SBS改性沥青掺量测试及加工质量评价
|
摘要
现代公路交通量大,轴载重,普通沥青常难以满足高等级公路的使用要求,必须对其加以处理以提高沥青的路用性能。SBS改性沥青由于具有良好的使用性能,因此,在我国高速公路的使用日益广泛。大量研究和实践表明,SBS改性沥青中改性剂掺量及加工质量对改性沥青质量至关重要。
本文在参考国内外研究的基础上,采用理论与试验相结合的办法,主要进行了以下研究工作：通过针入度、软化点和延度等常规技术性能指标测试,对SBS改性沥青中SBS掺量与三大指标相关性进行了测试与分析；通过测定改性沥青粘温特性,采用Saal公式发现,线型SBS改性沥青的lglgη值和lg(T+273.15)的线性相关性显著；通过红外光谱分析发现,SBS中反式丁二烯可以做为测定SBS掺量的依据；最终,基于荧光显微及图像处理技术,以微观相态结构作为指标并结合短、长期老化后的性能衰变,综合评价了SBS改性沥青的加工质量。
通过上述实验结果的分析和讨论,论文总结出了SBS改性沥青掺量测试及加工质量评价方法,该方法对于管理和控制SBS改性沥青的生产质量具有重要的指导意义。
Due to high volume of traffic and heavy loads on road surfaces, ordinary asphalt is usually not qualified enough to fulfill the requirements of modern highway systems and improvements need to be implemented to enhance pavement performance of asphalt. With its widely recognized satisfactory performance, SBS modifier has become one of the most promising polymer highway pavement modifiers in China. Dosage and processing quality of the modifier are the key issues in controlling the quality of SBS modified asphalt and preserving durability of pavement.
Based on experiments and theoretical analysis, this research conducted the following works:by testing several technical performance indicators including penetration, softening point and ductility, etc, discovered that linear correlation between dosage of SBS modifier and the three indicators is poor; by using Saal formula and testing viscosity of modified asphalt under various temperatures, found that there is significant leaner correlation between lglgηof SBS modified asphalt and lg(T+273.15); through infrared spectroscopy analysis, found that trans-butadiene in SBS can be used as a basis in measuring the dosage of SBS; Based on fluorescence microscopy and image processing technology, using micro-phase structure as the indicator and combined with analysis on performance decays after long-term and short-term aging, evaluated the processing quality of SBS modified asphalt.
With results from the experiments and analysis above, this paper summarized methods in testing the dosage of SBS modified asphalt and evaluating processing quality of it. These methods are important in managing and controlling the quality of SBS modified asphalt.
本文在参考国内外研究的基础上,采用理论与试验相结合的办法,主要进行了以下研究工作：通过针入度、软化点和延度等常规技术性能指标测试,对SBS改性沥青中SBS掺量与三大指标相关性进行了测试与分析；通过测定改性沥青粘温特性,采用Saal公式发现,线型SBS改性沥青的lglgη值和lg(T+273.15)的线性相关性显著；通过红外光谱分析发现,SBS中反式丁二烯可以做为测定SBS掺量的依据；最终,基于荧光显微及图像处理技术,以微观相态结构作为指标并结合短、长期老化后的性能衰变,综合评价了SBS改性沥青的加工质量。
通过上述实验结果的分析和讨论,论文总结出了SBS改性沥青掺量测试及加工质量评价方法,该方法对于管理和控制SBS改性沥青的生产质量具有重要的指导意义。
Due to high volume of traffic and heavy loads on road surfaces, ordinary asphalt is usually not qualified enough to fulfill the requirements of modern highway systems and improvements need to be implemented to enhance pavement performance of asphalt. With its widely recognized satisfactory performance, SBS modifier has become one of the most promising polymer highway pavement modifiers in China. Dosage and processing quality of the modifier are the key issues in controlling the quality of SBS modified asphalt and preserving durability of pavement.
Based on experiments and theoretical analysis, this research conducted the following works:by testing several technical performance indicators including penetration, softening point and ductility, etc, discovered that linear correlation between dosage of SBS modifier and the three indicators is poor; by using Saal formula and testing viscosity of modified asphalt under various temperatures, found that there is significant leaner correlation between lglgηof SBS modified asphalt and lg(T+273.15); through infrared spectroscopy analysis, found that trans-butadiene in SBS can be used as a basis in measuring the dosage of SBS; Based on fluorescence microscopy and image processing technology, using micro-phase structure as the indicator and combined with analysis on performance decays after long-term and short-term aging, evaluated the processing quality of SBS modified asphalt.
With results from the experiments and analysis above, this paper summarized methods in testing the dosage of SBS modified asphalt and evaluating processing quality of it. These methods are important in managing and controlling the quality of SBS modified asphalt.
引文
[1]陈惠敏.国外聚合物改性道路沥青技术和应用动向[J].石油沥青,1992,4：59-64
[2]熊萍.SBS聚合物改性沥青技术性能及形态结构研究[D].西安：长安大学,2003
[3]尤晓(?).现代道路路基路面工程[M].北京：清华大学出版社,2004
[4]张德勤,范耀华,师洪俊.石油沥青的生产与应用[M],中国石化出版社,2001,7：2
[5]沈金安.改性沥青与SMA路面[M].北京：人民交通出版社,1999
[6]Lewandowski LH. Polymer modification of paving asphalt binders[J]. Rubber Chem Technol,1994,67(3):447-480
[7]王铁宝,沥青改性及其机理的研究[D].石家庄：河北工业大学,2006
[8]R.L.Terrel, J.L.Walter. Modified Asphalt Pavement Materials:The European Experience[J]. APT,1986:482-519
[9]杨京伟,许瑞清,鲍浪.SBS改性道路沥青[J].北京化工大学学报,1997.24(4)：38-44
[10]中华人民共和国交通行业标准.公路改性沥青路面施工技术规范[S].北京：人民交通出版社.1999
[11]王春鸣.浅谈如何改善沥青路面使用性能[J].黑龙江交通科技,2009,12：16-19
[12]于进军,SBS改性道路沥青的性能概述.石化技术,2000,7(2)：121-125
[13]张争奇.改性沥青机理及应用研究.[D].西安：西安公路交通大学,1997
[14]赵可,原健安.改性沥青机理研究(之一)[J].西安公路交通大学学报,2001.4, 21(2)：34-37
[15]原健安,赵可.改性沥青机理研究(之二)[J].西安公路交通大学学报,2001.6,21(3)：21-24
[16]Maccarrone, GHolleran and GP.Gnanasseelan. Properties of polymer modified binder and relationship to mix and pavement performance[J]. AAPT 1995
[17]徐芸青.SBS改性沥青若干性能的研究[J].新型建筑材料,2001,8
[18]Bernard Brule and Michel Maze, Application of SHRP binder tests to the characteriza-tion, structure and properties [J]. AAPT 1995
[19]沥青和聚合物改性沥青特性与沥青混凝土混合料性能的关系[C].改性沥青译文集,1992
[20]郝培文,申艳梅.SBS与沥青相容性的研究[J].西安公路交通大学学报,2001.2
[21]聚合物改性沥青胶结料的特性[C].改性沥青译文集,1992
[22]原健安,赵可.改性剂剂量与改性沥青性质[J].石油沥青,1999.12,13(4)：10-14
[23]Brule, Y.Brion, and A.Tanguy. Paving asphalt polymer blends, relationship between composition, structure and properties[J]. AAPT 1988
[24]U.Isacsson, X.Lu. Laboratory investigation of polymer modified asphalt s[J]. APPT, 1999:35-631
[25]宁永成.有机化合物结构鉴定与有机波谱学[M].北京：科学出版社,2001
[26]柯以侃.董慧茹主编.分析化学手册.第三分册.光谱分析[M].北京：化学工业出版社.1998.09：866-1122
[27]金鸣林,冯安祖,史美仁等.胜利100B沥青老化过程中官能团分析与相对分子量分布[J],南京化工大学学报,2000,22(5)：66-69
[28]Chen J.S., Huang L.S. Developing an aging model to evaluate engineering properties of asphalt paving binders[J]. Materials and Structures,2000,33:559-565
[29]李炜光,周巧英等.SBS测试方法及机理研究[J].石油沥青,2010,24(5)：1-5
[30]柯以侃.董慧茹主编.分析化学手册.第三分册.光谱分析[M].北京：化学工业出版社.1998.09：866-1122
[31]李双瑞,林青,董声雄.SBS改性沥青机理研究进展[J].高分子通报,2008,5(5)：14-17
[32]U.Johanssonnad5.Linde, Polymer modified asphalt binder Part 1, Swedish National Testing and Research Institute[R], SP Report 1991.02
[33]X.Lu and U.Isacsson.Rheological characterization of styrene-butadiene-styrene copolymer modified asphalt [J].Construction and Building Materials,1997,11(1):23-3
[2]熊萍.SBS聚合物改性沥青技术性能及形态结构研究[D].西安：长安大学,2003
[3]尤晓(?).现代道路路基路面工程[M].北京：清华大学出版社,2004
[4]张德勤,范耀华,师洪俊.石油沥青的生产与应用[M],中国石化出版社,2001,7：2
[5]沈金安.改性沥青与SMA路面[M].北京：人民交通出版社,1999
[6]Lewandowski LH. Polymer modification of paving asphalt binders[J]. Rubber Chem Technol,1994,67(3):447-480
[7]王铁宝,沥青改性及其机理的研究[D].石家庄：河北工业大学,2006
[8]R.L.Terrel, J.L.Walter. Modified Asphalt Pavement Materials:The European Experience[J]. APT,1986:482-519
[9]杨京伟,许瑞清,鲍浪.SBS改性道路沥青[J].北京化工大学学报,1997.24(4)：38-44
[10]中华人民共和国交通行业标准.公路改性沥青路面施工技术规范[S].北京：人民交通出版社.1999
[11]王春鸣.浅谈如何改善沥青路面使用性能[J].黑龙江交通科技,2009,12：16-19
[12]于进军,SBS改性道路沥青的性能概述.石化技术,2000,7(2)：121-125
[13]张争奇.改性沥青机理及应用研究.[D].西安：西安公路交通大学,1997
[14]赵可,原健安.改性沥青机理研究(之一)[J].西安公路交通大学学报,2001.4, 21(2)：34-37
[15]原健安,赵可.改性沥青机理研究(之二)[J].西安公路交通大学学报,2001.6,21(3)：21-24
[16]Maccarrone, GHolleran and GP.Gnanasseelan. Properties of polymer modified binder and relationship to mix and pavement performance[J]. AAPT 1995
[17]徐芸青.SBS改性沥青若干性能的研究[J].新型建筑材料,2001,8
[18]Bernard Brule and Michel Maze, Application of SHRP binder tests to the characteriza-tion, structure and properties [J]. AAPT 1995
[19]沥青和聚合物改性沥青特性与沥青混凝土混合料性能的关系[C].改性沥青译文集,1992
[20]郝培文,申艳梅.SBS与沥青相容性的研究[J].西安公路交通大学学报,2001.2
[21]聚合物改性沥青胶结料的特性[C].改性沥青译文集,1992
[22]原健安,赵可.改性剂剂量与改性沥青性质[J].石油沥青,1999.12,13(4)：10-14
[23]Brule, Y.Brion, and A.Tanguy. Paving asphalt polymer blends, relationship between composition, structure and properties[J]. AAPT 1988
[24]U.Isacsson, X.Lu. Laboratory investigation of polymer modified asphalt s[J]. APPT, 1999:35-631
[25]宁永成.有机化合物结构鉴定与有机波谱学[M].北京：科学出版社,2001
[26]柯以侃.董慧茹主编.分析化学手册.第三分册.光谱分析[M].北京：化学工业出版社.1998.09：866-1122
[27]金鸣林,冯安祖,史美仁等.胜利100B沥青老化过程中官能团分析与相对分子量分布[J],南京化工大学学报,2000,22(5)：66-69
[28]Chen J.S., Huang L.S. Developing an aging model to evaluate engineering properties of asphalt paving binders[J]. Materials and Structures,2000,33:559-565
[29]李炜光,周巧英等.SBS测试方法及机理研究[J].石油沥青,2010,24(5)：1-5
[30]柯以侃.董慧茹主编.分析化学手册.第三分册.光谱分析[M].北京：化学工业出版社.1998.09：866-1122
[31]李双瑞,林青,董声雄.SBS改性沥青机理研究进展[J].高分子通报,2008,5(5)：14-17
[32]U.Johanssonnad5.Linde, Polymer modified asphalt binder Part 1, Swedish National Testing and Research Institute[R], SP Report 1991.02
[33]X.Lu and U.Isacsson.Rheological characterization of styrene-butadiene-styrene copolymer modified asphalt [J].Construction and Building Materials,1997,11(1):23-3