三聚氰胺和亚硝酸盐卫生检验新方法研究
|
摘要
三聚氰胺和亚硝酸盐都是含氮物质,是重要的卫生检测项目。三聚氰胺是广泛使用的化工原料,可诱发肾衰竭而导致死亡,禁止用于食品和动物饲料中。但由于三聚氰胺含氮量高达66%,高出氨基酸的3～4倍,近年来有人向奶粉中违规添加三聚氰胺,虚假提高蛋白质含量,对人体健康构成重大威胁,三聚氰胺事件向社会提出了卫生检验新任务。因此,研究、建立三聚氰胺新的卫生检测方法具有现实意义。亚硝酸盐广泛存在于人们赖以生存的环境当中,在体内亚硝酸根可转化形成强致癌物质N-亚硝胺。本文进行了三聚氰胺和亚硝酸盐的卫生检测新方法研究。
第一章:分别概述了三聚氰胺和亚硝酸盐卫生检验技术的发展趋势和研究进展;提出了几种卫生检测新方法研究工作的新思维。
第二章:应用荧光光谱、共振散射光谱方法研究了三聚氰胺–乙醇之间的相互作用。①应用荧光光谱法初步探讨了三聚氰胺对乙醇荧光的猝灭机理,根据不同温度下的热力学常数确定了三聚氰胺与乙醇之间的作用力类型;②首先应用共振散射光谱研究了三聚氰胺与乙醇的反应机理;在荧光猝灭理论分析基础上,首次应用共振散射光方法分析了荧光猝灭的作用力类型;两者对比研究结果一致。
第三章:应用荧光光谱技术,建立了三聚氰胺的卫生检验新方法。①在pH3.3 BR缓冲溶液中,三聚氰胺与甲醛、安息香缔合,使体系的荧光强度增强,建立了一种荧光光谱法水相测定三聚氰胺的新方法。在8.0×10~(-8)～2.4×10~(-5) mol/L范围内,体系荧光强度改变值(ΔF)与三聚氰胺的浓度呈现良好的线性关系,线性回归方程为ΔF=68.9c - 0.381(r = 0.9998),检出限为2.4×10~(-8) mol/L。方法用于乳制品中三聚氰胺的测定,样品加标回收率为95.7%～110.0%,RSD=2.5%～4.1%,结果满意。②在水介质中,三聚氰胺与荧光素钠缔合,使体系的荧光强度增强;应用酸效应对型体分布的影响,研究了反应机理;建立了荧光光谱法水相测定三聚氰胺的新方法。在4.8×10~(-3)～90.0μg/mL、1.6×10~(-2)～280.0μg/mL范围内,体系荧光强度改变值(ΔF)与三聚氰胺的浓度分别呈现良好的线性关系,线性回归方程分别为ΔF=2660.3ρ+ 36.67(r = 0.9992)、ΔF=768.92ρ+ 160.66(r =0.9996),检出限分别为1.4、5.0 ng/mL。文中研究了反应产物的光谱特征和适宜的反应条件;方法简便、快速、准确实用。
第四章:应用荧光光谱法研究了检测亚硝酸根新方法,首次研究了抗癌物质大蒜素(DADS)对其反应的抑制机理。在硫酸介质中,应用致癌物质NO_2~-与吖啶红(AR)发生亚硝化反应,导致体系荧光猝灭;加入大蒜素抑制亚硝化反应,降低了体系荧光猝灭。首次建立了亚硝酸根的同步荧光、三维荧光和共振荧光几种检测新方法;与直接荧光法相比,新方法具有灵敏度更高、检出限更低、线性范围更宽等优点。应用DADS阻抑AR-NO_2~-体系荧光猝灭结果,阐述了阻抑原理,为研究DADS的抗癌作用提供了新的研究方法和理论依据。
Melamine and nitrite are all the matter containing nitrogen element, and the important hygienic detection items at present. The former is used mainly as chemical industry material. It does not be permit to used as food additives and feedingstuff even now because its level of nitrogen (66% by mass, m:m) is higher more than the amino acids by 3-4 times, resulting in the failure of kidney and death. But melamine was illegally used in recent years due to that it can increase the protein content falsely, and threatening greatly to the health. Therefore, it is practical importance to study methods of hygienic detection of melamine. While the widely existed nitrite could be turned to N-nitrosamine in the human body, which is strong carcinogen. It was scientific researches on new methods of the hygienic detection of melamine and nitrite in this paper.
Part 1, the headways trend and research statuses were summarized briefly about melamine and nitrite respectively. The novel ideas on the health laboratory technologies for melamine and nitrite in scientific researches were developed.
Part 2, the interactions of melamine with ethanol were reviewed by the fluorescence spectroscopy method and one by Resonance Scattering Spectroscopy(RSS) in aqueous solution.①The fluorescence quenching mechanism of ethanol was investigated after adding melamine, and apparent binding constant K was measured by spectrofluorometric method. Thermodynamic parameters obtained from measured data at different temperatures showed the binding force of melamine and ethanol.②The binding between melamine and ethanol had been investigated by RSS. The effort types of fluorescence quenching mechanism were analyzed firstly by RSS on the basis of the fluorescence quenching mechanism theory. Results were consistent with each other.
Part 3, novel spectrofluorometric methods were developed for the determination of melamine.①A novel spectrofluorometric method was proposed based on the formation of ion-association complex between melamine and formaldehyde and benzoinum in pH3.3 Britton-Robinson (BR) buffer solution, resulting in the enhancement of fluorescence intensity. It was found that the enhanced intensity was propotional to the concentration of melamine in the range of 8.0×10~(-8)～2.4×10~(-5) mol/L, linear regression equation wasΔF=68.9c - 0.381(r = 0.9998) with the detection limit of 2.4×10~(-8) mol/L. The average recoveries were 95.7%～110.0% with relative standard deviation(RSD) of 2.5%～4.1%. Satisfactory results were obtained for the determination of melamine in dairy sample.②The other one was proposed in the water phase based on fluorescence intensity enhancement after fluorescein sodium forms ion-association complex with melamine. The reaction mechanism studied applying the influence of the acid effect on the species distribution. It was found that the enhanced intensity was propotional to the concentration of melamine in the range of 4.8×10~(-3)～90.0μg/mL and 1.6×10~(-2)～280.0μg/mL respectively, linear regression equation wereΔF=2660.3ρ+ 36.67(r=0.9992),ΔF=768.92ρ+ 160.66(r =0.9996)with the detection limits of 1.4 ng/mL, 5.0 ng/mL respectively. The optimum conditions of spectrofluorometric methods were investigated. It showed that the method was fast, convenient and accurate.
Part 4, two topics were studied on the determination of NO_2~- and inhibiting mechanism of diallyl disulfide(DADS) based on spectrofluorometric method. The nitrosation reaction of NO_2~- (carcinogen) and acridine red (AR) could make the system of fluorescence intensity decreased, while DADS could inhibit part of nitrosation reaction and quenching of the system of fluorescence in the sulphuric acid medium. Novel spectrofluorometric methods were constructed to assay NO_2~- by synchronous fluorescence, three-dimensional fluorescence, resonance fluorescence firstly in this paper. Compared with the direct fluorescent method, the new ones had higher sensitivity, lower detection limit and larger detection range and so on. Principal of the repression was expounded by applying with the results of fluorescence quenching of the system of AR-NO_2~-, then novel methods and theory evidence was supplied for studying the antitumous effect of DADS.
第一章:分别概述了三聚氰胺和亚硝酸盐卫生检验技术的发展趋势和研究进展;提出了几种卫生检测新方法研究工作的新思维。
第二章:应用荧光光谱、共振散射光谱方法研究了三聚氰胺–乙醇之间的相互作用。①应用荧光光谱法初步探讨了三聚氰胺对乙醇荧光的猝灭机理,根据不同温度下的热力学常数确定了三聚氰胺与乙醇之间的作用力类型;②首先应用共振散射光谱研究了三聚氰胺与乙醇的反应机理;在荧光猝灭理论分析基础上,首次应用共振散射光方法分析了荧光猝灭的作用力类型;两者对比研究结果一致。
第三章:应用荧光光谱技术,建立了三聚氰胺的卫生检验新方法。①在pH3.3 BR缓冲溶液中,三聚氰胺与甲醛、安息香缔合,使体系的荧光强度增强,建立了一种荧光光谱法水相测定三聚氰胺的新方法。在8.0×10~(-8)～2.4×10~(-5) mol/L范围内,体系荧光强度改变值(ΔF)与三聚氰胺的浓度呈现良好的线性关系,线性回归方程为ΔF=68.9c - 0.381(r = 0.9998),检出限为2.4×10~(-8) mol/L。方法用于乳制品中三聚氰胺的测定,样品加标回收率为95.7%～110.0%,RSD=2.5%～4.1%,结果满意。②在水介质中,三聚氰胺与荧光素钠缔合,使体系的荧光强度增强;应用酸效应对型体分布的影响,研究了反应机理;建立了荧光光谱法水相测定三聚氰胺的新方法。在4.8×10~(-3)～90.0μg/mL、1.6×10~(-2)～280.0μg/mL范围内,体系荧光强度改变值(ΔF)与三聚氰胺的浓度分别呈现良好的线性关系,线性回归方程分别为ΔF=2660.3ρ+ 36.67(r = 0.9992)、ΔF=768.92ρ+ 160.66(r =0.9996),检出限分别为1.4、5.0 ng/mL。文中研究了反应产物的光谱特征和适宜的反应条件;方法简便、快速、准确实用。
第四章:应用荧光光谱法研究了检测亚硝酸根新方法,首次研究了抗癌物质大蒜素(DADS)对其反应的抑制机理。在硫酸介质中,应用致癌物质NO_2~-与吖啶红(AR)发生亚硝化反应,导致体系荧光猝灭;加入大蒜素抑制亚硝化反应,降低了体系荧光猝灭。首次建立了亚硝酸根的同步荧光、三维荧光和共振荧光几种检测新方法;与直接荧光法相比,新方法具有灵敏度更高、检出限更低、线性范围更宽等优点。应用DADS阻抑AR-NO_2~-体系荧光猝灭结果,阐述了阻抑原理,为研究DADS的抗癌作用提供了新的研究方法和理论依据。
Melamine and nitrite are all the matter containing nitrogen element, and the important hygienic detection items at present. The former is used mainly as chemical industry material. It does not be permit to used as food additives and feedingstuff even now because its level of nitrogen (66% by mass, m:m) is higher more than the amino acids by 3-4 times, resulting in the failure of kidney and death. But melamine was illegally used in recent years due to that it can increase the protein content falsely, and threatening greatly to the health. Therefore, it is practical importance to study methods of hygienic detection of melamine. While the widely existed nitrite could be turned to N-nitrosamine in the human body, which is strong carcinogen. It was scientific researches on new methods of the hygienic detection of melamine and nitrite in this paper.
Part 1, the headways trend and research statuses were summarized briefly about melamine and nitrite respectively. The novel ideas on the health laboratory technologies for melamine and nitrite in scientific researches were developed.
Part 2, the interactions of melamine with ethanol were reviewed by the fluorescence spectroscopy method and one by Resonance Scattering Spectroscopy(RSS) in aqueous solution.①The fluorescence quenching mechanism of ethanol was investigated after adding melamine, and apparent binding constant K was measured by spectrofluorometric method. Thermodynamic parameters obtained from measured data at different temperatures showed the binding force of melamine and ethanol.②The binding between melamine and ethanol had been investigated by RSS. The effort types of fluorescence quenching mechanism were analyzed firstly by RSS on the basis of the fluorescence quenching mechanism theory. Results were consistent with each other.
Part 3, novel spectrofluorometric methods were developed for the determination of melamine.①A novel spectrofluorometric method was proposed based on the formation of ion-association complex between melamine and formaldehyde and benzoinum in pH3.3 Britton-Robinson (BR) buffer solution, resulting in the enhancement of fluorescence intensity. It was found that the enhanced intensity was propotional to the concentration of melamine in the range of 8.0×10~(-8)～2.4×10~(-5) mol/L, linear regression equation wasΔF=68.9c - 0.381(r = 0.9998) with the detection limit of 2.4×10~(-8) mol/L. The average recoveries were 95.7%～110.0% with relative standard deviation(RSD) of 2.5%～4.1%. Satisfactory results were obtained for the determination of melamine in dairy sample.②The other one was proposed in the water phase based on fluorescence intensity enhancement after fluorescein sodium forms ion-association complex with melamine. The reaction mechanism studied applying the influence of the acid effect on the species distribution. It was found that the enhanced intensity was propotional to the concentration of melamine in the range of 4.8×10~(-3)～90.0μg/mL and 1.6×10~(-2)～280.0μg/mL respectively, linear regression equation wereΔF=2660.3ρ+ 36.67(r=0.9992),ΔF=768.92ρ+ 160.66(r =0.9996)with the detection limits of 1.4 ng/mL, 5.0 ng/mL respectively. The optimum conditions of spectrofluorometric methods were investigated. It showed that the method was fast, convenient and accurate.
Part 4, two topics were studied on the determination of NO_2~- and inhibiting mechanism of diallyl disulfide(DADS) based on spectrofluorometric method. The nitrosation reaction of NO_2~- (carcinogen) and acridine red (AR) could make the system of fluorescence intensity decreased, while DADS could inhibit part of nitrosation reaction and quenching of the system of fluorescence in the sulphuric acid medium. Novel spectrofluorometric methods were constructed to assay NO_2~- by synchronous fluorescence, three-dimensional fluorescence, resonance fluorescence firstly in this paper. Compared with the direct fluorescent method, the new ones had higher sensitivity, lower detection limit and larger detection range and so on. Principal of the repression was expounded by applying with the results of fluorescence quenching of the system of AR-NO_2~-, then novel methods and theory evidence was supplied for studying the antitumous effect of DADS.
引文
[1]刘庆生,王加启.三聚氰胺在动物体内的毒性研究进展[J].化学研究, 2008, 35(10): 5-7.
[2]冯建民,秸俊红.中国三聚氰胺生产应用现状及产业技术分析[J].化工科技市场, 2006, 29(5): 11-16.
[3]汪家铭.我国三聚氰胺发展概况及市场前景[J].化工设计通讯, 2008, 34(2): 15-22.
[4]张俊燕,何吕兴.三聚氰胺的样品前处理及最新检测方法[J].生命科学仪器, 2007, (5): 57-59.
[5] Thomas R, Kulkarni G U. A hydrogen bonded channel structure formed by a complex of uracil and melamine[J]. Beilstein J Org Chem, 2007, 28: 3-17.
[6]王辉,董元华,安琼.环丙氨嗪的生物毒性与环境行为研究进展[J].农业工程学报, 2008, 24(1): 246-249.
[7] Burns K. Recall shines spotlight on pet foods[J]. J Am Vet Med Assoc, 2007, 230(9): 1285-1288.
[8]王征. GC-MS法测定动物食品中的三聚氰胺[J].福建分析测试, 2008, 17(2): 1-4.
[9] Thompson M E , Lewin-Smith M R , Kalasinsky V F, et al. Characterization of melamine-containing and calcium oxalate crystals in three dogs with suspected pet food-inducednephrotoxicosis[J]. Vet Pathol, 2008, 45: 417-426.
[10]冯家望,蔡勤仁,柳训才,等.高效液相色谱-电喷雾串联技术测定奶及奶制品中三聚氰胺和环丙氨嗪[J].现代食品科技, 2008, 24(10): 1058-1060.
[11] Okumara M, Hasegawa R, Shirai T, et al. Relationship between calculus formation and carcinogenesis in the urinary bladder of rats admistered the non-genotoxic agents thymine and melamine[J]. Carcinogenesis, 1992, 13(6): 1043-1045.
[12] Ogasawara H, Imaida K, Ishiwata H, et al. Urinary bladder carcinogenesis induced by melamine in F344 male rats: correlation between carcinogenicity and urolith formation[J]. Carcinogenesis, 1995, 16(11): 2773-2777.
[13] Ronald E B, Geof S, Sharon E. M, et a1. Pharmacokinetics of melamine in pigs following intravenous administration[J]. Food Chem. Toxicol., 2008, 46:1196-1200.
[14] Jennifer L.B, Ronald E.B, Jim E.R. Estimating meat with drawal times in pigs exposed to melamine contaminated feed using a physiologically based pharmaeokinetie model[J]. Regul. Toxicol. Pharm., 2008, 51: 324-331.
[15] Cathy A, Brown, Kyu-Shik J, et al. Outbreaks of renal failure associated with melamine and cyanuric acid in dogs and cats in 2004 and 2007[J]. J. Vet. Diagn. Investig., 2007, 19(5): 525-531.
[16]彭卫芳,凌志明,王学涛,等.亚硝酸盐测定方法研究进展[J].中国卫生检验杂志, 2007, 17(8): 1535-1536.
[17] Tsuda M, Hirayama T, Sugimura T. Presence of N-nitroso-L-thioproline and N-nitroso-L-methylthioproline in human urine as major N-nitroso compounds[J]. Jpn. J. Cancer Res. (Gann). 1983, 74(3): 331.
[18] Ohshima H, Friesen M, O’Neilll, et al. Presence in human urine of a new N-nitroso compound, N-nitrosothiazolidine 4-carboxylic acid[J]. Cacer Lett., 1983, 20(2): 183-190.
[19]王浩,刘艳琴,曹红,等.固相萃取与高效液相色谱联用测定宠物食品中三聚氰胺[J].分析化学, 2008, 36(2): 273.
[20]赵浩军,舒平.高效液相色谱法测定鸡蛋中三聚氰胺含量[J].大理学院学报, 2009, 8(4): 46-48.
[21]杨云霞,刘彤,周桂英,等.小麦谷元粉中三聚氰胺的高效液相色谱法测定[ J].分析测试学报, 2008, 27(3): 322-324.
[22] Filigenzi M S, Tor E R, Poppenga R H, et al. The determination of melamine in muscle tissue by liquid chromatography/tandem mass spectrometry[J]. Rapid Commun. Mass Spectrom, 2007, 21(24): 4027-4032.
[23] Andersen W C, Turnipseed S B, Karbiwnyk C M, et al. Detemination and confirmation of melamine residues in catfish, trout, tilapia, salmon and shrimp by liquid chromatography with tandem mass spectrometry[J]. J. AgricFood Chem, 2008, 56(12): 4340-4347.
[24]曹莹,张文刚,黄士新.高效液相色谱法分析饲料中的三聚氰胺[J].上海畜牧兽医通讯, 2007, (6): 47-48.
[25]王亚吨,林海丹,邓国东.反相高效液相色谱法测定饲料中三聚氰胺的含量[J].广东饲料, 2008, 17(3): 41-43.
[26]汪辉,曹小彦,彭新凯.高效液相色谱-二极管阵列法测定高蛋白食品中的三聚氰胺[J].食品与机械, 2007, 23(5):114-115.
[27]蒲云霞,刘丽珍,徐晓枫.反相离子对色谱法检测无水奶油中三聚氰胺方法的建立[J].中国卫生检验杂志, 2009, 19(1): 95-96.
[28]黄芳,黄晓兰,吴惠勤,等.高效液相色谱-质谱法对饲料及食品添加剂中三聚氰胺的测定[J].分析测试学报, 2008, 27(3): 313-315.
[29]丁涛,徐锦忠,李健忠,等.高效液相色谱-二极管阵列检测法及高效液相色谱-电喷雾串联质谱法测定植物源性蛋白中残留的三聚氰胺[J].色谱, 2008, 26(1): 6-9.
[30] James N K, William G. Screening for melamine adulteration in protein-based foods by GC/ MS, Gaschromatography/Mass spectrometry, 2007: 1-4. (www.perkinelmer.com)
[31] Thuy D T V, Markus H, Manuela H, et a1. Improved analysis of melamine- formaldehyde resins by capillary zone electrophoresis - mass spectrometry using ion - trap and quadrupole- time - of - flight mass spectrometers[J]. J. Chromatogr. A, 2008, 1213(1): 83-87.
[32] Schuiz W, Seitz W, Weber W H, et al. Detection of melamine in water[J]. Vom Wasser, 2007, 105(4): 18-22.
[33] Yoshida A Y, Murakami T, Takeda K, et al. Determination of melamine using LC-MS and applications to samples related to waste[J]. Kankyo Kagaku, 2006, 16(4): 635-641.
[34]化工部标准GB/T 9567-1997工业三聚氰胺.
[35]侯艳丽,张惠茹,刘来亭,等.三聚氰胺的检测方法[J].河南畜牧兽医综合版, 2007, 28(9): 32-33.
[36]陈江萍.食品中三聚氰胺的危害及其检测方法[J].中国农村小康科技, 2008, (11): 68-72.
[37]汪勇.升华法测定三聚氰胺纯度的局限[J].中氮肥, 2008, 2: 57-60.
[38] Garber E A. Detection of melamine using commercial enzyme-linked immunosorbent assay technology[J]. J Food Prot, 2008, 71(3): 590-594.
[39] Kim B, Perkins L B, Bushway R J, et al. Determination of melamine in pet food by enzyme immunoassay, high-performance liquid chromatography with diode array detection, and ultra-performance liquid chromatography with tandem mass spectrometry[J]. Jaoac Int, 2008, 91(2): 408-413.
[40]訾言勤,凌程凤.四波长负吸收催化光度法测定痕量亚硝酸根[J].分析化学, 2004, 32(8): 1039-1042.
[41]胡卫平,董学芝,何智娟.甲基紫电极催化动力学电位法测定亚硝酸根[J].分析化学, 2004, 32(6): 765-768.
[42]王洋,范世华.芯片式微型流通池顺序注射化学发光法测定水中的亚硝酸根[J].光谱学与光谱分析, 2005, 25(2): 184-187.
[43] Chao L, Jin M L, Carmen W, et al. Chemiluminescence study of carbonate and peroxynitrous acid and its application to the direct determination of nitrite based on solid surface enhancement[J]. Anal Chim Acta, 2004, (2): 29-34.
[44]周运友,佘世科,卢琴,等. N-(1-萘基)-乙二胺荧光光度法测定痕量亚硝酸根[J].光谱学与光谱分析, 2005, 25(8): 1318-1321.
[45] Salmon J, Mouren M, Baulieu E E. The antiprogestin steroid RU486 and human fertility control[M]. Plenum Press, New York, 1985. 99.
[46]李党生,李桂敏.碱性品红紫外光度法测定水中亚硝酸盐氮[J].环境工程, 2002, 20 (2): 61-63.
[47] Wang G F, Horita K, Satake M. Simultaneous spectrophotometric determination of nitrate and nitrite in water and some vegetable samples by column preconcentration[J]. Microchem. J., 1998, 58: 162-174.
[48] Kazemzadeh, Ensafi. Simultaneous determination of nitrite and nitrate in various samples using flow-injection spectrophotometric detection[J]. Microchemical J., 2001, 69: 159-166.
[49]赵新淮,林燕,张海霞.蔬菜中亚硝酸盐的光度测定[J].理化检验-化学分册, 2006, 42(2): 128-129.
[50]周之荣,王文敏,王黎.动力学光度法测定食品中痕量亚硝酸根[J].食品科技, 2005, 26(10): 181-183.
[51]方步武,靳珠华,林秀珍.测定血中亚硝酸盐的荧光分光光度法[J].中国应用生理学杂志, 2005, 21(2): 235-239.
[52] Huang K J, Wang H, Guo Y H, et al. Spectrofluorimetric determination of trace nitrite in food products with a new fluorescent probe 1,3,5,7- tetramethyl-2,6– dicarbethoxy - 8(3’,4’- diaminophenyl)– difluorobora– diazas - indacene[J]. Talanta, 2006, 69(1): 73-78.
[53] Li R, Yu J C, Jiang Z T, et al. A solid-phase fluorescent quenching method for the determination of traceamounts of nitrite in foods with neutral red[J]. J. Food Drug Anal, 2003, 11(3): 251-257.
[54] Mahgoub H. Spectrophotometric and fluorimetric determination of aztreonam in bulk and dosage forms[J]. J. Pharm. Biomed. Anal, 2003, 31(4): 767-774.
[55]孙媛媛.荧光光谱法在环境监测中的应用[J].环境监测管理与技术, 2000, 12(3): 12-16.
[56]刘峥,夏之宁.光谱法在分子间相互作用中的应用[J].激光杂志, 2001, 22(6): 9211-9218.
[57]姚文华.光分析仪的原理及其在生化工程上的应用[J].医药工程设计, 1991, 2: 39-42.
[58]何立芳,林丹丽,李耀群.同步荧光分析法的应用及其新进展[J].化学进展, 2004, 16 (6): 879-886.
[59]曾凡蓉,席水清,张淑青,等.荧光光度法测定环境水样中的苯酚和对苯二酚[J].分析试验室, 2007, 26(5): 76-79.
[60] Chen Z L, Liu Q L, Wang S Y, et al. Study on hemorrhagin III purified from the venom of agkistrodon acutus by three-dimensional fluorescence spectrometry[J]. Spectrochim .Acta. A, 1999, 55: 1909-1914.
[61]刘文涵,杨未.激光拉曼光谱内标法直接测定乙醇浓度[J].分析化学, 2007, 35(3): 416-418.
[62]彭勤纪,王壁人.波谱分析在精细化工中的应用[M].北京:中国石化出版社, 2001: 77-78.
[63] Liu Y, Peng C D, Ni X W, et al. Study on ethanol-water cluster types with steady state and time resolved fluorescence spectrometer[J]. Acta Phtonica Sini, 2007,36(9):1677-1682.
[64]刘莹,兰秀风,高淑梅,等. 253.7nm光辐照乙醇溶液荧光光谱分析[J].南京理工大学学报, 2003, 27(6): 720-723.
[65] Lakowicz J R. Principles of fluorescence spectroscopy(3rd Ed)[M]. Berlin: Springer, 2006: 277-283.
[66]许金钩,王尊本.荧光分析法[M].第三版.北京:科学出版社, 2006: 65-68.
[67] Ross P D, Subramanian S. Thermodynamics of protein association reactions: forces contributing to stability[J]. J. Biochem, 1981, 20(11): 3096-3102.
[68]孙雷,韩嘉媛,汪霞,等.三聚氰胺的毒性及残留检测方法研究进展[J].中国兽药杂志, 2008, 42(10): 37-39.
[69]吴惠勤,黄芳,林晓珊,等.气相色谱-质谱法测定奶粉及奶制品中的三聚氰胺[J].分析测试学报, 2008, 27(10): 1044-1048.
[70]周建科,张明翠,宋歌,等.高效液相色谱法测定鸭肉中的三聚氰胺[J].分析试验室, 2009, 28: 156-158.
[71]李爱军,张代辉,马书民,等.液相色谱-串联质谱法测定饲料中三聚氰胺残留[J].分析化学, 2008, 36(5):699-701.
[72]张勇,王淑红,朱亚先.同步荧光法检测鱼胆汁中的1-羟基芘[J].分析化学, 2002, 30(4): 467-469.
[73]孙衍增.荧光素钠荧光寿命的测定[J].分析化学, 2000, 28(11): 1413-1416.
[74]陈兰化,陈红旗.动力学荧光法测定痕量亚硝酸根的研究[J].淮北煤炭师范学院学报, 2004, 25(1): 21-23.
[75]刘秀萍,王洪芳.氯酸钾-灿烂甲酚蓝催化褪色光度法测定痕量亚硝酸根的研究[J].分析科学学报, 2008, 24(5): 606-608.
[76]司文会,訾言勤.多波长负吸收褪色光度法测定微量亚硝酸根及其反应机理[J].光谱学与光谱分析, 2005, 25(10): 1671-1673.
[77]吴湘江,刘狄,刘凤萍,等.催化溴酸钾氧化萘酚绿B褪色紫外光度法测定亚硝酸根[J].理化检验-化学分册, 2006, 42(1): 58-59.
[78]李贵荣,王永生,贺冬秀.催化共振光散射法测定痕量亚硝酸根[J].分析化学, 2005, 33(9): 1306-1304.
[79]王学锋,史选,皮运清.流动注射化学发光法测定水样中的痕量亚硝酸根[J].分析化学, 2005, 33(6): 865-868.
[80] Chao L, Jin M L, Carmen W, et al. Chemiluminescence study of carbonate and peroxynitrous acid and its application to the direct determination of nitrite based on solid surface enhancement[J]. Anal Chim Acta, 2004, (2): 29-34.
[81]唐学燕,陶冠军,秦昉.二阶导数-同步荧光法同时测定微量维生素B1, B2和烟酰胺[J].分析试验室, 2009, 28(10): 92-94.
[82]许金钩,王尊本.荧光分析法[M].北京:科学出版社, 2006, 137-140.
[83]高甲友.吖啶红荧光猝灭法测定痕量亚硝酸根[J].理化检验-化学分册, 2004, 40(1): 20-21.
[1]何立芳,林丹丽,李耀群.同步荧光分析法的应用及其新进展[J].化学进展, 2004, 16(6): 879-885.
[2]张先廷,赵惠玲,杜黎明.同步荧光光谱法测定人体尿液中加替沙星[J].分析科学学报, 2008, 24(3): 344-346.
[3] Lloyd J B F. Multicomponent analysis by synchronous luminescence spectrometry[J]. Nature, 1971, 231: 64-67.
[4]陈国珍,黄贤智,郑朱梓,等.荧光分析法[M].北京:科学出版社, 1990. 201-212.
[5]章汝平,陈克华,何立芳.大气飘尘中多环芳烃的超声波萃取-恒能量同步荧光法测定[J].分析测试学报, 2007, 26(6): 830-832.
[6]李耀群,黄贤智.固定能量同步发光光谱测定法[J].分析化学, 1989, 17(12): 1154-1158.
[7]吴晓红,高生平.同步荧光分析法的应用进展[J].光谱实验室, 2008, 25(4): 651-654.
[8]章汝平,郭健.恒能量同步荧光法测定食品中的多环芳烃[J].食品工业科技, 2007, 28(12): 198-200.
[9] Miller J N. Recent developments in fluorescence and chemilum- inescence analysis[J]. Analyst, 1984, 109: 191-198.
[10] Inman E L, Winefordner J D. Constant-energy synchronous fluorescence for re-duction of raman scatter interference[J]. Anal. Chim. Acta, 1982, 138: 245-252.
[11] Inman E L, Winefordner J D. Constant energy synchronous fluorescence for analysis of polycyclic aromatic hydrocarbon mixtures[J]. Anal. Chem, 1982, 54: 2018-2022.
[12] Inman E L, Files L A, Winefordner J D. Theoretical optimization of parameter selection in constant energy synchronous luminescence spectrometry[J]. Anal. Chem, 1986, 58: 2156-2160.
[13] Kerkhoff M J, Lee T M, Allen E R, et al. Spectral fingerprinting of polycyclic aromatic hydrocarbons in high-volume amibient air samples by constant energy synchronous lumicescecce spectroscopy[J]. Environ. Sci. Technol, 1985, 19: 695-699.
[14] Kerkhoff M J, Inman E L, Voigtman E, et al. Rapid scanning constant energy synchronous fluorescence spectrometry: acomparison of flow cells[J]. Appl. Spectrosc, 1984, 38(2): 239-245.
[15] Andre J C, Bouchy A, Jezequel J Y. Increased apparent sensitivity by means of constant-energy synchronous spectrofluorimetry[J]. Anal. Chim. Acta, 1986, 185(8): 91-99.
[16] Files L A, Jones B T, Hanamura S, et al. Gasoline-engine exhaust analysis using constant energy synchronous luminescence spectrometry[J]. Anal. Chem, 1986, 58(7): 1440-1443.
[17] Murillo, Pulgarin J A, Molina A A. Determination of nafcillin and methicillin by different spectrofluorimetric techniques[J]. Talanta. 2001, 41(1): 21-30.
[18] Murillo-Pulgarin J A, Molina A A. Matrix isopotential synchronous fluorescence direct determination of gentisic acid in urine[J]. Anal. Chim. Acta, 1994, 296(1): 87-97.
[19] Green G L, O′Haver T C. Derivative lumineecence spectroscopy[J]. Anal. Chem, 1974, 46: 2191-2196.
[20] Li Y Q, Sui W, Wu C, et al. Derivative matrix isopotential synchronous fluorescence spectroscopy for the direct determination of 1-hydroxypyrene as a urinary biomarker of exposure to polycyclic aromatic hydrocarbons[J]. Anal. Sci, 2001, 17(1): 167-170.
[21] Murillo-Pulgarin J A, Molina A A, López P F. Direct determination of amiloride in urine using isopotential fluorimetry[J]. Analyst, 1997, 122(3): 247-252.
[22] Murillo-Pulgarin J A, Molina A A. Direct determination of quinidine in urine[J]. Anal. Chim. Acta, 1995, 317(1-3): 359-364.
[23] Murillo-Pulgarin J A, Molina A A. Determination of Salicylic and gentisic acids in the presence of each other by matrix isopotential synchronous fluorescence spectrometry[J]. Analyst, 1994, 119: 1915-1919.
[24] Murillo-Pulgarin J A, Molina A A, López P F. Direct determination of triamterene in urine by matrix isopotential synchronous fluorescence spectrometry[J]. Anal. Chim. Acta, 1996, 326(1-3): 117-126.
[25] Nevado J J B, Murillo-Pulgarin J A, Laguna M A G. Determination of pyridoxamine in urine by matrix isopotential synchronous fluorescence spectrometry[J]. Analyst, 1995, 120(1): 171-174.
[26]眭蔚,吴春,李耀群,等.导数恒基体强度同步荧光分析法同时测定光谱严重重叠的1-氯蒽和9-溴蒽[J].分析化学, 2001, 29(3): 320-322.
[27] Hofstraat J W, Janser H J M, Hoornweg G P H, et al. Quantitative determination of polycyclic aromatic hydrocarbons in harbour sediment via high-resolution shpol'skii spectroscopy[J]. Intern. J. Environ. Anal. Chem, 1985, 21(4): 299-332.
[28]蒋淑艳.苯并[a]的同步荧光法测定条件研究[J].光谱学与光谱分析, 1997, 17(3): 115-118.
[29] Ferrer R, Beltran J L, Guiteras J. Multivariate calibration applied to synchronous fluorescence spectrometry. simultaneous determination of polycyclic aromatic hydrocarbons in water samples[J]. Talanta, 1998, 45(6): 1073-1080.
[30] Sanchez F G, Cruces C, Rubio A L R. Synchronously scanned derivative spectrofluorimetry: a new approach for the analysis of multicomponent fluorescent samples[J]. J. Mol. Struct, 1986, 143: 473-476.
[31] Sanchez F G, Rubio A L R, Blanco C C. Three-dimensional synchronous fluorescence spectrometry for the analysis of three-component alkaloid mixtures[J]. Talanta, 1990, 37(6): 579-584.
[32] Khakhel O A, Krykunova V E. Determination of dimers concentration of chromophores by the method of fluorescence synchronous scanning[J]. J. Luminescence, 1999, 81(1): 79-84.
[33] Dimitrios G K, Pinelopi C, Efstrations S. Simultaneous determination of naproxen and its desmethyl metabolite in human serum by second-derivative synchronous fluorescence spectrometry[J]. Anal. Chim. Acta, 1994, 290(1-2): 34-39.
[34] Stevenson C L, Vo-Dinh T. Analysis of polynuclear aromatic compounds using laser-excited synchronous fluorescence[J]. Anal. Chim. Acta, 1995, 303(2-3): 247-253.
[35] Munoz de la P A, Salinas F, Duran M S. Simultaneous determination of propranolol and hydralazine by derivative synchronous spectrofluorim- etry[J]. Anal. Chim. Acta, 1991, 255(2): 317-323.
[36] Reynolds D M. Rapid and direct determination of tryptophan in water using synchronous fluorescence spectroscopy[J]. Water Res, 2003, 37(13): 3055-3060.
[37] Kabbani M W, Rubio-Borroso S, Polo-Diez L M. Determination of traces of gallium in the presence of aluminium by synchronous derivative spectrofluorimetry[J]. Anal. Chim. Acta, 1989, 218: 167-171.
[38] Salinals F, Muoz de la P A, Capitan-Vellvey L F, et al. Simultaneous determination of molybdenum and tungsten by first-derivative synchronous spectrofluorimetry[J]. Analyst, 1989, 114: 1297-1301.
[39]陈慰宗,宋应谦,张振杰,等.食用油加热后荧光强度变化的实验研究[J].光子学报, 2000, 29(5): 478-480.
[40]陈健,孙爱东.同步荧光光谱在食品检测领域的应用[J].中国食物与营养, 2009, 10: 28-31.
[41] Miller J N. Recent developments in fluorescence and chemiluminescence analysis. Plenary Lecture[J]. Analyst, 1984, 109(3): 191-198.
[42] Clark B J, Fell A F, Miline K T. et al. Pharmaceutical applications of variable-angle synchronous scanning fluorescence spectroscopy[J]. Anal. Chim. Acta, 1985, 170(1): 35-44.
[43] Oms M T, Forteza R, Cerda V, et al. Simultaneous determination of two components by spectrofluorimetric techniques[J]. Anal. Chim. Acta, 1990, 233(1): 159-163.
[44] Sontag J M. Carcinogens in industry and the environment[M]. New York: ManelDekker Inc, 1981: 345-437.
[45] Neff J M. Polycyclic aromatic hydrocarbons in the aquatic environment, sources, fates and biological effects[M]. London: Applied Science Publishers, 1979: 262.
[46] Cabaniss S E, Shuman M S. Synchronous fluorescence spectra of natural waters: tracing sources of dissolved organic matter [J]. Mar. Chem, 1987, 21(1): 37-50.
[47] Lin D L, Zou Z X, He L F, et al. Rapid screening method for simultaneous determination of four polycyclic aromatic hydrocarbons in water samples by derivative non-linear variable-angle synchronous fluorescence spectrometry[J]. Luminescence, 2005, 20(4-5): 292-297.
[48]张勇,朱亚先等.同步荧光法检测芘的微生物降解[J].中国环境科学, 2002, 22(4): 289-292.
[49]李静红,于连生.同步荧光光谱同时分析苯并蒽和9,10-二甲基蒽[J].东北电力学院学报, 1995, 15(4): 63-67.
[50] Li Y Q, Huang X Z, Xu J G, et al. Derivative constant-energy synchronous fluorescence for simultaneous analysis of polynuclear aromatic hydrocarbon mixtures[J]. Anal. Chim. Acta, 1992, 256(2): 285-291.
[51]敖登高娃,张莹,樊海燕.同步-导数荧光光谱法测定混合样品中美他环素[J].光谱学与光谱分析, 2006, 26(8): 1530-1532.
[52] Li Y Q, Shi L, Qian F. Simultaneous determination fluorine, acenaphthene, anthracene and perylene by derivative constant energy synchronous fluorimetry[J]. Chem. J. Chinese Universities, 1997, 18(4): 538-540.
[53] Eiroa A A, Blanco E V, Machia P L. Resolution of benzo (a) pyrene in complex Mixtures of other polycyclic aromatic hydrocarbons. comparison of two spectrofluorimetric methods applied to water samples[J]. Analyst, 2000, 125(7): 1321-1326.
[54] Eiroa A A , Blanco E V, Machia P L. Determination of polycyclic aromatic hydrocarbons (PAHs) in a complex mixture by second-derivative constant-energy synchronous spectrofluorimetry[J]. Talanta, 2000, 51(4): 677-684.
[55] Eiroa A A, Huckins S, Blanco E V. Opimizing resolution in constant-energy synchronous spectrofluorimetry[J]. Appl. Spectrosc, 2000, 54(10): 1534-1538.
[56]何立芳,林丹丽,李耀群.导数恒能量同步荧光法同时分析咔唑、苯并(a)芘、苝和2,3-苯并蒽[J].环境化学, 2005, 24(1): 89-93.
[57]蔡其洪.恒波长同步荧光法同时测定三种多环芳烃[J].莆田学院学报, 2006, 13(5): 80-83.
[58]胡乃梁,赵一兵,王冬媛,等.同步荧光法同时测定强力霉素和土霉素[J].分析测试学报, 1996, 15(5): 77-80.
[59]吴惠毅,陈晋,申海莲,等.同步荧光法测定血清维生素E[J].临床检验杂志, 1995, 13(3): 120-121.
[60]杨培慧,齐剑英,冯德雄.微量元素对B族维生素同步荧光分析法影响的研究[J].光谱实验室, 2001, 18(6): 791-795.
[61]李耀群,黄贤智,许金钩,等.维生素B2和B6的同步荧光分析法及其在维生素复合制剂中的应用[J].药学学报, 1992, 27(1): 52-56.
[62]倪永年,蔡英俊.平行因子-同步荧光法测定食品中维生素B1,B2和B6[J].光谱学与光谱分析, 2005, 25(10): 1641-1644.
[63]关玉群,胡锡珉,王充,等.同步荧光法同时测定复合维生素制剂中B2和B6[J].中国卫生检验杂志, 1999, 18(30): 220-221.
[64]胡益水,苏文周.同步荧光法测定奶粉中维生素B1和B2[J].营养学报, 1996, 18(30): 375-377.
[65]蒋淑艳.同步荧光法测定食品中维生素B1[J].光谱实验室, 1997, 14(2): 83-85.
[66]蒋淑艳,张伟玲.几种中草药中痕量锗的同步荧光法测定[J].药物分析杂志, 1999, 19(2): 91-93.
[67]赵一兵,潘洁,郭祥群,等.同步荧光法同时测定四环素和脱水四环素[J].分析化学, 1993, 21(12): 1439-1441.
[68]李满秀,高首勤.同步荧光光谱法测定溴氰菊酯的研究[J].分析试验室, 2007, 26: 287-288.
[69]魏永锋,李小花,马冬梅.同步扫描荧光光谱法同时测定阿司匹林和水杨酸[J].光谱学与光谱分析, 2005, 25(4): 588-590.
[70] Miller J N. Recent advances in molecular luminescence analysis[J]. Proc. Anal. Div. Chem. Soc, 1979, 16(6): 203-208.
[71]黄贤智,许金钩,李耀群.同步荧光法同时测定色氨酸、酪氨酸和苯丙氨酸[J].分析化学, 1987, 15(3): 199-202.
[72] Cui F L, Fan J, Ma D L, et al. A study of the interaction between a new reagent and serum albumin by fluorescence spectroscopy [J]. Anal Lett, 2003, 36(10): 2151-2166.
[73] Cui F L, Cui Y R, Luo H X, et al. Interaction of APT with BSA and HSA[J]. Chin Sci Bull, 2006, 51(18): 2201-2207.
[74]胡秋娈,王春风,李全民,等.铜(Ⅱ)-茜素红S络合物与蛋白质作用的光谱性质及应用研究[J].分析测试学报, 2005, 24(6): 74-77.
[75]魏永巨,李克安,童沈阳.溴甲酚绿与血清白蛋白的结合反应[J].分析化学, 1996, 24 (4): 1175-1177.
[76]陈红旗,马娟,刁雪莲,等. PbS-PAA复合纳米粒子共振光散射法测定蛋白质[J].分析测试学报, 2005, 24(6): 56-58.
[77]江波,胡庆红.十二烷基苯磺酸钠共振瑞利散射法测定蛋白质[J].分析试验室, 2002, 21(3): 27-30.
[78]陈国珍,黄贤智,许金钩,等.荧光分析法[M].北京:科学出版社, 1990: 115-128.
[79]鄢远,彭学军,许金钩,等.褶合曲线分析法用于同步荧光光谱法同时测定苯酚和对苯二酚[J].分析测试学报, 1995, 14(1): 1-4.
[80] Cui F L, Wang J L, Cui Y R, et al. Fluorescence investigation of the interactions between N-(p-chlorophenyl)-N′-(1-naphthyl) thiourea and serum albumin: synchronous fluorescence determination of serum albumin[J]. Anal Chim Acta, 2006, 571(2): 175-183.
[81] Rao C M. Synchronous scan fluorescence spectroscopy of proteins and human eye lens[J]. Biochem. Biophys. Res. Commun, 1991, 176: 1351-1357.
[82]唐臻强,贺干武,易平贵.酸度对氧氟沙星与牛血清白蛋白结合的影响[J].光谱学与光谱分析, 2008, 28(5): 1107-1110.
[83]杜秀莲,李荣昌,王夔.用同步荧光光谱法研究(Ⅲ)与脱铁运铁蛋白的作用[J].科学通报, 2001, 46(5): 394-396.
[84]杨秀娟,丑菊,陆天虹.血红蛋白的同步荧光光谱随浓度变化的特性[J].分析化学, 1997, 25(9): 1021-1023.
[85]杨培慧,郑志雯,蔡继业,等.胰岛素分子存在形态及结构变化的同步荧光光谱研究[J].理化检验-化学分册, 2003, 39(6): 324-329.
[86]曲晓刚,陆天虹.用同步荧光光谱测定量测定细胞色素C[J].分析化学, 1994, 22(12): 1238-1240.
[87]石燕,鄢远.牛血清白蛋白的同步荧光分析法[J].南昌大学学报(理科版), 2000, 24(9): 282-285.
[88]剑菊,杜江燕,冯玉英,等.肌红蛋白的同步荧光光谱[J].分析化学, 2001, 29(2): 219-221.
[89] Chou J, Qu X, Lu T, et al. The effect of solution pH on synchronous fluorescence spectra of cytochromec solutions[J]. Microchem. J, 1995, 52: 159-165.
[90] Wang L Y, Zhou Y Y, Wang L, et al. Synchronous fluorescence determination of protein with functionalized CdS nanoparticles as a fluorescence probe[J]. Analytica Chimica Acta, 2002, 466: 87-92.
[91]崔凤灵,秦利霞,李芳,等. 5-硝基水杨酸同步荧光法测定生物样品中蛋白质[J].应用化学, 2009, 26(6): 730-733.
[92]杜俊鸥,郭祥群.同步荧光光谱比率法检测过氧亚硝酸根及其清除剂的研究[J].光谱学与光谱分析, 2008, 28(8): 1875-1878.
[93]陈红,徐欣.同步荧光法测定食品中维生素B[M].北京:科学出版社, 2005: 32-33.
[2]冯建民,秸俊红.中国三聚氰胺生产应用现状及产业技术分析[J].化工科技市场, 2006, 29(5): 11-16.
[3]汪家铭.我国三聚氰胺发展概况及市场前景[J].化工设计通讯, 2008, 34(2): 15-22.
[4]张俊燕,何吕兴.三聚氰胺的样品前处理及最新检测方法[J].生命科学仪器, 2007, (5): 57-59.
[5] Thomas R, Kulkarni G U. A hydrogen bonded channel structure formed by a complex of uracil and melamine[J]. Beilstein J Org Chem, 2007, 28: 3-17.
[6]王辉,董元华,安琼.环丙氨嗪的生物毒性与环境行为研究进展[J].农业工程学报, 2008, 24(1): 246-249.
[7] Burns K. Recall shines spotlight on pet foods[J]. J Am Vet Med Assoc, 2007, 230(9): 1285-1288.
[8]王征. GC-MS法测定动物食品中的三聚氰胺[J].福建分析测试, 2008, 17(2): 1-4.
[9] Thompson M E , Lewin-Smith M R , Kalasinsky V F, et al. Characterization of melamine-containing and calcium oxalate crystals in three dogs with suspected pet food-inducednephrotoxicosis[J]. Vet Pathol, 2008, 45: 417-426.
[10]冯家望,蔡勤仁,柳训才,等.高效液相色谱-电喷雾串联技术测定奶及奶制品中三聚氰胺和环丙氨嗪[J].现代食品科技, 2008, 24(10): 1058-1060.
[11] Okumara M, Hasegawa R, Shirai T, et al. Relationship between calculus formation and carcinogenesis in the urinary bladder of rats admistered the non-genotoxic agents thymine and melamine[J]. Carcinogenesis, 1992, 13(6): 1043-1045.
[12] Ogasawara H, Imaida K, Ishiwata H, et al. Urinary bladder carcinogenesis induced by melamine in F344 male rats: correlation between carcinogenicity and urolith formation[J]. Carcinogenesis, 1995, 16(11): 2773-2777.
[13] Ronald E B, Geof S, Sharon E. M, et a1. Pharmacokinetics of melamine in pigs following intravenous administration[J]. Food Chem. Toxicol., 2008, 46:1196-1200.
[14] Jennifer L.B, Ronald E.B, Jim E.R. Estimating meat with drawal times in pigs exposed to melamine contaminated feed using a physiologically based pharmaeokinetie model[J]. Regul. Toxicol. Pharm., 2008, 51: 324-331.
[15] Cathy A, Brown, Kyu-Shik J, et al. Outbreaks of renal failure associated with melamine and cyanuric acid in dogs and cats in 2004 and 2007[J]. J. Vet. Diagn. Investig., 2007, 19(5): 525-531.
[16]彭卫芳,凌志明,王学涛,等.亚硝酸盐测定方法研究进展[J].中国卫生检验杂志, 2007, 17(8): 1535-1536.
[17] Tsuda M, Hirayama T, Sugimura T. Presence of N-nitroso-L-thioproline and N-nitroso-L-methylthioproline in human urine as major N-nitroso compounds[J]. Jpn. J. Cancer Res. (Gann). 1983, 74(3): 331.
[18] Ohshima H, Friesen M, O’Neilll, et al. Presence in human urine of a new N-nitroso compound, N-nitrosothiazolidine 4-carboxylic acid[J]. Cacer Lett., 1983, 20(2): 183-190.
[19]王浩,刘艳琴,曹红,等.固相萃取与高效液相色谱联用测定宠物食品中三聚氰胺[J].分析化学, 2008, 36(2): 273.
[20]赵浩军,舒平.高效液相色谱法测定鸡蛋中三聚氰胺含量[J].大理学院学报, 2009, 8(4): 46-48.
[21]杨云霞,刘彤,周桂英,等.小麦谷元粉中三聚氰胺的高效液相色谱法测定[ J].分析测试学报, 2008, 27(3): 322-324.
[22] Filigenzi M S, Tor E R, Poppenga R H, et al. The determination of melamine in muscle tissue by liquid chromatography/tandem mass spectrometry[J]. Rapid Commun. Mass Spectrom, 2007, 21(24): 4027-4032.
[23] Andersen W C, Turnipseed S B, Karbiwnyk C M, et al. Detemination and confirmation of melamine residues in catfish, trout, tilapia, salmon and shrimp by liquid chromatography with tandem mass spectrometry[J]. J. AgricFood Chem, 2008, 56(12): 4340-4347.
[24]曹莹,张文刚,黄士新.高效液相色谱法分析饲料中的三聚氰胺[J].上海畜牧兽医通讯, 2007, (6): 47-48.
[25]王亚吨,林海丹,邓国东.反相高效液相色谱法测定饲料中三聚氰胺的含量[J].广东饲料, 2008, 17(3): 41-43.
[26]汪辉,曹小彦,彭新凯.高效液相色谱-二极管阵列法测定高蛋白食品中的三聚氰胺[J].食品与机械, 2007, 23(5):114-115.
[27]蒲云霞,刘丽珍,徐晓枫.反相离子对色谱法检测无水奶油中三聚氰胺方法的建立[J].中国卫生检验杂志, 2009, 19(1): 95-96.
[28]黄芳,黄晓兰,吴惠勤,等.高效液相色谱-质谱法对饲料及食品添加剂中三聚氰胺的测定[J].分析测试学报, 2008, 27(3): 313-315.
[29]丁涛,徐锦忠,李健忠,等.高效液相色谱-二极管阵列检测法及高效液相色谱-电喷雾串联质谱法测定植物源性蛋白中残留的三聚氰胺[J].色谱, 2008, 26(1): 6-9.
[30] James N K, William G. Screening for melamine adulteration in protein-based foods by GC/ MS, Gaschromatography/Mass spectrometry, 2007: 1-4. (www.perkinelmer.com)
[31] Thuy D T V, Markus H, Manuela H, et a1. Improved analysis of melamine- formaldehyde resins by capillary zone electrophoresis - mass spectrometry using ion - trap and quadrupole- time - of - flight mass spectrometers[J]. J. Chromatogr. A, 2008, 1213(1): 83-87.
[32] Schuiz W, Seitz W, Weber W H, et al. Detection of melamine in water[J]. Vom Wasser, 2007, 105(4): 18-22.
[33] Yoshida A Y, Murakami T, Takeda K, et al. Determination of melamine using LC-MS and applications to samples related to waste[J]. Kankyo Kagaku, 2006, 16(4): 635-641.
[34]化工部标准GB/T 9567-1997工业三聚氰胺.
[35]侯艳丽,张惠茹,刘来亭,等.三聚氰胺的检测方法[J].河南畜牧兽医综合版, 2007, 28(9): 32-33.
[36]陈江萍.食品中三聚氰胺的危害及其检测方法[J].中国农村小康科技, 2008, (11): 68-72.
[37]汪勇.升华法测定三聚氰胺纯度的局限[J].中氮肥, 2008, 2: 57-60.
[38] Garber E A. Detection of melamine using commercial enzyme-linked immunosorbent assay technology[J]. J Food Prot, 2008, 71(3): 590-594.
[39] Kim B, Perkins L B, Bushway R J, et al. Determination of melamine in pet food by enzyme immunoassay, high-performance liquid chromatography with diode array detection, and ultra-performance liquid chromatography with tandem mass spectrometry[J]. Jaoac Int, 2008, 91(2): 408-413.
[40]訾言勤,凌程凤.四波长负吸收催化光度法测定痕量亚硝酸根[J].分析化学, 2004, 32(8): 1039-1042.
[41]胡卫平,董学芝,何智娟.甲基紫电极催化动力学电位法测定亚硝酸根[J].分析化学, 2004, 32(6): 765-768.
[42]王洋,范世华.芯片式微型流通池顺序注射化学发光法测定水中的亚硝酸根[J].光谱学与光谱分析, 2005, 25(2): 184-187.
[43] Chao L, Jin M L, Carmen W, et al. Chemiluminescence study of carbonate and peroxynitrous acid and its application to the direct determination of nitrite based on solid surface enhancement[J]. Anal Chim Acta, 2004, (2): 29-34.
[44]周运友,佘世科,卢琴,等. N-(1-萘基)-乙二胺荧光光度法测定痕量亚硝酸根[J].光谱学与光谱分析, 2005, 25(8): 1318-1321.
[45] Salmon J, Mouren M, Baulieu E E. The antiprogestin steroid RU486 and human fertility control[M]. Plenum Press, New York, 1985. 99.
[46]李党生,李桂敏.碱性品红紫外光度法测定水中亚硝酸盐氮[J].环境工程, 2002, 20 (2): 61-63.
[47] Wang G F, Horita K, Satake M. Simultaneous spectrophotometric determination of nitrate and nitrite in water and some vegetable samples by column preconcentration[J]. Microchem. J., 1998, 58: 162-174.
[48] Kazemzadeh, Ensafi. Simultaneous determination of nitrite and nitrate in various samples using flow-injection spectrophotometric detection[J]. Microchemical J., 2001, 69: 159-166.
[49]赵新淮,林燕,张海霞.蔬菜中亚硝酸盐的光度测定[J].理化检验-化学分册, 2006, 42(2): 128-129.
[50]周之荣,王文敏,王黎.动力学光度法测定食品中痕量亚硝酸根[J].食品科技, 2005, 26(10): 181-183.
[51]方步武,靳珠华,林秀珍.测定血中亚硝酸盐的荧光分光光度法[J].中国应用生理学杂志, 2005, 21(2): 235-239.
[52] Huang K J, Wang H, Guo Y H, et al. Spectrofluorimetric determination of trace nitrite in food products with a new fluorescent probe 1,3,5,7- tetramethyl-2,6– dicarbethoxy - 8(3’,4’- diaminophenyl)– difluorobora– diazas - indacene[J]. Talanta, 2006, 69(1): 73-78.
[53] Li R, Yu J C, Jiang Z T, et al. A solid-phase fluorescent quenching method for the determination of traceamounts of nitrite in foods with neutral red[J]. J. Food Drug Anal, 2003, 11(3): 251-257.
[54] Mahgoub H. Spectrophotometric and fluorimetric determination of aztreonam in bulk and dosage forms[J]. J. Pharm. Biomed. Anal, 2003, 31(4): 767-774.
[55]孙媛媛.荧光光谱法在环境监测中的应用[J].环境监测管理与技术, 2000, 12(3): 12-16.
[56]刘峥,夏之宁.光谱法在分子间相互作用中的应用[J].激光杂志, 2001, 22(6): 9211-9218.
[57]姚文华.光分析仪的原理及其在生化工程上的应用[J].医药工程设计, 1991, 2: 39-42.
[58]何立芳,林丹丽,李耀群.同步荧光分析法的应用及其新进展[J].化学进展, 2004, 16 (6): 879-886.
[59]曾凡蓉,席水清,张淑青,等.荧光光度法测定环境水样中的苯酚和对苯二酚[J].分析试验室, 2007, 26(5): 76-79.
[60] Chen Z L, Liu Q L, Wang S Y, et al. Study on hemorrhagin III purified from the venom of agkistrodon acutus by three-dimensional fluorescence spectrometry[J]. Spectrochim .Acta. A, 1999, 55: 1909-1914.
[61]刘文涵,杨未.激光拉曼光谱内标法直接测定乙醇浓度[J].分析化学, 2007, 35(3): 416-418.
[62]彭勤纪,王壁人.波谱分析在精细化工中的应用[M].北京:中国石化出版社, 2001: 77-78.
[63] Liu Y, Peng C D, Ni X W, et al. Study on ethanol-water cluster types with steady state and time resolved fluorescence spectrometer[J]. Acta Phtonica Sini, 2007,36(9):1677-1682.
[64]刘莹,兰秀风,高淑梅,等. 253.7nm光辐照乙醇溶液荧光光谱分析[J].南京理工大学学报, 2003, 27(6): 720-723.
[65] Lakowicz J R. Principles of fluorescence spectroscopy(3rd Ed)[M]. Berlin: Springer, 2006: 277-283.
[66]许金钩,王尊本.荧光分析法[M].第三版.北京:科学出版社, 2006: 65-68.
[67] Ross P D, Subramanian S. Thermodynamics of protein association reactions: forces contributing to stability[J]. J. Biochem, 1981, 20(11): 3096-3102.
[68]孙雷,韩嘉媛,汪霞,等.三聚氰胺的毒性及残留检测方法研究进展[J].中国兽药杂志, 2008, 42(10): 37-39.
[69]吴惠勤,黄芳,林晓珊,等.气相色谱-质谱法测定奶粉及奶制品中的三聚氰胺[J].分析测试学报, 2008, 27(10): 1044-1048.
[70]周建科,张明翠,宋歌,等.高效液相色谱法测定鸭肉中的三聚氰胺[J].分析试验室, 2009, 28: 156-158.
[71]李爱军,张代辉,马书民,等.液相色谱-串联质谱法测定饲料中三聚氰胺残留[J].分析化学, 2008, 36(5):699-701.
[72]张勇,王淑红,朱亚先.同步荧光法检测鱼胆汁中的1-羟基芘[J].分析化学, 2002, 30(4): 467-469.
[73]孙衍增.荧光素钠荧光寿命的测定[J].分析化学, 2000, 28(11): 1413-1416.
[74]陈兰化,陈红旗.动力学荧光法测定痕量亚硝酸根的研究[J].淮北煤炭师范学院学报, 2004, 25(1): 21-23.
[75]刘秀萍,王洪芳.氯酸钾-灿烂甲酚蓝催化褪色光度法测定痕量亚硝酸根的研究[J].分析科学学报, 2008, 24(5): 606-608.
[76]司文会,訾言勤.多波长负吸收褪色光度法测定微量亚硝酸根及其反应机理[J].光谱学与光谱分析, 2005, 25(10): 1671-1673.
[77]吴湘江,刘狄,刘凤萍,等.催化溴酸钾氧化萘酚绿B褪色紫外光度法测定亚硝酸根[J].理化检验-化学分册, 2006, 42(1): 58-59.
[78]李贵荣,王永生,贺冬秀.催化共振光散射法测定痕量亚硝酸根[J].分析化学, 2005, 33(9): 1306-1304.
[79]王学锋,史选,皮运清.流动注射化学发光法测定水样中的痕量亚硝酸根[J].分析化学, 2005, 33(6): 865-868.
[80] Chao L, Jin M L, Carmen W, et al. Chemiluminescence study of carbonate and peroxynitrous acid and its application to the direct determination of nitrite based on solid surface enhancement[J]. Anal Chim Acta, 2004, (2): 29-34.
[81]唐学燕,陶冠军,秦昉.二阶导数-同步荧光法同时测定微量维生素B1, B2和烟酰胺[J].分析试验室, 2009, 28(10): 92-94.
[82]许金钩,王尊本.荧光分析法[M].北京:科学出版社, 2006, 137-140.
[83]高甲友.吖啶红荧光猝灭法测定痕量亚硝酸根[J].理化检验-化学分册, 2004, 40(1): 20-21.
[1]何立芳,林丹丽,李耀群.同步荧光分析法的应用及其新进展[J].化学进展, 2004, 16(6): 879-885.
[2]张先廷,赵惠玲,杜黎明.同步荧光光谱法测定人体尿液中加替沙星[J].分析科学学报, 2008, 24(3): 344-346.
[3] Lloyd J B F. Multicomponent analysis by synchronous luminescence spectrometry[J]. Nature, 1971, 231: 64-67.
[4]陈国珍,黄贤智,郑朱梓,等.荧光分析法[M].北京:科学出版社, 1990. 201-212.
[5]章汝平,陈克华,何立芳.大气飘尘中多环芳烃的超声波萃取-恒能量同步荧光法测定[J].分析测试学报, 2007, 26(6): 830-832.
[6]李耀群,黄贤智.固定能量同步发光光谱测定法[J].分析化学, 1989, 17(12): 1154-1158.
[7]吴晓红,高生平.同步荧光分析法的应用进展[J].光谱实验室, 2008, 25(4): 651-654.
[8]章汝平,郭健.恒能量同步荧光法测定食品中的多环芳烃[J].食品工业科技, 2007, 28(12): 198-200.
[9] Miller J N. Recent developments in fluorescence and chemilum- inescence analysis[J]. Analyst, 1984, 109: 191-198.
[10] Inman E L, Winefordner J D. Constant-energy synchronous fluorescence for re-duction of raman scatter interference[J]. Anal. Chim. Acta, 1982, 138: 245-252.
[11] Inman E L, Winefordner J D. Constant energy synchronous fluorescence for analysis of polycyclic aromatic hydrocarbon mixtures[J]. Anal. Chem, 1982, 54: 2018-2022.
[12] Inman E L, Files L A, Winefordner J D. Theoretical optimization of parameter selection in constant energy synchronous luminescence spectrometry[J]. Anal. Chem, 1986, 58: 2156-2160.
[13] Kerkhoff M J, Lee T M, Allen E R, et al. Spectral fingerprinting of polycyclic aromatic hydrocarbons in high-volume amibient air samples by constant energy synchronous lumicescecce spectroscopy[J]. Environ. Sci. Technol, 1985, 19: 695-699.
[14] Kerkhoff M J, Inman E L, Voigtman E, et al. Rapid scanning constant energy synchronous fluorescence spectrometry: acomparison of flow cells[J]. Appl. Spectrosc, 1984, 38(2): 239-245.
[15] Andre J C, Bouchy A, Jezequel J Y. Increased apparent sensitivity by means of constant-energy synchronous spectrofluorimetry[J]. Anal. Chim. Acta, 1986, 185(8): 91-99.
[16] Files L A, Jones B T, Hanamura S, et al. Gasoline-engine exhaust analysis using constant energy synchronous luminescence spectrometry[J]. Anal. Chem, 1986, 58(7): 1440-1443.
[17] Murillo, Pulgarin J A, Molina A A. Determination of nafcillin and methicillin by different spectrofluorimetric techniques[J]. Talanta. 2001, 41(1): 21-30.
[18] Murillo-Pulgarin J A, Molina A A. Matrix isopotential synchronous fluorescence direct determination of gentisic acid in urine[J]. Anal. Chim. Acta, 1994, 296(1): 87-97.
[19] Green G L, O′Haver T C. Derivative lumineecence spectroscopy[J]. Anal. Chem, 1974, 46: 2191-2196.
[20] Li Y Q, Sui W, Wu C, et al. Derivative matrix isopotential synchronous fluorescence spectroscopy for the direct determination of 1-hydroxypyrene as a urinary biomarker of exposure to polycyclic aromatic hydrocarbons[J]. Anal. Sci, 2001, 17(1): 167-170.
[21] Murillo-Pulgarin J A, Molina A A, López P F. Direct determination of amiloride in urine using isopotential fluorimetry[J]. Analyst, 1997, 122(3): 247-252.
[22] Murillo-Pulgarin J A, Molina A A. Direct determination of quinidine in urine[J]. Anal. Chim. Acta, 1995, 317(1-3): 359-364.
[23] Murillo-Pulgarin J A, Molina A A. Determination of Salicylic and gentisic acids in the presence of each other by matrix isopotential synchronous fluorescence spectrometry[J]. Analyst, 1994, 119: 1915-1919.
[24] Murillo-Pulgarin J A, Molina A A, López P F. Direct determination of triamterene in urine by matrix isopotential synchronous fluorescence spectrometry[J]. Anal. Chim. Acta, 1996, 326(1-3): 117-126.
[25] Nevado J J B, Murillo-Pulgarin J A, Laguna M A G. Determination of pyridoxamine in urine by matrix isopotential synchronous fluorescence spectrometry[J]. Analyst, 1995, 120(1): 171-174.
[26]眭蔚,吴春,李耀群,等.导数恒基体强度同步荧光分析法同时测定光谱严重重叠的1-氯蒽和9-溴蒽[J].分析化学, 2001, 29(3): 320-322.
[27] Hofstraat J W, Janser H J M, Hoornweg G P H, et al. Quantitative determination of polycyclic aromatic hydrocarbons in harbour sediment via high-resolution shpol'skii spectroscopy[J]. Intern. J. Environ. Anal. Chem, 1985, 21(4): 299-332.
[28]蒋淑艳.苯并[a]的同步荧光法测定条件研究[J].光谱学与光谱分析, 1997, 17(3): 115-118.
[29] Ferrer R, Beltran J L, Guiteras J. Multivariate calibration applied to synchronous fluorescence spectrometry. simultaneous determination of polycyclic aromatic hydrocarbons in water samples[J]. Talanta, 1998, 45(6): 1073-1080.
[30] Sanchez F G, Cruces C, Rubio A L R. Synchronously scanned derivative spectrofluorimetry: a new approach for the analysis of multicomponent fluorescent samples[J]. J. Mol. Struct, 1986, 143: 473-476.
[31] Sanchez F G, Rubio A L R, Blanco C C. Three-dimensional synchronous fluorescence spectrometry for the analysis of three-component alkaloid mixtures[J]. Talanta, 1990, 37(6): 579-584.
[32] Khakhel O A, Krykunova V E. Determination of dimers concentration of chromophores by the method of fluorescence synchronous scanning[J]. J. Luminescence, 1999, 81(1): 79-84.
[33] Dimitrios G K, Pinelopi C, Efstrations S. Simultaneous determination of naproxen and its desmethyl metabolite in human serum by second-derivative synchronous fluorescence spectrometry[J]. Anal. Chim. Acta, 1994, 290(1-2): 34-39.
[34] Stevenson C L, Vo-Dinh T. Analysis of polynuclear aromatic compounds using laser-excited synchronous fluorescence[J]. Anal. Chim. Acta, 1995, 303(2-3): 247-253.
[35] Munoz de la P A, Salinas F, Duran M S. Simultaneous determination of propranolol and hydralazine by derivative synchronous spectrofluorim- etry[J]. Anal. Chim. Acta, 1991, 255(2): 317-323.
[36] Reynolds D M. Rapid and direct determination of tryptophan in water using synchronous fluorescence spectroscopy[J]. Water Res, 2003, 37(13): 3055-3060.
[37] Kabbani M W, Rubio-Borroso S, Polo-Diez L M. Determination of traces of gallium in the presence of aluminium by synchronous derivative spectrofluorimetry[J]. Anal. Chim. Acta, 1989, 218: 167-171.
[38] Salinals F, Muoz de la P A, Capitan-Vellvey L F, et al. Simultaneous determination of molybdenum and tungsten by first-derivative synchronous spectrofluorimetry[J]. Analyst, 1989, 114: 1297-1301.
[39]陈慰宗,宋应谦,张振杰,等.食用油加热后荧光强度变化的实验研究[J].光子学报, 2000, 29(5): 478-480.
[40]陈健,孙爱东.同步荧光光谱在食品检测领域的应用[J].中国食物与营养, 2009, 10: 28-31.
[41] Miller J N. Recent developments in fluorescence and chemiluminescence analysis. Plenary Lecture[J]. Analyst, 1984, 109(3): 191-198.
[42] Clark B J, Fell A F, Miline K T. et al. Pharmaceutical applications of variable-angle synchronous scanning fluorescence spectroscopy[J]. Anal. Chim. Acta, 1985, 170(1): 35-44.
[43] Oms M T, Forteza R, Cerda V, et al. Simultaneous determination of two components by spectrofluorimetric techniques[J]. Anal. Chim. Acta, 1990, 233(1): 159-163.
[44] Sontag J M. Carcinogens in industry and the environment[M]. New York: ManelDekker Inc, 1981: 345-437.
[45] Neff J M. Polycyclic aromatic hydrocarbons in the aquatic environment, sources, fates and biological effects[M]. London: Applied Science Publishers, 1979: 262.
[46] Cabaniss S E, Shuman M S. Synchronous fluorescence spectra of natural waters: tracing sources of dissolved organic matter [J]. Mar. Chem, 1987, 21(1): 37-50.
[47] Lin D L, Zou Z X, He L F, et al. Rapid screening method for simultaneous determination of four polycyclic aromatic hydrocarbons in water samples by derivative non-linear variable-angle synchronous fluorescence spectrometry[J]. Luminescence, 2005, 20(4-5): 292-297.
[48]张勇,朱亚先等.同步荧光法检测芘的微生物降解[J].中国环境科学, 2002, 22(4): 289-292.
[49]李静红,于连生.同步荧光光谱同时分析苯并蒽和9,10-二甲基蒽[J].东北电力学院学报, 1995, 15(4): 63-67.
[50] Li Y Q, Huang X Z, Xu J G, et al. Derivative constant-energy synchronous fluorescence for simultaneous analysis of polynuclear aromatic hydrocarbon mixtures[J]. Anal. Chim. Acta, 1992, 256(2): 285-291.
[51]敖登高娃,张莹,樊海燕.同步-导数荧光光谱法测定混合样品中美他环素[J].光谱学与光谱分析, 2006, 26(8): 1530-1532.
[52] Li Y Q, Shi L, Qian F. Simultaneous determination fluorine, acenaphthene, anthracene and perylene by derivative constant energy synchronous fluorimetry[J]. Chem. J. Chinese Universities, 1997, 18(4): 538-540.
[53] Eiroa A A, Blanco E V, Machia P L. Resolution of benzo (a) pyrene in complex Mixtures of other polycyclic aromatic hydrocarbons. comparison of two spectrofluorimetric methods applied to water samples[J]. Analyst, 2000, 125(7): 1321-1326.
[54] Eiroa A A , Blanco E V, Machia P L. Determination of polycyclic aromatic hydrocarbons (PAHs) in a complex mixture by second-derivative constant-energy synchronous spectrofluorimetry[J]. Talanta, 2000, 51(4): 677-684.
[55] Eiroa A A, Huckins S, Blanco E V. Opimizing resolution in constant-energy synchronous spectrofluorimetry[J]. Appl. Spectrosc, 2000, 54(10): 1534-1538.
[56]何立芳,林丹丽,李耀群.导数恒能量同步荧光法同时分析咔唑、苯并(a)芘、苝和2,3-苯并蒽[J].环境化学, 2005, 24(1): 89-93.
[57]蔡其洪.恒波长同步荧光法同时测定三种多环芳烃[J].莆田学院学报, 2006, 13(5): 80-83.
[58]胡乃梁,赵一兵,王冬媛,等.同步荧光法同时测定强力霉素和土霉素[J].分析测试学报, 1996, 15(5): 77-80.
[59]吴惠毅,陈晋,申海莲,等.同步荧光法测定血清维生素E[J].临床检验杂志, 1995, 13(3): 120-121.
[60]杨培慧,齐剑英,冯德雄.微量元素对B族维生素同步荧光分析法影响的研究[J].光谱实验室, 2001, 18(6): 791-795.
[61]李耀群,黄贤智,许金钩,等.维生素B2和B6的同步荧光分析法及其在维生素复合制剂中的应用[J].药学学报, 1992, 27(1): 52-56.
[62]倪永年,蔡英俊.平行因子-同步荧光法测定食品中维生素B1,B2和B6[J].光谱学与光谱分析, 2005, 25(10): 1641-1644.
[63]关玉群,胡锡珉,王充,等.同步荧光法同时测定复合维生素制剂中B2和B6[J].中国卫生检验杂志, 1999, 18(30): 220-221.
[64]胡益水,苏文周.同步荧光法测定奶粉中维生素B1和B2[J].营养学报, 1996, 18(30): 375-377.
[65]蒋淑艳.同步荧光法测定食品中维生素B1[J].光谱实验室, 1997, 14(2): 83-85.
[66]蒋淑艳,张伟玲.几种中草药中痕量锗的同步荧光法测定[J].药物分析杂志, 1999, 19(2): 91-93.
[67]赵一兵,潘洁,郭祥群,等.同步荧光法同时测定四环素和脱水四环素[J].分析化学, 1993, 21(12): 1439-1441.
[68]李满秀,高首勤.同步荧光光谱法测定溴氰菊酯的研究[J].分析试验室, 2007, 26: 287-288.
[69]魏永锋,李小花,马冬梅.同步扫描荧光光谱法同时测定阿司匹林和水杨酸[J].光谱学与光谱分析, 2005, 25(4): 588-590.
[70] Miller J N. Recent advances in molecular luminescence analysis[J]. Proc. Anal. Div. Chem. Soc, 1979, 16(6): 203-208.
[71]黄贤智,许金钩,李耀群.同步荧光法同时测定色氨酸、酪氨酸和苯丙氨酸[J].分析化学, 1987, 15(3): 199-202.
[72] Cui F L, Fan J, Ma D L, et al. A study of the interaction between a new reagent and serum albumin by fluorescence spectroscopy [J]. Anal Lett, 2003, 36(10): 2151-2166.
[73] Cui F L, Cui Y R, Luo H X, et al. Interaction of APT with BSA and HSA[J]. Chin Sci Bull, 2006, 51(18): 2201-2207.
[74]胡秋娈,王春风,李全民,等.铜(Ⅱ)-茜素红S络合物与蛋白质作用的光谱性质及应用研究[J].分析测试学报, 2005, 24(6): 74-77.
[75]魏永巨,李克安,童沈阳.溴甲酚绿与血清白蛋白的结合反应[J].分析化学, 1996, 24 (4): 1175-1177.
[76]陈红旗,马娟,刁雪莲,等. PbS-PAA复合纳米粒子共振光散射法测定蛋白质[J].分析测试学报, 2005, 24(6): 56-58.
[77]江波,胡庆红.十二烷基苯磺酸钠共振瑞利散射法测定蛋白质[J].分析试验室, 2002, 21(3): 27-30.
[78]陈国珍,黄贤智,许金钩,等.荧光分析法[M].北京:科学出版社, 1990: 115-128.
[79]鄢远,彭学军,许金钩,等.褶合曲线分析法用于同步荧光光谱法同时测定苯酚和对苯二酚[J].分析测试学报, 1995, 14(1): 1-4.
[80] Cui F L, Wang J L, Cui Y R, et al. Fluorescence investigation of the interactions between N-(p-chlorophenyl)-N′-(1-naphthyl) thiourea and serum albumin: synchronous fluorescence determination of serum albumin[J]. Anal Chim Acta, 2006, 571(2): 175-183.
[81] Rao C M. Synchronous scan fluorescence spectroscopy of proteins and human eye lens[J]. Biochem. Biophys. Res. Commun, 1991, 176: 1351-1357.
[82]唐臻强,贺干武,易平贵.酸度对氧氟沙星与牛血清白蛋白结合的影响[J].光谱学与光谱分析, 2008, 28(5): 1107-1110.
[83]杜秀莲,李荣昌,王夔.用同步荧光光谱法研究(Ⅲ)与脱铁运铁蛋白的作用[J].科学通报, 2001, 46(5): 394-396.
[84]杨秀娟,丑菊,陆天虹.血红蛋白的同步荧光光谱随浓度变化的特性[J].分析化学, 1997, 25(9): 1021-1023.
[85]杨培慧,郑志雯,蔡继业,等.胰岛素分子存在形态及结构变化的同步荧光光谱研究[J].理化检验-化学分册, 2003, 39(6): 324-329.
[86]曲晓刚,陆天虹.用同步荧光光谱测定量测定细胞色素C[J].分析化学, 1994, 22(12): 1238-1240.
[87]石燕,鄢远.牛血清白蛋白的同步荧光分析法[J].南昌大学学报(理科版), 2000, 24(9): 282-285.
[88]剑菊,杜江燕,冯玉英,等.肌红蛋白的同步荧光光谱[J].分析化学, 2001, 29(2): 219-221.
[89] Chou J, Qu X, Lu T, et al. The effect of solution pH on synchronous fluorescence spectra of cytochromec solutions[J]. Microchem. J, 1995, 52: 159-165.
[90] Wang L Y, Zhou Y Y, Wang L, et al. Synchronous fluorescence determination of protein with functionalized CdS nanoparticles as a fluorescence probe[J]. Analytica Chimica Acta, 2002, 466: 87-92.
[91]崔凤灵,秦利霞,李芳,等. 5-硝基水杨酸同步荧光法测定生物样品中蛋白质[J].应用化学, 2009, 26(6): 730-733.
[92]杜俊鸥,郭祥群.同步荧光光谱比率法检测过氧亚硝酸根及其清除剂的研究[J].光谱学与光谱分析, 2008, 28(8): 1875-1878.
[93]陈红,徐欣.同步荧光法测定食品中维生素B[M].北京:科学出版社, 2005: 32-33.