甲苯液相氧化反应催化剂及其催化性能研究
|
摘要
甲苯是最简单的取代芳烃,其氧化反应是芳烃氧化反应中的典型例子。甲苯氧化产物苯甲醇、苯甲醛和苯甲酸均是有机合成工业中的重要中间体,广泛的应用于农药、香料、医药、染料等领域。目前,甲苯氧化常用的工艺是甲苯液相空气催化氧化法,该工艺具有环境友好、反应条件温和、安全性好等优点。本文采用无卤素和无溶剂的绿色工艺,以纯甲苯为原料,苯甲酸为引发剂,空气为氧化剂,在间歇搅拌式反应釜中,系统研究了Co(acac)2、Co/Mn、[ace-min]Co、CoSBA-15等催化剂对甲苯液相氧化反应的催化性能及其影响规律。
以Co(acac)2为催化剂,考察了反应时间、反应温度、催化剂用量、苯甲酸添加量对甲苯液相氧化反应的影响。研究表明,该催化剂的催化活性存在“催化一一抑制”转换现象,有适宜的催化剂用量范围(<0.011w%)。Co(acac)2催化剂的适宜反应温度为165℃,用量仅为0.0044w%时,催化剂寿命即长达6h。反应体系初始无催化剂和苯甲酸时,反应存在明显诱导期。相比于醋酸钴、环烷酸钴等钴盐催化剂,Co(acac)2催化剂具有用量少、催化活性时间长的优点,可有效地减缓钴盐结垢现象。因此,Co(acac)2催化剂对甲苯液相空气氧化反应具有良好的催化性能。
探索了二元/三元金属催化体系对甲苯液相氧化反应的协同催化性能,研究了Co/Mn二元催化体系和Co/Mn/Zr三元催化体系对甲苯液相氧化反应的催化性能。结果表明,钴(Ⅱ)锰(Ⅱ)比为1：1是较适宜的催化剂配比。此时,反应选择性相比于全钴催化剂情况下提高了50%。Co/Mn/Zr三元催化体系并不适用于本反应体系。
在已有的甲苯液相氧化反应动力学模型基础上,综合考察了苯甲醛、苯甲醇、苯甲酸和苯甲酸苄酯等氧化产物在反应过程中的变化,同时考察了苯甲酸苄酯的逆反应及苯甲酸对反应的促进作用,以此提出了新的反应网络,并根据该反应网络建立了相应的动力学模型。拟合结果表明该动力学模型能较好的描述甲苯液相空气氧化过程中甲苯及各氧化产物的浓度变化。乙酰丙酮钴催化剂相比于环烷酸盐催化剂,能降低甲苯氧化反应的活化能,更有利于反应进行。
自行合成了[ace-min]Co催化剂,采用核磁氢谱对其进行表征,并将该催化剂用于甲苯液相氧化反应。研究结果表明[ace-min]Co催化剂首次使用的催化效果与Co(acac)2催化剂相当,[ace-min]Co催化剂再次使用时活性大大降低。钴催化剂失活的主要原因是生成了COC2O4·2H2O沉淀。草酸根的来源有二,分别是从催化剂带入的醋酸转化而来以及烃类过度氧化生成。钴催化剂的沉淀问题在甲苯氧化反应体系中不可避免。
自行合成了CoSBA-15分子筛催化剂,采用XRD、N2吸附对其结构进行表征,研究了CoSBA-15分子筛催化剂对甲苯液相氧化反应的催化性能。结果表明,该催化剂能将甲苯选择性的氧化为苯甲醛和苯甲醇,160℃下反应6h,苯甲醛和苯甲醇的选择性之和高于86%。
Toluene is the simplest substituted aromatic compound and its oxidation reaction is a typical example of the aromatic hydrocarbon oxidation. The toluene oxidation products, such as benzyl alcohol, benzaldehyde and benzoic acid, are important intermidiates in organic synthesis industry and widely used in pesticides, perfumes, pharmaceuticals, dyes industry and so on. At present, the liquid-phase oxidation of toluene by air is the commonly used process, which is environmentally friendly for its mild reaction conditions and good security. In this paper, the work is to investigate the catalytic activities in the liquid-phase oxidation of pure toluene without halogen and solvent by using Co(acac)2, Co/Mn,[ace-min]Co, CoSBA-15as catalysts separately and benzoic acid as initiator in a stirred tank reactor.
Study on aerobic liquid-phase oxidation of toluene with Co(acac)2was investigated and the effects of operation parameters, such as reaction time, reaction temperature, Co concentration, benzoic acid addition were studied. A phenomenon of 'catalyst-inhibitor'transition was found for Co(acac)2catalyst like other Co salt catalyst. The appropriate range of Co(acac)2dosage is<0.011w%. Optimal operation conditions are reaction temperature165℃and Co concentration0.0044w%. At this situation, the life of catalyst can reach6h. There is an obvious induction period when the reaction system was absence of catalyst and benzoic acid. Co(acac)2catalyst has less catalyst dosage and longer lifetime than other Co salt catalysts like Co(OAc)2, etc., which could slow down the cobalt oxalate scaling during reaction. Therefore, Co(acac)2catalyst has a good application prospect as catalyst in liquid-phase oxidation of toluene.
The catalytic activities of Co/Mn binary and Co/Mn/Zr ternary catalytic system in toluene liquid-phase oxidation were studied. The results show that the appropriate ratio of Co/Mn is1:1. In this situation, reaction selectivity increase50%compared with only cobalt catalyst. But the Co/Mn/Zr ternary catalyst system does not show the catalytic activities.
On the basis of existed kinetic models, we took into account the toluene oxidation products, such as benzyl alcohol, benzaldehyde, benzoic acid and benzyl benzoate, also considered the reverse reaction of benzyl benzoate and promotion of benzoic acid. A new reaction network was proposed, on which a kinetic model was established. The fitting results show that this kinetic model can agree well with the experimental data. Cobalt acetylcaetonate catalyst could reduce activation energy of the reaction of toluene oxidation and make more conducive to the reaction compared to cobalt naphthenate catalyst.
[Ace-min]Co catalyst was synthesized successfully, characterized by1H-NMR and used as catalyst for toluene liquid-phase oxidation. The catalytic activity of [ace-min]Co catalyst used for the first time was the same as the Co(acac)2catalyst, but greatly reduced when the [ace-min]Co catalyst was used again. The deactivation of cobalt catalysts is due to the generation of COC2O4·2H2O. And the oxalate ions come from the catalyst and excessive oxidation of hydrocarbon. The precipitation of cobalt catalyst in toluene oxidation is inevitable.
Mesoporous CoSBA-15molecular sieves were directly synthesized and characterized using XRD, N2adsorption. CoSBA-15materials were used as catalyst for toluene liquid-phase selective oxidation to benzyl alcohol and benzaldehyde using dioxygen as the oxidant. At160℃, the sum selectivity of benzaldehyde and benzyl alcohol is higher than86%.
以Co(acac)2为催化剂,考察了反应时间、反应温度、催化剂用量、苯甲酸添加量对甲苯液相氧化反应的影响。研究表明,该催化剂的催化活性存在“催化一一抑制”转换现象,有适宜的催化剂用量范围(<0.011w%)。Co(acac)2催化剂的适宜反应温度为165℃,用量仅为0.0044w%时,催化剂寿命即长达6h。反应体系初始无催化剂和苯甲酸时,反应存在明显诱导期。相比于醋酸钴、环烷酸钴等钴盐催化剂,Co(acac)2催化剂具有用量少、催化活性时间长的优点,可有效地减缓钴盐结垢现象。因此,Co(acac)2催化剂对甲苯液相空气氧化反应具有良好的催化性能。
探索了二元/三元金属催化体系对甲苯液相氧化反应的协同催化性能,研究了Co/Mn二元催化体系和Co/Mn/Zr三元催化体系对甲苯液相氧化反应的催化性能。结果表明,钴(Ⅱ)锰(Ⅱ)比为1：1是较适宜的催化剂配比。此时,反应选择性相比于全钴催化剂情况下提高了50%。Co/Mn/Zr三元催化体系并不适用于本反应体系。
在已有的甲苯液相氧化反应动力学模型基础上,综合考察了苯甲醛、苯甲醇、苯甲酸和苯甲酸苄酯等氧化产物在反应过程中的变化,同时考察了苯甲酸苄酯的逆反应及苯甲酸对反应的促进作用,以此提出了新的反应网络,并根据该反应网络建立了相应的动力学模型。拟合结果表明该动力学模型能较好的描述甲苯液相空气氧化过程中甲苯及各氧化产物的浓度变化。乙酰丙酮钴催化剂相比于环烷酸盐催化剂,能降低甲苯氧化反应的活化能,更有利于反应进行。
自行合成了[ace-min]Co催化剂,采用核磁氢谱对其进行表征,并将该催化剂用于甲苯液相氧化反应。研究结果表明[ace-min]Co催化剂首次使用的催化效果与Co(acac)2催化剂相当,[ace-min]Co催化剂再次使用时活性大大降低。钴催化剂失活的主要原因是生成了COC2O4·2H2O沉淀。草酸根的来源有二,分别是从催化剂带入的醋酸转化而来以及烃类过度氧化生成。钴催化剂的沉淀问题在甲苯氧化反应体系中不可避免。
自行合成了CoSBA-15分子筛催化剂,采用XRD、N2吸附对其结构进行表征,研究了CoSBA-15分子筛催化剂对甲苯液相氧化反应的催化性能。结果表明,该催化剂能将甲苯选择性的氧化为苯甲醛和苯甲醇,160℃下反应6h,苯甲醛和苯甲醇的选择性之和高于86%。
Toluene is the simplest substituted aromatic compound and its oxidation reaction is a typical example of the aromatic hydrocarbon oxidation. The toluene oxidation products, such as benzyl alcohol, benzaldehyde and benzoic acid, are important intermidiates in organic synthesis industry and widely used in pesticides, perfumes, pharmaceuticals, dyes industry and so on. At present, the liquid-phase oxidation of toluene by air is the commonly used process, which is environmentally friendly for its mild reaction conditions and good security. In this paper, the work is to investigate the catalytic activities in the liquid-phase oxidation of pure toluene without halogen and solvent by using Co(acac)2, Co/Mn,[ace-min]Co, CoSBA-15as catalysts separately and benzoic acid as initiator in a stirred tank reactor.
Study on aerobic liquid-phase oxidation of toluene with Co(acac)2was investigated and the effects of operation parameters, such as reaction time, reaction temperature, Co concentration, benzoic acid addition were studied. A phenomenon of 'catalyst-inhibitor'transition was found for Co(acac)2catalyst like other Co salt catalyst. The appropriate range of Co(acac)2dosage is<0.011w%. Optimal operation conditions are reaction temperature165℃and Co concentration0.0044w%. At this situation, the life of catalyst can reach6h. There is an obvious induction period when the reaction system was absence of catalyst and benzoic acid. Co(acac)2catalyst has less catalyst dosage and longer lifetime than other Co salt catalysts like Co(OAc)2, etc., which could slow down the cobalt oxalate scaling during reaction. Therefore, Co(acac)2catalyst has a good application prospect as catalyst in liquid-phase oxidation of toluene.
The catalytic activities of Co/Mn binary and Co/Mn/Zr ternary catalytic system in toluene liquid-phase oxidation were studied. The results show that the appropriate ratio of Co/Mn is1:1. In this situation, reaction selectivity increase50%compared with only cobalt catalyst. But the Co/Mn/Zr ternary catalyst system does not show the catalytic activities.
On the basis of existed kinetic models, we took into account the toluene oxidation products, such as benzyl alcohol, benzaldehyde, benzoic acid and benzyl benzoate, also considered the reverse reaction of benzyl benzoate and promotion of benzoic acid. A new reaction network was proposed, on which a kinetic model was established. The fitting results show that this kinetic model can agree well with the experimental data. Cobalt acetylcaetonate catalyst could reduce activation energy of the reaction of toluene oxidation and make more conducive to the reaction compared to cobalt naphthenate catalyst.
[Ace-min]Co catalyst was synthesized successfully, characterized by1H-NMR and used as catalyst for toluene liquid-phase oxidation. The catalytic activity of [ace-min]Co catalyst used for the first time was the same as the Co(acac)2catalyst, but greatly reduced when the [ace-min]Co catalyst was used again. The deactivation of cobalt catalysts is due to the generation of COC2O4·2H2O. And the oxalate ions come from the catalyst and excessive oxidation of hydrocarbon. The precipitation of cobalt catalyst in toluene oxidation is inevitable.
Mesoporous CoSBA-15molecular sieves were directly synthesized and characterized using XRD, N2adsorption. CoSBA-15materials were used as catalyst for toluene liquid-phase selective oxidation to benzyl alcohol and benzaldehyde using dioxygen as the oxidant. At160℃, the sum selectivity of benzaldehyde and benzyl alcohol is higher than86%.
引文
[1]Suresh A. K., Sharma M. M., Sridhar T. Engineering Aspects of Industrial Liquid-Phase Air Oxidation of Hydrocarbons [J]. Industrial & Engineering Chemistry Research,2000,39: 3958-3997.
[2]李晓强.锰氧化物对甲苯液相氧化反应的催化作用研究[D].大连,中国科学院大连化学物理研究所,2006.
[3]王峰.多相催化选择氧化甲苯合成芳香醛类化合物的研究[D].大连,中国科学院大连化学物理研究所,2004.
[4]http://baike.baidu.com/view/77606.htm
[5]http://www.chemyq.com/xz/xz11/105837qpdsi.htm
[6]李传兆,江浩,王秀娟,谈遒.氯化苄水解合成苯甲醇反应过程的研究[J].现代化工,1999,19(5)：1-6.
[7]吴鑫干,李陵岚.苯甲醇制造方法[J].工业催化,2002,10(2)：26-32.
[8]化工百科全书编委会.化工百科全书[M].北京：化学工业出版社,1990.
[9]李树安,张珍明.间接法相转移催化水解氯化苄制备苯甲醇的研究[J].现代化工,1996,7：34-35.
[10]栾天平.混合氯化苄合成苯甲醇[J].安徽化工,1998,3：20.
[11]Yadav G. D., Mehta P. H. Theoretical and Experimental Analysis of Capsule Membrane Phase Transfer Catalysis:Selective Alkaline Hydrolysis of Benzyl Chloride to Benzyl Alcohol [J]. Catalysis Letters,1993,21 (3-4):391-403.
[12]Ruddick C. L., Hodge P., Houghton M. P. Conversion of Alkyl Halides into the Corresponding Alcohols under Mild Reaction Conditions [J]. Synthesis,1996,11:1359-1362.
[13]Bryant D. R., McKeon J. E., Ream B. C. A Palladium-Catalyzed Synthesis of Benzyl Esters from Methylbenzenes [J]. Journal of Organic Chemistry,1998,33 (11):4123-4127.
[14]Gonzalez M. A., Howell S. G., Sikdar S. K. Photocatalytic Selective Oxidation of Hydrocarbons in the Aqueous Phase [J]. Journal of Catalysis,1999,183 (1):159-162.
[15]Otsuka K., Ishizuka K., Yamanaka I. Partial Oxidation of Toluene to Benzaldehyde and Benzyl Alcohol by Applying an H2-O2 Fuel Cell System [J]. Chemistry Letters,1992,21 (5):773-776.
[16]Augugliaro V., Coluccia S., Loddo V., Marchese L., Martra G, Palmisano L., Schiavello M. Photocatalytic Oxidation of Gaseous Toluene on Anatase TiO2 Catalyst:Mechanistic Aspects and FT-IR Investigation [J]. Applied Catalysis B:Environmental,1999,20 (1):15-27.
[17]Sharifi A., Mojtahedi M. M., Saidi M. R. Microwave Irradiation Techniques for the Cannizzaro Reaction [J]. Tetrahedron Letters,1999,40 (6):1179-1180.
[18]Varma R. S., Naicker K. P., Liesen P. J. Microwave-accelerated Crossed Cannizzaro Reaction Using Barium Hydroxide under Solvent-free Conditions [J]. Tetrahedron Letters,1998,39 (46): 8437-8440.
[19]Akamanchi K. G., Noorani V. R. Truly Catalytic Meerwein-Ponndorf-Verley (MPV) Reduction [J]. Tetrahedron Letters,1995,36 (28):5085-5088.
[20]Mizugaki T., Ebitani K., Kaneda K. Highly Chemoselective Reduction of Aldehyde Function Catalyzed by Polymer-Bound Rh6 Cluster Complex under Water-Gas Shift Reaction Conditions [J]. Tetrahedron Letters,1997,38 (17):3005-3008.
[21]Firouazabadi H., Adibi M. Modified Borohydride Agents1a-d Methyltriphenylphosphonium Tetrahydroborate; MePh3P+BH4- as a Selective and An Efficient Reducing Agent [J]. Synthetic Communications,1996,26 (13):2429-2441.
[22]Blanton J. R. The Selective Reduction of Aldehydes Using Polyethylene Glycol-Sodium Borohydride Derivatives as Phase Transfer Reagents [J]. Synthetic Communications,1997,27 (12):2093-2102.
[23]Kardile G. B., Desai D. G., Swami S. S. Benzyltriethylammonium Chloride-Zinc-Methanol:A Novel System for Selective Reduction of Aldehydes to Alcohols [J]. Synthetic Communications,1999,29 (12):2129-2131.
[24]Bordoloi M., Sharmat R. P., Chakraborty V. Magnesium-Tin (Ⅱ) Chloride Dihydrate:A New System for Chemoselective Reduction of Aldehydes into Alcohols in the Presence of Ketones, Ketalization of Ketones and Dehalogenation of Benzyl Halides [J]. Synthetic Communications, 1999,29 (14):2501-2506.
[25]Narasimhan S., Madhavan S., Prasad K. G. A Simple Alkene-Catalyzed Reduction of Aromatic Esters to Alcohols by Zinc Borohydride [J]. Synthetic Communications,1997,27 (3):385-390.
[26]Teunissen H. T. Homogeneous Ruthenium Catalyzed Hydrogenation of Esters to Alcohols [J]. Chemical Communications,1998,13:1367-1368.
[27]Cha J. S., Brown H. C. Reaction of Aluminum Hydride-triethylamine Complex with Selected Organic Compounds Containing Representative Functional Groups [J]. Journal of Organic Chemistry,1993,58 (15):3974-3979.
[28]Narasimhan S., Madhavan S., Prasad K. G. Facile Reduction of Carboxylic Acids to Alcohols by Zinc Borohydride [J]. Journal of Organic Chemistry,1995,60 (16):5314-5315.
[29]Ravikumar K. S., Chandrasekaran S. Reaction of Diisopoxytitanium (111) Tetrahydroborate with Selected Organic Compounds Containing Representative Functional Groups [J]. Journal of Organic Chemistry,1996,61 (3):826-830.
[30]Kokotos G., Noula C. Selective One-Pot Convertion of Carboxylic Acids into Alcohols [J]. Journal of Organic Chemistry,1996,61 (20):6994-6996.
[31]http://baike.baidu.com/view/77542.htm
[32]王敏.苯甲醛的生产技术及市场概述[J].精细化工原理及中间体,2005,6：15-18.
[33]樊春玲,刘文明.甲苯选择氧化制苯甲醛的研究进展[J].化工时刊,2008,22(9)：61-67.
[34]缪伶,朱宪.苯甲醛绿色化生产进展[J].上海大学学报自然科学版,2002,8(4)：333.340.
[35]王旭涛.金属卟啉选择性催化空气氧化甲苯制备苯甲醛与苯甲醇研究[D].长沙,湖南大学,2004.
[36]曹志红,刘文明,项学明. La-OMS-2催化剂催化甲苯氧化制苯甲醛[J].石油化工,2006,35(11)：1069-1073.
[37]Borgaonkar H. V., Raverkar S. R., Chandalia S. B. Liquid Phase Oxidation of Toluene to Benzaldehyde by Air [J]. Ind. Eng. Chem. Prod. Res. Dev.,1984,23 (3):455-458.
[38]徐华龙,沈伟,潘欣蔚,项一非.苯甲酸气相加氢合成无氯苯甲醛用MnOx/Al2O3催化剂[J].催化学报,1997,18(5)：384-387.
[39]Yokoyama T., Setoyama T., Fujita N., Nakajima M., Maki T., Fujii K. Novel Direct Hydrogenation Process of Aromatic Carboxylic Acids to the Corresponding Aldehydes with Zirconia Catalyst [J]. Applied Catalysis A:General,1992,88 (2):149-161.
[40]王文英,刘伟,丁克强,顾登平.间接电氧化法合成苯甲醛[J].现代化工,1996,6：33-35.
[41]卢文庆,蔡政,李国栋,邓海山,程宝荣.均匀设计法研究甲苯间接电氧化合成苯甲醛[J].精细化工,2000,17：31-33.
[42]Abramovici S., Neumann R., Sasson Y. Sodium Hypochlorite as Oxidation in Phase Transfer Catalytic Systems:Part Ⅱ. Oxidation of Aromatic Alcohols [J]. Journal of Molecular Catalysis,1985,29 (3):299-303.
[43]Do J. S., Chou T. C. Anodic Oxidation of Benzyl Alcohol to Benzaldehyde in the Presence of both Redox Mediator and Phase Transfer Catalyst [J]. Journal of Applied Electrochemistry, 1989,19 (6):922-927.
[44]http://baike.baidu.com/view/123351.htm
[45]张丽君.苯甲酸生产工艺及进展[J].金陵石油化工,1992,4：30-34.
[46]吴鑫干,陈舒伐.苯甲酸的合成和精制[J].现代化工,2000,20(8)：10-14.
[47]邵坚,马全生,郭法寅.常压法甲苯液相氧化制苯甲酸的研究[J].华北水利水电学院学报,1993,2：67-71.
[48]王忠元,张艳熹.甲苯液相空气氧化制苯甲酸[J].黑龙江石油化工,1996,1：1-3.
[49]柳艳修,宋华,王宝辉.甲苯直接氧化制苯甲醛研究进展[J].工业催化,2005,13(2)：24-28.
[50]Subrahmanyam C., Louis B., Rainone F., Viswanathan B., Renken A., Varadarajan T. K. Catalytic Oxidation of Toluene with Molecular Oxygen over Cr-substituted Mesoporous Materials [J]. Applied Catalysis A:General,2003,241:205-215.
[51]Subrahmanyam C., Louis B., Rainone F., Viswanathan B., Renken A., Varadarajan T. K. Partial Oxidation of Toluene by O2 over Mesoporous Cr-AlPO [J]. Catalysis Communications,2002,3: 45-50.
[52]Zahedi-Niaki M. H., Javaid Zaidi S. M., Kaliaguine S. Comparative Study of Vanadium Aluminophosphate Molecular Sieves VAPO-5,-11,-17 and -31 [J]. Applied Catalysis A: General,2000,196:9-24.
[53]Whittington B. I., Anderson J. R. Nature and Activity of Some Vanadium Catalysts [J]. J. Phys. Chem.,1993,97:1032-1041.
[54]Lopez Nieto J. M. Microporous and Mesoporous Materials with Isolated Vanadium Species as Selective Catalysts in the Gas Phase Oxidation Reactions [J]. Topic in Catalysis,2001,15 (2-4): 189-194.
[55]Loder D. J. Catalytic Oxidaton of Alkyl Substituted Aromatic Compounda, as in the Production of Benzoic Acid from Toluene [P]. US 2245528,1938.
[56]Messina G. Upgrade Toluene to Benzoic Acid [J]. Petrochemical Developments,1964,43 (11): 191-192.
[57]唐盛伟.甲苯液相空气氧化反应过程研究[D].成都,四川大学,2005.
[58]Saffer A., Roberts B. Preparation of Aromatic Polycarboxylic Acid [P]. US 2833816 (A),1985.
[59]Partenheimer W. Methodology and Scope of Metal/bromide Autoxidation of Hydrocarbons [J]. Catalysis Today,1995,23:69-158.
[60]化工百科全书编委会.化工百科全书[M].北京：化学工业出版社,1990,1：447.
[61]Trost B. M. The Atom Economy-a Search for Synthetic Efficiency [J]. Science,1991,254 (5037):1471-1477.
[62]Anastas R. T., Warner J. C. Green Chemistry:Theory and Practice [M]. New York:Oxford University Press,1998,30.
[63]赵劲松,雷庆英.甲苯经苯甲酸制苯酚[J].四川化工,1989,3：39-43.
[64]张帅.醋酸钴和金属卟啉复合催化甲苯氧化研究[D].长沙,湖南大学,2007.
[65]张祥富,时效天.甲苯常压催化氧化制苯甲酸及其它芳烃的氧化反应的研究[J].合成化学,1998,6(4)：433-437.
[66]Partenheimer W. Catalysis of Organic Reaction [M]. New York:Marcel Dekker,1990.
[67]成有为.MC工艺烃类液相催化氧化过程的研究[D].杭州,浙江大学,2004.
[68]王丽军.PX氧化动力学研究及氧化反应器模拟[D].杭州,浙江大学,2001.
[69]谢刚,成有为,李希.对二甲苯液相氧化催化机理[J].聚酯工业,2002,15(4)：1-4.
[70]Chester A. W., Scott E. J. Y, Landis P. S. Zirconium Cocatalysis of the Cobalt-catalyzed Autoxidation of Alkylaromatic Hydrocarbons [J]. Journal of the Catalysis,1977,46:308.
[71]Zuo X. B., Sabramaniam B., Busch D. H. Liquid-Phase Oxidation of Toluene and p-toluic Acid under Mild Conditions:Synergistic Effects of Cobalt, Zirconium, ketones, and Carbon Dioxide [J]. Ind. Eng. Chem. Res.,2008,47:546-552.
[72]Bezhanishvili G. S., Digurov N. G., Lebedev N. N., et al. Kinetics of the Oxidation of Toluene over a Cobalt Bromide Catalyst with the Addition of Zirconyl Chloride [J]. Trans. Kinet. Katal, 1983,24(4):1000.
[73]Park S. E., Yoo J. S., Jun K. W., Raju D. B., Kim Y. H. Method for Preparing Aromatic Carboxylic Acids from Alkylaromatics by Liquid-phase Oxidation [P]. US 6476257,2002.
[74]Partenheimer W. The Effect of Zirconium in Metal/bromide Catalysts during the Autoxidation of p-xylene Part]. Activation and Changes in Benzaldehyde Intermediate Formation [J]. Journal of Molecular Catalysis A:Chemical,2003,206:105-119.
[75]Partenheimer W. The Effect of Zirconium in Metal/bromide Catalysts on the Autoxidation of p-xylene Part Ⅱ. Alternative Metals to Zirconium and the Effect of Zirconium on Manganese (IV) Dioxide Formation and Precipitation with Pyromellitic acid [J]. Journal of Molecular Catalysis A:Chemical,2003,206:131-144.
[76]Jhung S. H., Park Y. S. Precipitation of Manganese in the p-Xylene Oxidation with Oxygen-Enriched Gas in Liquid Phase [J]. Bull. Korean. Chem. Soc.,2002,23 (3):369-373.
[77]胡兴邦.绿色空气氧化催化剂的设计、合成及应用[D].杭州,浙江大学,2007.
[78]http://baike.baidu.com/view/122795.htm
[79]沈秋婵.离子液体支载的催化剂在三甲酚氧化反应中的应用[D].杭州,浙江大学,2008.
[80]户安军,吕春绪,李斌栋,霍婷.对氯甲苯选择性氧化新催化体系研究[J].有机化学,2006,26(8)：1083-1086.
[81]李志刚,陈丽,邓立生,李贤均.对硝基甲苯的液相催化氧化研究[J].化学研究与应用,2001,13(6)：661-664.
[82]范谦,黎耀忠,程溥明,胡家元,李贤均.环已烯烯丙位氧化研究[J].化学研究与应用,2001,13(5)：557-559.
[83]刘长辉.紫罗兰酮的烯丙位选择性氧化反应方法与工艺研究[D].长沙,中南大学,2006.
[84]王丽娜,陆维敏,吕重青,鲁越青.异戊二烯脱氢环氧化的研究[J].催化学报,2002,23(2)：121-124.
[85]Dell'Anna M. M., Mastrorilli P., Nobile C. F. Aerobic Oxidation of Sulfides Catalysed by Cobalt(Ⅱ) Complexes under Homogeneous and Heterogeneous Conditions [J]. Journal of Molecular Catalysis A:Chemical,1996,108:57-62.
[86]Dell'Anna M. M., Mastrorilli P., Nobile C. F., Lopez L. Aerobic Oxidation of a-Hydroxyketones Catalysed by Cobalt(Ⅱ) and Iron(Ⅲ) Complexes under Homogeneous and Heterogeneous Conditions [J]. Journal of Molecular Catalysis A:Chemical,1996,111:33-36.
[87]熊永莲,李静,杨向光,吴越Fe(acac)3/phen/O2体系中苯甲醇的选择氧化[J].石油化工,2004.33：1423-1424.
[88]Matienko L. I., Mosolova L. A. Oxidation of Ethyl benzene with Dioxygen in the Presence of Iron(Ⅲ) Tris(acetylacetonate)-Based Catalytic Systems:1. Mechanism of Ethylbenzene Oxidation with Dioxygen Catalyzed by Fe(Ⅲ)(acac)3 [J]. Kinetics and Catalysis,2005,46 (3): 328-333.
[89]Kobayashi H., Yamanaka I. High Production of Adamantane Oxygenates in Propionic Acid Using VO(acac)2 and Eu(OTf)3 with O2 [J]. Journal of Molecular Catalysis A:Chemical,2008, 294:43-50.
[90]Kobayashi H., Yamanaka I. Oxidation of Adamantane with O2 by VO(acac)2 and Reactivity of Active Species in Acetic Acid [J]. Journal of Molecular Catalysis A:Chemical,2008,294: 37-42.
[91]Lattanzi A., Senatore A., Massa A., Scettri A. Novel Highly Regioselective VO(acac)2/TBHP Mediated Oxidation of o-Alkenyl Phenols to o-Hydroxybenzyl Ketones [J]. J. Org. Chem., 2003,68:3691-3694.
[92]Csanyi L. J., Jaky K.., Galbacs G. Oxidation of Hydrocarbons by O2 in the Presence of VO(acac)2 as Catalyst [J]. Journal of Molecular Catalysis A:Chemical,2002,179:65-72.
[93]http://baike.baidu.com/view/2309455.htm
[94]Ishii Y., Sakaguchi S., Iwahama T. Innovation of Hydrocarbon Oxidation with Molecular Oxygen and Related Reactions [J]. Adv. Synth. Catal.,2001,343:393-427.
[95]Ishii Y, Sakaguchi S. A New Strategy for Alkane Oxidation with O2 Using N-hydroxyphthalimide (NHPI) as a Radical Catalyst [J]. Catalysis Surveys from Japan,1999,3: 27-35.
[96]Ishii Y A Novel Catalysis of N-hydroxyphthalimide (NHPI) Combined with Co(acac)n (n=2 or 3) in the Oxidation of Organic Substrates with Molecular Oxygen [J]. Journal of Molecular Catalysis A:Chemical,1997,117:123-137.
[97]Ishii Y., Iwahama T., Sakaguchi S., Nakayama K., Nishiyama Y. Alkane Oxidation with Molecular Oxygen Using a New Efficient Catalytic System:N-hydroxyphthalimide (NHPI) Combined with Co(acac)n (n=2 or 3) [J]. J. Org. Chem.,1996,61:4520-4526.
[98]Ishii Y., Kato S., Iwahama T., Sakaguchi S. Hydroxylation of Polycyclic Alkanes with Molecular Oxygen Catalyzed by N-Hydroxyphthalimide (NHPI) Combined with Transition Metal Salts [J]. Tetrahedron Letters,1996,37 (28):4993-4996.
[99]Iwahama T., Syojyo K., Sakaguchi S., Ishii Y. Direct Convertion of Cyclohexane into Adipic Acid with Molecular Oxygen Catalyzed by N-hydroxyphthalimide (NHPI) Combined with Mn(acac)2 and Co(OAc)2 [J]. Organic Process Research & Development,1998,2:255-260.
[100]Figiel P. J., Sobczak J. M. Aerobic Oxidation of Alcohols and Alkylaromatics with Dioxygen Catalysed by N-hydroxyphthalimide with Vanadium Co-catalysts [J]. New J. Chem.,2007,31: 1668-1673.
[101]Figiel P. J., Sobczak J. M., Ziolkowski J. J. New Efficient Aerobic Oxidation of Some Alcohols with Dioxygen Catalysed by N-hydroxyphtalimede with Vanadium Co-catalysts [J]. Chem. Commun.,2004,244-245.
[102]卓广澜,赵卫娟,姜玄珍.甲苯氧化制苯甲酸的新催化体系[J].有机化学,2004,24(8)：962-965.
[103]方亚辉,户安军,李斌栋,吕春绪.NHPI/过渡金属催化甲苯氧化制苯甲酸[J].化工进 展,2006,25(11)：1358-1361.
[104]葛凤燕,赵继全,郑岩,户秋义.p.二酮钴配合物催化空气氧化二苯甲醇反应的研究[J].分子催化,2003,17(4)：259-263.
[105]江文辉,周亚平,唐瑞仁,李菲.N.羟基邻苯二甲酰亚胺/Co(acac)2催化的α-紫罗兰酮的氧化反应[J].应用化学,2009,26(11)：1305-1309.
[106]谭新良,黎艳玲,陈雄,朱卓越等.N.羟基邻苯二甲酰亚胺催化分子氧氧化合成4-氧代-β-紫罗兰酮[J].香料香精化妆品,2010,3：3-5.
[107]Maurya M. R., Arya A., Adao P., Pessoa J. C. Immobilisation of Oxovanadium (Ⅳ), Dioxomolybdenum (Ⅵ) and Copper (Ⅱ) Complexes on Polymers for the Oxidation of Styrene, Cyclohexene and Ethylbenzene [J]. Applied Catalysis A:General,2008,351: 239-252.
[108]方钊,唐瑞仁,黄可龙,张瑞荣.咪唑修饰硅胶负载乙酰丙酮钴(II)催化分子氧氧化单萜烯研究[J].高等学校化学学报,2009,30(9)：1748-1753.
[109]Zavoianu R., lonescu R., Pavel O. D., Birjega R., Angelescu E. Comparison between Me" Mg/Al Hydrotalcites and Hydrotalcite-Supported Me (Ⅱ) Acetylacetonates (Me (Ⅱ)=Co, Cu or Ni) Catalysts for the Epoxidation of Cyclohexene with Molecular Oxygen [J]. Applied Clay Science,2011.52:1-10.
[110]Hu Q., Zhao J. Q. Wang Y. J., Zhu L. D., Li M. Q., Li G. H., Wang Y., Ge F. Y. Sol-gel Encapsulated Cobalt (Ⅲ) Acetylacetonate for Air Oxidation of Penicillin Derivatives [J]. Journal of Molecular Catalysis A:General,2003,200:271-277.
[111]李汝雄.绿色溶剂一离子液体的合成与应用[M].北京：化学工业出版社,2004.
[112]Miao W. S., Chan T. H. Ionic-Liquid-Supported Synthesis:A Novel Liquid-Phase Strategy for Organic Synthesis [J]. Acc, Chem, Res.,2006,39:897-908.
[113]Sing K. S. W., Everett D. H., Haul R. A. W., Moscow L., Pierotti R. A., Ronquerol J., Wska S. Reporting Physisorption Data for Gas/Solid Systems with Special Reference to the Determination of Surface Area and Porosity [J]. Pure ppl. Chem.1985,57:603-619.
[114]Beck J. S. Vartuli J. C. Roth W. J., Leonowicz M. E. Kresge C. T., Schmitt K. D., Chu C. T. W. Olson D. H., Sheppard E. W., Cullen S. C. Higgins J. B., Schlenker J. L. A New Family of Mesoporous Molecular-Sieves Prepared with Liquid-Crystal Template [J]. J. Am. Chem. Soc.1992,114:10834-10843.
[115]Kresge J. S., Leonowicz M. E., Roth W. J., Vartuli J. C.,Beck J. S. Ordered Mesoporous Molecular Sieve Synthesized by a Liquid-Crystal Template Mechanism [J]. Nature (London), 1992,359:710-712.
[116]Monnier A., Schuth F., Huo Q. Cooperative Formation of Inorganic-Organic Interfaces in the Synthesis of Silicate Mesostructure [J]. Science,1993,261:1299-1303.
[117]Bagshaw S. A., Prouzet E., Pinnavaia T. J. Templating of Molecular Sieves by Nonionic Polyethylene Oxide Surfactant [J]. Science,1995,269:1242-1244.
[118]Tanev P. T., Pinnavaia T. J. A Neutral Templating Route to Mesoporous Molecular Sieves [J]. Science,1995,267:865-867.
[119]Tanev P. T., Pinnavaia T. J. Biomimetic Templating of Porous Lamellar Silicas by Vesicular Surfactant Assemblies [J]. Science,1996,271 (5253):1267-1269.
[120]Bagshaw S. A., Prouzet E., Pinnavaia T. J. Templating of Mesoporous Molecular-Sieves by Nonionic Polyethylene Oxide [J]. Science,1995,269 (5228):1242-1244.
[121]Huo Q., Margolese D., Ciesla U., Feng P., Sieger P., Leon R., Petroff P., Schuth F., Stucky G. D. Generalized Synthesis of Periodic Surfactant Inorganic Composite-Materials [J]. Nature, 1994,368:317-319.
[122]Huo Q., Leon R., Petrof P. M.f, Stucky G. D. Mesostructure Design with Gemini Surfactant-Supercage Formation in a 3-Dimensional Hexagonal Array [J]. Science,1995,268: 1324-1327.
[123]Zhao D., Feng J., Huo Q., Melosh N., Fredrickson G. H., Chmelka B. F, Stucky G. D. Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores [J]. Science,1998,279:548-552.
[124]Zhao D., Huo Q., Feng J., Chmelka B. F., Stucky G. D. Nonionic Triblock and Star Diblock Copolymer and Oligomeric Surfactant Syntheses of Highly Ordered, Hydrothermal Stable, Mesoporous Silica Structures [J]. J. Am. Chem. Soc.,1998,120:6024-6036.
[125]李瑛Al-SBA-15和Fe-SBA-15介孔材料的合成、表征及催化性能研究[D].大连,中国科学院大连化学物理研究所,2005.
[126]徐如人,庞文琴等.分子筛与多孔材料化学[M].北京：科学出版社,2004,616.
[127]张微,徐恒泳,毕亚东,李文钊.介孔分子筛SBA-15的改性研究进展[J].化工进展,2007,26(2)：152-157.
[128]郭昌文.环戊烯合成戊二醛催化新材料的研究[D].上海,复旦大学,2003.
[129]Grieken R. V., Escola J. M., Moreno J., Rodriguez R. Direct Synthesis of Mesoporous M-SBA-15 (M=Al, Fe, B, Cr) and Application to 1-hexene Oligomerization [J]. Chemical Engineering Journal,2009,155:442-450.
[130]Luz Jr G. E., Lima S. H., Melo A. C. R., Araujo A. S., Fernandes Jr V. J. Direct Synthesis and Characterization of LaSBA-15 Mesoporous Molecular Sieves [J]. J. Mater. Sci.,2010,45: 1117-1122.
[131]Lizama L. Y., Klimova T. E. SBA-15 Modified with Al, Ti, or Zr as Supports for Highly Active NiW Catalysts for HDS [J]. J. Mater. Sci.,2009,44:6617-6628.
[132]Chen S. Y., Tsai H. D., Chuang W. T., Lee J. J., Tang C. Y., Lin C. Y., Cheng S. Direct Preparation of Thermally Stable Sn-Incorporated SBA-15 Mesoporous Materials in the Self-Generated Acidic Environment [J]. J. Phys. Chem. C.,2009,113:15226-15238.
[133]Lou Z. S., Wang R. H., Sun H., Chen Y., Yang Y. H. Direct Synthesis of Highly Ordered Co-SBA-15 Mesoporous Materials by the pH-adjusting Approach [J]. Microporous and Mesoporous Materials,2008,110:347-354.
[134]Ying F., Li J. H., Huang C. J., Weng W. Z., Wan H. L. Direct Synthesis and Superior Catalytic Performance of V-containing SBA-15 Mesoporous Materials for Oxidative Dehydrogenation of Propane [J]. Catalysis Letters,2007,115 (3-4):137-142.
[135]Selvaraj M., Lee T. G. Direct Synthesis of Well-Ordered and Unusually Reactive MnSBA-15 Mesoporous Molecular Sieves with High Manganese Content [J]. J. Phys. Chem. B.,2006, 110:21793-21802.
[136]Zhang W. H., Lu J. Q., Han B., Li M. J., Xiu J. H., Ying P. L., Li C. Direct Synthesis and Characterization of Titanium-Substituted Mesoporous Molecular Sieve SBA-15 [J]. Chem. Mater.,2002,14:3413-3421.
[137]Chen Y. Y., Huang Y. L., Xiu J. H., Han X. W., Bao X. H. Direct Synthesis, Characterization and Catalytic Activity of Titanium-Substituted SBA-15 Mesoporous Molecular Sieves [J]. Applied Catalysis A:General,2004,273:185-191.
[138]Wang L. P., Kong A. G, Chen B., Ding H. M., Shan Y. K., He M. Y. Direct Synthesis, Characterization of Cu-SBA-15 and High Catalytic Activity in Hydroxylation of Phenol by H2O2 [J]. Journal of Molecular Catalysis A:Chemical,2005,230:143-150.
[139]Vinu A., Sawant D. P., Ariga K., Hossain K. Z., Halligudi S. B., Hartmann M., Nomura M. Direct Synthesis of Well-Ordered and Unusually Reactive FeSBA-15 Mesoporous Molecular Sieves [J]. Chem. Mater.,2005,17:5339-5345.
[140]Li Y, Feng Z. C., Lian Y. X., Sun K. Q., Zhang L., Jia G. Q., Yang Q. H., Li C. Direct Synthesis of Highly Ordered Fe-SBA-15 Mesoporous Materials under Weak Acidic Conditions [J]. Microporous and Mesoporous Materials,2005,84:41-49.
[141]Li F. X., Yu F., Li Y. L., Li R. F., Xie K. C. Direct Synthesis of Zr-SBA-15 Mesoporous Molecular Sieves High Zirconium Loading:Characterization and Catalytic Performance after Sulfated [J]. Microporous and Mesoporous Materials,2007,101:250-255.
[142]杨丽娜,亓玉台,袁兴东等.磷钨酸改性介孔分子筛SBA-15催化剂的酸性及水热稳定性的研究[J].石油化工,2005,34(3)：222-225.
[143]张雪峥,乐英红,高滋PW/SBA-15负载型催化剂的性能研究[J].高等学校化学学报,2001,22(7)：1169-1172.
[144]Liu Q. Y., Wu W. L., Wang J., et al. Characterization of 12-tungstophosphoric Acid Impregnated on Mesoporous Silica SBA-15 and its Catalytic Performance in Isopropylation of Naphthalene with Isopropanol [J]. Microporous and Mesoporous Materials,2004,76: 51-60.
[145]Yang L. N., Qi Y. T., Yuan X. D., et al. Direct Synthesis, Characterization and Catalytic Application of SBA-15 Containing Heteropolyacid H3PW12O40 [J]. J. Mol. Catal. A: Chemical,2005,229:199-205.
[146]Rao P. M., Wolfson A., Kababya S., et al. Immobilization of Molecular H3PW12O40 Heteropolyacid Catalyst in Alumina-Grafted Silica-Gel and Mesostructured SBA-15 Silica Matrices [J]. J. Catal.,2005,232:210-225.
[147]袁兴东,沈健,李国辉,等.SBA.15介孔分子筛表面的磺酸基改性及其催化性能[J].催化学报,2002,23(5)：435-438.
[148]皇艳蕾,陈杨英,刘秀梅,等.苯基改性的中孔分子筛SBA-15的合成及其磺化[J].催化学报,2004,25(5)：413-416.
[149]Yang L. M., Wang Y. J., Luo G. S., et al. Functionalization of SBA-15 Mesoporous Silica with Thiol or Sulfonic Acid Groups under the Crystallization Conditions [J]. Micropor. Mesopor. Mater.,2005,84:275-282.
[150]Reddy S. S., Raju B. D., Kumar V. S., et al. Sulfonic Acid Functionalized Mesoporous SBA-15 for Selective Synthesis of 4-phenyl-1,3-dioxane [J]. Catal. Commun..,2007,8: 261-266.
[151]顾晓利,何明,史以俊,罗振扬,姚春才.镧改性SBA-15分子筛的制备及对甲苯催化氧化性能的研究[J].天然气化工,2010,35(5)：29-33.
[152]杜建亮,刘丹,桂建舟,张晓彤,宋丽娟,孙兆林Cu/SBA-15催化苯甲醇氧化制苯甲醛[J].石油化工高等学校学报,2006,19(1)：13-16.
[153]Reddy S. S., Raju B. D., Padmasri A. H., Prakash P. K. S., Rao K. S. R. Novel and Efficient Cobalt Encapsulated SBA-15 Catalysts for the Selective Oxidation of Cyclohexane [J]. Catalysis Today,2009,141:61-65.
[154]Li L., Li H., Jin C., Wang X. C., Ji W. J., Pan Y., Knaap T. V. D., Stoel R. V. D., Au C. T. Surface Cobalt Silicate and CoOx Cluster Anchored to SBA-15:Highly Efficient for Cyclohexane Partial Oxidation [J]. Catal Lett.,2010,136:20-27.
[155]Selvaraj M., Park D. W., Ha C. S. Well Ordered Two-Dimensional Mesoporous CeSBA-15 Synthesized with Improved Hydrothermal Stability and Catalytic Activity [J]. Microporous and Mesoporous Materials,2011,138:94-101.
[156]Raju G., Reddy P. S., Ashok J., Reddy B. M., Venugopal A. Solvent-Free Aerobic Oxidation of Ethylbenzene over Supported Ni Catalysts Using Molecular Oxygen at Atmospheric Pressure [J]. Journal of Natural Gas Chemistry,2008,17:293-297.
[157]Cui H. T., Zhang Y., Qiu Z. G., Zhao L. F., Zhu Y L. Synthesis and Characterization of Cobalt-Substituted SBA-15 and Its High Activity in Epoxidation of Styrene with Molecular Oxygen [J]. Applied Catalysis B:Environmental,2010,101:45-53.
[158]Selvaraj M., Kawi S. Direct Synthesis of Mesoporous CrSBA-15 Catalyst and Its High Activity and Selectivity for Oxidation of Anthracene [J]. Microporous and Mesoporous Materials,2007,101:240-249.
[159]Howarth J. Oxidation of Aromatic Aldehydes in the Ionic Liquid [bmim]PF6 [J]. Tetrahedron Letters,2000, (41):6627-6629.
[160]刘耀华,崔鹏,孙靖等.离子液体中芳烃侧链分子氧催化氧化反应研究[J].高等学校化学学报,2006,27(12)：2314-2318.
[161]Seddon K. R., Stark A. Selective Catalytic Oxidation of Benzyl Alcohol and Alkylbenzenes in Ionic Liquids [J]. Green Chemistry,2002,4:119-123.
[162]Haas G. R., Kolis J. W. Oxidation of Alkenes in Supercritical Carbon Dioxide Catalyzed by Molybdenum Hexacarbonyl [J]. Organometallics,1998,17:4454-4460.
[163]Zhu J., Tsang S. C. Micellar Catalysis for Partial Oxidation of Toluene to Benzoic Acid in Supercritical CO2:Effects of Fluorinated Surfactants [J]. Catalysis Today,2003,81:673-679.
[164]Holliday R. L., Jong B. Y. M, Kolis J. W. Organic Synthesis in Subcritical Water Oxidation of Alkyl Aromatics [J]. Journal of Supercritical Fluids,1998,12:255-260.
[165]Guo C. C., Li Q.u, Wang X. T., Hu H. Y. Selective Liquid Phase Oxidation of Toluene with Air [J]. Applied Catalysis A:General,2005,282:55-59.
[166]Bastock T. W., Clark J. H., Martin K., Trenbirth B. W. Mild, Solvent-Free Oxidation of Toluene and Substituted Toluenes to Their Benzoic Acids Using Carboxylic Acid-Promoted Heterogeneous Catalysis [J]. Green Chemistry,2002,4:615-617.
[167]Gao J., Tong X. L., Li X. Q., Miao H., Xu J. The Efficient Liquid-phase Oxidation of Aromatic Hydrocarbons by Molecular Oxygen in the Presence of MnCO3 [J]. Journal of Chemical Technology and Biotechnology,2007,82:620-625.
[168]Falgayrac G., Savall A. Electrochemical Activation of the Catalytic Effect of Cobalt in Autoxidation of Toluene in Acetic Acid [J]. Journal of Applied Electrochemistry,1999,29: 253-258.
[169]李德江,孙碧海,李斌.相转移催化氧化合成苯甲酸[J].化学研究与应用,2002,14(6)：753.7555.
[170]杨芝萍,郭孟萍.相转移催化剂在甲苯氧化反应中的应用[J].江西教育学院学报(自然科学),1998,19(6)：37-38.
[171]张彰,朱宪,张彬.非均相Mn(11]).甲苯氧化反应的动力学[J].高校化学工程学报,2002,16(2)：174-179.
[172]Satrio J. A. B., Doraiswamy I. K. Production of Benzyldehyde:a Case Study in a Possible Industrial Application of Phase-Transfer Catalysis [J]. Chemical Engineering Journal,2001, 82:43-56.
[173]Roby A. K., Kingsley J. P. Enhanced Oxidation of Organic Chemical [P]. US 5536875 (A), 1996.
[174]Bukharkina T. V., Digurov N. G. Kinetics of Aerobic Liquid-Phase Oxidation of Organic Compounds [J]. Organic Process Research & Development,2004,8:320-329.
[175]Hoorn J. A. A., Alsters P. L., Versteeg G. F. A Kinetic Model for Toluene Oxidation Comprising Benzylperoxy Benzoate Ester as Reactive Intermediate in the Formation of Benzaldehyde [J]. International Journal of Chemical Reactor Engineering,2005,3:1-19.
[176]Morimoto T., Ogata Y. Kinetics of the Autoxidation of Toluene Catalysed by Cobaltic Acetate [J]. J. Chem. Soc (B),1967,62-66.
[177]Helfferich F. G. Kinetics of Homogeneous Multistep Reactions [M]. R.G. Compton & G. Hancock Eds., Elsevier, Amsterdam,2001,38:283-286.
[178]Scott E. J. Y., Chester A. W. Kinetics of the Cobalt-catalyzed Autoxidation of Toluene in Acetic Acid [J]. J. Phys. Chem.,1972,76(11):1520-1524.
[179]Kagami K. Anomalous Effect of the Concentration of Metal-salt Catalysts in the Liquid-phase Oxdation of p-xylene and Toluene [J]. Bull. Chem. Soc. Jap.,1968,41 (7):1552-1557.
[180]Bhattacharya D., Guha D. K., Roy A. N. Liquid Phase Air Oxidation of Toluene to Benzoic Acid. Ⅱ. Kinetics and Mechanism [J]. Chem. Age. India.,1973,24 (2):87-90.
[181]Quiroga O. D., Gottifredi J. C., Capretto de Castillo M. E. Liquid Phase Catalytic Toluene Oxidation, Formulation of a Kinetic Model [J]. Rev. Latinoam. Ing. Quim. Quim. Apl.,1980, 10:77-88.
[182]Gadelle C., Clement G. Etude cinetique de l'oxydation radicalaire par l'oxygene des alcoylaromatiques en phase liquid [J]. Bull. Soc. Chim. De France,1968,1:44-54.
[183]Korthals Altes F. W., van den Berg P. J. Kinetics of the Autoxidation of Ethylbenzene [J]. Receuil,1966,85:538-544.
[184]Ivanov S. K., Kalitchin Z. H. D., Hinkova M. K. Direct Oxidation of Toluene to Benzaldehyde in the Presence of N-bromosuccinimide [J]. Oxidation Communications,1983, 3 (2):89-102.
[185]Hendriks C. F., van Beek H. C. A., Heertjes P. M. The Oxidation of Substituted Toluenes by Cobalt(Ⅲ) Acetate in Acetic Acid Solution [J]. Ind. Chem. Prod. Res. Dev.,1978a,17 (3): 256-260.
[186]Russell G. A. Deuterium-isotope Effects in the Autoxidation of Aralkyl Hydrocarbons. Mechanism of the interaction of peroxy radicals [J]. J. Am. Chem. So.c,1957,79:3871-3877.
[187]肖春妹,李国清.甲苯液相空气催化氧化技术研究进展[J].化工生产与技术,2006,13(2)：46-50.
[188]Borgaonkar Hemant V, Raverkar Sanjay R, Chandalla Sampatral B. Liquid Phase Oxidation of Toluene to Benzaldehyde by Air [J]. Ind. Eng. Chem. Prod. Res. Dev.,1984,23:455-458.
[189]Hay Llan S, Blanchard Harry S. Autoxidation Reactions Catalyzed by Cobalt Acetate Bromide [J]. Canadian Journal of Chemistry,1965,43:1306-1317.
[190]Hendriks Charles F, van Beck Hendfik C A, Heertjes Pleter M. The Oxidation of Substituted Toluenes by Cobalt(Ⅲ) Acetate in Acetic Acid Solution [J]. Ind. Eng. Chem. Prod. Res. Dev., 1978,17 (3):256-260.
[191]唐盛伟,梁斌,吴潘,张全忠,刘长军.甲苯液相氧化反应过程动力学的研究[J].反应工程与工艺,2005,4：333-338.
[192]刘含茂.甲苯液相空气氧化法制苯甲醛[D].长沙：湖南大学,2003.
[193]邹隐文,顾雄毅,程宗泽,于广欣,王志侃.甲苯液相氧化动力学研究[J].化学工程,2007,35(9)：33-36.
[194]张玉坤,李初福,任世明,何小荣,陈丙珍.甲苯液相催化氧化过程稳态模拟[J].化工进展,2006,25(12)：1481-1483.
[195]Hoorn J. A. A., Soolingen J. V., Versteeg G. F. Modelling Toluene Oxidaton Incorporation of Mass Transfer Phenomena [J]. Chemical Engineering Research and Design,2005,83 (A2): 187-195.
[196]古凤才,王金明,刘荫藩,叶文强,孙淑梅.西拂碱钴络合物对亚甲基的催化氧化研究[J].天津大学学报,1998,31(5)：666-670.
[197]陈甘棠.化学反应工程(第二版)[M].北京：化学工业出版社,1990.
[198]刘建松.甲苯液相催化氧化动力学的研究[D].杭州,浙江大学,2006.
[199]陈舒伐.甲苯液相空气氧化法制苯甲醛工艺条件研究[D].长沙,湖南大学,2001.
[200]Kamiya Y., Ingold K. U. The Metal-catalyzed Autoxidation of Tetralin:Ⅳ. The Effect of Solvent and Temperature [J]. Canadian Journal of Chemistry,1964,42:2424-2433.
[201]唐盛伟.甲苯液相空气氧化反应过程研究[D].成都,四川大学,2005.
[202]Hancock E. G. Toluene, the Xylenes and Theirs Industrial Derivatives [M]. Eleservier Scientific Publishing Company. Amsterdan-Oxford New York,1982.
[203]Hanotier J., Hanotier-Bridoux M. Mechanism of the Liquid Phase Homogeneous Oxidation of Alkylaromatic Hydrocarbons by Cobalt Salts [J]. J. Mol. Catal.,1981,12:133-147.
[204]Van Der Ploeg R. E., De Kort R. W., Kooyman E. C. Intermediate Steps in Autoxidation Ⅲ. Reactions of MnⅢ Acetate in Acetic Acid with Benzene, Chlorobenzene, and Toluene [J]. Journal of Catalysis,1968,10:52-59.
[205]Heiba E. I., Dessau R. M., Koehl Jr W. J. Oxidation of Metal Salts.Ⅲ. The Reaction of Manganic Acetate with Aromatic Hydrocarbons and the Reactivity of Carboxy Methyl Radical [J].J.Am. Chem. Soc.,1969,91:138-145.
[206]Kantam M. L., Sreekanth P., Rao K. K. et al. An Improved Process for Selective Liquid-phase Air Oxidation of Toluene [J]. Catalysis Letters,2002,81 (3-4):223-232.
[207]Nair K., Sawant D. P., Shanbhag G. V., Halligudi S. B. Aerial Oxidation of Substituted Aromatic Hydrocarbons Catalyzed by Co/Mn/Br in Water-dioxane Medium [J]. Catalysis Communications,2004,5:9-13.
[208]蔡敏敏.氧气/空气液相氧化一元取代甲苯成芳香醛工艺及机理研究[D].南京,南京理工大学,2001.
[209]Chavan S. A., Halligudi S. B., Srinivas D., Ratnasamy P. Formation and Role of Cobalt and Manganese Cluster Complexes in the Oxidation of p-Xylene [J]. Journal of Molecular Catalysis A:Chemical,2000,161:49-64.
[210]Partenheimer W. The Structure of Metal/Bromide Catalysts in Acetic Acid/Water Mixtures and Its Significance in Autoxidation [J]. Journal of Molecular Catalysis A:Chemical,2001, 174:29-33.
[211]张楠,刘建松,陈纪忠.甲苯液相催化氧化反应动力学[J].化学反应工程与工艺,2008,24(1)：18-23.
[212]lchikawa Y., Yamashita G, Tokashiki, M. Yamaji T. New Oxidation Process for Production of Terephthalic Acid from p-Xylene [J]. Ind. And Eng. Chem.,1970,62:38-42.
[213]高恩君,陈盛民,葛欣喜.钴(II)、镍(II)与系列二元羧酸配合物稳定性的研究[J].沈阳化工学院学报,1995,9(1)：14-20.
[214]Kamiya Y. The Autoxidation of Tetralin Catalysed by Cobalt Salt and Sodium Bromide in Acetic Acid [J]. Tetrahedron,1966,22:2029-2038.
[215]唐盛伟,张全忠,梁斌.甲苯液相氧化过程中结垢成分的分析[J].石油化工,2004,33(4)：372-376.
[216]Tang Shengwei, Liang Bin. Scale Formation and Its Mechanism in the Liquid-Phase Oxidation of Tolene by Air [J]. Ind. Eng. Chem. Res.,2007,46:7826-7829.
[217]Shende R. V., Mahajani V. V. Kinetics of Wet Oxidation of Formic Acid and Acetic Acid [J]. Ind. Eng. Chem. Res.,1997,36:4809-4814.
[218]Shende R. V., Levee J. Wet Oxidation Kinetics of Refractory Low Molecular Mass Carboxylic Acids [J]. Ind. Eng. Chem. Res.,1999,38:3830-3837.
[219]Klinghoffer A. A., Cerro R. L., Abraham M. A. Influence of Flow Properties on the Performance of the Monolith Froth Reactor for Catalytic Wet Oxidation of Acetic Acid [J]. Ind. Eng. Chem. Res.,1998,37:1203-1210.
[220]Zhao D. Y, Sun J. Y., Li Q. Z., et al. Morphological Control of Highly Ordered Mesoporous Silica SBA-15 [J]. Chem. mater.,2000,12:275-279.
[221]王莉萍.介孔分子筛的功能化修饰及其催化性能研究[D].上海：华东师范大学,2005.
[222]Hu Longxing, Yang Xiaping, Dang Songtao. An Easily Recyclable Co/SBA-15 Catalyst: Heterogeneous Activation of Peroxymonosulfate for the Degradation of Phenol in Water [J]. Applied Catalysis B:Environmental,2011,102:19-26.
[223]Shukla Pradeep, Wang Shaobin, Sun Hongqi, Ang Hua-Ming, Tade Moses. Adsorption and Heterogeneous Advanced Oxidation of Phenolic Contaminants Using Fe Loaded Mesoporous SBA-15 and H2O2 [J]. Chemical Engineering Journal,2010,164:255-260.
[2]李晓强.锰氧化物对甲苯液相氧化反应的催化作用研究[D].大连,中国科学院大连化学物理研究所,2006.
[3]王峰.多相催化选择氧化甲苯合成芳香醛类化合物的研究[D].大连,中国科学院大连化学物理研究所,2004.
[4]http://baike.baidu.com/view/77606.htm
[5]http://www.chemyq.com/xz/xz11/105837qpdsi.htm
[6]李传兆,江浩,王秀娟,谈遒.氯化苄水解合成苯甲醇反应过程的研究[J].现代化工,1999,19(5)：1-6.
[7]吴鑫干,李陵岚.苯甲醇制造方法[J].工业催化,2002,10(2)：26-32.
[8]化工百科全书编委会.化工百科全书[M].北京：化学工业出版社,1990.
[9]李树安,张珍明.间接法相转移催化水解氯化苄制备苯甲醇的研究[J].现代化工,1996,7：34-35.
[10]栾天平.混合氯化苄合成苯甲醇[J].安徽化工,1998,3：20.
[11]Yadav G. D., Mehta P. H. Theoretical and Experimental Analysis of Capsule Membrane Phase Transfer Catalysis:Selective Alkaline Hydrolysis of Benzyl Chloride to Benzyl Alcohol [J]. Catalysis Letters,1993,21 (3-4):391-403.
[12]Ruddick C. L., Hodge P., Houghton M. P. Conversion of Alkyl Halides into the Corresponding Alcohols under Mild Reaction Conditions [J]. Synthesis,1996,11:1359-1362.
[13]Bryant D. R., McKeon J. E., Ream B. C. A Palladium-Catalyzed Synthesis of Benzyl Esters from Methylbenzenes [J]. Journal of Organic Chemistry,1998,33 (11):4123-4127.
[14]Gonzalez M. A., Howell S. G., Sikdar S. K. Photocatalytic Selective Oxidation of Hydrocarbons in the Aqueous Phase [J]. Journal of Catalysis,1999,183 (1):159-162.
[15]Otsuka K., Ishizuka K., Yamanaka I. Partial Oxidation of Toluene to Benzaldehyde and Benzyl Alcohol by Applying an H2-O2 Fuel Cell System [J]. Chemistry Letters,1992,21 (5):773-776.
[16]Augugliaro V., Coluccia S., Loddo V., Marchese L., Martra G, Palmisano L., Schiavello M. Photocatalytic Oxidation of Gaseous Toluene on Anatase TiO2 Catalyst:Mechanistic Aspects and FT-IR Investigation [J]. Applied Catalysis B:Environmental,1999,20 (1):15-27.
[17]Sharifi A., Mojtahedi M. M., Saidi M. R. Microwave Irradiation Techniques for the Cannizzaro Reaction [J]. Tetrahedron Letters,1999,40 (6):1179-1180.
[18]Varma R. S., Naicker K. P., Liesen P. J. Microwave-accelerated Crossed Cannizzaro Reaction Using Barium Hydroxide under Solvent-free Conditions [J]. Tetrahedron Letters,1998,39 (46): 8437-8440.
[19]Akamanchi K. G., Noorani V. R. Truly Catalytic Meerwein-Ponndorf-Verley (MPV) Reduction [J]. Tetrahedron Letters,1995,36 (28):5085-5088.
[20]Mizugaki T., Ebitani K., Kaneda K. Highly Chemoselective Reduction of Aldehyde Function Catalyzed by Polymer-Bound Rh6 Cluster Complex under Water-Gas Shift Reaction Conditions [J]. Tetrahedron Letters,1997,38 (17):3005-3008.
[21]Firouazabadi H., Adibi M. Modified Borohydride Agents1a-d Methyltriphenylphosphonium Tetrahydroborate; MePh3P+BH4- as a Selective and An Efficient Reducing Agent [J]. Synthetic Communications,1996,26 (13):2429-2441.
[22]Blanton J. R. The Selective Reduction of Aldehydes Using Polyethylene Glycol-Sodium Borohydride Derivatives as Phase Transfer Reagents [J]. Synthetic Communications,1997,27 (12):2093-2102.
[23]Kardile G. B., Desai D. G., Swami S. S. Benzyltriethylammonium Chloride-Zinc-Methanol:A Novel System for Selective Reduction of Aldehydes to Alcohols [J]. Synthetic Communications,1999,29 (12):2129-2131.
[24]Bordoloi M., Sharmat R. P., Chakraborty V. Magnesium-Tin (Ⅱ) Chloride Dihydrate:A New System for Chemoselective Reduction of Aldehydes into Alcohols in the Presence of Ketones, Ketalization of Ketones and Dehalogenation of Benzyl Halides [J]. Synthetic Communications, 1999,29 (14):2501-2506.
[25]Narasimhan S., Madhavan S., Prasad K. G. A Simple Alkene-Catalyzed Reduction of Aromatic Esters to Alcohols by Zinc Borohydride [J]. Synthetic Communications,1997,27 (3):385-390.
[26]Teunissen H. T. Homogeneous Ruthenium Catalyzed Hydrogenation of Esters to Alcohols [J]. Chemical Communications,1998,13:1367-1368.
[27]Cha J. S., Brown H. C. Reaction of Aluminum Hydride-triethylamine Complex with Selected Organic Compounds Containing Representative Functional Groups [J]. Journal of Organic Chemistry,1993,58 (15):3974-3979.
[28]Narasimhan S., Madhavan S., Prasad K. G. Facile Reduction of Carboxylic Acids to Alcohols by Zinc Borohydride [J]. Journal of Organic Chemistry,1995,60 (16):5314-5315.
[29]Ravikumar K. S., Chandrasekaran S. Reaction of Diisopoxytitanium (111) Tetrahydroborate with Selected Organic Compounds Containing Representative Functional Groups [J]. Journal of Organic Chemistry,1996,61 (3):826-830.
[30]Kokotos G., Noula C. Selective One-Pot Convertion of Carboxylic Acids into Alcohols [J]. Journal of Organic Chemistry,1996,61 (20):6994-6996.
[31]http://baike.baidu.com/view/77542.htm
[32]王敏.苯甲醛的生产技术及市场概述[J].精细化工原理及中间体,2005,6：15-18.
[33]樊春玲,刘文明.甲苯选择氧化制苯甲醛的研究进展[J].化工时刊,2008,22(9)：61-67.
[34]缪伶,朱宪.苯甲醛绿色化生产进展[J].上海大学学报自然科学版,2002,8(4)：333.340.
[35]王旭涛.金属卟啉选择性催化空气氧化甲苯制备苯甲醛与苯甲醇研究[D].长沙,湖南大学,2004.
[36]曹志红,刘文明,项学明. La-OMS-2催化剂催化甲苯氧化制苯甲醛[J].石油化工,2006,35(11)：1069-1073.
[37]Borgaonkar H. V., Raverkar S. R., Chandalia S. B. Liquid Phase Oxidation of Toluene to Benzaldehyde by Air [J]. Ind. Eng. Chem. Prod. Res. Dev.,1984,23 (3):455-458.
[38]徐华龙,沈伟,潘欣蔚,项一非.苯甲酸气相加氢合成无氯苯甲醛用MnOx/Al2O3催化剂[J].催化学报,1997,18(5)：384-387.
[39]Yokoyama T., Setoyama T., Fujita N., Nakajima M., Maki T., Fujii K. Novel Direct Hydrogenation Process of Aromatic Carboxylic Acids to the Corresponding Aldehydes with Zirconia Catalyst [J]. Applied Catalysis A:General,1992,88 (2):149-161.
[40]王文英,刘伟,丁克强,顾登平.间接电氧化法合成苯甲醛[J].现代化工,1996,6：33-35.
[41]卢文庆,蔡政,李国栋,邓海山,程宝荣.均匀设计法研究甲苯间接电氧化合成苯甲醛[J].精细化工,2000,17：31-33.
[42]Abramovici S., Neumann R., Sasson Y. Sodium Hypochlorite as Oxidation in Phase Transfer Catalytic Systems:Part Ⅱ. Oxidation of Aromatic Alcohols [J]. Journal of Molecular Catalysis,1985,29 (3):299-303.
[43]Do J. S., Chou T. C. Anodic Oxidation of Benzyl Alcohol to Benzaldehyde in the Presence of both Redox Mediator and Phase Transfer Catalyst [J]. Journal of Applied Electrochemistry, 1989,19 (6):922-927.
[44]http://baike.baidu.com/view/123351.htm
[45]张丽君.苯甲酸生产工艺及进展[J].金陵石油化工,1992,4：30-34.
[46]吴鑫干,陈舒伐.苯甲酸的合成和精制[J].现代化工,2000,20(8)：10-14.
[47]邵坚,马全生,郭法寅.常压法甲苯液相氧化制苯甲酸的研究[J].华北水利水电学院学报,1993,2：67-71.
[48]王忠元,张艳熹.甲苯液相空气氧化制苯甲酸[J].黑龙江石油化工,1996,1：1-3.
[49]柳艳修,宋华,王宝辉.甲苯直接氧化制苯甲醛研究进展[J].工业催化,2005,13(2)：24-28.
[50]Subrahmanyam C., Louis B., Rainone F., Viswanathan B., Renken A., Varadarajan T. K. Catalytic Oxidation of Toluene with Molecular Oxygen over Cr-substituted Mesoporous Materials [J]. Applied Catalysis A:General,2003,241:205-215.
[51]Subrahmanyam C., Louis B., Rainone F., Viswanathan B., Renken A., Varadarajan T. K. Partial Oxidation of Toluene by O2 over Mesoporous Cr-AlPO [J]. Catalysis Communications,2002,3: 45-50.
[52]Zahedi-Niaki M. H., Javaid Zaidi S. M., Kaliaguine S. Comparative Study of Vanadium Aluminophosphate Molecular Sieves VAPO-5,-11,-17 and -31 [J]. Applied Catalysis A: General,2000,196:9-24.
[53]Whittington B. I., Anderson J. R. Nature and Activity of Some Vanadium Catalysts [J]. J. Phys. Chem.,1993,97:1032-1041.
[54]Lopez Nieto J. M. Microporous and Mesoporous Materials with Isolated Vanadium Species as Selective Catalysts in the Gas Phase Oxidation Reactions [J]. Topic in Catalysis,2001,15 (2-4): 189-194.
[55]Loder D. J. Catalytic Oxidaton of Alkyl Substituted Aromatic Compounda, as in the Production of Benzoic Acid from Toluene [P]. US 2245528,1938.
[56]Messina G. Upgrade Toluene to Benzoic Acid [J]. Petrochemical Developments,1964,43 (11): 191-192.
[57]唐盛伟.甲苯液相空气氧化反应过程研究[D].成都,四川大学,2005.
[58]Saffer A., Roberts B. Preparation of Aromatic Polycarboxylic Acid [P]. US 2833816 (A),1985.
[59]Partenheimer W. Methodology and Scope of Metal/bromide Autoxidation of Hydrocarbons [J]. Catalysis Today,1995,23:69-158.
[60]化工百科全书编委会.化工百科全书[M].北京：化学工业出版社,1990,1：447.
[61]Trost B. M. The Atom Economy-a Search for Synthetic Efficiency [J]. Science,1991,254 (5037):1471-1477.
[62]Anastas R. T., Warner J. C. Green Chemistry:Theory and Practice [M]. New York:Oxford University Press,1998,30.
[63]赵劲松,雷庆英.甲苯经苯甲酸制苯酚[J].四川化工,1989,3：39-43.
[64]张帅.醋酸钴和金属卟啉复合催化甲苯氧化研究[D].长沙,湖南大学,2007.
[65]张祥富,时效天.甲苯常压催化氧化制苯甲酸及其它芳烃的氧化反应的研究[J].合成化学,1998,6(4)：433-437.
[66]Partenheimer W. Catalysis of Organic Reaction [M]. New York:Marcel Dekker,1990.
[67]成有为.MC工艺烃类液相催化氧化过程的研究[D].杭州,浙江大学,2004.
[68]王丽军.PX氧化动力学研究及氧化反应器模拟[D].杭州,浙江大学,2001.
[69]谢刚,成有为,李希.对二甲苯液相氧化催化机理[J].聚酯工业,2002,15(4)：1-4.
[70]Chester A. W., Scott E. J. Y, Landis P. S. Zirconium Cocatalysis of the Cobalt-catalyzed Autoxidation of Alkylaromatic Hydrocarbons [J]. Journal of the Catalysis,1977,46:308.
[71]Zuo X. B., Sabramaniam B., Busch D. H. Liquid-Phase Oxidation of Toluene and p-toluic Acid under Mild Conditions:Synergistic Effects of Cobalt, Zirconium, ketones, and Carbon Dioxide [J]. Ind. Eng. Chem. Res.,2008,47:546-552.
[72]Bezhanishvili G. S., Digurov N. G., Lebedev N. N., et al. Kinetics of the Oxidation of Toluene over a Cobalt Bromide Catalyst with the Addition of Zirconyl Chloride [J]. Trans. Kinet. Katal, 1983,24(4):1000.
[73]Park S. E., Yoo J. S., Jun K. W., Raju D. B., Kim Y. H. Method for Preparing Aromatic Carboxylic Acids from Alkylaromatics by Liquid-phase Oxidation [P]. US 6476257,2002.
[74]Partenheimer W. The Effect of Zirconium in Metal/bromide Catalysts during the Autoxidation of p-xylene Part]. Activation and Changes in Benzaldehyde Intermediate Formation [J]. Journal of Molecular Catalysis A:Chemical,2003,206:105-119.
[75]Partenheimer W. The Effect of Zirconium in Metal/bromide Catalysts on the Autoxidation of p-xylene Part Ⅱ. Alternative Metals to Zirconium and the Effect of Zirconium on Manganese (IV) Dioxide Formation and Precipitation with Pyromellitic acid [J]. Journal of Molecular Catalysis A:Chemical,2003,206:131-144.
[76]Jhung S. H., Park Y. S. Precipitation of Manganese in the p-Xylene Oxidation with Oxygen-Enriched Gas in Liquid Phase [J]. Bull. Korean. Chem. Soc.,2002,23 (3):369-373.
[77]胡兴邦.绿色空气氧化催化剂的设计、合成及应用[D].杭州,浙江大学,2007.
[78]http://baike.baidu.com/view/122795.htm
[79]沈秋婵.离子液体支载的催化剂在三甲酚氧化反应中的应用[D].杭州,浙江大学,2008.
[80]户安军,吕春绪,李斌栋,霍婷.对氯甲苯选择性氧化新催化体系研究[J].有机化学,2006,26(8)：1083-1086.
[81]李志刚,陈丽,邓立生,李贤均.对硝基甲苯的液相催化氧化研究[J].化学研究与应用,2001,13(6)：661-664.
[82]范谦,黎耀忠,程溥明,胡家元,李贤均.环已烯烯丙位氧化研究[J].化学研究与应用,2001,13(5)：557-559.
[83]刘长辉.紫罗兰酮的烯丙位选择性氧化反应方法与工艺研究[D].长沙,中南大学,2006.
[84]王丽娜,陆维敏,吕重青,鲁越青.异戊二烯脱氢环氧化的研究[J].催化学报,2002,23(2)：121-124.
[85]Dell'Anna M. M., Mastrorilli P., Nobile C. F. Aerobic Oxidation of Sulfides Catalysed by Cobalt(Ⅱ) Complexes under Homogeneous and Heterogeneous Conditions [J]. Journal of Molecular Catalysis A:Chemical,1996,108:57-62.
[86]Dell'Anna M. M., Mastrorilli P., Nobile C. F., Lopez L. Aerobic Oxidation of a-Hydroxyketones Catalysed by Cobalt(Ⅱ) and Iron(Ⅲ) Complexes under Homogeneous and Heterogeneous Conditions [J]. Journal of Molecular Catalysis A:Chemical,1996,111:33-36.
[87]熊永莲,李静,杨向光,吴越Fe(acac)3/phen/O2体系中苯甲醇的选择氧化[J].石油化工,2004.33：1423-1424.
[88]Matienko L. I., Mosolova L. A. Oxidation of Ethyl benzene with Dioxygen in the Presence of Iron(Ⅲ) Tris(acetylacetonate)-Based Catalytic Systems:1. Mechanism of Ethylbenzene Oxidation with Dioxygen Catalyzed by Fe(Ⅲ)(acac)3 [J]. Kinetics and Catalysis,2005,46 (3): 328-333.
[89]Kobayashi H., Yamanaka I. High Production of Adamantane Oxygenates in Propionic Acid Using VO(acac)2 and Eu(OTf)3 with O2 [J]. Journal of Molecular Catalysis A:Chemical,2008, 294:43-50.
[90]Kobayashi H., Yamanaka I. Oxidation of Adamantane with O2 by VO(acac)2 and Reactivity of Active Species in Acetic Acid [J]. Journal of Molecular Catalysis A:Chemical,2008,294: 37-42.
[91]Lattanzi A., Senatore A., Massa A., Scettri A. Novel Highly Regioselective VO(acac)2/TBHP Mediated Oxidation of o-Alkenyl Phenols to o-Hydroxybenzyl Ketones [J]. J. Org. Chem., 2003,68:3691-3694.
[92]Csanyi L. J., Jaky K.., Galbacs G. Oxidation of Hydrocarbons by O2 in the Presence of VO(acac)2 as Catalyst [J]. Journal of Molecular Catalysis A:Chemical,2002,179:65-72.
[93]http://baike.baidu.com/view/2309455.htm
[94]Ishii Y., Sakaguchi S., Iwahama T. Innovation of Hydrocarbon Oxidation with Molecular Oxygen and Related Reactions [J]. Adv. Synth. Catal.,2001,343:393-427.
[95]Ishii Y, Sakaguchi S. A New Strategy for Alkane Oxidation with O2 Using N-hydroxyphthalimide (NHPI) as a Radical Catalyst [J]. Catalysis Surveys from Japan,1999,3: 27-35.
[96]Ishii Y A Novel Catalysis of N-hydroxyphthalimide (NHPI) Combined with Co(acac)n (n=2 or 3) in the Oxidation of Organic Substrates with Molecular Oxygen [J]. Journal of Molecular Catalysis A:Chemical,1997,117:123-137.
[97]Ishii Y., Iwahama T., Sakaguchi S., Nakayama K., Nishiyama Y. Alkane Oxidation with Molecular Oxygen Using a New Efficient Catalytic System:N-hydroxyphthalimide (NHPI) Combined with Co(acac)n (n=2 or 3) [J]. J. Org. Chem.,1996,61:4520-4526.
[98]Ishii Y., Kato S., Iwahama T., Sakaguchi S. Hydroxylation of Polycyclic Alkanes with Molecular Oxygen Catalyzed by N-Hydroxyphthalimide (NHPI) Combined with Transition Metal Salts [J]. Tetrahedron Letters,1996,37 (28):4993-4996.
[99]Iwahama T., Syojyo K., Sakaguchi S., Ishii Y. Direct Convertion of Cyclohexane into Adipic Acid with Molecular Oxygen Catalyzed by N-hydroxyphthalimide (NHPI) Combined with Mn(acac)2 and Co(OAc)2 [J]. Organic Process Research & Development,1998,2:255-260.
[100]Figiel P. J., Sobczak J. M. Aerobic Oxidation of Alcohols and Alkylaromatics with Dioxygen Catalysed by N-hydroxyphthalimide with Vanadium Co-catalysts [J]. New J. Chem.,2007,31: 1668-1673.
[101]Figiel P. J., Sobczak J. M., Ziolkowski J. J. New Efficient Aerobic Oxidation of Some Alcohols with Dioxygen Catalysed by N-hydroxyphtalimede with Vanadium Co-catalysts [J]. Chem. Commun.,2004,244-245.
[102]卓广澜,赵卫娟,姜玄珍.甲苯氧化制苯甲酸的新催化体系[J].有机化学,2004,24(8)：962-965.
[103]方亚辉,户安军,李斌栋,吕春绪.NHPI/过渡金属催化甲苯氧化制苯甲酸[J].化工进 展,2006,25(11)：1358-1361.
[104]葛凤燕,赵继全,郑岩,户秋义.p.二酮钴配合物催化空气氧化二苯甲醇反应的研究[J].分子催化,2003,17(4)：259-263.
[105]江文辉,周亚平,唐瑞仁,李菲.N.羟基邻苯二甲酰亚胺/Co(acac)2催化的α-紫罗兰酮的氧化反应[J].应用化学,2009,26(11)：1305-1309.
[106]谭新良,黎艳玲,陈雄,朱卓越等.N.羟基邻苯二甲酰亚胺催化分子氧氧化合成4-氧代-β-紫罗兰酮[J].香料香精化妆品,2010,3：3-5.
[107]Maurya M. R., Arya A., Adao P., Pessoa J. C. Immobilisation of Oxovanadium (Ⅳ), Dioxomolybdenum (Ⅵ) and Copper (Ⅱ) Complexes on Polymers for the Oxidation of Styrene, Cyclohexene and Ethylbenzene [J]. Applied Catalysis A:General,2008,351: 239-252.
[108]方钊,唐瑞仁,黄可龙,张瑞荣.咪唑修饰硅胶负载乙酰丙酮钴(II)催化分子氧氧化单萜烯研究[J].高等学校化学学报,2009,30(9)：1748-1753.
[109]Zavoianu R., lonescu R., Pavel O. D., Birjega R., Angelescu E. Comparison between Me" Mg/Al Hydrotalcites and Hydrotalcite-Supported Me (Ⅱ) Acetylacetonates (Me (Ⅱ)=Co, Cu or Ni) Catalysts for the Epoxidation of Cyclohexene with Molecular Oxygen [J]. Applied Clay Science,2011.52:1-10.
[110]Hu Q., Zhao J. Q. Wang Y. J., Zhu L. D., Li M. Q., Li G. H., Wang Y., Ge F. Y. Sol-gel Encapsulated Cobalt (Ⅲ) Acetylacetonate for Air Oxidation of Penicillin Derivatives [J]. Journal of Molecular Catalysis A:General,2003,200:271-277.
[111]李汝雄.绿色溶剂一离子液体的合成与应用[M].北京：化学工业出版社,2004.
[112]Miao W. S., Chan T. H. Ionic-Liquid-Supported Synthesis:A Novel Liquid-Phase Strategy for Organic Synthesis [J]. Acc, Chem, Res.,2006,39:897-908.
[113]Sing K. S. W., Everett D. H., Haul R. A. W., Moscow L., Pierotti R. A., Ronquerol J., Wska S. Reporting Physisorption Data for Gas/Solid Systems with Special Reference to the Determination of Surface Area and Porosity [J]. Pure ppl. Chem.1985,57:603-619.
[114]Beck J. S. Vartuli J. C. Roth W. J., Leonowicz M. E. Kresge C. T., Schmitt K. D., Chu C. T. W. Olson D. H., Sheppard E. W., Cullen S. C. Higgins J. B., Schlenker J. L. A New Family of Mesoporous Molecular-Sieves Prepared with Liquid-Crystal Template [J]. J. Am. Chem. Soc.1992,114:10834-10843.
[115]Kresge J. S., Leonowicz M. E., Roth W. J., Vartuli J. C.,Beck J. S. Ordered Mesoporous Molecular Sieve Synthesized by a Liquid-Crystal Template Mechanism [J]. Nature (London), 1992,359:710-712.
[116]Monnier A., Schuth F., Huo Q. Cooperative Formation of Inorganic-Organic Interfaces in the Synthesis of Silicate Mesostructure [J]. Science,1993,261:1299-1303.
[117]Bagshaw S. A., Prouzet E., Pinnavaia T. J. Templating of Molecular Sieves by Nonionic Polyethylene Oxide Surfactant [J]. Science,1995,269:1242-1244.
[118]Tanev P. T., Pinnavaia T. J. A Neutral Templating Route to Mesoporous Molecular Sieves [J]. Science,1995,267:865-867.
[119]Tanev P. T., Pinnavaia T. J. Biomimetic Templating of Porous Lamellar Silicas by Vesicular Surfactant Assemblies [J]. Science,1996,271 (5253):1267-1269.
[120]Bagshaw S. A., Prouzet E., Pinnavaia T. J. Templating of Mesoporous Molecular-Sieves by Nonionic Polyethylene Oxide [J]. Science,1995,269 (5228):1242-1244.
[121]Huo Q., Margolese D., Ciesla U., Feng P., Sieger P., Leon R., Petroff P., Schuth F., Stucky G. D. Generalized Synthesis of Periodic Surfactant Inorganic Composite-Materials [J]. Nature, 1994,368:317-319.
[122]Huo Q., Leon R., Petrof P. M.f, Stucky G. D. Mesostructure Design with Gemini Surfactant-Supercage Formation in a 3-Dimensional Hexagonal Array [J]. Science,1995,268: 1324-1327.
[123]Zhao D., Feng J., Huo Q., Melosh N., Fredrickson G. H., Chmelka B. F, Stucky G. D. Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores [J]. Science,1998,279:548-552.
[124]Zhao D., Huo Q., Feng J., Chmelka B. F., Stucky G. D. Nonionic Triblock and Star Diblock Copolymer and Oligomeric Surfactant Syntheses of Highly Ordered, Hydrothermal Stable, Mesoporous Silica Structures [J]. J. Am. Chem. Soc.,1998,120:6024-6036.
[125]李瑛Al-SBA-15和Fe-SBA-15介孔材料的合成、表征及催化性能研究[D].大连,中国科学院大连化学物理研究所,2005.
[126]徐如人,庞文琴等.分子筛与多孔材料化学[M].北京：科学出版社,2004,616.
[127]张微,徐恒泳,毕亚东,李文钊.介孔分子筛SBA-15的改性研究进展[J].化工进展,2007,26(2)：152-157.
[128]郭昌文.环戊烯合成戊二醛催化新材料的研究[D].上海,复旦大学,2003.
[129]Grieken R. V., Escola J. M., Moreno J., Rodriguez R. Direct Synthesis of Mesoporous M-SBA-15 (M=Al, Fe, B, Cr) and Application to 1-hexene Oligomerization [J]. Chemical Engineering Journal,2009,155:442-450.
[130]Luz Jr G. E., Lima S. H., Melo A. C. R., Araujo A. S., Fernandes Jr V. J. Direct Synthesis and Characterization of LaSBA-15 Mesoporous Molecular Sieves [J]. J. Mater. Sci.,2010,45: 1117-1122.
[131]Lizama L. Y., Klimova T. E. SBA-15 Modified with Al, Ti, or Zr as Supports for Highly Active NiW Catalysts for HDS [J]. J. Mater. Sci.,2009,44:6617-6628.
[132]Chen S. Y., Tsai H. D., Chuang W. T., Lee J. J., Tang C. Y., Lin C. Y., Cheng S. Direct Preparation of Thermally Stable Sn-Incorporated SBA-15 Mesoporous Materials in the Self-Generated Acidic Environment [J]. J. Phys. Chem. C.,2009,113:15226-15238.
[133]Lou Z. S., Wang R. H., Sun H., Chen Y., Yang Y. H. Direct Synthesis of Highly Ordered Co-SBA-15 Mesoporous Materials by the pH-adjusting Approach [J]. Microporous and Mesoporous Materials,2008,110:347-354.
[134]Ying F., Li J. H., Huang C. J., Weng W. Z., Wan H. L. Direct Synthesis and Superior Catalytic Performance of V-containing SBA-15 Mesoporous Materials for Oxidative Dehydrogenation of Propane [J]. Catalysis Letters,2007,115 (3-4):137-142.
[135]Selvaraj M., Lee T. G. Direct Synthesis of Well-Ordered and Unusually Reactive MnSBA-15 Mesoporous Molecular Sieves with High Manganese Content [J]. J. Phys. Chem. B.,2006, 110:21793-21802.
[136]Zhang W. H., Lu J. Q., Han B., Li M. J., Xiu J. H., Ying P. L., Li C. Direct Synthesis and Characterization of Titanium-Substituted Mesoporous Molecular Sieve SBA-15 [J]. Chem. Mater.,2002,14:3413-3421.
[137]Chen Y. Y., Huang Y. L., Xiu J. H., Han X. W., Bao X. H. Direct Synthesis, Characterization and Catalytic Activity of Titanium-Substituted SBA-15 Mesoporous Molecular Sieves [J]. Applied Catalysis A:General,2004,273:185-191.
[138]Wang L. P., Kong A. G, Chen B., Ding H. M., Shan Y. K., He M. Y. Direct Synthesis, Characterization of Cu-SBA-15 and High Catalytic Activity in Hydroxylation of Phenol by H2O2 [J]. Journal of Molecular Catalysis A:Chemical,2005,230:143-150.
[139]Vinu A., Sawant D. P., Ariga K., Hossain K. Z., Halligudi S. B., Hartmann M., Nomura M. Direct Synthesis of Well-Ordered and Unusually Reactive FeSBA-15 Mesoporous Molecular Sieves [J]. Chem. Mater.,2005,17:5339-5345.
[140]Li Y, Feng Z. C., Lian Y. X., Sun K. Q., Zhang L., Jia G. Q., Yang Q. H., Li C. Direct Synthesis of Highly Ordered Fe-SBA-15 Mesoporous Materials under Weak Acidic Conditions [J]. Microporous and Mesoporous Materials,2005,84:41-49.
[141]Li F. X., Yu F., Li Y. L., Li R. F., Xie K. C. Direct Synthesis of Zr-SBA-15 Mesoporous Molecular Sieves High Zirconium Loading:Characterization and Catalytic Performance after Sulfated [J]. Microporous and Mesoporous Materials,2007,101:250-255.
[142]杨丽娜,亓玉台,袁兴东等.磷钨酸改性介孔分子筛SBA-15催化剂的酸性及水热稳定性的研究[J].石油化工,2005,34(3)：222-225.
[143]张雪峥,乐英红,高滋PW/SBA-15负载型催化剂的性能研究[J].高等学校化学学报,2001,22(7)：1169-1172.
[144]Liu Q. Y., Wu W. L., Wang J., et al. Characterization of 12-tungstophosphoric Acid Impregnated on Mesoporous Silica SBA-15 and its Catalytic Performance in Isopropylation of Naphthalene with Isopropanol [J]. Microporous and Mesoporous Materials,2004,76: 51-60.
[145]Yang L. N., Qi Y. T., Yuan X. D., et al. Direct Synthesis, Characterization and Catalytic Application of SBA-15 Containing Heteropolyacid H3PW12O40 [J]. J. Mol. Catal. A: Chemical,2005,229:199-205.
[146]Rao P. M., Wolfson A., Kababya S., et al. Immobilization of Molecular H3PW12O40 Heteropolyacid Catalyst in Alumina-Grafted Silica-Gel and Mesostructured SBA-15 Silica Matrices [J]. J. Catal.,2005,232:210-225.
[147]袁兴东,沈健,李国辉,等.SBA.15介孔分子筛表面的磺酸基改性及其催化性能[J].催化学报,2002,23(5)：435-438.
[148]皇艳蕾,陈杨英,刘秀梅,等.苯基改性的中孔分子筛SBA-15的合成及其磺化[J].催化学报,2004,25(5)：413-416.
[149]Yang L. M., Wang Y. J., Luo G. S., et al. Functionalization of SBA-15 Mesoporous Silica with Thiol or Sulfonic Acid Groups under the Crystallization Conditions [J]. Micropor. Mesopor. Mater.,2005,84:275-282.
[150]Reddy S. S., Raju B. D., Kumar V. S., et al. Sulfonic Acid Functionalized Mesoporous SBA-15 for Selective Synthesis of 4-phenyl-1,3-dioxane [J]. Catal. Commun..,2007,8: 261-266.
[151]顾晓利,何明,史以俊,罗振扬,姚春才.镧改性SBA-15分子筛的制备及对甲苯催化氧化性能的研究[J].天然气化工,2010,35(5)：29-33.
[152]杜建亮,刘丹,桂建舟,张晓彤,宋丽娟,孙兆林Cu/SBA-15催化苯甲醇氧化制苯甲醛[J].石油化工高等学校学报,2006,19(1)：13-16.
[153]Reddy S. S., Raju B. D., Padmasri A. H., Prakash P. K. S., Rao K. S. R. Novel and Efficient Cobalt Encapsulated SBA-15 Catalysts for the Selective Oxidation of Cyclohexane [J]. Catalysis Today,2009,141:61-65.
[154]Li L., Li H., Jin C., Wang X. C., Ji W. J., Pan Y., Knaap T. V. D., Stoel R. V. D., Au C. T. Surface Cobalt Silicate and CoOx Cluster Anchored to SBA-15:Highly Efficient for Cyclohexane Partial Oxidation [J]. Catal Lett.,2010,136:20-27.
[155]Selvaraj M., Park D. W., Ha C. S. Well Ordered Two-Dimensional Mesoporous CeSBA-15 Synthesized with Improved Hydrothermal Stability and Catalytic Activity [J]. Microporous and Mesoporous Materials,2011,138:94-101.
[156]Raju G., Reddy P. S., Ashok J., Reddy B. M., Venugopal A. Solvent-Free Aerobic Oxidation of Ethylbenzene over Supported Ni Catalysts Using Molecular Oxygen at Atmospheric Pressure [J]. Journal of Natural Gas Chemistry,2008,17:293-297.
[157]Cui H. T., Zhang Y., Qiu Z. G., Zhao L. F., Zhu Y L. Synthesis and Characterization of Cobalt-Substituted SBA-15 and Its High Activity in Epoxidation of Styrene with Molecular Oxygen [J]. Applied Catalysis B:Environmental,2010,101:45-53.
[158]Selvaraj M., Kawi S. Direct Synthesis of Mesoporous CrSBA-15 Catalyst and Its High Activity and Selectivity for Oxidation of Anthracene [J]. Microporous and Mesoporous Materials,2007,101:240-249.
[159]Howarth J. Oxidation of Aromatic Aldehydes in the Ionic Liquid [bmim]PF6 [J]. Tetrahedron Letters,2000, (41):6627-6629.
[160]刘耀华,崔鹏,孙靖等.离子液体中芳烃侧链分子氧催化氧化反应研究[J].高等学校化学学报,2006,27(12)：2314-2318.
[161]Seddon K. R., Stark A. Selective Catalytic Oxidation of Benzyl Alcohol and Alkylbenzenes in Ionic Liquids [J]. Green Chemistry,2002,4:119-123.
[162]Haas G. R., Kolis J. W. Oxidation of Alkenes in Supercritical Carbon Dioxide Catalyzed by Molybdenum Hexacarbonyl [J]. Organometallics,1998,17:4454-4460.
[163]Zhu J., Tsang S. C. Micellar Catalysis for Partial Oxidation of Toluene to Benzoic Acid in Supercritical CO2:Effects of Fluorinated Surfactants [J]. Catalysis Today,2003,81:673-679.
[164]Holliday R. L., Jong B. Y. M, Kolis J. W. Organic Synthesis in Subcritical Water Oxidation of Alkyl Aromatics [J]. Journal of Supercritical Fluids,1998,12:255-260.
[165]Guo C. C., Li Q.u, Wang X. T., Hu H. Y. Selective Liquid Phase Oxidation of Toluene with Air [J]. Applied Catalysis A:General,2005,282:55-59.
[166]Bastock T. W., Clark J. H., Martin K., Trenbirth B. W. Mild, Solvent-Free Oxidation of Toluene and Substituted Toluenes to Their Benzoic Acids Using Carboxylic Acid-Promoted Heterogeneous Catalysis [J]. Green Chemistry,2002,4:615-617.
[167]Gao J., Tong X. L., Li X. Q., Miao H., Xu J. The Efficient Liquid-phase Oxidation of Aromatic Hydrocarbons by Molecular Oxygen in the Presence of MnCO3 [J]. Journal of Chemical Technology and Biotechnology,2007,82:620-625.
[168]Falgayrac G., Savall A. Electrochemical Activation of the Catalytic Effect of Cobalt in Autoxidation of Toluene in Acetic Acid [J]. Journal of Applied Electrochemistry,1999,29: 253-258.
[169]李德江,孙碧海,李斌.相转移催化氧化合成苯甲酸[J].化学研究与应用,2002,14(6)：753.7555.
[170]杨芝萍,郭孟萍.相转移催化剂在甲苯氧化反应中的应用[J].江西教育学院学报(自然科学),1998,19(6)：37-38.
[171]张彰,朱宪,张彬.非均相Mn(11]).甲苯氧化反应的动力学[J].高校化学工程学报,2002,16(2)：174-179.
[172]Satrio J. A. B., Doraiswamy I. K. Production of Benzyldehyde:a Case Study in a Possible Industrial Application of Phase-Transfer Catalysis [J]. Chemical Engineering Journal,2001, 82:43-56.
[173]Roby A. K., Kingsley J. P. Enhanced Oxidation of Organic Chemical [P]. US 5536875 (A), 1996.
[174]Bukharkina T. V., Digurov N. G. Kinetics of Aerobic Liquid-Phase Oxidation of Organic Compounds [J]. Organic Process Research & Development,2004,8:320-329.
[175]Hoorn J. A. A., Alsters P. L., Versteeg G. F. A Kinetic Model for Toluene Oxidation Comprising Benzylperoxy Benzoate Ester as Reactive Intermediate in the Formation of Benzaldehyde [J]. International Journal of Chemical Reactor Engineering,2005,3:1-19.
[176]Morimoto T., Ogata Y. Kinetics of the Autoxidation of Toluene Catalysed by Cobaltic Acetate [J]. J. Chem. Soc (B),1967,62-66.
[177]Helfferich F. G. Kinetics of Homogeneous Multistep Reactions [M]. R.G. Compton & G. Hancock Eds., Elsevier, Amsterdam,2001,38:283-286.
[178]Scott E. J. Y., Chester A. W. Kinetics of the Cobalt-catalyzed Autoxidation of Toluene in Acetic Acid [J]. J. Phys. Chem.,1972,76(11):1520-1524.
[179]Kagami K. Anomalous Effect of the Concentration of Metal-salt Catalysts in the Liquid-phase Oxdation of p-xylene and Toluene [J]. Bull. Chem. Soc. Jap.,1968,41 (7):1552-1557.
[180]Bhattacharya D., Guha D. K., Roy A. N. Liquid Phase Air Oxidation of Toluene to Benzoic Acid. Ⅱ. Kinetics and Mechanism [J]. Chem. Age. India.,1973,24 (2):87-90.
[181]Quiroga O. D., Gottifredi J. C., Capretto de Castillo M. E. Liquid Phase Catalytic Toluene Oxidation, Formulation of a Kinetic Model [J]. Rev. Latinoam. Ing. Quim. Quim. Apl.,1980, 10:77-88.
[182]Gadelle C., Clement G. Etude cinetique de l'oxydation radicalaire par l'oxygene des alcoylaromatiques en phase liquid [J]. Bull. Soc. Chim. De France,1968,1:44-54.
[183]Korthals Altes F. W., van den Berg P. J. Kinetics of the Autoxidation of Ethylbenzene [J]. Receuil,1966,85:538-544.
[184]Ivanov S. K., Kalitchin Z. H. D., Hinkova M. K. Direct Oxidation of Toluene to Benzaldehyde in the Presence of N-bromosuccinimide [J]. Oxidation Communications,1983, 3 (2):89-102.
[185]Hendriks C. F., van Beek H. C. A., Heertjes P. M. The Oxidation of Substituted Toluenes by Cobalt(Ⅲ) Acetate in Acetic Acid Solution [J]. Ind. Chem. Prod. Res. Dev.,1978a,17 (3): 256-260.
[186]Russell G. A. Deuterium-isotope Effects in the Autoxidation of Aralkyl Hydrocarbons. Mechanism of the interaction of peroxy radicals [J]. J. Am. Chem. So.c,1957,79:3871-3877.
[187]肖春妹,李国清.甲苯液相空气催化氧化技术研究进展[J].化工生产与技术,2006,13(2)：46-50.
[188]Borgaonkar Hemant V, Raverkar Sanjay R, Chandalla Sampatral B. Liquid Phase Oxidation of Toluene to Benzaldehyde by Air [J]. Ind. Eng. Chem. Prod. Res. Dev.,1984,23:455-458.
[189]Hay Llan S, Blanchard Harry S. Autoxidation Reactions Catalyzed by Cobalt Acetate Bromide [J]. Canadian Journal of Chemistry,1965,43:1306-1317.
[190]Hendriks Charles F, van Beck Hendfik C A, Heertjes Pleter M. The Oxidation of Substituted Toluenes by Cobalt(Ⅲ) Acetate in Acetic Acid Solution [J]. Ind. Eng. Chem. Prod. Res. Dev., 1978,17 (3):256-260.
[191]唐盛伟,梁斌,吴潘,张全忠,刘长军.甲苯液相氧化反应过程动力学的研究[J].反应工程与工艺,2005,4：333-338.
[192]刘含茂.甲苯液相空气氧化法制苯甲醛[D].长沙：湖南大学,2003.
[193]邹隐文,顾雄毅,程宗泽,于广欣,王志侃.甲苯液相氧化动力学研究[J].化学工程,2007,35(9)：33-36.
[194]张玉坤,李初福,任世明,何小荣,陈丙珍.甲苯液相催化氧化过程稳态模拟[J].化工进展,2006,25(12)：1481-1483.
[195]Hoorn J. A. A., Soolingen J. V., Versteeg G. F. Modelling Toluene Oxidaton Incorporation of Mass Transfer Phenomena [J]. Chemical Engineering Research and Design,2005,83 (A2): 187-195.
[196]古凤才,王金明,刘荫藩,叶文强,孙淑梅.西拂碱钴络合物对亚甲基的催化氧化研究[J].天津大学学报,1998,31(5)：666-670.
[197]陈甘棠.化学反应工程(第二版)[M].北京：化学工业出版社,1990.
[198]刘建松.甲苯液相催化氧化动力学的研究[D].杭州,浙江大学,2006.
[199]陈舒伐.甲苯液相空气氧化法制苯甲醛工艺条件研究[D].长沙,湖南大学,2001.
[200]Kamiya Y., Ingold K. U. The Metal-catalyzed Autoxidation of Tetralin:Ⅳ. The Effect of Solvent and Temperature [J]. Canadian Journal of Chemistry,1964,42:2424-2433.
[201]唐盛伟.甲苯液相空气氧化反应过程研究[D].成都,四川大学,2005.
[202]Hancock E. G. Toluene, the Xylenes and Theirs Industrial Derivatives [M]. Eleservier Scientific Publishing Company. Amsterdan-Oxford New York,1982.
[203]Hanotier J., Hanotier-Bridoux M. Mechanism of the Liquid Phase Homogeneous Oxidation of Alkylaromatic Hydrocarbons by Cobalt Salts [J]. J. Mol. Catal.,1981,12:133-147.
[204]Van Der Ploeg R. E., De Kort R. W., Kooyman E. C. Intermediate Steps in Autoxidation Ⅲ. Reactions of MnⅢ Acetate in Acetic Acid with Benzene, Chlorobenzene, and Toluene [J]. Journal of Catalysis,1968,10:52-59.
[205]Heiba E. I., Dessau R. M., Koehl Jr W. J. Oxidation of Metal Salts.Ⅲ. The Reaction of Manganic Acetate with Aromatic Hydrocarbons and the Reactivity of Carboxy Methyl Radical [J].J.Am. Chem. Soc.,1969,91:138-145.
[206]Kantam M. L., Sreekanth P., Rao K. K. et al. An Improved Process for Selective Liquid-phase Air Oxidation of Toluene [J]. Catalysis Letters,2002,81 (3-4):223-232.
[207]Nair K., Sawant D. P., Shanbhag G. V., Halligudi S. B. Aerial Oxidation of Substituted Aromatic Hydrocarbons Catalyzed by Co/Mn/Br in Water-dioxane Medium [J]. Catalysis Communications,2004,5:9-13.
[208]蔡敏敏.氧气/空气液相氧化一元取代甲苯成芳香醛工艺及机理研究[D].南京,南京理工大学,2001.
[209]Chavan S. A., Halligudi S. B., Srinivas D., Ratnasamy P. Formation and Role of Cobalt and Manganese Cluster Complexes in the Oxidation of p-Xylene [J]. Journal of Molecular Catalysis A:Chemical,2000,161:49-64.
[210]Partenheimer W. The Structure of Metal/Bromide Catalysts in Acetic Acid/Water Mixtures and Its Significance in Autoxidation [J]. Journal of Molecular Catalysis A:Chemical,2001, 174:29-33.
[211]张楠,刘建松,陈纪忠.甲苯液相催化氧化反应动力学[J].化学反应工程与工艺,2008,24(1)：18-23.
[212]lchikawa Y., Yamashita G, Tokashiki, M. Yamaji T. New Oxidation Process for Production of Terephthalic Acid from p-Xylene [J]. Ind. And Eng. Chem.,1970,62:38-42.
[213]高恩君,陈盛民,葛欣喜.钴(II)、镍(II)与系列二元羧酸配合物稳定性的研究[J].沈阳化工学院学报,1995,9(1)：14-20.
[214]Kamiya Y. The Autoxidation of Tetralin Catalysed by Cobalt Salt and Sodium Bromide in Acetic Acid [J]. Tetrahedron,1966,22:2029-2038.
[215]唐盛伟,张全忠,梁斌.甲苯液相氧化过程中结垢成分的分析[J].石油化工,2004,33(4)：372-376.
[216]Tang Shengwei, Liang Bin. Scale Formation and Its Mechanism in the Liquid-Phase Oxidation of Tolene by Air [J]. Ind. Eng. Chem. Res.,2007,46:7826-7829.
[217]Shende R. V., Mahajani V. V. Kinetics of Wet Oxidation of Formic Acid and Acetic Acid [J]. Ind. Eng. Chem. Res.,1997,36:4809-4814.
[218]Shende R. V., Levee J. Wet Oxidation Kinetics of Refractory Low Molecular Mass Carboxylic Acids [J]. Ind. Eng. Chem. Res.,1999,38:3830-3837.
[219]Klinghoffer A. A., Cerro R. L., Abraham M. A. Influence of Flow Properties on the Performance of the Monolith Froth Reactor for Catalytic Wet Oxidation of Acetic Acid [J]. Ind. Eng. Chem. Res.,1998,37:1203-1210.
[220]Zhao D. Y, Sun J. Y., Li Q. Z., et al. Morphological Control of Highly Ordered Mesoporous Silica SBA-15 [J]. Chem. mater.,2000,12:275-279.
[221]王莉萍.介孔分子筛的功能化修饰及其催化性能研究[D].上海：华东师范大学,2005.
[222]Hu Longxing, Yang Xiaping, Dang Songtao. An Easily Recyclable Co/SBA-15 Catalyst: Heterogeneous Activation of Peroxymonosulfate for the Degradation of Phenol in Water [J]. Applied Catalysis B:Environmental,2011,102:19-26.
[223]Shukla Pradeep, Wang Shaobin, Sun Hongqi, Ang Hua-Ming, Tade Moses. Adsorption and Heterogeneous Advanced Oxidation of Phenolic Contaminants Using Fe Loaded Mesoporous SBA-15 and H2O2 [J]. Chemical Engineering Journal,2010,164:255-260.