两亲聚合物及其用作亲水涂料的研究
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摘要
本文研究了可聚合高分子乳化剂的合成工艺及其水溶液的性质，并利用其水溶液的性质来监控合成条件。在此基础上研究了两亲聚合物作为纯有机空调用亲水涂料的应用。为了解决有机亲水涂膜的持续亲水性，我们进行了分子设计，即将亲水大分子HTP利用乳液聚合通过化学键和疏水PA主链接枝，并通过调整聚合工艺，来调整可聚合高分子乳化剂的接枝率、胶束形态、乳胶粒的形态，通过调整成膜方法，达到疏水、亲水不同链段的自组装和微相分离，再使疏水相交联固化，达到持续亲水性的目的。同时分析了有机亲水膜亲水机理，并讨论了影响有机亲水摸持续亲水性的因素。
Synthesizing of amphiphilic polymer and its solution's properties have been studied in this paper. The conditions of synthesizing can be controlled by using its solution's properties. On this basic ,we studied the amphiphilic polymer's application to pure organic hydrophilic coating for air-condition. In order to solve continuous hydrophilic, we adopt molecular design梙ydrophilic macromolecular HTP can be grafted to PA main chain by using emulsification,modify polymer technics, polymeric emulsifier graft ratio, micelle shape or emulsion particle shape and film-forming method so that hydrophobic chain and hydrophilic chain can self-assemble and micro-phase separate, then cross-linking solidify the hydrophobic phase under high temperature. At the same time, we analyse hydrophilic mechanism of organic hydrophilic membrane and discuss the factors of affecting continuous hydrophilic of pure organic hydrophilic film.
Synthesizing of amphiphilic polymer and its solution's properties have been studied in this paper. The conditions of synthesizing can be controlled by using its solution's properties. On this basic ,we studied the amphiphilic polymer's application to pure organic hydrophilic coating for air-condition. In order to solve continuous hydrophilic, we adopt molecular design梙ydrophilic macromolecular HTP can be grafted to PA main chain by using emulsification,modify polymer technics, polymeric emulsifier graft ratio, micelle shape or emulsion particle shape and film-forming method so that hydrophobic chain and hydrophilic chain can self-assemble and micro-phase separate, then cross-linking solidify the hydrophobic phase under high temperature. At the same time, we analyse hydrophilic mechanism of organic hydrophilic membrane and discuss the factors of affecting continuous hydrophilic of pure organic hydrophilic film.
引文
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[56] 方治齐，张新云，涂料工业，2002，(4)：13．
[57] 方治齐，陈宏伟，高分子材料科学与工程，(以被录用)．
[58] 曹同玉，刘庆莆，胡金生，聚合物乳液合成原理、性能及应用，化学工业出版社，1997．
[59] M. Okubo, M. Ando, A. Yamada, J. Polym. Sci., Polym. Lett. Ed., 1981,19:143.
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[63] I. Cho, K. W. Lee, J.Appl. Polym. Sci.,1985,30:1903.
[64] V. Dimonie, M. S.El-Aasser, A. Klein, J. Polym. Sci., Polym. Chem. Ed.,
1984,22:2197.
[65] Barrett K.E., J. Dispersion Polym. In Organic Media, New York, Interscience, 1975.
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[69] Jayakrishnan A. Shah D.O., J. Polym. Lell. Ed., 1984,22:31.
[70] Ferrick M.R., Murtagl J.,Thomas J.K., Macromolecules, 1990,23:3796.
[71] 高均，吴奇，金熹高，化学通报，1996．8：53．
[72] O. V. Borisov, A. Halperin, Macromolecules, 1996,29:2612.
[73] A. Halperin, Macromolecules, 1991,24:1418.
[74] 尚振平，方天如，高分子学报，1994，(1)：76～84．
[75] Haruta, Mitsuski, Roshihara. 英国专利 2288178, 1995.
[76] Masahiko, Fujio, Hidekimi. 欧洲专利 0654514A1,1995.
[2] Riess G, Hurtrez G, Bahadur P. Encyclopedia of Polymer Science and Engineering, Wiley, NewYork, 1985,324.
[3] Tuza. Z, Adv. Colloid. Interface Sci.,1976,6:201.
[4] Nguyen D. ,Williams CE., Eisenber A., Macromol., 1994,27:5090.
[5] Linse P., Macromol., 1992,25:5434.
[6] Swlb J., Gallot Y.,In Polymeric Amines and Ammorium Salts,Pergamon Press,NewYork,1980,205.
[7] Gao Z, Eisenberg A, Macromol.,1993,26:7375.
[8] G.L.Gaines,Jr. Insoluble monolayers at Liquid-Gas Interfaces. Interscience Publishers, New York, 1965.
[9] 福田清成等编“LB膜”CNC 东京，1986．
[10] A. W. Adamson,Physical of Surfaces, John-Wiley, 1976.
[11] Y.Ikada, H.Iwata, S.Nagaoka, F.Hofii, J.Macromol. Sci.,-Phys.,B 17(2), 1980:191
[12] Y.Kawaguchi, H. Nakahara, K.Fukuda, Thin Solid Films, 1985,133:235
[13] H.Tiedtke,G.Buhling, R.Kinne, F.R.G.Patent DE3444354,AL, 1985.
[14] Balzani V.,Gomwz-lopez M.,Stoddart J.F.,Acc.Chem. Des., 1998,31,4051.
[15] Collier C.P.,Saykally R.J.,Shiang J.J.,Science, 1997,277,1978-1981.
[16] 刘冬生，张榕本，中国科学，B辑，1997，27：315．
[17] Rotz,U., Lindau,J.,Fischer,H.,Polym.Bull., 1992,27:481.
[18] Eich, M.,Wendorff, J.H., Makcromol. Chem.Rapid Commun.,1987,8:359.
[19] 李从武，潘昂，功能高分子学报，1993，6(2)：181．
[20] 鹤田祯二，桵井靖久，Biomaterial Sci．，第一集，南江堂，1982．
[21] A.Takahara, J.I.Tashita, Polym., 1985,26:978.
[22] 谢静薇，江明，高分子材料科学与工程，1987，4：17．
[23] Y. Ikada, Adv. Polym. Sci., 1984,57:103.
[24] 日本专利公开 JP096239541．
[25] 日本专利公开 JP2000-204357．
[26] 日本专利公开 JP96-157626．
[27] 施良和，胡汉范主编．高分子科学的今天与明天，化学工业出版社，1994．
[28] 鲁德平，熊传溪，高分子材料科学与工程，2000，2：26
[29] Lee D.Y.,Kim J.H.,J. Polym. Sci.,Part A: Polym. Chem.,1998,36:2865.
[30] 任天斌，张洪涛，胶体与聚合物，1999，2：1．
[31] Jakasawa, Reiko. JP: 99-300269,1999.
[32] 王强，曹爱丽，黄积涛，高分子材料科学与工程，1999，15(2)35～37．
[33] Hiroshi Uyama, Yoichiro Horda, Shiro Kobayashi, Macromonomers.
[34] B. N. Greene, B. P. Sheetz ,T. D. Filer, J.Colloid Interface Sci., 1970,32:90
[35] H. Uyama, Y. Honda, S. Kobayashi,Macromonomers, 1992,25:123.
[36] C. M.Paleos, A. Malliaris, J. Macromol. Sci.,Rev. Macromol. Chem. Phys., 1988,C28,403.
[37] David，国际专利申请．9721780，1997．
[38] 清谷明弘，春日司，野世溪精等．住友轻金属技报，1991．
[39] Takasawa, Reiko, JP:99-300269,1999.
[40] 范德拉安．CN：1234846A，1999．
[41] Anazawa, Takanori. JP:99-209648,1999.
[42] Ishibashi, Hirotaka. JP:99-181339,1999.
[43] Fujmoto, Hidefumi. JP:99-315224,1999.
[44] Jakahashi, Kazuo. JP-324194,1999.
[45] Higashiura，日本专利公开．305568，1998．32(4)：255．
[46] Saito,Kiyotaka，日本专利公开．5279，1998．
[47] Shiozawa,Kimihide等，日本专利公开．20148，1997．
[48] Osako,Tomohiro，欧洲专利公开．54431，1998．
[49] 北京化工学院，空调机换热器亲水防蚀处理新技术，1993，6．
[50] 周爱娟．沈阳化工学院学报，1996，(1)：21．
[51] 史兴利，轻合金加工技术，1995，23(5)：20．
[52] 关鲁熊，黄可龙，湘军．中南工业大学学报，1997，28(3)：298
[53] 陈立新．涂料工业，1999，(9)：10．
[54] 赵晓宁，方治齐，涂料工业，(3)：33．
[55] 方治齐，胡勇辰，上海涂料，(2)：8．
[56] 方治齐，张新云，涂料工业，2002，(4)：13．
[57] 方治齐，陈宏伟，高分子材料科学与工程，(以被录用)．
[58] 曹同玉，刘庆莆，胡金生，聚合物乳液合成原理、性能及应用，化学工业出版社，1997．
[59] M. Okubo, M. Ando, A. Yamada, J. Polym. Sci., Polym. Lett. Ed., 1981,19:143.
[60] M.Narkis, M. Silverstein, J. Elastomers Plastic, 1987,18:136.
[61] D.I. Lee, T. Ishikawa, J. Polym. Sci. Polym. Chem. Ed., 1983,21:147.
[62] T. Matsumots, M. Obuto, S. Shikas, Kobunshi Ronbunshu, 1976,33:575.
[63] I. Cho, K. W. Lee, J.Appl. Polym. Sci.,1985,30:1903.
[64] V. Dimonie, M. S.El-Aasser, A. Klein, J. Polym. Sci., Polym. Chem. Ed.,
1984,22:2197.
[65] Barrett K.E., J. Dispersion Polym. In Organic Media, New York, Interscience, 1975.
[66] Hoar T.F.,Schalman J.H.,Nature, 1943,(52):102.
[67] J.S.Guo,E.D.Sukol,J. W. Vanderhoff, J.Polym. Sci.Polym. Chem., 1992,(30):691.
[68] Douglas S.L., Iuum T., Davis S.S., J. Colloid Interface Sci., 1985,103:154.
[69] Jayakrishnan A. Shah D.O., J. Polym. Lell. Ed., 1984,22:31.
[70] Ferrick M.R., Murtagl J.,Thomas J.K., Macromolecules, 1990,23:3796.
[71] 高均，吴奇，金熹高，化学通报，1996．8：53．
[72] O. V. Borisov, A. Halperin, Macromolecules, 1996,29:2612.
[73] A. Halperin, Macromolecules, 1991,24:1418.
[74] 尚振平，方天如，高分子学报，1994，(1)：76～84．
[75] Haruta, Mitsuski, Roshihara. 英国专利 2288178, 1995.
[76] Masahiko, Fujio, Hidekimi. 欧洲专利 0654514A1,1995.