类水滑石化合物的合成及处理含第一类重金属离子废水的试验研究
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摘要
随着电镀、制革、防腐和染料等工业的发展,人们向自然界排放的金属废弃物越来越多,特别是工业生产过程中产生的含铬、砷、镍、汞、镉、铅等重金属离子的废水造成了严重的环境污染。含重金属离子的废水对人体和环境造成的危害越来越严重,有效去除废水中重金属离子成为当前十分迫切的任务。而类水滑石化合物作为一种功能材料,其层板阳离子和层间阴离子具有可调控性,一定条件下可将多种金属阳离子及阴离子引入其结构中,并且可以通过在线合成类水滑石化合物消除第一类重金属离子造成的污染,同时得到类水滑石化合物,实现废物资源化利用。因此,利用类水滑石化合物的这一特性来处理含重金属离子的废水,具有重要的现实意义。本文合成了多种类水滑石化合物并分别用离线和在线的方法研究了类水滑石化合物对第一类重金属离子的吸附行为。论文主要包括以下几个方面的内容:
第一部分概述了重金属离子的污染现状、常用的处理方法,类水滑石化合物的研究概况、结构组成、一般性能以及合成和表征方法,利用类水滑石化合物处理含重金属离子废水的优点和意义,以及本论文研究的内容及特点。
第二部分介绍了类水滑石化合物的合成机理,以分析纯氢氧化钠、碳酸钠、硝酸镁、硝酸铝为原料,采用共沉淀法合成了镁铝类水滑石化合物,同时用红外光谱分析、X-射线衍射分析、比表面积分析以及差热-热重分析对合成的样品进行了表征。
第三部分研究了焙烧后镁铝类水滑石化合物对废水中第一类重金属离子的吸附行为。配制含第一类重金属离子的模拟废水样,在一定的条件下做镁铝类水滑石化合物对模拟废水样中第一类重金属离子的静态吸附试验。在试验过程中,分别改变模拟废水样的初始浓度、pH值、吸附平衡时间、吸附温度等反应条件,探讨了影响镁铝类水滑石化合物对模拟废水样中第一类重金属离子吸附的主要因素,并对影响因素进行了分析评价。同时测定了吸附等温线,研究了吸附类型,探讨镁铝类水滑石化合物对模拟废水样中第一类重金属离子吸附的机理。
第四部分研究了在线合成类水滑石化合物处理含第一类重金属离子废水的相关内容。以含第一类重金属离子废水做为处理对象,研究了在废水处理过程中利用在线合成类水滑石化合物消除污染,实现废物资源化的可行性。由于重金属离子在废水中的存在形式有两种,试验过程中分两种情况,考察了去除六种第一类重金属离子各个体系的终点pH值、配料中Mg2+/Al3+摩尔比值、反应时间以及废水中第一类重金属离子初始浓度对处理效果的影响,并且通过正交试验考察了以上各个因素对处理效果的综合影响。最后,借助X-射线衍射分析和红外光谱分析等手段,对试验过程中产生的固体样品进行了表征分析,通过类水滑石化合物的合成过程分析,研究了废水中第一类重金属离子的去除机理。
With the development of galvanization, tannage, antisepsis and dye etc, metal waste was discharged into the nature environment more and more, especially heavy metal ions such as chromium, arsenic, nickel, hydrargyrum, cadmium and plumbum. People’s bodies and environment have been damaged badly by metal-bearing wastewater, so it has been the urgent assignment to wipe off heavy metal ions effectively. As one of the functional materials, hydrotalcite-like compounds’cationic on the laminates and anion in the interlayer have equilibrum situation, manifold metal cations and anions can be introduced in its structure. And the heavy metal ions can be removed by synthesizing hydrotalcite-like compounds online in the process of wastewater treatment, realizing the feasibility of utilization waste. So,it has important significance to process waste water containing heavy metal ions by synthesizing hydrotalcite-like compounds. In this paper, various of hydrotalcite-like compounds were synthesized and their adsorptive behavior to heavy metal ions was studied by synthesizing hydrotalcite-like compounds offline and online. The main contents of this paper were provided as follows:
In the first part, the pollution actuality, common disposal measure of heavy metal and research survey, structure compose, general capability, synthesize and token measure of hydrotalcite-like compounds were summarized. Subsequently, virtue and meaning of treating wastewater containing heavy metal ions using hydrotalcite-like compounds and the characteristics of this paper were also included.
And in the second part, the synthesize mechanism of hydrotalcite-like compounds was introduced. Mg/Al hydrotalcite-like compounds were synthesized using the materials of analysis pure NaOH, Na2CO3, Mg(NO3)2, Al(NO3)3. At the same time, the sample synthesized in the experiment was tokened by infrared spectrum, X-ray diffraction, specific surface area anlysise and differential thermal analysis- thermogravimetry.
In the third part, the adsorptive behavior of calcined Mg2+/A13+ hydrotalcite-like compounds to the first category heavy metal ions in the waste water was studied. The adsorptive experiments of Mg2+/A13+ hydrotalcite-like compounds to the first category heavy metals were done under certain conditions. In experimental process, the reaction conditions of simulated wastewater were changed like initial concentration, pH value, adsorptive time, adsorption temperature and so on. Then, the factors which impact Mg2+/A13+ hydrotalcite-like compounds that adsorbing the first category heavy metal ions in the simulated wastewater samples were studied, and the impact factors were also analyzed and evaluated. Simultaneously, we determined the adsorption isotherm, studied the adsorption type and investigated the mechanism of Mg2+/A13+ hydrotalcite-like compounds adsorbing the first category heavy metal ions in the simulated wastewater samples.
Treatment of wastewater containing heavy metal ions by synthesizing hydrotalcite-like compounds online was studied in the forth part. The wastewater containing heavy metal ions as processing object, the heavy metals ions were removed by synthesizing hydrotalcite-like compounds online in the process of wastewater treatment, realizing the feasibility of utilization waste. Due to the two existing forms of heavy metal ions in wastewater, our experiment was individed into two cases. The pH values、Mg2+/A13+ ratios、reaction time and initial concentration of metal ions in wastewater were investigated, and comprehensive influence of each factor for treatment efficiency was studued by orthogonal experiment. Finally, the samples produced in the experiment process were anlysised by infrared spectrum and X-ray diffraction. The removal mechanism of heavy metal ions was studied through analysising the synthesizing process of HTLcs.
第一部分概述了重金属离子的污染现状、常用的处理方法,类水滑石化合物的研究概况、结构组成、一般性能以及合成和表征方法,利用类水滑石化合物处理含重金属离子废水的优点和意义,以及本论文研究的内容及特点。
第二部分介绍了类水滑石化合物的合成机理,以分析纯氢氧化钠、碳酸钠、硝酸镁、硝酸铝为原料,采用共沉淀法合成了镁铝类水滑石化合物,同时用红外光谱分析、X-射线衍射分析、比表面积分析以及差热-热重分析对合成的样品进行了表征。
第三部分研究了焙烧后镁铝类水滑石化合物对废水中第一类重金属离子的吸附行为。配制含第一类重金属离子的模拟废水样,在一定的条件下做镁铝类水滑石化合物对模拟废水样中第一类重金属离子的静态吸附试验。在试验过程中,分别改变模拟废水样的初始浓度、pH值、吸附平衡时间、吸附温度等反应条件,探讨了影响镁铝类水滑石化合物对模拟废水样中第一类重金属离子吸附的主要因素,并对影响因素进行了分析评价。同时测定了吸附等温线,研究了吸附类型,探讨镁铝类水滑石化合物对模拟废水样中第一类重金属离子吸附的机理。
第四部分研究了在线合成类水滑石化合物处理含第一类重金属离子废水的相关内容。以含第一类重金属离子废水做为处理对象,研究了在废水处理过程中利用在线合成类水滑石化合物消除污染,实现废物资源化的可行性。由于重金属离子在废水中的存在形式有两种,试验过程中分两种情况,考察了去除六种第一类重金属离子各个体系的终点pH值、配料中Mg2+/Al3+摩尔比值、反应时间以及废水中第一类重金属离子初始浓度对处理效果的影响,并且通过正交试验考察了以上各个因素对处理效果的综合影响。最后,借助X-射线衍射分析和红外光谱分析等手段,对试验过程中产生的固体样品进行了表征分析,通过类水滑石化合物的合成过程分析,研究了废水中第一类重金属离子的去除机理。
With the development of galvanization, tannage, antisepsis and dye etc, metal waste was discharged into the nature environment more and more, especially heavy metal ions such as chromium, arsenic, nickel, hydrargyrum, cadmium and plumbum. People’s bodies and environment have been damaged badly by metal-bearing wastewater, so it has been the urgent assignment to wipe off heavy metal ions effectively. As one of the functional materials, hydrotalcite-like compounds’cationic on the laminates and anion in the interlayer have equilibrum situation, manifold metal cations and anions can be introduced in its structure. And the heavy metal ions can be removed by synthesizing hydrotalcite-like compounds online in the process of wastewater treatment, realizing the feasibility of utilization waste. So,it has important significance to process waste water containing heavy metal ions by synthesizing hydrotalcite-like compounds. In this paper, various of hydrotalcite-like compounds were synthesized and their adsorptive behavior to heavy metal ions was studied by synthesizing hydrotalcite-like compounds offline and online. The main contents of this paper were provided as follows:
In the first part, the pollution actuality, common disposal measure of heavy metal and research survey, structure compose, general capability, synthesize and token measure of hydrotalcite-like compounds were summarized. Subsequently, virtue and meaning of treating wastewater containing heavy metal ions using hydrotalcite-like compounds and the characteristics of this paper were also included.
And in the second part, the synthesize mechanism of hydrotalcite-like compounds was introduced. Mg/Al hydrotalcite-like compounds were synthesized using the materials of analysis pure NaOH, Na2CO3, Mg(NO3)2, Al(NO3)3. At the same time, the sample synthesized in the experiment was tokened by infrared spectrum, X-ray diffraction, specific surface area anlysise and differential thermal analysis- thermogravimetry.
In the third part, the adsorptive behavior of calcined Mg2+/A13+ hydrotalcite-like compounds to the first category heavy metal ions in the waste water was studied. The adsorptive experiments of Mg2+/A13+ hydrotalcite-like compounds to the first category heavy metals were done under certain conditions. In experimental process, the reaction conditions of simulated wastewater were changed like initial concentration, pH value, adsorptive time, adsorption temperature and so on. Then, the factors which impact Mg2+/A13+ hydrotalcite-like compounds that adsorbing the first category heavy metal ions in the simulated wastewater samples were studied, and the impact factors were also analyzed and evaluated. Simultaneously, we determined the adsorption isotherm, studied the adsorption type and investigated the mechanism of Mg2+/A13+ hydrotalcite-like compounds adsorbing the first category heavy metal ions in the simulated wastewater samples.
Treatment of wastewater containing heavy metal ions by synthesizing hydrotalcite-like compounds online was studied in the forth part. The wastewater containing heavy metal ions as processing object, the heavy metals ions were removed by synthesizing hydrotalcite-like compounds online in the process of wastewater treatment, realizing the feasibility of utilization waste. Due to the two existing forms of heavy metal ions in wastewater, our experiment was individed into two cases. The pH values、Mg2+/A13+ ratios、reaction time and initial concentration of metal ions in wastewater were investigated, and comprehensive influence of each factor for treatment efficiency was studued by orthogonal experiment. Finally, the samples produced in the experiment process were anlysised by infrared spectrum and X-ray diffraction. The removal mechanism of heavy metal ions was studied through analysising the synthesizing process of HTLcs.
引文
[1]沈杰,张朝晖,周晓云,等.生物法去除水中重金属离子的研究[J].水处理技术, 2005, 31(3): 5-8.
[2] Zhang L X, Yu C C, Zhao W R, et al. Preparation of multi-amine-grafted mesoporous silicas and their application to heavy metal ions adsorption[J]. Journal of Non-Crystalline Solids, 2007, 353(44): 4055-4061.
[3] Bruzzoniti M C, Prelle A, Sarzanini C, et al. Retention of heavy metal ions on SBA-15 mesoporous silica functionalised with carboxylic groups[J]. Journal of separation science, 2007, 30(15): 2414-2420.
[4] Liu, P, Wang, T M. Adsorption properties of hyperbranched aliphatic polyester grafted attapulgite towards heavy metal ions[J]. Journal of hazardous materials, 2007, 149(1): 75-79.
[5] Kocaoba S, Orhan Y, Akyuz T. Kinetics and equilibrium studies of heavy metal ions removalby use of natural zeolite[J]. Desalination, 2007, 214(1): 1-10.
[6]马云,刘存海.高浓度含铬污水中铬的回收及其应用[J].表面技术, 2004, 33(3): 56-58.
[7]任志宏.重金属废水中含镍废水的处理[J].太原科技, 2007, 2: 72-74.
[8]喻劲松,周国华,马生明,等.武汉主要湖泊重金属污染的特点研究[J].物探化探计算技术, 2007, 29(增刊): 243-248.
[9]龙於洋,胡立芳,沈东升,等.城市生活垃圾中重金属污染研究进展[J].科技通报, 2007, 23(5): 760-764.
[10]何光俊,李俊飞,谷丽萍.河流底泥的重金属污染现状及治理进展[J].水利渔业, 2007, 27(5): 60-62.
[11]侯晓龙,马祥庆.垃圾焚烧灰治理垃圾渗滤液重金属污染的试验研究[J].亚热带资源与环境学报, 2007, 2(2): 30-36.
[12]易秀.西安市污灌区土壤中重金属潜在生态危害评价[J].干旱区资源与环境, 2007, 21(3): 118-120.
[13] Lynes M A, Kang, Y J, Sensi S L, et al. Heavy metal ions in normal physiology, toxic stress, and cytoprotection[J]. Annals of the New York Academy of Sciences, 2007, 11(13): 159-172.
[14] Sato S, Yoshihara K, Moriyama K, et al. Influence of activated carbon surface acidity on adsorptionof heavy metal ions and aromatics from aqueous solution[J]. Applied Surface Science, 2007, 253(20): 8554-8559.
[15] Wang S P, Forzani E S, Tao N J. Detection of heavy metal ions in water by high-resolution surface plasmon resonance spectroscopy combined with anodic stripping voltammetry[J]. Analytical chemistry, 2007, 79(12: 4427-4432.
[16] Chen C Y, Chiang C L, Chen C R. Removal of heavy metal ions by a chelating resin containing glycine as chelating groups[J]. Separation and Purification Technology, 2007, 54(3): 396-403.
[17]李洪利,高晓田.水体常见几种重金属污染物及对水生物的危害[J].河北渔业, 2007, 3: 1-4.
[18]吕新元,梁统玲.镉污染及其防治[J].上海环境科学, 1997, 7: 45.
[19]唐宁,柴立元,阂小波.含汞废水处理技术的研究进展[J].工业水处理, 2004, 24(8): 5-8,13.
[20]张英,周长民.重金属铅污染对人体的危害[J].辽宁化工, 2007, 36(6): 395-397.
[21]邹玉华.张家港市铬作业危害现状调查[J].中国工业医学杂志, 2007, 20(4): 262.
[22]常学秀,文传浩,王焕校.重金属污染与人体健康[J].云南环境科学, 2000, 19(1): 59-61.
[23]蒋清民.工业废水处理技术进展[J].河南化工, 2003, 1: 8-10.
[24]张建梅.重金属废水处理技术研究进展[J].西安联合大学学报, 2003, 6(2): 55-59.
[25]邱廷省,成先雄,郝志伟,等.含镉废水处理技术现状及发展[J].四川有色金属, 2002, 4: 38-41.
[26]阳争荣,王洪涛.含汞废水处理研究进展[J].广东水利水电, 2004,增刊: 55-57.
[27]李红,赵雪丽,任乃林.吸附法处理含铅废水的研究[J].韩山师范学院学报, 2001, 2: 70-73.
[28]纪柱.铬渣的危害及无害化处理综述[J].无机盐工业, 2003, 35(3): 1-4.
[29]高永灿,潘惠芳.催化裂化催化剂抗重金属镍污染技术的进展[J].石油化工, 1998, 27(4): 299-303.
[30]邹图德.浅谈含砷废水的危害和治理[J].新余高专学报, 2000, 5(2): 43-44.
[31] Cheng S. Heavy metal pollution in China: origin, pattern and control[J]. Environ Sci Pollut Res Int. 2003, 10(3): 192-198.
[32] Marinos A S, Demetra K, Katherine J H. Effect of acid treatment on the removal of heavy metals from sewage sludge[J]. Desalination, 2007, 215(2): 73-81.
[33] Sprynskyya M, Kosobuckia P, Kowalkowskia T. Influence of clinoptilolite rock on chemical speciation of selected heavy metals in sewage sludge[J]. Journal of Hazardous Materials, 2007, 149(4): 310-316.
[34]梅光泉.重金属废水的危害及治理[J].微量元素与健康研究, 2004, 21(4): 54-56.
[35] Wang W, Qiao X, Chen J ,et al. Facile synthesis of magnesium oxide nanoplates via chemical precipitation[J]. Materials Letters, 2007, 61(14): 3218-3220.
[36]石长恩.弱碱性阴离子交换树脂去除饮用水中微量重金属离子及再生试验研究[D].重庆大学, 2002, 7-8.
[37]高永,董亚玲,顾平.化学沉淀-微滤处理含铅废水[J].膜科学与技术, 2005, 25(5): 40-44.
[38]陈阳,钟国清,张永强,等.电镀镉废水处理的工艺研究[J].电镀与精饰, 2004, 26(5): 36-38.
[39]白猛,刘万宇,郑雅杰,等.冶炼厂含砷废水的硫化沉淀与碱浸[J].铜业工程, 2007, 2: 19-22.
[40]陈明,黄万抚,倪文.含铜酸性废水硫化沉淀高浓度调浆的试验研究[J].金属矿山, 2006, 9: 81-83.
[41]周继森,易求实.铁盐共沉淀法高效简便去除生活饮用水中的铬[J].湖北教育学院学报, 2001, 18(2): 44-48.
[42]金焰,李敦顺,曹阳.铁氧体沉淀法处理模拟含铅废水[J].化学与生物工程, 2006, 23(7): 45-47.
[43]董红星,孙兆申,裴建,等.铁盐共沉淀泡沫分离法去除水中铬离子[J].化工学报, 2006, 57(9): 2116-2122.
[44]钟琼,高栗,杨婵,等.用离子交换膜—电解法处理电解金属锰生产废水的研究[J].中国锰业, 2007, 25(1): 27-29.
[45]陈英杰,丁希楼,唐胜卫,等.铁炭内电解处理含铬废水的工艺改进[J].工业用水与废水, 2006, 37(6): 48-51.
[46]赵丽,王成端,赵诚,等.电解还原法处理含铬废水[J].科技导报, 2006, 24(11): 58-60.
[47]张梅玲,蔚东升,陶阳宇,等.离子膜电解技术在废水处理中的应用研究进展[J].工业水处理, 2006, 26(8): 5-8.
[48]王昕彤,孙余凭.一种新型NF膜在含镍废水回用中的应用[J].电镀与环保, 2007, 27(1): 38-41.
[49]卿春霞,宗刚,张建民,等.应用厚体液膜法处理含镍废水[J].过滤与分离, 2006, 16(4): 14-16.
[50]唐玉霖,王三反.膜电解法在处理酸性含镍废水中的研究[J].工业用水与废水, 2004, 35(3): 38-41.
[51]欧阳深耕,王晓光,杨永江,等.用无机膜处理含镍废水[J].电镀与环保, 2002, 22(3): 35-36.
[52]于丽青,孙建民.壳聚糖超滤膜的制备及在低含量重金属废水处理中的应用[J].化学世界, 2005, 1: 24-25, 62.
[53]江伟武,雷恒毅,张小红.沸石分子筛处理含汞废水研究[J].广东工业大学学报, 2000, 17(3): 97-100.
[54]张宇,赵剑英.凹凸棒土处理含镍废水的研究[J].江苏化工, 1997, 25(1): 48-49.
[55]高效江,戎秋涛.麦饭石对金属的吸附作用研究[J].环境污染与防治, 1997, 19(4): 4-8.
[56]杨智宽.用蛇纹石处理含钢废水的研究[J].环境科学技术, 1997, 10(2): 15-17.
[57]周勤俭,李先柏,杨静,等.大洋多金属结核吸附重金属离子的研究[J].湿法冶金, 1999, 69(1): 51-53.
[58]邵振华,周明华,雷乐成.旋流澄清/涂膜硅藻土过滤处理电镀废水[J].中国给水排水, 2005, 21(5): 14-17.
[59]王代芝,姬艳萍.酸改性膨润土处理含铅废水的研究[J].中国非金属矿工业导刊, 2005, 2: 44-46.
[60]胡恭任,于瑞莲.酸改性膨润土处理含铅废水[J].中国矿业, 2007, 16(2): 100-102.
[61]孙庆业,杨林章.改性泥炭对水溶液中铬的去除[J].城市环境与城市生态, 2002, 15(3): 5-8.
[62]王代芝,赵艳萍,周珊.改性膨润土处理含汞废水研究[J].非金属矿, 2004, 27(3): 43-44.
[63]周勤,苏彩燕,袁笑一,等.重金属捕集剂WY5处理综合铜、镍废水的研究[J].工业水处理, 2006, 26(4): 31-33.
[64]王雅静,戴惠新.生物吸附法在去除废水中重金属离子的应用研究[J].云南冶金, 2004, 33(6): 6-9.
[65] Zhang Z B, Zhao J F, Xia S Q, et al. Particle size distribution and removal by a chemical-biological flocculation process[J]. Journal of Environmental Sciences, 2007, 19(5): 559-563.
[66] Xia S Q, Yang D H, Xu B, et al. Chemical and biological flocculation process to treat municipal sewage and analysis of biological function[J]. J Environ Sci (China), 2005: 17(1): 163-167.
[67]辛宝平,庄源溢,李彤,等.生物絮凝剂的研究和应用[J].环境科学进展, 1998, 6(5): 57-62.
[68]张志斌,赵建夫,夏四清,等.化学生物絮凝工艺的反应机理初探[J].环境科学, 2007, 28(5): 993- 996.
[69]陶颖,王竟,周集体.新型生物吸附剂去除水中六价铬的研究[J].上海环境科学, 2000, 19(12): 572-574.
[70]陈林,邱廷省,陈明.生物吸附剂去除水中六价铬的试验研究[J].皮革科学与工程, 2003,13(4): 48-51.
[71] Cavani F., Trifiro F., Vaccan A., et al. Hydrotalcite-type anionic clays: preparation,properties and applications[J]. Catal. Today, 1991, 11: 173-181.
[72] Carlino S. Anionic clays. Anionic photocatalysts support in layered double hydroxides: Intercalation and photophysical properties of a ruthenium complex anion in synthetic hydrotalcite[J]. Education in chemistry, 1997, 7: 135-140.
[73] Zelinskii N D, Kommarevskii V. Catalytic action of nickelated A12O3 hydrates[J]. Chem Ber, 1942, 57(22): 667-669.
[74] Feitknecht W, Gerber W. Double hydroxides and basic double salts(Ⅲ) Mg-Al double hydroxides[J]. Helv Chim Acta Ibid, 1942, 25(21): 131-137.
[75] Feitknecht W. Formation of double hydroxides between bivalent and trivalent metals[J]. Helv Chim Acta, 1942, 25(1): 555-569.
[76] Allmannn R, Jepsen H P. Structure of hydrotalcite[J]. Neues Jahrb Mineral Monatsh, 1966, 45(12): 544-551.
[77] Taylor H F W. Segregation and cation-ordering in sjogrenite and pyroaurite[J]. Miner Mag, 1969, 37(287): 338-342.
[78] Miyata S, Kumura T, Hattori H, et al. Physicochemicalp roperties and structure of magnesia- alumina[J]. Nippon Kagaku Zasshi, 1971, 92(6): 514-519.
[79] Taylor H F W. Crystal structures of some double hydroxide minerals[J]. Miner Mag, 1973, 39(304): 377-389.
[80] Reichle W T. Catalytic reactions by thermally activated[J]. synthetic anionic clayminerals, 1985, 94(13): 547-557.
[81] Tichit D, Lhouty M H, Guida A. Textural prooerties and catalytic activity of hydrotalcites[J]. J Catal, 1995, 151(55): 50-59.
[82] Tu M, Shen J, Chen Y. Microcalorimetric studies of surface acid/base prooerties of Mg-Fe catalysts prepared from hydrotalcite-typep recursors[J]. Solid State Chem, 1997, 128(1): 73-79.
[83]刘玉敏,吴越.钴铜铝水滑石类化合物的合成及催化氧化[J].应用化学, 1998, 15(2): 11-15.
[84] Harasawa, Isamu, Ishisake, et al. Agricultural covering material[P]. USA: 7714630, 1998-5-21.
[85] Watanabe, Takayoshi, Aoki, et al. Anti-bacterial film suitable for food packaging[P]. USA: 5929133, 1999-7-27.
[86] J. Inacio, C. Taviot-Gueho, C. Forano, et al. Adsorption of MCPA pesticide by MgAl-layer double hydroxides[J]. Applied Clay Science, 2001, 18: 255-264.
[87] Yihang G, Danfeng L, Changwen H, et al. Preparation and Photocatalytic behavior of Zn/Al/W(Mn) mixed oxides via polyoxometalates intercalated layer double hydroxides[J]. Microporous And Mesoporous Materials,2002, 56: 153-162.
[88]彭书传,杨远盛,陈天虎,等.即时合成层状双氢氧化物去除阴离子染料刚果红[J].环境科学研究. 2005, 18(6): 72-74.
[89]姚铭,杜莉珍,王凯雄,等.合成水滑石治理水体阴离子染料污染研究[J].环境科学学报. 2005, 25(8): 1034-1040.
[90] Paulo C. P., Eduardo L.C., Joao B.V. Sorptions of anion surfactants on layer double hydroxides[J]. Journal of Colloid and Interface Science, 2000, 229: 346-352.
[91] Paulo C. P., Eduado L. C,Gilmar de A., et al. Adsorption of sodium dodecylsulfate on a hydrotalcite-like compound: Effect of temperature, pH and ionic strength[J]. Colloids And Surfaces, 1999,154: 399-410.
[92] Sandrine M., Christine M., Pierre P., et al. Concomitant intercalation and decomplexation of Forrecen sulfonate in layer double hydroxides[J]. Journal of Solid State Chemistry, 1999, 144: 143-151.
[93] Hang-Sik S, Mi-Joo K, Se-Yong N, et al. Phosphorus removal by hydrotalcite-like compounds(HTLcs)[J]. Wat. Sci.Tech., 1996, 34: 161-168.
[94]郑丽波,叶瑛,季珊珊,等. Mg /Al型双金属氧化物对六价铬的吸附作用[J].地球化学, 2004, 33(2): 208-214.
[95]郭志强,倪哲明,俞卫华,等.二元金属类水滑石的合成及其作为前驱体对NOx的吸附性能研究[J].材料科学与工程学报, 2004, 22(6): 878-880.
[96]郭军,孙铁,沈剑平,等.硅钨系列三元杂多阴离子柱撑水滑石的合成、表征及其酸碱催化性能[J].高等学校化学学报, 1995, 16: 346-349.
[97]周燕婷,李峰,杜以波,等.镁铝复合金属氧化物结构、催化性能及其在一步法制备醇醚醋酸酯中的应用[J].北京化工大学学报, 2000, 27(1): 70-73.
[98]刘建才,廉世勋,朱爱玲,等.铕掺杂类水滑石的发光性质及其选择性红外吸收[J].发光学报, 2007, 28(1): 67-73.
[99]刘鹏,郑建华,皮振邦,等.镁铝铟类水滑石的合成与表征[J].中国地质大学学报, 2003,28(2): 163-166.
[100]刘炳华. Co-Cu-Mg-Al四元类水滑石的合成与表征[J].淮阴师范学院学报(自然科学版), 2006, 5(3): 216-218, 232.
[101]郭雄华,侯万国,王书瑞,等. Mg-Zn-Al-Fe型类水滑石纳米颗粒的制备及表征[J].山东大学学报(理学版), 2003, 38(1): 89-92.
[102]谢鲜梅,安霞,李晋平,等. Zn-Al-Ce三元类水滑石的制备及性质研究[J].量子催化, 2004, 18(1): 36-40.
[103]金莲,王志国.掺杂Cu2+离子的类水滑石[CdxMg6-xAl2(OH)16]2+[S·2H2O]2-中Cu2+离子的含量及其順磁光谱研究[J].内蒙古民族师院学报(自然科学版), 2000, 15(2): 174-175, 196.
[104] Inaoio J, Taviot G C, Forano C, et al. Adsorption of MC-PA pesticide by Mg-Al layered double hydroxides[J]. Applied Clay Science, 2001, 18(5-6): 255-264.
[105]姚铭,申震,杜莉珍,等.水滑石类材料在水污染治理中的应用研究[J].环境科学动态, 2004, (4): 26-28.
[106]樊明德,陈天虎,刘景丽,等.即时合成Zn/Mg/Al层状双氢氧化物处理含Zn2+废水试验研究[J].矿物学报, 2006, 26(3): 261-266.
[107]陈天虎,冯有亮,徐汇芳,等.层状双氢氧化物即时合成处理含Cr(Ⅵ)废水[J].环境科学, 2004, 25(2): 89-93.
[108] Hermosin M C, Pavloic I, Ulibarri M A, et al. Hydrotalcite as sorbent for trinitrophenol: sorption capacity and mechanism[J]. Water Research, 1996, 30: 171-177.
[109] You Y W, Zhao H T, Vance G F. Surfactant-enhanced adsorption of organic compounds by layered double hydroxides[J]. Colloid Surface A, 2002, 205 (3): 161-172.
[110] Ulibarri M A, Pavlovic I, Barriga C. et al. Adsorption of anionic species on hydrotalcite- like compounds: effect of interlayer crystallinity[J]. Applied Clay Science, 1999, 18(1-2): 17-27.
[111]刘炳华,张惠良,沈俭一.以水滑石及类水滑石为前体的Mg/Al、Co/Mg/Al混合氧化物的合成表征和异丙醇催化性能[J].无机化学学报, 2005, 21(1): 43-50.
[112]杨锡尧,任韶玲.镁铝复合氧化物的制备及其物理化学性质[J].分子催化, 1996, 10(2): 88-94.
[113]郭军,孙铁,沈剑平,等. Keggin结构磷钨钒杂多阴离子柱撑水滑石的合成、表征与热稳定性研究[J].无机化学学报, 1995, 11(2): 136-139.
[114]李连生,包玉敏.稀土水滑石催化合成邻苯二甲酸二戊酯的研究[J].高等化学学报, 1995,16(8): 1164-1167.
[115] Dan S, Serce C, Christine M. Layered double hydroxides: an attractive material for electrochemical biosensor design[J]. Analytical chemistry, 2003, 75(15): 3872-3879.
[116] Ei M M, Jerome I, Besse J P. Adsorption of styrene sulfonate vs. polystyrene sulfonate on layered double hydroxides[J]. Microporous and Mesoporous Materials, 2003, 57: 37-46.
[117]张波,郑遗凡,卢晗锋,等. Mg/Zn/Al类水滑石的热性质和水化性能研究[J].浙江工业大学学报, 2006, 34(1): 37-42.
[118] Wen B, He M Y, Song J Q, et al. Study on the thermal decomposition of a copper-containing hydrotalcite-like catalytic material[J]. Chinese Journal of Inorganic Chemistry, 2000, 16(1): 58-62.
[119]李蕾,张春英,矫庆泽,等. Mg-Al-CO3与Zn-Al-CO3水滑石热稳定性差异的研究[J].无机化学学报, 2001, 17(1): 113-118.
[120] Hibino T, Tsunashima A. Characterization of repeatedly reconstructed Mg-Al hydrotalcite-like compounds: gradual segregation of aluminum from the structure[J]. Chemistry of Materials, 1998, 10: 4055-4061.
[121] Odair P ,Oswaldo L A, Daniel X G, et al. Thermal decomposition and structural reconstruction effects on Mg-Fe based hydrotalcite compounds[J]. Journal of Solid State Chemistry, 2004, 8: 3058-3069.
[122]赵强,权变利,白华,等.水滑石类化合物重构性能的研究[J].科技情报开发与经济, 2007, 17(1): 176-178.
[123]许国志,郭灿雄,段雪,等. PE膜中层状双轻基复合氢氧化物的红外吸收性能[J].应用化学, 1999, 16(3): 45-48.
[124] Bora M, Mufit A. Three-component layer double hydroxides by urea precipitation: structure stability and electrochemistry[J]. Journal of Power Sources, 2004, 134: 308-317.
[125]王仲鹏,苏继新,蒋政,等. Cu/Mg/Al/Fe/NO3型纳米层状复合氢氧化物的制备与表征[J].中国稀土学报, 2003, 21(2): 108-110.
[126]谢晖,矫庆泽,段雪,等.镁铝型水滑石水热合成[J].应用化学, 2001, 18(1): 70-72.
[127] Drezdzon M A. Synthesis of isopolymetalate-pillared hydrotalcites via organic-anion-pillared precursors[J]. Inorg Chem, 1988, 27(3): 4628-4632.
[128] Chibwe K, Jones W. Intercalation of organic and inorganic anions into layered double hydroxides[J].Chem Soc Chem Commu, 1989, 23(21): 926-927.
[129] Tetsuya S, Shinsuke Y, Katsuhiko,T. Photopolymerization of 4-vinylbenzoate and m-and p-phenylendiacrylates in hydrotalcite interlayers[J]. Superramolcular Science, 1998, 5(3-4): 303-308.
[130] Kanezaki E. Unexchange able inter layer anions: synthesis and characterization of Zn/Al-and Mg/Al-layered double hydroxideswith interlayer Alizarin red S[J].Ind Phenom Macro, 2003, 46(1-2): 89-95.
[131] Christoph H. Description of sorption data with isotherm equations[J]. Geoderma, 2001, 99(3-4): 225-243.
[132]李学垣.土壤化学[M].北京:高等教育出版社, 2001.
[2] Zhang L X, Yu C C, Zhao W R, et al. Preparation of multi-amine-grafted mesoporous silicas and their application to heavy metal ions adsorption[J]. Journal of Non-Crystalline Solids, 2007, 353(44): 4055-4061.
[3] Bruzzoniti M C, Prelle A, Sarzanini C, et al. Retention of heavy metal ions on SBA-15 mesoporous silica functionalised with carboxylic groups[J]. Journal of separation science, 2007, 30(15): 2414-2420.
[4] Liu, P, Wang, T M. Adsorption properties of hyperbranched aliphatic polyester grafted attapulgite towards heavy metal ions[J]. Journal of hazardous materials, 2007, 149(1): 75-79.
[5] Kocaoba S, Orhan Y, Akyuz T. Kinetics and equilibrium studies of heavy metal ions removalby use of natural zeolite[J]. Desalination, 2007, 214(1): 1-10.
[6]马云,刘存海.高浓度含铬污水中铬的回收及其应用[J].表面技术, 2004, 33(3): 56-58.
[7]任志宏.重金属废水中含镍废水的处理[J].太原科技, 2007, 2: 72-74.
[8]喻劲松,周国华,马生明,等.武汉主要湖泊重金属污染的特点研究[J].物探化探计算技术, 2007, 29(增刊): 243-248.
[9]龙於洋,胡立芳,沈东升,等.城市生活垃圾中重金属污染研究进展[J].科技通报, 2007, 23(5): 760-764.
[10]何光俊,李俊飞,谷丽萍.河流底泥的重金属污染现状及治理进展[J].水利渔业, 2007, 27(5): 60-62.
[11]侯晓龙,马祥庆.垃圾焚烧灰治理垃圾渗滤液重金属污染的试验研究[J].亚热带资源与环境学报, 2007, 2(2): 30-36.
[12]易秀.西安市污灌区土壤中重金属潜在生态危害评价[J].干旱区资源与环境, 2007, 21(3): 118-120.
[13] Lynes M A, Kang, Y J, Sensi S L, et al. Heavy metal ions in normal physiology, toxic stress, and cytoprotection[J]. Annals of the New York Academy of Sciences, 2007, 11(13): 159-172.
[14] Sato S, Yoshihara K, Moriyama K, et al. Influence of activated carbon surface acidity on adsorptionof heavy metal ions and aromatics from aqueous solution[J]. Applied Surface Science, 2007, 253(20): 8554-8559.
[15] Wang S P, Forzani E S, Tao N J. Detection of heavy metal ions in water by high-resolution surface plasmon resonance spectroscopy combined with anodic stripping voltammetry[J]. Analytical chemistry, 2007, 79(12: 4427-4432.
[16] Chen C Y, Chiang C L, Chen C R. Removal of heavy metal ions by a chelating resin containing glycine as chelating groups[J]. Separation and Purification Technology, 2007, 54(3): 396-403.
[17]李洪利,高晓田.水体常见几种重金属污染物及对水生物的危害[J].河北渔业, 2007, 3: 1-4.
[18]吕新元,梁统玲.镉污染及其防治[J].上海环境科学, 1997, 7: 45.
[19]唐宁,柴立元,阂小波.含汞废水处理技术的研究进展[J].工业水处理, 2004, 24(8): 5-8,13.
[20]张英,周长民.重金属铅污染对人体的危害[J].辽宁化工, 2007, 36(6): 395-397.
[21]邹玉华.张家港市铬作业危害现状调查[J].中国工业医学杂志, 2007, 20(4): 262.
[22]常学秀,文传浩,王焕校.重金属污染与人体健康[J].云南环境科学, 2000, 19(1): 59-61.
[23]蒋清民.工业废水处理技术进展[J].河南化工, 2003, 1: 8-10.
[24]张建梅.重金属废水处理技术研究进展[J].西安联合大学学报, 2003, 6(2): 55-59.
[25]邱廷省,成先雄,郝志伟,等.含镉废水处理技术现状及发展[J].四川有色金属, 2002, 4: 38-41.
[26]阳争荣,王洪涛.含汞废水处理研究进展[J].广东水利水电, 2004,增刊: 55-57.
[27]李红,赵雪丽,任乃林.吸附法处理含铅废水的研究[J].韩山师范学院学报, 2001, 2: 70-73.
[28]纪柱.铬渣的危害及无害化处理综述[J].无机盐工业, 2003, 35(3): 1-4.
[29]高永灿,潘惠芳.催化裂化催化剂抗重金属镍污染技术的进展[J].石油化工, 1998, 27(4): 299-303.
[30]邹图德.浅谈含砷废水的危害和治理[J].新余高专学报, 2000, 5(2): 43-44.
[31] Cheng S. Heavy metal pollution in China: origin, pattern and control[J]. Environ Sci Pollut Res Int. 2003, 10(3): 192-198.
[32] Marinos A S, Demetra K, Katherine J H. Effect of acid treatment on the removal of heavy metals from sewage sludge[J]. Desalination, 2007, 215(2): 73-81.
[33] Sprynskyya M, Kosobuckia P, Kowalkowskia T. Influence of clinoptilolite rock on chemical speciation of selected heavy metals in sewage sludge[J]. Journal of Hazardous Materials, 2007, 149(4): 310-316.
[34]梅光泉.重金属废水的危害及治理[J].微量元素与健康研究, 2004, 21(4): 54-56.
[35] Wang W, Qiao X, Chen J ,et al. Facile synthesis of magnesium oxide nanoplates via chemical precipitation[J]. Materials Letters, 2007, 61(14): 3218-3220.
[36]石长恩.弱碱性阴离子交换树脂去除饮用水中微量重金属离子及再生试验研究[D].重庆大学, 2002, 7-8.
[37]高永,董亚玲,顾平.化学沉淀-微滤处理含铅废水[J].膜科学与技术, 2005, 25(5): 40-44.
[38]陈阳,钟国清,张永强,等.电镀镉废水处理的工艺研究[J].电镀与精饰, 2004, 26(5): 36-38.
[39]白猛,刘万宇,郑雅杰,等.冶炼厂含砷废水的硫化沉淀与碱浸[J].铜业工程, 2007, 2: 19-22.
[40]陈明,黄万抚,倪文.含铜酸性废水硫化沉淀高浓度调浆的试验研究[J].金属矿山, 2006, 9: 81-83.
[41]周继森,易求实.铁盐共沉淀法高效简便去除生活饮用水中的铬[J].湖北教育学院学报, 2001, 18(2): 44-48.
[42]金焰,李敦顺,曹阳.铁氧体沉淀法处理模拟含铅废水[J].化学与生物工程, 2006, 23(7): 45-47.
[43]董红星,孙兆申,裴建,等.铁盐共沉淀泡沫分离法去除水中铬离子[J].化工学报, 2006, 57(9): 2116-2122.
[44]钟琼,高栗,杨婵,等.用离子交换膜—电解法处理电解金属锰生产废水的研究[J].中国锰业, 2007, 25(1): 27-29.
[45]陈英杰,丁希楼,唐胜卫,等.铁炭内电解处理含铬废水的工艺改进[J].工业用水与废水, 2006, 37(6): 48-51.
[46]赵丽,王成端,赵诚,等.电解还原法处理含铬废水[J].科技导报, 2006, 24(11): 58-60.
[47]张梅玲,蔚东升,陶阳宇,等.离子膜电解技术在废水处理中的应用研究进展[J].工业水处理, 2006, 26(8): 5-8.
[48]王昕彤,孙余凭.一种新型NF膜在含镍废水回用中的应用[J].电镀与环保, 2007, 27(1): 38-41.
[49]卿春霞,宗刚,张建民,等.应用厚体液膜法处理含镍废水[J].过滤与分离, 2006, 16(4): 14-16.
[50]唐玉霖,王三反.膜电解法在处理酸性含镍废水中的研究[J].工业用水与废水, 2004, 35(3): 38-41.
[51]欧阳深耕,王晓光,杨永江,等.用无机膜处理含镍废水[J].电镀与环保, 2002, 22(3): 35-36.
[52]于丽青,孙建民.壳聚糖超滤膜的制备及在低含量重金属废水处理中的应用[J].化学世界, 2005, 1: 24-25, 62.
[53]江伟武,雷恒毅,张小红.沸石分子筛处理含汞废水研究[J].广东工业大学学报, 2000, 17(3): 97-100.
[54]张宇,赵剑英.凹凸棒土处理含镍废水的研究[J].江苏化工, 1997, 25(1): 48-49.
[55]高效江,戎秋涛.麦饭石对金属的吸附作用研究[J].环境污染与防治, 1997, 19(4): 4-8.
[56]杨智宽.用蛇纹石处理含钢废水的研究[J].环境科学技术, 1997, 10(2): 15-17.
[57]周勤俭,李先柏,杨静,等.大洋多金属结核吸附重金属离子的研究[J].湿法冶金, 1999, 69(1): 51-53.
[58]邵振华,周明华,雷乐成.旋流澄清/涂膜硅藻土过滤处理电镀废水[J].中国给水排水, 2005, 21(5): 14-17.
[59]王代芝,姬艳萍.酸改性膨润土处理含铅废水的研究[J].中国非金属矿工业导刊, 2005, 2: 44-46.
[60]胡恭任,于瑞莲.酸改性膨润土处理含铅废水[J].中国矿业, 2007, 16(2): 100-102.
[61]孙庆业,杨林章.改性泥炭对水溶液中铬的去除[J].城市环境与城市生态, 2002, 15(3): 5-8.
[62]王代芝,赵艳萍,周珊.改性膨润土处理含汞废水研究[J].非金属矿, 2004, 27(3): 43-44.
[63]周勤,苏彩燕,袁笑一,等.重金属捕集剂WY5处理综合铜、镍废水的研究[J].工业水处理, 2006, 26(4): 31-33.
[64]王雅静,戴惠新.生物吸附法在去除废水中重金属离子的应用研究[J].云南冶金, 2004, 33(6): 6-9.
[65] Zhang Z B, Zhao J F, Xia S Q, et al. Particle size distribution and removal by a chemical-biological flocculation process[J]. Journal of Environmental Sciences, 2007, 19(5): 559-563.
[66] Xia S Q, Yang D H, Xu B, et al. Chemical and biological flocculation process to treat municipal sewage and analysis of biological function[J]. J Environ Sci (China), 2005: 17(1): 163-167.
[67]辛宝平,庄源溢,李彤,等.生物絮凝剂的研究和应用[J].环境科学进展, 1998, 6(5): 57-62.
[68]张志斌,赵建夫,夏四清,等.化学生物絮凝工艺的反应机理初探[J].环境科学, 2007, 28(5): 993- 996.
[69]陶颖,王竟,周集体.新型生物吸附剂去除水中六价铬的研究[J].上海环境科学, 2000, 19(12): 572-574.
[70]陈林,邱廷省,陈明.生物吸附剂去除水中六价铬的试验研究[J].皮革科学与工程, 2003,13(4): 48-51.
[71] Cavani F., Trifiro F., Vaccan A., et al. Hydrotalcite-type anionic clays: preparation,properties and applications[J]. Catal. Today, 1991, 11: 173-181.
[72] Carlino S. Anionic clays. Anionic photocatalysts support in layered double hydroxides: Intercalation and photophysical properties of a ruthenium complex anion in synthetic hydrotalcite[J]. Education in chemistry, 1997, 7: 135-140.
[73] Zelinskii N D, Kommarevskii V. Catalytic action of nickelated A12O3 hydrates[J]. Chem Ber, 1942, 57(22): 667-669.
[74] Feitknecht W, Gerber W. Double hydroxides and basic double salts(Ⅲ) Mg-Al double hydroxides[J]. Helv Chim Acta Ibid, 1942, 25(21): 131-137.
[75] Feitknecht W. Formation of double hydroxides between bivalent and trivalent metals[J]. Helv Chim Acta, 1942, 25(1): 555-569.
[76] Allmannn R, Jepsen H P. Structure of hydrotalcite[J]. Neues Jahrb Mineral Monatsh, 1966, 45(12): 544-551.
[77] Taylor H F W. Segregation and cation-ordering in sjogrenite and pyroaurite[J]. Miner Mag, 1969, 37(287): 338-342.
[78] Miyata S, Kumura T, Hattori H, et al. Physicochemicalp roperties and structure of magnesia- alumina[J]. Nippon Kagaku Zasshi, 1971, 92(6): 514-519.
[79] Taylor H F W. Crystal structures of some double hydroxide minerals[J]. Miner Mag, 1973, 39(304): 377-389.
[80] Reichle W T. Catalytic reactions by thermally activated[J]. synthetic anionic clayminerals, 1985, 94(13): 547-557.
[81] Tichit D, Lhouty M H, Guida A. Textural prooerties and catalytic activity of hydrotalcites[J]. J Catal, 1995, 151(55): 50-59.
[82] Tu M, Shen J, Chen Y. Microcalorimetric studies of surface acid/base prooerties of Mg-Fe catalysts prepared from hydrotalcite-typep recursors[J]. Solid State Chem, 1997, 128(1): 73-79.
[83]刘玉敏,吴越.钴铜铝水滑石类化合物的合成及催化氧化[J].应用化学, 1998, 15(2): 11-15.
[84] Harasawa, Isamu, Ishisake, et al. Agricultural covering material[P]. USA: 7714630, 1998-5-21.
[85] Watanabe, Takayoshi, Aoki, et al. Anti-bacterial film suitable for food packaging[P]. USA: 5929133, 1999-7-27.
[86] J. Inacio, C. Taviot-Gueho, C. Forano, et al. Adsorption of MCPA pesticide by MgAl-layer double hydroxides[J]. Applied Clay Science, 2001, 18: 255-264.
[87] Yihang G, Danfeng L, Changwen H, et al. Preparation and Photocatalytic behavior of Zn/Al/W(Mn) mixed oxides via polyoxometalates intercalated layer double hydroxides[J]. Microporous And Mesoporous Materials,2002, 56: 153-162.
[88]彭书传,杨远盛,陈天虎,等.即时合成层状双氢氧化物去除阴离子染料刚果红[J].环境科学研究. 2005, 18(6): 72-74.
[89]姚铭,杜莉珍,王凯雄,等.合成水滑石治理水体阴离子染料污染研究[J].环境科学学报. 2005, 25(8): 1034-1040.
[90] Paulo C. P., Eduardo L.C., Joao B.V. Sorptions of anion surfactants on layer double hydroxides[J]. Journal of Colloid and Interface Science, 2000, 229: 346-352.
[91] Paulo C. P., Eduado L. C,Gilmar de A., et al. Adsorption of sodium dodecylsulfate on a hydrotalcite-like compound: Effect of temperature, pH and ionic strength[J]. Colloids And Surfaces, 1999,154: 399-410.
[92] Sandrine M., Christine M., Pierre P., et al. Concomitant intercalation and decomplexation of Forrecen sulfonate in layer double hydroxides[J]. Journal of Solid State Chemistry, 1999, 144: 143-151.
[93] Hang-Sik S, Mi-Joo K, Se-Yong N, et al. Phosphorus removal by hydrotalcite-like compounds(HTLcs)[J]. Wat. Sci.Tech., 1996, 34: 161-168.
[94]郑丽波,叶瑛,季珊珊,等. Mg /Al型双金属氧化物对六价铬的吸附作用[J].地球化学, 2004, 33(2): 208-214.
[95]郭志强,倪哲明,俞卫华,等.二元金属类水滑石的合成及其作为前驱体对NOx的吸附性能研究[J].材料科学与工程学报, 2004, 22(6): 878-880.
[96]郭军,孙铁,沈剑平,等.硅钨系列三元杂多阴离子柱撑水滑石的合成、表征及其酸碱催化性能[J].高等学校化学学报, 1995, 16: 346-349.
[97]周燕婷,李峰,杜以波,等.镁铝复合金属氧化物结构、催化性能及其在一步法制备醇醚醋酸酯中的应用[J].北京化工大学学报, 2000, 27(1): 70-73.
[98]刘建才,廉世勋,朱爱玲,等.铕掺杂类水滑石的发光性质及其选择性红外吸收[J].发光学报, 2007, 28(1): 67-73.
[99]刘鹏,郑建华,皮振邦,等.镁铝铟类水滑石的合成与表征[J].中国地质大学学报, 2003,28(2): 163-166.
[100]刘炳华. Co-Cu-Mg-Al四元类水滑石的合成与表征[J].淮阴师范学院学报(自然科学版), 2006, 5(3): 216-218, 232.
[101]郭雄华,侯万国,王书瑞,等. Mg-Zn-Al-Fe型类水滑石纳米颗粒的制备及表征[J].山东大学学报(理学版), 2003, 38(1): 89-92.
[102]谢鲜梅,安霞,李晋平,等. Zn-Al-Ce三元类水滑石的制备及性质研究[J].量子催化, 2004, 18(1): 36-40.
[103]金莲,王志国.掺杂Cu2+离子的类水滑石[CdxMg6-xAl2(OH)16]2+[S·2H2O]2-中Cu2+离子的含量及其順磁光谱研究[J].内蒙古民族师院学报(自然科学版), 2000, 15(2): 174-175, 196.
[104] Inaoio J, Taviot G C, Forano C, et al. Adsorption of MC-PA pesticide by Mg-Al layered double hydroxides[J]. Applied Clay Science, 2001, 18(5-6): 255-264.
[105]姚铭,申震,杜莉珍,等.水滑石类材料在水污染治理中的应用研究[J].环境科学动态, 2004, (4): 26-28.
[106]樊明德,陈天虎,刘景丽,等.即时合成Zn/Mg/Al层状双氢氧化物处理含Zn2+废水试验研究[J].矿物学报, 2006, 26(3): 261-266.
[107]陈天虎,冯有亮,徐汇芳,等.层状双氢氧化物即时合成处理含Cr(Ⅵ)废水[J].环境科学, 2004, 25(2): 89-93.
[108] Hermosin M C, Pavloic I, Ulibarri M A, et al. Hydrotalcite as sorbent for trinitrophenol: sorption capacity and mechanism[J]. Water Research, 1996, 30: 171-177.
[109] You Y W, Zhao H T, Vance G F. Surfactant-enhanced adsorption of organic compounds by layered double hydroxides[J]. Colloid Surface A, 2002, 205 (3): 161-172.
[110] Ulibarri M A, Pavlovic I, Barriga C. et al. Adsorption of anionic species on hydrotalcite- like compounds: effect of interlayer crystallinity[J]. Applied Clay Science, 1999, 18(1-2): 17-27.
[111]刘炳华,张惠良,沈俭一.以水滑石及类水滑石为前体的Mg/Al、Co/Mg/Al混合氧化物的合成表征和异丙醇催化性能[J].无机化学学报, 2005, 21(1): 43-50.
[112]杨锡尧,任韶玲.镁铝复合氧化物的制备及其物理化学性质[J].分子催化, 1996, 10(2): 88-94.
[113]郭军,孙铁,沈剑平,等. Keggin结构磷钨钒杂多阴离子柱撑水滑石的合成、表征与热稳定性研究[J].无机化学学报, 1995, 11(2): 136-139.
[114]李连生,包玉敏.稀土水滑石催化合成邻苯二甲酸二戊酯的研究[J].高等化学学报, 1995,16(8): 1164-1167.
[115] Dan S, Serce C, Christine M. Layered double hydroxides: an attractive material for electrochemical biosensor design[J]. Analytical chemistry, 2003, 75(15): 3872-3879.
[116] Ei M M, Jerome I, Besse J P. Adsorption of styrene sulfonate vs. polystyrene sulfonate on layered double hydroxides[J]. Microporous and Mesoporous Materials, 2003, 57: 37-46.
[117]张波,郑遗凡,卢晗锋,等. Mg/Zn/Al类水滑石的热性质和水化性能研究[J].浙江工业大学学报, 2006, 34(1): 37-42.
[118] Wen B, He M Y, Song J Q, et al. Study on the thermal decomposition of a copper-containing hydrotalcite-like catalytic material[J]. Chinese Journal of Inorganic Chemistry, 2000, 16(1): 58-62.
[119]李蕾,张春英,矫庆泽,等. Mg-Al-CO3与Zn-Al-CO3水滑石热稳定性差异的研究[J].无机化学学报, 2001, 17(1): 113-118.
[120] Hibino T, Tsunashima A. Characterization of repeatedly reconstructed Mg-Al hydrotalcite-like compounds: gradual segregation of aluminum from the structure[J]. Chemistry of Materials, 1998, 10: 4055-4061.
[121] Odair P ,Oswaldo L A, Daniel X G, et al. Thermal decomposition and structural reconstruction effects on Mg-Fe based hydrotalcite compounds[J]. Journal of Solid State Chemistry, 2004, 8: 3058-3069.
[122]赵强,权变利,白华,等.水滑石类化合物重构性能的研究[J].科技情报开发与经济, 2007, 17(1): 176-178.
[123]许国志,郭灿雄,段雪,等. PE膜中层状双轻基复合氢氧化物的红外吸收性能[J].应用化学, 1999, 16(3): 45-48.
[124] Bora M, Mufit A. Three-component layer double hydroxides by urea precipitation: structure stability and electrochemistry[J]. Journal of Power Sources, 2004, 134: 308-317.
[125]王仲鹏,苏继新,蒋政,等. Cu/Mg/Al/Fe/NO3型纳米层状复合氢氧化物的制备与表征[J].中国稀土学报, 2003, 21(2): 108-110.
[126]谢晖,矫庆泽,段雪,等.镁铝型水滑石水热合成[J].应用化学, 2001, 18(1): 70-72.
[127] Drezdzon M A. Synthesis of isopolymetalate-pillared hydrotalcites via organic-anion-pillared precursors[J]. Inorg Chem, 1988, 27(3): 4628-4632.
[128] Chibwe K, Jones W. Intercalation of organic and inorganic anions into layered double hydroxides[J].Chem Soc Chem Commu, 1989, 23(21): 926-927.
[129] Tetsuya S, Shinsuke Y, Katsuhiko,T. Photopolymerization of 4-vinylbenzoate and m-and p-phenylendiacrylates in hydrotalcite interlayers[J]. Superramolcular Science, 1998, 5(3-4): 303-308.
[130] Kanezaki E. Unexchange able inter layer anions: synthesis and characterization of Zn/Al-and Mg/Al-layered double hydroxideswith interlayer Alizarin red S[J].Ind Phenom Macro, 2003, 46(1-2): 89-95.
[131] Christoph H. Description of sorption data with isotherm equations[J]. Geoderma, 2001, 99(3-4): 225-243.
[132]李学垣.土壤化学[M].北京:高等教育出版社, 2001.