聚丙烯高性能化材料结构和性能的研究
|
摘要
聚丙烯基体中加入少量 PA6、PET、环氧树脂及反应增容剂，通过反
应共混提高了材料的力学性能。
用扫描电镜和图象处理软件分析 PP/PA6、PP/PET 共混物的形貌，在
扭矩流变仪中研究环氧树脂在 PP 熔体中的固化行为，测量了 PP/EPOXY
共混物与水的动态接触角和 PP/EPOXY 共混物的熔体流动性，用偏光显微
镜观察合金等温结晶形态并测量力学性能，最后对三体系力学性能进行对
比。
PP/PA6 是典型的不相容体系，加入两种反应增容剂后相容性改善且
EPDM-g-GMA 增容效果较好；PP 球晶尺寸随 PA6 含量增加而减小，PA6
相分布在 PP 球晶之间，加入 PP-g-MAH 或 EPDM-g-GMA 后相容性改善；
PP/PA6 中加入 EPDM-g-GMA 后起到反应增容和橡胶增韧的协同效应；
PP/PA6 中加入 PP-g-MAH 后杨氏模量提高，同时屈服强度高于未增容体
系。
PP/PET 也是典型的不相容体系，加入两种反应增容剂后相容性提高
且 EPDM-g-GMA 的效果较好； PP 球晶随 PET 的混入而明显减小，PET
相 分 散 在 球 晶 之 间 ， 加 入 EPDM-g-GMA 后 二 者 相 容 性 改 善 ，
PP/PET/EPDM-g-GMA 中加入成核剂后对 PET 结晶有细化作用；PP/PET
体系中加入 EPDM-g-GMA 起到反应增容和橡胶增韧的协同效应，进一步
加入的成核剂有利于增韧；PP/PET 体系中加入 PP-g-MAH 后模量提高；
PP/PET 中加入 PP-g-MAH 后屈服强度缓慢下降。
当共混时间达到 10~15 分钟时，环氧树脂可能凝胶化使扭矩曲线升高，
之后进入固化阶段； PP 中加入环氧树脂后，交联阻碍结晶，使 PP 球晶
尺寸变小、变模糊；PP 中加入环氧树脂后亲水性提高，熔体流动性下降；
随 E-51 含量的增加，未增容体系的模量提高，屈服强度下降，韧性下降，
加入 PP-g-MAH 后，模量进一步提高，屈服强度缓慢上升，韧性改善。
力 学 性 能 对 比 表 明 ： PP/PA6/EPDM-g-GMA 体 系 的 韧 性 最 好 ，
PP/PET/PP-g- MAH 体系刚性最大，PP/E-51/203#/PP-g-MAH 体系的屈服强
度最高。
The mechanical properties of polypropylene were improved by
reactive blending with a few nylon6, polyethylene terephthalate, epoxy
and compatibilizer.
The morphology of PP/PA6 blends and PP/PET blends were
analysized by ESEM and image processing software. The crosslink action
of epoxy in PP melt was studied in torque rheometer. The melt flow index
and dynamic contact angle of PP/EPOXY blends in water were measured.
The isothermal crystalline state of PP/PA6 blends, PP/ PET blends and
PP/EPOXY blends were observed by polarizing microscope and their
mechanical properties were also tested. At last, the mechanical properties
of the three systems were contrasted.
PP/PA6 is a typical immiscible system. The compatibility was
improved by adding two kinds of compatibilizer, and EPDM-g-GMA was
more efficient. The dimension of PP spherulites minished with PA6
content increasing. PA6 phase distributed among PP spherulites, and the
compatibility was improved by adding PP-g-MAH or EPDM-g-GMA. The
reactive compatibilization and rubber tougheness had cooperative
effectiveness on PP/PA6 blends, after adding EPDM-g-GMA. The Yang’s
modulus of PP/PA6 blends was improved after adding PP-g-MAH, at the
same time, the yield stress was higher than that of immiscible system.
PP/PET is also a typical immiscible system. The compatibility was
improved by adding two kinds of compatibilizer, and EPDM-g-GMA was
more efficient. The dimension of PP spherulites minished after PP had
blended with PET . PET phase distributed among PP spherulites, and the
compatibility was improved by adding EPDM-g-GMA. PET crystal phase
became finer after adding nucleating agent in PP/PET/EPDM-g-GMA
blends. The reactive compatibilization and rubber tougheness had
cooperative effectiveness on PP/PET blends, furthermore, nucleating
agent takes advantage in improving toughness. The Yang’s modulus of
PP/PET blends was improved after adding PP-g-MAH, at the same time,
the yield stress decrease slowly.
Epoxy was likely to begin gelationization, which lift torque curve in
10~15minute, and then Epoxy come into solidify period. After PP blends
with epoxy, the crystallization was baffled by crosslinking and the
dimension of PP spherulites become small and illegible, at the same time,
the hydrophilicity increase and the fluidity descend. The Yang’s modulus
of uncompatibile system increase while the yield stress and toughness
decrease. After adding PP-g-MAH, the Yang’s modulus of blend increase
more, and the yield stress increase slowly and toughness improve.
The results of mechanical properties contrasting show that
PP/PA6/EPDM-g-GMA system was toughest, PP/PET/PP-g-MAH system
was rigidest and PP/E-51/ 203#/PP-g-MAH system is best at yield stress.
应共混提高了材料的力学性能。
用扫描电镜和图象处理软件分析 PP/PA6、PP/PET 共混物的形貌，在
扭矩流变仪中研究环氧树脂在 PP 熔体中的固化行为，测量了 PP/EPOXY
共混物与水的动态接触角和 PP/EPOXY 共混物的熔体流动性，用偏光显微
镜观察合金等温结晶形态并测量力学性能，最后对三体系力学性能进行对
比。
PP/PA6 是典型的不相容体系，加入两种反应增容剂后相容性改善且
EPDM-g-GMA 增容效果较好；PP 球晶尺寸随 PA6 含量增加而减小，PA6
相分布在 PP 球晶之间，加入 PP-g-MAH 或 EPDM-g-GMA 后相容性改善；
PP/PA6 中加入 EPDM-g-GMA 后起到反应增容和橡胶增韧的协同效应；
PP/PA6 中加入 PP-g-MAH 后杨氏模量提高，同时屈服强度高于未增容体
系。
PP/PET 也是典型的不相容体系，加入两种反应增容剂后相容性提高
且 EPDM-g-GMA 的效果较好； PP 球晶随 PET 的混入而明显减小，PET
相 分 散 在 球 晶 之 间 ， 加 入 EPDM-g-GMA 后 二 者 相 容 性 改 善 ，
PP/PET/EPDM-g-GMA 中加入成核剂后对 PET 结晶有细化作用；PP/PET
体系中加入 EPDM-g-GMA 起到反应增容和橡胶增韧的协同效应，进一步
加入的成核剂有利于增韧；PP/PET 体系中加入 PP-g-MAH 后模量提高；
PP/PET 中加入 PP-g-MAH 后屈服强度缓慢下降。
当共混时间达到 10~15 分钟时，环氧树脂可能凝胶化使扭矩曲线升高，
之后进入固化阶段； PP 中加入环氧树脂后，交联阻碍结晶，使 PP 球晶
尺寸变小、变模糊；PP 中加入环氧树脂后亲水性提高，熔体流动性下降；
随 E-51 含量的增加，未增容体系的模量提高，屈服强度下降，韧性下降，
加入 PP-g-MAH 后，模量进一步提高，屈服强度缓慢上升，韧性改善。
力 学 性 能 对 比 表 明 ： PP/PA6/EPDM-g-GMA 体 系 的 韧 性 最 好 ，
PP/PET/PP-g- MAH 体系刚性最大，PP/E-51/203#/PP-g-MAH 体系的屈服强
度最高。
The mechanical properties of polypropylene were improved by
reactive blending with a few nylon6, polyethylene terephthalate, epoxy
and compatibilizer.
The morphology of PP/PA6 blends and PP/PET blends were
analysized by ESEM and image processing software. The crosslink action
of epoxy in PP melt was studied in torque rheometer. The melt flow index
and dynamic contact angle of PP/EPOXY blends in water were measured.
The isothermal crystalline state of PP/PA6 blends, PP/ PET blends and
PP/EPOXY blends were observed by polarizing microscope and their
mechanical properties were also tested. At last, the mechanical properties
of the three systems were contrasted.
PP/PA6 is a typical immiscible system. The compatibility was
improved by adding two kinds of compatibilizer, and EPDM-g-GMA was
more efficient. The dimension of PP spherulites minished with PA6
content increasing. PA6 phase distributed among PP spherulites, and the
compatibility was improved by adding PP-g-MAH or EPDM-g-GMA. The
reactive compatibilization and rubber tougheness had cooperative
effectiveness on PP/PA6 blends, after adding EPDM-g-GMA. The Yang’s
modulus of PP/PA6 blends was improved after adding PP-g-MAH, at the
same time, the yield stress was higher than that of immiscible system.
PP/PET is also a typical immiscible system. The compatibility was
improved by adding two kinds of compatibilizer, and EPDM-g-GMA was
more efficient. The dimension of PP spherulites minished after PP had
blended with PET . PET phase distributed among PP spherulites, and the
compatibility was improved by adding EPDM-g-GMA. PET crystal phase
became finer after adding nucleating agent in PP/PET/EPDM-g-GMA
blends. The reactive compatibilization and rubber tougheness had
cooperative effectiveness on PP/PET blends, furthermore, nucleating
agent takes advantage in improving toughness. The Yang’s modulus of
PP/PET blends was improved after adding PP-g-MAH, at the same time,
the yield stress decrease slowly.
Epoxy was likely to begin gelationization, which lift torque curve in
10~15minute, and then Epoxy come into solidify period. After PP blends
with epoxy, the crystallization was baffled by crosslinking and the
dimension of PP spherulites become small and illegible, at the same time,
the hydrophilicity increase and the fluidity descend. The Yang’s modulus
of uncompatibile system increase while the yield stress and toughness
decrease. After adding PP-g-MAH, the Yang’s modulus of blend increase
more, and the yield stress increase slowly and toughness improve.
The results of mechanical properties contrasting show that
PP/PA6/EPDM-g-GMA system was toughest, PP/PET/PP-g-MAH system
was rigidest and PP/E-51/ 203#/PP-g-MAH system is best at yield stress.
引文
参考文献
1. 吴培熙，张留成，聚合物共混物，北京：中国轻工业出版社，1996
2. 张玉清，葛从辛， 聚丙烯合金的新发展，合成树脂及塑料，2000，
17（3）: 49～52
3. 钟明强，刘俊华，胡华峰,等，聚丙烯共混改性研究进展，中国塑料，
1999，13（9）: 9～19
4. 张增民， 聚丙烯的高性能技术及应用开发方向，塑料，1993，22（2）:
42～43
5. 李忠明，扬明波，聚烯烃工程化研究现状（续），四川化工，1996，
4: 35～38
6. 徐光景，聚丙烯共混改性影响因素初探，塑料，1998，27(6): 27～32
7. 童筱芳，张增民， 聚丙烯/高密度聚乙烯共混体系的结晶形态，塑料，
1989，18（2）: 11～18
8. 钱冀清，李光杰， 聚丙烯接枝共聚物增大聚丙烯共混体系相容性研
究，中国塑料，1989，3（1）: 9～14
9. 晋日呀，王培霞，聚丙烯改性研究进展，中国塑料，2001，15(2): 20～
23
10.封朴，聚合物合金，上海：同济大学出版社，1997
11.魏京华， 聚丙烯共混增韧研究进展,合成树脂及塑料，2002，19(2): 47～51
12.张增民，吕荣侠.PP/HDPE/弹性体三元共混体系力学性能，形态及结
构，塑料工业，1989，1: 31～38
13.段予忠，塑料改性，北京：科技文献出版社，1987
14.赵劲松，王俊，聚丙烯复合材料的性能与形态，塑料，1990，11（3）:
3～9
15.吴培熙，张留成，聚合物共混改性原理及工艺，北京：中国轻工业出
版社，1984
16.Wei G X, Sue H J, Chu J, et al. Toughening and strengthening of
polypropylene using the rigid-rigid polymer toughening concept Part
Ⅰ.Morphology and mechanical property investigations , Polymer, 2000,
41(8): 2947～2960
94
参考文献
17.Wei G X, Sue H J. Toughening and strengthening of polypropylene using
the rigid-rigid polymer toughening concept Part Ⅱ , Toughening
mechanisms investigations, Journal of Materials Science, 2000, 35(3):
555～566
18.Kwan H Y, Lee H W , Park O K, et al. Properties of poly(ethylene
terephthalate) and maleic anthydride-grafted polypropylene blends by
reactive processing, Journal of Applied Polymer Science, 1998, 70(2):
389～395
19.Pang Y X, Jia D M, Hu H J, et al. Effects of a compatibilizing agent on
the morphology, interface and mechanical behavior of polyproylene/
poly(ethylene terephthalate) blends, Polymer, 2000, 41(1): 357～365
20.Song M, Pang Y. Correlation among morphology, interface and mech-
anical properties experimental study, Journal of macromolecules science
physics, 2001, vol B 40(6): 1153-1167
21.Champange M F，Huneault M A, Roux C, et al. Reactive compatibili-
zation of polypropylene/polyethylene terephthalate blends, Polymer
Engineering and Science, 1999, 39(6): 976～984
22.Heino M, Kirjava J, Hietaoja P, et al. Compatibilization of polyethylene
terephthalate/polypropylene blends with styrene-ethylene/butylene-
styrene (SEBS) block copolymers, Journal of Applied Polymer Science,
1997, 65(2): 241～249
23.Tseng F P, Lin J J, Tseng C R, et al. Poly(oxypropylene)-amide grafted
polypropylene as novel compatibilizer for PP and PA6 blends, Polymer,
2001, 42(2): 713～725
24.Jannerfekdt G ， Boogh L, Manson J A E. The morphology of
hyperbranced polymer compatibilized polypropylene/polyamide6 blends,
Polymer Engineering and Science 2001, 41(2): 293～300
25.Janerfekdt G, Boogh L, Manson J A E. Tailored interfacial properties for
immiscible polymers by hyperbranced polymers Polymer, 2000, 41
(21): 7627～7634
26.Gonzalez-Montiel A, Keskkula H, Paul D R. Impact-modified nylon6/
polypropylene blends: Morphology-property relationships, Polymer,
1995, 36 (23): 4587～6305
27.Wilkinson A N, Laugel L, Clemens M L, et al. Phase structure in
polypropylene/ PA6/SEBS blends, Polymer, 1999, 40(17): 4971～4975
95
参考文献
28.Gupta A K ,Tain A K .Study on binary and ternary blends of
polypropylene with ABS and LDPE, ⅡImpact and tensile properties,
Journal of Applied Polymer Science, 1990, 39(3): 515～530
29.Pate A C, Brahmb H, Sarawade R B, et al. Mophological and mechanical
properties of PP/ABS blends compalibilized with PP-g-acrylic，Journal
of Applied Polymer Science, 2001, 81(7): 1731～1741
30.周明义，ABS/改性 PP 共混物形态与冲击性能，工程塑料应用, 2000,
28(10): 29～32
31.Souza A M C，Demarquette N R. Influence of coalescence and interfacial
on the mophology of PP/HDPE compatibilized blends, Polymer, 2002,
43(7): 3959～3967
32.Schürman B L, Nieberqall U, Swverin N, et al. Polyethylene(PEHD)
/poly propylene(iPP) blends: mechanical properties, structure and
morphology, Polymer, 1998, 39(22): 5283～5291
33.汪晓东,励杭泉，分子量对 PP/UHMWPE 合金力学性能，形态和流变
性能的影响，高分子材料科学与工程，1996，12(3)：54～60
34.杨军，李炳海， UHMWPE 改性 PP 的结晶行为和亚微观形态研究，
塑料，1998,27(4)：32～36
35.KeJun Wang, zhou chixing. The effects of melt vibration blending on the
subsequent crystallization and melting behavior of polypropylene/ultra
high molecular weight polyethylene , Polymer Engineering and Science,
2001, 41（12）: 2249～2258
36.杨军，李炳海， PP/UHMWPE 原为成纤复合材料的混炼及成形工艺
研究，中国塑料, 1999, 13（11）: 34～38
37.Zhang M L, Liu Y G, Zhang X H, et al. The effect of elastomeric
nano[hyphen] particles on the mechanical properties and crystallization
behaviour of poly propylene, Polymer, 2002, 43(19): 5133～5142
38.Da Silva Ana lucia N, Rocha Marisa C G, Fdrnada C, et al. Evaluation of
rheological and mechanical behavior of blends based on polypropylene
and metallocene elastomers, Polymer Testing, 2002, 21(6): 647～652
39.Mcnally T, MCSHANE P, MALLY G M, et al. Rheology , phase
morphology, me- chanical, impact and thermal properties of
polypropylene/metallocene catalysed ethylene 1-octene copolymer
blends, Polymer, 2002, 43(13): 3785～3793
96
参考文献
40.Zhang H J, Wang J W, Li J, et al. Toughened polypropylene with
balanced rigidity III Compositions and mechanical properties, Journal of
Applied Polymer Science, 2001, 79(8): 1345～1350
41.Lustiger A, Marzinsky C N ,Mueller R R. Spherulite boundary
strengthening concept for toughening polypropylene, Journal of Polymer
Science Part B: Polymer physics, 1998 , 36(11): 2047～2056
42.吕彦梅，唐华杰，侯馨，刚性增韧材料 塑料科技，1999，1: 33～37
43.杨军忠，周春怀，王延伟，PP/PS/SEBS 三元共混物的研究,中国塑料,
2000, 14(11): 32～37
44.周春怀，杨军忠，王延伟，高刚性、高韧性、高流动性聚丙烯的研制,
工程塑料应用，2001，29（3）: 8～11
45.闫瑞萍，梁善杰，PP/HDPE/EPDM 三元共混材料微观结构及增韧机理
分析, 工程塑料应用,1994,22(3): 31～34.
46.Srinivasa K R , Gupta A K. Mechanical properties and morphology of
PP/SEBS/PC blends, Journal of Applied Polymer Science, 1996, 53(1):
1～9
47.刘平安，李笃信，贾德民等，聚丙烯/尼龙 6 共混物的 X 射线衍射研
究，高分子材料科学与工程，2000，16（6）: 83～85
48.凌绳，王秀芬，吴友平，聚合物材料，北京：中国轻工业出版社,2000
49.刘长生，王琪， 尼龙 6/聚丙烯共混改性研究，湖北化工，2001，3: 1～
3
50.谢续明，陈年欢，李松， 尼龙 6/多单体接枝聚丙烯共混物的形态结
构及力学性能的研究，高分子学报, 1999，5: 527～533
51.张丁浩，聚丙烯/尼龙 1010 体系共混过程中的在线分析及其结构与性能研究：
[硕士学位论文]，天津；天津大学，2001
52.杨石海，聚乙烯/尼龙 1010 体系共混过程中的在线分析及相结构研究：
[硕士学位论文]，天津；天津大学，2003
53.Rudol phD. Deanin, Aldo M. Crugnola Toughness and Brittleness, 1976, chap: 23
54.崔丽莉，多相聚合物形成过程中的相结构与性能研究：[硕士学位论
文]，天津；天津大学，2001
55.李锦春，愈强，林明德等， 热致性液晶共聚酯/聚丙烯共混物，工程
塑料应用，1997，25（5）: 1～4
56.张宏放，陈玉， 热致性液晶乙基纤维素和聚丙烯共混物的结构与性
能，应用化学，1993，10（6）: 35～38
97
参考文献
57.塑料用聚合物（修订版），天津：天津轻工业学院化工系，1993
58.环氧树脂与环氧化合物, 天津：天津人民出版社, 1974
59.高分子物理实验，天津：天津大学材料科学与工程学院高分子材料教
研室， 1996
60.吴 S.，高聚物的界面与粘合，北京：纺织工业出版社，1987
61.施来顺，曹晓新.等离子体改性聚合物表面动力学的动态接触角分析，
山东工业大学学报,2000,30（2）: 120～126
62.潘加宇，董建华，邓卓，等.苯乙烯/甲基丙烯酸和苯乙烯/甲基丙烯酸
（β-羟丙酯）嵌段共聚物的表面动态行为，高分子学报，1999,3: 297～
299
1. 吴培熙，张留成，聚合物共混物，北京：中国轻工业出版社，1996
2. 张玉清，葛从辛， 聚丙烯合金的新发展，合成树脂及塑料，2000，
17（3）: 49～52
3. 钟明强，刘俊华，胡华峰,等，聚丙烯共混改性研究进展，中国塑料，
1999，13（9）: 9～19
4. 张增民， 聚丙烯的高性能技术及应用开发方向，塑料，1993，22（2）:
42～43
5. 李忠明，扬明波，聚烯烃工程化研究现状（续），四川化工，1996，
4: 35～38
6. 徐光景，聚丙烯共混改性影响因素初探，塑料，1998，27(6): 27～32
7. 童筱芳，张增民， 聚丙烯/高密度聚乙烯共混体系的结晶形态，塑料，
1989，18（2）: 11～18
8. 钱冀清，李光杰， 聚丙烯接枝共聚物增大聚丙烯共混体系相容性研
究，中国塑料，1989，3（1）: 9～14
9. 晋日呀，王培霞，聚丙烯改性研究进展，中国塑料，2001，15(2): 20～
23
10.封朴，聚合物合金，上海：同济大学出版社，1997
11.魏京华， 聚丙烯共混增韧研究进展,合成树脂及塑料，2002，19(2): 47～51
12.张增民，吕荣侠.PP/HDPE/弹性体三元共混体系力学性能，形态及结
构，塑料工业，1989，1: 31～38
13.段予忠，塑料改性，北京：科技文献出版社，1987
14.赵劲松，王俊，聚丙烯复合材料的性能与形态，塑料，1990，11（3）:
3～9
15.吴培熙，张留成，聚合物共混改性原理及工艺，北京：中国轻工业出
版社，1984
16.Wei G X, Sue H J, Chu J, et al. Toughening and strengthening of
polypropylene using the rigid-rigid polymer toughening concept Part
Ⅰ.Morphology and mechanical property investigations , Polymer, 2000,
41(8): 2947～2960
94
参考文献
17.Wei G X, Sue H J. Toughening and strengthening of polypropylene using
the rigid-rigid polymer toughening concept Part Ⅱ , Toughening
mechanisms investigations, Journal of Materials Science, 2000, 35(3):
555～566
18.Kwan H Y, Lee H W , Park O K, et al. Properties of poly(ethylene
terephthalate) and maleic anthydride-grafted polypropylene blends by
reactive processing, Journal of Applied Polymer Science, 1998, 70(2):
389～395
19.Pang Y X, Jia D M, Hu H J, et al. Effects of a compatibilizing agent on
the morphology, interface and mechanical behavior of polyproylene/
poly(ethylene terephthalate) blends, Polymer, 2000, 41(1): 357～365
20.Song M, Pang Y. Correlation among morphology, interface and mech-
anical properties experimental study, Journal of macromolecules science
physics, 2001, vol B 40(6): 1153-1167
21.Champange M F，Huneault M A, Roux C, et al. Reactive compatibili-
zation of polypropylene/polyethylene terephthalate blends, Polymer
Engineering and Science, 1999, 39(6): 976～984
22.Heino M, Kirjava J, Hietaoja P, et al. Compatibilization of polyethylene
terephthalate/polypropylene blends with styrene-ethylene/butylene-
styrene (SEBS) block copolymers, Journal of Applied Polymer Science,
1997, 65(2): 241～249
23.Tseng F P, Lin J J, Tseng C R, et al. Poly(oxypropylene)-amide grafted
polypropylene as novel compatibilizer for PP and PA6 blends, Polymer,
2001, 42(2): 713～725
24.Jannerfekdt G ， Boogh L, Manson J A E. The morphology of
hyperbranced polymer compatibilized polypropylene/polyamide6 blends,
Polymer Engineering and Science 2001, 41(2): 293～300
25.Janerfekdt G, Boogh L, Manson J A E. Tailored interfacial properties for
immiscible polymers by hyperbranced polymers Polymer, 2000, 41
(21): 7627～7634
26.Gonzalez-Montiel A, Keskkula H, Paul D R. Impact-modified nylon6/
polypropylene blends: Morphology-property relationships, Polymer,
1995, 36 (23): 4587～6305
27.Wilkinson A N, Laugel L, Clemens M L, et al. Phase structure in
polypropylene/ PA6/SEBS blends, Polymer, 1999, 40(17): 4971～4975
95
参考文献
28.Gupta A K ,Tain A K .Study on binary and ternary blends of
polypropylene with ABS and LDPE, ⅡImpact and tensile properties,
Journal of Applied Polymer Science, 1990, 39(3): 515～530
29.Pate A C, Brahmb H, Sarawade R B, et al. Mophological and mechanical
properties of PP/ABS blends compalibilized with PP-g-acrylic，Journal
of Applied Polymer Science, 2001, 81(7): 1731～1741
30.周明义，ABS/改性 PP 共混物形态与冲击性能，工程塑料应用, 2000,
28(10): 29～32
31.Souza A M C，Demarquette N R. Influence of coalescence and interfacial
on the mophology of PP/HDPE compatibilized blends, Polymer, 2002,
43(7): 3959～3967
32.Schürman B L, Nieberqall U, Swverin N, et al. Polyethylene(PEHD)
/poly propylene(iPP) blends: mechanical properties, structure and
morphology, Polymer, 1998, 39(22): 5283～5291
33.汪晓东,励杭泉，分子量对 PP/UHMWPE 合金力学性能，形态和流变
性能的影响，高分子材料科学与工程，1996，12(3)：54～60
34.杨军，李炳海， UHMWPE 改性 PP 的结晶行为和亚微观形态研究，
塑料，1998,27(4)：32～36
35.KeJun Wang, zhou chixing. The effects of melt vibration blending on the
subsequent crystallization and melting behavior of polypropylene/ultra
high molecular weight polyethylene , Polymer Engineering and Science,
2001, 41（12）: 2249～2258
36.杨军，李炳海， PP/UHMWPE 原为成纤复合材料的混炼及成形工艺
研究，中国塑料, 1999, 13（11）: 34～38
37.Zhang M L, Liu Y G, Zhang X H, et al. The effect of elastomeric
nano[hyphen] particles on the mechanical properties and crystallization
behaviour of poly propylene, Polymer, 2002, 43(19): 5133～5142
38.Da Silva Ana lucia N, Rocha Marisa C G, Fdrnada C, et al. Evaluation of
rheological and mechanical behavior of blends based on polypropylene
and metallocene elastomers, Polymer Testing, 2002, 21(6): 647～652
39.Mcnally T, MCSHANE P, MALLY G M, et al. Rheology , phase
morphology, me- chanical, impact and thermal properties of
polypropylene/metallocene catalysed ethylene 1-octene copolymer
blends, Polymer, 2002, 43(13): 3785～3793
96
参考文献
40.Zhang H J, Wang J W, Li J, et al. Toughened polypropylene with
balanced rigidity III Compositions and mechanical properties, Journal of
Applied Polymer Science, 2001, 79(8): 1345～1350
41.Lustiger A, Marzinsky C N ,Mueller R R. Spherulite boundary
strengthening concept for toughening polypropylene, Journal of Polymer
Science Part B: Polymer physics, 1998 , 36(11): 2047～2056
42.吕彦梅，唐华杰，侯馨，刚性增韧材料 塑料科技，1999，1: 33～37
43.杨军忠，周春怀，王延伟，PP/PS/SEBS 三元共混物的研究,中国塑料,
2000, 14(11): 32～37
44.周春怀，杨军忠，王延伟，高刚性、高韧性、高流动性聚丙烯的研制,
工程塑料应用，2001，29（3）: 8～11
45.闫瑞萍，梁善杰，PP/HDPE/EPDM 三元共混材料微观结构及增韧机理
分析, 工程塑料应用,1994,22(3): 31～34.
46.Srinivasa K R , Gupta A K. Mechanical properties and morphology of
PP/SEBS/PC blends, Journal of Applied Polymer Science, 1996, 53(1):
1～9
47.刘平安，李笃信，贾德民等，聚丙烯/尼龙 6 共混物的 X 射线衍射研
究，高分子材料科学与工程，2000，16（6）: 83～85
48.凌绳，王秀芬，吴友平，聚合物材料，北京：中国轻工业出版社,2000
49.刘长生，王琪， 尼龙 6/聚丙烯共混改性研究，湖北化工，2001，3: 1～
3
50.谢续明，陈年欢，李松， 尼龙 6/多单体接枝聚丙烯共混物的形态结
构及力学性能的研究，高分子学报, 1999，5: 527～533
51.张丁浩，聚丙烯/尼龙 1010 体系共混过程中的在线分析及其结构与性能研究：
[硕士学位论文]，天津；天津大学，2001
52.杨石海，聚乙烯/尼龙 1010 体系共混过程中的在线分析及相结构研究：
[硕士学位论文]，天津；天津大学，2003
53.Rudol phD. Deanin, Aldo M. Crugnola Toughness and Brittleness, 1976, chap: 23
54.崔丽莉，多相聚合物形成过程中的相结构与性能研究：[硕士学位论
文]，天津；天津大学，2001
55.李锦春，愈强，林明德等， 热致性液晶共聚酯/聚丙烯共混物，工程
塑料应用，1997，25（5）: 1～4
56.张宏放，陈玉， 热致性液晶乙基纤维素和聚丙烯共混物的结构与性
能，应用化学，1993，10（6）: 35～38
97
参考文献
57.塑料用聚合物（修订版），天津：天津轻工业学院化工系，1993
58.环氧树脂与环氧化合物, 天津：天津人民出版社, 1974
59.高分子物理实验，天津：天津大学材料科学与工程学院高分子材料教
研室， 1996
60.吴 S.，高聚物的界面与粘合，北京：纺织工业出版社，1987
61.施来顺，曹晓新.等离子体改性聚合物表面动力学的动态接触角分析，
山东工业大学学报,2000,30（2）: 120～126
62.潘加宇，董建华，邓卓，等.苯乙烯/甲基丙烯酸和苯乙烯/甲基丙烯酸
（β-羟丙酯）嵌段共聚物的表面动态行为，高分子学报，1999,3: 297～
299