等离子体处理有机磷农药废水
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摘要
有机磷农药废水具有污染物浓度高,毒性大,可生化性差等特点,一直是水治理的一个难点。而现有的处理方法存在成本较高、容易引起二次污染、处理周期长、效果差等缺点,难以满足环境污染治理工程的需要。研究结合国家支撑计划重点项目(2006BAC11B06)和江苏省环保科技计划“等离子体处理高浓度有机废水的研究(2000)21.19”,利用电离放电产生等离子体技术对有机磷农药的代表品种敌敌畏和三唑磷进行降解处理,取得了较好的处理效果。
研究内容主要包括有机磷农药的自然降解模拟研究和等离子体处理有机磷农药废水两方面,可为相关研究提供参考与借鉴。
有机磷农药的自然降解模拟研究主要考察了相关因素对降解率的影响。结果表明:降解率随初始浓度的增大而降低;光照对有机磷农药降解影响较弱;降解率随温度的升高而上升;碱性条件更有利于有机磷农药的降解;水体中有机磷农药的降解符合拟一级动力学规律。
等离子体处理有机磷农药废水实验研究中,通过考察有关因素对有机磷农药模拟废水降解率的影响,得出了降解率随各因素的变化趋势。结论如下:降解率随初始浓度的增加而下降;随着温度的升高,降解率先上升后下降,敌敌畏在25℃时达到最大值,而三唑磷在25℃与35℃时降解率变化不明显,当温度高于35℃时降解率出现下降;降解率随pH值的上升先升后降,当pH＜7时变化不太明显。敌敌畏废水在pH值为11时,处理12 min时降解率将近100%,三唑磷废水在pH值为10时,处理12 min时100%降解;降解率随氧气流量的增加呈现下降趋势,随功率的增加呈现较明显的上升趋势;在一定水平条件下,各参数对降解率影响程度的大小依次为:pH值＞温度＞初始浓度＞输入功率＞氧气流量。
实验结果表明等离子体技术用于处理难生物降解的有机磷农药废水是可行的。
It is still a problem to treat the organophosphorus pesticide wastewater effectively, which is characterized as high concentration of organic matter, high toxicity for biotic systems, biorecalcitrant etc. Furthermore, the available methods could not be satisfied to the environmental pollution control engineering by means of their higher costs, lead to secondary pollution, long-term processes and low efficiency. The financial support for this work was provided by the National Key Technology R&D Program (No. 2006BAC11B06) and the Environmental Science and Technology Plan of Jiangsu Province (No. 2000, 21.19). Two typical pesticide wastewaters containing dichlorvos and triazophos were degraded using plasma produced by ionization discharge, respectively.
The dichlorvos and triazophos were degraded in a simulated natural environment and using plasma. And it could provide some valuable references on the following correlation studies.
The effects of the initial wastewater concentration, light, temperature and pH value the natural degradation of organophosphorus pesticide wastewaters had been discussed, respectively. The result shows that: the degradation of organophosphorus pesticide wastewater declined with increase of initial concentration; intensity of light irradiation enhanced the pesticide degradation; the degradation efficiency rose dramatically at high temperature; alkaline condition could accelerated the reaction.
Considering some main parameters, such as initial concentration, temperature, pH value, oxygen flow and intensity of light irradiation, the tendency of the degeneration of the organophosphorus pesticides had been determined. Finally the optimizing condition and impact of the factors were obtained by orthogonal experiments. The degradation efficiency declined as pesticide primary concentration increased. But the temperature had different effect on the degradation that the degradation efficiency of triazophos did not change significantly in the range of 25 degree Centigrade to 35 degree Centigrade. Generally, alkaline condition advantaged the pesticide degradation and the degradation efficiency increased with pH value increased. The dichlorvos had been almost entirely degraded in 12 minutes at the pH value about 11; and the degradation efficiency slightly decreased at the pH value above 11. When the pH value was about 10, the degradation efficiency of triazophos would up to 100% in 12 minutes; and the degradation efficiency would appear less obviously decline at pH value above 10. With the increase of oxygen flow, the degradation efficiency of dichlorvos and triazophos showed a downward trend; and the degradation efficiency pronounced upward trend with the increase of intensity of light irradiation. Under a certain level conditions, pH value had the significant effect on the degradation efficiency, followed by the temperature, concentration, intensity of light irradiation; and the less impact of the degradation efficiency was oxygen flow.
As a conclusion, plasma technology is an effective method for the treatment of organic phosphorus pesticide wastewater.
研究内容主要包括有机磷农药的自然降解模拟研究和等离子体处理有机磷农药废水两方面,可为相关研究提供参考与借鉴。
有机磷农药的自然降解模拟研究主要考察了相关因素对降解率的影响。结果表明:降解率随初始浓度的增大而降低;光照对有机磷农药降解影响较弱;降解率随温度的升高而上升;碱性条件更有利于有机磷农药的降解;水体中有机磷农药的降解符合拟一级动力学规律。
等离子体处理有机磷农药废水实验研究中,通过考察有关因素对有机磷农药模拟废水降解率的影响,得出了降解率随各因素的变化趋势。结论如下:降解率随初始浓度的增加而下降;随着温度的升高,降解率先上升后下降,敌敌畏在25℃时达到最大值,而三唑磷在25℃与35℃时降解率变化不明显,当温度高于35℃时降解率出现下降;降解率随pH值的上升先升后降,当pH＜7时变化不太明显。敌敌畏废水在pH值为11时,处理12 min时降解率将近100%,三唑磷废水在pH值为10时,处理12 min时100%降解;降解率随氧气流量的增加呈现下降趋势,随功率的增加呈现较明显的上升趋势;在一定水平条件下,各参数对降解率影响程度的大小依次为:pH值＞温度＞初始浓度＞输入功率＞氧气流量。
实验结果表明等离子体技术用于处理难生物降解的有机磷农药废水是可行的。
It is still a problem to treat the organophosphorus pesticide wastewater effectively, which is characterized as high concentration of organic matter, high toxicity for biotic systems, biorecalcitrant etc. Furthermore, the available methods could not be satisfied to the environmental pollution control engineering by means of their higher costs, lead to secondary pollution, long-term processes and low efficiency. The financial support for this work was provided by the National Key Technology R&D Program (No. 2006BAC11B06) and the Environmental Science and Technology Plan of Jiangsu Province (No. 2000, 21.19). Two typical pesticide wastewaters containing dichlorvos and triazophos were degraded using plasma produced by ionization discharge, respectively.
The dichlorvos and triazophos were degraded in a simulated natural environment and using plasma. And it could provide some valuable references on the following correlation studies.
The effects of the initial wastewater concentration, light, temperature and pH value the natural degradation of organophosphorus pesticide wastewaters had been discussed, respectively. The result shows that: the degradation of organophosphorus pesticide wastewater declined with increase of initial concentration; intensity of light irradiation enhanced the pesticide degradation; the degradation efficiency rose dramatically at high temperature; alkaline condition could accelerated the reaction.
Considering some main parameters, such as initial concentration, temperature, pH value, oxygen flow and intensity of light irradiation, the tendency of the degeneration of the organophosphorus pesticides had been determined. Finally the optimizing condition and impact of the factors were obtained by orthogonal experiments. The degradation efficiency declined as pesticide primary concentration increased. But the temperature had different effect on the degradation that the degradation efficiency of triazophos did not change significantly in the range of 25 degree Centigrade to 35 degree Centigrade. Generally, alkaline condition advantaged the pesticide degradation and the degradation efficiency increased with pH value increased. The dichlorvos had been almost entirely degraded in 12 minutes at the pH value about 11; and the degradation efficiency slightly decreased at the pH value above 11. When the pH value was about 10, the degradation efficiency of triazophos would up to 100% in 12 minutes; and the degradation efficiency would appear less obviously decline at pH value above 10. With the increase of oxygen flow, the degradation efficiency of dichlorvos and triazophos showed a downward trend; and the degradation efficiency pronounced upward trend with the increase of intensity of light irradiation. Under a certain level conditions, pH value had the significant effect on the degradation efficiency, followed by the temperature, concentration, intensity of light irradiation; and the less impact of the degradation efficiency was oxygen flow.
As a conclusion, plasma technology is an effective method for the treatment of organic phosphorus pesticide wastewater.
引文
[1]林玉锁等.农药与生态环境保护[M].第一版.北京:化学工业出版社,2000
[2]江希流,华小梅.加强农药的环境管理刻不容缓[J].农村生态环境.2000(2):35-38
[3]王雪芳.农药污染与生态环境保护[J].广西农学报.2004(2):21-23
[4]陈先平,林其汉等.一起有机磷农药污染饮用水源引起中毒事件的调查与处理[J].海峡预防医学杂志:2008(2):51-52
[5]华小梅,单正军.我国农药的生产使用状况及其污染环境因子分析[J].环境科学进展.1996(4):33-45
[6]扬友明,柳庸行,王维国.潜在有毒化学品优先控制名单筛选方法研究[J].环境科学研究.1993(5):1-9
[7]任萍.一起有机磷农药污染引起中毒的报告[J].江苏预防医学.2007(4):83-85
[8]徐悦华.纳米二氧化钛光催化降解有机磷农药的研究[J].广州:华南理工大学,2004
[9]娄金生,王宇.水污染治理新工艺与设计[M].第一版.北京海洋出版社,2002
[10]易辰俞,戴友芝.我国有机磷农药废水处理方法的新进展[J].精细化工中间体.2001(4):1-3
[11]谢冰,史家梁,岳宝等.有机磷农药废水处理技术[J].化工环保.1999(4):89-92
[12]杜敏,李世华,李娟.混凝沉淀法预处理乐果农药废水的研究[J].中山大学学报.1999(3):94-97
[13]W H Glaze.Drinking water Treatment with Ozone[J].Environ,Sci& Technol.1987,21:224-225
[14]Susan J Masten,Simon H R Davies.There are more than 40 municipal wastewater treatment plants in the united states that have ozonation facilities[J].Environ SciTechnol.1994,28:181-185
[15]Hulya Erkonak,Onur O.sogut,Mesut Akgun.Treatment of olive mill wastewater by supercritical water oxidation[J].The Journal of Supercdtical Fluids.2008,46:142-148
[16]Jin F M,Kishita A,Moriyo T,et al.Kinetics of oxidation of food wastes with H_2O_2 in supercritical Fluid[J].J.SupercriticalFluids.2001,19:251-262
[17]林春绵,方建平,袁细宁等.超临界水氧化法降解氧乐果的研究[J].中国环境科学.2000(2):305-308
[18]林春绵,袁细宁,杨馗等.超临界水氧化法降解甲胺磷的研究[J].环境科学学报.2000(2):714-718
[19]Aymonier C.Gratias A.Mercadier J,et al.Global reaction heat of acetic acid oxidation in supercritical water[J].Supercritical Fluids.2001,21:219-226
[20]Phillip E S.Johanna R.Nicole S.et al.Oxidation kinetics for met hane:met hanoi mixtures in supercdtical water[J].Supercdtical Fluids.2000,17:155-170
[21]Yukihiko M,Teppei N,Taro U,et al.Supercritical water oxidation of high content rations of phenol[J].Journal of Hazardous Matedal.2000,73:245-254
[22]卞华松,张大年,赵一先.水污染物的超声波降解研究进展[J].环境污染治理技术与设备.2000(1):56-64
[23]王宏青,聂长明,徐伟昌.超声诱导降解有机磷[J].水处理技术.2001(2):109-111
[24]孙德智主编.环境工程中的高级氧化技术[M].第一版.北京:化学工业出版社,2002
[25]侯纪蓉.湿式氧化法处理乐果废水[J].化工环保.1999(2):6-11
[26]沈阳化工研究院环保室.农药废水处理[M].第一版.北京:化工出版社,2000
[27]杨民,王贤高,杜鸿章等.催化湿式氧化处理农药废水的研究[J].工业水处理.2002(2):35-36
[28]荆国华,周作明.UV/Fenton处理三唑磷农药废水[J].华侨大学学报(自然科学版).2006(1):197-200
[29]王敏,董雯,周国柱.UV/Fenton光解处理含三唑磷废水的研究[J].中国环境管理干部学院学报.2007(3):79-81
[30]A.Fujishima,K.Honda.Electrochemical Photolysis of Water at a Semiconductor Eletrode[J].Nature.1972,37:238-245
[31]H.K.Shon,Vigneswaran,H.H.Ngo,J.H.Kim,J.Kandasamy.Effect of flocculation as a pretreatment to photocatalysis in the removal of organic matter from wastewater[J].Separation Purification Technology.2007,56:388-391
[32]Pehkonen SO,Zhang Q.The degradation of organophosphoms pesticides in natural waters a critical review[J].Crit Rev Environ Sci Technol.2002,32:71-72
[33]Burrows HD,Canle LM,Santaballa JA,et al.Reaction pathways and mechanisms of photodegradation of pesticides[J].Photochem Photobiol.2002,67:71-108
[34]Cecile Zamy,Patrick Mazellier and Bernard Legube.Phototransformation of selected organophosphorus pesticides in dilute aqueous solutions[J].Wat Res.2004,38:2305-2314
[35]马维新,徐斌海,顾立新.GC—100光催化降解有机磷农药的研究[J].化工时刊.2001(1):34-37
[36]周波,鲍长利,冯志兵.天然沸石负载TiO_2光催化降解敌敌畏和对硫磷[J].环境污染治理技术与设备.2004(5):33-35
[37]徐悦华,古国榜,伍志锋等.纳米TiO_2光催化降解有机磷农药的研究[J].土壤与环境,2001(2):173-175
[38]武正簧,王宝风.基片上镀TiO_2薄膜光催化降解有机磷农药[J].过程工程学报.2001(1):432-435
[39]陈士夫,梁新,陶跃武等.光催化降解磷酸酯类农药的研究[J].感光科学与光化学.2000(1):7-11
[40]葛飞,易辰俞,陈鹏.TiO_2固定膜光催化降解甲胺磷农药废水[J].中国给水排水.2001(2):9-11
[41]张明让,艾仕云,何国方.分子筛负载纳米TiO_2催化降解有机磷农药废水[J].净水技术.2004(2):7-9
[42]信欣,汤亚飞.活性炭负载TiO_2光降解水中敌敌畏的研究[J].工业用水与废水.2004(3):30-31
[43]H.Heli,M.Jafarian,M.G.Mahjani,F.Gobal.Electro-oxidation of methanol on copper in alkaline solution[J].Electrochimica Acta.2004,49:4999-5006
[44]Junichiro Otomo,Satoru Nishida,Hiroshi Takahashi et al.Electro-oxidation of methanol and ethanol on carbon-supported Pt catalyst at intermediate temperature[J].Journal of Electroanalytical Chemistry.2008,615:84-90
[45]Cao Peiqen,Sun Yuhua,Yao jianlin et al.Adsorption and electro-oxidation of carbon monoxide at the platinum-acetonitrile interface as probed by surface-enhanced Raman spectroscopy[J].Langrnuir.2002,18:2737-2742
[46]Fu Jian-gang,Zhong Hong,Bu xiang-Ming.Electro-oxidation process for molybdenum concentrates[J].Journal of Central South University of Technology(English Edition).2005,12:134-139
[47]雍文彬,孙彦富,陈震华等.铁屑微电解法处理农药废水的研究[J].环境污染治理技术与设备.2002(3):86-88
[48]严文瑶.微电解-ClO_2催化氧化法处理毒死蜱农药废水[J].江苏工业学院学报.2003(1):14-16
[49]张树艳,程丽华,曹为祥.铁炭微电解处理农药废水的研究[J].化学工程师.2004(2):35-37
[50]程鸣,何文英,彭光明等.农药草甘膦生产废水处理的研究[J].工业用水与废水.2003(1):30-32
[51]D.Arapoglou,A.Vlyssides,C.Israilides,et al.Detoxification of methyl-parathion pesticide in aqueous solutions by electrochemical oxidation[J].Journal of Hazardous Materials.2003,98:191-199
[52]Apostolos Vlyssides,Dimitris Arapoglou,Sofia Mai,et al.Electrochemical detoxification of four phosphorothioate obsolete pesticides stocks[J].Chemosphere.2005,58:439-447
[53]邹启光,周恭明.电催化氧化处理有机废水的应用现状和展望[J].福建环境.2003(1):35-36
[54]Yang Xian-li,Bai min-Dong,Han Feng.Study on the degradation of phenol wastewater using hydroxyl radical produced by plasma and the course by UV spectra[J].Guang Pu Xue Yu Guang Pu Fen Xi.2008,28:2649-2652
[55]胡又平,白希尧,严立.高压电晕放电产生离子的研究[J].大连海事大学学报.2008(3):56-58
[56]姜东峰.介质阻挡放电低温等离子体净化脱除柴油机排放物的初步研究[D].天津:天津大学,2005
[57]吴向阳,仰榴青,储金宇,陈钧等.低温等离子体处理废液技术[J].化工环保.2002(3):111-113
[58]王龙.等离子体物理概貌[M].第一版.北京:科学技术文献出版社,1998
[59]赵化侨.等离子体化学与工艺[M].第一版.合肥:中国科学技术大学出版社,1993
[60]朱元右.等离子体技术在废水处理中的应用[J].工业水处理.2004(2):13-16
[61]Yin-Sheng Chen,Xin-Sheng Zhang,Yin-Chun Dai et al.Pulsed high-voltage discharge plasma for degradation of phenol in aqueous solution[J].Separation Purification Technology.2004,34:5-12
[62]Jie Li,Zhigang Zhou,Huijuan Wang,Guofeng Li et al.Research on decoloration of dye wastewater by combination of pulsed discharge plasma and TiO_2 nanoparticles[J].Desalination.2007,212:123-128
[63]Zhang li,Sun Bing,Zhu Xiao Mei.Treatment of wastewater from azo dye production by pulsed discharge plasma technology[J].Dalian Haishi Daxue Xuebao.2007,33:67-70
[64]Ayers.Richard A,Vivona Tony.Pulsed plasma[J].Pollution Engineering.2008,40:45-48
[65]Wolf Rory A,Primm Todd,Florio et al.Innovation through plasma treatment-atnospheric cold plasma sterilization.International Nonwoveus Technical Conference-INTC.2007:438-443.
[66]李胜利,李劲等.高压脉冲放电等离子体处理印染废水的研究[J].中国环境科学.1996,16(1):73-76
[67]Gao Jinzhang,Hu Zhongai,Wang Xiaoyan et al.Degradation of α-naphthol by plasma in aqueous solution[J].Plasma Science&Technology.2001,3(1):641-645
[68]李劲,王泽文,高秋华.放电等离子体水处理技术中的放电问题[J].高电压技术.1997,23(2):7-8
[69]文岳中,姜玄珍,刘维屏.高压脉冲放电与臭氧氧化联用降解水中对氯苯酚[J].环境科学.2002,23(2):73-76
[70]Zhu Tao,Li jian,Liang Wenjun et al.Toluene decomposition in a non-equilibrium plasma[J].Huanjing Kexue Xuebao.2008,28:2299-2304
[71]Jingwei Feng,Zheng Zheng,Jingfei Luan,et al.Gas-liquid hybrid discharge-induced degradation of diuron in aqueous solution[J].Journal of Hazardous Materials.2009,164:838-846
[72]S.Tanaka,H.Uyama,O.Matsumoto.Plasma Chem and Plasma Process[J].1994,14:491
[73]M.R.Ghezzar,F.Abdelmalek,M.Belhadj,et al.Enhancement of the bleaching and degradation of textile wastewaters by Gliding arc discharge plasma in the presence of TiO_2catalyst[J].Journal of Hazardous Materials.2009,164:1266-1274
[74]H.V.Boenig Fundamentals of Plasma Chemistry and Technology[J].Lancaster,UK:Technomic,1988
[75]北京大学数学力学系概率统计编写组.正交设计法[M].第一版.北京:石油化学工业出版社,1976
[76]Kusvuran,E.and O.Erbatur.Degradation of aldrin in adsorbed system using advanced oxidation processes:comparison of the treatment methods[J].Journal of Hazardous Materials.2004,106:115-125
[77]Michael E S,Peter F S.Mechanism of Phrene Photochemical Oxidation in Aqueous and Surfactant Solutions[J].Environ Sci Technol.1998,32:3980-3985
[78]卢桂宁,陶雪琴,杨琛等.土壤中有机农药的自然降解行为[J].土壤.2006(3):130-135
[79]邱道骥,赵启红,刘红等.环境中有机磷农药降解方法的研究进展[J].化工时刊.2006(1):64-67
[80]杨克武,莫汉宏,安凤春等.有机化合物水解的研究方法[J].环境化学.1994(1):206-209
[81]欧晓明.农药在环境中的水解机理及其影响因子研究进展[J].生态环境.2006(2):1352-1359
[82]杨仁斌,彭娟莹,袁芳.农药在环境中的水解途径[J].农业环境科学学报.2006(1):389-391
[83]刘维屏.农药环境化学[M].第一版.北京:化学工业出版社,2006
[84]方晓航,仇荣亮.有机磷农药在土壤环境中的降解转化[J].环境科学与技术.2003(2):57-59
[85]王敏欣,朱书全.水环境中农药的水解研究分析[J].黑龙江科技学院学报.2004(3):75-76
[86]M.J.B.Juarez,A.Zafra-G6mez,B.Luzo et al.Gas chromatographic-mass spectrometric study of the degradation of phenolic compounds in wastewater olive oil by Azotobacter Chroococcum[J].Bioresource Technology.2008,99:2392-2398
[87]A.Zafra,M.J.B.Juarez,R.Blanc,A.Navalon et al.Determination of polyphenolic compounds in wastewater olive oil by gas chromatography-mass spectrometry[J].Talanta.2006,70:213-218
[88]严国奇.高压电晕与臭氧联用技术处理有机磷农药废水的试验研究[D].杭州:浙江工业大学,2006
[89]J.H.Yan,Y.N.Liu,Zh.Bo et al.Degradation of gas-liquid gliding arc discharge on Acid Orange Ⅱ[J].Journal of Hazardous Materials.2008,157:441-447
[90]于红,刘彦民,韩治德等.介质阻挡放电等离子体与淀粉溶液的反应[J].中国石油大学学报(自然科学版).2008(1):108-112
[91]刘亚纳,严建华,李晓东等.滑动弧等离子体处理酸性橙Ⅱ废水[J].化工学报.2008,59(1):220-225
[92]Rotich.Henry K,Zhang Zhouyong,Zhao Yongsheng et al.The adsorption of three organophosphorus pesticides in peat and soil samples and their degradation in aqueous solutions at different temperatures and pH values[J].International Journal of Environmental Analytical Chemistry.2004,84:289-301
[93]邓淑芳,白敏冬,白希尧等.羟基自由基特性及其化学反应[J].大连海事大学学报.2004(3):62-64
[94]胡冰.超声强化臭氧化处理水中有机磷农药的研究[D].大庆:大庆石油学院,2006
[95]Wu J.N.,et al.Oxidation of aqueous phenol by ozone and peroxidase.Advances in Environmental Research[J].2000(4):329-346
[96]许恒韬.臭氧氧化法深度处理硝基氯苯类化工废水研究[D].杭州:浙江大学,2006
[97]宗旭.制取高浓度臭氧水的实验研究[D].大连:大连海事大学,2004
[98]竹涛,李坚,梁文俊等.非平衡等离子体联合技术降解甲苯气体[J].环境科学学报.2008,28(11):2300-2305
[99]竹涛,李坚,梁文俊等.低温等离子体净化甲苯气体的实验研究[J].北京工业大学学报.2008,34(9):971-975
[100]储金宇,吴春笃,陈万金等.臭氧技术及应用[M].第一版.北京:化学工业出版社,2002
[101]依成武.高浓度臭氧产生方法的础研究[D].大连:大连海事大学,2004
[102]代文,陈砺,王红林等.非平衡等离子体降解两种不同VOCs的研究[J].环境科学与技术.2009,32(1):10-13
[103]沈丽,杨波等.产生臭氧等离子体过程的理论基础研究[J].大连海事大学学报.2002(1):97-99
[104]白敏的,白希尧,张芝涛.强电场电离放电产生羟基等离子体反应过程的研究[J].核聚变与等离子体物理.2004,24(3):219-223
[105]李坚,薛红弟,梁文俊等.等离子体法去除HCHO的实验研究[J].北京工业大学学报.2006(6):534-537
[106]李坚,李洁,梁文俊等.等离子体法去除甲醛的实验研究[J].高电压技术.2007(2):171-173
[107]沈丽,白敏的,白希尧等.强电离放电产生高浓度臭氧的实验研究[J].大连海事大学学报.2001,27(1):67-70
[108]邓淑芳,白敏冬,白希尧等.羟基自由基特性及其化学反应[J].大连海事大学学报.2004,30(3):62-63
[2]江希流,华小梅.加强农药的环境管理刻不容缓[J].农村生态环境.2000(2):35-38
[3]王雪芳.农药污染与生态环境保护[J].广西农学报.2004(2):21-23
[4]陈先平,林其汉等.一起有机磷农药污染饮用水源引起中毒事件的调查与处理[J].海峡预防医学杂志:2008(2):51-52
[5]华小梅,单正军.我国农药的生产使用状况及其污染环境因子分析[J].环境科学进展.1996(4):33-45
[6]扬友明,柳庸行,王维国.潜在有毒化学品优先控制名单筛选方法研究[J].环境科学研究.1993(5):1-9
[7]任萍.一起有机磷农药污染引起中毒的报告[J].江苏预防医学.2007(4):83-85
[8]徐悦华.纳米二氧化钛光催化降解有机磷农药的研究[J].广州:华南理工大学,2004
[9]娄金生,王宇.水污染治理新工艺与设计[M].第一版.北京海洋出版社,2002
[10]易辰俞,戴友芝.我国有机磷农药废水处理方法的新进展[J].精细化工中间体.2001(4):1-3
[11]谢冰,史家梁,岳宝等.有机磷农药废水处理技术[J].化工环保.1999(4):89-92
[12]杜敏,李世华,李娟.混凝沉淀法预处理乐果农药废水的研究[J].中山大学学报.1999(3):94-97
[13]W H Glaze.Drinking water Treatment with Ozone[J].Environ,Sci& Technol.1987,21:224-225
[14]Susan J Masten,Simon H R Davies.There are more than 40 municipal wastewater treatment plants in the united states that have ozonation facilities[J].Environ SciTechnol.1994,28:181-185
[15]Hulya Erkonak,Onur O.sogut,Mesut Akgun.Treatment of olive mill wastewater by supercritical water oxidation[J].The Journal of Supercdtical Fluids.2008,46:142-148
[16]Jin F M,Kishita A,Moriyo T,et al.Kinetics of oxidation of food wastes with H_2O_2 in supercritical Fluid[J].J.SupercriticalFluids.2001,19:251-262
[17]林春绵,方建平,袁细宁等.超临界水氧化法降解氧乐果的研究[J].中国环境科学.2000(2):305-308
[18]林春绵,袁细宁,杨馗等.超临界水氧化法降解甲胺磷的研究[J].环境科学学报.2000(2):714-718
[19]Aymonier C.Gratias A.Mercadier J,et al.Global reaction heat of acetic acid oxidation in supercritical water[J].Supercritical Fluids.2001,21:219-226
[20]Phillip E S.Johanna R.Nicole S.et al.Oxidation kinetics for met hane:met hanoi mixtures in supercdtical water[J].Supercdtical Fluids.2000,17:155-170
[21]Yukihiko M,Teppei N,Taro U,et al.Supercritical water oxidation of high content rations of phenol[J].Journal of Hazardous Matedal.2000,73:245-254
[22]卞华松,张大年,赵一先.水污染物的超声波降解研究进展[J].环境污染治理技术与设备.2000(1):56-64
[23]王宏青,聂长明,徐伟昌.超声诱导降解有机磷[J].水处理技术.2001(2):109-111
[24]孙德智主编.环境工程中的高级氧化技术[M].第一版.北京:化学工业出版社,2002
[25]侯纪蓉.湿式氧化法处理乐果废水[J].化工环保.1999(2):6-11
[26]沈阳化工研究院环保室.农药废水处理[M].第一版.北京:化工出版社,2000
[27]杨民,王贤高,杜鸿章等.催化湿式氧化处理农药废水的研究[J].工业水处理.2002(2):35-36
[28]荆国华,周作明.UV/Fenton处理三唑磷农药废水[J].华侨大学学报(自然科学版).2006(1):197-200
[29]王敏,董雯,周国柱.UV/Fenton光解处理含三唑磷废水的研究[J].中国环境管理干部学院学报.2007(3):79-81
[30]A.Fujishima,K.Honda.Electrochemical Photolysis of Water at a Semiconductor Eletrode[J].Nature.1972,37:238-245
[31]H.K.Shon,Vigneswaran,H.H.Ngo,J.H.Kim,J.Kandasamy.Effect of flocculation as a pretreatment to photocatalysis in the removal of organic matter from wastewater[J].Separation Purification Technology.2007,56:388-391
[32]Pehkonen SO,Zhang Q.The degradation of organophosphoms pesticides in natural waters a critical review[J].Crit Rev Environ Sci Technol.2002,32:71-72
[33]Burrows HD,Canle LM,Santaballa JA,et al.Reaction pathways and mechanisms of photodegradation of pesticides[J].Photochem Photobiol.2002,67:71-108
[34]Cecile Zamy,Patrick Mazellier and Bernard Legube.Phototransformation of selected organophosphorus pesticides in dilute aqueous solutions[J].Wat Res.2004,38:2305-2314
[35]马维新,徐斌海,顾立新.GC—100光催化降解有机磷农药的研究[J].化工时刊.2001(1):34-37
[36]周波,鲍长利,冯志兵.天然沸石负载TiO_2光催化降解敌敌畏和对硫磷[J].环境污染治理技术与设备.2004(5):33-35
[37]徐悦华,古国榜,伍志锋等.纳米TiO_2光催化降解有机磷农药的研究[J].土壤与环境,2001(2):173-175
[38]武正簧,王宝风.基片上镀TiO_2薄膜光催化降解有机磷农药[J].过程工程学报.2001(1):432-435
[39]陈士夫,梁新,陶跃武等.光催化降解磷酸酯类农药的研究[J].感光科学与光化学.2000(1):7-11
[40]葛飞,易辰俞,陈鹏.TiO_2固定膜光催化降解甲胺磷农药废水[J].中国给水排水.2001(2):9-11
[41]张明让,艾仕云,何国方.分子筛负载纳米TiO_2催化降解有机磷农药废水[J].净水技术.2004(2):7-9
[42]信欣,汤亚飞.活性炭负载TiO_2光降解水中敌敌畏的研究[J].工业用水与废水.2004(3):30-31
[43]H.Heli,M.Jafarian,M.G.Mahjani,F.Gobal.Electro-oxidation of methanol on copper in alkaline solution[J].Electrochimica Acta.2004,49:4999-5006
[44]Junichiro Otomo,Satoru Nishida,Hiroshi Takahashi et al.Electro-oxidation of methanol and ethanol on carbon-supported Pt catalyst at intermediate temperature[J].Journal of Electroanalytical Chemistry.2008,615:84-90
[45]Cao Peiqen,Sun Yuhua,Yao jianlin et al.Adsorption and electro-oxidation of carbon monoxide at the platinum-acetonitrile interface as probed by surface-enhanced Raman spectroscopy[J].Langrnuir.2002,18:2737-2742
[46]Fu Jian-gang,Zhong Hong,Bu xiang-Ming.Electro-oxidation process for molybdenum concentrates[J].Journal of Central South University of Technology(English Edition).2005,12:134-139
[47]雍文彬,孙彦富,陈震华等.铁屑微电解法处理农药废水的研究[J].环境污染治理技术与设备.2002(3):86-88
[48]严文瑶.微电解-ClO_2催化氧化法处理毒死蜱农药废水[J].江苏工业学院学报.2003(1):14-16
[49]张树艳,程丽华,曹为祥.铁炭微电解处理农药废水的研究[J].化学工程师.2004(2):35-37
[50]程鸣,何文英,彭光明等.农药草甘膦生产废水处理的研究[J].工业用水与废水.2003(1):30-32
[51]D.Arapoglou,A.Vlyssides,C.Israilides,et al.Detoxification of methyl-parathion pesticide in aqueous solutions by electrochemical oxidation[J].Journal of Hazardous Materials.2003,98:191-199
[52]Apostolos Vlyssides,Dimitris Arapoglou,Sofia Mai,et al.Electrochemical detoxification of four phosphorothioate obsolete pesticides stocks[J].Chemosphere.2005,58:439-447
[53]邹启光,周恭明.电催化氧化处理有机废水的应用现状和展望[J].福建环境.2003(1):35-36
[54]Yang Xian-li,Bai min-Dong,Han Feng.Study on the degradation of phenol wastewater using hydroxyl radical produced by plasma and the course by UV spectra[J].Guang Pu Xue Yu Guang Pu Fen Xi.2008,28:2649-2652
[55]胡又平,白希尧,严立.高压电晕放电产生离子的研究[J].大连海事大学学报.2008(3):56-58
[56]姜东峰.介质阻挡放电低温等离子体净化脱除柴油机排放物的初步研究[D].天津:天津大学,2005
[57]吴向阳,仰榴青,储金宇,陈钧等.低温等离子体处理废液技术[J].化工环保.2002(3):111-113
[58]王龙.等离子体物理概貌[M].第一版.北京:科学技术文献出版社,1998
[59]赵化侨.等离子体化学与工艺[M].第一版.合肥:中国科学技术大学出版社,1993
[60]朱元右.等离子体技术在废水处理中的应用[J].工业水处理.2004(2):13-16
[61]Yin-Sheng Chen,Xin-Sheng Zhang,Yin-Chun Dai et al.Pulsed high-voltage discharge plasma for degradation of phenol in aqueous solution[J].Separation Purification Technology.2004,34:5-12
[62]Jie Li,Zhigang Zhou,Huijuan Wang,Guofeng Li et al.Research on decoloration of dye wastewater by combination of pulsed discharge plasma and TiO_2 nanoparticles[J].Desalination.2007,212:123-128
[63]Zhang li,Sun Bing,Zhu Xiao Mei.Treatment of wastewater from azo dye production by pulsed discharge plasma technology[J].Dalian Haishi Daxue Xuebao.2007,33:67-70
[64]Ayers.Richard A,Vivona Tony.Pulsed plasma[J].Pollution Engineering.2008,40:45-48
[65]Wolf Rory A,Primm Todd,Florio et al.Innovation through plasma treatment-atnospheric cold plasma sterilization.International Nonwoveus Technical Conference-INTC.2007:438-443.
[66]李胜利,李劲等.高压脉冲放电等离子体处理印染废水的研究[J].中国环境科学.1996,16(1):73-76
[67]Gao Jinzhang,Hu Zhongai,Wang Xiaoyan et al.Degradation of α-naphthol by plasma in aqueous solution[J].Plasma Science&Technology.2001,3(1):641-645
[68]李劲,王泽文,高秋华.放电等离子体水处理技术中的放电问题[J].高电压技术.1997,23(2):7-8
[69]文岳中,姜玄珍,刘维屏.高压脉冲放电与臭氧氧化联用降解水中对氯苯酚[J].环境科学.2002,23(2):73-76
[70]Zhu Tao,Li jian,Liang Wenjun et al.Toluene decomposition in a non-equilibrium plasma[J].Huanjing Kexue Xuebao.2008,28:2299-2304
[71]Jingwei Feng,Zheng Zheng,Jingfei Luan,et al.Gas-liquid hybrid discharge-induced degradation of diuron in aqueous solution[J].Journal of Hazardous Materials.2009,164:838-846
[72]S.Tanaka,H.Uyama,O.Matsumoto.Plasma Chem and Plasma Process[J].1994,14:491
[73]M.R.Ghezzar,F.Abdelmalek,M.Belhadj,et al.Enhancement of the bleaching and degradation of textile wastewaters by Gliding arc discharge plasma in the presence of TiO_2catalyst[J].Journal of Hazardous Materials.2009,164:1266-1274
[74]H.V.Boenig Fundamentals of Plasma Chemistry and Technology[J].Lancaster,UK:Technomic,1988
[75]北京大学数学力学系概率统计编写组.正交设计法[M].第一版.北京:石油化学工业出版社,1976
[76]Kusvuran,E.and O.Erbatur.Degradation of aldrin in adsorbed system using advanced oxidation processes:comparison of the treatment methods[J].Journal of Hazardous Materials.2004,106:115-125
[77]Michael E S,Peter F S.Mechanism of Phrene Photochemical Oxidation in Aqueous and Surfactant Solutions[J].Environ Sci Technol.1998,32:3980-3985
[78]卢桂宁,陶雪琴,杨琛等.土壤中有机农药的自然降解行为[J].土壤.2006(3):130-135
[79]邱道骥,赵启红,刘红等.环境中有机磷农药降解方法的研究进展[J].化工时刊.2006(1):64-67
[80]杨克武,莫汉宏,安凤春等.有机化合物水解的研究方法[J].环境化学.1994(1):206-209
[81]欧晓明.农药在环境中的水解机理及其影响因子研究进展[J].生态环境.2006(2):1352-1359
[82]杨仁斌,彭娟莹,袁芳.农药在环境中的水解途径[J].农业环境科学学报.2006(1):389-391
[83]刘维屏.农药环境化学[M].第一版.北京:化学工业出版社,2006
[84]方晓航,仇荣亮.有机磷农药在土壤环境中的降解转化[J].环境科学与技术.2003(2):57-59
[85]王敏欣,朱书全.水环境中农药的水解研究分析[J].黑龙江科技学院学报.2004(3):75-76
[86]M.J.B.Juarez,A.Zafra-G6mez,B.Luzo et al.Gas chromatographic-mass spectrometric study of the degradation of phenolic compounds in wastewater olive oil by Azotobacter Chroococcum[J].Bioresource Technology.2008,99:2392-2398
[87]A.Zafra,M.J.B.Juarez,R.Blanc,A.Navalon et al.Determination of polyphenolic compounds in wastewater olive oil by gas chromatography-mass spectrometry[J].Talanta.2006,70:213-218
[88]严国奇.高压电晕与臭氧联用技术处理有机磷农药废水的试验研究[D].杭州:浙江工业大学,2006
[89]J.H.Yan,Y.N.Liu,Zh.Bo et al.Degradation of gas-liquid gliding arc discharge on Acid Orange Ⅱ[J].Journal of Hazardous Materials.2008,157:441-447
[90]于红,刘彦民,韩治德等.介质阻挡放电等离子体与淀粉溶液的反应[J].中国石油大学学报(自然科学版).2008(1):108-112
[91]刘亚纳,严建华,李晓东等.滑动弧等离子体处理酸性橙Ⅱ废水[J].化工学报.2008,59(1):220-225
[92]Rotich.Henry K,Zhang Zhouyong,Zhao Yongsheng et al.The adsorption of three organophosphorus pesticides in peat and soil samples and their degradation in aqueous solutions at different temperatures and pH values[J].International Journal of Environmental Analytical Chemistry.2004,84:289-301
[93]邓淑芳,白敏冬,白希尧等.羟基自由基特性及其化学反应[J].大连海事大学学报.2004(3):62-64
[94]胡冰.超声强化臭氧化处理水中有机磷农药的研究[D].大庆:大庆石油学院,2006
[95]Wu J.N.,et al.Oxidation of aqueous phenol by ozone and peroxidase.Advances in Environmental Research[J].2000(4):329-346
[96]许恒韬.臭氧氧化法深度处理硝基氯苯类化工废水研究[D].杭州:浙江大学,2006
[97]宗旭.制取高浓度臭氧水的实验研究[D].大连:大连海事大学,2004
[98]竹涛,李坚,梁文俊等.非平衡等离子体联合技术降解甲苯气体[J].环境科学学报.2008,28(11):2300-2305
[99]竹涛,李坚,梁文俊等.低温等离子体净化甲苯气体的实验研究[J].北京工业大学学报.2008,34(9):971-975
[100]储金宇,吴春笃,陈万金等.臭氧技术及应用[M].第一版.北京:化学工业出版社,2002
[101]依成武.高浓度臭氧产生方法的础研究[D].大连:大连海事大学,2004
[102]代文,陈砺,王红林等.非平衡等离子体降解两种不同VOCs的研究[J].环境科学与技术.2009,32(1):10-13
[103]沈丽,杨波等.产生臭氧等离子体过程的理论基础研究[J].大连海事大学学报.2002(1):97-99
[104]白敏的,白希尧,张芝涛.强电场电离放电产生羟基等离子体反应过程的研究[J].核聚变与等离子体物理.2004,24(3):219-223
[105]李坚,薛红弟,梁文俊等.等离子体法去除HCHO的实验研究[J].北京工业大学学报.2006(6):534-537
[106]李坚,李洁,梁文俊等.等离子体法去除甲醛的实验研究[J].高电压技术.2007(2):171-173
[107]沈丽,白敏的,白希尧等.强电离放电产生高浓度臭氧的实验研究[J].大连海事大学学报.2001,27(1):67-70
[108]邓淑芳,白敏冬,白希尧等.羟基自由基特性及其化学反应[J].大连海事大学学报.2004,30(3):62-63