BAF强化二级出水处理效能的中试研究
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摘要
随着城市化脚步进程的加快,国家为加强对城镇污水处理厂建设和运行的管理,提高了污水排放标准,污水厂不得不在原有基础上进行升级改造。曝气生物滤池作为一种成熟的生物膜技术,在城市污水升级改造中有较好的应用前景。
     本文研究了BAF工艺在污水厂二级出水中的应用。首先针对污水厂二级出水中污染物特征,筛选、驯化出10株菌进行单菌株净水效能实验,对比考察了不同菌株对污水COD及总氮的去除效果;优选出Q1、Q5、L4、ZW四株菌株进行复配试验,确定Q1与ZW按照菌量比1:1复配,作为接种菌剂投加到反应器中,用于BAF的启动。
     在太平污水厂建立中试研究模型,摸索曝气生物滤池在实际应用中的运行参数。分别采用自然挂膜和人工投菌的启动方式,研究不同启动方法的启动时间及处理效果。确定采用人工投菌法,经过9天启动成功。研究了反应器沿程高度各污染物去除情况,确定滤池有效高度在1.5m-1.8m之间。通过调控不同的运行参数,探索不同的水力负荷及气水比对反应器去除效率的影响,指出在水力负荷为1.25 m3/m2·h、进水流量为22.12 L/h、停留时间为0.54h、气水比控制在10:1左右的条件下,出水处理效果最好。确定了曝气生物滤池反冲洗参数,冲洗周期18d,气洗3min,强度为8-10 L/(m2·s),气水联合冲洗3min,水洗强度为2-3 L/(m2·s),最后水漂洗5min。通过摸索能够处理二级出水的BAF反应器运行参数,为反应器的设计提供依据,为BAF工艺的工程应用提供试验依据。
     生物膜是BAF的核心。本文探讨了BAF生物膜形成机理,微生物通过载体与自身的相互作用,固定在填料上,通过特殊的基质扩散方式,导致微生物分级分层现象。本文研究了BAF系统生物群落结构多样及活性,分析系统内细菌群落结构随时间的演替规律,指出投加工程菌能够与水中土著微生物共同形成优势菌群;探索了不同滤池位置处生物群落多样性变化及演替规律,为曝气生物滤池的设计及稳定高效运行提供微生物方面的依据。
Severe quality standards has been published which forced sewage treatment plants to upgrade. Biological aerated filter is a reactor having double functions,including biofilm and activated sludge,which has better application prospect in secondary treatment of urban sewage.
     Treatment of secondary effluent from a wastewater treatment plant by biological aerated filter was discussed in this paper. Ten bacterial strains obtained from the wastewater by separating and domesticating were used to treatment wastewater experimental of Single strain; the removal efficiency of COD and total nitrogen were studied to obtain the dominant bacteria: Q1、Q5、L4、ZW which were then used in composite stabilizer test. Study result showed that the suitable start-up conditions were Q1:ZW as the percentage of 1:1.
     Pilot scale text model was established in TaiPing wastewater treatment plant to grope the practical running parameters of BAF. Experiments on start-up forms demonstrated that the way of artifical adding bacteria was better tha natrual enrichment both on start-up time and on the subsequent treatment effect. The biological aerated filter was successfully started up within 9 days. The suggested conditions for wastewater treatment by BAF were: heights1.5m-1.8m, hydraulic loading1.25 m3/m2·h, water flow 22.12 L/h , HRT 0.54h,gas-water ratio10:1 under which the effect was the best. During the process, a simple and periodic backwash was used to regenerate the used BAF, with gas rate 8-10 L/(m2·s),water rate 2-3 L/(m2·s) and back washing time 11min.The capability of regenerated BAF was recovered almost completely after reprocess.
     The mechanism of biofilm forming were investigated and it was found that interception and adsorption closely lined with biofilm forming. Also diversity and activity of microbial community of BAF were examined and the succession rule of indigenous microorganisms was analyzed; How microbial community structure changed along different heights were discussed. These studies have not only developed the theory of biological aerated filter in some extent, but also will provide a foundation for the application of BAF to water deep treatment.
引文
1.城市水环境可持续发展.北京:中国建筑工业出版社.
    2.国家环保局.2008年环境公报.中国环境科学出版社,2008.
    3.于萍萍,张尽忠,林存刚.水资源现状分析及保护对策的研究[J].资源环境与发展.2006,2:21-27.
    4.张薇,史开武,孔惠.曝气生物滤池(BAF)的发展与现状[J].北京石油化工学院学报, 2005,(03) .
    5.冯奇,邱珊,马放,陶鑫. Efficiency characterization of ceramic filtering materials used for drinking water treatment[J].Journal of Harbin Institute of Technology, 2007,(05)
    6.刘灿灿,金吴云,沈耀良.上流式曝气生物滤池两种填料启动挂膜的试验研究[J].江苏环境科技,2008,21(1):61~64.
    7.贾国正,张林生,张显球,等.曝气生物滤池技术的研究与应用[J].水资源保护,2006,22(4):71~74.
    8.邹伟国,沈裘昌,李正明,徐立顺,王锦华,李春森. BIOSMEDI工艺在微污染原水预处理中的工程应用[J].给水排水, 2003,(10).
    9.王春荣.曝气生物滤池用于污水处理和回用的净化效能与机理研究.哈尔滨工业大学博士论文,2005.
    10 .熊志斌,邵林广.曝气生物滤池技术研究进展[J].当代化工.2009 ,38(1):61:64.
    11.李汝琪,钱易,孔波,金冬霞.曝气生物滤池去除污染物的机理研究[J].环境科学, 1999,(06) .
    12.Pujol R, Hamon M, Kandel X, et al. Biofilters: flexible,reliable biological reactors .Wat Sci Tech, 1994, 29(10-11) :33-38
    13.潘碌亭.中国微污染水源水处理技术研究现状与进展[J].工业水处理, 2006,(06) .
    14.桑军强,王占生.BAF在微污染源水生物预处理中的应用.中国给水排水[J].2003,19(2):21-23
    15.张杰,曹相生,孟雪征.曝气生物滤池的研究进展[J].中国给水排水, 2002,(08)
    16.乔晓时,许云闳,全燮.BIOFOR曝气生物滤池用于城市污水处理[J].中国给水排水,2004,20(7):83-85
    17.王立立,刘焕彬,胡勇有,周勤.曝气生物滤池处理低浓度生活污水的研究[J].工业水处理,2003,23(3):29-32
    18 .江萍.曝气生物滤池处理城市污水的研究[J].水处理技术, 2003 ,29(3):172-174.
    19.王荣,陈学民.不同流向对曝气生物滤池处理洗浴废水效果的影响[J] .净水技术, 2007-06-015.
    20.曝气生物滤池滤层高度与去除率关系的研究[J].南昌水专学报.2004,23(2):42-45.
    21 . S. S. Athanasios , S. T. Nikolaos , N. Anastasia , et al. Aerobic Biodegradation of Organotin Compounds in Activated Sludge Batch Reactors .Environmental Pullution, 2005,134, 134 (3) :431~438.
    22.Chen J J, Mccarty D, Slack D, et al. Full scale case studies of a simplified aerated filter(BAF)for organics and nitrogen removal .Wat Sci Tech, 2000, 41(4-5) :1-4 .
    23.李汝琪孙长虹钱易.曝气生物滤池处理啤酒废水的研究[J].环境科学,1999,20(4):83-85.
    24.袁泉,郭满囤,蒋洪静.焦化废水生物脱氮工艺[J].山西化工, 2005,(04) .
    25.丁晓玲,贾春宁.生物接触氧化工艺处理难降解有机废水的研究[J].水处理技术, 2005,(07) .
    26.卢徐节,孙芮,柳林,陈季华.水解酸化/接触氧化/生物滤池工艺处理针织印染废水[J].中国给水排水, 2008,(22) .
    27.张征,周兴求,方江敏,汤凌洪,罗周铨.生物滤塔/射流曝气/BAF法处理制糖废水[J].中国给水排水, 2003,(11) .
    28.李文捷,卢少勇,程丽. BAF系统中有机物对氨氮去除的影响研究[J].工业水处理, 2006,(10) .
    29.RebeccaE.Moore,Jo Quarmby,Tom Stephenson. Assessing the potential of foamed clay as a biological aerated filter (BAF) medium[J]. Biotechnology Letters, 1999,21(7) :589~593.
    30.Payraudeau M, Paffoni C, Gousailles M. Tertiary nitrification in an up flow biofilter on floating media: influence of temperature and load .Wat Sci Tech, 2000, 41(45) :21-27 .
    31.Arlene K.Rowan,Jason R.Snape,David Fearnside,et al.Composition and diversity of ammonia-oxidising bacterial communities in wastewater treatment reactors of different design treating identical wastewanter[J].FEMS MicrobiologyEcology,2003,43(2):195~206
    32.赵颖.不同填料曝气生物滤池处理二级出水的对比实验[D].[硕士论文].大连理工大学,2006,6.
    33.夏明芳;陆继来.曝气生物滤池处理印染废水二级出水试验研究[J].污染防治技术, 2006 04
    34.胡保安.曝气生物滤池深度处理石化废水的试验研究[J].中国给水排水, 2007,(07) .
    35.陈玥,齐春对,闫立娟.应用曝气生物滤池深度处理垃圾渗沥液[J].污染防治技术.2006,19(1):3-5.
    36.程晓虎,程晓玲,刘明坤,et al.曝气生物滤池在污水再生利用中的应用.给水排水.2008,34(1):65-66.
    37.李文捷,卢少勇,程丽. BAF系统中有机物对氨氮去除的影响研究[J].工业水处理, 2006,(10) .
    38.Canler J P, Perretl J M. Biological aerated filters: assessment of the process based on 12 sewage treatment palnts .Wat Sci Tech, 1994, 29(10-11) :13-22 .
    39.Chen J J, Mccarty D, Slack D, et al. Full scale case studies of a simplified aerated filter(BAF)for organics and nitrogen removal .Wat Sci Tech, 2000, 41(4-5) :1-4 .
    40. Pujol P, Lemmel H, Goudsilles M. A keypoint of nitrification in an upflow biofiltration reactor .Wat Sci Tech, 1998, 38(3) :43-49 .
    41.Tschui M, Boller M, Gujer W, et al. Tertiary nitrification in aerated pilot biofilters .Wat Sci Tech, 1994, 29(10-11) :53-60 .
    42.Payraudeau M, Paffoni C, Gousailles M. Tertiary nitrification in an up flow biofilter on floating media: influence of temperature and load .Wat Sci Tech, 2000, 41(45) :21-27 .
    43.RebeccaE.Moore,Jo Quarmby,Tom Stephenson. Assessing the potential of foamed clay as a biological aerated filter (BAF) medium[J]. Biotechnology Letters, 1999,21(7) :589~593.
    44.E.B.Muller,A.H.Stouthamer,H.W.Verseveld. Simultaneous NH3 oxidation and N2 production at reduced O2 tensions by sewage sludge subcultured with chemolithotrophic medium[J]. Biodegradation, 1995,6(4) :339~349.
    45.徐丰果,罗建中,凌定勋.废水化学除磷的现状与进展[J].工业水处理, 2003,(05) .
    46.成官文.生物脱氮除磷技术及其在水处理中的应用[J].桂林工学院学报,1996,(01) .
    47.城镇污水处理厂污染物排放标准(GB18918-2002).
    48.《城镇污水处理厂污染物排放标准》(GB18918-2002)修改单.
    49.我国水体富营养化的产生根源与治理对策[J]Journal of Anhui Agricultural Sciences. 2009-21-122.
    50.《污染控制微生物学》.哈尔滨工业大学.
    51.苏俊峰,马放,王弘宇,侯宁,高珊珊,王强.利用PCR-DGGE技术分析生物陶粒硝化反应器中微生物群落动态[J].环境科学学报, 2007,(03)
    52.王弘宇,马放,苏俊峰,左薇,张献旭,张佳.好氧反硝化菌株的鉴定及其反硝化特性研究[J].环境科学, 2007,(7)
    53.左微,马放.《一株好氧反硝化细菌的筛选鉴定及其脱氮特性分析》[D]:[硕士学位论文].哈尔滨工业大学,2006, 6
    54.郭艳微.《好氧反硝化细菌的诱变及固定化技术研究》[D]:[硕士学位论文].吉林大学,2007, 5
    55.王立文,徐敏等.BAF低温挂膜的影响因素分析[J].电力环境保护.2007,23(5):50-51.
    56.Annelies J.Balkema, et al. Indicators for the sustainability assessment of wastewater treatment systems[J].Urban Water,2002(4):153-161.
    57.Thongchai, Panswad .Apiradee Doungchai. Temperature effect on microbial community of enhanced biological phosphorus removal system[J].Water Research,2003,37(8):409-415.
    58.Andrew Dixon,Mattthew Simon,Tom Burkitt.Assessing the environmental impact of two options for small-scale wastewater treatment:comparing a reedbed and an aerated biological filter using a life cycle approach[J].Ecological Engineering,2003(20):297~308.
    59.滕济林,李星伟,殷杰,于光,张文虎,王文兵.废水处理新型填料的挂膜试验研究[J]电力建设, 2002,(02).
    60.Svend Erik Jepsen,et al. Biological filters for post denitrification. Wat Sci Tech,1993,27(56):369~379.
    61.Innocent Nhapi.A framework for the decentralized management of wastewater in Zimbabwe[J].PHYSICS and CHEMISTRY of the EARTH.2004(29):1265-1273.
    62.张晓丹.高效脱氮除磷工艺NPR中试实验研究[D]:[硕士学位论文].中国环境科学研究院,2007, 7.
    63.张杰,陈秀荣.曝气生物滤池反冲洗的特性[J].环境科学.2003,24(5):86-91.
    64.G.Farabegoli,A.Chiavola,E,Rolle.The Biological Aerated Filter (BAF) as alternative treatment for domestic sewage.Journal of Hazardous Materials.2009:1126-1132.
    65.Rother E.Cornel P,Ante A,et,al.Comparison of combined and separated biological aerated filter (BAF) performance for predenitrification/nitrification of municipal wasterwater.Water Sci Technol,2002,46(4-5):149-156.
    66.袁志宇,程晓茹.滤池冲洗方式探讨[J].给水排水,1999,25(1):8-9.
    67.李思敏,宿程远,张建昆.生物砂滤池气水反冲洗的最佳运行参数确定[J].中国给水排水.2007,23(7):102~105.
    68.David Hall,Carolin S,B Fitzpatrick.Research note spectral analysis of pressure cariations during combined air and water backwash of rapid granity filters.Wat,Sci.Tech.1999,33(17):3666-3672.
    69.刘灿灿,金吴云,沈耀良.上流式曝气生物滤池两种填料启动挂膜的试验研究[J].江苏环境科技,2008,21(1):61~64.
    70.蒋侃,马放,孙铁珩,徐善文,苏俊峰,魏利.电气石对好氧反硝化菌株反硝化特性的影响[A]《硅酸盐学报》创刊50周年暨中国硅酸盐学会2007年学术年会论文集[C], 2007.
    71.Shan Qiu,Fang Ma,Lili Feng,Shanwen Xu.A Study on the formation mechanism of biologically immobilized ceramic particles and the distribution rule of microorganisms.ICBBE.2010,15.
    72.Komelia Smalla,Ute Wachtendorf, Holger Heuer, et al. Analysis of Biolog GN substrate utilization patterns by microbial communities[J].Applied Environmental Microbiology,1998,64(4):1220 ~1225.
    73.Rittmann B.E. Biofilm Technology Used to Improve Water Quality [J]. Journal of Shanghai Normal University, 2004,33(4):1~8.

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