FeCrBCSi系非晶/纳米晶电弧喷涂层组织和性能的研究
|
摘要
本文从非晶/纳米晶合金成分设计出发,研究了B元素对Fe-Cr-B-C-Si合金系非晶相含量及纳米晶晶粒尺寸的影响机制及规律;建立了非晶相含量、纳米晶粒尺寸与涂层显微组织形貌等微结构特征的影响关系,并研究了非晶/纳米晶涂层的磨粒磨损与腐蚀行为及其相应的失效机理。主要研究结果如下:
在一定范围内,通过调整粉芯丝材中B元素含量,采用电弧喷涂方法制备了五组不同非晶相含量、纳米晶粒尺寸的Fe基非晶/纳米晶涂层。涂层由变形良好的扁平化粒子相互搭接堆积而成,呈典型的层状结构形貌,结构致密,通过图像分析软件测量涂层孔隙率约在3%左右。其中Fe_(56)Cr_(15)B_(26)(CSi)_3合金具有相对最高的非晶相含量、最小的纳米晶粒尺寸,其非晶含量可达36.4%,纳米晶粒尺寸为12.4nm。所制备的涂层均具有较好的热稳定性,差热分析结果表明在760K以下使用涂层不会发生晶化。
制备的非晶/纳米晶涂层均具有较高的硬度,维氏硬度值保持在865~1166HV0.1。涂层在室温下的耐磨粒磨损性能约为基体Q235钢的6~13倍,主要磨损机制以疲劳磨损为主。随涂层中纳米晶粒尺寸的减小和非晶相含量的增加,涂层的维氏硬度逐渐提高,耐磨粒磨损性能相应增加。涂层在经过923K两个小时的退火处理后,其维氏硬度和相对耐磨性均得到提升,保持了良好的热稳定性。
制备的非晶/纳米晶涂层在室温3.5%NaCl溶液中的电化学结果与基体相比均具有较高的自腐蚀电位,呈现相对较好的抗氯离子腐蚀能力,能够很好的对基体起到保护作用。腐蚀行为以点蚀为主同时兼有均匀腐蚀的进行。对合金成分差别较大的Fe_(62)Cr_(15)B_(20)(CSi)_3、Fe_(56)Cr_(15)B_(26)(CSi)_3两涂层对其进行高温腐蚀的研究,结果表明,在923K经过100h的高温腐蚀后,其高温氧化动力学曲线和涂盐(Na_2SO_4+K_2SO_4)热腐蚀动力学曲线均呈抛物线状,最终两涂层的氧化增重量稳定在6mg/cm~2左右,涂盐热腐蚀增重量约为10mg/cm~2,均明显优于基体材料,呈现相对较好的抗高温氧化和热腐蚀性能。两涂层高温氧化和涂盐热腐蚀后的表面产物均为Fe_2O_3和尖晶石FeCr_2O_4氧化物,由这些氧化物在涂层表层所构成的均匀致密的钝化膜有效的保护了涂层内部组织。
In this study the effect of boron addtion on the Fe-Cr-B-C-Si amorphous alloy’s amorphous content and nanocrystalline grain size during arc spraying process was invistigated based on the design amorphous/nanocrystalline alloy system. The relationship between amorphous content, nanocrystalline grain size and microstructure of the coatings was established, the corrosion and abrasive wear behavior of the amorphous/nanocrystalline alloy coatings were studied in details. The major results are summarized as follows:
Fe-based coatings with different amorphous content and nanocrystalline grain size were prepared by arc spraying technology by adjusting the boron content in certain exten. The coating consisted of numerous flattened lamellae parallel to the substrate. The porosity was measured by the image analysis software and the value was about 3%. It was found that the optimum boron content in the alloy for the most amorphous content and nanocrystallin grain size was 26at%. The highest amorphous content was about 36.4%; and the smallest nanocrystalline grain size was 12.4 nm. With this composition the alloy possessed high thermal stability as the crystallization temperature exceeded 760K.
It was found that the coatings possessed higher value of microstruture in the range of 865~1166HV0.1. The coatings abrasive wear resistance was 6~13 times higher than that of the Q235 mild steel. In addition, fatigue abrasion form was observed on the surfaces of the coatings during abrasion testing processes. The wear resistance and hardness improved with the higher amorphous content and lower nano-grain size. The coatings annealed at the temperature of 923K expressed the greated thermal stability with relativly higher mircohardness and wear resistance. The amorphous/nanocrystalline alloy coatings showed excellent corrosion resistance in 3.5% NaCl solution, which were much better than Q235 mild carbon steel. Testing results shows that main corrosion mechinanism of coatings were pitting corrosion and uniform corrosion. Fe_(62)Cr_(15)B_(20)(CSi)_3 and Fe_(56)Cr_(15)B_(26)(CSi)_3 coatings after high-temperature corrosion at 923K for 100h, both the oxidation kinetics and the molten salt thermal etching kinetics showed a parabolic relationship. The coatings possess of high oxidation and thermal etching resistance with a final weight gain of 6mg/cm~2 and 10mg/cm~2 for each condition. Most of the products after high temperature oxidation and thermal etching were Fe_2O_3 and FeCr_2O_4. The existence of the passive film consist of these oxides gave a protection to the inner coating.
在一定范围内,通过调整粉芯丝材中B元素含量,采用电弧喷涂方法制备了五组不同非晶相含量、纳米晶粒尺寸的Fe基非晶/纳米晶涂层。涂层由变形良好的扁平化粒子相互搭接堆积而成,呈典型的层状结构形貌,结构致密,通过图像分析软件测量涂层孔隙率约在3%左右。其中Fe_(56)Cr_(15)B_(26)(CSi)_3合金具有相对最高的非晶相含量、最小的纳米晶粒尺寸,其非晶含量可达36.4%,纳米晶粒尺寸为12.4nm。所制备的涂层均具有较好的热稳定性,差热分析结果表明在760K以下使用涂层不会发生晶化。
制备的非晶/纳米晶涂层均具有较高的硬度,维氏硬度值保持在865~1166HV0.1。涂层在室温下的耐磨粒磨损性能约为基体Q235钢的6~13倍,主要磨损机制以疲劳磨损为主。随涂层中纳米晶粒尺寸的减小和非晶相含量的增加,涂层的维氏硬度逐渐提高,耐磨粒磨损性能相应增加。涂层在经过923K两个小时的退火处理后,其维氏硬度和相对耐磨性均得到提升,保持了良好的热稳定性。
制备的非晶/纳米晶涂层在室温3.5%NaCl溶液中的电化学结果与基体相比均具有较高的自腐蚀电位,呈现相对较好的抗氯离子腐蚀能力,能够很好的对基体起到保护作用。腐蚀行为以点蚀为主同时兼有均匀腐蚀的进行。对合金成分差别较大的Fe_(62)Cr_(15)B_(20)(CSi)_3、Fe_(56)Cr_(15)B_(26)(CSi)_3两涂层对其进行高温腐蚀的研究,结果表明,在923K经过100h的高温腐蚀后,其高温氧化动力学曲线和涂盐(Na_2SO_4+K_2SO_4)热腐蚀动力学曲线均呈抛物线状,最终两涂层的氧化增重量稳定在6mg/cm~2左右,涂盐热腐蚀增重量约为10mg/cm~2,均明显优于基体材料,呈现相对较好的抗高温氧化和热腐蚀性能。两涂层高温氧化和涂盐热腐蚀后的表面产物均为Fe_2O_3和尖晶石FeCr_2O_4氧化物,由这些氧化物在涂层表层所构成的均匀致密的钝化膜有效的保护了涂层内部组织。
In this study the effect of boron addtion on the Fe-Cr-B-C-Si amorphous alloy’s amorphous content and nanocrystalline grain size during arc spraying process was invistigated based on the design amorphous/nanocrystalline alloy system. The relationship between amorphous content, nanocrystalline grain size and microstructure of the coatings was established, the corrosion and abrasive wear behavior of the amorphous/nanocrystalline alloy coatings were studied in details. The major results are summarized as follows:
Fe-based coatings with different amorphous content and nanocrystalline grain size were prepared by arc spraying technology by adjusting the boron content in certain exten. The coating consisted of numerous flattened lamellae parallel to the substrate. The porosity was measured by the image analysis software and the value was about 3%. It was found that the optimum boron content in the alloy for the most amorphous content and nanocrystallin grain size was 26at%. The highest amorphous content was about 36.4%; and the smallest nanocrystalline grain size was 12.4 nm. With this composition the alloy possessed high thermal stability as the crystallization temperature exceeded 760K.
It was found that the coatings possessed higher value of microstruture in the range of 865~1166HV0.1. The coatings abrasive wear resistance was 6~13 times higher than that of the Q235 mild steel. In addition, fatigue abrasion form was observed on the surfaces of the coatings during abrasion testing processes. The wear resistance and hardness improved with the higher amorphous content and lower nano-grain size. The coatings annealed at the temperature of 923K expressed the greated thermal stability with relativly higher mircohardness and wear resistance. The amorphous/nanocrystalline alloy coatings showed excellent corrosion resistance in 3.5% NaCl solution, which were much better than Q235 mild carbon steel. Testing results shows that main corrosion mechinanism of coatings were pitting corrosion and uniform corrosion. Fe_(62)Cr_(15)B_(20)(CSi)_3 and Fe_(56)Cr_(15)B_(26)(CSi)_3 coatings after high-temperature corrosion at 923K for 100h, both the oxidation kinetics and the molten salt thermal etching kinetics showed a parabolic relationship. The coatings possess of high oxidation and thermal etching resistance with a final weight gain of 6mg/cm~2 and 10mg/cm~2 for each condition. Most of the products after high temperature oxidation and thermal etching were Fe_2O_3 and FeCr_2O_4. The existence of the passive film consist of these oxides gave a protection to the inner coating.
引文
1徐滨士,朱绍华,刘世参.表面工程与维修.北京:机械工业出版社, 1996: 227-228
2 N. A. Waterman. Treatise on Materials Science and Technology. Wear, 1979, 6(13): 280-281
3邓世均.高性能陶瓷涂层.北京:化学工业出版社, 2003: 517-518
4谢友柏.工程前沿,第2卷,摩擦学科学与工程前沿.北京:高等教育出版社, 2005: 2-5
5章熙康.非晶态材料及其应用.北京:北京科学技术出版社, 1987: 129-130
6曾荣昌,韩恩厚等.材料的腐蚀与防护.北京:化学工业出版社, 2006: 1-7
7刘家浚.材料磨损原理及其耐磨性.北京:清华大学出版社, 1993: 33-37
8 M. El-Sharif, J. McDougall, C. U. Chisholm. Electrodeposition of Thick Chromium Coatings from an Environmentally Acceptable Chromium(III)-Glycine Complex. Transactions of the Institute of Metal Finishing, 1999, 77(4): 139-144
9李家柱,林安,甘复兴.取代重污染六价铬电镀的技术及应用, 2004, 23(5): 30-33
10樊自拴,孙冬柏,俞宏英等.等离子喷涂制备铁基非晶/纳米晶复合涂层.北京科技大学学报, 2005, 27(5): 582-585
11 Y. P. Wu, P. Lin, G. Xie, et al. Formation of Amorphous and Nanocrystalline Phases in High Velocity Oxy-fuel Thermally Sprayed a Fe-Cr-Si-B-Mn Alloy. Material Science and Engineer, 2006, 430(1-2): 34-39
12梁秀兵,程江波,刘燕等.铁基非晶纳米晶涂层耐磨性的研究.装甲兵工程学院学报, 2009, 23(5): 77-81
13 J. B. Cheng, X. B. Liang, B. S. Xu. Formation and Properties of Fe-based Amorphous/Nanocrystalline Alloy Coating Prepared by Wire Arc Spraying Process. Journal of Non-Crystalline Solids, 2009, 355(34): 1673-1678
14 P. Georgieva, R. Thorpe, A. Yanski, et al. An Innovative Turnover for the Wire Arc Spraying Technology. Advanced Materials and Processes, 2006, 164(8): 18-19
15 W. Klement, R. H. Willens, P. Duwez. Non-crystalline Structure in Solidified Gold-silicon Alloys. Nature, 1960, 187(4740): 869-870
16 Y. Yoshizawa, S. Oguma. New Fe-based Soft Magnetic Alloys Composed Fultrafine Grainstrucure. Journal of Applied Physics, 1988, 64(10): 6044-6060
17何圣静,高莉如.非晶态材料及其应用.北京:机械工业出版社, 1987: 127-132
18张甫飞.非晶纳米晶合金材料的工艺技术、产业化和应用.磁性材料及器件, 2004, 35(5): 13-16
19 F. E. Luborsky. Amorphous Metallic Alloys. London, 1983: 534
20马仁殿.铁基块状非晶合金的制备与性能研究.山东大学硕士论文, 2004: 1-3
21王一禾,杨膺善.非晶态合金.北京:冶金工业出版社, 1989: 134-157
22王绪威.非晶态材料及应用.北京:高等教育出版社, 1992: 27-45
23 A. Inoue, H. Kimura. Fabrications and Mechanical Properties of Bulk Amorphous, Nanocrystalline, Nanoquasicrystalline Alloys in Aluminum-based. Journal of Light Metals, 2001, 1(1): 31-41
24 A. Inoue, C. Fan, A. Takenchi. High-strength Nanocrystalline Alloys in a Zr-based System Containing Compound and Glass Phases. Journal of Non-crystalline Solids, 1999, 250-252(2): 724-728
25 A. Inoue, W. Zhang, T. Zhang, et al. High-strength Cu-based Bulk Glassy Alloys in Cu-Zr-Ti and Cu-Hf-Ti Ternary Systems. Acta Mater, 2001, 49(14): 2645-2652
26 Choigs, Kimyh, Chohk, et al. Ultrahigh Tensile Strength of Amorphous Al-Ni-(Nd,Gd)-Fe Alloys Containing Nanocrystalline Al Particles. Scripta Mater, 1995, 33(8): 1301-1306
27赵占奎,李建忱,蒋青.激冷非晶P纳米晶Al65Si35合金的显微组织.材料工程, 2002, (11): 32-34
28 A. Inoue. Bulk Amorphous and Nanocrystalline Alloys With High Functional Properties. Materials Science and Engineering A, 2001, 304-306: 1-10
29高木诚,河村能人. Zr基金属ガテス及びその复合材料の结晶化と械的性质.日本:日本金属学会, 2001
30汪卫华,王文魁.新型Zr-Ti-Cu-Ni-Be-C大块非晶合金的形成.中国科学(A辑), 1998, 28(5): 443-447
31朱立群,李卫平等.电沉积Ni-W非晶态合金复合镀层研究,机械工程材料, 1998, 22(4): 9-11
32郑瑞伦,张家树,刘荣泰等.纳米微粒-Al2O3化学复合镀层分形特性探讨.化学物理学报, 1997, 10(6): 529-533
33 I. Skorvanek, C. G. Kim, J. Kovac, et al. Soft Magnetic Behaviour and Permeability Spectra in Amorphous and Nanocrystalline Fe80.5Nb7B12.5 Alloys. Journal of Magnetism and Magnetic Materials, 2000, 215-216: 440-442
34 M. E. Mchenry, F. Johnson, T. Ohkubo, et al. The Kinetics of Nanocrystallization and Microst Ructural Observations in Finemet, Nanoperm and Hitperm Nanocomposite Magnetic Materials. Scripta Mater, 2003, 48(7): 881-887
35 W. Zhang, K. Fujita. Synthesis of Fe-Co-Nd-B Amorphous Alloys With Glass Transition and Their Crystallization-induced Hard Magnetic Properties. Materials Transactions, JIM, 1999, 40(10): 1123-1129
36张长桥,主沉浮,于萍等. Zn-5%Al合金热浸镀层微结构及其防腐机理研究.材料工程, 2002, (4): 24-26
37黄新民,吴玉程,郑玉春.纳米功能复合涂层.功能材料, 2000, 31(4): 419-420
38熊忠华,魏锡文,黄锋.化学复合镀Ni-P-TiO2光催化降解次甲基蓝.材料开发与应用, 2002, 17(1): 11-13
39 S. S. Wang, G. Lu, Z. Y. Zhang, et al. Quantum Size Effect and Nonlinear Optical Effect of Nano ZnS in Noncrystal Silica. Chinese Science Bulletin, 1996, 41(1): 83
40王玉,张文礼,孙冬柏等.非晶纳米晶复合材料的性能与制备.材料科学与工程学报, 2006, 24(2): 292-296
41肖华星,陈光.大块非晶晶化研究的现状和动态.兵器材料科学与工程, 2003, 26(1): 65-68
42孙桂琴,喻晓军.非晶及纳米晶合金研究进展.金属功能材料, 1999, 6(4): 156-160
43 S. Zhang, D. Sun, Y. Q. Fu. Super Hard Nanocomposite Coatings. Journal of Materials Science & Technology, 2002, 18(6): 485-491
44 H. W. Jin, C. G. Park, M. C. Kim. In Situ TEM Heating Studies on the Phase Transformation of Metastable Phases in Fe-Cr-B Alloy Spray Coatings. Materials Science and Engineering A, 2001, 304-306: 321-326
45 H. W. Jin, Y. M. Rhyim, S. G. Hong, C. G. Park. Microstructural Evolution of the Rapidly Quenched Fe-Cr-B Alloy Thermal Spray Coatings. Materials Science and Engineering A, 2001, 304-306: 1069-1074
46潘继岗,樊自栓,孙冬柏等.超音速火焰喷涂Fe基非晶合金涂层的性能研究.材料工程, 2005, (9): 53-55
47潘继岗,樊自栓,孙冬柏等.采用两种喷涂技术制备铁基合金涂层的摩擦磨损特性研究.摩擦学学报, 2005, 25(5): 412-415
48 J. Gang, E. Omar, G. Thierry. Deposition and Corrosion Resistance of HVOF Sprayed Nanocrystalline Iron Aluminide Coatings. Surface and Coatings Technology, 2005, 190(2-3): 406-416
49 F. Otsubo, H. Era, K. Kishitake, H. Matsumoto. High Corrosion Resistant Iron-based Amorphous Coatings Obtained by Thermal Spraying. Proceedings of the 15th International Thermal Spray Conference, 1998, 1: 659-664
50向兴华,穆晓东,刘正义. Fe基非晶合金涂层的等离子喷涂成形特征.焊接学报, 2003, 24(1): 48-54
51向兴华,穆晓东,李建三. Fe基非晶合金涂层的磨损与电化学腐蚀特征.材料热处理学报, 2003, 24(4): 59-62
52穆晓冬,向兴华,刘正义. Fe基非晶合金涂层在晶化过程中的硬度与组织变化.材料工程, 2003, (5): 33-36
53向兴华,穆晓冬. Fe基非晶合金涂层的多晶型晶化过程研究.材料科学与工程学报, 2004, 22(1): 44-47
54 D. J. Branagan, W. D. Swank, D. C. Haggard, J. R. Fincke. Wear Resistant Amorphous and Nanocomposite Steel Coatings. Physical Metallurgy and Materials Science, 2001, 32(10): 2615-2621
55 D. J. Branagan, Y. Tang. Developing Extreme Hardness(>15GPa) in Iron Based Nanocomposites. Applied Science and Manufacturing A, 2002, 33(6): 855-859
56 D. J. Branagan, M. Breitsameter, B. E. Meacham, et al. High-Performance Nanoscale Composite Coatings for Boiler Applications. Journal of Thermal Spray Technology, 2005, 14(2): 196-204
57傅斌友,贺定勇,蒋建敏等.电弧喷涂含非晶相铁基涂层的研究.材料热处理学报, 2008, 29(3): 159-162
58 A. Inoue, A. Takeuchi, T. Zhang. Ferromagnetic Bulk Amorphous Alloys. Metallurgical and Materials Transactions A, 1998, 29(7): 1779-1793
59 A. Inoue. Preparation and Novel Properties of Nanocrystalline and Nanoquasicrystalline Alloys, Nanostructure Materials, 1995, 6(1-4): 53-64
60 C. Verdon, A. Karimi, J. L. Martin. A Study of High Velocity Oxy-fuel Thermally Sprayed Tungsten Carbide Based Coatings. Microstructures. Materials Science and Engineering A. 1998, 246(1-2): 11-24
61 M. F. Cerqueiraa, J. A. Ferreira, G. J. Adriaenssen. Structural Studies and Influence of the Structure on the Electrical and Optical Properties of Microcrystalline Silicon Thin Films Produced by RF Sputtering. Thin Solid Films, 2000, 370(1-2): 128-136
62 J. I. Langford. A Rapid Method for Analysing the Breadths of Diffraction and Spectral Lines Using the Voigt Function. Journal of Applied Crystallography, 1978, 11(1): 10-14
63 M. Kirchgassner, E. Badisch, F. Franek. Behaviour of Iron-based Hardfacing Alloys Under Abrasion and Impact. Wear, 2008, 265(5-6): 772-779
64傅斌友,含非晶涂层制备及其晶化规律研究.北京工业大学博士论文, 2009: 76-77
65 A. Takeuchi, A. Inoue. Classification of Bulk Metallic Glasses by Atomic Size Difference, Heat of Mixing and Period of Constituent Elements and Its Application to Characterization of the Main Alloying Element. Materials Transactions, 2005, 46(12): 2817-2829
66 A. Inoue, T. Zhang. Stabilization of Super-cooled Liquid and Blue Glassy Alloys in Ferrous and Non-ferrous System. Journal of Non-crystalline Solids, 1999, 250-252(2): 552-559
67于会生,罗守福,王永瑞.化学沉积Ni-P及Ni-Cu-P合金渡层晶化行为的比较.材料工程, 2002(4): 19-22
68陈华辉,邢建东,李卫.耐磨材料应用手册.北京:机械工业出版社, 2006: 38-39
69何肇基.金属的力学性质.北京:冶金工业出版社, 1982: 56-68
70束德林.工程材料力学性能.北京:机械工业出版社, 2003: 35-36
71 X. D. Liu, J. T. Wang, B. Z. Ding. Preparation and Properties of Nanocrystalline (Fe0.99Mo0.01)78Si9B13 Alloys. Scripta Metallurgica et Materialia, 1993, 28(1): 59-64
72周正.热喷涂Fe基非晶合金涂层的工艺及性能研究.北京理工大学博士论文, 2008: 115-116
73王爱萍,常新春,候万良等.镍基非晶合金涂层的制备与腐蚀性能.金属学报, 2006, 42(5): 537-539
74 J. Jayaraj, D. J. Sordelet, D. H. Kim, et al. Corrosion Behaviour of Ni-Zr-Ti-Si-Sn Amorphous Plasma Spray Coating. Corrosion Science, 2006, 48(4): 950-964.
75肖纪美,曹楚南.材料腐蚀学原理.北京:化学工业出版社, 2002: 88-90
76王新建,朱雪梅,张彦生等. Fe-Mn-Al与Fe-Mn奥氏体合金的高温氧化性能与组织结构.大连铁道学院学报, 2004, 23(1): 69-73
2 N. A. Waterman. Treatise on Materials Science and Technology. Wear, 1979, 6(13): 280-281
3邓世均.高性能陶瓷涂层.北京:化学工业出版社, 2003: 517-518
4谢友柏.工程前沿,第2卷,摩擦学科学与工程前沿.北京:高等教育出版社, 2005: 2-5
5章熙康.非晶态材料及其应用.北京:北京科学技术出版社, 1987: 129-130
6曾荣昌,韩恩厚等.材料的腐蚀与防护.北京:化学工业出版社, 2006: 1-7
7刘家浚.材料磨损原理及其耐磨性.北京:清华大学出版社, 1993: 33-37
8 M. El-Sharif, J. McDougall, C. U. Chisholm. Electrodeposition of Thick Chromium Coatings from an Environmentally Acceptable Chromium(III)-Glycine Complex. Transactions of the Institute of Metal Finishing, 1999, 77(4): 139-144
9李家柱,林安,甘复兴.取代重污染六价铬电镀的技术及应用, 2004, 23(5): 30-33
10樊自拴,孙冬柏,俞宏英等.等离子喷涂制备铁基非晶/纳米晶复合涂层.北京科技大学学报, 2005, 27(5): 582-585
11 Y. P. Wu, P. Lin, G. Xie, et al. Formation of Amorphous and Nanocrystalline Phases in High Velocity Oxy-fuel Thermally Sprayed a Fe-Cr-Si-B-Mn Alloy. Material Science and Engineer, 2006, 430(1-2): 34-39
12梁秀兵,程江波,刘燕等.铁基非晶纳米晶涂层耐磨性的研究.装甲兵工程学院学报, 2009, 23(5): 77-81
13 J. B. Cheng, X. B. Liang, B. S. Xu. Formation and Properties of Fe-based Amorphous/Nanocrystalline Alloy Coating Prepared by Wire Arc Spraying Process. Journal of Non-Crystalline Solids, 2009, 355(34): 1673-1678
14 P. Georgieva, R. Thorpe, A. Yanski, et al. An Innovative Turnover for the Wire Arc Spraying Technology. Advanced Materials and Processes, 2006, 164(8): 18-19
15 W. Klement, R. H. Willens, P. Duwez. Non-crystalline Structure in Solidified Gold-silicon Alloys. Nature, 1960, 187(4740): 869-870
16 Y. Yoshizawa, S. Oguma. New Fe-based Soft Magnetic Alloys Composed Fultrafine Grainstrucure. Journal of Applied Physics, 1988, 64(10): 6044-6060
17何圣静,高莉如.非晶态材料及其应用.北京:机械工业出版社, 1987: 127-132
18张甫飞.非晶纳米晶合金材料的工艺技术、产业化和应用.磁性材料及器件, 2004, 35(5): 13-16
19 F. E. Luborsky. Amorphous Metallic Alloys. London, 1983: 534
20马仁殿.铁基块状非晶合金的制备与性能研究.山东大学硕士论文, 2004: 1-3
21王一禾,杨膺善.非晶态合金.北京:冶金工业出版社, 1989: 134-157
22王绪威.非晶态材料及应用.北京:高等教育出版社, 1992: 27-45
23 A. Inoue, H. Kimura. Fabrications and Mechanical Properties of Bulk Amorphous, Nanocrystalline, Nanoquasicrystalline Alloys in Aluminum-based. Journal of Light Metals, 2001, 1(1): 31-41
24 A. Inoue, C. Fan, A. Takenchi. High-strength Nanocrystalline Alloys in a Zr-based System Containing Compound and Glass Phases. Journal of Non-crystalline Solids, 1999, 250-252(2): 724-728
25 A. Inoue, W. Zhang, T. Zhang, et al. High-strength Cu-based Bulk Glassy Alloys in Cu-Zr-Ti and Cu-Hf-Ti Ternary Systems. Acta Mater, 2001, 49(14): 2645-2652
26 Choigs, Kimyh, Chohk, et al. Ultrahigh Tensile Strength of Amorphous Al-Ni-(Nd,Gd)-Fe Alloys Containing Nanocrystalline Al Particles. Scripta Mater, 1995, 33(8): 1301-1306
27赵占奎,李建忱,蒋青.激冷非晶P纳米晶Al65Si35合金的显微组织.材料工程, 2002, (11): 32-34
28 A. Inoue. Bulk Amorphous and Nanocrystalline Alloys With High Functional Properties. Materials Science and Engineering A, 2001, 304-306: 1-10
29高木诚,河村能人. Zr基金属ガテス及びその复合材料の结晶化と械的性质.日本:日本金属学会, 2001
30汪卫华,王文魁.新型Zr-Ti-Cu-Ni-Be-C大块非晶合金的形成.中国科学(A辑), 1998, 28(5): 443-447
31朱立群,李卫平等.电沉积Ni-W非晶态合金复合镀层研究,机械工程材料, 1998, 22(4): 9-11
32郑瑞伦,张家树,刘荣泰等.纳米微粒-Al2O3化学复合镀层分形特性探讨.化学物理学报, 1997, 10(6): 529-533
33 I. Skorvanek, C. G. Kim, J. Kovac, et al. Soft Magnetic Behaviour and Permeability Spectra in Amorphous and Nanocrystalline Fe80.5Nb7B12.5 Alloys. Journal of Magnetism and Magnetic Materials, 2000, 215-216: 440-442
34 M. E. Mchenry, F. Johnson, T. Ohkubo, et al. The Kinetics of Nanocrystallization and Microst Ructural Observations in Finemet, Nanoperm and Hitperm Nanocomposite Magnetic Materials. Scripta Mater, 2003, 48(7): 881-887
35 W. Zhang, K. Fujita. Synthesis of Fe-Co-Nd-B Amorphous Alloys With Glass Transition and Their Crystallization-induced Hard Magnetic Properties. Materials Transactions, JIM, 1999, 40(10): 1123-1129
36张长桥,主沉浮,于萍等. Zn-5%Al合金热浸镀层微结构及其防腐机理研究.材料工程, 2002, (4): 24-26
37黄新民,吴玉程,郑玉春.纳米功能复合涂层.功能材料, 2000, 31(4): 419-420
38熊忠华,魏锡文,黄锋.化学复合镀Ni-P-TiO2光催化降解次甲基蓝.材料开发与应用, 2002, 17(1): 11-13
39 S. S. Wang, G. Lu, Z. Y. Zhang, et al. Quantum Size Effect and Nonlinear Optical Effect of Nano ZnS in Noncrystal Silica. Chinese Science Bulletin, 1996, 41(1): 83
40王玉,张文礼,孙冬柏等.非晶纳米晶复合材料的性能与制备.材料科学与工程学报, 2006, 24(2): 292-296
41肖华星,陈光.大块非晶晶化研究的现状和动态.兵器材料科学与工程, 2003, 26(1): 65-68
42孙桂琴,喻晓军.非晶及纳米晶合金研究进展.金属功能材料, 1999, 6(4): 156-160
43 S. Zhang, D. Sun, Y. Q. Fu. Super Hard Nanocomposite Coatings. Journal of Materials Science & Technology, 2002, 18(6): 485-491
44 H. W. Jin, C. G. Park, M. C. Kim. In Situ TEM Heating Studies on the Phase Transformation of Metastable Phases in Fe-Cr-B Alloy Spray Coatings. Materials Science and Engineering A, 2001, 304-306: 321-326
45 H. W. Jin, Y. M. Rhyim, S. G. Hong, C. G. Park. Microstructural Evolution of the Rapidly Quenched Fe-Cr-B Alloy Thermal Spray Coatings. Materials Science and Engineering A, 2001, 304-306: 1069-1074
46潘继岗,樊自栓,孙冬柏等.超音速火焰喷涂Fe基非晶合金涂层的性能研究.材料工程, 2005, (9): 53-55
47潘继岗,樊自栓,孙冬柏等.采用两种喷涂技术制备铁基合金涂层的摩擦磨损特性研究.摩擦学学报, 2005, 25(5): 412-415
48 J. Gang, E. Omar, G. Thierry. Deposition and Corrosion Resistance of HVOF Sprayed Nanocrystalline Iron Aluminide Coatings. Surface and Coatings Technology, 2005, 190(2-3): 406-416
49 F. Otsubo, H. Era, K. Kishitake, H. Matsumoto. High Corrosion Resistant Iron-based Amorphous Coatings Obtained by Thermal Spraying. Proceedings of the 15th International Thermal Spray Conference, 1998, 1: 659-664
50向兴华,穆晓东,刘正义. Fe基非晶合金涂层的等离子喷涂成形特征.焊接学报, 2003, 24(1): 48-54
51向兴华,穆晓东,李建三. Fe基非晶合金涂层的磨损与电化学腐蚀特征.材料热处理学报, 2003, 24(4): 59-62
52穆晓冬,向兴华,刘正义. Fe基非晶合金涂层在晶化过程中的硬度与组织变化.材料工程, 2003, (5): 33-36
53向兴华,穆晓冬. Fe基非晶合金涂层的多晶型晶化过程研究.材料科学与工程学报, 2004, 22(1): 44-47
54 D. J. Branagan, W. D. Swank, D. C. Haggard, J. R. Fincke. Wear Resistant Amorphous and Nanocomposite Steel Coatings. Physical Metallurgy and Materials Science, 2001, 32(10): 2615-2621
55 D. J. Branagan, Y. Tang. Developing Extreme Hardness(>15GPa) in Iron Based Nanocomposites. Applied Science and Manufacturing A, 2002, 33(6): 855-859
56 D. J. Branagan, M. Breitsameter, B. E. Meacham, et al. High-Performance Nanoscale Composite Coatings for Boiler Applications. Journal of Thermal Spray Technology, 2005, 14(2): 196-204
57傅斌友,贺定勇,蒋建敏等.电弧喷涂含非晶相铁基涂层的研究.材料热处理学报, 2008, 29(3): 159-162
58 A. Inoue, A. Takeuchi, T. Zhang. Ferromagnetic Bulk Amorphous Alloys. Metallurgical and Materials Transactions A, 1998, 29(7): 1779-1793
59 A. Inoue. Preparation and Novel Properties of Nanocrystalline and Nanoquasicrystalline Alloys, Nanostructure Materials, 1995, 6(1-4): 53-64
60 C. Verdon, A. Karimi, J. L. Martin. A Study of High Velocity Oxy-fuel Thermally Sprayed Tungsten Carbide Based Coatings. Microstructures. Materials Science and Engineering A. 1998, 246(1-2): 11-24
61 M. F. Cerqueiraa, J. A. Ferreira, G. J. Adriaenssen. Structural Studies and Influence of the Structure on the Electrical and Optical Properties of Microcrystalline Silicon Thin Films Produced by RF Sputtering. Thin Solid Films, 2000, 370(1-2): 128-136
62 J. I. Langford. A Rapid Method for Analysing the Breadths of Diffraction and Spectral Lines Using the Voigt Function. Journal of Applied Crystallography, 1978, 11(1): 10-14
63 M. Kirchgassner, E. Badisch, F. Franek. Behaviour of Iron-based Hardfacing Alloys Under Abrasion and Impact. Wear, 2008, 265(5-6): 772-779
64傅斌友,含非晶涂层制备及其晶化规律研究.北京工业大学博士论文, 2009: 76-77
65 A. Takeuchi, A. Inoue. Classification of Bulk Metallic Glasses by Atomic Size Difference, Heat of Mixing and Period of Constituent Elements and Its Application to Characterization of the Main Alloying Element. Materials Transactions, 2005, 46(12): 2817-2829
66 A. Inoue, T. Zhang. Stabilization of Super-cooled Liquid and Blue Glassy Alloys in Ferrous and Non-ferrous System. Journal of Non-crystalline Solids, 1999, 250-252(2): 552-559
67于会生,罗守福,王永瑞.化学沉积Ni-P及Ni-Cu-P合金渡层晶化行为的比较.材料工程, 2002(4): 19-22
68陈华辉,邢建东,李卫.耐磨材料应用手册.北京:机械工业出版社, 2006: 38-39
69何肇基.金属的力学性质.北京:冶金工业出版社, 1982: 56-68
70束德林.工程材料力学性能.北京:机械工业出版社, 2003: 35-36
71 X. D. Liu, J. T. Wang, B. Z. Ding. Preparation and Properties of Nanocrystalline (Fe0.99Mo0.01)78Si9B13 Alloys. Scripta Metallurgica et Materialia, 1993, 28(1): 59-64
72周正.热喷涂Fe基非晶合金涂层的工艺及性能研究.北京理工大学博士论文, 2008: 115-116
73王爱萍,常新春,候万良等.镍基非晶合金涂层的制备与腐蚀性能.金属学报, 2006, 42(5): 537-539
74 J. Jayaraj, D. J. Sordelet, D. H. Kim, et al. Corrosion Behaviour of Ni-Zr-Ti-Si-Sn Amorphous Plasma Spray Coating. Corrosion Science, 2006, 48(4): 950-964.
75肖纪美,曹楚南.材料腐蚀学原理.北京:化学工业出版社, 2002: 88-90
76王新建,朱雪梅,张彦生等. Fe-Mn-Al与Fe-Mn奥氏体合金的高温氧化性能与组织结构.大连铁道学院学报, 2004, 23(1): 69-73