涤棉织物抗紫外、抗起毛起球整理
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摘要
本课题对涤棉机织物的抗紫外线和抗起毛起球两种整理工艺进行研究,研究最佳整理工艺并实现多功能整理效果。制备TiO2水溶胶,研究了制备过程的影响因素,并对其制备条件进行了优化；将TiO2水溶胶与现有的常规抗紫外整理剂、抗起毛起球整理剂进行抗紫外和抗起毛起球单一功能的比较,选出较优的整理剂及其最佳工艺条件；研究兼具抗紫外和抗起毛起球双功能整理效果的工艺及条件。研究中采用马丁代尔起毛起球测试法来测定起毛起球等级,通过测定紫外线透过率并计算UPF值来评价织物的抗紫外线性能。
研究结果表明：采用溶胶-凝胶法制备TiO2水溶胶时,影响制备的主要因素为：钛酸四丁酯的溶剂、钛酸四丁酯与水的摩尔比、钛酸四丁酯与螯合剂的摩尔比、催化剂用量、反应时间等。采用激光粒度仪测定TiO2水溶胶的粒径分布,使用稳定时间表征TiO2水溶胶的稳定性并对其制备条件进行优化,得到最佳制备工艺。
常规整理剂中CTA-765的抗紫外性能较优,FK-833的抗起毛起球性能较优,但TiO2水溶胶的各项单一功能都要优于以上两种整理剂。对TiO2水溶胶进行抗紫外、抗起毛起球双功能整理工艺的研究,最佳工艺条件为：TiO2水溶胶用量50%,焙烘温度130℃,焙烘时间3min。经整理后,织物的UPF值可达到61,起毛起球等级可达4-5级,耐久性较好,达到了较理想的效果。
The subject systemized the two effect which including anti-ultraviolet and anti-pilling, to research the double effect of the polyester-cotton fabric in this paper. TiO2 hydrosol was prepared, the effect of preparaed process was studied and its preparation conditions were improved. Then the anti-ultraviolet or anti-pilling finishing effect was compared among TiO2 hydrosol, conventional anti-ultraviolet finishing agent and anti-pilling finishing agent. Optimum agent and its optimal technology conditions were selected. The technology and conditions of the double function finishing—anti-ultraviolet and anti-pilling were researched. The study used Martindale pilling test method to measure the pilling grade and evaluated the performance of anti-ultraviolet by measuring the ultraviolet transmittance and calculating the UPF values.
The results of the study show that:In the sol-gel methods applied to prepare TiO2 hydrosol, the effect of Ti(OBu)4 with the amount of water,the chelating agent, the catalyst and reaction time.on prepared process was studied The particle size of TiO2 hydrosol was tested by laser particle sizw analyzer,steady time was used to verify the stability of TiO2 hydrosol, and its preparation conditions were optimized to obtain the best preparation conditions.
Among the conventional finishing agent, CTA-765 has a better anti-ultraviolet performance and FK-833 has a better anti-pilling performance, but each function of TiO2 hydrosol is superior to the two agents above.Based on its double function, the best finishing conditions of TiO2 hydrosol are as follows:the amount of TiO2 hydrosol is 50%, baking temperature is 130℃, baking time is 3min. After the finishing, the UPF value of the fabric can reach 61, the pilling grade of the fabric can reach 4 to 5 level, and good durability and the ideal effect are achieved.
研究结果表明：采用溶胶-凝胶法制备TiO2水溶胶时,影响制备的主要因素为：钛酸四丁酯的溶剂、钛酸四丁酯与水的摩尔比、钛酸四丁酯与螯合剂的摩尔比、催化剂用量、反应时间等。采用激光粒度仪测定TiO2水溶胶的粒径分布,使用稳定时间表征TiO2水溶胶的稳定性并对其制备条件进行优化,得到最佳制备工艺。
常规整理剂中CTA-765的抗紫外性能较优,FK-833的抗起毛起球性能较优,但TiO2水溶胶的各项单一功能都要优于以上两种整理剂。对TiO2水溶胶进行抗紫外、抗起毛起球双功能整理工艺的研究,最佳工艺条件为：TiO2水溶胶用量50%,焙烘温度130℃,焙烘时间3min。经整理后,织物的UPF值可达到61,起毛起球等级可达4-5级,耐久性较好,达到了较理想的效果。
The subject systemized the two effect which including anti-ultraviolet and anti-pilling, to research the double effect of the polyester-cotton fabric in this paper. TiO2 hydrosol was prepared, the effect of preparaed process was studied and its preparation conditions were improved. Then the anti-ultraviolet or anti-pilling finishing effect was compared among TiO2 hydrosol, conventional anti-ultraviolet finishing agent and anti-pilling finishing agent. Optimum agent and its optimal technology conditions were selected. The technology and conditions of the double function finishing—anti-ultraviolet and anti-pilling were researched. The study used Martindale pilling test method to measure the pilling grade and evaluated the performance of anti-ultraviolet by measuring the ultraviolet transmittance and calculating the UPF values.
The results of the study show that:In the sol-gel methods applied to prepare TiO2 hydrosol, the effect of Ti(OBu)4 with the amount of water,the chelating agent, the catalyst and reaction time.on prepared process was studied The particle size of TiO2 hydrosol was tested by laser particle sizw analyzer,steady time was used to verify the stability of TiO2 hydrosol, and its preparation conditions were optimized to obtain the best preparation conditions.
Among the conventional finishing agent, CTA-765 has a better anti-ultraviolet performance and FK-833 has a better anti-pilling performance, but each function of TiO2 hydrosol is superior to the two agents above.Based on its double function, the best finishing conditions of TiO2 hydrosol are as follows:the amount of TiO2 hydrosol is 50%, baking temperature is 130℃, baking time is 3min. After the finishing, the UPF value of the fabric can reach 61, the pilling grade of the fabric can reach 4 to 5 level, and good durability and the ideal effect are achieved.
引文
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[2]李欢,孟家光.抗紫外线纺织品及其发展现状[J].纺织科技进展,2009,(1):9-11.
[3]杨志清.防紫外线织物的开发[J].现代纺织技术,2007,(3)：34-36.
[4]陈颂声.国外防紫外线技术在纺织品上的应用及奔向美公司的UV-80产品[R].北京：纺织行业生产力促进中心,2001.
[5]曾显华,刘维锦.紫外线防护织物[J].针织工业,2004,(6)：101-103.
[6]B.R. Das, S.M. Ishtiaque, R.S. Rengasamy, Ultraviolet Absorbers for Textiles[J].2010, (1):42-52.
[7]周蓉,刘杰.抗紫外线服用织物的开发研究[J].河南纺织高等专科学校学报,2002,(3)：1-3.
[8]邵苏秀,安玉山.抗紫外线纺织品的研究与评价[J].江苏纺织,2005,(6):25-27.
[9]Schindler.W.D.,Hauser.p.Chapter 14:Ultraviolet protection finishes. Chemical Finishing of Textiles[J].2004,8:157-164.
[10]康芳,张鹏飞.织物起毛起球研究现状分析与展望[J].上海纺织科技,2006,(12)：5-7.
[11]陈英.影响织物防紫外性能的因素[J].北京服装学院学报(自然科学版),2001,(2)：30-34.
[12]刘义.棉织物抗紫外线整理及其影响因素分析[D].五邑：五邑大学,2006.
[13]Dr. Nemailal Tarafder.Textiles for protection against Harmful Ultraviolet Radiation, Textile Technolog[J].2007,411-415.
[14]兰红艳.织物起毛起球的因素分析[J].上海毛麻科技,2010,(1):6-9.
[15]李彦滨,张敏,赵翠侠.织物起毛起球成因分析及解决工艺[J].针织工业,2005,(10):31-33.
[16]Rakesh Goyal, Prabhu,C.N.Anti-pilling solutions[J].Colourage,2008,9:95-97.
[17]王健宁.纺织品抗紫外整理剂的开发与应用研究[D].上海：东华大学,2006.
[18]李峥嵘,许海育.纳米材料及其在织物防紫外线中的应用[J].广西纺织科技,2003,(1):48-49.
[19]曲健健,但卫华,但年华.微胶囊技术及其在制革工业中的应用[J].中国皮革,2006,35(9)： 41-42.
[20]Park, Soo-JinKang, Yong C. Park, Ju Y. Physical Characteristics of Titania Nanofibers Synthesized by Sol-Gel and Electrospinning Techniques[J] Journal of Engineered Fabrics & Fibers (JEFF),2010,5 (1):50-56.
[21]陈晓光.溶胶一凝胶技术在棉织物抗紫外性能中的应用研究[J].化纤与纺织技术,2008,(3)：4-6.
[22]王芳辉,朱红,高苏珍.溶胶一凝胶技术的应用及研究进展[J].化工时刊,2003,17(4):4-6.
[23]李永庚,许海育.泡沫整理发泡原液组成的研究[J].印染,2008,(18):22-27.
[24]Anti-pilling finishes[M].Chemical Finishing of Textiles,2004,129-137.
[25]张平禄,张嘉璇.织物抗起毛起球新技术现状分析[J].广西轻工业,2008,(11)：92-95.
[26]周世香,赵振河.纯棉针织物抗起毛起球整理[J].印染,2004,(08):21-22.
[27]曹万里,顾志安.织物抗起毛起球整理及抗起毛起球剂ATP的应用[J].印染助剂,2003,20(2)：35-38.
[28]段新峰.抗起毛起球整理剂KD1的合成与应用研究[J].印染,2008,24:35-37.
[29]段新峰,孙占永.环保型抗起毛起球整理剂KD-1的合成与应用研究[J].2008,31(12):9-11.
[30]杜韩静,卢霜,邓东海etal.抗起毛起球整理剂DM-3761应用探讨[J].染整技术,2007,(06)：39-49.
[31]曹万里,顾志安.涤纶及其混纺织物的抗起毛起球整理[J].印染,2004,(7):31-32.
[32]Jeanette M. Cardamone, Efforts to Control Pilling in Wool/Cotton Fabrics[J].Textile Chemist and Colorist,1999,V31 (6):29-31.
[33]汪苏南.抗紫外线技术及其产品效果测试[J].北京纺织,1996,(03)：30-32.
[34]李平.抗紫外线织物测试结果的统计分析[J].印染,2001,(5):44-45.
[35]王玉.防紫外线织物的加工与检测进展[J].江苏纺织,2010,(1)：55-57.
[36]唐增荣.纺织品抗紫外线整理的研究[J].2006,(6):75-78.
[37]李志刚.起毛起球测试方法[J].印染,2004,(24)：39-40.
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