塑料水性凹印油墨的研究
摘要
塑料水性凹印油墨作为一种新型包装印刷材料,其最大的优点是不含有挥发性有机溶剂,不会对环境产生污染,是一种极具前途的环保型印刷油墨。水性凹印油墨由于在附着力、干燥速度等方面还不能满足印刷的要求,因此在塑料薄膜上的应用还没有得到推广。
本课题采用高速研磨的分散手段,选用多种颜料种类、乳液聚合物和助剂,通过大量实验确定了塑料水性凹印油墨的组分,研究了多种组分对塑料水性凹印油墨性能的影响,得到了塑料水性凹印油墨的优化配方。
研究结果表明,采用高速研磨的分散手段得到的塑料水性凹印油墨样品各项性能良好,基墨的粒径在10μm以下;影响基墨分散性的因素包括颜基比、分散剂种类及其添加量,不同颜色基墨达到最佳分散性能时所采用的颜基比不同;对于黑墨和青墨,混合不同种类分散剂制备的基墨基墨分散状况比使用单一分散剂制备的基墨要好,基墨中分散剂的添加量有一个最佳值,分散剂含量过大或过小都会导致基墨的分散性变差。不同消泡剂在塑料水性凹印基墨中的消泡效率不同,消泡剂A8具有高的消泡效率;单一的树脂配制的油墨往往无法满足油墨印刷适性的要求,通常采用混合不同混合树脂的方法来改善油墨的印刷适性,适合PET和BOPP表面印刷的油墨对应的混合调稀树脂溶液不同;适量的助溶剂可提高塑料水性凹印油墨的干燥速度,同时降低油墨体系的表面张力,流平剂主要对油墨的光学性能产生影响,而基材润湿剂的加入通过降低接触角,改善了油墨在塑料表面的润湿,油墨的印刷适性也得到较大的改善,影响油墨附着力的主要因素是调稀树脂、颜基比、分散剂种类及其添加量。
As a new packaging and printing material, the biggest advantage of plastic water-based gravure ink is it do not contain volatile organic solvents and do not polute the environment, it will be environment-friendly printing ink with good future. As plastic water-based gravure ink can not meet the requirements of printability in adherence and dryness, the application of water-based ink on plastic has not been promoted.
This project adopted dispering method of high speed grinding, selecting many kinds of pigments, emulsions and additions, determining the component of plastic water-based gravure ink through many experiments, developing the effects of component on performance of plastic water-based gravure ink, abtaining the optimum formulation of plastic water-based gravure ink.
The result indicated that, the performance of plastic water-based gravure ink prepared by high speed grinding was good, the particle size of primary ink was below 10μm. The factors which influenced dispersivity of primary ink included pigment/resin ratios, types and amounts of dispersant. The pigment/resin ratios were different when preparing different types of primary inks with good dispersivity. The dispersivity of primary ink prepared by mixed dispersants was better than that prepared by single dispersant in both black and cyan inks. The amounts of dispersant in primary ink had a best value. Dispersivity of primary ink became worse when the the amount of dispersant was too large or too little. Different defoamers in the plastic water-based gravure ink had different results. The defoamer of 810 had great efficiency of defoaming. Inks prepared by single resin would not satisfy the desire of printability. In order to obtain inks with good printability, the method of mixing different types of resins was used. The mixed resin solution of inks was different on PET and BOPP. Proper quantities of cosolvent could increase drying rate and reduce the suface tention of the system. Levelling agent could improve optical performance of the inks. Substrate wetting agent improved the wetting condition by reducing the contact angle, and at the same time printablity of inks was also improved. The factors which influenced adherence of inks included resins, pigment/resin ratios, different types and amounts of dispersant.
本课题采用高速研磨的分散手段,选用多种颜料种类、乳液聚合物和助剂,通过大量实验确定了塑料水性凹印油墨的组分,研究了多种组分对塑料水性凹印油墨性能的影响,得到了塑料水性凹印油墨的优化配方。
研究结果表明,采用高速研磨的分散手段得到的塑料水性凹印油墨样品各项性能良好,基墨的粒径在10μm以下;影响基墨分散性的因素包括颜基比、分散剂种类及其添加量,不同颜色基墨达到最佳分散性能时所采用的颜基比不同;对于黑墨和青墨,混合不同种类分散剂制备的基墨基墨分散状况比使用单一分散剂制备的基墨要好,基墨中分散剂的添加量有一个最佳值,分散剂含量过大或过小都会导致基墨的分散性变差。不同消泡剂在塑料水性凹印基墨中的消泡效率不同,消泡剂A8具有高的消泡效率;单一的树脂配制的油墨往往无法满足油墨印刷适性的要求,通常采用混合不同混合树脂的方法来改善油墨的印刷适性,适合PET和BOPP表面印刷的油墨对应的混合调稀树脂溶液不同;适量的助溶剂可提高塑料水性凹印油墨的干燥速度,同时降低油墨体系的表面张力,流平剂主要对油墨的光学性能产生影响,而基材润湿剂的加入通过降低接触角,改善了油墨在塑料表面的润湿,油墨的印刷适性也得到较大的改善,影响油墨附着力的主要因素是调稀树脂、颜基比、分散剂种类及其添加量。
As a new packaging and printing material, the biggest advantage of plastic water-based gravure ink is it do not contain volatile organic solvents and do not polute the environment, it will be environment-friendly printing ink with good future. As plastic water-based gravure ink can not meet the requirements of printability in adherence and dryness, the application of water-based ink on plastic has not been promoted.
This project adopted dispering method of high speed grinding, selecting many kinds of pigments, emulsions and additions, determining the component of plastic water-based gravure ink through many experiments, developing the effects of component on performance of plastic water-based gravure ink, abtaining the optimum formulation of plastic water-based gravure ink.
The result indicated that, the performance of plastic water-based gravure ink prepared by high speed grinding was good, the particle size of primary ink was below 10μm. The factors which influenced dispersivity of primary ink included pigment/resin ratios, types and amounts of dispersant. The pigment/resin ratios were different when preparing different types of primary inks with good dispersivity. The dispersivity of primary ink prepared by mixed dispersants was better than that prepared by single dispersant in both black and cyan inks. The amounts of dispersant in primary ink had a best value. Dispersivity of primary ink became worse when the the amount of dispersant was too large or too little. Different defoamers in the plastic water-based gravure ink had different results. The defoamer of 810 had great efficiency of defoaming. Inks prepared by single resin would not satisfy the desire of printability. In order to obtain inks with good printability, the method of mixing different types of resins was used. The mixed resin solution of inks was different on PET and BOPP. Proper quantities of cosolvent could increase drying rate and reduce the suface tention of the system. Levelling agent could improve optical performance of the inks. Substrate wetting agent improved the wetting condition by reducing the contact angle, and at the same time printablity of inks was also improved. The factors which influenced adherence of inks included resins, pigment/resin ratios, different types and amounts of dispersant.
引文
[1]辛秀兰.水性油墨[M].北京:化学工业出版社,2005
[2]方红霞.高档水基柔版油墨的研制和开发. 2002
[3]洪申伟.凹印水性油墨的现状与今后的课题[J].印刷杂志,1995
[4]楼永财.水性多用途塑料复合与表印系列油墨及其制备方法.知识产权出版社,2003
[5]周震.印刷油墨(第二版)[M].北京:化学工业出版社,2006
[6]卢文辉 虞永跃.水性塑料油墨的应用[J].中国包装报,2004
[7]李凤华,王肖伟.浅谈水性油墨[J].印刷世界,2006
[8]侯玲玲.水性油墨性能及应用分析[J].网印工业,2007
[9]卢庆沙,任群.水性凹版塑料薄膜油墨在印刷中的应用[J].印刷杂志,2002
[10]王小妹.水性塑料复合油墨.知识产权出版社,2003
[11]马禾.浅谈塑料薄膜凹版印刷水性油墨的特点[J].塑料包装,2006
[12]金振华.环保型水性油墨的研发和市场展望[J].湖北化工,2002
[13]李荣兴.油墨[M].北京:印刷工业出版社,1986
[14]费华,张莉莎,周赛春.丙烯酸类树脂为基料的水性油墨的研究[J].华中师范大学学报,2001
[15]周震,凌云星,赵诗华.油墨研发新技术[M]. 北京:化学工业出版社,2006
[16]董明达,王城.纸张油墨的印刷适性[M]. 北京:印刷工业出版社,2001
[17]钱逢麟,竺玉书.涂料助剂—品种和性能手册[M].北京:化学工业出版社,2003
[18]林剑雄,黄勇平,王小妹,麦堪成,马宏.不同种类消泡剂在水性油墨中的性能[J].中国科技成果,2003
[19]王能友.墨膜附着力的检测[J].丝网印刷,2005
[20]王能友.包装漆膜附着力的检测与分析[J].中国包装业
[21]蔡栋宇,项尚林,陈贤益,张文.以聚氨酯–聚丙烯酸酯乳液为连接料的塑料凹版水性油墨的研制[J].包装工程,2005
[22]王新城.影响油墨附着牢度的因素[J].丝网印刷,2005
[23]赵新.浅谈油墨干燥类型及干燥机理[J].广东印刷,2001
[24]任俊,沈健,卢寿慈.颗粒分散科学与技术[M]. 北京:化学工业出版社,2005
[25]林宣益.涂料助剂(第二版)[M]. 北京:化学工业出版社,2006
[26]黄宪章,黄登宇.有机硅消泡剂消泡机理、特性及其用途研究[J].科技情报开发与经济,2003
[27]李云雁,胡传荣.试验设计与数据处理[M].北京:化学工业出版社,2005
[28]Maria Rentzhog,Andrew Fogden. Print quality and resistance for water-based flexography on polymer-coated boards: Dependence on ink formulation and substrate pretreatment. [M] Progress in Organic Coating, 2006
[29]洪啸吟.冯汉保.涂料化学(第二版)[M].北京.科学出版社,2005
[2]方红霞.高档水基柔版油墨的研制和开发. 2002
[3]洪申伟.凹印水性油墨的现状与今后的课题[J].印刷杂志,1995
[4]楼永财.水性多用途塑料复合与表印系列油墨及其制备方法.知识产权出版社,2003
[5]周震.印刷油墨(第二版)[M].北京:化学工业出版社,2006
[6]卢文辉 虞永跃.水性塑料油墨的应用[J].中国包装报,2004
[7]李凤华,王肖伟.浅谈水性油墨[J].印刷世界,2006
[8]侯玲玲.水性油墨性能及应用分析[J].网印工业,2007
[9]卢庆沙,任群.水性凹版塑料薄膜油墨在印刷中的应用[J].印刷杂志,2002
[10]王小妹.水性塑料复合油墨.知识产权出版社,2003
[11]马禾.浅谈塑料薄膜凹版印刷水性油墨的特点[J].塑料包装,2006
[12]金振华.环保型水性油墨的研发和市场展望[J].湖北化工,2002
[13]李荣兴.油墨[M].北京:印刷工业出版社,1986
[14]费华,张莉莎,周赛春.丙烯酸类树脂为基料的水性油墨的研究[J].华中师范大学学报,2001
[15]周震,凌云星,赵诗华.油墨研发新技术[M]. 北京:化学工业出版社,2006
[16]董明达,王城.纸张油墨的印刷适性[M]. 北京:印刷工业出版社,2001
[17]钱逢麟,竺玉书.涂料助剂—品种和性能手册[M].北京:化学工业出版社,2003
[18]林剑雄,黄勇平,王小妹,麦堪成,马宏.不同种类消泡剂在水性油墨中的性能[J].中国科技成果,2003
[19]王能友.墨膜附着力的检测[J].丝网印刷,2005
[20]王能友.包装漆膜附着力的检测与分析[J].中国包装业
[21]蔡栋宇,项尚林,陈贤益,张文.以聚氨酯–聚丙烯酸酯乳液为连接料的塑料凹版水性油墨的研制[J].包装工程,2005
[22]王新城.影响油墨附着牢度的因素[J].丝网印刷,2005
[23]赵新.浅谈油墨干燥类型及干燥机理[J].广东印刷,2001
[24]任俊,沈健,卢寿慈.颗粒分散科学与技术[M]. 北京:化学工业出版社,2005
[25]林宣益.涂料助剂(第二版)[M]. 北京:化学工业出版社,2006
[26]黄宪章,黄登宇.有机硅消泡剂消泡机理、特性及其用途研究[J].科技情报开发与经济,2003
[27]李云雁,胡传荣.试验设计与数据处理[M].北京:化学工业出版社,2005
[28]Maria Rentzhog,Andrew Fogden. Print quality and resistance for water-based flexography on polymer-coated boards: Dependence on ink formulation and substrate pretreatment. [M] Progress in Organic Coating, 2006
[29]洪啸吟.冯汉保.涂料化学(第二版)[M].北京.科学出版社,2005