用户名: 密码: 验证码:
我国化肥产业发展特征及可持续性研究
详细信息    本馆镜像全文|  推荐本文 |  |   获取CNKI官网全文
摘要
化肥是支持粮食生产的重要生产资料。但由于我国化肥生产与施用消耗大量的自然资源和产生巨大的环境影响而可持续性差。本文运用国家统计数据、文献资料和工业协会数据分析了我国建国以来氮肥、磷肥和钾肥的产业发展特征,并结合情景分析提出了我国化肥可持续发展方向。在此研究基础上分析提出了不同化肥品种的发展建议。主要结论如下:
     (1)我国氮肥产量从1949年的6000吨N增加到2013年的5287万吨N,不仅实现了自给,而且成为第一出口大国。生产规模也不断扩大,大型装置明显增加。产业布局向能源产地转移,尿素成为主导产品。氮肥消费量从1961年53万吨N增加到2012年的4105万吨N。近些年工业消费量继续快速增长,而农业消费量基本维持在3300万吨N左右。
     (2)由于技术进步,单位合成氨能耗从2714kg标煤/t NH3下降到1561k标煤/tNH3,温室气体排放从6.3t CO2-eq/tNH3下降到3.7tCO2-eq/tNH3;由于尿素比重的增加,氮肥生产到施用单位氮的能耗和农田损失增加,但温室气体排放减少。由于氮肥产量与消费量的增加,氮肥生产与消费的总能耗、总温室气体排放和总损失都增加。如果能提高技术水平、优化产品结构、禁止氮肥出口和优化氮肥农业消费量(生产量与消费量相同),能显著降低氮肥生产到施用的能耗、温室气体排放和氮损失,分别降低40.9%、29.8%和63.4%(国内水平)。
     (3)我国磷肥产量从1961年的12万吨P205增加到2013年的1653万吨P205,不仅实现自给,而且成为主要的出口大国。磷肥生产主要集中在磷矿产地,企业规模扩大,生产集中度提高,高浓度磷肥成为主要产品。磷肥消费量从1961年的12万吨P205增加到2012年的1176万吨P205,近些年消费基本稳定在1100万吨P205。
     (4)由于磷矿生产量的快速增加和高浓度磷肥的生产导致磷矿开采与加工回收率降低,磷矿产量迅速增加,从13万吨P205增加到3196万吨P2O5。未来由于人口增加、社会经济发展和饮食结构的变化,磷矿需求量将进一步增加,从2010年的3196万吨P2O5增加到2030年的3556万吨P205,2100年降至2462万吨P205。保持2100年需求量,探明的磷矿储量将在2118年消耗完。然而,如果能在开采、加工、磷肥需求与粪便和废水磷回收环节采取措施,磷矿的需求将会显著下降,中国磷矿资源可以利用到2593年。采取措施还能显著的降低磷素向环境中的排放量。
     (5)我国钾肥产量从1981年的2万吨K2O增加到2013年的472万吨K20。产量增加的同时,产品种类多样化。钾肥生产主要集中在青海和新疆钾矿资源地。由于受到资源短缺的制约,钾肥产量依然不能满足国内消费,但是进口量减少,进口依存度下降,目前保持在50%。近年来,我国工农业钾肥消费量约600万吨K2O,趋于稳定。
     (6)从目前的化肥产业总体分析发现:氮磷肥产能过剩显现,产品高浓度单一化,资源消耗与环境影响增大。与先进水平及我国可持续发展目标相比,提升工业生产和农业施用效率仍是主要目标,工业环节应化解过剩产能,通过基础肥料产业向资源产地集中以及生产装置大型化进一步提高资源效率;进一步优化产品结构,发展适合土壤、作物和现代农业生产方式的产品,并配套科学施用方法,进一步提升肥料利用效率。钾肥由于资源紧缺,应该保持国内钾肥现有产量,这样利于钾肥进口谈判。同时,应建设海外钾肥项目打破国际垄断和开发利用丰富的难溶性钾资源。
Chemical fertilizer is an important material to support grain production. However, the sustainability of China's fertilizer industry is poor due to the higher resource consumption and higher environmental costs during the process of fertilizer production and consumption. This thesis analyzes the China's industrial development characteristics of the nitrogen, phosphorus and potash fertilizer since1949by using data from National Bureau of Statistics, fertilizer industry association, and literature. Meanwhile, this thesis presents the direction and measures of sustainable development of China's fertilizer industry based on scenario analysis. Finally, this thesis gives development proposals of different fertilizer products. The principal conclusions as follows:
     (1) The total production of nitrogen fertilizer (N nutrient) in China increased from6000tons in1949to52.98MT in2013, which not only achieved the self-sufficiency, but also became the largest exporter of nitrogen fertilizers in the world. Meanwhile, with the scale of production expanded, the large equipment increased significantly. Furthermore, the industrial layout transferred to producing areas of energy resources, and urea became the most important product. The consumption of N-fertilizers has been grown from0.53MT to41.1MT over the period between1961and2012. In recent years, the most of N-fertilizers were consumed by industrial sectors instead of agricultural sectors, and the total consumption of N-fertilizer by agricultural sectors remained constant at33MT.
     (2)The Energy consumption by per unit ammonia production decreased from2714kg tce/t NH3in1981tol561kg tce/t NH3in2012, and GHG emission decreased from6.3t CO2-eq/1NH3to3.7t CO2-eq/t NH3thanks to adoption of advanced technologies in China; Meanwhile, the energy consumption and N loss in the process of production and application of N-fertilizers increased due to the increase in the proportion of urea production, but the GHG emission dcreased. Meanwhile, the total energy consumption, greenhouse gas emissions and total reactive nitrogen losses of nitrogen fertilizer in the process of production and consumption increased significantly due to the increased nitrogen fertilizer production and consumption. However, total energy consumption, greenhouse gas emissions and total reactive nitrogen losses can be decreased by40.9%,29.8%and63.4%respectively if some measures would be implemented, such as the improving technical level, optimizing product structure, prohibiting the export of nitrogen fertilizer, and optimizing nitrogen fertilizer consumption in agriculture.
     (3) The production of phosphate fertilizers increased from122,000tonnes in1961to16.53MT P2O5in2012, which not only achieved self-sufficiency, but also became the main exporter in the world. Phosphate fertilizer producers are mainly concentrated in provinces where are rich in phosphate rocks, the scale of production has been expanded, the degree of production concentration increased, and the high-concentration phosphate fertilizers became the main product. Moreover, the consumption of phosphate fertilizers increased from122,000tonnes P2O5in1961to11.76MT P2O5in2012. Currently, the consumption is stabilizing at11MT.
     (4) Due to the rapid increase of phosphate production and the low level of recovery in process of phosphate rock's mining and processing, the production of phosphate rock increased from130000tonnes P2O5to31.96MT P2O5. In future, the Phosphorus demand will increase from31.96MT P2O5in2010to35.56MT P2O5, and will decrease to24.62MT P205in2100because of population increase, the social and economic development and change in dietary structure. Furthermore, the current reserves of phosphate rock will be depleted in2118according to the demand in2100. However, the phosphate rock reserves will last to year of2593, if certain measures can be adopted in the process of mining, processing, application of phosphate rock, and enhanced the utilization and recovery of phosphorus from the wastewater
     (5) Potash production increased from36,000tonnes K2O in1990to4.72MT K2O in2013. Meanwhile, with the increase of the production, the structure of products became variety. Potash production mainly concentrated in producing areas of potassium resource, like Qinghai and Xinxiang province. Due to the shortage of resources, potash production still cannot meet domestic demand,50%of the total consumption need to be imported from other countries at present. In recent years, the consumption of K fertilizers is stabilizing at6MT K2O.
     (6) The problems, such as the overcapacity of nitrogen and phosphorus fertilizers, simplified product structure, and great impacts on resource consumption and ecological environment. Therefore, improving the industrial production and agricultural efficiency is still the main target for sustainable development of fertilizer industry. Specific measures like digesting excess capacity in industrial chain, improving the resource efficiency by shifting fertilizer producers to the origin of resources and using advanced equipment; Meanwhile, improving the fertilizer utilization efficiency by optimizing the product structure, developing the products according the soil quality, and supporting the scientific method of fertilizer application. Moreover, because of the scarcity of resources, the production of potash fertilizer should maintain at current level. At the same time, government should encourage overseas potash project in order to break the international monopoly and utilization of the plentiful insoluble potassium resource.
引文
Ashley, K., Cordell, D., Mavinic, D.2011. A brief history of phosphorus:From the philosopher's stone to nutrient recovery and reuse. Chemosphere,84(6),737-746.
    Bai, Z.H., Li, H.G., Yang, X.Y. et al.2013. The critical soil P levels for crop yield, soil fertility and environmental safety in different soil types. Plant and Soil. doi:10.1007/s11104-013-1696-y
    Barth, J., Amlinger, F., Favoino, E., et al.2008. Final Report-Compost production and use in the EU. European Commission, DG Joint Research Centre/ITPS. Belaruskali Home, http://www.kali.by/english/future.html
    Bell, J. M.1984, Nutrients and toxicants in rapeseed meal:a review. Journal of Animal Science,58(4),996-1010.
    Bellarby J., Aberdeen U.O., Sciences S.O.B., et al.2008. Cool Farming:Climate impacts of agriculture and mitigation potential.:Greenpeace International.
    Bouwman A.F., Boumans L.2002. Estimation of global NH3 volatilization loss from synthetic fertilizers and animal manure applied to arable lands and grasslands. Global Biogeochem Cy,16(2):1024.
    Bouwman A.F., Boumans L., Batjes N.H.2002. Modeling global annual N2O and NO emissions from fertilized fields. Global Biogeochem Cy,16(4):1080.
    Bremner, J. M.1997. Sources of nitrous oxide in soils. Nutrient cycling in Agroecosystems,49(1-3),7-16.
    Bronick C J.2005. Soil structure and management. Geoderma,124(1-2):3-22.
    Brown, L. R.1995. Who will feed China? Washington, DC:World Watch Institute.
    Burney, J. A., Davis, S. J., Lobell, D. B.2010. Greenhouse gas mitigation by agricultural intensification. Proceedings of the national Academy of Sciences,107(26),12052-12057.
    Cai Z., Xing G., Yan X., et al.1997. Methane and nitrous oxide emissions from rice paddy fields as affected by nitrogen fertilisers and water management. Plant Soil,196(1):7-14.
    Cole, C. V., Duxbury, J., Freney, J., et al.1997. Global estimates of potential mitigation of greenhouse gas emissions by agriculture. Nutrient Cycling in Agroecosystems,49(1-3),221-228.
    Cordell, D., Drangert, J. O., White, S.2009. The story of phosphorus:Global food security and food for thought. Global environmental change,19(2),292-305.
    Cromwell G L.1980. Biological availability of phosphorus for pigs. Feedstuffs,52.
    Erisman, J. W., Sutton, M. A., Galloway, J., et al.2008. How a century of ammonia synthesis changed the world. Nature Geoscience,1(10),636-639.
    Ertl, D. S., Young, K. A., Raboy, V.1998. Plant genetic approaches to phosphorus management in agricultural production. Journal of Environmental Quality,27(2),299-304.
    Espedal, B., Jordahl, A.2008. Investor Relations Stockholm of Yara international ASA-Yara AS.
    Food and Agriculture Organization of the United Nations (FAO) Database.2013. http://faostat.fao.org/site/291/default.aspx
    Food and Agriculture Organization of the United Nations (FAO).2006. Comprehensive Assessment of water management in agriculture.2006.
    Foereid, B., Hastings, A., Smith, P.2008. Cool farming:Climate impacts of agriculture and mitigation potential (p.28). Amsterdam:Greenpeace International.
    Food and Agriculture Organization of the United Nations (FAO). Plant Nutrition for Food Security:A Guide for Integrated Nutrient Management, FAO Fertilizer and Plant Nutrition Bulletin 16..Rome.2006.
    Gilbert, N.2009. Environment:The disappearing nutrient. Nature,461(7265),716.
    Gillis, M. B., Keane, K. W., Collins, R, A.1957. Comparative metabolism of phytate and inorganic P32 by chicks and poults. The Journal of nutrition,62(1),13-26.
    Guo, J. H., Liu, X. J., Zhang, Y., et al.2010. Significant acidification in major Chinese croplands. Science,327(5968), 1008-1010.
    Haque, S. A., Miah, M. U. A.2005. Point Placement of Multi-Nutrient Super Granules on Rice. Bulletin of the Institute of Tropical Agriculture, Kyushu University,28(2),69-74.
    Hou, Y., Ma, L., Gao, Z. L., et al.2013. The driving forces for nitrogen and phosphorus flows in the food chain of China, 1980 to 2010. Journal of environmental quality,42(4),962-971.
    Hua, X., Guangxi, X., Cai, Z. C., et al.1997. Nitrous oxide emissions from three rice paddy fields in China. Nutrient Cycling in Agroecosystems,49(1-3),23-28.
    International Fertilizer Industry Association(IFA),2013. http://www.fertilizer.org/ifa/HomePage/STATISTICS/Conversions-factors.
    International Fertilizer Industry Association(IFA). DATA Statistics. http://www.fertilizer.org/ifa/HomePage/STATISTICS
    International Fertilizer Industry Association(IFA). Global Estimates of Gaseous Emissions of NH3, NO and N2O from Agricultural Land. http://www.fertilizer.org/ifa/HomePage/LIBRARY/Publication-database.html/Global-Estimates-of-Gaseous-Emissi ons-of-NH3-NO-and-N20-from-Agricultural-Land.html.
    International Fertilizer Industry Association(IFA).2012. Production and international trade 2012-2013, The 38th IFA enlarged Council Meeting,11.28-29.Nov.
    International Fertilizer Industry Association(IFA).2012. Short-Term Prospects for World Agriculture and Fertilizer Demand. The 38th IFA enlarged Council Meeting,11.28-29.Nov.
    Intergovernmental Panel on Climate Change (IPCC).2006. IPCC. Guidelines for National Greenhouse Gas Inventories.
    Jasmin.2001. Slough sewage treatment works UK potential for struvite recovery//the Second International Conference on the Recovery of Phosphorus from Sewage and Animal Wastes, CEFIC, CEEP. SCOPE Newsletter 41,607
    Ju, X. T., Kou, C. L., Zhang, F. S., et al.2006. Nitrogen balance and groundwater nitrate contamination:Comparison among three intensive cropping systems on the North China Plain. Environmental Pollution,143(1),117-125.
    Ju, X. T., Xing, G. X., Chen, X. P., et al.2009. Reducing environmental risk by improving N management in intensive Chinese agricultural systems. Proceedings of the National Academy of Sciences,106(9),3041-3046.
    Ju, X.T., Liu, X. J., Zhang, F. S., et al.2004. Nitrogen fertilization, soil nitrate accumulation, and policy recommendations in several agricultural regions of China. AMBIO:A Journal of the Human Environment,33(6), 300-305.
    Ju, X.T., Liu, X. J., Zhang, F. S., et al.2005. Utilization and management of organic wastes in Chinese agriculture:Past, present and perspectives. Science in China Series C:Life Sciences,48(2),965-979.
    Kauwenbergh. V.2010. World Phosphate Rock Reserves and Resources Technical Bulletin. IFDC-T-75.
    Li, H.G., Huang, G.Q., Meng, Q.F., et al.2011. Integrated soil and plant phosphorus management for crop and environment in China. A review. Plant and soil,349(1-2),157-167.
    Li, Y. X., Zhang, W. F., Ma, L., et al.2013. An analysis of China's grain production:looking back and looking forward. Food and Energy Security, http://onlinelibrary.wiley.com/doi/10.1002/fes3.41/full
    Lienert, J., Larsen, T. A.2007. Soft Paths in Wastewater Management The Pros and Cons of Urine Source Separation. Gaia-Ecological Perspectives for Science and Society,16(4),280-288.
    Lindkvist, M., Gren, M., Elofsson, K.2013. A Study of Climate Change and Cost Effective Mitigation of the Baltic Sea Eutrophication. Climate Change-Realities, Impacts Over Ice Cap, Sea Level And Risks,459.
    Lott, J. N., Ockenden, I., Raboy, V., et al.2000. Phytic acid and phosphorus in crop seeds and fruits:a global estimate. Seed Science Research,10(1),11-34.
    Lu Y., Huang Y., Zou J., et al.2006. An inventory of N2O emissions from agriculture in China using precipitation-rectified emission factor and background emission. Chemosphere,65(11):1915-1924.
    Ma, D., Hu, S., Chen, D., et al.2013. The temporal evolution of anthropogenic phosphorus consumption in China and its environmental implications. Journal of Industrial Ecology,17(4),566-577.
    Ma, L., Ma, W. Q., Velthof, G. L., et al.2010. Modeling nutrient flows in the food chain of China. Journal of environmental quality,39(4),1279-1289.
    Ma, L., Velthof, G. L., Wang, F. H., et al.2012. Nitrogen and phosphorus use efficiencies and losses in the food chain in China at regional scales in 1980 and 2005. Science of the Total Environment,434,51-61.
    Makinia, J.2010. Mathematical modelling and computer simulation of activated sludge systems, 1wa Publishing.
    Moore, P. A., Daniel, T. C., Edwards, D. R.2000. Reducing phosphorus runoff and inhibiting ammonia loss from poultry manure with aluminum sulfate. Journal of Environmental Quality,29(1),37-49.
    Morse, G. K., Brett, S. W., Guy, J. A., et al.1998. Review:phosphorus removal and recovery technologies. Science of the total environment,212(1),69-81.
    Mosaic Homepage. http://www.mosaicco.com/media_center/3102.htm
    OPC Group:Homeapge. http://www.ocpgroup.ma/en/search/node/capacity
    PhosAgro:Homepage. http://www.phosagro.com/search/index.php?q=capacity
    PotashCorp:Homeapge. http://www.potashcorp.com/about/facilities/phosphate/aurora/
    Rao, M. V., Reddy, B. B., Ghosh, B. C., et al.1985. Nitrogen management in direct sown intermediate deep water rice (15-50 cm). Plant and soil,83(2),243-253.
    Ravindran, K. E., Bryden, W. L., Komegay, E. T.1995. Phytates:occurrence, bioavailability and implications in poultry nutrition. Poultry and Avian Biology Reviews (United Kingdom).
    Rittmann, B. E., Mayer, B., Westerhoff, P., et al.2011. Capturing the lost phosphorus. Chemosphere,84(6),846-853.
    Skoglund. E, Larsen. T, Sandberg. A.S.1977. Comparison between steeping and pelleting a mixed diet at different calcium levels on phytata degradation in pigs. Canadian Journal Animal Science,77:471-477.
    Smith K.A.,Mctaggart I.P.,Tsuruta H.2007. Emissions of N2O and NO associated with nitrogen fertilization in intensive agriculture, and the potential for mitigation. Soil Use Manage,13(s4):296-304.
    Smith, D. R., Moore, P. A., Miles, D. M., et al.2004. Decreasing phosphorus runoff losses from land-applied poultry litter with dietary modifications and alum addition. Journal of environmental quality,33(6),2210-2216.
    Smith, K. A., McTaggart, I. P., Tsuruta, H.1997. Emissions of N2O and NO associated with nitrogen fertilization in intensive agriculture, and the potential for mitigation. Soil use and management,13(4),296-304.
    Thorn, K. A., Mikita, M. A.2000. Nitrite Fixation by Humic Substances Nitrogen-15 Nuclear Magnetic Resonance Evidence for Potential Intermediates in Chemodenitrification. Soil Science Society of America Journal,64(2), 568-582.
    Turner, R. E., Rabalais, N. N.1994. Coastal eutrophication near the Mississippi river delta. Nature,368,619-621
    Ueno, Y., Fujii, M.2001.3 years operating experience selling recovered struvite from full-scale plant. In Second international conference on Recovery of Phosphates from sewage and animal waste, Noordwijkerhout, Holland (pp. 12-13).
    United Nations Population Division.2012. http://esa.un.org/unpd/wpp/Excel-Data/population.htm
    Uralkali Homepage.2013. http://www.uralkali.com/about/#tab_2756
    USGS. Mineral Commodity Summaries:Phosphate Rock.2002-2012.
    USGS. http://minerals.usgs.gov/minerals/pubs/commodity/potash
    Vennemo, H., Aunan, K., Lindhjem, H., et al.2009. Environmental pollution in China:Status and trends. Review of Environmental Economics and Policy,3(2),209-230.
    Wang, F., Sims, J. T., Ma, L., et al.2011. The phosphorus footprint of China's food chain:implications for food security, natural resource management, and environmental quality. Journal of environmental quality,40(4),1081-1089.
    Wrage, N., Velthof, G. L., Van Beusichem, et al.2001. Role of nitrifier denitrification in the production of nitrous oxide. Soil Biology and Biochemistry,33(12),1723-1732.
    Xu H., Xing G.X., Cai Z.C., et al.1997. Nitrous oxide emissions from three rice paddy fields in China. Nutr Cycl Agroecosys,49(1):23-28.
    Yan Z.J., Liu P.P., Li Y.H., et al.2013. Phosphorus in China's intensive vegetable production systems:over-fertilization, soil enrichment, and environmental implications. Journal of Environmental Quality,2013,42 (4):982-989.
    Zhang, W. F., Dou, Z. X., He, P., et al.2013. New technologies reduce greenhouse gas emissions from nitrogenous fertilizer in China. Proceedings of the National Academy of Sciences,110(21),8375-8380.
    Zhang, W. F., Ma, W. Q., Ji, Y. X., et al.2008. Efficiency, economics, and environmental implications of phosphorus resource use and the fertilizer industry in China. Nutrient Cycling in Agroecosystems,80(2),131-144.
    Zhou, W., Zhu, B., Li, Q., et al.2010. CO2 emissions and mitigation potential in China's ammonia industry. Energy Policy,38(7),3701-3709.
    鲍荣华,亓昭英.2011.全球钾盐资源分布及钾肥供需形势分析.中国农资,(8):40-45
    闭武勤.2004.型煤工艺在我厂的技术实践.化工技术与开发,(3):48-50,31
    曹兵,李新慧,张琳,等.2001.冬小麦不同基肥施用方式对土壤氨挥发的影响.华北农学报,16(2):83-86
    曹宁,曲东,陈新平,等.2007.从土壤肥力变化预测中国未来磷肥需求.土壤学报,44(3):536-541
    常近时.2013.我国湿法磷酸生产与磷肥施用对环境污染严重.中国石油和化工,(7):26-27
    常苏娟,朱杰勇,刘益.2010.世界磷矿资源形势分析.化工矿物与加工,(9):1-5
    陈玲玲,林振山,郭杰,等.2009.基于EMD的中国粮食安全保障研究.中国农业科学,42(1):180-188
    戴景瑞.1998.发展玉米育种科学迎接21世纪的挑战.作物杂志,(6):14
    董印丽.2001.河北省农田土壤化肥污染及其防治对策.南京农专学报,17(3):47-49
    董志昌.1981.谈谈我厂能耗情况及降低能耗的途径.化肥设计,(6):19-22
    高兵.2012.华北平原不同作物和管理措施温室气体排放及净温室效应.[博士学位论文].北京:中国农业大学
    高利伟,马林,张卫峰,等.2009.中国作物秸秆养分资源数量估算及其利用状况.农业工程学报,25(7):173-179
    高永峰.2009.关于做强我国磷化工产业的建议.化学工业,27(8):19-24
    郭宇杰,王学超,周振民.2012.我国城市污水处理现状调查.环境化学,31(7):1114-1115
    国投新疆罗布泊钾盐有限责任公司主页http://www.sdic.com.cn/cn/tzqy/kgqy/2007/08/1188178175328201.ht
    韩国章,郑长安,林峰.1986.不同磷肥品种在酸性土壤上对大麦的增产效应试验.大麦通讯,(2):40-46
    韩延明.1989.植酸磷的可利用性及钙的影响.国外畜牧科技,16(1):36-37
    郝文强,李翠梅,姜远茂.2012.栖霞市苹果园养分投入状况调查分析.山东农业科学,44(6):77-88
    郝晓.2006.可持续污水-废水处理技术.北京:中国建筑工业厨业出版社,63-68
    贺盼.2010.基于生命周期评价的中国氮肥温室气体排放核算.[硕士学位论文].北京:中国农业大学
    胡波,韩效钊,肖正辉.2005.我国钾长石矿产资源分布、开发、利用、问题与对策.化工矿产地质,27(1):25-32
    胡瑞法,黄季煜,李立秋.2004.中国农技推广体系现状堪忧——来自7省28县的典型调查.中国农技推广,(3):6-8.
    胡天毅.1986.对我国磷矿露天开采中若干技术问题的探讨.化工矿山技术,(4):12-15
    胡小康.2011.华北平原冬小麦-夏玉米轮作体系温室气体排放及减排措施.[博士学位论文].北京:中国农业大学
    黄安智.1995.磷肥生产中的氟污染及其综合利用.云南环境科学,14(1):4546,23
    黄高强,武良,李宇轩,等.2013.我国磷肥产业发展及建议.现代化工,33(11):14
    黄季煜,胡瑞法,智华勇.2009.基层农业技术推广体系30年发展与改革:政策评估和建议.农业技术经济,(1):4-11
    黄江南,余莹.2006.氮肥生产污染及其清洁生产的探讨.江西化工,(4):67-68
    黄耀,孙文娟.2006.近20年来中国大陆农田表土有机碳含量的变化趋势.科学通报,51(7):750-763
    李绵庆,朱爱军.2008.美国Bager等温二水湿法磷酸生产技术的吸收、消化与创新.磷肥与复肥,23(1):19-24
    李永恒.2003.我国氮肥工业历史回顾与发展趋势.化肥工业,31(1):21-23
    李震.2004.预防水域富营养化洗涤剂禁磷刻不容缓.化工环保,24(增刊):461-463
    梁术.1981.中美两国合成氨能耗.现代化工,1
    林葆,李家康.1989.我国化肥的肥效及其提高的途径—全国化肥试验网的主要结果.土壤学报.26(3):273-281
    刘建雄.2009.我国磷矿资源分析与开发利用.化肥工业,36(6):27-31
    刘秀珍,郭丽娜,赵兴杰.不同水分条件下氮肥形态配比对苋菜养分与产量的影响.水土保持学报,2008,22(6):141-144
    刘颐华.2005.我国与世界磷资源及开发利用现状.磷肥与复肥,(5):1-6
    刘颖,项学敏,王刃.2008.城市生活污水中磷的回收和再利用研究进展.环境保护与循环经济,(5):25-27
    柳正.2006.我国磷矿资源的开发利用现状及发展战略.中国非金属矿工业导刊,(1):21-23
    龙涛,余斌,高玉宝.2010.磷矿露天与地下合理开采范围与条件的优化.化工矿物与加工,(1):39-41
    龙涛,余斌,胡建军.2006.磷矿开采对粮食安全的保障及其对策分析.中国矿业,18(5)88-90
    鲁如坤,时正元,熊礼明.1992.我国磷矿磷肥中镉的含量及其对生态环境影响的评价.土壤学报,29(2):150-153
    罗佳捷,张彬,王洁,陈宇光.2011.植酸酶在动物生产中的研究进展.湖南饲料,(2):27-28
    罗云红.2012.10kt/a饲料磷酸氢钙生产工艺改进.磷肥与复肥,(3):38-39
    马凯,马培华,贲艳英.我国需增加硝基肥产量,提升硝态氮施肥比例.磷肥与复肥,2010(1):13-17
    马骥.2006.农户粮食作物化肥施用量及其影响因素分析——以华北平原为例.农业技术经济,6:36-42
    马玺,单安山.2001.植酸酶研究进展及其在饲料工业中的应用粮食与饲料工业.粮食与饲料工业,(4):27-30
    马晓河,蓝海涛.2008.中国粮食综合生产能力与粮食安全.北京:经济科学出版社
    马晓河,王为农.2004.农经发展喜人,要防负担反弹.中国经济信息,25-27
    能源统计年鉴.2011.国家统计局能源统计司.北京:中国统计出版社
    青海盐湖集团股份有限公司主页http://www.qhyhgf.com/wzzwy-f.jsp?urltype=tree.TreeTempUrl&wbtreeid=1002
    全国饲料工作办公室.2011.行业整合加快发展势头不减http://www.boyar.cn/article/2011/05/23/377741.3.shtml
    石小荣,李梅,崔益斌.2012.以太湖流域为例探讨我国淡水生物氨氮基准.环境科学学报,32(6):1406-1414
    孙凯宁,袁亮,李絮花.2010.增值尿素对氨挥发和土壤脲酶活性的影响.山东农业科学,(6):60-62,71
    孙腾良.2007.化肥重大技术装备工作的发展方向.石油和化工设备,(2):19-25
    孙先良.1982.我国化肥工业节能现状及其发展.化肥设计,(6):29-38,114
    谭明,魏明安.2010.磷矿选矿技术进展.矿冶,(4):1-6
    陶俊法.2009.应正确定位我国磷矿资源的现状与前景-我国磷矿资源服务年限分析.磷肥与复肥,24(3):6-8,16
    田琳,谭玉兰,潘万华.2008.磷资源供应与农药发展.世界农药,30(6):23-28
    王昶,吕晓翠,贾青竹.2009.含磷废水处理技术研究进展.水处理技术,35,(12):16-21
    王恩慧.2011.中国饲料生产状况及发展趋势.农业展望,1-4
    王辉,胡全胜.2006.沧州大化大氮肥装置系统节能改造.节能与石油化工,(1):20-21
    王奇峰,易琼,李昆志,等.2010.铝胁迫下柱花草SSH文库构建及表达序列标签分析.植物学报,45(6):679-688
    王山虎.1996.土壤硝化、反硝化过程空问变异性及N20的产生.[硕士学位论文].北京:中国农业大学
    王晓玉,薛帅,谢光辉.2012.大田作物秸秆量评估中秸秆系数取值研究.中国农业大学学报,17(1):1-8
    王孝峰,李永亮.2008我国钾肥产业现状及发展前景分析.中国石油和化工经济分析,(8):20-22
    王雁峰.2011.中国主要粮食作物测土配方施肥工程实施效果及优化策略.[博士学位论文].北京:中国农业大学
    魏鹏.2011.我国磷矿分布特点及主要开采技术.武汉工程大学学报,33(2):108-110
    吴志高.1984.小氮肥厂节能潜力及途径探讨——兼论合成弛放气的利用方式.氮肥技术,(3):17-19,31
    奚振邦.2004.关于化肥对作物产量贡献的评估问题.磷肥与复肥,19(3):68-71
    辛克庆,石永江.1996.庆阳石油化工总厂天然气合成氨生产尿素扩改设计三个方案简介.甘肃化工,(4):21-28
    许俊香,刘晓利,王方浩,等.2005.中国畜禽粪尿磷素养分资源分布以及利用状况.河北农业大学学报,28(4):5-9
    许秀成,侯翠红,崔学军,等.2013.关于推进我国中、低品位磷矿合理利用及提倡“中浓度、多营养、功能性复合肥料”理念的联合倡导方案.
    杨丽珍,魏祥松.2007.北方低品位磷矿综合回收利用选矿研究及应用.化工矿产地质,29(1):27-30
    杨沛浩.2009.磷石膏的综合利用.中国资源综合利用,(1):13-15
    杨胜天,程红光,步青松.2006.全国土壤侵蚀量估算及其在吸附态氮磷流失量匡算中的应用.环境科学学报,2006,26(3):366-374
    杨兆娟,向兰.2007.磷石膏综合利用现状评述.无机盐工业,(1):8-10
    叶学东.2008.树立磷石膏是产品的理念,为磷石膏资源化利用奠定基础.磷肥与复肥,(1):6-8
    宜华集团主页.http://www.hbyihua.cn/viewcontent.aspx?id=1149
    尹丽文.2009.中国磷矿资源分布及开发建议.资源与人居环境,10:26-27
    於子方.2007.合成氨行业能耗现状与主要节能途径.小氮肥,37(2):1-5
    于炎湖.1999.植酸的抗营养作用及植酸酶在饲料中的应用,粮食与饲料工业,2:25-27
    余利丰.2010.我国化肥价格波动与农民收入关系的实证分析.经济学研究.8(31):62-68
    郁红.2013.合成氨:有多少潜力可以变为现实?http://www.ccin.com.cn/ccin/5408/5409/index.shtml
    云天化集团主页http://www.yth.cn/front/product/171.shtml
    张北赢,陈天林,王兵.2010.长期施用化肥对土壤质量的影响.中国农学通报,26(11):182-187
    张福锁,陈新平,陈清.2009.中国主要作物施肥指南.北京:中国农业大学出版社.39
    张福锁,张卫峰,马文奇.2007.中国化肥产业技术与展望.北京:化学工业出版社.109-110.
    张林海.2010.借鉴国外经验完善我国资源税制度.涉外税务,11:44-48
    张强.2009.中国农田施氮引起N2O排放量估算及统计模型构建.[博士学位论文].北京:中国农业大学
    张瑞清.2002.我国农业生态系统的养分平衡[硕士学位论文].山东:莱阳农学院硕士论文
    张田,卜美东,耿维.2012.中国畜禽粪便污染现状及产沼气潜力.中国生态学,31 (5):1241-1249
    张维理,徐爱国,冀宏杰,Kolbe.2004.中国农业面源污染控制中存在问题分析.农业面源污染综合防治.全国农业面源污染与综合防治学术研讨会论文集.1-8
    张卫峰,马林,黄高强,等.2013a.中国氮肥发展、贡献和挑战.中国农业科学,46(15):3161-3171
    张卫峰,马文奇,张福锁,等2005.中国、美国、摩洛哥磷矿资源优势及开发战略比较分析.自然资源学报,20(3):378-386
    张卫峰,张福锁.2013b.中国肥料发展报告.北京:中国农业出版社,153
    张卫峰.2007.中国化肥供需关系及调控战略研究.[博士学位论文].北京:中国农业大学
    张文学.2011.我国磷资源开发利用及趋势.武汉工程大学学报,33(2):1-5
    张毅.2008.氮素形态及其配比对川穹产量与品质的影响.[博士学位论文]雅安:四川农业大学
    张颖.2012.中国农田生态系统氮素的平衡.[博士后出站报告].北京:中国农业大学
    中国化肥信息网.2012.2010. http://www.china-fertinfo.com.cn/viewxx.aspx?id=14973&tb=jrgz
    中国农业科学院蔬菜花卉研究所.2010.中国蔬菜栽培学.北京:中国农业出版社,31-34
    中华人民共和国环境保护部.2010.《中国环境状况公报》.http://jcs.mep.gov.cn/hjzl/zkgb/2010zkgb/
    中华人民共和国统计局.2012.中国统计年鉴北京:中国统计出版社
    朱兆良.2008.中国土壤氮素研究.土壤学报,(5):778-783
    邹国元.2001.冬小麦/夏玉米轮作体系中肥料氮的硝化-反硝化作用研究.[博士学位论文].北京:中国农业大学

© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号

地址:北京市海淀区学院路29号 邮编:100083

电话:办公室:(+86 10)66554848;文献借阅、咨询服务、科技查新:66554700