怀伟,方德新.邻羟基苯基重氮氨基偶氮苯与铊(Ⅲ)的显色反应及其应用[J].光谱学与光谱分析,2001,21(3):350-352.
[15]王余华,译.盐酸氯丙嗪分光光度法测定铊(Ⅲ)[J].预防医学情报杂志,1989,5(4):244-246.
[16]曹小安,陈永亨,张诠,谢长生.测定痕量铊的泡沫塑料吸附分离.镉试剂2B分光光度法[J].分析测试学报,2000,19(3):11-14.
[17]李锦文,吴惠明,陈永亨,邝杰辉,苏雅琴.八-羟基喹啉紫外分光光度法测定铊的研究[J].广州大学学报(自然科学版),2005,4(3):234-236.
[18]艾军,汤志勇,金泽祥.流动注射.在线萃取-火焰原子吸收法测定化探样品中痕量铊[J].分析化学,1997,25(8):988-991.
[19]杨春霞,陈永亨,彭平安,常向阳,谢长生.活性炭吸附-火焰原子吸收光 谱法测定环境样品中微量铊[J].理化检验.化学分册,2004,40(2):66-68.
[20]孙晓玲,胡瑞莲,张勤,周丽沂.泡沫塑料吸附石墨炉原子吸收测定地质物料中痕量铊[J].光谱实验室,1997,14(2):71-75.
[21]熊昭春.泡沫塑料对分散金属的吸附及其分析应用[J].地质实验室,1990,6(5):277-280.
[22]董云会,张少全.痕量铊的液膜分离富集与测定[J].分析科学学报,2005,21(2):191-193.
[23]Otruba V,Stepankova J,Sommer L.Selective preconcentration of T1 on modified silica gel for its determination by flame emission and absorption spectrometry[J].Talanta,1994,41(7):1185-1190.
[24]Wengener S,Pohl B.Determination of thallium environmental materials with GFAAS[J].Fresenius' J.Anal.Chem.,1992,243(1):153-167.
[25]李海涛,马冰洁.石墨炉原子吸收测定水中铊[J].光谱学与光谱分析,1993,13(1):127-134.
[26]程信良,鲍长利,郭旭明.涂钼石墨管石墨炉原子吸收法测定镓、铟、铊热蒸发行为的探讨[J].分析化学,1994,22(5):512-515.
[27]Welz B,Schlemmer G,Mudakavi J R.Investigation and elimination of chloride interference on thallium in graphite furnace atomic absorption spectrometry[J].Analytical Chemistry,1988,60:2567-2572.
[28]Matsusaki K.Matrix modification for the determination of thallium by graphite furnace atomic absorption spectrometry[J].Bunseki Kagaku,1991,40(8):413-417.
[29]Chen G,Jackson K W.Low-temperature migration of lead,thallium and selenium onto a palladium modifier during the analysis of solutions and slurries by electrothermal atomic absorption spectrometry[J].Spectrochim Acta Part B,1996,51(12):1505-1515.
[30]Arabinda K Das,Milli Dutta,Luisa Cervera M,Miguel de Guardia.Determination of thallium in water samples[J].Microchemical Journal,2007,86:2-8.
[31]Tser-Sheng Lin,Jerome O N.Thallium speciation in river waters with Chelex-100 resin[J].Analytica Chimica Acta,1999,395:301-307.
[32]罗津新.TBP萃淋树脂分离GFAAS测定水与废水中的铊[J].现代科学仪器,2000,4:39-41.
[33]Suzuki S,Katsuragi H.Determination of trace amounts of thallium in some sediments by graphite furnace AAS after preconcentration as xanthogenae complex on activated carbon[J].Bunseki Kagaka,1991,40(5):251-256.
[34]Ivanova E,Yan XP,Van Mol W.Determination of thallium in river sediment by flow injection on line sorption preconcentration in a knotted reactor coupled with ETAAS[J].Analyst(Cambridge,U.K),1997,122(7):667-670.
[35]Liao Yiping,Chen Guang,Du Yan,Li Anmo,Ni Zheming.Investigation of thallium hydride generation using in situ trapping in graphite tube by atomic absorption spectrometry[J].Anal.Chim.Acta,1998,360(123):209-214.
[36]Bjern Frengstad,Aase Kjersti Midtgard Skrede,David Banks,Jan Reidar Krog,Ulrich Siewers.The chemistry of Norwegian groundwater:Ⅲ.The distribution of trace elements in 476 crystalline bedrock groundwater,as analysed by ICP-MS techniques[J].The Science of the Total Environment,2000,246:21-40.
[37]王耐芬,解清,刘雅琼,王小燕,刘虎生,赵金垣.ICP-MS检测铊中毒事件中的痕量[J].质谱学报,2001,21(3):43-46.
[38]Wei Ming-Tsai,Jiang Shiuh-Jen.Determination of thallium in sea-water by flow injection hydride generation isotope dilution ICP-MS[J].Journal of Analytical Atomic Spectrometry,1999,14(8):1177-1181.
[39]Liu Hung wei.Determination of mercury and thallium in sea-water by electrothermal vaporization ICP-MS[J].Journal the Chinese Chemical Society,2000,47(3):481-488.
[40]陈中道,王洪恩,朱军,孙勤枢.电位溶出法测定环境水中的痕量铊[J].济宁医学院学报,1998,21(2):18-20.
[41]曹小安,陈永亨,黄橄荣,吴颖娟.差示脉冲阳极溶出伏安法测定痕量铊的研究[J].广州大学学报(自然科学版),2002,1(4):20-22.
[42]张月霞,刘杰民,朱腾.混合表面活性剂对铊(Ⅰ)的示波极谱电流的增敏效应[J].分析化学,1996,24(12):1391-1395.
[43]Tsai-Hwa Lu,Hao-Yun Yang,Sun Wen I.Square-wave anodic stripping voltammetric determination of thallium(Ⅰ) at a nafion-/mercury film modified electrode[J].Talanta,1999,49(1):59-68.
[44]Rounaghi C,Eshagi Z,Ghiamati E.Study of the complex formation between 18C6 Crown either and T1~+,Pb~(2+) and Cd~(2+) in binary non-aqueous solvents using differential pulse polarography[J].Talanta,1996,43:1043-1048.
[45]Perez-Ruiz T,Mart nez-Lozano C,Tom as V.Simple flow injection spectrofluorinetril method for speciation of thallium[J].Analyst,1996,121:813-816.
[46]Vassileva E,Furuta N.Application of iminodiacetate chelating resin muromac A-1 in on-line preconcentration and inductively couple dplasma optical emission spectroscopy determination of trace elements in natural waters[J].Spectrochimica Acta Part B,2003,58:1541-1552.
[47]Maia S M,Vale M G R,Welz B,Curtius A J.Feasibility of isotope dilution calibration for the determination of thallium in sediment using slurry sampling electrothermal vaporization inductively coupled plasma mass spectrometry[J].Spectrochim Acta Part B:Atomic Spectroscopy,2001,56(7):1263-1275.
[48]Zenon Lukaszewski,Wlodzimierz Zembrzuski,Anna Piela.Direct determination of ultratraces of thallium in water by flowinjection-differential-pulse anodic stripping voltammetry[J].Anal.Chim.Acta,1996,318:159-165.
[49]Sudarshan M,Dutta R K,Vijayan V,Chintalapudi S N.PIXE measurements of drinking water of Salt Lake,Calcutta,India[J].Nuclear Instruments and Methods in Physics Research B,2000,168:553-558.
[50]Oliver F Schedlbauer.Development of an isotope dilution mass spectrometric method for dimethylthallium speciation and first evidence of its existence in the ocean[J].Analytical.Chemistry,1999,71(18):5459-5464.
[51]赵锦瑞,何应律,钱徐根,赵中一,王茀鹏.8-羟基喹啉-5-磺酸-溴化十六烷基三甲胺荧光光度法痕量铊[J].分析化学,1994,22(10):1057-1060.
[52]王献科,李玉萍,李莉芬.释放螯合滴定法测定铊[J].上海有色金属,2000,21(1):25-27.
[53]Bontchev,P.R.,Mikrochinm.Acta,1964,(1).
[54]Budarin,L.I.,and K.E.Prik,Determination of ruthenium by a kinetic method based on the oxidation of p-anisidine with manganese(Ⅲ) sulfate[J].Zavod.Lab.,1960,26(8).
[55]G..G..吉尔鲍特,动力学和催化在分析中的应用,钱君贤译.
[56]Albrecht H O.Z Phys Chem,1928,136:321
[57]Dyke K van,McCapra F,Behesti I.Bioluminescence and Chemiluminescence:Instruments and Applications.CRC Press,West Palm Beach.1985.
[58]李德英,汪芸,汪敬武.盐酸倍他司汀对鲁米诺-高碘酸钾体系后发光作用机理的探讨及其快速测定[J].分析科学学报,2008,24(6):697-700.
[59]刘丽珍,赵守苗,赵鹏祥,等.流动注射化学发光法测定黄藤素[J].分析科学学报,2008,24(6):693-696.
[60]石杰,陈桂娟,吴拥军,等.流动注射化学发光法测定那格列奈[J].分析试验室,2008,27(12):69-71.
[61]白浩,吕九如.流动注射化学发光法测定哈西奈德[J].理化检验(化学分册),2008,44(10):927-929.
[62]任世奇,王栩,唐宝军,等.微板式化学发光酶免疫分析法临床测定人血清中孕酮[J].分析化学,2008,36(6):729-734.
[63]石文兵,流动注射微乳液化学发光法测定福尔可定[J].分析试验室,2008,27(6):35-38.
[64]史犇,石杰,吴拥军,等.流动注射化学发光法测定佐米曲谱坦[J].分析试验室,2008,27(2):62-64.
[65]刘晓宇,李爱芳,陈明,等.蔬菜中有机磷农药辛硫磷的化学发光分析研究[J].分析化学,2007,35(12):1809-1812.
[66]周园,何建波.毛细管电泳—电致化学发光法检测儿茶素[J].传感器世界,2007,(12):11-14.
[67]屈颖娟,段淑娥,王少英.鲁米诺-铁氰化钾化学发光体系测定利福平[J].光谱实验室,2007,24(5):798-781.
[68]唐玉海,姚宏,孙媛媛,流动注射抑制化学发光法测定盐酸环丙沙星[J].理化检验(化学分册),2007,43(8):639-641.
[69]王学锋,崔英,崔倩,等.流动注射化学发光法测定Mn(Ⅱ)[J].分析试验室,2007,26(9):110-113.
[70]杨玲娟,杜建修,李建军,等.流动注射电化学还原-化学发光法测定铀[J].理化检验(化学分册),2007,43(5):348-353.
[71]何树华,流动注射化学发光法测定盐酸仑氨西林[J].分析测试学报,2006,25(6):115-116.
[72]王术皓,庄惠生,姚型军,等.流动注射阻抑化学发光法测定己烯雌酚[J].分析试验室,2006,25(8):10-12.
[73]裴翠锦,章竹君,刘伟,微流动注射芯片化学发光法检测鱼虾中的四环素[J].分析测试学报,2006,25(3):83-85.
[74]余宇燕,沙玫,张淑玲,等.流动注射化学发光法测定茶饮料中的茶多酚[J].分析试验室,2006,25(4):101-103.
[75]李卫华,王雅珍,流动注射化学发光法测定硫脲[J].理化检验.化学分册,2006,42(2):111-112.
[76]陈福南,张迎雪,章竹君,等.高效液相色谱化学发光检测人体血清及尿样中的盐酸肾上腺素[J].分析化学,2005,33(12):1771-1774.
[77]杜凌云,季宁宁,王术皓,等.N-溴代丁二酰亚胺氧化体系流动注射化学发光法测定水中苯酚[J].光谱学与光谱分析,2005,25(12):1943-1946.
[78]冯娜,何云华,杜建修,等.铁氰化钾-鲁米诺体系后化学发光行为的研究-流动注射后化学发光法测定可待因[J].分析试验室,2005,24(5):1-3.
[79]李卫华,无机偶合流动注射化学发光测定钛的研究[J].分析试验室,2005,24(2):32-34.
[80]高新,张小燕,范晓东,等.谷氨酸流动注射化学发光法测定[J].理化检验.化学分册,2004,40(11):635-637.
[81]徐红,赖春泽,廉玫,等.流动注射化学发光法测定丁香酚[J].发光学报,2004,25(4):429-434.
[82]马红燕,郑行望,章竹君.流动注射电化学发光分析法测定诺氟沙星的研究[J].分析化学,2004,32(7):857-860.
[83]Song Z,Zhang N.In vitro detecting ultra-trace novalgin in medicine and human urine by chemiluminescence[J].Talanta,2003,60(1):161-170.
[84]Song Z,Hou S.Sub-picogram determination of Vitamin B12 in pharmaceuticals and human serum using flow injection with chemiluminescence detection[J].Anal Chim Acta,2003,488(1):71-79.
[85]Du J,Shen L,Lu J.Flow injection chemiluminescence determination of epinephrine using epinephrine-imprinted polymer as recognition material[J].Anal Chim Acta,2003,489(2):183-189.
[86]Song Z,Zhang N.In vitro detecting ultra-trace novalgin in medicine and human urine by chemiluminescence[J].Talanta,2003,60:161-170.
[87]Li N,Chi Y,Wang J,et al.Determination of procaine hydrochloride using flow injection inhibitory chemiluminescence[J],Luminescence,2003,18(3):125-130.
[88]Kiba N,Tlkizawa T,Kato S,et al.Flow-through micro sensor using immobilized peroxidase with chemiluminometric FIA system for determining hydrogen peroxide[J].Anal Sci,2003,19(6):823-827.
[89]Lv Y,Zhang Z,He D,Hu Y.Flow-injection determination of ornidazole by chemiluminescence detection based on a luminol-ferricyanide reaction[J].Anal Sci,2003,19(4):625-627.
[90]Yao D,Vlessidis A G,Evmiridis N P,et al.Luminol chemiluminescense reaction:a new method for monitoring nitric oxide in vivo[J].Anal Chim Acta,2002,485(2):281-289.
[91]Safavi A,Karimi M A.Flow injection determination of cationic surfactants by using N-bromosuccinimide and N-chlorosuccinimide as new oxidizing agents for luminol chemiluminescence[J].Anal Chim Acta,2002,486(1):53-63.
[92]Yao D,Vlessidis A G,Evmiridis N P.Development of an interference-free chemiluminescence method for monitoring acetylcholine and choline based on immobilized enzymes[J].Anal Chim Acta,2002,462(2):199-208.
[93]Croot P L,Laan P.Continuous shipboard determination of Fe(Ⅱ) in polar waters using flow injection analysis with chemiluminescence detection[J].Anal Chim Acta, 2002,466(2): 261-273.
[94] Anastasios E, Demetrius G. T., Georgios T., Paraskevas D. Sensitive determination of captopril by flow injection analysis with chemiluminescence detection based on the enhancement of the luminol reaction[J]. Anal Chim Acta,2002, 463(2): 249-255.
[95] Lau C, Lu J, Yagisawa S, et al, Simple chemiluminescence method for the determination of mercaptopurine[J]. Anal Sci, 2002,18(9): 1043-1045.
[96] Campins P, Tortajada-Genaro L A, Meseguer-Lloret S, Bosch-Reig F.Multivariate calibration applied to simultaneous chemiluminescence determination of cobalt and chromium[J]. Anal Bioanal Chem, 2002,374:1223-1229.
[97] Li B, Zhang Z, Jin Y. Chemiluminescence flow sensor for in vivo on-line monitoring of glucose in awake rabbit by microdialysis sampling[J]. Anal Chim Acta, 2001, 432(1):95-100.
[98] Li B, Zhang Z, Jin Y. Plant tissue-based chemiluminescence flow biosensor for glycolic acid[J]. Anal. Chem, 2001, 73(6): 1203-1206.
[99] Song Z, Wang L, Zhao T. Chemiluminescence flow sensor for hydrazine with immobilized reagents[J]. Anal Lett, 2001,34(3): 399-413.
[100] Du J, Li Y, Lu J. Flow injection chemiluminescence determination of rutin based on its enhancing effect on the luminol-ferricyanide/ferrocyanide system[J]. Anal Lett, 2001,34(10): 1741-1748.
[101] Sekiguchi Y, Nishikawa A, Makita H, et al. Flow-through chemiluminescence sensor using immobilized histamine oxidase from Arthrobacter crystallopoietes KAIT-B007 and peroxidase for selective determination of histamine[J]. Anal Sci, 2001,17: 1161-1164.
[102] Danet A F, Badea M, Aboul-Enein H Y, Flow injection system with chemiluminometric detection for enzymatic determination of ascorbic acid[J].Luminescence, 2000, 15: 305-309.
[103] Marquette C A, Ravaud S, Blum L J. Luminol Electrochemiluminescence-Based Biosensor for Total Cholesterol Determination in Natural Samples[J]. Anal Lett, 2000, 33(9): 1779-1796.
[104] Li Z, Li K, Tong S. Study of the Catalytic Effect of Copper(Ⅱ)-Protein Complexes on Luminol-H2O2 Chemiluminescence Reaction and its Analytical Application[J]. Anal Lett, 1999, 32(5): 901-913.
[105] Barnett N W, Francis P S, Lewis S W. Determination of α,4-dihydroxy-3-methoxybenzeneacetic acid (vanilmandelic acid) by flow injection analysis coupled with luminol-hexacyano ferrate(Ⅲ)chemiluminescence detection[J].Anal Commun,1999,36:131-134.
[106]Zheng X,Zheng Z.Flow-injection chemiluminescence determination of isoniazid using on-line electrogenerated BrO-as an oxidant[J].Analyst,1999,124:763-766.
[107]Qin W,Zhang Z,Peng Y,Li B.Plant tissue-based chemiluminescence flow biosensor for oxalate[J].Anal Commun,1999,36:337-339.
[108]Qin W,Zhang Z,Peng Y,Li B,Peng Y.Chemiluminescence flow system for the determination of ammonium ion[J].Talanta,1999,48:225-229.
[109]Perez-Ruiz T,Martinez-Lozano C,Tomas V.J Martin,Flow injection determination of lactate based on a photochemical reaction using photometric and chemiluminescence detection[J].Analyst,1999,124:1512-1517.
[110]Li J,Wang K-M,Yang X,Xiao D.Sol-gel horseradish peroxidase biosensor for the chemiluminescent flow determination of hydrogen peroxide[J].Anal Commun,1999,36:195-197.
[111]朱智甲,周清泽.液相色谱化学发光检测法的进展[J].河北师范太学学报(自然科学版),1997,21(4):402-406.
[112]Jianxiu Du,Jiuru Lu.Flow injection chemiluminescence determination of isoniazid using the lucigenin-periodate system[J].Luminescence,2006,21:26-30.
[113]庄惠生,陈国南,黄金陵.9,9-双吖啶衍生物的化学发光反应新机理[J].福州大学学报(自然科学版),1999,27:54-55.
[114]庄惠生,陈国南,王琼娥,等.9-羧基吖啶-DNA-H_2O_2-KOH化学发光分析新体系的研究[J].福州大学学报(自然科学版),1999,27:52-53.
[115]石明娟,Aung Myint,董永平,等.苯酚和苯胺类化合物对光泽精化学发光的增强和抑制作用[J].光谱学与光谱分析,2007,27(10):1945-1950.
[116]Takeyoshi O,Takeo O.Electrogenerated chemiluminescence of lucigenin enhanced by the modifications of electrodes with self-assembled monolayers and of solutions with surfactants[J].Journal of Electroanalytical Chemistry,2002,534(2):181-187.