氟氯烃选择性脱氯加氢反应的研究
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摘要
二氯二氟甲烷CCl2F2五氟氯乙烷CClF2CF3和四氯化碳CCl4三种氟氯烃的脱氯加氢被用作研究几类新型加氢脱氯催化剂催化性能的模型反应新型催化剂包括负载型PdCl2-(n-C4H9)4N+Cl-熔融盐以钯配合物为前驱体制备的负载型钯催化剂负载型钯酞菁催化剂和镓修饰的负载型铂催化剂
新型的负载型液膜催化剂负载型PdCl2-(n-C4H9)4N+Cl-熔融盐催化剂首次被用于催化CCl2F2的选择性加氢脱氯反应生成产物主要为具有良好商业应用前景的CH2F2和CHClF2在优化的反应条件下CH2F2 + CHClF2的选择性可达80以上同时该催化剂在广泛的H2/CCl2F2 0.25-10范围内具有良好的催化稳定性熔融盐介质中添加GaCl3和CuCl2能提高负载型PdCl2-(n-C4H9)4N+Cl-熔融盐催化下CCl2F2向CH2F2 + CHClF2转化的选择性遗憾的是该催化体系中CCl2F2向CH2F2或CHClF2单一产物转化的选择性较低< 50有必要进一步探索对单一产物特别是CH2F2生成具有高选择性的催化剂
本文率先在负载型钯酞菁催化剂上实现了CCl2F2加氢脱氯向CH2F2的选择性转化微分反应条件下以氟化物MgF2和AlF3为载体的催化剂PdPc/MgF2和PdPc/AlF3上CH2F2的选择性分别可达80.0和76.0与负载型PdCl2-(n-C4H9)4N+Cl-熔融盐相比负载型钯酞菁催化剂上单一产物CH2F2的选择性有了较大的提高在低H2/CCl2F2摩尔比2 : 1和含HCl和HF等酸性物质的催化反应条件负载型钯酞菁催化剂在上述反应中能够保持良好的催化稳定性酞菁环能够在反应条件下保持结构稳定酞菁环对Pd催化活性相的修饰作用是催化剂保持良好催化稳定性的主要原因进一步的研究揭示部分还原的钯为催化加氢脱氯的活性中心
合成了新型的钯有机配合物二氯二(三苯基膦)钯DCTPPP和二硫氰根二(三苯基膦)钯DTTPPP创新性地作为制备新型负载型钯催化剂的前驱体进一步研究了新型负载型钯催化剂上CCl2F2的选择性加氢脱氯反应结果表明在微分反应条件下DCTPPP/MgF2和DTTPPP/MgF2催化剂上CH2F2的选择性分别可达88.1和85.8催化稳定性考察揭示DCTPPP/MgF2和DTTPPP/MgF2催化剂上CCl2F2加氢脱氯反应能够保持稳定达60小时以上CCl2F2加氢脱氯中新型负载型钯催化剂具有高催化活性高CH2F2选择性和良好的催化稳定性主要归因于钯活性相的高分散度90
以CrF3首次作为加氢脱氯催化剂载体研制了负载型钯催化剂DCTPPP/CrF3和Pd/CrF3与普通的Pd/γ-Al2O3催化剂相比较以CrF3为载体的新型负载型钯催
Dichlorofluoromethane (CCl2F2), chloropentafluroethane (CClF2CF3) and tetrachloro-methane (CCl4) were chosen as the model reactants to evaluate the catalytic activity for selective hydrodechlorination over several novel supported catalysts e.g. supported PdCl2-(n-C4H9)4N+Cl- molten salts, supported palladium phthcyanine catalysts, supported palladium catalysts prepared through organometallic palladium compound as precursors, and supported gallium modified platinum catalysts as describled in follows:
A novel supported liquid phase film catalyst, supported PdCl2-(n-C4H9)4N+Cl- molten salts was firstly found to be an effective catalyst with good stability for selective hydrodechlorination of CCl2F2 (CFC-12) to its alternatives CH2F2 and CHClF2. the selectivity of more than 80% for CH2F2+CHClF2 was achieved under optimized reaction conditions. Addition of GaCl3 and CuCl2 to PdCl2-(n-C4H9)4N+Cl- supported molten salts was beneficial to improve the selectivity to CH2F2+CHClF2.
Supported palladium phthalocyanine was also found to be an interesting catalyst with good stability for selective conversion of CCl2F2 into CH2F2 under flowing hydrogen further. Relatively high selectivities towards CH2F2 formation over palladium phthalocyanine catalysts with fluoride supports were achieved at limited conversion levels (<10%). Particularly, supported palladium phthalocyanine exhibited excellent stability even at low H2/CCl2F2 ratio in the corrosive reaction conditions due to the formation of HCl and HF. The fractionally reduced palladium in palladium phthalocyanine was suggested to be the main active site for the catalytic hydrodechlorination. Moreover, novel supported palladium catalysts were prepared through organometallic Pd compounds including dichlorobistriphenylphosphine palladium (DCTPPP) and dithiocyanatobistriphenylphosphine palladium (DTTPPP) for the hydrodechlorination of CFC-12 for the first time. These catalysts exhibited excellent catalytic activities in hydrodechlorination of CFC-12. Particularly, high selectivities of CH2F2 formation were achieved over the catalysts, DCTPPP/MgF2 with 88.1% and DTTPPP/MgF2 with 85.8%, at a limited conversion level (<5%). No obvious deactivation was observed for DCTPPP/MgF2 and DTTPPP/MgF2 catalysts within 60 hours. The higher catalytic activity, CH2F2 selectivity and catalyst stability may be mainly attributed to high dispersions of palladium.
Additionally, novel CrF3 supported palladium catalysts have been prepared through two different precursors i.e. dichlorobistriphenylphosphine palladium (DCTPPP) and
新型的负载型液膜催化剂负载型PdCl2-(n-C4H9)4N+Cl-熔融盐催化剂首次被用于催化CCl2F2的选择性加氢脱氯反应生成产物主要为具有良好商业应用前景的CH2F2和CHClF2在优化的反应条件下CH2F2 + CHClF2的选择性可达80以上同时该催化剂在广泛的H2/CCl2F2 0.25-10范围内具有良好的催化稳定性熔融盐介质中添加GaCl3和CuCl2能提高负载型PdCl2-(n-C4H9)4N+Cl-熔融盐催化下CCl2F2向CH2F2 + CHClF2转化的选择性遗憾的是该催化体系中CCl2F2向CH2F2或CHClF2单一产物转化的选择性较低< 50有必要进一步探索对单一产物特别是CH2F2生成具有高选择性的催化剂
本文率先在负载型钯酞菁催化剂上实现了CCl2F2加氢脱氯向CH2F2的选择性转化微分反应条件下以氟化物MgF2和AlF3为载体的催化剂PdPc/MgF2和PdPc/AlF3上CH2F2的选择性分别可达80.0和76.0与负载型PdCl2-(n-C4H9)4N+Cl-熔融盐相比负载型钯酞菁催化剂上单一产物CH2F2的选择性有了较大的提高在低H2/CCl2F2摩尔比2 : 1和含HCl和HF等酸性物质的催化反应条件负载型钯酞菁催化剂在上述反应中能够保持良好的催化稳定性酞菁环能够在反应条件下保持结构稳定酞菁环对Pd催化活性相的修饰作用是催化剂保持良好催化稳定性的主要原因进一步的研究揭示部分还原的钯为催化加氢脱氯的活性中心
合成了新型的钯有机配合物二氯二(三苯基膦)钯DCTPPP和二硫氰根二(三苯基膦)钯DTTPPP创新性地作为制备新型负载型钯催化剂的前驱体进一步研究了新型负载型钯催化剂上CCl2F2的选择性加氢脱氯反应结果表明在微分反应条件下DCTPPP/MgF2和DTTPPP/MgF2催化剂上CH2F2的选择性分别可达88.1和85.8催化稳定性考察揭示DCTPPP/MgF2和DTTPPP/MgF2催化剂上CCl2F2加氢脱氯反应能够保持稳定达60小时以上CCl2F2加氢脱氯中新型负载型钯催化剂具有高催化活性高CH2F2选择性和良好的催化稳定性主要归因于钯活性相的高分散度90
以CrF3首次作为加氢脱氯催化剂载体研制了负载型钯催化剂DCTPPP/CrF3和Pd/CrF3与普通的Pd/γ-Al2O3催化剂相比较以CrF3为载体的新型负载型钯催
Dichlorofluoromethane (CCl2F2), chloropentafluroethane (CClF2CF3) and tetrachloro-methane (CCl4) were chosen as the model reactants to evaluate the catalytic activity for selective hydrodechlorination over several novel supported catalysts e.g. supported PdCl2-(n-C4H9)4N+Cl- molten salts, supported palladium phthcyanine catalysts, supported palladium catalysts prepared through organometallic palladium compound as precursors, and supported gallium modified platinum catalysts as describled in follows:
A novel supported liquid phase film catalyst, supported PdCl2-(n-C4H9)4N+Cl- molten salts was firstly found to be an effective catalyst with good stability for selective hydrodechlorination of CCl2F2 (CFC-12) to its alternatives CH2F2 and CHClF2. the selectivity of more than 80% for CH2F2+CHClF2 was achieved under optimized reaction conditions. Addition of GaCl3 and CuCl2 to PdCl2-(n-C4H9)4N+Cl- supported molten salts was beneficial to improve the selectivity to CH2F2+CHClF2.
Supported palladium phthalocyanine was also found to be an interesting catalyst with good stability for selective conversion of CCl2F2 into CH2F2 under flowing hydrogen further. Relatively high selectivities towards CH2F2 formation over palladium phthalocyanine catalysts with fluoride supports were achieved at limited conversion levels (<10%). Particularly, supported palladium phthalocyanine exhibited excellent stability even at low H2/CCl2F2 ratio in the corrosive reaction conditions due to the formation of HCl and HF. The fractionally reduced palladium in palladium phthalocyanine was suggested to be the main active site for the catalytic hydrodechlorination. Moreover, novel supported palladium catalysts were prepared through organometallic Pd compounds including dichlorobistriphenylphosphine palladium (DCTPPP) and dithiocyanatobistriphenylphosphine palladium (DTTPPP) for the hydrodechlorination of CFC-12 for the first time. These catalysts exhibited excellent catalytic activities in hydrodechlorination of CFC-12. Particularly, high selectivities of CH2F2 formation were achieved over the catalysts, DCTPPP/MgF2 with 88.1% and DTTPPP/MgF2 with 85.8%, at a limited conversion level (<5%). No obvious deactivation was observed for DCTPPP/MgF2 and DTTPPP/MgF2 catalysts within 60 hours. The higher catalytic activity, CH2F2 selectivity and catalyst stability may be mainly attributed to high dispersions of palladium.
Additionally, novel CrF3 supported palladium catalysts have been prepared through two different precursors i.e. dichlorobistriphenylphosphine palladium (DCTPPP) and
引文
1 M.J. Molina and F.S. Rowland, Stratospheric sink of chlorofluoromethane: Chlorine atom catalysed destruction of ozone, Nature, 249 (1974) 810.
2 R.S. Stolarski, The antarctic ozone hole, Scient. Am. 258 (1988) 20.
3 S. Solomon, The mystery of the Antarctic ozone ‘hole’, Rev. Geophys. 26 (1988) 131.
4 科技文萃 编辑室, 全球一齐来补天, 科技文萃, 2 (2000 46.
5 United Nation Environment Programme, Report of the Ad-hoc technical advisory committee on ODS destruction technologies, May, 1992.
6 M.J. Prather and R.T. Watson, Stratospheric ozone depletion and future levels of atmospheric chlorine and bromine, Nature, 344 (1990) 729.
7 D.G. Cogan, Investor responsibility research center (USA), 1988,68:65
8 冯元恭, 氯氟烷烃与温室效应, 上海环境科学, 1990,9(9): 36.
9 Climate change, the IPCC scientific assessment, University of Cambridge, 1990.
10 The 1994 report of the scientific assessment working group of IPCC: Radiative Forcaing of Climate Change, IPCC, 1994: p4~28.
11 A. McCulloch, CFC and Halon replacements in the environment, J. Fluor. Chem., 100 (1999) 163; and references there in.
12 L.E. Manzer, An overview of the commercial development of chlorofluorocarbon (CFC) alternatives, Catalysis Today, 13 (1992) 13.
13 J. Burdenauc and R.H. Crabtree, Mineralization of chlorofluorocarbons and aromatization of saturated fluorocarbons by a convenient thermal process, Science, 271 (1996) 340.
14 S. Karmakar and H.L. Greene, Oxidative destruction of chlorofluorocarbons by zeolite catalysts, J. Catal. 138 (1992) 364.
15 S. Karmakar and H.L. Greene, Characterization of Y-and Cr-Y- Zeolite catalysts during theoxidative destruction of CFC-11 and CFC-12, J. Catal. 148 (1994) 324.
16 T.Aida, R. Higuchi and H. Niigama, Decomposition of Freon-12 and methylchlorine over supported gold catalysts, Chem. Lett., 10 (1990) 2247.
17 S. Imamura, K. Imakubo and S. Furuyoshi, Decomposition of dichlorofluoro-methane on BPO4 catalysts, Ind. Eng. Chem. Res.,30 (1991) 2355.
18 S.S. Kumaran, K.P. Lim, J.V. Michael and A.F. Wagner, Thermal decomposition of CF2Cl2, J. Phys. Chem., 99 (1995) 8673.
19 R.G. Tonkyn, S.E. Barlow and T.M. Orlanto, Destruction of carbon tetrachloromethane in a dielectric barrier packed- bed corona reactor, J. App. Phys. 80 (1996) 4877.
20 T. Yamamoto, K. Mizuno, I Tamori, A Ogata, M. Nifuku, M. Michalska and G. Prieto, Catalysis assisted plasma technology for carbon tetrachloride destruction, IEEE Trans. Ind. App. 32 (1996) 100.
21 Y.F. Wang, W.J. Lee, C.Y. Chen and L.T. Hsieh, Decomposition of dichloro-difluoromethane by adding hydrogen in a cold plasma system, Environ. Sci. Technol. 33 (1999) 2234.
22 A. Schizodimou, G. Kyriacou and Ch. Lambrou, Electrochemical reduction of dichlorodifluoromethane in acetonitrile medium to useful fluorinated compounds, J. Electro-analytical Chem. 471 (1999) 26.
23 M.A. Malik, Research on non-equilibrium plasma for toxic VOCs destruction, Ozonation and Methane conversion. [D], Zhejiang University, 1999.
24 C. Menini, C. Park and R. Brydson et al, Low temperature (553K) catalytic growth of highly ordered carbon filaments during hydrodechlorination reaction, J. Phys. Chem. B 104 (2000) 4281.
25 A.R. Pinder, The hydrogenolysis of organic halides, Synthesis (1980) 425.
26 G. Centi, Supported palladium catalysts in environmental catalytic technologies for gaseous emissions, J. Mol. Catal. A: Chemical 173 (2001) 287.
27 T. Imamoto, Reduction of saturated alkyl halides to alkanes, in: I. Fleming (Ed.), Reduction, Vol. 8, Pergamon Press,Oxford, 1991, pp. 793–809.
28 P.Y. Bruice, Organic Chemistry, 2nd Edition, Prentice-Hall,New Jersey, 1998.
29 B. Coq, S. Hub, F. Figueras, D. Tournigant, Convesion under hydrogen of dichlorodifluoromethane over bimetallic palladium catalysts, Appl. Catal. A101 (1993) 41.
30 B. Coq, G. Ferrat, F. Figueras, Convesion of chlorobenzene over palladium and Rhodium catalysts of widely varing dispersion, J. Catal. 101 (1986) 434.
31 A.H. Weiss, B.S. Gambhir, R.B. Leon, Hydrodechlorination of carbon tetrachloride, J. Catal. 22 (1971) 245.
32 H.C. Choi, S.H. Choi, J.S. Lee K.H. Lee, Y.G. Kim, Effects of Pt precursors on hydrodechlorination of carbon tetrachloride over Pt/Al2O3, J. Catal. 166 (1997) 284.
33 S.C. Fung, J.H. Sinfelt, hydrogenolysis of methyl chloride on metals, J. Catal. 103 (1987) 220.
34 P.P. Kulkarni, S.S. Deshmukh, V.I. Kovalchuk, J.L. d’Itri, Hydrodechlorination of dichlorodifluoromethane on carbon supported group VIII noble metal catalysts, Catal. Lett. 61 (1999) 161.
35 P. Bodnariuk, B. Coq, G. Ferrat, F. Figueras, Carbon-chlorine hydrogenolysis over PdRh and PdSn bimetallic catalysts, J. Catal. 116(1989) 459.
36 N. Lingaiah, M.A. Uddin, A. Muto, Y. Sakata, Hydrodechlorination of chlorinated hydrocarbons over metal-carbon composite catalysts prepared by a modified carbo-thermal reduction method, Chem.Commun. (1999) 1657.
37 L. Prati, M. Rossi, Reductive catalytic dehalogenation of light chlorocarbons, Appl. Catal. B 23 (1999) 135.
38 A. Gampine, D.P. Eyman, Catalytic Hydrodechlorination of Chlorocarbons. 2. Ternary OxideSupports for Catalytic Conversions of 1,2-Dichlorobenzene, J. Catal. 179 (1998) 315.
39 E.J.A.X. van de Sandt, A. Wiersma, M. Makkee, H.Vanbekkum, J.A. Moulijn, Catalyst development for the selective hydrodechlorination of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Catal. Today 35 (1997) 163.
40 A. Wiersma, E.J.A.X. van de Sandt, M. Makkee, C.P. Luteijn,H. Vanbekkum, J.A. Moulijn, Process for the selective hydrogenolysis of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Catal. Today 27 (1996) 257.
41 T. Mori, W. Ueda, Y. Morikawa, hydrodechlorinative dimerization of 1,1,1-trifluorohaloethane over Ru/SiO2 catalyst, Catal. Lett. 38 (1996) 73.
42 U. Folli, F. Goldoni, D. Iarossi, S. Shardellati, F. Taddei, Selectivity towards hydrodechlorination and dehalo-coupling in the reduction of trichloromethyl derivatives with iron (II) chloride, J.Chem. Soc., Perkin Trans. II (1995) 1017.
43 E.J.A.X. van de Sandt, A. Wiersma, M. Makkee, H.Vanbekkum, J.A. Moulijn, Palladium black as model catalyst in the hydrogenolysis of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Appl. Catal. A 155 (1997) 59.
44 M. Ocal, M. Maciejewski, A. Baiker, Conversion of CCl2F2 (CFC-12) in the presence and absence of H2 on sol–gel derived Pd/Al2O3 catalysts, Appl. Catal. B 21 (1999) 279.
45 S.S. Deshmukh, V.I. Kovalchuk, V.Y. Borovkov, J.L. d’Itri, FTIR spectroscopic and reaction kinetics study of the interaction of CF3CFCl2 with γ-Al2O3, J. Phys. Chem. B 104 (2000) 1277.
46 B. Coq, J.M. Cognion, F. Figueras, D. Tournigant, convesion under hydrogen of dichlorodifluoromethane over supported palladium catalysts, J. Catal.141 (1993) 21.
47 F. Solymosi, J. Rasko, Infra-Red Spectroscopic Study of the Adsorption and Dissociation of CH2Cl2 on Pd/SiO2: Generation of CH2 Species, J. Catal. 155 (1995) 74.
48 S. Ordonez, H. Sastre, F.V. Diez, Hydrodechlorination of aliphatic organochlorinat-ed compounds over commercial hydrogenation catalysts, Appl. Catal. B 25 (2000) 49.
49 F.H. Ribeiro, C.A. Gerken, G.A. Somorjai, C.S. Kellner, G.W.Coulston, L.E. Manzer, L. Abrams, Turnover rate and kinetic mechanism for the reaction of hydrodechlorination of 1,1-dichlorotetrafluoroethane (CF3CFCl2) over a polycrystalline Pd foil, Catal. Lett. 45 (1997) 149.
50 C.W. Chan, A.J. Gellman, Carbon-chlorine bond cleavage in chlorofluororthanes on Pd (111), Catal. Lett. 53 (1998) 139.
51 M.T. Buelow, G. Zhou, A.J. Gellman, B. Immaraporn, The transition state for metal-catalyzed dehalogenation, Catal.Lett. 59 (1999) 9.
52 O. Exner, Correlation Analysis of Chemical Data, PlenumPress, New York, 1988.
53 Z. Karpinski, K. Early, J.L. d’Itri, Catalytic hydrodechlorination of 1,1-dichlorotetrafluoroethane by Pd/Al2O3, J. Catal. 164 (1996) 378.
54 S. Deshmukh, J.L. d’Itri, Transient kinetics investigations of reaction intermediates involved in CF2Cl2 hydrodechlorination, Catal. Today 40 (1998) 377.
55 A. Wiersma, E.J.A.X. van de Sandt, M. Makkee, H.Vanbekkum, J.A. Moulijn, Process development for the selective hydrogenolysis of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Stud. Surf. Sci. Catal. 101 (1996) 369.
56 A. Wiersma, E.J.A.X. van de Sandt, M.A. den Hollander, H.van Bekkum, M. Makkee, J.A. Moulijn, Comparison of the performance of activated carbon supported noble metal catalysts in the hydrogenolysis of CF2Cl2, J. Catal. 177 (1998) 29.
57 B. Coq, F. Figueras, Structure–activity relationships in catalysis by metals: some aspects of particle size, bimetallic and supports effects, Coord. Chem. Rev. 180 (1998) 1753.
58 M. Makkee, A. Wiersma, E.J.A.X. van de Sandt, H. Van Bekkum, J.A. Moulijn, Development of a palladium on activated carbon for a conceptual process in the selective hydrogenolysis ofCCl2F2 (CFC-12) into CH2F2 (HFC-32), Catal. Today 55 (2000) 125.
59 M. Makkee, E.J.A.X. van de Sandt, A. Wiersma, J.A. Moulijn, Development of a satisfactory palladium on activated carbon catalyst for the selective hydrogenolysis of CCl2F2 (CFC-12) into CH2F2 (HFC-32), J. Mol. Catal. A 134 (1998) 191.
60 K. Early, V.I. Kovalchuk, F. Lonyi, S. Deshmukh, J.L. d’Itri, Catalytic hydrodechlorination of 1,1-dichlorotetrafluoroethane and dichlorofluoromethane catalyzed by Pd on flurinated alumina: the role of support material, J. Catal. 182 (1999) 219.
61 E.J.A.X. van de Sandt, A. Wiersma, M. Makkee, H. Van Bekkum, J.A. Moulijn, Selection of activated carbon for the selective hydrogenolysis of CCl2F2 (CFC-12) into CH2F2 (HFC-32) over palladium-supported catalysts, Appl. Catal. A 173 (1998) 161.
62 W. Juszczyk, A. Malinowski, Z. Karpinski, Hydrodechlorination of CCl2F2 (CFC-12) over γ-alumina supported palladium catalysts, Appl. Catal. A166 (1998) 311.
63 A. Malinowski, W. Juszczyk, M. Bonarowska, J. Pielaszek,Z. Karpinski, Pd-Re/Al2O3: characterization and catalytic activity in hydrodechlorination of CCl2F2, J. Catal. 177 (1998) 153.
64 A. Malinowski, W. Juszczyk, J. Pielaszek, M. Bonarowska, M. Wojciechowska, Z. Karpinski, Magnesium fluoride as a support in hydrodechlorination of CCl2F2 (CFC-12), Chem. Commun. (1999) 685.
65 U.S. EPA, 1992 Toxics Release Inventory Public Data Release, EPA 745-R-94-001, 1994.
66 A.H. Weiss, B.S. Gambhir, R.B. Leon, Hydrodechlorination of carbon tetrachloride, J. Catal. 22 (1971) 245.
67 B.S. Gambhir, A.H. Weiss, Depletion of reactants on a catalytic surface during reaction, J. Catal.
26 (1972) 82.
68 S.Y. Kim, H.C. Choi, O.B. Yanga, K.H. Lee, J.S. Lee, Y.G. Kim, Hydrodechlorination of carbon tetrachloride over supported Pt catalysts, J. Chem. Soc., Chem. Commun. (1995) 2169.
69 H.C. Choi, S.H. Choi, J.S. Lee, K.H. Lee, Y.G. Kim, Hydrodechlorination of Carbon Tetrachloride over Pt/MgO, J. Catal. 161 (1997) 790.
70 J.W. Bae, E.D. Park, J.S. Lee, K.H. Lee, Y.G. Kim, S.H. Yeon, B.H. Sung, Hydrodechlorination of CCl4 over Pt/γ-Al2O3 effects of reaction pressure and diluent gases on distribution of products and catalyst stability, Appl. Catal. A: General 2172 (2001) 79.
71 Z.C. Zhang, B.C. Beard, Genesis of durable catalyst for selective hydrodechlori-nation of CCl4 to CHCl3, Appl. Catal. A: General 174 (1998) 33.
72 S. Ordonez, F.V. Diez, H. Sastre, Hydrodehclorination of tetrachloroethylene over vanadium-modified Pt/Al2O3 catlysts, Catal. Lett. 72 (2001) 177.
73 L.S. Vadlamannati, V.I. Kovalchuk, J.L. d’Itri Dechloriantion of 1,2-dichloroethane catalyzed by Pt-Cu/C: unraveling the role of each metal, Catal. Lett. 58 (1999) 178.
74 K.O. Early, W.D. Rhodes, V.I. Kovalchuk, J.L. d’Itri, Hydrogen-assisted 1,2,3-trichloropropane on supported Pt-Sn catalysts, Appl. Catal. B: evironmental 26 (2000) 257.
75 E.S. Lokteva, V.I. Simagina, E.V. Golubina, I.V. Stoyanova, V.V. Lunin, Formation of C1-C5 hydrocarbons from CCl4 in the presence of carbon-supported palladium catalysts, Kinetics and Catalysis 41 (2000) 776.
76 X. Wu, Y.A. Letuchy, D.P. Eyman, Catalytic hydrodechlorination of CCl4 over silica-supported PdCl2 containing molten salt catalysts: the promotional effects of CoCl2 and CuCl2, J. Catal. 161 (1996) 164.
77 B. Heinrichs, P. Delhez, J.P. Schoebrechts, J.P. Pirard, Palladium-Silver Sol-Gel Catalysts for Selective Hydrodechlorination of 1,2-Dichloroethane into Ethylene, J. Catal.172 (1997) 322.
78 B. Heinrichs, F. Noville, J.P. Schoebrechts, J.P. Pirard, Palladium-Silver Sol-Gel Catalysts for Selective Hydrodechlorination of 1,2-Dichloroethane into Ethylene II. Surface composition ofalloy particles, J. Catal. 192 (2000) 108.
79 B. Heinrichs, J.P. Schoebrechts, J.P. Pirard, Palladium-Silver Sol-Gel Catalysts for Selective Hydrodechlorination of 1,2-Dichloroethane into Ethylene III. Kinetics and reaction mechanism, J. Catal. 200 (2001) 309.
80 L. Prati, M. Rossi, Reductive catalytic dehalogenation of light chlorocarbons, Appl. Catal. B: Environmental 23 (1999) 135.
81 J.W. Bozzelli, Y.M. Chen, S.S.C. Chuang, Catalytic hydrodechlorination of 1,2,-dichloroethane and trichloroethylene over Rh/SiO2 catalyst, Chem. Eng. Commun. 115 (1992) 1.
82 A.H. Weiss, K.A. Krieger, Hydrodechlorination kinetics and reaction mechanism, 6 (1966) 167.
83 A.H. Weiss, S. Valinski, Hydrodechlorination and oligomerization of carbon tetrachloride over nickel Y zeolites, J. Catal. 74 (1982) 136.
84 M. Martino, R. Rosal, H. Sastre, F.V. Diez, Hydrodechlorination of dichlorometh-ane, trichloroethane, trichloroethylene and tetrachloroethylene over sulfided Ni/Mo-γ-alumina catalyst, Appl. Catal. B: Environmental 20 (1999) 301.
85 R.B. Timmons, W.L. Jang, Y. He, D.J.Jr Houpt, Catalytic hydrodechlorination of polyhalogenated hydrocarbons, U.S. Patent 5276240, 1994.
86 L.N. Ito, C.B. Murchison, M.T. Holbrook, A.D. Harley, D.D. Smith, Process for converting chlorinated alkenes to useful less chlorinated alkenes, U.S. Patent 5476979, 1995.
87 A.D. Harley, M.T. Holbrook, D.D. Smith, M.D. Cisneros, L.N. Ito, C.B. Murchison, U.S. Patent 5453557, 1995.
88 A. Morano, C. Alonso, F. Medina, P. Salagre, J.E. Sueiras, R. Terrado, A. Giralt, Conversion of hydrogen of dichlorofluoromethane and chlorofluoromethane over nickel catalysts, Appl. Catal. B 23 (1999) 175.
89 L. Delannoy, J.M. Giraudon, P. Granger, L. Leclereq, G. Leclercq, Group VI transition metal carbides as alternatives in the hydrodechlorination of chlorofluorocarbons, Catal. Today 59 (2000) 231.
90 M.A. Aramendia, V. Borau, I.M. Garcia, C. Jimenez, A.Marinas, J.M. Marinas, F.J. Urbano, Influence of the reaction conditions and catalytic properties on the liquid-phase hydrodechlorination of chlorobenzene over palladium supported catalysts: Activity and deactivation, J. Catal. 187 (1999) 392.
91 Y.C. Cao, X.Z. Jiang, W.H. Song, Z.Q. Bai, X.Q. Fang, Hydrodechlorination of CFC-12 over novel supported palladium catalysts, Catal. Lett. 76 (2001) 53.
92 B. Coq, F. Figueras, S. Hub, D. Tournigant, Effect of the metal-support interaction on the catalytic properties of palladium for the conversion of dichlorodofluoromethane with hydrogen: compariso of oxides and fluorides as supports, J. Phys. Chem. 99 (1995) 11159.
93 D.J. Moon, M.J.Chung, K.Y. Park, S.I. Hong, Deactivation of Pd catalysts in the hydrodechlorination of chloropentafluoroethane, Appl. Catal. A 168 (1998) 159.
94 W.Juszczyk, A.Malinowski, M. Bonarowska, Z. Karpinski, Hydrodechlorination of CCl2F2 (CFC-12) over Pd/Al2O3 catalysts, Polish. J. Chem. 71 (1997) 1314.
95 M. Bonarowska, A. Malinowski, Z. Karpinski, Hydrogenolysis of C–C and C–Cl bonds by Pd–Re/Al2O3 catalysts, Appl. Catal. A 188 (1999) 145.
96 S.P. Scott, M. Sweetman, J. Thomson, A.G. Fitzgerald, E.J. Sturrock, Catalytic hydrogenolysis of 1,1,2-trichlorotrifluoroethane on γ-Al2O3 supported palladium / Zinc oxide catalyst, J. Catal. 168 (1997) 501.
97 A.Hess, E. Kemnitz, Heterogeneous catalyzed dismutation and conmutation reaction of CHCl3-nFn chlorofluorocarbons, Appl. Catal. A 82 (1992) 247.
98 F.R. Reinoso, The role of carbon materials in the heterogeneous catalysts, Carbon 36 (1998) 159.
99 M.H. Schoonenboom, H.E. Zoetemeijer, K. Olie, Dechlorination of octachloro-dibenzo-p-dioxin and octachlorodibenzofunan on an alumina support, Appl. Catal. B 6 (1995) 11.
100 W.X. Zhang, C.B. Wang, H.L. Lien, Treatment of chlorinated organic contaminants with nanoscale bimetallic particles , Catal. Today 40 (1998) 387.
101 R. Ohnishi, I. Suzuki, M. Ichikawa, Bi-Pd for selective hydrodechlorination of 1,1,2-trichlorotrifluoroethane to trifluoroethene, a key intermediate to 1,1,1,2-tetrafluoroethane as a CFC replacements for refrigeration, Chem. Lett. (1991) 841.
102 R. Ohnishi, W.L. Wang, M. Ichikawa, Selective hydrodechlorination of CFC-113 on Bi and Tl-modified palladium catalysts, Appl. Catal. A 113 (1994) 29.
103 M. Bonarowska, A. Malinowski, W. Juszczyk, Z. Karpinski, Hydrodechlorination of CCl2F2 (CFC-12) over Silica-supported palladium-gold catalysts, Appl. Catal. B 30 (2001) 187.
104 F.H. Ribeiro, C.A. Gerken, G. Rupprechter, G.A. Somorjai, C.S. Kellner, G.W. Coulston, L.E. Manzer, L. Abrams, Structure insensitivity and effect of sulfur in the reaction of hydrodechlorination of 1,1-dichlorotetrafluoroethane (CF3CFCl2) over Pd catalysts, J. Catal. 176 (1998) 352.
105 A. Malinowski, M. Bonarowska, Hydrodechlorination of CH2Cl2 over Pd/Al2O3. Correlation with the hydrodechlorination of CCl2F2 (CFC-12), Appl. Catal. B 19 (1998) L79.
106 J.R. Anderson, Structure of Metallic Catalysts, Academic Press, New York, 1975.
107 F.J. Urbano, J.M. Marinas, Hydrogenolysis of organohalogen compounds over palladium supported catalysts, J. Mol. Catal. A 173 (2001) 329, and reference therein.
108 C.C. Chang, C.M. Reo, C.R.F. Lund, The effect of a membrane reactor upon catalyst deactivation during hydrodechlorination of dichloroethane, Appl. Catal. B 20 (1999) 309.
109 P. Forni, L. Prati, M. Rossi, Catalytic dehydrohalogenation of polychlorinated biphenyls Part II: Studies on a continuous process, Appl. Catal. B 14 (1997) 49.
110 G. Rupprechter, G.A. Somorjai, Palladium-catalyzed hydrogenation without hydrogen: the hydrodechlorination of chlorofluorocarbons with solid state hydrogen over the palladium (111) crystal surface and its implications, Catal. Lett. 48 (1997) 17.
1. W. Juszczyk, A. Malinowski and Z. Karpinski, Hydrodechlorination of CCl2F2 (CFC-12) over γ-alumina supported palladium catalysts, Appl. Catal. A: General, 166 (1998) 311.
2. A. Malinowski, W. Juszczyk, J. Pielaszek, M. Bonarowska, M. Wojciechowska and Z. Karpinski, Magnesium fluorideas a catalytic support in hydrodechlorination of CCl2F2, Chem. Commun. (1999) 685.
3. J.E. Benson, H.S. Hwang and M.J. Boudart, Hydrogen-Oxygen Titration Method for the Mesurement of Supported Palladium Surface Areas, J. Catal. 30 (1973) 146.
4. X.Z. Jiang, T.F. Hayden, J.A. Dumesic, Evidence for slow uptake of hydrogen by titania-supported samples: consequence for estimating metallic surface areas, J. Catal. 83 (1983) 168.
1. R. Datta, R.G. Rinker, Supported liquid-phase catalysts I. A theoretical model for transport and reaction, J. Catal. 95 (1985) 181.
2. R. Datta, W. Savage, R.G. Rinker, Supported liquid-phase catalysts II. Experimental evaluation of the flux model for liqid phase porous media, J. Catal. 95 (1985) 193.
3. R. Datta, J. Rydant, R.G. Rinker, Supported liquid-phase catalysts III. Experimental evaluation of the difussion reaction model, J. Catl. 95 (1985) 202.
4. H. Livbjerg, K.F. Jensen, J. Villadsen, Sulfur dioxide oxidation on supported molten V2O5-K2S2O7 catalyst. Influence of liquid diffusion resistance, J. Catal. 45 (1976) 216.
5. A.C. Buchanan, III, A.S. Dworkin, G.P. Smith, Molten salt catalysis. Selective bond cleavage reactions for some α,ω-diphenylalkanes in SbCl3 melts, J. Am. Chem. Soc. 105 (1983), 2843.
6. V. Rao, R. Datta, Development of a supported molten salts Wacker catalyst for the oxidation of ethylene to acetaldehyde, J. Catal. 114 (1988) 377.
7. X. Wu, Y.A. Letuchy, D.P. Eyman, Catalytic hydrodechlorination of CCl4 over silica-supported PdCl2 containing molten salt catalysts: the promotional effects of CoCl2 and CuCl2, J. Catal. 161 (1996) 164.
8. G.J. Janz, Molten salts handbook, Academic Press, New York, 1967.
9. H. Bloom, The chemistry of molten salts, Benjamin, New York, 1967.
10. M.J. Naughton, R,S, Drago, Supported homogeneous film catalysts, J. Catl. 155 (1995) 383.
11. G.W. Parshall, Catalysis in molten salt media, J. Am. Chem. Soc. 94 (1972) 8716.
12. W. Dafinger, L. Schmidhammer, EP 0523553A1, 1991 ( or US 5233106).
13. B. Coq, J.M. Cognion, F. Figueras, D. Tournigant, convesion under hydrogen of dichlorodifluoromethane over supported palladium catalysts, J. Catal.141 (1993) 21.
14. B. Coq, F. Figueras, S. Hub, D. Tournigant, Effect of the metal-support interaction on the catalytic properties of palladium for the conversion of dichlorodofluoromethane with hydrogen: compariso of oxides and fluorides as supports, J. Phys. Chem. 99 (1995) 11159.
15. A. Wiersma, E.J.A.X. van de Sandt, M. Makkee, C.P. Luteijn,H. Vanbekkum, J.A. Moulijn, Process for the selective hydrogenolysis of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Catal. Today 27 (1996) 257.
16. W. Juszczyk, A. Malinowski, Z. Karpinski, Hydrodechlorination of CCl2F2 (CFC-12) over γ-alumina supported palladium catalysts, Appl. Catal. A166 (1998) 311.
17. S. Deshmukh, J.L. d’Itri, Transient kinetics investigations of reaction intermediates involved in CF2Cl2 hydrodechlorination, Catal. Today 40 (1998) 377.
18. P.S.S. Prasad, N. Lingaiah, S. Chandrasekhar, K.S.R. Rao, P.K. Rao, K.V. Raghavan, F.J. Berry, L.E. Smart, Microwave irradiation: an effective method for the preparation of low dispersed Pd/Al2O3 catalysts used in the hydrodechlorination of CCl2F2 to CH2F2, Catal. Lett. 66 (2000) 201.
19. B.S. Ahn, S.G. Jeon, H. Lee, K.Y. Park, Y.G. Shul, Hydrogenolysis of CFC-12 (CF2Cl2) over Pd/γ-Al2O3 pretreated with HCFC-22 (CHF2Cl), Appl. Catal. B: General 193 (2000) 87.
20. Z. Karpinski, K. Early, J.L. d’Itri, Catalytic hydrodechlorination of 1,1-dichlorotetrafluoroethane by Pd/Al2O3, J. Catal. 164 (1996) 378.
21. Y.C. Cao, X.Z. Jiang, Novel catalytic hydrodechlorination of CCl2F2 over supported PdCl2-(n-C4H9)N+Cl- molten salts, Chin. Chem. Lett. 12 (2001) 533.
22. E.E. Getty, S.C. Petrosius, R.S. Drago, The strong solid acid, (SG)nAlCl2, as a catalyst for the dehydrochlorination and hydrodechlorination of polychlorinated molecules, J. Mol. Catal. 67 (1991) 127.
23. 吴越, 催化化学 第二版 , 科学出版社, 北京, 1998, p152.
24. M. Asscher, D. Vofsi, Chlorine activation by redox-transfer. Part I. The reaction between aliphatic amines and carbon tetrachloride, J. Chem. Soc. (1961) 2261.
25. M. Asscher, D. Vofsi, Chlorine activation by redox-transfer. Part II. The addition of carbon tetrachloride to olefins, J. Chem. Soc. (1963) 1887.
26. M. Asscher, D. Vofsi, Chlorine activation by redox-transfer. Part III. The abnormal addition of chloroform to olefins, J. Chem. Soc. (1963) 3921.
27. F.O.H. Pirrung, H.Hiemstra, W.N. Speckamp, Synthesis of medium-sized lactones by the copper (I) chloride/2,2’-bipyridine catalysed cylization of di- and trichloroactates, Tetrahedron, 50 (1994) 12415.
28. F. De Campo, D. Lastecoueres, J.B. Verlhac, New and improved catalysts for transition metal catalysed radical reactions, Chem. Commun. 19 (1998) 2117.
29. P. Martin, E. Steiner, J. Streith, T. Winkler, D. Bellus, Convenient approaches to heterocycles via copper catalysed addition of organic polyhalides to activated olefins, Tetrahedron, 41 (1985) 4057.
30. H. Nagashima, H. Wakamatsu, K. Itoh, Y. Tomo, J. Tsuji, New regio- and stereo-selective preparation of trichlorinated γ-butyrolactones by copper catalyzed cyclization of allyl trichloroacetates, Tetrahedron Letters, 24 (1983) 2395.
31. E. Steiner, P. Martin, D. Bellus, A new simple synthesis of 2,3,5-trichloropyridine, Helvetica Chimica Acta, 65 (1982) 983.
32. R.G. Pews, J.A. Gall, Use of chlorine ion as a catalyst for dehydrochlorination reaction: the synthesis of 3,5,6-trichloropyridin-2-ol, J. Org. Chem. 59 (1994) 6783.
33. R.G. Pews, Z. Lysenko, Synthesis of halogenated pyridine via the CuCl-catalysed addition of polyhaloacetonitriles to olefins, J. Org. Chem. 50 (1985) 5115.
1. Z. Ainbinder, L.E. Manzer and M.J. nappa, Catalytic routes to hydro (chloro)-fluorocarbons, In: G. Ertl, H. Knzoinger, J. Weitkamp Edited Handbook of Heterogeneous Catalysis, Vol 4, (1997) 1677; and references there in.
2. L.E. Manzer, An overview of the commercial development of chlorofluorocarbon (CFC) alternatives, Catalysis Today, 13 (1992) 13.
3. B. Coq, J.M. Cognion, F. Figueras, D. Tournigant, convesion under hydrogen of dichlorodifluoromethane over supported palladium catalysts, J. Catal.141 (1993) 21.
4. B. Coq, F. Figueras, S. Hub, D. Tournigant, Effect of the metal-support interaction on the catalytic properties of palladium for the conversion of dichlorodofluoromethane with hydrogen: compariso of oxides and fluorides as supports, J. Phys. Chem. 99 (1995) 11159.
5. A. Wiersma, E.J.A.X. van de Sandt, M. Makkee, C.P. Luteijn,H. Vanbekkum, J.A. Moulijn, Process for the selective hydrogenolysis of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Catal. Today 27 (1996) 257.
6. E.J.A.X. van de Sandt, A. Wiersma, M. Makkee, H.Vanbekkum, J.A. Moulijn, Catalyst development for the selective hydrodechlorination of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Catal. Today 35 (1997) 163.
7. W. Juszczyk, A. Malinowski, Z. Karpinski, Hydrodechlorination of CCl2F2 (CFC-12) over γ-alumina supported palladium catalysts, Appl. Catal. A166 (1998) 311.
8. A. Wiersma, E.J.A.X. van de Sandt, M.A. den Hollander, H.van Bekkum, M. Makkee, J.A. Moulijn, Comparison of the performance of activated carbon supported noble metal catalysts in the hydrogenolysis of CF2Cl2, J. Catal. 177 (1998) 29.
9. A. Malinowski, W. Juszczyk, M. Bonarowska, J. Pielaszek, Z. Karpinski, Pd-Re/Al2O3: characterization and catalytic activity in hydrodechlorination of CCl2F2, J. Catal. 177 (1998) 153.
10. S. Deshmukh, J.L. d’Itri, Transient kinetics investigations of reaction intermediates involved in CF2Cl2 hydrodechlorination, Catal. Today 40 (1998) 377.
11. A. Malinowski, W. Juszczyk, J. Pielaszek, M. Bonarowska, M. Wojciechowska, Z. Karpinski, Magnesium fluoride as a support in hydrodechlorination of CCl2F2 (CFC-12), Chem. Commun. (1999) 685.
12. P.P. Kulkarni, S.S. Deshmukh, V.I. Kovalchuk, J.L. d’Itri, Hydrodechlorination of dichlorodi-fluoromethane on carbon supported group VIII noble metal catalysts, Catal. Lett. 61 (1999) 161.
13. P.S.S. Prasad, N. Lingaiah, S. Chandrasekhar, K.S.R. Rao, P.K. Rao, K.V. Raghavan, F.J. Berry, L.E. Smart, Microwave irradiation: an effective method for the preparation of low dispersed Pd/Al2O3 catalysts used in the hydrodechlorination of CCl2F2 to CH2F2, Catal. Lett. 66 (2000) 201.
14. J.A. Moulijn, M. Makkee, A. Wiersma, Selective hydrogenolysis of CCl2F2 into CH2F2 overpalladium on activated carbon kinetic mechanism and process design, Catal. Today 59 (2000) 221.
15. B.S. Ahn, S.G. Jeon, H. Lee, K.Y. Park, Y.G. Shul, Hydrogenolysis of CFC-12 (CF2Cl2) over Pd/γ-Al2O3 pretreated with HCFC-22 (CHF2Cl), Appl. Catal. B: General 193 (2000) 87.
16. Y.C. Cao, X.Z. Jiang, W.H. Song, Z.Q. Bai, X.Q. Fang, Hydrodechlorination of CFC-12 over novel supported palladium catalysts, Catal. Lett. 76 (2001) 53.
17. Y.C. Cao, X.Z. Jiang, Novel hydrodechlorination of CCl2F2 over supported PdCl2-(n-C4H9)4N+Cl-molten salts, Chin. Chem. Lett. 12 (2001) 533.
18. A. Morato, C. Alonso, F. Medina, Y. Cesteros, P. Salagre, J.E. Sueiras, D. Tichit, B. Coq, Palladium hydrotalcites as precursors for the catalytic hydroconversion of CCl2F2 (CFC-12) and CHClF2 (HCFC-22), Appl. Catal. B: Environmental 32 (2001) 167.
19. M. Bonarowska, A. Malinowski, W. Juszczyk, Z. Karpi ski, Hydrodechlorination of CCl2F2 (CFC-12) over silica-supported palladium–gold catalysts, Appl. Catal. B: Environmental 30 (2001) 187.
20. A. Wiersma, E.J.A.X. van de Sandt, M. Makkee, J.A. Moulijn, Deactivation of palladium on activated carbon in the selective hydrogenolysis of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Appl. Catal. A: General 212 (2001) 223.
21. C. Gervasutti, L. Marangoni, W. Marra, Hydrogenolysis of dichlorotetrafluoroethane isomeric mixtures for the formation of 1,1,1,2-tetrafluoroethane, J. Fluorine Chem. 19 (1982) 1.
22. Z. Karpinski, K. Early, J.L. d’Itri, Catalytic hydrodechlorination of 1,1-dichlorotetrafluoroethane by Pd/Al2O3, J. Catal. 164 (1996) 378.
23. F.H. Ribeiro, C.A. Gerken, G.A. Somorjai, C.S. Kellner, G.W.Coulston, L.E. Manzer, L. Abrams, Turnover rate and kinetic mechanism for the reaction of hydrodechlorination of 1,1-dichlorotetrafluoroethane (CF3CFCl2) over a polycrystalline Pd foil, Catal. Lett. 45 (1997) 149.
24. F.H. Ribeiro, C.A. Gerken, G. Rupprechter, G.A. Somorjai, C.S. Kellner, G.W. Coulston, L.E. Manzer, L. Abrams, Structure insensitivity and effect of sulfur in the reaction of hydrodechlorination of 1,1-dichlorotetrafluoroethane (CF3CFCl2) over Pd catalysts, J. Catal. 176 (1998) 352.
25. C.W. Chan, A.J. Gellman, Carbon-chlorine bond cleavage in chlorofluororthanes on Pd (111), Catal. Lett. 53 (1998) 139.
26. M.T. Buelow, G. Zhou, A.J. Gellman, B. Immaraporn, The transition state for metal-catalyzed dehalogenation, Catal.Lett. 59 (1999) 9.
27. K. Early, V.I. Kovalchuk, F. Lonyi, S. Deshmukh, J.L. d’Itri, Catalytic hydrodechlorination of 1,1-dichlorotetrafluoroethane and dichlorofluoromethane catalyzed by Pd on flurinated alumina: the role of support material, J. Catal. 182 (1999) 219.
28. G. Zhou, C. Chan, A.J. Gellman, Dechlorination of fluorinated 1,1-dichlororthanes on Pd (111), J. Phys. Chem. B 103 (1999) 1134.
29. A.L.D. Ramos, M. Schmal, D.A.G. Aranda, G.A. Somorjai, Hydrodechlorination of dichlrodifluoromethane over palladium model catalysts and a comparison with the hydrodechlorination of 1,1-dichlorotetrafluoroethane, J. Catal. 192 (2000) 423.
30. S.S. Deshmukh, V.I. Kovalchuk, V.Y. Borovkov, J.L. d’Itri, FTIR spectroscopic and reaction kinetics study of the interaction of CF3CFCl2 with γ-Al2O3, J. Phys. Chem. B 104 (2000) 1277.
31. V.Y. Borovkov, F. Lonyi, V.I. Kovalchuk, J.L. d’Itri, Fourier transfer infrared study of 1,1-dichlorotetrafluoroethane adsorption on an alumina supported Pd catalyst, J. Phys. Chem. B 104 (2000) 5603.
32. R.M. Rioux, C.D. Thompson, N. Chen, F.H. Ribeiro, Hydrodechlorination of chlorofluorocarbons CF3-CFCl2 over Pd/Carbon and Pd black catalysts, Catal. Today 62 (2000) 269.
33. C.D. Thompson, R.M. Rioux, N. Chen, F.H. Ribeiro, Turnover rate, reaction order, and elementary steps for the hydrodechlorination of chlorofluorocarbon compounds on palladium catalysts, J. Phys. Chem. B 104 (2000) 3067.
34. D.J. Moon, M.J. Chung, K.Y. Park, S.I. Hong, Deactivation of Pd catalysts in the hydrodechlorinationof chloropentafluoroethane, Appl. Catal. A: General 168 (1998) 159.
35. D.J. Moon, M.J. Chung, K.Y. Park, S.I. Hong, Adsorption equlibrium and catalytic reaction of CFC-115 on Pd/Activated carbon powder, Carbon 37 (1999) 123.
36. L. Delannoy, J.M. Giraudon, P. Granger, L. Leclercq, G. Leclercq, Group IV transition metal carbides asalternatives in the hydrodechlorination of chlorofluorocarbons, Catal. Today 59 (2000) 231.
37. R. Ohnishi, I. Suzuki, M. Ichikawa, Bi-Pd catalyst for selective hydrodechlorination of 1,1,2-trichlorotrifluoroethane to trifluoroethane, a key intermediate to 1,1,1,2-tetrafluoroethane as a CFC replacement for refrigeration, Chem. Lett. (1991), 841.
38. R. Ohnishi, W.L. Wang, M. Ichikawa, Selective hydrodechlorination of CFC-113 on Bi- and Tl-modified palladium catalysts, Appl. Catal. A: General 113 (1994) 29.
39. S.P. Scott, M. Sweetman, J. Thomson, A.G. Fitzgerald, E.J. Sturrock, Catalytic hydrogenolysis of 1,1,2-trichlorotrifluoroethane on γ-Al2O3 supported palladium/Zinc oxide catalyst, J. Catal. 168 (1997) 501.
40. H.S. Kim, O.J. Cho, I.M. Lee, H.P. Hong, C.Y. Kwag, B.S. Ahn, Selective hydrogenolysis of chlorofluorocarbons by RhCl(PPh3)3, J. Mol. Catal. A: Chemical 111 (1996) 49.
41. S. Ordó?ez, M. Makkee, J.A. Moulijn, Performance of activated carbon-supported noble metal catalysts in the hydrogenolysis of CCl3F, Appl. Catal. B: Environmental 29 (2001) 13.
42. B. Basu, S. Satapathy, A.K. Bhatnagar, Merox and related metal phthalocyanine catalyzed oxidation processes, Catal. Rev.-Sci. Eng. 35 (1993) 571.
43. H. Shirai, H. Tsuiki, E. Masuda, T. Koyama, K. Hanabusa, N. Kobayashi, Functional metallomacro-cycles and their polymers, 25. Kinetics and mechanism of the biomimetic oxidation of thiol by oxygen catalysed by homogeneous (polycarboxyphthalocyanato) metals, J. Phys. Chem. 95 (1991) 417.
44. T. Ichinohe, H. Miyasaka, A. Isoda, M. Kimura, K. Hanabusa, H. Shirai, Functional metallomacrocycles and their polymers, Part 37: Oxidative decomposition of 2,4,6-trichloro-phenol by polymer-bound phthalocyanines, Reactive and Functional Polymers 43 (2000) 63.
45. A. Kempa, J. Dobrowlski, Palladium phthalocyanine and its polymorphic forms, Can. J. Chem. 66 (1988) 2553.
46. M.P. Sammes, The infrared spectrum of phthalocyanine: assignment of N-H modes, J. Chem. Soc., Perkin Trans. (1972) 160.
47. A.W. Snow, J.R. Griffith, Syntheses and characterization of heteroatom- bridged metal free phthalo-cyanine network ploymers and model compounds, Macromolecule 17 (1984) 1614.
48. A.M. Schaffer, M. Gouterman, E.R. Davidson, Porphyrins XXVIII*. Extended Hückel caculations on metal phthalocyanines and tetrazaporphins, Theo. Chim. Acta, Berl. 30 (1973) 9.
49. R.D. Farina, D.J. Halko, J.H. Swinehart, A kinetic study of the monomer-Dimer equilibrium in aqueouse vanadium (IV) tetrasulfophthalocyanine solutions, J. Phys. Chem. 76 (1972) 2343.
50. S.J. Kim, M. Matsumoto, K. Shigenhara, Synthesis and electrical properties of poly ( -1,4-diisocyanobenzene) octacyanophthalocyaninatoiron (II), Synth. Met. 107 (1999) 27.
51. T.N. Bell, P. Kirszensztejn, B. Czajka, Catalytic conversion of CCl2F2 on Pt/γ-Al2O3 catalyst, React. Kinet. Catal. Lett. 56 (1995) 221.
52. F. Ciardelli, E. Tsuchida, D. W?hrle (Eds.), Macromolecule- Metal Complexes, Springer, Germany, 1996.
53. B.N. Achar, P.K. Jayasree, Synth. Met. Novel `synthetic metals based on symmetrically tetrasubstituted nickel phthalocyanines, 104 (1999) 101.
54. H.C. Choi, S.H. Choi, J.S. Lee K.H. Lee, Y.G. Kim, Effects of Pt precursors on hydrodechlorination of carbon tetrachloride over Pt/Al2O3, J. Catal. 166 (1997) 284.
1. B. Coq, F. Figueras, S. Hub, D. Tournigant, Effect of the metal-support interaction on the catalytic properties of palladium for the conversion of dichlorodofluoromethane with hydrogen: compariso of oxides and fluorides as supports, J. Phys. Chem. 99 (1995) 11159.
2. W. Juszczyk, A. Malinowski, Z. Karpinski, Hydrodechlorination of CCl2F2 (CFC-12) over γ-alumina supported palladium catalysts, Appl. Catal. A166 (1998) 311.
3. S. Deshmukh, J.L. d’Itri, Transient kinetics investigations of reaction intermediates involved in CF2Cl2 hydrodechlorination, Catal. Today 40 (1998) 377.
4. K. Early, V.I. Kovalchuk, F. Lonyi, S. Deshmukh, J.L. d’Itri, Catalytic hydrodechlorination of 1,1-dichlorotetrafluoroethane and dichlorofluoromethane catalyzed by Pd on flurinated alumina: therole of support material, J. Catal. 182 (1999) 219.
5. B. Coq, J.M. Cognion, F. Figueras, D. Tournigant, convesion under hydrogen of dichlorodifluoromethane over supported palladium catalysts, J. Catal.141 (1993) 21.
6. B.S. Ahn, S.C. Lee, D.J. Moon and B.G. Lee, A study of hydrodechlorination reaction of dichlorodifluoromethane over Pd/AlF3 catalyst, J. Mol. Catal. A 106 (1996) 83.
7. A. Malinowski, W. Juszczyk, J. Pielaszek, M. Bonarowska, M. Wojciechowska, Z. Karpinski, Magnesium fluoride as a support in hydrodechlorination of CCl2F2 (CFC-12), Chem. Commun. (1999) 685.
8. E.J.A.X. van de Sandt, A. Wiersma, M. Makkee, H.Vanbekkum, J.A. Moulijn, Palladium black as model catalyst in the hydrogenolysis of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Appl. Catal. A 155 (1997) 59.
9. E.J.A.X. van de Sandt, A. Wiersma, M. Makkee, H.Vanbekkum, J.A. Moulijn, Catalyst development for the selective hydrodechlorination of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Catal. Today 35 (1997) 163.
10. M. Makkee, A. Wiersma, E.J.A.X. van de Sandt, H. Van Bekkum, J.A. Moulijn, Development of a palladium on activated carbon for a conceptual process in the selective hydrogenolysis of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Catal. Today 55 (2000) 125.
11. A.L.D. Ramos, M. Schmal, D.A.G. Aranda and G.A. Somorjai, Hydrodechlorination of dichlorodifluoromethane over palladium catalysts and a comparison with the hydrodeclorination of 1,1-dichlorotetrafluoroethane, J. Catal. 192 (2000) 423.
12. F.H. Ribeiro, C.A. Gerken, G. Rupprechter, G.A. Somorjai, C.S. Kellner, G.W.Coulston, L.E. Manzer and L. Abrams, Structure insensitivity and effect of sulfur in the reaction of hydrodechlorination of 1,1-dichlorotetrafluoroethane (CF3-CFCl2) over Pd catalysts, J. Catal. 176 (1998) 352.
13. H. Itatani and J.C.Bailar, Jc., Homogeneous catalysts in the reaction of olefinic substances V: hydrogenation of soybean oil methyl ester with triphenylphosphine and triphenylarsine palladium catlysts, J. Am. Oil Chem. Soc. 44 (1967) 147.
14. A.Morato, C. Alonso, F. Medina, J.L. Garreta, J.E. Sueiras, Y. Cesteros, P. Salagre, D. Tichit and B. Coq, KMg1-xPdxF3 with perovskite-like sructures as precursors for the catalytic hydroconversion of CCl2F2 and CHClF2, Catal. Lett. 77 (2001) 141.
15. J.E. Benson, H.S. Hwang and M.J. Boudart, Hydrogen-Oxygen Titration Method for the Mesurement of Supported Palladium Surface Areas, J. Catal. 30 (1973) 146.
16. M. Wojciechowska, B. Czajka, M. Pietrowski and M. Zielinski, MgF2 as a non-conventional catalytic support. Surface and structure characterization, Catal. Lett. 66 (2000) 147.
17. M.Maciejewski and A. Baiker, Incorporation and reactivity of carbon in palladium, Pure Appl. Chem. 67 (1995) 1879.
18. M.A. Subramanian and V.N.M. Rao, Cubic chromium trifluoride and its use for halogenated hydrocarbon processing, US patent 6028026, 2000-02-22.
19. 刘世宏, 王当憨, 潘承璜, X射线光电子能谱分析, 科学出版社: 北京, 1988.
20. L. Delannoy, J.M. Giraudon, P. Granger, L. Leclercq and G. Leclercq, Group VI transition metal carbides as alternatives in the hydrodechlorination of chlorofluorocarbons, Catal. Today, 59 (2000) 231.
21. L. Delannoy, J.M. Giraudon, P. Granger, L. Leclercq and G. Leclercq, Hydrodechlorination of CCl4 over Group VI transition metal carbides, Appl. Catal. B: Enironmental, 37 (2002) 161.
22. R.J. Levis, L.A. Delouise, E.J. White and N. Winograd, Defect induced surface chemistry: A comparison of the adsorption and thermal decomposition of ethene on Rhodium [111] and Rhodium [331], Surf. Sci. 230 (1990) 35.
23. H.P. Bonzel and H.J. Krebs, On the chemical nature of the carbonaceous deposit iron after carbonmonoxide hydrogenation, Surf. Sci. 90 (1980) 499.
24. Y. Yuan, K.Asakura, H. Wan, K. Tsai and Y. Iwasawa, Supported gold catalysts derived from gold complexes and as precipitated metal hydroxides highly active for low temperature CO oxidation, Chem. Lett. (1996) 755.
25. A.P. Kozlova, S. Sugiyama, A.I. Kozlov, K.Asakura and Y. Iwasawa, Iron-Oxide Supported Gold Catalysts Derived from Gold-Phosphine Complex Au (PPh3)(NO3): State and Structure of the Support, J. Catal. 176 (1998) 426.
26. A.I. Kozlov, A.P. Kozlova, K.Asakura, Y. Matsui, T. Kogure, T. Shido and Y. Iwasawa, Supported Gold Catalysts Prepared from a Gold Phosphine Precursor and As-Precipitated Metal-Hydroxide Precursors: Effect of Preparation Conditions on the Catalytic Performance, J. Catal. 196 (2000) 56.
27. T.N. Bell, P. Kirszensztejn and B. Czajka, Catalytic conversion of CCl2F2 on Pt/γ-Al2O3 catalyst, React. Kinet. Catal. Lett. 56 (1995) 221.
28. E.H. van Broekhoven and V. Ponec, Surface chemistry of small particles, Surface Sci. 162 (1985) 731.
29. B. Coq, G. Ferrat and F. Figuéras, Conversion of chlorobenzene over palladium and rhodium catalysts of widely varying dispersion, J. Catal. 101 (1986) 434.
1. C.D. Thompson, R.M. Rioux, N. Chen and F.H. Ribeiro, Turnover rate, reaction order, and Elementary steps for the hydrodechlorination of chlorofluorocarbon compounds on Pd catalysts, J. Phys. Chem. B 104 (2000) 3067.
2. F.H. Ribeiro, C.A. Gerken, G.A. Somorjai, C.S. Kellner, G.W. Coulston, L.E. Manzer and L. Abrams, Turnoiver rate and kinetic mechanism for the reaction of hydrodechlorination of 1,1-dichlorotetrafluoroethane (CF3-CFCl2) over a polycrystalline Pd foid, Catal. Lett. 45 (1997) 149.
3. A.L.D. Ramos, M. Schmal, D.A.G. Aranda and G.A. Somorjai, Hydrodechlorination of dichlorodifluoromethane over palladium catalysts and a comparison with the hydrodeclorination of 1,1-dichlorotetrafluoroethane, J. Catal. 192 (2000) 423.
4. W. Juszczyk, A. Malinowski, Z. Karpinski, Hydrodechlorination of CCl2F2 (CFC-12) over γ-alumina supported palladium catalysts, Appl. Catal. A166 (1998) 311.
5. A.V. Vernov, W.A. Steele and A. Abrams, Sorption of xenon zeolite Rho: A thernodynamic/Simulation study, J. Phys. Chem. 97 (1993) 7660.
6. B. Coq, J.M. Cognion, F. Figueras, D. Tournigant, convesion under hydrogen of dichlorodifluoromethane over supported palladium catalysts, J. Catal.141 (1993) 21.
7. Y.C. Cao, X.Z. Jiang, W.H. Song, Z.Q. Bai, X.Q. Fang, Hydrodechlorination of CFC-12 over novel supported palladium catalysts, Catal. Lett. 76 (2001) 53.
8. B. Coq, F. Figueras, S. Hub, D. Tournigant, Effect of the metal-support interaction on the catalytic properties of palladium for the conversion of dichlorodofluoromethane with hydrogen: compariso of oxides and fluorides as supports, J. Phys. Chem. 99 (1995) 11159.
9. D.J. Moon, M.J. Chung, K.Y. Park, S.I. Hong, Deactivation of Pd catalysts in the hydrodechlorination of chloropentafluoroethane, Appl. Catal. A: General 168 (1998) 159.
10. J.A. Moulijn, M. Makkee, A. Wiersma, E.J.A.X. van de Sandt, Selective hydrogenolysis of CCl2F2 into CH2F2 over palladium on activated carbon Kinetic mechanism and process design, Catalysis Today 59 (2000) 221.
11. F.R. Reinoso, The role of carbon materials in the heterogeneous catalysts, Carbon 36 (1998) 159.
12. E.J.A.X. van de Sandt, A. Wiersma, M. Makkee, H.Vanbekkum, J.A. Moulijn, Catalyst development for the selective hydrodechlorination of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Catal. Today 35 (1997) 163.
13. A. Wiersma, E.J.A.X. van de Sandt, M. Makkee, C.P. Luteijn,H. Vanbekkum, J.A. Moulijn, Process for the selective hydrogenolysis of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Catal. Today 27 (1996) 257.
1. Y.C. Cao, X.Z. Jiang, W.H. Song, Z.Q. Bai, X.Q. Fang, Hydrodechlorination of CFC-12 over novel supported palladium catalysts, Catal. Lett. 76 (2001) 53.
2. Y.C. Cao and X.Z. Jiang, Supported palladium phthalocyanine in Hydrodechlorination of CFC-12, J. Mol. Catal. A: Chenmical, 2002 (in press)
3. Y.C. Cao and X.Z. Jiang, Novel hydodechlorination of CCl2F2 over supported PdCl2-(n-C4H9)4N+Cl- molten salts, Chinese Chemical Letters, 12 (2001) 533.
4. N.I. Buchan, T.F. Kuech, G.J. Scilla and F. Cardone, Carbon incorporation in metalorganic vapor phase epitaxy grown gallium arsenide using CHyX4-y trimethylgallium and arsine, J. Cryst. Growth 110 (1991) 405.
5. J. Tokuda, M. Takai, H. Nakai, K. Gamo, S. Nawaba, Laser induced thermochemical etching of ferrite in carbon tetrachloride, J. Opt. Soc., Am. B4 (1987) 267.
6. N. Supranat, T. Nunno, M. Kravett, M. Breton, Halogenated Organic Containing Wastes: Treatment Technologies, Noyes Data Corporation, Park Ridge, NJ, 1988.
7. S. Morikawa, M. Yoshitake, S. Tatematsu, Method for producing a hydrogen-containing chloromethane, US Patent 5,334,782 (1989).
8. E.T. Miguel, J.M.S. Gimenez, A.C. Arroyo, X.L.S. Gomez, A.A. Martin, process for the manufacture of chloroform, US Patent 5,208,393 (1993).
9. A.H. Weiss, B.S. Gambhir, R.B. Leon, Hydrodechlorination of carbon tetrachloride, J. Catal. 22 (1971) 245.
10. A.H. Weiss, S. Valinski, Hydrodechlorination and oligomerization of carbon tetrachloride over nickel Y zeolites, J. Catal. 74 (1982) 136.
11. S.Y. Kim, H.C. Choi, O.B. Yanga, K.H. Lee, J.S. Lee, Y.G. Kim, Hydrodechlorination of carbon tetrachloride over supported Pt catalysts, J. Chem. Soc., Chem. Commun. (1995) 2169.
12. H.C. Choi, S.H. Choi, J.S. Lee, K.H. Lee, Y.G. Kim, Hydrodechlorination of Carbon Tetrachloride over Pt/MgO, J. Catal. 161 (1996) 790.
13. H.C. Choi, S.H. Choi, J.S. Lee K.H. Lee, Y.G. Kim, Effects of Pt precursors on hydrodechlorination of carbon tetrachloride over Pt/Al2O3, J. Catal. 166 (1997) 284.
14. Z.C. Zhang, B.C. Beard, Genesis of durable catalyst for selective hydrodechlori-nation of CCl4 to CHCl3, Appl. Catal. A: General 174 (1998) 33.
15. F.G. Sherif, Catalytic hydrodechlorination of a chloromethane, US Patent 5,426,252 (1995).
16. L. Delannoy, J.-M. Giraudon, P. Granger, L. Leclercq and G. Leclercq, Hydrodechlorination of CCl4 over group VI transition metal carbides, Applied Catalysis B: Environmental 37 (2002) 161.
17. P. Bodnariuk, B. Coq, G. Ferrat and F. Figueras, Carbon-Chlorine hydrogenolysis over PdRh and PdSn bimetallic catalysts, J. Catal. 116 (1989) 459.
18. B. Coq, S. Hub, F. Figueras, D. Tournigant, Convesion under hydrogen of dichlorodifluoromethane over bimetallic palladium catalysts, Appl. Catal. A101 (1993) 41.
19. A. Malinowski, W. Juszczyk, M. Bonarowska, J. Pielaszek,Z. Karpinski, Pd-Re/Al2O3: characterization and catalytic activity in hydrodechlorination of CCl2F2, J. Catal. 177 (1998) 153.
20. R. Ohnishi, W.L. Wang, M. Ichikawa, Selective hydrodechlorination of CFC-113 on Bi and Tl-modified palladium catalysts, Appl. Catal. A 113 (1994) 29.
21. B. Heinrichs, F. Noville, J.P. Schoebrechts, J.P. Pirard, Palladium-Silver Sol-Gel Catalysts for Selective Hydrodechlorination of 1,2-Dichloroethane into Ethylene II. Surface composition of alloy particles, J. Catal. 192 (2000) 108.
22. S.T. Srinivas, L. Jansi Lankshmi and P. Kanta Rao, Selective vapour-phase hydrodechlorination of chlorobezene over alumina supported platinum bimetallic catalysts, Appl. Catal. A 135 (1996) 201.
23. K.O. Early, W.D. Rhodes, V.I. Kovalchuk, J.L. d’Itri, Hydrogen-assisted 1,2,3-trichloropropane on supported Pt-Sn catalysts, Appl. Catal. B: evironmental 26 (2000) 257.
24. B. Coq, A. Tijani and F. Figueras, Influence of alloying platinum for the hydrogenation of p-chloronitrobenzene over PtM/Al2O3 catalysts with M=Sn, Pb, Ge, Al, Zn, J. Mol. Catal. 71 (1992) 317.
25. X. Wu, Y.A. Letuchy, D.P. Eyman, Catalytic hydrodechlorination of CCl4 over silica-supportedPdCl2 containing molten salt catalysts: the promotional effects of CoCl2 and CuCl2, J. Catal. 161 (1996) 164.
26. A. Wiersma, E.J.A.X. van de Sandt, M.A. den Hollander, H.van Bekkum, M. Makkee, J.A. Moulijn, Comparison of the performance of activated carbon supported noble metal catalysts in the hydrogenolysis of CF2Cl2, J. Catal. 177 (1998) 29.
27. A. Malinowski, W. Juszczyk, J. Pielaszek, M. Bonarowska, M. Wojciechowska, Z. Karpinski, Magnesium fluoride as a support in hydrodechlorination of CCl2F2 (CFC-12), Chem. Commun. (1999) 685.
28. Carl L. Yaws, Thermodynamic and physical property data, Gulf Publishing Company, Houston Texas, 1992, P78.
29. 蒋晓原, 毛建新, 陆维敏, 郑小明, 四氯化碳加氢制氯仿 Pt-Pd/C催化剂的制备研究, 石油化工, 29 (2000) 483.
30. 毛建新, 蒋晓原, 陆维敏, 郑小明, 四氯化碳液相催化加氢反应动力学的研究, 燃料化学学报, 29 (2001) 277.
31. 杨锡尧 候镜德 物理化学的气相色谱研究法 北京大学出版社 北京 1989 p242.
2 R.S. Stolarski, The antarctic ozone hole, Scient. Am. 258 (1988) 20.
3 S. Solomon, The mystery of the Antarctic ozone ‘hole’, Rev. Geophys. 26 (1988) 131.
4 科技文萃 编辑室, 全球一齐来补天, 科技文萃, 2 (2000 46.
5 United Nation Environment Programme, Report of the Ad-hoc technical advisory committee on ODS destruction technologies, May, 1992.
6 M.J. Prather and R.T. Watson, Stratospheric ozone depletion and future levels of atmospheric chlorine and bromine, Nature, 344 (1990) 729.
7 D.G. Cogan, Investor responsibility research center (USA), 1988,68:65
8 冯元恭, 氯氟烷烃与温室效应, 上海环境科学, 1990,9(9): 36.
9 Climate change, the IPCC scientific assessment, University of Cambridge, 1990.
10 The 1994 report of the scientific assessment working group of IPCC: Radiative Forcaing of Climate Change, IPCC, 1994: p4~28.
11 A. McCulloch, CFC and Halon replacements in the environment, J. Fluor. Chem., 100 (1999) 163; and references there in.
12 L.E. Manzer, An overview of the commercial development of chlorofluorocarbon (CFC) alternatives, Catalysis Today, 13 (1992) 13.
13 J. Burdenauc and R.H. Crabtree, Mineralization of chlorofluorocarbons and aromatization of saturated fluorocarbons by a convenient thermal process, Science, 271 (1996) 340.
14 S. Karmakar and H.L. Greene, Oxidative destruction of chlorofluorocarbons by zeolite catalysts, J. Catal. 138 (1992) 364.
15 S. Karmakar and H.L. Greene, Characterization of Y-and Cr-Y- Zeolite catalysts during theoxidative destruction of CFC-11 and CFC-12, J. Catal. 148 (1994) 324.
16 T.Aida, R. Higuchi and H. Niigama, Decomposition of Freon-12 and methylchlorine over supported gold catalysts, Chem. Lett., 10 (1990) 2247.
17 S. Imamura, K. Imakubo and S. Furuyoshi, Decomposition of dichlorofluoro-methane on BPO4 catalysts, Ind. Eng. Chem. Res.,30 (1991) 2355.
18 S.S. Kumaran, K.P. Lim, J.V. Michael and A.F. Wagner, Thermal decomposition of CF2Cl2, J. Phys. Chem., 99 (1995) 8673.
19 R.G. Tonkyn, S.E. Barlow and T.M. Orlanto, Destruction of carbon tetrachloromethane in a dielectric barrier packed- bed corona reactor, J. App. Phys. 80 (1996) 4877.
20 T. Yamamoto, K. Mizuno, I Tamori, A Ogata, M. Nifuku, M. Michalska and G. Prieto, Catalysis assisted plasma technology for carbon tetrachloride destruction, IEEE Trans. Ind. App. 32 (1996) 100.
21 Y.F. Wang, W.J. Lee, C.Y. Chen and L.T. Hsieh, Decomposition of dichloro-difluoromethane by adding hydrogen in a cold plasma system, Environ. Sci. Technol. 33 (1999) 2234.
22 A. Schizodimou, G. Kyriacou and Ch. Lambrou, Electrochemical reduction of dichlorodifluoromethane in acetonitrile medium to useful fluorinated compounds, J. Electro-analytical Chem. 471 (1999) 26.
23 M.A. Malik, Research on non-equilibrium plasma for toxic VOCs destruction, Ozonation and Methane conversion. [D], Zhejiang University, 1999.
24 C. Menini, C. Park and R. Brydson et al, Low temperature (553K) catalytic growth of highly ordered carbon filaments during hydrodechlorination reaction, J. Phys. Chem. B 104 (2000) 4281.
25 A.R. Pinder, The hydrogenolysis of organic halides, Synthesis (1980) 425.
26 G. Centi, Supported palladium catalysts in environmental catalytic technologies for gaseous emissions, J. Mol. Catal. A: Chemical 173 (2001) 287.
27 T. Imamoto, Reduction of saturated alkyl halides to alkanes, in: I. Fleming (Ed.), Reduction, Vol. 8, Pergamon Press,Oxford, 1991, pp. 793–809.
28 P.Y. Bruice, Organic Chemistry, 2nd Edition, Prentice-Hall,New Jersey, 1998.
29 B. Coq, S. Hub, F. Figueras, D. Tournigant, Convesion under hydrogen of dichlorodifluoromethane over bimetallic palladium catalysts, Appl. Catal. A101 (1993) 41.
30 B. Coq, G. Ferrat, F. Figueras, Convesion of chlorobenzene over palladium and Rhodium catalysts of widely varing dispersion, J. Catal. 101 (1986) 434.
31 A.H. Weiss, B.S. Gambhir, R.B. Leon, Hydrodechlorination of carbon tetrachloride, J. Catal. 22 (1971) 245.
32 H.C. Choi, S.H. Choi, J.S. Lee K.H. Lee, Y.G. Kim, Effects of Pt precursors on hydrodechlorination of carbon tetrachloride over Pt/Al2O3, J. Catal. 166 (1997) 284.
33 S.C. Fung, J.H. Sinfelt, hydrogenolysis of methyl chloride on metals, J. Catal. 103 (1987) 220.
34 P.P. Kulkarni, S.S. Deshmukh, V.I. Kovalchuk, J.L. d’Itri, Hydrodechlorination of dichlorodifluoromethane on carbon supported group VIII noble metal catalysts, Catal. Lett. 61 (1999) 161.
35 P. Bodnariuk, B. Coq, G. Ferrat, F. Figueras, Carbon-chlorine hydrogenolysis over PdRh and PdSn bimetallic catalysts, J. Catal. 116(1989) 459.
36 N. Lingaiah, M.A. Uddin, A. Muto, Y. Sakata, Hydrodechlorination of chlorinated hydrocarbons over metal-carbon composite catalysts prepared by a modified carbo-thermal reduction method, Chem.Commun. (1999) 1657.
37 L. Prati, M. Rossi, Reductive catalytic dehalogenation of light chlorocarbons, Appl. Catal. B 23 (1999) 135.
38 A. Gampine, D.P. Eyman, Catalytic Hydrodechlorination of Chlorocarbons. 2. Ternary OxideSupports for Catalytic Conversions of 1,2-Dichlorobenzene, J. Catal. 179 (1998) 315.
39 E.J.A.X. van de Sandt, A. Wiersma, M. Makkee, H.Vanbekkum, J.A. Moulijn, Catalyst development for the selective hydrodechlorination of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Catal. Today 35 (1997) 163.
40 A. Wiersma, E.J.A.X. van de Sandt, M. Makkee, C.P. Luteijn,H. Vanbekkum, J.A. Moulijn, Process for the selective hydrogenolysis of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Catal. Today 27 (1996) 257.
41 T. Mori, W. Ueda, Y. Morikawa, hydrodechlorinative dimerization of 1,1,1-trifluorohaloethane over Ru/SiO2 catalyst, Catal. Lett. 38 (1996) 73.
42 U. Folli, F. Goldoni, D. Iarossi, S. Shardellati, F. Taddei, Selectivity towards hydrodechlorination and dehalo-coupling in the reduction of trichloromethyl derivatives with iron (II) chloride, J.Chem. Soc., Perkin Trans. II (1995) 1017.
43 E.J.A.X. van de Sandt, A. Wiersma, M. Makkee, H.Vanbekkum, J.A. Moulijn, Palladium black as model catalyst in the hydrogenolysis of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Appl. Catal. A 155 (1997) 59.
44 M. Ocal, M. Maciejewski, A. Baiker, Conversion of CCl2F2 (CFC-12) in the presence and absence of H2 on sol–gel derived Pd/Al2O3 catalysts, Appl. Catal. B 21 (1999) 279.
45 S.S. Deshmukh, V.I. Kovalchuk, V.Y. Borovkov, J.L. d’Itri, FTIR spectroscopic and reaction kinetics study of the interaction of CF3CFCl2 with γ-Al2O3, J. Phys. Chem. B 104 (2000) 1277.
46 B. Coq, J.M. Cognion, F. Figueras, D. Tournigant, convesion under hydrogen of dichlorodifluoromethane over supported palladium catalysts, J. Catal.141 (1993) 21.
47 F. Solymosi, J. Rasko, Infra-Red Spectroscopic Study of the Adsorption and Dissociation of CH2Cl2 on Pd/SiO2: Generation of CH2 Species, J. Catal. 155 (1995) 74.
48 S. Ordonez, H. Sastre, F.V. Diez, Hydrodechlorination of aliphatic organochlorinat-ed compounds over commercial hydrogenation catalysts, Appl. Catal. B 25 (2000) 49.
49 F.H. Ribeiro, C.A. Gerken, G.A. Somorjai, C.S. Kellner, G.W.Coulston, L.E. Manzer, L. Abrams, Turnover rate and kinetic mechanism for the reaction of hydrodechlorination of 1,1-dichlorotetrafluoroethane (CF3CFCl2) over a polycrystalline Pd foil, Catal. Lett. 45 (1997) 149.
50 C.W. Chan, A.J. Gellman, Carbon-chlorine bond cleavage in chlorofluororthanes on Pd (111), Catal. Lett. 53 (1998) 139.
51 M.T. Buelow, G. Zhou, A.J. Gellman, B. Immaraporn, The transition state for metal-catalyzed dehalogenation, Catal.Lett. 59 (1999) 9.
52 O. Exner, Correlation Analysis of Chemical Data, PlenumPress, New York, 1988.
53 Z. Karpinski, K. Early, J.L. d’Itri, Catalytic hydrodechlorination of 1,1-dichlorotetrafluoroethane by Pd/Al2O3, J. Catal. 164 (1996) 378.
54 S. Deshmukh, J.L. d’Itri, Transient kinetics investigations of reaction intermediates involved in CF2Cl2 hydrodechlorination, Catal. Today 40 (1998) 377.
55 A. Wiersma, E.J.A.X. van de Sandt, M. Makkee, H.Vanbekkum, J.A. Moulijn, Process development for the selective hydrogenolysis of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Stud. Surf. Sci. Catal. 101 (1996) 369.
56 A. Wiersma, E.J.A.X. van de Sandt, M.A. den Hollander, H.van Bekkum, M. Makkee, J.A. Moulijn, Comparison of the performance of activated carbon supported noble metal catalysts in the hydrogenolysis of CF2Cl2, J. Catal. 177 (1998) 29.
57 B. Coq, F. Figueras, Structure–activity relationships in catalysis by metals: some aspects of particle size, bimetallic and supports effects, Coord. Chem. Rev. 180 (1998) 1753.
58 M. Makkee, A. Wiersma, E.J.A.X. van de Sandt, H. Van Bekkum, J.A. Moulijn, Development of a palladium on activated carbon for a conceptual process in the selective hydrogenolysis ofCCl2F2 (CFC-12) into CH2F2 (HFC-32), Catal. Today 55 (2000) 125.
59 M. Makkee, E.J.A.X. van de Sandt, A. Wiersma, J.A. Moulijn, Development of a satisfactory palladium on activated carbon catalyst for the selective hydrogenolysis of CCl2F2 (CFC-12) into CH2F2 (HFC-32), J. Mol. Catal. A 134 (1998) 191.
60 K. Early, V.I. Kovalchuk, F. Lonyi, S. Deshmukh, J.L. d’Itri, Catalytic hydrodechlorination of 1,1-dichlorotetrafluoroethane and dichlorofluoromethane catalyzed by Pd on flurinated alumina: the role of support material, J. Catal. 182 (1999) 219.
61 E.J.A.X. van de Sandt, A. Wiersma, M. Makkee, H. Van Bekkum, J.A. Moulijn, Selection of activated carbon for the selective hydrogenolysis of CCl2F2 (CFC-12) into CH2F2 (HFC-32) over palladium-supported catalysts, Appl. Catal. A 173 (1998) 161.
62 W. Juszczyk, A. Malinowski, Z. Karpinski, Hydrodechlorination of CCl2F2 (CFC-12) over γ-alumina supported palladium catalysts, Appl. Catal. A166 (1998) 311.
63 A. Malinowski, W. Juszczyk, M. Bonarowska, J. Pielaszek,Z. Karpinski, Pd-Re/Al2O3: characterization and catalytic activity in hydrodechlorination of CCl2F2, J. Catal. 177 (1998) 153.
64 A. Malinowski, W. Juszczyk, J. Pielaszek, M. Bonarowska, M. Wojciechowska, Z. Karpinski, Magnesium fluoride as a support in hydrodechlorination of CCl2F2 (CFC-12), Chem. Commun. (1999) 685.
65 U.S. EPA, 1992 Toxics Release Inventory Public Data Release, EPA 745-R-94-001, 1994.
66 A.H. Weiss, B.S. Gambhir, R.B. Leon, Hydrodechlorination of carbon tetrachloride, J. Catal. 22 (1971) 245.
67 B.S. Gambhir, A.H. Weiss, Depletion of reactants on a catalytic surface during reaction, J. Catal.
26 (1972) 82.
68 S.Y. Kim, H.C. Choi, O.B. Yanga, K.H. Lee, J.S. Lee, Y.G. Kim, Hydrodechlorination of carbon tetrachloride over supported Pt catalysts, J. Chem. Soc., Chem. Commun. (1995) 2169.
69 H.C. Choi, S.H. Choi, J.S. Lee, K.H. Lee, Y.G. Kim, Hydrodechlorination of Carbon Tetrachloride over Pt/MgO, J. Catal. 161 (1997) 790.
70 J.W. Bae, E.D. Park, J.S. Lee, K.H. Lee, Y.G. Kim, S.H. Yeon, B.H. Sung, Hydrodechlorination of CCl4 over Pt/γ-Al2O3 effects of reaction pressure and diluent gases on distribution of products and catalyst stability, Appl. Catal. A: General 2172 (2001) 79.
71 Z.C. Zhang, B.C. Beard, Genesis of durable catalyst for selective hydrodechlori-nation of CCl4 to CHCl3, Appl. Catal. A: General 174 (1998) 33.
72 S. Ordonez, F.V. Diez, H. Sastre, Hydrodehclorination of tetrachloroethylene over vanadium-modified Pt/Al2O3 catlysts, Catal. Lett. 72 (2001) 177.
73 L.S. Vadlamannati, V.I. Kovalchuk, J.L. d’Itri Dechloriantion of 1,2-dichloroethane catalyzed by Pt-Cu/C: unraveling the role of each metal, Catal. Lett. 58 (1999) 178.
74 K.O. Early, W.D. Rhodes, V.I. Kovalchuk, J.L. d’Itri, Hydrogen-assisted 1,2,3-trichloropropane on supported Pt-Sn catalysts, Appl. Catal. B: evironmental 26 (2000) 257.
75 E.S. Lokteva, V.I. Simagina, E.V. Golubina, I.V. Stoyanova, V.V. Lunin, Formation of C1-C5 hydrocarbons from CCl4 in the presence of carbon-supported palladium catalysts, Kinetics and Catalysis 41 (2000) 776.
76 X. Wu, Y.A. Letuchy, D.P. Eyman, Catalytic hydrodechlorination of CCl4 over silica-supported PdCl2 containing molten salt catalysts: the promotional effects of CoCl2 and CuCl2, J. Catal. 161 (1996) 164.
77 B. Heinrichs, P. Delhez, J.P. Schoebrechts, J.P. Pirard, Palladium-Silver Sol-Gel Catalysts for Selective Hydrodechlorination of 1,2-Dichloroethane into Ethylene, J. Catal.172 (1997) 322.
78 B. Heinrichs, F. Noville, J.P. Schoebrechts, J.P. Pirard, Palladium-Silver Sol-Gel Catalysts for Selective Hydrodechlorination of 1,2-Dichloroethane into Ethylene II. Surface composition ofalloy particles, J. Catal. 192 (2000) 108.
79 B. Heinrichs, J.P. Schoebrechts, J.P. Pirard, Palladium-Silver Sol-Gel Catalysts for Selective Hydrodechlorination of 1,2-Dichloroethane into Ethylene III. Kinetics and reaction mechanism, J. Catal. 200 (2001) 309.
80 L. Prati, M. Rossi, Reductive catalytic dehalogenation of light chlorocarbons, Appl. Catal. B: Environmental 23 (1999) 135.
81 J.W. Bozzelli, Y.M. Chen, S.S.C. Chuang, Catalytic hydrodechlorination of 1,2,-dichloroethane and trichloroethylene over Rh/SiO2 catalyst, Chem. Eng. Commun. 115 (1992) 1.
82 A.H. Weiss, K.A. Krieger, Hydrodechlorination kinetics and reaction mechanism, 6 (1966) 167.
83 A.H. Weiss, S. Valinski, Hydrodechlorination and oligomerization of carbon tetrachloride over nickel Y zeolites, J. Catal. 74 (1982) 136.
84 M. Martino, R. Rosal, H. Sastre, F.V. Diez, Hydrodechlorination of dichlorometh-ane, trichloroethane, trichloroethylene and tetrachloroethylene over sulfided Ni/Mo-γ-alumina catalyst, Appl. Catal. B: Environmental 20 (1999) 301.
85 R.B. Timmons, W.L. Jang, Y. He, D.J.Jr Houpt, Catalytic hydrodechlorination of polyhalogenated hydrocarbons, U.S. Patent 5276240, 1994.
86 L.N. Ito, C.B. Murchison, M.T. Holbrook, A.D. Harley, D.D. Smith, Process for converting chlorinated alkenes to useful less chlorinated alkenes, U.S. Patent 5476979, 1995.
87 A.D. Harley, M.T. Holbrook, D.D. Smith, M.D. Cisneros, L.N. Ito, C.B. Murchison, U.S. Patent 5453557, 1995.
88 A. Morano, C. Alonso, F. Medina, P. Salagre, J.E. Sueiras, R. Terrado, A. Giralt, Conversion of hydrogen of dichlorofluoromethane and chlorofluoromethane over nickel catalysts, Appl. Catal. B 23 (1999) 175.
89 L. Delannoy, J.M. Giraudon, P. Granger, L. Leclereq, G. Leclercq, Group VI transition metal carbides as alternatives in the hydrodechlorination of chlorofluorocarbons, Catal. Today 59 (2000) 231.
90 M.A. Aramendia, V. Borau, I.M. Garcia, C. Jimenez, A.Marinas, J.M. Marinas, F.J. Urbano, Influence of the reaction conditions and catalytic properties on the liquid-phase hydrodechlorination of chlorobenzene over palladium supported catalysts: Activity and deactivation, J. Catal. 187 (1999) 392.
91 Y.C. Cao, X.Z. Jiang, W.H. Song, Z.Q. Bai, X.Q. Fang, Hydrodechlorination of CFC-12 over novel supported palladium catalysts, Catal. Lett. 76 (2001) 53.
92 B. Coq, F. Figueras, S. Hub, D. Tournigant, Effect of the metal-support interaction on the catalytic properties of palladium for the conversion of dichlorodofluoromethane with hydrogen: compariso of oxides and fluorides as supports, J. Phys. Chem. 99 (1995) 11159.
93 D.J. Moon, M.J.Chung, K.Y. Park, S.I. Hong, Deactivation of Pd catalysts in the hydrodechlorination of chloropentafluoroethane, Appl. Catal. A 168 (1998) 159.
94 W.Juszczyk, A.Malinowski, M. Bonarowska, Z. Karpinski, Hydrodechlorination of CCl2F2 (CFC-12) over Pd/Al2O3 catalysts, Polish. J. Chem. 71 (1997) 1314.
95 M. Bonarowska, A. Malinowski, Z. Karpinski, Hydrogenolysis of C–C and C–Cl bonds by Pd–Re/Al2O3 catalysts, Appl. Catal. A 188 (1999) 145.
96 S.P. Scott, M. Sweetman, J. Thomson, A.G. Fitzgerald, E.J. Sturrock, Catalytic hydrogenolysis of 1,1,2-trichlorotrifluoroethane on γ-Al2O3 supported palladium / Zinc oxide catalyst, J. Catal. 168 (1997) 501.
97 A.Hess, E. Kemnitz, Heterogeneous catalyzed dismutation and conmutation reaction of CHCl3-nFn chlorofluorocarbons, Appl. Catal. A 82 (1992) 247.
98 F.R. Reinoso, The role of carbon materials in the heterogeneous catalysts, Carbon 36 (1998) 159.
99 M.H. Schoonenboom, H.E. Zoetemeijer, K. Olie, Dechlorination of octachloro-dibenzo-p-dioxin and octachlorodibenzofunan on an alumina support, Appl. Catal. B 6 (1995) 11.
100 W.X. Zhang, C.B. Wang, H.L. Lien, Treatment of chlorinated organic contaminants with nanoscale bimetallic particles , Catal. Today 40 (1998) 387.
101 R. Ohnishi, I. Suzuki, M. Ichikawa, Bi-Pd for selective hydrodechlorination of 1,1,2-trichlorotrifluoroethane to trifluoroethene, a key intermediate to 1,1,1,2-tetrafluoroethane as a CFC replacements for refrigeration, Chem. Lett. (1991) 841.
102 R. Ohnishi, W.L. Wang, M. Ichikawa, Selective hydrodechlorination of CFC-113 on Bi and Tl-modified palladium catalysts, Appl. Catal. A 113 (1994) 29.
103 M. Bonarowska, A. Malinowski, W. Juszczyk, Z. Karpinski, Hydrodechlorination of CCl2F2 (CFC-12) over Silica-supported palladium-gold catalysts, Appl. Catal. B 30 (2001) 187.
104 F.H. Ribeiro, C.A. Gerken, G. Rupprechter, G.A. Somorjai, C.S. Kellner, G.W. Coulston, L.E. Manzer, L. Abrams, Structure insensitivity and effect of sulfur in the reaction of hydrodechlorination of 1,1-dichlorotetrafluoroethane (CF3CFCl2) over Pd catalysts, J. Catal. 176 (1998) 352.
105 A. Malinowski, M. Bonarowska, Hydrodechlorination of CH2Cl2 over Pd/Al2O3. Correlation with the hydrodechlorination of CCl2F2 (CFC-12), Appl. Catal. B 19 (1998) L79.
106 J.R. Anderson, Structure of Metallic Catalysts, Academic Press, New York, 1975.
107 F.J. Urbano, J.M. Marinas, Hydrogenolysis of organohalogen compounds over palladium supported catalysts, J. Mol. Catal. A 173 (2001) 329, and reference therein.
108 C.C. Chang, C.M. Reo, C.R.F. Lund, The effect of a membrane reactor upon catalyst deactivation during hydrodechlorination of dichloroethane, Appl. Catal. B 20 (1999) 309.
109 P. Forni, L. Prati, M. Rossi, Catalytic dehydrohalogenation of polychlorinated biphenyls Part II: Studies on a continuous process, Appl. Catal. B 14 (1997) 49.
110 G. Rupprechter, G.A. Somorjai, Palladium-catalyzed hydrogenation without hydrogen: the hydrodechlorination of chlorofluorocarbons with solid state hydrogen over the palladium (111) crystal surface and its implications, Catal. Lett. 48 (1997) 17.
1. W. Juszczyk, A. Malinowski and Z. Karpinski, Hydrodechlorination of CCl2F2 (CFC-12) over γ-alumina supported palladium catalysts, Appl. Catal. A: General, 166 (1998) 311.
2. A. Malinowski, W. Juszczyk, J. Pielaszek, M. Bonarowska, M. Wojciechowska and Z. Karpinski, Magnesium fluorideas a catalytic support in hydrodechlorination of CCl2F2, Chem. Commun. (1999) 685.
3. J.E. Benson, H.S. Hwang and M.J. Boudart, Hydrogen-Oxygen Titration Method for the Mesurement of Supported Palladium Surface Areas, J. Catal. 30 (1973) 146.
4. X.Z. Jiang, T.F. Hayden, J.A. Dumesic, Evidence for slow uptake of hydrogen by titania-supported samples: consequence for estimating metallic surface areas, J. Catal. 83 (1983) 168.
1. R. Datta, R.G. Rinker, Supported liquid-phase catalysts I. A theoretical model for transport and reaction, J. Catal. 95 (1985) 181.
2. R. Datta, W. Savage, R.G. Rinker, Supported liquid-phase catalysts II. Experimental evaluation of the flux model for liqid phase porous media, J. Catal. 95 (1985) 193.
3. R. Datta, J. Rydant, R.G. Rinker, Supported liquid-phase catalysts III. Experimental evaluation of the difussion reaction model, J. Catl. 95 (1985) 202.
4. H. Livbjerg, K.F. Jensen, J. Villadsen, Sulfur dioxide oxidation on supported molten V2O5-K2S2O7 catalyst. Influence of liquid diffusion resistance, J. Catal. 45 (1976) 216.
5. A.C. Buchanan, III, A.S. Dworkin, G.P. Smith, Molten salt catalysis. Selective bond cleavage reactions for some α,ω-diphenylalkanes in SbCl3 melts, J. Am. Chem. Soc. 105 (1983), 2843.
6. V. Rao, R. Datta, Development of a supported molten salts Wacker catalyst for the oxidation of ethylene to acetaldehyde, J. Catal. 114 (1988) 377.
7. X. Wu, Y.A. Letuchy, D.P. Eyman, Catalytic hydrodechlorination of CCl4 over silica-supported PdCl2 containing molten salt catalysts: the promotional effects of CoCl2 and CuCl2, J. Catal. 161 (1996) 164.
8. G.J. Janz, Molten salts handbook, Academic Press, New York, 1967.
9. H. Bloom, The chemistry of molten salts, Benjamin, New York, 1967.
10. M.J. Naughton, R,S, Drago, Supported homogeneous film catalysts, J. Catl. 155 (1995) 383.
11. G.W. Parshall, Catalysis in molten salt media, J. Am. Chem. Soc. 94 (1972) 8716.
12. W. Dafinger, L. Schmidhammer, EP 0523553A1, 1991 ( or US 5233106).
13. B. Coq, J.M. Cognion, F. Figueras, D. Tournigant, convesion under hydrogen of dichlorodifluoromethane over supported palladium catalysts, J. Catal.141 (1993) 21.
14. B. Coq, F. Figueras, S. Hub, D. Tournigant, Effect of the metal-support interaction on the catalytic properties of palladium for the conversion of dichlorodofluoromethane with hydrogen: compariso of oxides and fluorides as supports, J. Phys. Chem. 99 (1995) 11159.
15. A. Wiersma, E.J.A.X. van de Sandt, M. Makkee, C.P. Luteijn,H. Vanbekkum, J.A. Moulijn, Process for the selective hydrogenolysis of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Catal. Today 27 (1996) 257.
16. W. Juszczyk, A. Malinowski, Z. Karpinski, Hydrodechlorination of CCl2F2 (CFC-12) over γ-alumina supported palladium catalysts, Appl. Catal. A166 (1998) 311.
17. S. Deshmukh, J.L. d’Itri, Transient kinetics investigations of reaction intermediates involved in CF2Cl2 hydrodechlorination, Catal. Today 40 (1998) 377.
18. P.S.S. Prasad, N. Lingaiah, S. Chandrasekhar, K.S.R. Rao, P.K. Rao, K.V. Raghavan, F.J. Berry, L.E. Smart, Microwave irradiation: an effective method for the preparation of low dispersed Pd/Al2O3 catalysts used in the hydrodechlorination of CCl2F2 to CH2F2, Catal. Lett. 66 (2000) 201.
19. B.S. Ahn, S.G. Jeon, H. Lee, K.Y. Park, Y.G. Shul, Hydrogenolysis of CFC-12 (CF2Cl2) over Pd/γ-Al2O3 pretreated with HCFC-22 (CHF2Cl), Appl. Catal. B: General 193 (2000) 87.
20. Z. Karpinski, K. Early, J.L. d’Itri, Catalytic hydrodechlorination of 1,1-dichlorotetrafluoroethane by Pd/Al2O3, J. Catal. 164 (1996) 378.
21. Y.C. Cao, X.Z. Jiang, Novel catalytic hydrodechlorination of CCl2F2 over supported PdCl2-(n-C4H9)N+Cl- molten salts, Chin. Chem. Lett. 12 (2001) 533.
22. E.E. Getty, S.C. Petrosius, R.S. Drago, The strong solid acid, (SG)nAlCl2, as a catalyst for the dehydrochlorination and hydrodechlorination of polychlorinated molecules, J. Mol. Catal. 67 (1991) 127.
23. 吴越, 催化化学 第二版 , 科学出版社, 北京, 1998, p152.
24. M. Asscher, D. Vofsi, Chlorine activation by redox-transfer. Part I. The reaction between aliphatic amines and carbon tetrachloride, J. Chem. Soc. (1961) 2261.
25. M. Asscher, D. Vofsi, Chlorine activation by redox-transfer. Part II. The addition of carbon tetrachloride to olefins, J. Chem. Soc. (1963) 1887.
26. M. Asscher, D. Vofsi, Chlorine activation by redox-transfer. Part III. The abnormal addition of chloroform to olefins, J. Chem. Soc. (1963) 3921.
27. F.O.H. Pirrung, H.Hiemstra, W.N. Speckamp, Synthesis of medium-sized lactones by the copper (I) chloride/2,2’-bipyridine catalysed cylization of di- and trichloroactates, Tetrahedron, 50 (1994) 12415.
28. F. De Campo, D. Lastecoueres, J.B. Verlhac, New and improved catalysts for transition metal catalysed radical reactions, Chem. Commun. 19 (1998) 2117.
29. P. Martin, E. Steiner, J. Streith, T. Winkler, D. Bellus, Convenient approaches to heterocycles via copper catalysed addition of organic polyhalides to activated olefins, Tetrahedron, 41 (1985) 4057.
30. H. Nagashima, H. Wakamatsu, K. Itoh, Y. Tomo, J. Tsuji, New regio- and stereo-selective preparation of trichlorinated γ-butyrolactones by copper catalyzed cyclization of allyl trichloroacetates, Tetrahedron Letters, 24 (1983) 2395.
31. E. Steiner, P. Martin, D. Bellus, A new simple synthesis of 2,3,5-trichloropyridine, Helvetica Chimica Acta, 65 (1982) 983.
32. R.G. Pews, J.A. Gall, Use of chlorine ion as a catalyst for dehydrochlorination reaction: the synthesis of 3,5,6-trichloropyridin-2-ol, J. Org. Chem. 59 (1994) 6783.
33. R.G. Pews, Z. Lysenko, Synthesis of halogenated pyridine via the CuCl-catalysed addition of polyhaloacetonitriles to olefins, J. Org. Chem. 50 (1985) 5115.
1. Z. Ainbinder, L.E. Manzer and M.J. nappa, Catalytic routes to hydro (chloro)-fluorocarbons, In: G. Ertl, H. Knzoinger, J. Weitkamp Edited Handbook of Heterogeneous Catalysis, Vol 4, (1997) 1677; and references there in.
2. L.E. Manzer, An overview of the commercial development of chlorofluorocarbon (CFC) alternatives, Catalysis Today, 13 (1992) 13.
3. B. Coq, J.M. Cognion, F. Figueras, D. Tournigant, convesion under hydrogen of dichlorodifluoromethane over supported palladium catalysts, J. Catal.141 (1993) 21.
4. B. Coq, F. Figueras, S. Hub, D. Tournigant, Effect of the metal-support interaction on the catalytic properties of palladium for the conversion of dichlorodofluoromethane with hydrogen: compariso of oxides and fluorides as supports, J. Phys. Chem. 99 (1995) 11159.
5. A. Wiersma, E.J.A.X. van de Sandt, M. Makkee, C.P. Luteijn,H. Vanbekkum, J.A. Moulijn, Process for the selective hydrogenolysis of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Catal. Today 27 (1996) 257.
6. E.J.A.X. van de Sandt, A. Wiersma, M. Makkee, H.Vanbekkum, J.A. Moulijn, Catalyst development for the selective hydrodechlorination of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Catal. Today 35 (1997) 163.
7. W. Juszczyk, A. Malinowski, Z. Karpinski, Hydrodechlorination of CCl2F2 (CFC-12) over γ-alumina supported palladium catalysts, Appl. Catal. A166 (1998) 311.
8. A. Wiersma, E.J.A.X. van de Sandt, M.A. den Hollander, H.van Bekkum, M. Makkee, J.A. Moulijn, Comparison of the performance of activated carbon supported noble metal catalysts in the hydrogenolysis of CF2Cl2, J. Catal. 177 (1998) 29.
9. A. Malinowski, W. Juszczyk, M. Bonarowska, J. Pielaszek, Z. Karpinski, Pd-Re/Al2O3: characterization and catalytic activity in hydrodechlorination of CCl2F2, J. Catal. 177 (1998) 153.
10. S. Deshmukh, J.L. d’Itri, Transient kinetics investigations of reaction intermediates involved in CF2Cl2 hydrodechlorination, Catal. Today 40 (1998) 377.
11. A. Malinowski, W. Juszczyk, J. Pielaszek, M. Bonarowska, M. Wojciechowska, Z. Karpinski, Magnesium fluoride as a support in hydrodechlorination of CCl2F2 (CFC-12), Chem. Commun. (1999) 685.
12. P.P. Kulkarni, S.S. Deshmukh, V.I. Kovalchuk, J.L. d’Itri, Hydrodechlorination of dichlorodi-fluoromethane on carbon supported group VIII noble metal catalysts, Catal. Lett. 61 (1999) 161.
13. P.S.S. Prasad, N. Lingaiah, S. Chandrasekhar, K.S.R. Rao, P.K. Rao, K.V. Raghavan, F.J. Berry, L.E. Smart, Microwave irradiation: an effective method for the preparation of low dispersed Pd/Al2O3 catalysts used in the hydrodechlorination of CCl2F2 to CH2F2, Catal. Lett. 66 (2000) 201.
14. J.A. Moulijn, M. Makkee, A. Wiersma, Selective hydrogenolysis of CCl2F2 into CH2F2 overpalladium on activated carbon kinetic mechanism and process design, Catal. Today 59 (2000) 221.
15. B.S. Ahn, S.G. Jeon, H. Lee, K.Y. Park, Y.G. Shul, Hydrogenolysis of CFC-12 (CF2Cl2) over Pd/γ-Al2O3 pretreated with HCFC-22 (CHF2Cl), Appl. Catal. B: General 193 (2000) 87.
16. Y.C. Cao, X.Z. Jiang, W.H. Song, Z.Q. Bai, X.Q. Fang, Hydrodechlorination of CFC-12 over novel supported palladium catalysts, Catal. Lett. 76 (2001) 53.
17. Y.C. Cao, X.Z. Jiang, Novel hydrodechlorination of CCl2F2 over supported PdCl2-(n-C4H9)4N+Cl-molten salts, Chin. Chem. Lett. 12 (2001) 533.
18. A. Morato, C. Alonso, F. Medina, Y. Cesteros, P. Salagre, J.E. Sueiras, D. Tichit, B. Coq, Palladium hydrotalcites as precursors for the catalytic hydroconversion of CCl2F2 (CFC-12) and CHClF2 (HCFC-22), Appl. Catal. B: Environmental 32 (2001) 167.
19. M. Bonarowska, A. Malinowski, W. Juszczyk, Z. Karpi ski, Hydrodechlorination of CCl2F2 (CFC-12) over silica-supported palladium–gold catalysts, Appl. Catal. B: Environmental 30 (2001) 187.
20. A. Wiersma, E.J.A.X. van de Sandt, M. Makkee, J.A. Moulijn, Deactivation of palladium on activated carbon in the selective hydrogenolysis of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Appl. Catal. A: General 212 (2001) 223.
21. C. Gervasutti, L. Marangoni, W. Marra, Hydrogenolysis of dichlorotetrafluoroethane isomeric mixtures for the formation of 1,1,1,2-tetrafluoroethane, J. Fluorine Chem. 19 (1982) 1.
22. Z. Karpinski, K. Early, J.L. d’Itri, Catalytic hydrodechlorination of 1,1-dichlorotetrafluoroethane by Pd/Al2O3, J. Catal. 164 (1996) 378.
23. F.H. Ribeiro, C.A. Gerken, G.A. Somorjai, C.S. Kellner, G.W.Coulston, L.E. Manzer, L. Abrams, Turnover rate and kinetic mechanism for the reaction of hydrodechlorination of 1,1-dichlorotetrafluoroethane (CF3CFCl2) over a polycrystalline Pd foil, Catal. Lett. 45 (1997) 149.
24. F.H. Ribeiro, C.A. Gerken, G. Rupprechter, G.A. Somorjai, C.S. Kellner, G.W. Coulston, L.E. Manzer, L. Abrams, Structure insensitivity and effect of sulfur in the reaction of hydrodechlorination of 1,1-dichlorotetrafluoroethane (CF3CFCl2) over Pd catalysts, J. Catal. 176 (1998) 352.
25. C.W. Chan, A.J. Gellman, Carbon-chlorine bond cleavage in chlorofluororthanes on Pd (111), Catal. Lett. 53 (1998) 139.
26. M.T. Buelow, G. Zhou, A.J. Gellman, B. Immaraporn, The transition state for metal-catalyzed dehalogenation, Catal.Lett. 59 (1999) 9.
27. K. Early, V.I. Kovalchuk, F. Lonyi, S. Deshmukh, J.L. d’Itri, Catalytic hydrodechlorination of 1,1-dichlorotetrafluoroethane and dichlorofluoromethane catalyzed by Pd on flurinated alumina: the role of support material, J. Catal. 182 (1999) 219.
28. G. Zhou, C. Chan, A.J. Gellman, Dechlorination of fluorinated 1,1-dichlororthanes on Pd (111), J. Phys. Chem. B 103 (1999) 1134.
29. A.L.D. Ramos, M. Schmal, D.A.G. Aranda, G.A. Somorjai, Hydrodechlorination of dichlrodifluoromethane over palladium model catalysts and a comparison with the hydrodechlorination of 1,1-dichlorotetrafluoroethane, J. Catal. 192 (2000) 423.
30. S.S. Deshmukh, V.I. Kovalchuk, V.Y. Borovkov, J.L. d’Itri, FTIR spectroscopic and reaction kinetics study of the interaction of CF3CFCl2 with γ-Al2O3, J. Phys. Chem. B 104 (2000) 1277.
31. V.Y. Borovkov, F. Lonyi, V.I. Kovalchuk, J.L. d’Itri, Fourier transfer infrared study of 1,1-dichlorotetrafluoroethane adsorption on an alumina supported Pd catalyst, J. Phys. Chem. B 104 (2000) 5603.
32. R.M. Rioux, C.D. Thompson, N. Chen, F.H. Ribeiro, Hydrodechlorination of chlorofluorocarbons CF3-CFCl2 over Pd/Carbon and Pd black catalysts, Catal. Today 62 (2000) 269.
33. C.D. Thompson, R.M. Rioux, N. Chen, F.H. Ribeiro, Turnover rate, reaction order, and elementary steps for the hydrodechlorination of chlorofluorocarbon compounds on palladium catalysts, J. Phys. Chem. B 104 (2000) 3067.
34. D.J. Moon, M.J. Chung, K.Y. Park, S.I. Hong, Deactivation of Pd catalysts in the hydrodechlorinationof chloropentafluoroethane, Appl. Catal. A: General 168 (1998) 159.
35. D.J. Moon, M.J. Chung, K.Y. Park, S.I. Hong, Adsorption equlibrium and catalytic reaction of CFC-115 on Pd/Activated carbon powder, Carbon 37 (1999) 123.
36. L. Delannoy, J.M. Giraudon, P. Granger, L. Leclercq, G. Leclercq, Group IV transition metal carbides asalternatives in the hydrodechlorination of chlorofluorocarbons, Catal. Today 59 (2000) 231.
37. R. Ohnishi, I. Suzuki, M. Ichikawa, Bi-Pd catalyst for selective hydrodechlorination of 1,1,2-trichlorotrifluoroethane to trifluoroethane, a key intermediate to 1,1,1,2-tetrafluoroethane as a CFC replacement for refrigeration, Chem. Lett. (1991), 841.
38. R. Ohnishi, W.L. Wang, M. Ichikawa, Selective hydrodechlorination of CFC-113 on Bi- and Tl-modified palladium catalysts, Appl. Catal. A: General 113 (1994) 29.
39. S.P. Scott, M. Sweetman, J. Thomson, A.G. Fitzgerald, E.J. Sturrock, Catalytic hydrogenolysis of 1,1,2-trichlorotrifluoroethane on γ-Al2O3 supported palladium/Zinc oxide catalyst, J. Catal. 168 (1997) 501.
40. H.S. Kim, O.J. Cho, I.M. Lee, H.P. Hong, C.Y. Kwag, B.S. Ahn, Selective hydrogenolysis of chlorofluorocarbons by RhCl(PPh3)3, J. Mol. Catal. A: Chemical 111 (1996) 49.
41. S. Ordó?ez, M. Makkee, J.A. Moulijn, Performance of activated carbon-supported noble metal catalysts in the hydrogenolysis of CCl3F, Appl. Catal. B: Environmental 29 (2001) 13.
42. B. Basu, S. Satapathy, A.K. Bhatnagar, Merox and related metal phthalocyanine catalyzed oxidation processes, Catal. Rev.-Sci. Eng. 35 (1993) 571.
43. H. Shirai, H. Tsuiki, E. Masuda, T. Koyama, K. Hanabusa, N. Kobayashi, Functional metallomacro-cycles and their polymers, 25. Kinetics and mechanism of the biomimetic oxidation of thiol by oxygen catalysed by homogeneous (polycarboxyphthalocyanato) metals, J. Phys. Chem. 95 (1991) 417.
44. T. Ichinohe, H. Miyasaka, A. Isoda, M. Kimura, K. Hanabusa, H. Shirai, Functional metallomacrocycles and their polymers, Part 37: Oxidative decomposition of 2,4,6-trichloro-phenol by polymer-bound phthalocyanines, Reactive and Functional Polymers 43 (2000) 63.
45. A. Kempa, J. Dobrowlski, Palladium phthalocyanine and its polymorphic forms, Can. J. Chem. 66 (1988) 2553.
46. M.P. Sammes, The infrared spectrum of phthalocyanine: assignment of N-H modes, J. Chem. Soc., Perkin Trans. (1972) 160.
47. A.W. Snow, J.R. Griffith, Syntheses and characterization of heteroatom- bridged metal free phthalo-cyanine network ploymers and model compounds, Macromolecule 17 (1984) 1614.
48. A.M. Schaffer, M. Gouterman, E.R. Davidson, Porphyrins XXVIII*. Extended Hückel caculations on metal phthalocyanines and tetrazaporphins, Theo. Chim. Acta, Berl. 30 (1973) 9.
49. R.D. Farina, D.J. Halko, J.H. Swinehart, A kinetic study of the monomer-Dimer equilibrium in aqueouse vanadium (IV) tetrasulfophthalocyanine solutions, J. Phys. Chem. 76 (1972) 2343.
50. S.J. Kim, M. Matsumoto, K. Shigenhara, Synthesis and electrical properties of poly ( -1,4-diisocyanobenzene) octacyanophthalocyaninatoiron (II), Synth. Met. 107 (1999) 27.
51. T.N. Bell, P. Kirszensztejn, B. Czajka, Catalytic conversion of CCl2F2 on Pt/γ-Al2O3 catalyst, React. Kinet. Catal. Lett. 56 (1995) 221.
52. F. Ciardelli, E. Tsuchida, D. W?hrle (Eds.), Macromolecule- Metal Complexes, Springer, Germany, 1996.
53. B.N. Achar, P.K. Jayasree, Synth. Met. Novel `synthetic metals based on symmetrically tetrasubstituted nickel phthalocyanines, 104 (1999) 101.
54. H.C. Choi, S.H. Choi, J.S. Lee K.H. Lee, Y.G. Kim, Effects of Pt precursors on hydrodechlorination of carbon tetrachloride over Pt/Al2O3, J. Catal. 166 (1997) 284.
1. B. Coq, F. Figueras, S. Hub, D. Tournigant, Effect of the metal-support interaction on the catalytic properties of palladium for the conversion of dichlorodofluoromethane with hydrogen: compariso of oxides and fluorides as supports, J. Phys. Chem. 99 (1995) 11159.
2. W. Juszczyk, A. Malinowski, Z. Karpinski, Hydrodechlorination of CCl2F2 (CFC-12) over γ-alumina supported palladium catalysts, Appl. Catal. A166 (1998) 311.
3. S. Deshmukh, J.L. d’Itri, Transient kinetics investigations of reaction intermediates involved in CF2Cl2 hydrodechlorination, Catal. Today 40 (1998) 377.
4. K. Early, V.I. Kovalchuk, F. Lonyi, S. Deshmukh, J.L. d’Itri, Catalytic hydrodechlorination of 1,1-dichlorotetrafluoroethane and dichlorofluoromethane catalyzed by Pd on flurinated alumina: therole of support material, J. Catal. 182 (1999) 219.
5. B. Coq, J.M. Cognion, F. Figueras, D. Tournigant, convesion under hydrogen of dichlorodifluoromethane over supported palladium catalysts, J. Catal.141 (1993) 21.
6. B.S. Ahn, S.C. Lee, D.J. Moon and B.G. Lee, A study of hydrodechlorination reaction of dichlorodifluoromethane over Pd/AlF3 catalyst, J. Mol. Catal. A 106 (1996) 83.
7. A. Malinowski, W. Juszczyk, J. Pielaszek, M. Bonarowska, M. Wojciechowska, Z. Karpinski, Magnesium fluoride as a support in hydrodechlorination of CCl2F2 (CFC-12), Chem. Commun. (1999) 685.
8. E.J.A.X. van de Sandt, A. Wiersma, M. Makkee, H.Vanbekkum, J.A. Moulijn, Palladium black as model catalyst in the hydrogenolysis of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Appl. Catal. A 155 (1997) 59.
9. E.J.A.X. van de Sandt, A. Wiersma, M. Makkee, H.Vanbekkum, J.A. Moulijn, Catalyst development for the selective hydrodechlorination of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Catal. Today 35 (1997) 163.
10. M. Makkee, A. Wiersma, E.J.A.X. van de Sandt, H. Van Bekkum, J.A. Moulijn, Development of a palladium on activated carbon for a conceptual process in the selective hydrogenolysis of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Catal. Today 55 (2000) 125.
11. A.L.D. Ramos, M. Schmal, D.A.G. Aranda and G.A. Somorjai, Hydrodechlorination of dichlorodifluoromethane over palladium catalysts and a comparison with the hydrodeclorination of 1,1-dichlorotetrafluoroethane, J. Catal. 192 (2000) 423.
12. F.H. Ribeiro, C.A. Gerken, G. Rupprechter, G.A. Somorjai, C.S. Kellner, G.W.Coulston, L.E. Manzer and L. Abrams, Structure insensitivity and effect of sulfur in the reaction of hydrodechlorination of 1,1-dichlorotetrafluoroethane (CF3-CFCl2) over Pd catalysts, J. Catal. 176 (1998) 352.
13. H. Itatani and J.C.Bailar, Jc., Homogeneous catalysts in the reaction of olefinic substances V: hydrogenation of soybean oil methyl ester with triphenylphosphine and triphenylarsine palladium catlysts, J. Am. Oil Chem. Soc. 44 (1967) 147.
14. A.Morato, C. Alonso, F. Medina, J.L. Garreta, J.E. Sueiras, Y. Cesteros, P. Salagre, D. Tichit and B. Coq, KMg1-xPdxF3 with perovskite-like sructures as precursors for the catalytic hydroconversion of CCl2F2 and CHClF2, Catal. Lett. 77 (2001) 141.
15. J.E. Benson, H.S. Hwang and M.J. Boudart, Hydrogen-Oxygen Titration Method for the Mesurement of Supported Palladium Surface Areas, J. Catal. 30 (1973) 146.
16. M. Wojciechowska, B. Czajka, M. Pietrowski and M. Zielinski, MgF2 as a non-conventional catalytic support. Surface and structure characterization, Catal. Lett. 66 (2000) 147.
17. M.Maciejewski and A. Baiker, Incorporation and reactivity of carbon in palladium, Pure Appl. Chem. 67 (1995) 1879.
18. M.A. Subramanian and V.N.M. Rao, Cubic chromium trifluoride and its use for halogenated hydrocarbon processing, US patent 6028026, 2000-02-22.
19. 刘世宏, 王当憨, 潘承璜, X射线光电子能谱分析, 科学出版社: 北京, 1988.
20. L. Delannoy, J.M. Giraudon, P. Granger, L. Leclercq and G. Leclercq, Group VI transition metal carbides as alternatives in the hydrodechlorination of chlorofluorocarbons, Catal. Today, 59 (2000) 231.
21. L. Delannoy, J.M. Giraudon, P. Granger, L. Leclercq and G. Leclercq, Hydrodechlorination of CCl4 over Group VI transition metal carbides, Appl. Catal. B: Enironmental, 37 (2002) 161.
22. R.J. Levis, L.A. Delouise, E.J. White and N. Winograd, Defect induced surface chemistry: A comparison of the adsorption and thermal decomposition of ethene on Rhodium [111] and Rhodium [331], Surf. Sci. 230 (1990) 35.
23. H.P. Bonzel and H.J. Krebs, On the chemical nature of the carbonaceous deposit iron after carbonmonoxide hydrogenation, Surf. Sci. 90 (1980) 499.
24. Y. Yuan, K.Asakura, H. Wan, K. Tsai and Y. Iwasawa, Supported gold catalysts derived from gold complexes and as precipitated metal hydroxides highly active for low temperature CO oxidation, Chem. Lett. (1996) 755.
25. A.P. Kozlova, S. Sugiyama, A.I. Kozlov, K.Asakura and Y. Iwasawa, Iron-Oxide Supported Gold Catalysts Derived from Gold-Phosphine Complex Au (PPh3)(NO3): State and Structure of the Support, J. Catal. 176 (1998) 426.
26. A.I. Kozlov, A.P. Kozlova, K.Asakura, Y. Matsui, T. Kogure, T. Shido and Y. Iwasawa, Supported Gold Catalysts Prepared from a Gold Phosphine Precursor and As-Precipitated Metal-Hydroxide Precursors: Effect of Preparation Conditions on the Catalytic Performance, J. Catal. 196 (2000) 56.
27. T.N. Bell, P. Kirszensztejn and B. Czajka, Catalytic conversion of CCl2F2 on Pt/γ-Al2O3 catalyst, React. Kinet. Catal. Lett. 56 (1995) 221.
28. E.H. van Broekhoven and V. Ponec, Surface chemistry of small particles, Surface Sci. 162 (1985) 731.
29. B. Coq, G. Ferrat and F. Figuéras, Conversion of chlorobenzene over palladium and rhodium catalysts of widely varying dispersion, J. Catal. 101 (1986) 434.
1. C.D. Thompson, R.M. Rioux, N. Chen and F.H. Ribeiro, Turnover rate, reaction order, and Elementary steps for the hydrodechlorination of chlorofluorocarbon compounds on Pd catalysts, J. Phys. Chem. B 104 (2000) 3067.
2. F.H. Ribeiro, C.A. Gerken, G.A. Somorjai, C.S. Kellner, G.W. Coulston, L.E. Manzer and L. Abrams, Turnoiver rate and kinetic mechanism for the reaction of hydrodechlorination of 1,1-dichlorotetrafluoroethane (CF3-CFCl2) over a polycrystalline Pd foid, Catal. Lett. 45 (1997) 149.
3. A.L.D. Ramos, M. Schmal, D.A.G. Aranda and G.A. Somorjai, Hydrodechlorination of dichlorodifluoromethane over palladium catalysts and a comparison with the hydrodeclorination of 1,1-dichlorotetrafluoroethane, J. Catal. 192 (2000) 423.
4. W. Juszczyk, A. Malinowski, Z. Karpinski, Hydrodechlorination of CCl2F2 (CFC-12) over γ-alumina supported palladium catalysts, Appl. Catal. A166 (1998) 311.
5. A.V. Vernov, W.A. Steele and A. Abrams, Sorption of xenon zeolite Rho: A thernodynamic/Simulation study, J. Phys. Chem. 97 (1993) 7660.
6. B. Coq, J.M. Cognion, F. Figueras, D. Tournigant, convesion under hydrogen of dichlorodifluoromethane over supported palladium catalysts, J. Catal.141 (1993) 21.
7. Y.C. Cao, X.Z. Jiang, W.H. Song, Z.Q. Bai, X.Q. Fang, Hydrodechlorination of CFC-12 over novel supported palladium catalysts, Catal. Lett. 76 (2001) 53.
8. B. Coq, F. Figueras, S. Hub, D. Tournigant, Effect of the metal-support interaction on the catalytic properties of palladium for the conversion of dichlorodofluoromethane with hydrogen: compariso of oxides and fluorides as supports, J. Phys. Chem. 99 (1995) 11159.
9. D.J. Moon, M.J. Chung, K.Y. Park, S.I. Hong, Deactivation of Pd catalysts in the hydrodechlorination of chloropentafluoroethane, Appl. Catal. A: General 168 (1998) 159.
10. J.A. Moulijn, M. Makkee, A. Wiersma, E.J.A.X. van de Sandt, Selective hydrogenolysis of CCl2F2 into CH2F2 over palladium on activated carbon Kinetic mechanism and process design, Catalysis Today 59 (2000) 221.
11. F.R. Reinoso, The role of carbon materials in the heterogeneous catalysts, Carbon 36 (1998) 159.
12. E.J.A.X. van de Sandt, A. Wiersma, M. Makkee, H.Vanbekkum, J.A. Moulijn, Catalyst development for the selective hydrodechlorination of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Catal. Today 35 (1997) 163.
13. A. Wiersma, E.J.A.X. van de Sandt, M. Makkee, C.P. Luteijn,H. Vanbekkum, J.A. Moulijn, Process for the selective hydrogenolysis of CCl2F2 (CFC-12) into CH2F2 (HFC-32), Catal. Today 27 (1996) 257.
1. Y.C. Cao, X.Z. Jiang, W.H. Song, Z.Q. Bai, X.Q. Fang, Hydrodechlorination of CFC-12 over novel supported palladium catalysts, Catal. Lett. 76 (2001) 53.
2. Y.C. Cao and X.Z. Jiang, Supported palladium phthalocyanine in Hydrodechlorination of CFC-12, J. Mol. Catal. A: Chenmical, 2002 (in press)
3. Y.C. Cao and X.Z. Jiang, Novel hydodechlorination of CCl2F2 over supported PdCl2-(n-C4H9)4N+Cl- molten salts, Chinese Chemical Letters, 12 (2001) 533.
4. N.I. Buchan, T.F. Kuech, G.J. Scilla and F. Cardone, Carbon incorporation in metalorganic vapor phase epitaxy grown gallium arsenide using CHyX4-y trimethylgallium and arsine, J. Cryst. Growth 110 (1991) 405.
5. J. Tokuda, M. Takai, H. Nakai, K. Gamo, S. Nawaba, Laser induced thermochemical etching of ferrite in carbon tetrachloride, J. Opt. Soc., Am. B4 (1987) 267.
6. N. Supranat, T. Nunno, M. Kravett, M. Breton, Halogenated Organic Containing Wastes: Treatment Technologies, Noyes Data Corporation, Park Ridge, NJ, 1988.
7. S. Morikawa, M. Yoshitake, S. Tatematsu, Method for producing a hydrogen-containing chloromethane, US Patent 5,334,782 (1989).
8. E.T. Miguel, J.M.S. Gimenez, A.C. Arroyo, X.L.S. Gomez, A.A. Martin, process for the manufacture of chloroform, US Patent 5,208,393 (1993).
9. A.H. Weiss, B.S. Gambhir, R.B. Leon, Hydrodechlorination of carbon tetrachloride, J. Catal. 22 (1971) 245.
10. A.H. Weiss, S. Valinski, Hydrodechlorination and oligomerization of carbon tetrachloride over nickel Y zeolites, J. Catal. 74 (1982) 136.
11. S.Y. Kim, H.C. Choi, O.B. Yanga, K.H. Lee, J.S. Lee, Y.G. Kim, Hydrodechlorination of carbon tetrachloride over supported Pt catalysts, J. Chem. Soc., Chem. Commun. (1995) 2169.
12. H.C. Choi, S.H. Choi, J.S. Lee, K.H. Lee, Y.G. Kim, Hydrodechlorination of Carbon Tetrachloride over Pt/MgO, J. Catal. 161 (1996) 790.
13. H.C. Choi, S.H. Choi, J.S. Lee K.H. Lee, Y.G. Kim, Effects of Pt precursors on hydrodechlorination of carbon tetrachloride over Pt/Al2O3, J. Catal. 166 (1997) 284.
14. Z.C. Zhang, B.C. Beard, Genesis of durable catalyst for selective hydrodechlori-nation of CCl4 to CHCl3, Appl. Catal. A: General 174 (1998) 33.
15. F.G. Sherif, Catalytic hydrodechlorination of a chloromethane, US Patent 5,426,252 (1995).
16. L. Delannoy, J.-M. Giraudon, P. Granger, L. Leclercq and G. Leclercq, Hydrodechlorination of CCl4 over group VI transition metal carbides, Applied Catalysis B: Environmental 37 (2002) 161.
17. P. Bodnariuk, B. Coq, G. Ferrat and F. Figueras, Carbon-Chlorine hydrogenolysis over PdRh and PdSn bimetallic catalysts, J. Catal. 116 (1989) 459.
18. B. Coq, S. Hub, F. Figueras, D. Tournigant, Convesion under hydrogen of dichlorodifluoromethane over bimetallic palladium catalysts, Appl. Catal. A101 (1993) 41.
19. A. Malinowski, W. Juszczyk, M. Bonarowska, J. Pielaszek,Z. Karpinski, Pd-Re/Al2O3: characterization and catalytic activity in hydrodechlorination of CCl2F2, J. Catal. 177 (1998) 153.
20. R. Ohnishi, W.L. Wang, M. Ichikawa, Selective hydrodechlorination of CFC-113 on Bi and Tl-modified palladium catalysts, Appl. Catal. A 113 (1994) 29.
21. B. Heinrichs, F. Noville, J.P. Schoebrechts, J.P. Pirard, Palladium-Silver Sol-Gel Catalysts for Selective Hydrodechlorination of 1,2-Dichloroethane into Ethylene II. Surface composition of alloy particles, J. Catal. 192 (2000) 108.
22. S.T. Srinivas, L. Jansi Lankshmi and P. Kanta Rao, Selective vapour-phase hydrodechlorination of chlorobezene over alumina supported platinum bimetallic catalysts, Appl. Catal. A 135 (1996) 201.
23. K.O. Early, W.D. Rhodes, V.I. Kovalchuk, J.L. d’Itri, Hydrogen-assisted 1,2,3-trichloropropane on supported Pt-Sn catalysts, Appl. Catal. B: evironmental 26 (2000) 257.
24. B. Coq, A. Tijani and F. Figueras, Influence of alloying platinum for the hydrogenation of p-chloronitrobenzene over PtM/Al2O3 catalysts with M=Sn, Pb, Ge, Al, Zn, J. Mol. Catal. 71 (1992) 317.
25. X. Wu, Y.A. Letuchy, D.P. Eyman, Catalytic hydrodechlorination of CCl4 over silica-supportedPdCl2 containing molten salt catalysts: the promotional effects of CoCl2 and CuCl2, J. Catal. 161 (1996) 164.
26. A. Wiersma, E.J.A.X. van de Sandt, M.A. den Hollander, H.van Bekkum, M. Makkee, J.A. Moulijn, Comparison of the performance of activated carbon supported noble metal catalysts in the hydrogenolysis of CF2Cl2, J. Catal. 177 (1998) 29.
27. A. Malinowski, W. Juszczyk, J. Pielaszek, M. Bonarowska, M. Wojciechowska, Z. Karpinski, Magnesium fluoride as a support in hydrodechlorination of CCl2F2 (CFC-12), Chem. Commun. (1999) 685.
28. Carl L. Yaws, Thermodynamic and physical property data, Gulf Publishing Company, Houston Texas, 1992, P78.
29. 蒋晓原, 毛建新, 陆维敏, 郑小明, 四氯化碳加氢制氯仿 Pt-Pd/C催化剂的制备研究, 石油化工, 29 (2000) 483.
30. 毛建新, 蒋晓原, 陆维敏, 郑小明, 四氯化碳液相催化加氢反应动力学的研究, 燃料化学学报, 29 (2001) 277.
31. 杨锡尧 候镜德 物理化学的气相色谱研究法 北京大学出版社 北京 1989 p242.