摘要
加脂剂是重要的皮革化学品之一,在赋予皮革良好性能的同时,由于其与皮革纤维之间的结合牢度比较低,在受热过程中极易迁移至皮革表面,直接成为燃料,从而提高了皮革的易燃性。因此,阻燃性已经成为高层建筑内装潢、飞机和汽车内装饰、办公家具制造、森林防火装备制造用皮革的要求之一。传统的阻燃皮革以外加含卤素阻燃剂为主,但卤素作为阻燃剂燃烧时会产生大量烟雾并释放有毒、腐蚀性的卤化氢气体,对人体和环境造成严重的危害。因此绿色环保型阻燃剂的研究备受研究者的关注。由于石油资源的有限性带来的能源危机以及使用过程中造成的环境污染,迫使人们以天然油脂替代石油作为化工原料进行深度加工;另一方面,我国是世界油料大国,天然油脂成为制备加脂剂的最主要原材料。菜籽油是制革工业中最早使用且沿用至今的植物油基加脂剂原料之一。
本课题以廉价的菜籽油为原料,将其与乙二胺进行部分酰胺化反应,适当降低碳链长度,同时引进-OH,然后通过丙烯酸引入-COOH,再加入亚硫酸氢钠对菜籽油进行亚硫酸化改性,制得改性菜籽油(MRO)加脂剂;通过超声波法将钠基蒙脱土引入改性菜籽油中。分别采用季铵盐、脂肪酸、鞣性离子、硅烷偶联剂对蒙脱土(MMT)进行改性,制备了季铵盐改性蒙脱土(季铵盐-MMT)、脂肪酸改性蒙脱土(脂肪酸-MMT)、鞣性离子改性蒙脱土(鞣性离子-MMT)、硅烷偶联剂改性蒙脱土(硅烷偶联剂-MMT);采用XRD、FT-IR及TGA对改性蒙脱土进行了表征。进而将不同类型的改性蒙脱土分别通过原位法引入改性菜籽油加脂剂的合成中,对制得的纳米复合加脂剂各项稳定性进行了检测,采用FT-IR、XRD、TGA、DLS对纳米复合加脂剂进行了表征;将纳米复合加脂剂分别应用于山羊皮服装革加脂工艺中,对加脂后革样的物理机械性能、柔软度和加脂后废液进行了检测,并通过垂直燃烧对革样的阻燃性能进行了测定,采用SEM与EDS对加脂后革样进行了表征。将改性菜籽油加脂剂与植物油、矿物油等复配制备复合加脂剂,将其与国外同类产品的应用性能进行对比。
通过单因素试验、正交试验对改性菜籽油的最优工艺进行了优化,最优制备条件为:菜籽油用量为1mol,乙二胺用量为0.6mol,丙烯酸用量为2.6mol,氧化铝用量为0.12mol,亚硫酸氢钠用量为2.88mol。FT-IR、UV结果表明:成功制备了改性菜籽油加脂剂。应用结果表明:MRO加脂剂具有更好的吸收效果,能赋予革样更好的柔软性、丰满性及弹性,加脂后革样的物理机械性能与同类商业产品相当。
通过均匀试验、单因素试验和正交试验优化了超声法制备改性菜籽油/钠基蒙脱土纳米复合加脂剂(MRO/Na-MMT)的最优条件为:超声功率700W(50g),超声总时间35min,超声间隔时间2s/1s,蒙脱土用量7%。FT-IR、TEM及XRD结果表明:改性菜籽油能够顺利进入蒙脱土层间,制备了插层型纳米复合材料;随着蒙脱土用量的增加,纳米复合材料中蒙脱土的层间距先增加后降低。应用结果表明:与MRO加脂后革样相比较,蒙脱土的加入能够有效提高革样的阻燃性、抗张强度和撕裂强度,降低革样的塑性;采用MRO/Na-MMT加脂后革样的抗张强度、撕裂强度、弹性、柔软性及丰满性均优于同类商业产品加脂后革样。
对于不同链长的季铵盐-MMT,经FT-IR、XRD及TGA分析结果表明:季铵盐能够进入蒙脱土层间,成功改性蒙脱土。将季铵盐-MMT通过原位法引入改性菜籽油加脂剂中,XRD与FT-IR结果表明:成功制备了改性菜籽油/季铵盐改性蒙脱土纳米复合加脂剂(MRO/季铵盐-MMT),当引入适量季铵盐-MMT,纳米复合加脂剂中蒙脱土片层以剥离的形态存在。应用结果表明:与MRO加脂后革样相比,使用MRO/季铵盐-MMT加脂后革样的柔软度、物理机械性能和阻燃性均有所提高;当烷基链长相等时,含单链和三链烷基链的季铵盐所制得的纳米复合加脂剂阻燃效果均优于双链季铵盐制得的纳米复合加脂剂;当烷基取代数相等时,季铵盐中烷基链长越短,阻燃效果越好;其中改性菜籽油/三辛基甲基氯化铵改性蒙脱土纳米复合加脂剂(MRO/T811-MMT)加脂后革样的综合性能最优。
对于不同种类的脂肪酸-MMT,经FT-IR、XRD及TGA分析结果表明:各种脂肪酸均能进入蒙脱土层间,成功改性蒙脱土。将油酸改性蒙脱土、芥酸改性蒙脱土和肉豆蔻酸改性蒙脱土通过原位法分别引入改性菜籽油中,能够成功制备纳米复合加脂剂;然而将硬脂酸改性蒙脱土、棕榈酸改性蒙脱土、月桂酸改性蒙脱土通过原位法分别引入改性菜籽油中时,无法获得稳定的纳米复合加脂剂。应用结果表明:与MRO加脂后革样相比,采用稳定的改性菜籽油/脂肪酸-蒙脱土纳米复合加脂剂(MRO/脂肪酸-MMT)加脂后革样的柔软度、机械性能均有不同程度提高;革样阻燃性能随着蒙脱土用量的增加而增强,其中改性菜籽油/油酸-蒙脱土纳米复合加脂剂加脂后革样的综合性能最优。
对于鞣性离子-MMT,经FT-IR、XRD及TGA分析结果表明:Cr~(3+)、Al~(3+)、Fe~(3+)、Zr~(4+)与钠基蒙脱土反应的最佳pH分别为3.5、4.5、7.0、2.0,在最优pH条件下,各种离子改性蒙脱土的层间距分别为1.55nm、1.54nm、1.53nm、1.43nm。将鞣性离子-MMT通过原位法引入改性菜籽油中,XRD、FT-IR及TGA结果表明:成功制备了改性菜籽油/鞣性离子-蒙脱土纳米复合加脂剂(MRO/鞣性离子-MMT);采用不同用量铝离子改性蒙脱土(Al-MMT)制备纳米复合加脂剂时,蒙脱土片层均以剥离的形态存在;改性菜籽油/铝离子-蒙脱土纳米复合加脂剂(MRO/Al-MMT)的热稳定性最好。应用结果表明:与MRO加脂后革样相比,改性菜籽油/鞣性离子-蒙脱土纳米复合加脂剂加脂后革样的柔软度、物理机械性能、阻燃性能均有所提高。
采用不同种类的硅烷偶联剂对蒙脱土进行改性,结果表明:γ-(甲基丙烯酰氧)丙基三甲氧基硅烷(KH570)、g-氨丙基三甲氧基硅烷(KH551)、3-哌嗪基丙基甲基二甲氧基硅烷(KH108)与γ-氨丙基三乙氧基硅烷(KH550)均能成功插层到蒙脱土层间;但是KH560、十六烷基三甲氧基硅烷、N-十二烷基三甲氧基硅烷及A-151未能顺利进入蒙脱土层间进行改性。将硅烷偶联剂-MMT通过原位法引入改性菜籽油中,XRD、FT-IR及TGA结果表明:成功制备了改性菜籽油/硅烷偶联剂-蒙脱土纳米复合加脂剂(MRO/硅烷偶联剂-MMT);当硅烷偶联剂-MMT用量小于2%时,MRO/硅烷偶联剂-MMT中蒙脱土片层均以剥离的形态存在;应用结果表明:与MRO加脂后革样相比,MRO/硅烷偶联剂-MMT加脂后革样的柔软度、物理机械性能、阻燃性能均有所提高,其中改性菜籽油/g-氨丙基三甲氧基硅烷改性蒙脱土纳米复合加脂剂(MRO/KH551-MMT)加脂后革样的综合性能最优。SEM及EDS结果表明:蒙脱土片层能够有效地渗透到革样的内部,均匀地分散到胶原纤维之间,不改变原纤维的三股螺旋结构,使胶原纤维的分散程度有所增加。
将改性菜籽油加脂剂与动物油、矿物油等复配制备复合加脂剂,应用结果表明:复合加脂剂能提高革样的柔软性、丰满性等,且其抗张强度、撕裂强度和断裂伸长率等均与同类商业产品接近。通过对工业化原料进行工艺调整,该改性菜籽油复合加脂剂已投入工业化生产,且市场反映效果良好。
本文通过改性菜籽油制备功能性皮革加脂剂,能够满足皮革工业发展需要,提高菜籽油在皮革工业中的使用价值。将传统制革工业与新兴纳米技术结合起来,分别将不同类型改性蒙脱土引入制备阻燃型改性菜籽油/蒙脱土纳米复合加脂剂,不仅能够满足人们日常生活的需要、拓展皮革的用途,也对无卤阻燃型皮革化学品的开发和皮革工业的可持续发展具有重要意义。
Fatliquoring agent is one of the important leather chemicals with widelyapplications in leather industry, and can endow the leather with goodperformances. However, it can migrate easily to the surface of leather to becomefuel due to the low fixation between fatliquoring agent and collagen fibers. Thusit improves the flammability. Therefore, flame retardance has become one of therequirements of leather used in decorating of high building, aircraft and car,manufacturing of office furniture, fire-prevention equipment in forest. Thetraditional flame retardant leather is obtained through adding halogen-containingflame retardants. But the halogen could release a lot of smoke and toxic,corrosive hydrogen halide when flaming which could cause serious harm tohumans and environment. Therefore, green flame retardant has attracted muchconcern. The energy crisis caused by the limitation of non-renewable petroleumresource and environmental pollution during using force people to replacepetroleum with natural oils to process in-depth as chemical raw materials. On theother hand, our country has become a global oil country. Natural oils become themain raw material to prepare fatliquoring agent. Rapeseed oil is one of rawmaterials to prepare vegetable oil-based fatliquoring agent which is earliest usedand still in used.
In our research, modified rapeseed oil (MRO) was prepared by usingrapeseed oil, ethylene diamine, acrylic acid and sodium bisulfite as raw material.Then modified rapeseed oil/Na-montmorillonite was prepared by ultrasonicmethod. On the other hand, modified montmorillonite was prepared usingquaternary ammonium salt (fatty acid, tanning ion or silane coupling agents) asmodifiers. Modified montmorillonite was characterized by XRD, FT-IR andTGA. Then modified rapeseed oil/modified montmorillonite by quaternary ammonium salt (fatty acid, tanning ion or silane coupling agents) nanocompositefatliquoring agent were synthesized by in-situ method. The stabilities ofnanocomposite fatliquoring agent were investigated and nanocompositefatliquoring agents were characterized using XRD, FT-IR, TGA and SEM, andapplied in fatliquoring process of goatskin garment leather. Physical andmechanical properties, flexibility and flame retardant property of leather usingnanocomposite as fatliquoring agent and the waste liquid after fatliquoringprocess were discussed. SEM and EDS were used to characterize the leather afterfatliquoring. At last, composite fatliquoring agent was prepared through mixingmodified rapeseed oil, vegetable oil and mineral oil. The performances ofleathers fatliquored by our product and similar foreign products as fatliquoringagent were compared.
Synthetic process of modified rapeseed oil was optimized throughorthogonal experiment and single factor experiment. The optimal preparationconditions were: dosage of rapeseed oil was1mol, dosage of ethylene diaminewas0.6mol, dosage of acrylic acid was2.6mol, dosage of aluminum oxide was0.12mol, and dosage of sodium hydrogen sulfite was2.88mol. The FT-IR andUV results show that the modified rapeseed oil fatliquoring agent was preparedsuccessfully. Then MRO was applied in leather fatliquoring process. Comparedwith commercial product, the application results show that MRO has goodabsorption effect and could endow leather with better flexibility, fullness,flexibility.
The optimum preparation condition of modified rapeseedoil/montmorillonite (MRO/Na-MMT) was investigated through the single factorexperiment and the orthogonal experiment. The optimal conditions were:ultrasonic power was700W (50g), total ultrasonic time was35min, ultrasonicinterval time was2s/1s, and dosage of montmorillonite was7%. FT-IR, TEM andXRD results show that the modified rapeseed oil could smoothly into theinterlayer of montmorillonite and intercalation nano-meter composite wasobtained. Interlamellar spacing of MMT in nanocomposite increased and thendecreased. The modified rapeseed oil, MRO/Na-MMT and commercial productfatliquoring separately applied in leather fatliquoring process. The applicationresults show that MRO/MMT could improve the flame retardancy effectively, tensile strength and tear strength of leather and reduce plastic of crust leathercompared with MRO. Tensile strength, tear strength, flexibility, softness andfullness of leather fatliquoried by MRO/Na-MMT were better than that of leatherfatliquored with commercial product.
Modified montmorillonite using quaternary ammonium salt with differentchain length as modifiers were prepared. FT-IR, XRD, TGA results show thatquaternary ammonium salt could enter into the interlayer of montmorillonite andmodify montmorillonite successfully. The modified montmorillonite byquaternary ammonium was introduced into the modified rapeseed oil by in-situmethod. FT-IR and XRD results show that MRO/quaternary ammoniumsalt-MMT nanocomposite fatliquoring agent was prepared successfully andlayers of MMT were existed in the form of stripping. Application results indicatethat softness, physical mechanical properties and flame retardant performance ofleather fatliquored by MRO/quaternary ammonium salt-MMT were improvedcomparing with that of leather fatliquored by MRO. The flame retardancy ofnanocomposite fatliquoring agent containing modified MMT by single-chain andthree-chain quaternary ammoniums were both better than that of nanocompositefatliquoring agent containing modified MMT by double-chain quaternaryammonium when the length of alkyl chains were equal. As the substitutionnumber of alkyl were equal, the flame retardancy was better with increasing thelength of alkyl in quaternary ammonium salt. Among them, the comprehensiveperformance of leather farliquored by MRO/trioctylphosphine methylammonium chloride-MMT nanocomposite fatliquoring agent was optimal.
Modified MMT by a variety of fatty acid were prepared. FT-IR, XRD, TGAresults show that a serious of fatty acid could enter the interlayer of MMT andMMT was modified successfully. The nanocomposite fatliquoring agent wasobtained through introducing the modified MMT by a serious of fatty acid intomodified rapeseed oil by in-situ method. Stable nanocomposite fatliquoringagent containing stearic acid-MMT, cetylic acid-MMT or lauric acid-MMT couldnot be obtained. Application results show that softness, physical and mechanicalproperties of leather fatliquored by MRO/fatty acid-MMT were improvedcomparing with that of leather fatliquored by MRO. And flame retardancy ofleather was increased with increasing amount of MMT. Among them, the comprehensive performance of leather farliquored by MRO/oleic acid-MMTnanocomposite fatliquoring agent was optimal.
Modified MMT by tanning ions was characterized by FT-IR, XRD andTGA. The result indicates that the best pH for reaction between Cr~(3+)、Al~(3+)、Fe~(3+)、Zr~(4+)and Na-montmorillonite were3.5,4.5,7.0,2.0, respectively. The interlayerspacing of various ions-MMT was1.55nm,1.54nm,1.53nm,1.43nm,respectively. The modified MMT by tanning ions were introduced into modifiedrapeseed oil by in-situ method. The results of FT-IR, XRD and TGA show thatMRO/tanning ions-MMT nanocomposite fatliquoring agent were preparedsuccessfully. Layers of MMT were existed in the form of stripping whendifferent amount of Al ion were utilized to prepare nanocomposite fatliquoringagent and the thermal stability of MRO/Al-MMT nanocomposite fatliquoringagent was the highest. Softness, physical and mechanical properties and flameretardant performance of leather fatliquored by MRO/tanning ions-MMT wereimproved compared with that of leather fatliquored by MRO.
Different kinds of silane coupling agent were used to modify MMT. Theresults show that KH570,KH551,KH108and KH550could enter the interlayerof MMT. However, hexadecyltrimethoxysilane, dodecyltrimethoxysilane,KH560and A-151could not enter the interlayer of MMT. The silane couplingagent-MMT was introduced into the modified rapeseed oil by in-situ method.The results of FT-IR, XRD and TGA show that MRO/silane couplingagent-MMT nanocomposite fatliquoring agent was obtained successfully. Layersof MMT were existed in the form of stripping when the amount of silanecoupling agent-MMT was lower than2%. Application results show that softness,physical and mechanical properties and flame retardancty of leather fatliquoredby MRO/silane coupling agent-MMT were improved compared with that ofleather fatliquored by MRO. Among them, the comprehensive performance ofleather fatliquored by MRO/KH551-MMT nanocomposite fatliquoring agentwas optimal. The results of SEM and EDS show that the layers of MMT couldpenetrate effectively into or disperse uniformly into the collagen fiber withoutany changes on structure of fibers which make the loose of collagen fiberincreased.
Composite fatliquoring agent was prepared through mixing MRO and vegetable oil, mineral oil. Application results show that softness and fullness offatliquored leather could be improved. Tensile strength, tear strength andelongation at break of leather were approximate to that of leather farliquored bysimilar commercial products. The MRO composite fatliquoring agent has alreadyput into industrial production through adjustment on process and raw materialand market effect is good.
In this paper, functional leather fatliquoring agent was prepared usingmodified rapeseed oil as raw material, which could achieve the developmentneeds of the leather industry and improve the value in use of rapeseed oil inleather industry. The combination of traditional leather industry with theemerging nanotechnology and introduction of different modified montmorilloniteinto flame retardant modified rapeseed oil/MMT nanocomposite fatliquoringagent can not only satisfy the needs of people's daily life, expand leatherapplication, but also has an important significance to development ofhalogen-free flame retardant leather chemical and sustainable development ofleather industry.
引文
[1]马建中,卿宁,吕生华.皮革化学品[M].北京:化学工业出版社,2008:31.
[2] Bajza Z, V I Vinkovic. Fatliquoring agent and drying temperature effects on leatherproperties[J]. Journal of materals scance,2001,36(21):5265-5270.
[3]魏世林.制革工艺学[M].北京:中国轻工业出版社,2001:400-402.
[4] Prabhavathy C, De S. Treatment of fatliquoring effluent from a tannery using membraneseparationprocess: Experimental and modeling[J]. Journal of Hazardous Materials.2010,176(1-3):434-443.
[5] Kronick P L. Leather processing, Bailey’s industrial oil and fat products[M]. In:Industrial and consumer non-edible products from oils and fats. New York: John Wiley&Sons,1996:309-316.
[6]赵维妹.国内外皮革加脂剂的发展概况[J].中国皮革,1997,26(3):32-33.
[7]周华龙,何有节.皮革化工材料[M].北京:科学出版社,2010:168-169.
[8]聂小安,蒋剑春,杨凯华,等.天然油脂制备生物柴油新技术的研究[J].生物质化学工程,2006,40(2):27-30.
[9]李秋小.我国油脂深加工研发现状[J].日用化学品科学,2007,30(8):15-20.
[10]张华涛.中国油脂化工行业现状与展望[J].中国油脂,2010,35(9):9-12.
[11]刘大川.我国油脂工业发展现状[J].农业机械,2010,14(19):34-36.
[12]李娜,杨涛.我国油菜籽产业发展现状及趋势展望[J].农业生产展望,2009,2:19-21.
[13]李云昌,胡琼,梅德圣,等.高产油量优质杂交油菜中油杂8号的选育及优良特性[J].中国农业科学,2005,38(11):2198-2204.
[14]陈兆波,余健.我国油菜生产形势分析及科研对策研究[J].中国油料作物学报,2010,32(2):303-308.
[15]卢荣,孙立蓉,卢行芳,等.菜籽油聚合加脂剂的制备[J].陕西科技大学学报,2005,23(2):36-40.
[16] Aider M, Barbana C. Conola Proteins: composition, extraction, functional, properties,bioactivity, applications as a food ingredient and allergenicity-A practical and criticalreview[J]. Trends in Food Science and Technology,2011,22(1):21-39.
[17] Vaitilingom G, Perilhon C, Liennard A, et al. Development of rape seed oil burners fordrying and heating[J]. Industrial Crops and Products,1998,7(2-3):273-279.
[18]苏玉光.磺化油生产技术[J].广西化工,1988(1):44-45.
[19]张世平,王照临,黄良莹.菜籽油的亚硫酸化[J].中国皮革,1998,27(2):31-33.
[20]张辉,强西怀.光催化下菜籽油氧化亚硫酸化工艺的研究[J].中国皮革,2007,36(11):34-36.
[21]曹向禹,吴平,张君礼.磷酸化反应及其在皮革上的应用[J].皮革化工,2005,22(2):27-30.
[22]兰云军,董贵平,许晓红,等.关于用磷酸化清洁生产技术制备皮革加脂剂的探讨[J].皮革与化工,2008,25(1):2-4.
[23]兰云军,鲍利红,钱志达,等.PVO系列磷酸化植物油加脂剂的研制[J].中国皮革,2002,31(1):32-34.
[24]邹祥龙,兰云军,银德海,等.菜籽油脂肪酸单乙醇酰胺的合成及其在皮革工业中的应用[J].西部皮革,2005(12):33-35.
[25]方建华,陈水波,董凌.含氮、氧改性菜籽油润滑添加剂对钢-钢摩擦副和钢-铝摩擦副摩擦学性能的影响[J].润滑油,2007,22(1):26-30.
[26]曹向禹,兰云军.醇解技术在制备皮革加脂剂方面的研究进展[J].皮革化工,2003,20(5):24-28.
[27] Tang Y, Meng M, Zhang J, et al. Effcient preparation of biodiesel from rapeseed oil overmodifed CaO[J].Applied Energy,2011,88(8):2735-3739.
[28] Galia A l, Scialdone O, Tortorici E. Transesterifcation of rapeseed oil over acid resinspromoted by supercritical carbon dioxide[J]. The Journal of Supercritical Fluids,2011,56(2):186-193.
[29]刘荣厚,曹卫星,黄彩霞.菜籽油碱催化酯交换法制备生物柴油工艺参数的优化[J].农业工程学报,2010,26(6):245-250.
[30]汤颖,汪济,张群正,等.氧化钙催化菜籽油酯交换制备生物柴油[J].安徽农业科学,2009,37(23):10858-10859.
[31]孟永禄.Ca/Al复合氧化物催化剂制备生物柴油的研究[D].天津:天津大学,2010.
[32]张家仁.固体碱催化甲醇与菜籽油酯交换合成生物柴油[D].武汉:华中科技大学,2006.
[33]韩磊.碱性离子液体催化菜籽油制备生物柴油的试验研究[D].昆明:昆明理工大学,2010.
[34] Fukuda H, Kondo A, Noda H. Biodiesel Fuel Production by Transesterification of oil[J].Journal of Bioscience and Bioengineering,2001,92(5):405-416.
[35]陈忠祥.硫磷化改性菜籽油制备极压润滑油工艺探索[J].安徽化工,2006(1):22-24.
[36]张浩,涂政文.含氮硼酸酯的合成及其在菜籽油中摩擦学性能研究[J].武汉工程学大学学报,2008,30(2):44-46.
[37]方建华,陈波水,黄伟九,等.磷氮化改性菜籽油润滑添加剂在菜籽油基础油和矿物油中的摩擦学性能[J].石油炼材与化工,2002,33(4):29-33.
[38]方建华,陈波水,董凌,等.含硫、硼的改性菜籽油润滑添加剂的制备及摩擦学性能[J].石油学报,2004,20(4):93-96.
[39]何忠义,熊丽萍,张少明.一种硫磷氮衍生物在菜籽油中的摩擦学研究[J].润滑与密封,2006(7):126-128.
[40]万银松,江英,于望,等.菜籽油酶法改性的研究[J].石河子大学学报(自然科学版),2007,25(3):354-356.
[41]王瑛瑶,栾霞,陈翔,等.菜籽油酶催化改性反应参数及产物性质研究[J].中国粮油学报,2011,26(4):52-56.
[42] Weselake R J, Taylorb D C. The study of storage lipid biosynthesis using microspore-derived cultures of oilseed rape[J]. Progress in Lipid Research,1999,38(5-6):401-460.
[43] Walker R L, Booth E J, Whytock G P, et al. Volunteer potential of genetically modifedoilseed rape with altered fatty acid content[J]. Agriculture, Ecosystems and Environment,2004,104(3):653-661.
[44] Reuter H, Schmidt G, Schroder W, et al. Regional distribution of genetically modifedorganisms (GMOs)-Up-scaling the dispersal and persistence potential of herbicideresistant oilseed rape[J]. Ecological Indicators,2011,11(4):989-999.
[45]殷树梅,岳葆泰,曲波.菜籽油脂肪酸丁酯加脂剂的研制[J].皮革化工,2000,17(5):22-23,35.
[46]张辉,强西怀.光催化下菜籽油氧化亚硫酸化工艺的研究[J].中国皮革,2007,36(11):34-36.
[47]王坤余,孙兵,但卫华,等.香型氧化亚硫酸化菜籽油加脂剂的研制及应用(Ⅰ)[J].中国皮革,2004,33(9):1-9.
[48]强西怀,樊国栋,李晓星.结合型氧化亚硫酸化菜籽油皮革加脂剂的制备与性能[J].精细化工,2002,19(6):346-349.
[49]单志华,于莉.磷酸化油脂组分性能分析[J].四川皮革,1995(1):26-28.
[50]邹祥龙,兰云军.菜籽油聚合物加脂剂PCF的合成及应用性能研究[J].西部皮革,2006(12):20-22.
[51]徐大鹏,卢荣.马来酸酐接枝菜籽油反应的反应[J].陕西科技大学学报,2006,24(3):55-57,80.
[52]程瑞,王嘉图,杜光伟,等.水溶液聚合法制备复鞣加脂剂[J].合成化学,2002,10(4):338-340.
[53]罗朝阳,张霞,范浩军,等.改性方法对加脂剂生物降解性的影响[J].中国皮革,2011,40(13):1-6.
[54] Wang X C, Ren Y Q, Qiang T T. Study on the biodegradability of oxidized sulfitingrapeseed oil fatliquor[J]. Applied Mechanics and Materials,2013,316-317:574-579.
[55]王晨,李书平,李民.皮革加脂剂制备中天然油脂的官能团反应[J].山东轻工业学院学报,2002,16(4):65-68.
[56]程凤霞,张岱民,王学川.毛皮加工原理及技术[M].北京:化学工业出版社,2005:153-158.
[57]郑顺姬,强西怀,张景斌,等.亚硫酸化羊毛脂皮革加脂剂的制备[J].日用化学工业,2003,33(6):363-365.
[58]王全杰,赵凤燕,高龙.阳离子皮革加脂剂的研究及进展[J].皮革与化工,2011,28(2):26-28.
[59]刘力,邵双喜.阳离子加脂剂的制备及应用[J].中国皮革,2001,30(11):12-15.
[60]赵永丽,丁秀云,崔元臣.一种新型阳离子蓖麻油加脂剂的合成及性能[J].皮革化工,2005,22(4):11-13.
[61]张静,涂伟萍,夏正斌.多功能加脂剂的研究进展[J].皮革化工,2004,21(5):9-12.
[62]马建中,王学川,石碧.皮革化学品的合成原理与应用技术[M].北京:中国轻工业出版社,2009:326-327.
[63]许戈文,熊潜生,王彤,等.水性聚氨酯填充性加脂剂的研制[J].中国皮革,2001,30(11):6-8.
[64]吕生华,马建中,杨宗邃,等.亚硫酸化填充加脂剂SAA的应用研究[J].皮革化工,2001,5(18):33-35.
[65]李文飞,周世龙,刘军海.防水性加脂剂的研究进展[J].皮革与化工,2011,28(3):17-19.
[66]郑顺姬,曹向禹,李晓波,等.高碳醇磷酸酯加脂剂的结构与组成对皮革性能的影响[J].齐齐哈尔大学学报,2006,22(4):82-85.
[67]廖银念,强西怀,周亚丽.皮革防水加脂剂的活性组分结构与其防水性相关性的研究[J].陕西科技大学学报,2006,2(24):47-49.
[68]郑顺姬,张丰,田甜,等.两亲复鞣加脂剂合成工艺的研究[J].日用化学工业,2007,37(4):275-277.
[69]胡强,俞从正.含磷化学品在皮革中的应用[J].西部皮革,2009,31(2l):25-28.
[70]曹向禹,张景彬.磷酸酯加脂剂的阻燃性能分析[J].皮革与化工,2010,27(6):13-16.
[71]王全杰,段宝荣,孙根行,等.加脂剂对皮革阻燃性的影响[J].中国皮革,2006,35(7):17-19.
[72]张静,夏正斌,涂伟萍.低雾化性加脂剂的研究进展[J].皮革科学与工程,2004,14(4):34-37.
[73] Du E, Yu S, Zuo L, et al. Pb(II)sorption on molecular sieve analogues of MCM-41synthesized from kaoliniteand montmorillonite[J]. Applied Clay Science,2011,51(1-2):94-101.
[74]余志伟.玉山蒙脱土结构改性及应用研究[J].非金属矿,2008,31:37-39.
[75]翁祖华,黄双路,郑玉婴,等.季铵盐表面活性剂烷烃链数目对改性蒙脱石结构的影响[J].日用化学工业,2001(5):8-9.
[76]吴婷,闫新亚,蔡祥,等.季铵盐插层蒙脱土及其去除海洋卡盾藻的研究[J].无机化学学报,2010,26(8):1399-1400.
[77]方宏,宋磊,郝振军,等.季铵盐对蒙脱土插层效果及表面活化的研究[J].塑料工业,2007,35:238-240.
[78] Li Y Q, Ishida H. A differential scanning calorimetry study of the assembly ofhexadecylamine molecules in the nanoscale confined space of silicate galleries[J].Chemistry,2002,14(3):1398-1404.
[79]刘玉芳,赵玲,尹平河,等.季磷盐改性蒙脱土去除球形棕囊藻的实验研究[J].中国环境科学,2011,31(8):1295-1299.
[80]周坤豪,戈明亮,胡小芳.季磷盐对蒙脱土/PA6纳米复合材料冲击性能的影响[J].塑料工业,2012,40(2):64-67,95.
[81]王小萍,谭井华,陈友林,等.固相法改性蒙脱土在聚氯乙烯中的应用[J].高分子材料科学与工程,2010,26(3):97-100.
[82]王小萍,沈威,贾德民.聚氯乙烯/蒙脱土纳米复合发泡材料的研究[J].合成材料老化与应用,2012,41(1):8-10,33.
[83] Bradley W F. Molecular associations between montmorillonite and some polyfunctionalorganic liquids[J]. Journal of the American Chemical Society,1945,67:975-981.
[84]李研,凌凤香,张喜文,等.蒙脱土催化材料的研究进展[J].当代化工,2006,35(2):80-83.
[85] Silva A A., Dahmouche K, Soares B G.. Nanostructure and dynamic mechanicalproperties of silane-functionalized montmorillonite/epoxy nanocomposites[J]. AppliedClay Science,2011,54(2):151-158.
[86] Mishra A K, Jena K K, Raju K V S N. Synthesis and characterization of hyperbranchedpolyester-urethane-urea/K10-clay hybrid coatings[J]. Progress in Organic Coatings,2009,64(1):1,47.
[87] Castel C D, Jr T P, Barbosa R V, et al. Mauler. Properties of silane graftedpolypropylene/montmorillonite nanocomposites[J]. Composites: Part A,2010,41(2):185-191.
[88] Wu P, Dai Y, Long H, et al. Characterization of organo-montmorillonites andcomparison for Sr(II) removal: Equilibrium and kinetic studies[J]. Chemical EngineeringJournal,2012,19(5):288-296.
[89]陈修栋,初本莉,王嘉承,等.Fe-Cr微波柱撑蒙脱土的制备及其对茜素红的吸附[J].广州化工,2010,39(24):61-63.
[90] Fatma T. Adsorption and catalytic properties of Fe/Cr-Pillared Bentonites[J]. ChemicalEngineering Journal,2012,185-186(5):380-390.
[91] Wu P, Zhou J, Wang X, et al. Adsorption of Cu-EDTA complexes from aqueous solutionsby polymeric Fe/Zr pillared montmorillonite: Behaviors and mechanisms[J].Desalination,2011,277(1-3):288-295.
[92] Luengoa C, Pucciaa V, Avena M. Arsenate adsorption and desorption kinetics on aFe(III)-modified montmorillonite[J]. Joural of Hazardous Materials,2011,186(2-3):1713-1719.
[93] Zhao S, Fenga C, Huang X, et al. Role of uniform pore structure and high positivecharges in the arsenate adsorption performance of Al13-modified montmorillonite[J].Joural of Hazardous Materials,2012,203-204:317-325.
[94]王立岩,李继新,杨恩宁,等.聚丙烯/共聚酯/蒙脱土复合材料结晶行为的研究[J].合成纤维,2010,(9):20-24.
[95] Qiu L, Chen W, Qu B. Morphology and thermal sTab.ilization mechanism ofLLDPE/MMT and LLDPE/LDH nanocomposites[J]. Polymer,2006,47(3):922-930.
[96] Kameshima Y, Tamura1Y, Nakajima A, et al. Preparation and properties ofTiO2/montmorillonite composites[J]. Applied Clay Science,2009,45(1-2):20-23.
[97]李春生,周春晖,李庆伟,等.聚合物/蒙脱土纳米复合材料的研究进展[J].化工生产与技术,2002,9(4):22-26.
[98] Han Y S, Lee S Y, Yang J H, et al. Paraquat release control using intercalatedmontmorillonite compounds[J]. Journal of Physics and Chemistry of Solids,2010,71(4):460-463.
[99] Yang X, Li Q, Chen Z, et al. Mechanical properties and flame retardancy research ofmontmorillonite intercalate polyamide66composites[J]. Journal of Composite Materials,2009,43(23):2785-2792.
[100]于志纲,贾朝霞.蒙脱土改性的研究进展[J].精细石油化工进展,2005,6(8):5-8.
[101]王丽梅,贺爱华,杜凯,等.聚丙烯/蒙脱土纳米复合材料的结构及物理性能研究[J].高校化学工程学报,2010,24(1):132-137.
[102] Zulfiqar S, Ahmad Z, Ishaq M, et al. Aromatic-aliphatic polyamide/montmorillonite claynanocomposite materials: Synthesis, nanostructure and properties[J]. Materials Scienceand Engineering A,2009,525(1-2):30-36.
[103] Zhang K, Wang L J, Wu X M, et al. Preparation and characteristics ofpolypropylene/nylon/montmorillonite flame retardant nanocomposites[J]. Plastics,Rubber and Composites,2008,37(5-6):210-213.
[104]兰云军.用科学发展观指导我国皮革工业的持续健康发展[J].中国皮革,2006,35(1):11-16.
[105]张淑华.当代皮革化学工作者的神圣职责及义务[J].精细化工,2008,25(2):105-108.
[106] Jian C H, Lin F H, Lee Y H. A study of purified montmorillonite intercalated with5-Fluorouracil as drug carrier[J]. Biomedical Sciences Instrumentation,2000,36:391-396.
[107] Xu D, Zhou N L, Zhu H L, et al. Study on chlorhexidime acetate-terbinafinehydrochloride/montmorillonite intercalation composites as drug release system.Gongneng Cailiao/Journal of Functional Materials[J].2009,40:1169-1171.
[108] Patel H A, Shah S, Shah D O, et al. Sustained release of venlafaxine fromvenlafaxine-montmorillonite-polyvinylpyrrolidone composites [J]. Applied Clay Science,2011,51(1-2):126-130.
[109]周丽梅,付海燕,李强,等.高分散Ru/MMT催化剂的制备及其催化喹啉加氢性能[J].催化学报,2010,31(6):695-700.
[110] Marvi O, Giah M. Montmorillonite KSF Clay as Novel and Recyclable HeterogeneousCatalyst for the Microwave Mediated Synthesis of Indan-1,3-Diones[J]. Bull. KoreanChem. Soc,2009,30(12):2918-2920.
[111] Ovcharenko F D, Dimov I Y, Tarasevich Y I. Use of montmorillonite as theisomerization catalyst of alpha-and beta-pinenes to camphene[J]. Soviet Progress inChemistry,1983,49:27-30.
[112] Joseph T, Shanbhag G V, Halligudi S B. Copper(II) ion-exchanged montmorillonite ascatalyst for the direct addition of N H bond to CC triple bond[J]. Journal of MolecularCatalysis A,2005,236(1-2):139-144.
[113] Daud N K, Ahmad M A, Hameed B H. Decolorization of Acid Red1dye solution byFenton-like process using Fe-Montmorillonite K10catalyst[J]. Chemical EngineeringJournal,2010,165:111-116.
[114] Rode C V, Kshirsagar V S, Nadgeri J M, et al. Cobalt-salen Intercalated MontmorilloniteCatalyst for Air Oxidation of p-Cresol under Mild Conditions[J]. Industrial andEngineering Chemistry Research,2007,46(25):8413-8419.
[115] Zheng E, Zheng X. Dehalogenation of Aryl Halides Catalyzed by MontmorilloniteImmobilized Bimetal Catalyst in Aqueous System[J]. Journal of Natural Gas Chemistry,2006,15(1):70-72.
[116] Lei Z, Ma G, Jia C G. Montmorillonite(MMT) supported tin(II) chloride: An efficientand recyclable heterogeneous catalyst for clean and selective Baeyer-Villiger oxidationwith hydrogen peroxide[J]. Catalysis Communications,2007,8(3):305-309.
[117] Jiang J, Ma K, Zheng Y, et al. Cobalt salophen complex immobilized intomontmorillonite as catalyst for the epoxidation of cyclohexene by air[J]. Applied ClayScience,2009,45(3):117-122.
[118] Dai H, Kang X, Wang P. Ruthenium nanoparticles immobilized in montmorillonite usedas catalyst for methanolysis of ammonia borane[J]. International Journal of HydrogenEnergy,2010,35(19):10317-10323.
[119] Louloudi A, Papayannakos N. Hydrogenation of benzene on Ni/Al-pillaredmontmorillonite catalysts[J]. Applied Catalysis A,2000,204(1):167-176.
[120] Li S Z, Wu P X. Characterization of sodium dodecyl sulfate modified iron pillaredmontmorillonite and its application for the removal of aqueous Cu(II) and Co(II)[J].Journal of Hazardous Materials,2010,173(1-3):62-70.
[121]谭绍早,张葵花,刘应亮.季鳞盐-铜/蒙脱土复合材料的制备及性能[J].复舍材料学报,2006,(3):82-86.
[122]朱家义.蒙脱土的改性及其在废水处理中的应用研究[J].广东化工,2009,36(10):136-140.
[123] Luck W. The History of Chrome Tanning Materials[J]. Journal of Society of LeatherTechnologists and Chemists,1986,70(4):99-103.
[124]鲁德平,管蓉,王必勤.纳米技术在高分子材料中的应用[J].现代塑料加工应用,2001,13(5):55-57.
[125]潘兆橹.结晶学及矿物学(下册)[M].北京:地质出版社,1984:165.
[126]李伟东,许承晃.粘土-有机物夹层复合物的形成及应用[J].中国矿业,1994,3(5):80-83.
[127]王永在,唐立兵.聚合物-蒙托石纳米复合材料的制备、结构与性能[J].材料导报,2003,17(9):107-109.
[128] Lakshminarayana Y., Jaisankar S. N., Saravanan P., et al. Leather retanning agent basedon acrylics onto montmorillonite[C]. Proceedings of the Ⅷ th Asian InternationalConference on Leather Science&Technology (AICLST),2010,12-14:89.
[129] Ma J Z, Gao D G, Chen X J, et al. Synthesis and characterization of VP/O-MMTmacromolecule nanocomposite material via polymer exfoliation-Adsorption method[J].Journal of Composite Materials,2006,40(24):2279-2286.
[130] Ma J Z, Gao DG, Lü B, et al. Study on PVP/C-MMT Nanocomposite Material viaPolymer Solution-Intercalation Method[J]. Materials and Manufacturing Processes,2007,22:715-720.
[131] Chu Y, Ma J Z, Gao D G, et al. Preparation and Application of Organic/Inorganic NanoTanning Agent[C]. The6th Asian International Conference of Leather Science andTechnology,2004,11:241-249.
[132] Ma J Z, Gao DG, Lü B, et al. Study on PVP/C-MMT nanocomposite material viapolymer solution intercalation method[C]. ACUN-5Conference,2006:421-430.
[133] Bao Y, Ma J Z, Wang Y L. Preparation of acrylic resin/montmorillonite nanocompositefor leather tanning agent[J]. Journal of the American Leather Chemists Association.2009,104(10):352-358.
[134]鲍艳,马建中,杨宗邃,等.PMAA/MMT纳米复合材料的制备研究[J].高分子材料科学与工程,2008,24(7):32-35.
[135]鲍艳,马建中,鄂涛.聚甲基丙烯酸/蒙脱土纳米复合材料的制备及性能研究[J].硅酸盐学报,2007,35(9):1253-1257.
[136]鄂涛,马建中,鲍艳.蒙脱土负载引发剂法制备PMAA/MMT纳米复合材料[J].功能材料,2008,39(7):1219-1222.
[137]马建中,鄂涛,鲍艳.蒙脱土负载引发剂的制备及活性研究[J].现代化工,2008,28(8):62-65.
[138] Gao D G, Ma J Z, LüB, et al. Study on PDM-AM-GL/MMT nanocomposites and itsapplication[J]. Materials and Manufacturing Processes,2009,24(12):1306-1311.
[139] Gao D G, Ma J Z, Lü B, et al. Characterization and Properties of PolymerDiallyldimethylammonium Chloride/Montmorillonite Nanocomposite Tannage[C].Proceedings of the30th IULTCS Congress,2009,10:143-152.
[140]高党鸽,马建中,吕斌,等.DMDAAC在蒙脱土中插层环化聚合及其应用的研究[J].高分子材料科学与工程,2006,22(6):71-75.
[141] Arias F, Sen T K. Removal of zinc metal ion (Zn2+) from its aqueous solution by kaolinclay mineral: A kinetic and equilibrium study[J]. Colloid sand Surfaces A:Physicochemical and Engineering Aspects,2009,348(1):100-108.
[142] Karamanis D T, Aslanoglou X A, Assimakopoulos P A, et al. An aluminum pillaredmontmorillonite with fast uptake of strontium and cesium from aqueous[J]. Clays andClay Miner,1997,45(5):709-717.
[143] Gupta S S, Bhattacharyya K G. Immobilization of Pb (II), Cd (II) and Ni(II) ions onkaolinite and montmorillonite surfaces from aqueous medium[J]. Journal ofEnvironmental Management,2008,87(1):46-58.
[144] Mahdavian A R, Ashjari M, Makoo A B. Preparation of poly (styrene-methylmethacrylate)/SiO2composite nanoparticles via emulsion polymerization. Aninvestigation into the compatiblization[J]. European Polymer Journal,2007,43(2):336-344.
[145] Zhao F C, Zeng X G, Li H Q, et al. Preparation and characterization ofnano-SiO2/fluorinated polyacrylate composite latex via nano-SiO2/acrylate dispersion[J].Colloids and Surfaces A: Physicochemical and Engineering Aspects,2012,396:328-335.
[146] Dyab A K F, Al-Lohedan H A, Essawy H A, et al. Fabrication of core/shell hybridorganic-inorganic polymer microspheres via Pickering emulsion polymerization usinglaponite nanoparticles[J]. Journal of Saudi Chemical Society,2011:1-7.
[147]高富堂.硅丙树脂/蒙脱土纳米复合成膜材料的研究[D].西安:陕西科技大学,2006.
[148]刘庆兰.有机硅改性丙烯酸树脂纳米复合涂饰材料的研究[D].西安:陕西科技大学,2005.
[149] Yilmaz O, Chiriac A P, Natalia C, et al. Nanocomposites based onmontmorillonite/acrylic copolymer for aqueous coating of soft surfaces[J]. Diffusion andDefect Data Pt. B: Solid State Phenomena,2009,151:129-134.
[150]王菊华.水性聚氨酯/蒙脱土纳米复合材料的制备及在皮革光油上的应用[D].杭州:浙江工业大学,2010.
[151] Zhang X L, Chen Y, Fan H J, et al. Waterborne polyurethane/O-MMT nanocompositesfor flame retardant leather finishing[J]. Journal of the Society of Leather Technologiesand Chemists,2010,94(2):77-83.
[152]欧育湘.阻燃剂[M].北京:国防工业出版社,2009:40-43.
[153] Grand A F, Wilkie C A. Fire Retardancy of Polymeric Materials[M]. New York: Taylor&Francis,2000:34-96
[154] Nangiaps B W. Someunresolvedproblemsin oxidationand combustion[J]. Accounts ofChemical Research,1979,12(7):23-228.
[155] Zanetti M, Caminogc G, Reichert P. Thermal behaviour of poly (propylene) layeredsilicate nanocomposites[J]. Macromolecular Rapid Communications,2001,22(3):176-180.
[156] Gogen J M, Lia T S. Flame Retardant Composition[P]. US:2006269771A1,2006.
[157] Messersmith P B, Giannelis E P. Synthesis and barrier properties ofpoly(e-caprolactone)-layered silicate nanocomposites[J]. Journal of Polymer Science PartA: Polymer Chemistry,1995,33:1047-1057.
[158] Lewinm M. Somecomments on themodes of action of nanocomposites in the flameretardancy of polymers [J]. FireMater,2003,27(1):1-7.
[159] Wang J, Du J, Zhu J, et al. An XPS study of thethermal degradation and flame retardantmechanism of polystyrene-clay nanocomposites[J]. Polymer Degradation and STab.ility,2002,77(2):249-252.
[160] Kashiwagi T, Harris R H, Zhang X, et al. Flame retardant mechanismof polyamide6clay nanocomposites[J]. Polymer,2004,45(3):881-891.
[161] Gilman J W, Jackson C L, Morgan A B, et al. Flamm-ability properties ofpolymer-layered-silicate nanocomposites. Polypropylene and polystyrenenanocomposites[J]. Chemistry of Materials,2000,12(7):1866-1873.
[162] Zhu J, Uhl F M, Morgan A B, et al. Studies on the mechanism by which the formation ofnanocomposites enhances thermal stability[J]. Chemistry of Materials,2001,13(12):4649-4654.
[163]漆宗能,尚文宇.聚合物/层状硅酸盐纳米复合材料理论与实践[M].北京:化学工业出版社,2002:57-58.
[164]米耀荣,于中振.聚合物纳米复合材料[M].北京:机械工业出版社,2010:24-43.
[165]许妃娟,邱祖民,刘钟薇.改性蒙脱土硅橡胶阻燃复合材料的制备[J].化工新型材料,2010,38(10):16-19.
[166]王庆国,张晓红,乔金梁.钠基蒙脱土在丁腈橡胶中的剥离分散及性能影响[J].科学通报,2008,53(12):482-1484.
[167]杨玲,钮英建.阻燃硅橡胶电缆材料热解动力学研究[J].消防科学与技术,2011,30(8):721-724.
[168]张涛,熊燕兵,郝建薇.尼龙66/蜜胺聚磷酸盐阻燃体系的增韧改性研究[J].工程塑料应用,2006,34(3):12-14.
[169] Kashiwagi T, Jr R H H, Zhang X, et al. Flame retardant mechanism of polyamide6-claynanocomposites[J]. Polymer,2004,45(3):881-891.
[170] Qin H L, Su Q H, Zhang S L, et al. Thermal stability and flammability of polyamide66/montmorillonite nanocomposites[J]. Polymer,2003,44(24):7533-7538.
[171] Qin H L, Zhang S M, Zhao C G, et al. Flame retardant mechanism of polymer/claynanocomposites based on polypropylene[J]. Polymer,2005,46(19):8386-8395.
[172]润德,童筱莉,费正新.聚氨酯/OMT纳米原位复合材料的制备及性能[J].高分子材料科学与工程,2006,22(2):59-62.
[173]毛文英,李巧玲,王亚昆.无卤阻燃尼龙66/蒙脱土纳米复合材料的制备及性能研究[J].化工新型材料,2007,35(4):60-62.
[174]马思远,杨伟,蒋舒,等.尼龙6/有机蒙脱土阻燃复合材料的结构与性能[J].塑料工业,2007,35(1):25-28.
[175]曹太山,何力,张纯,等.纳米蒙脱土对聚丙烯微孔发泡行为的影响[J].塑料,2009,38(6):28-30.
[176]龚维,高家诚,何力,等.纳米蒙脱土在聚丙烯微发泡材料中的应用[J].塑料科技,2009,37(9):47-51.
[177] Hu Z, Chen L, Zhao B, et al. A novel efficient halogen-free flame retardant system forpolycarbonate[J]. Polymer Degradation and STab.ility,2011,96(3):320-327.
[178]陈艳君.我国2010年油菜籽、菜籽油市场分析暨2011年展望[J].粮食与油脂,2011,38(1):38-41.
[179] Sivakumar V, Prakash R P, Rao P G. Power ultrasound in fatliquor preparation based onvegetable oil for leather application[J]. Journal of Cleaner Production,2008,16(4):549-553.
[180] Luo Z, Xia C C, Fan H J, et al. The Biodegradabilities of Different Oil-BasedFatliquors[J]. Journal of the American Oil Chemists Society,2011,88(7):1029-1036.
[181] Luo Z Y, Yao J, Fan H J. The biodegradabilities of rape oilbased fatliquors preparedfrom different methods[J]. Journal of The American Leather Chemists Association,2010,105:121-128.
[182]陈高明.皮革阻燃技术的研究[J].中国皮革,1997,26(11):16-18.
[183]段宝荣,王全杰,马先宝,等.皮革阻燃技术研究进展[J].西部皮革,2008,30(6):9-13.
[184]郝向阳,刘吉平,冯顺山.蒙脱土与阻燃剂的协效作用[J].高分子材料科学与工程,2003,(5):123-126.
[185] Zhi Hu, Li Chen, Bin Zhao, et al. A novel efficient halogen-free flame retardant systemfor polycarbonate[J]. Polymer Degradation and STab.ility,2011,96(3):320-327.
[186]俞从正,王坤余.皮革生产过程分析[M].北京:中国轻工业出版社,2006:114-121.
[187]何少华,文竹青.实验设计与数据处理[M].北京:国防科技大学出版社,2002:62-100.
[188] Sivakumar V, Prakash R. P, Rao P G, et al. Power ultrasound in fatliquor preparationbased on vegeTab.le oil for leather application[J]. Journal of Cleaner Production,2008,16(4):549-553.
[189] Sivakumar V, Swaminathan G, Rao P G. Studies on the application of power ultrasoundin fatliquoring process[J]. Journal of The American Leather Chemists Association,2005,100(5):187-195.
[190] Lin J, Hsu Y, Wei K. Mechanistic aspects of clay intercalation with anhydride-graftingpolyamine salts[J]. Macromolecules,2007,40(5):1579-1584.
[191]徐秉业,刘信声.应用弹塑性力学[M].北京:清华大学出版社,2003:74-75.
[192]王全杰.加脂剂对皮革阻燃性的影响[J].中国皮革,2006,35(7):17-19.
[193]谢友利,张猛,周永红.蒙脱土的有机改性研究进展[J].化工进展,2012,31(4):844-851.
[194]杨科,王锦成,郑晓昱.蒙脱土的结构、性能及其改性研究现状[J].上海工程技术大学学报,2011,25(1):65-70.
[195]马建中,陈新江,储芸,等.蒙脱土纳米复合材料的制备及应用研究[J].中国皮革,2002,31(21):14-19.
[196]梁建生.季铵盐类消毒剂及其应用[J].Chinese Journal of Disinfection,2012,29(2):129-131.
[197]薛文清,薛广波.季铵盐类阳离子表面活性消毒剂研究进展[J].中华医院感染学杂志,2002,12(8):634-636.
[198]水玲玲,郑利强,刘少杰,等.双子表面活性剂的研究进展[J].日用化学工业,2001,8(4):28.
[199] C1iment M J, Corma A, Garica H, et al. Acid-Base Bifunctional Catalysts for thepreparation of fine Chemicals: Synthesis of Jasminaldehyde[J]. Journal of Catalysis,197(2):385-393.
[200]郑广,高芒来,罗忠新,等.季铵盐改性蒙脱土的微观结构与表面分形特征[J].石油化工高等学校学报,2011,24(1):6-11.
[201] Xie W, Gao Z M, Pan W P, et al. Thermal degradation chemistry of alkyl quaternaryammonium montmorillonite[J]. Chemistry Material,2001,13(9):2979-2990.
[202]欧育湘,李建军,叶南飚.阻燃聚合物纳米复合材料[M].北京:国防工业出版社,2011:164.
[203]杨荣杰,王建祺.聚合物纳米复合物加工、热行为与阻燃性能[M].北京:科学出版社,2010:28.
[204]杨荣杰,王建祺.聚合物纳米复合物加工、热行为与阻燃性能[M].北京:科学出版社,2010:119-121.
[205] Kiliaris P, Papaspyrides C D. Polymer/layered silicate(clay)nanocomposites: Anoverview of fame retardancy[J]. Progress in Polymer Science,2010,35(7):902-908.
[206] Ghiaci M, Aghabarari B, Gil A. Production of biodiesel by esterification of natural fattyacids over modified organoclay catalysts[J]. Fuel,2011,90(11):3382-3389.
[207] Wang Y, Zheng H, Feng H X, et al. Effect of preparation methods on the structure andthermal properties of stearic acid/activated montmorillonite phase change materials[J].Fuel,2012,47:467-473.
[208] Li M, Wu Z S. A review of intercalation composite phase change material:Preparation, structure and properties[J]. Renewable and Sustainable Energy Reviews,2012,16(4):2094-2101.
[209]谢有利,张猛,周永红,等.硬脂酸酯季铵盐插层蒙脱土的制备及表征[J].非金属矿,2012,35(6):4-5,67.
[210]马银陈,周宁琳,陈亚红,等.二元脂肪酸、蒙脱土复合相变储能材料的制备及性能研究[J].化工新型材料,2007,35(10):7-9,35.
[211]李忠,井波,于少明.CA-SA/蒙脱土复合相变贮能材料的制备、结构与性能[J].化工新型材料,2007,35(3):42-44.
[212] Sarier N, Onder E, Ersoy S. The modification of Na-montmorillonite by salts of fattyacids: An easy intercalation process[J]. Colloids and Surfaces A: Physicochemical andEngineering Aspects,2010,371(1-3):40-49.
[213] Rooj S, Das A, St ckelhuber K W, et al. Pre-intercalation of long chain fatty acid inthe interlayer space of layered silicates and preparation of montmorillonite/naturalrubber nanocomposites[J]. Applied Clay Science,2012,67-68:50-56.
[214]陈修栋,初本莉,王嘉承,等.Fe-Cr微波柱撑蒙脱土的制备及其对茜素红的吸附[J].广州化工,2010,39(24):61-63.
[215] Zhou J B, Wu P X, Dang Z, et al. Polymeric Fe/Zr pillared montmorillonite for theremoval of Cr(VI) from aqueous solutions[J]. Chemical Engineering Journal,2010,162(3):1035-1044.
[216] Zhao S, Feng C H, Huang X N, et al. Role of uniform pore structure and high positivecharges in the arsenate adsorption performance of Al13-modified montmorillonite[J].2012,203-204:317-325.
[217] Park S, Kim B, Seo D, et al. Effects of a silane treatment on the mechanical interfacialproperties of montmorillonite/epoxy nanocomposites[J]. Materials Science andEngineering A,2009,526(1-2):74-78.
[218] Silva A A, Dahmouche K, Soares B G. Nanostructure and dynamic mechanical propertiesof silane-functionalized montmorillonite/epoxy nanocomposites[J]. Applied ClayScience,2011,54(2):151-158.
[219] Lu B, Ma J Z, Gao D G, et al. Synthesis and properties of modified rapeseedoil/montmorillonite nanocomposite fatliquoring agent[J]. Journal of Composite Materials,2011,45(24):2573-2578.
[220]李志强,廖隆理.生皮化学与组织学[M].北京:中国轻工业出版社,2010:167.
[221]杨玲,杨秦欢,张廷有.阴离子皮革加脂剂和阳离子聚合物的复配[J].中国皮革,2007,36(9):58-61.
[222]杨秦欢,杨玲,张廷有.阴离子皮革加脂剂与非离子表面活性剂的复配[J].皮革科学与工程,2008,18(3):5-10.
[223]宋照斌,宋启煌.高分子表面活性剂在水处理剂中的应用[J].精细化工,2000,17(12):700.
[224]王学川,郝晓丽,雒香,等.阴离子皮革加脂剂和阳离子聚合物的复配体系研究[J].皮革科学与工程,2011,21(4):11-16.
[225]王艳姣,强西怀,张辉,等.磺化大豆磷脂SPS复配加脂剂的应用[J].皮革科学与工程,2011,21(4):41-44.