半夹心结构有机金属框架化合物的设计、可控制备与性能研究
|
摘要
有机金属超分子化合物的研究是当代化学的一个前沿,本论文选定含有半夹心结构Cp~*Ir(Cp~*=η~5-C_5Me_5),Cp~*Rh和(p-Cymene)Ru (p-Cymene=η~6-4-isopropy-1-toluene)的有机金属化合物为构筑单元,设计、合成了一系列大环、分子夹、三棱柱和笼装结构的有机金属超分子化合物,并对目标化合物的性质和应用做出了一些有意义的探索。
(1)合成得到一系列由四个氧原子桥连的双核有机金属化合物(A-D),然后利用其作为起始原料,分别与两齿、三齿和四齿的含氮配体自组装形成具有大环、三棱柱和笼装结构的有机金属超分子化合物。
首先以草酸配体桥连的半夹心结构有机金属双核化合物(A)为起始原料,分别与两齿、三齿和四齿的含氮配体进行配位合成了一系列大环、三棱柱和笼装结构的有机金属超分子化合物。系统研究结果表明,具有不同尺寸的矩形大环化合物由于分子间的相互作用,形成了孔道结构。在化合物[Cp_4~*M_4(μ-bpe)_2(μ-η~2-η~2-C_2O_4)_2](OTf)_4 (M=Ir,Rh;bpe=trans-1,2-bis(4-pyridyl)-ethylene)晶体结构中,两个桥连的4,4'-bpe分子之间由于π-π相互作用,从而使两个分子相互平行靠近,双键之间的距离为3.23 (?),在光照下,可以发生分子内[2+2]光化学反应,而且可以实现晶体到晶体之间的转化。
其次,引入了具有功能性的2,5-二羟基-3,6-二氯苯醌(B)和1,4-羟基-蒽醌(C)作为桥连配体,得到一系列具有不同尺寸大环结构的有机金属超分子化合物。循环伏安结果表明,四核大环化合物有较好的电化学性质。
接着研究了6,11-二羟基-5,12-萘并萘醌为桥连配体的有机金属双核化合物(D)与吡嗪的反应,得到了“分子夹”形状的大环化合物。研究表明此类化合物对有机小分子如二氯甲烷,1,2-氯乙烷具有选择性吸附效应,在同等条件下,可以从混合溶剂的蒸汽中优先选择吸附二氯甲烷分子。进一步研究发现:大环化合物不但可以在晶态下实现二氯甲烷分子的可逆性吸附和脱附,也可以在晶态下实现不同客体分子之间的交换反应。四氯乙烯分子亦可以被“分子夹”形状的大环化合物“吸附”,每个四氯乙烯分子与相邻的四个独立分子之间存在弱相互作用,化合物的空间结构由一维链状结构延伸形成了空间网状结构。当有机金属双核化合物(D)与其它的含氮双齿配体进行反应时,可以得到不同尺寸“分子夹”形状的大环化合物。当有机金属双核化合物(D)与含氮三齿配体反应时,可得到相应的六核三棱柱型化合物,此类化合物的具有较大的空腔体积,研究表明它们可以与具有平面结构的芳香类化合物形成“夹心”型化合物,芳香类化合物镶嵌在六核三棱柱型化合物的空腔内,分子之间存在非常强的π...π相互作用。
(2)利用三种含有N,S配位点的不同配体在不同的反应条件下与[Cp~*MCl_2]_2 (M=Ir,Rh)反应合成了一系列有机金属化合物。首先研究了[Cp~*IrCl_2]_2与4-巯基吡啶配体的反应。当[Cp~*IrCl_2]_2与两倍量的4-巯基吡啶的钠盐在甲醇溶液中进行反应时,得到“三角形”形状的大环化合物;当[Cp~*IrCl_2]_2与六倍量的4-巯基吡啶在二氯甲烷溶液中进行反应时,得到含有半夹心结构的单核化合物;单核化合物可以在三乙胺作用下重新组装成“正方形”形状的大环化合物。当[Cp~*MCl_2]_2 (M=Ir,Rh)与2-巯基吡啶配体进行反应时,可以得到单核的化合物,化合物中存在非常强的分子内氢键。进一步研究表明,草酸配体桥连的含有半夹心结构有机金属双核化合物与2,4,6-三巯基-1,3,5-均三嗪反应时,桥连的草酸根被取代,配体以N,S作为六齿配体与中心金属结合,可以得到两种含有三个金属中心的三核化合物。铱的三核化合物对催化降冰片烯聚合反应具有中等活性。
(3)将具有特定结构的4-DPDS(4,4'-二吡啶基二硫)配体分别与[Cp~*MCl_2]_2 (M=Ir,Rh)或[p-cymene)RuCl_2]_2反应,得到相应的双核化合物,接着与两倍量的银盐反应,可以生成含有两个4-DPDS配体的双核有机金属大环化合物。此外,还研究了不同的溶剂对生成的大环化合物空间结构的影响,发现不同的客体分子可以诱导化合物生成不同的空间排列方式。
(4)利用由-CH_2CH_2-、-CH_2CH_2CH_2-和-CH_2-Ph-CH_2-桥连的双齿中性硫酮类化合物为配体合成了一系列的半夹心结构有机金属化合物。研究结果表明:当配体为-CH_2CH_2CH_2-和-CH_2-Ph-CH_2-桥连的双齿中性硫酮类化合物时,可以生成双核金属大环化合物;当配体为-CH_2CH_2-桥连的双齿中性硫酮类化合物时,生成了一个含有桥基上的C-H活化的化合物。
(5)利用含氮双齿配体构筑了一系列含有半夹心结构有机金属双核碳硼烷化合物。通过改变双齿有机配体的结构,不仅可以调控金属.金属原子间的距离,而且可以合成具有新颖结构的超分子化合物。利用设计合成的含有四硫富瓦烯结构单元的配体与16电子体系碳硼烷化合物发生反应,得到的化合物结构表明分子之间通过硫.硫原子之间的相互作用,形成了独特的“碗状”空间结构,探索了含碳硼烷配体的有机金属孔道结构材料的合成方法。
(6)引入一系列双希夫碱类配体,通过[Cp~*MCl_2]_2 (M=Ir,Rh)诱导苯环上的两个C-H位点同时活化形成了含M-C键的有机金属双核化合物,利用含M-C键的双核金属化合物与炔烃类化合物发生插入反应,形成新一类的有机金属双核化合物,并对此类化合物作为桥连配体用来构筑有机金属大环化合物进行了初步尝试,利用单晶结构表征了含有新M-C键的大环化合物,并且在温和条件下成功实现了此类化合物的后修饰。
Supramolecular chemistry with organometallic half-sandwich complexes based on Ir, Rh, Ru fragments has received considerable attention over recent years. In this dissertation, some results in the rational design and synthesis of organometallic half-sandwich complexes and their potential applications are presented.
(1) The binuclear complexes with two parallel coordination sites, such as oxalate (A), chloranilate (B), 1,4-dihydroxyanthraquinone (C) and 6,11-dihydroxy-5,12-naphthacenedione (D) bridging irdium, rhodium and ruthenium complexes can be served as precursors, which can be interlinked by pyridyl-based ligands.
Following the general design strategy, many supramolecular rectangles, prisms and cages have been synthesized in high yields and characterized structurally. Efforts were paid to the functional properties and applications of these supramolecular structures, such as template-controlled topochemical photodimerization based on "organometallic macrocycles" through single-crystal-to-single-crystal transformation (SCSC), selectively recognize CH_2Cl_2 and ClCH_2CH_2Cl molecules with retention of single crystallinity in "organometallic molecular splints", and a simple, straightforward access to the preparation of metallo-prismatic cages able to encapsulate aromatic molecules was included.
(2) The reactions of [Cp~*IrCl_2]_2 with a flexible pyridine-4-thiolate ligand are explored. We have synthesized mono-, tri- and tetra-iridium complexes containing pyridine-4-thiolato ligand and revealed their novel skeletal transformations from mono-iridium complex to tetra-iridium complex via using base. In addition, two new half-sandwich trinuclear complexes in which the bridging unit [L]~(3-) ([L]~(3-) = 1,3,5-triazine-2,4,6-trithiolato) functions as a tris-bidentate [N,S]~- donor ligand have been synthesized via the reactions of the bridging oxalato complexes with the trisodium salt of 1,3,5-triazine-2,4,6-trithiol, respectively. The reactions of half-sandwich iridium and rhodium complexes with 2-pyridinethione gave the corresponding mononuclear complexes also be studied.
(3) By introducing additional nonlinear spacers between the two pyridine rings of bipyridine, such as the hindered rotation seen in the S-S bond of 4,4'-dipyridyldisulfide (4-DPDS) generates 2:2 M:L macrocyclic compounds. When the bidentate organochalcogen (S,Se) ligands bearing N-methylimidazole groups were used, we assembled several binuclear macrocycles rather than tetranuclear complexes.
(4) Base on the rule of addition reaction at the metal center of [Cp~*Ir[E_2C_2(B_(10)H_(10))] (E=S,Se), both of cluster-based carboranyl complexes and 2,6(7)-bis(4-pyridyl)-1,4,5,8-tetrathiafulvalene or Schiff-based bipyridyl ligands, have been proved to be versatile precursors to accomplish diverse architectures.
(5) Aromatic C-H activation in a series of phenyl dimines was promoted by sodium acetate with [Cp~*MCl_2]_2 (M=Ir,Rh) at room temperature to form dicyclometalated compounds. The unsaturated molecule, dimethylacetylenedicarboxylate, was employed insert into the metal-carbon bonds of the cyclometalated compounds in order to expand the metallocycles. These compounds can be used as "clips", which can be interlinked by pyrazine to build supramolecular rectangles.
(1)合成得到一系列由四个氧原子桥连的双核有机金属化合物(A-D),然后利用其作为起始原料,分别与两齿、三齿和四齿的含氮配体自组装形成具有大环、三棱柱和笼装结构的有机金属超分子化合物。
首先以草酸配体桥连的半夹心结构有机金属双核化合物(A)为起始原料,分别与两齿、三齿和四齿的含氮配体进行配位合成了一系列大环、三棱柱和笼装结构的有机金属超分子化合物。系统研究结果表明,具有不同尺寸的矩形大环化合物由于分子间的相互作用,形成了孔道结构。在化合物[Cp_4~*M_4(μ-bpe)_2(μ-η~2-η~2-C_2O_4)_2](OTf)_4 (M=Ir,Rh;bpe=trans-1,2-bis(4-pyridyl)-ethylene)晶体结构中,两个桥连的4,4'-bpe分子之间由于π-π相互作用,从而使两个分子相互平行靠近,双键之间的距离为3.23 (?),在光照下,可以发生分子内[2+2]光化学反应,而且可以实现晶体到晶体之间的转化。
其次,引入了具有功能性的2,5-二羟基-3,6-二氯苯醌(B)和1,4-羟基-蒽醌(C)作为桥连配体,得到一系列具有不同尺寸大环结构的有机金属超分子化合物。循环伏安结果表明,四核大环化合物有较好的电化学性质。
接着研究了6,11-二羟基-5,12-萘并萘醌为桥连配体的有机金属双核化合物(D)与吡嗪的反应,得到了“分子夹”形状的大环化合物。研究表明此类化合物对有机小分子如二氯甲烷,1,2-氯乙烷具有选择性吸附效应,在同等条件下,可以从混合溶剂的蒸汽中优先选择吸附二氯甲烷分子。进一步研究发现:大环化合物不但可以在晶态下实现二氯甲烷分子的可逆性吸附和脱附,也可以在晶态下实现不同客体分子之间的交换反应。四氯乙烯分子亦可以被“分子夹”形状的大环化合物“吸附”,每个四氯乙烯分子与相邻的四个独立分子之间存在弱相互作用,化合物的空间结构由一维链状结构延伸形成了空间网状结构。当有机金属双核化合物(D)与其它的含氮双齿配体进行反应时,可以得到不同尺寸“分子夹”形状的大环化合物。当有机金属双核化合物(D)与含氮三齿配体反应时,可得到相应的六核三棱柱型化合物,此类化合物的具有较大的空腔体积,研究表明它们可以与具有平面结构的芳香类化合物形成“夹心”型化合物,芳香类化合物镶嵌在六核三棱柱型化合物的空腔内,分子之间存在非常强的π...π相互作用。
(2)利用三种含有N,S配位点的不同配体在不同的反应条件下与[Cp~*MCl_2]_2 (M=Ir,Rh)反应合成了一系列有机金属化合物。首先研究了[Cp~*IrCl_2]_2与4-巯基吡啶配体的反应。当[Cp~*IrCl_2]_2与两倍量的4-巯基吡啶的钠盐在甲醇溶液中进行反应时,得到“三角形”形状的大环化合物;当[Cp~*IrCl_2]_2与六倍量的4-巯基吡啶在二氯甲烷溶液中进行反应时,得到含有半夹心结构的单核化合物;单核化合物可以在三乙胺作用下重新组装成“正方形”形状的大环化合物。当[Cp~*MCl_2]_2 (M=Ir,Rh)与2-巯基吡啶配体进行反应时,可以得到单核的化合物,化合物中存在非常强的分子内氢键。进一步研究表明,草酸配体桥连的含有半夹心结构有机金属双核化合物与2,4,6-三巯基-1,3,5-均三嗪反应时,桥连的草酸根被取代,配体以N,S作为六齿配体与中心金属结合,可以得到两种含有三个金属中心的三核化合物。铱的三核化合物对催化降冰片烯聚合反应具有中等活性。
(3)将具有特定结构的4-DPDS(4,4'-二吡啶基二硫)配体分别与[Cp~*MCl_2]_2 (M=Ir,Rh)或[p-cymene)RuCl_2]_2反应,得到相应的双核化合物,接着与两倍量的银盐反应,可以生成含有两个4-DPDS配体的双核有机金属大环化合物。此外,还研究了不同的溶剂对生成的大环化合物空间结构的影响,发现不同的客体分子可以诱导化合物生成不同的空间排列方式。
(4)利用由-CH_2CH_2-、-CH_2CH_2CH_2-和-CH_2-Ph-CH_2-桥连的双齿中性硫酮类化合物为配体合成了一系列的半夹心结构有机金属化合物。研究结果表明:当配体为-CH_2CH_2CH_2-和-CH_2-Ph-CH_2-桥连的双齿中性硫酮类化合物时,可以生成双核金属大环化合物;当配体为-CH_2CH_2-桥连的双齿中性硫酮类化合物时,生成了一个含有桥基上的C-H活化的化合物。
(5)利用含氮双齿配体构筑了一系列含有半夹心结构有机金属双核碳硼烷化合物。通过改变双齿有机配体的结构,不仅可以调控金属.金属原子间的距离,而且可以合成具有新颖结构的超分子化合物。利用设计合成的含有四硫富瓦烯结构单元的配体与16电子体系碳硼烷化合物发生反应,得到的化合物结构表明分子之间通过硫.硫原子之间的相互作用,形成了独特的“碗状”空间结构,探索了含碳硼烷配体的有机金属孔道结构材料的合成方法。
(6)引入一系列双希夫碱类配体,通过[Cp~*MCl_2]_2 (M=Ir,Rh)诱导苯环上的两个C-H位点同时活化形成了含M-C键的有机金属双核化合物,利用含M-C键的双核金属化合物与炔烃类化合物发生插入反应,形成新一类的有机金属双核化合物,并对此类化合物作为桥连配体用来构筑有机金属大环化合物进行了初步尝试,利用单晶结构表征了含有新M-C键的大环化合物,并且在温和条件下成功实现了此类化合物的后修饰。
Supramolecular chemistry with organometallic half-sandwich complexes based on Ir, Rh, Ru fragments has received considerable attention over recent years. In this dissertation, some results in the rational design and synthesis of organometallic half-sandwich complexes and their potential applications are presented.
(1) The binuclear complexes with two parallel coordination sites, such as oxalate (A), chloranilate (B), 1,4-dihydroxyanthraquinone (C) and 6,11-dihydroxy-5,12-naphthacenedione (D) bridging irdium, rhodium and ruthenium complexes can be served as precursors, which can be interlinked by pyridyl-based ligands.
Following the general design strategy, many supramolecular rectangles, prisms and cages have been synthesized in high yields and characterized structurally. Efforts were paid to the functional properties and applications of these supramolecular structures, such as template-controlled topochemical photodimerization based on "organometallic macrocycles" through single-crystal-to-single-crystal transformation (SCSC), selectively recognize CH_2Cl_2 and ClCH_2CH_2Cl molecules with retention of single crystallinity in "organometallic molecular splints", and a simple, straightforward access to the preparation of metallo-prismatic cages able to encapsulate aromatic molecules was included.
(2) The reactions of [Cp~*IrCl_2]_2 with a flexible pyridine-4-thiolate ligand are explored. We have synthesized mono-, tri- and tetra-iridium complexes containing pyridine-4-thiolato ligand and revealed their novel skeletal transformations from mono-iridium complex to tetra-iridium complex via using base. In addition, two new half-sandwich trinuclear complexes in which the bridging unit [L]~(3-) ([L]~(3-) = 1,3,5-triazine-2,4,6-trithiolato) functions as a tris-bidentate [N,S]~- donor ligand have been synthesized via the reactions of the bridging oxalato complexes with the trisodium salt of 1,3,5-triazine-2,4,6-trithiol, respectively. The reactions of half-sandwich iridium and rhodium complexes with 2-pyridinethione gave the corresponding mononuclear complexes also be studied.
(3) By introducing additional nonlinear spacers between the two pyridine rings of bipyridine, such as the hindered rotation seen in the S-S bond of 4,4'-dipyridyldisulfide (4-DPDS) generates 2:2 M:L macrocyclic compounds. When the bidentate organochalcogen (S,Se) ligands bearing N-methylimidazole groups were used, we assembled several binuclear macrocycles rather than tetranuclear complexes.
(4) Base on the rule of addition reaction at the metal center of [Cp~*Ir[E_2C_2(B_(10)H_(10))] (E=S,Se), both of cluster-based carboranyl complexes and 2,6(7)-bis(4-pyridyl)-1,4,5,8-tetrathiafulvalene or Schiff-based bipyridyl ligands, have been proved to be versatile precursors to accomplish diverse architectures.
(5) Aromatic C-H activation in a series of phenyl dimines was promoted by sodium acetate with [Cp~*MCl_2]_2 (M=Ir,Rh) at room temperature to form dicyclometalated compounds. The unsaturated molecule, dimethylacetylenedicarboxylate, was employed insert into the metal-carbon bonds of the cyclometalated compounds in order to expand the metallocycles. These compounds can be used as "clips", which can be interlinked by pyrazine to build supramolecular rectangles.
引文
[1] Pedersen, C. J. "Cyclic polyethers and their complexes with metal salts." [J] J. Am. Chem.Soc.1967,89,7017 - 7036.
[2]Cram,D.J.;Cram,J.M.“Host-Guest Chemistry-Complexes between Organic Compound Simulate the Substrate Selectivity of Enzymes.” [J]Science 1974,183,803 - 805.
[3]J.-M.Lehn,“Cryptates:inclusion complexes of macropolycyclic receptor molecules.” [J]Pure Appl.Chem.1978,50,871 - 875.
[4]J.-M.Lehn,“Supermolecular Chemistry Scope and Perspectives of Molecules,Supramolecules,and Molecular Devices.”[J]Angew.Chem.Int.Ed.1988,27,89-112.
[5]J.-M.Lehn,“Design of organic complexing agents.Strategies towards properties.” [J]Struct.Bonding 1973,16,1 - 9.
[6]James,S.L.“Metal-organic Frameworks.”[J]Chem.Soc.Rev.2003,32,276 - 288.
[7]Fujita,M.;Yazaki,J.;Ogura,K.“Preparation of a macrocyclic polynuclear complex,[(en)Pd(4,4'-bpy)]4(N03)8 (en = ethylenediamine,bpy = bipyridine),which recognizes an organic molecule in aqueous media.”[J]J.Am.Chem.Soc,1990,112,5645 - 5647
[8](a) Stang,P.J.;Olenyuk,B.“Self-assembly,symmetry,and molecular architecture:Coordination as the motif in the rational design of supramolecular metallacyclic polygons and polyhedra.”[J]Acc.Chem.Res.1997,30,502 - 518;(b) Leininger,S.;Olenyuk,B.;Stang,P.J.“Self-Assembly of Discrete Cyclic Nanostructures Mediated by Transition Metals.”[J]Chem.Rev.2000,100,853 - 907.(c) Seidel,S.R.;Stang,P.J.“High-Symmetry Coordination Cages via Self-Assembly.”[J]Acc.Chem.Res.2002,35,972 - 983.
[9]Cho,Y.L.;Uh,H.;Chang,S.-Y.;Chang,H.-Y.;Choi,M.-G.;Shin,I.;Jeong,K.-S.“A Double-Walled Hexagonal Supermolecule Assembled by Guest Binding.”[J]J.Am.Chem.Soc.2001,123,1258 -1259
[10]Fujita,M.;Tominaga,M.;Hori,A.;Therrien,B.“Coordination Assemblies from a Pd(Ⅱ)-Cornered Square Complex.”[J]Acc.Chem.Res.2005,38,369 - 378.
[11](a) Fujita,M.;Oguro,D.;Miyazawa,M.;Oka,H.;Yamaguchi,K.;Ogura,K."Self-assembly of ten molecules into a nanometer-sized organic host frameworks.”[J]Nature 1995,578,469 - 471.(b) Takeda,N.;Umemoto,K.;Yamaguchi K.;Fujita,M.“A nanometersized hexahedral coordination capsule assembled from 24 components.” [J]Nature 1999,398,794-796.
[12](a)Kusukawa,T.;Fujita,M.“Encapsulation of large,neutral molecules in a self-assembled nanocage incorporating six palladium(Ⅱ)ions.” [J]Angew.Chem.Int.Ed.1998,37,3142-3144.(b) Kusukawa,T.;Fujita,M.'“Ship-in-a-bottle” formation of stable hydrophobic dimers of cis-azobenzene and-stilbene derivatives in a self-assembled coordination nanocage.” [J]J.Am.Chem.Soc.1999,121,1397-1398.
[13]Kusukawa,T.;Yoshizawa,M.;Fujita,M.“Probing guest geometry and dynamics through host-guest interactions.” [J]Angew.Chem.Int.Ed.2001,40,1879-1884.
[14]Kusukawa,T.;Fujita,M.“Self-assembled M_6L_4-type coordination nanocage with 2,2'-bipyridine ancillary ligands.Facile crystallization and X-ray analysisof shape-selective enclathration of neutral guests in the cage.” [J]J.Am.Chem.Soc.2002,124,13576-13582.
[15]Ito,H.;Kusukawa,T.;Fujita,M.“Wacker oxidation in an aqueous phase through the reverse phase-transfer catalysis of a selfassembled nanocage.” [J]Chem.Lett.2000,598-599.
[16]Umemoto,K.;Yamaguchi,K.;Fujita,M.“Molecular paneling via coordination:Guest-controlled assembly of open cone and tetrahedron structures from eight metals and four ligands.” [J]J.Am.Chem.Soc.2000,122,7150-7151.
[17]Kumazawa, K.; Biradha, K.; Kusukawa, T.; Okano, T.; Fujita, M.“Multicomponent assembly of a pyrazine-pillared coordination cage that selectively binds planar guests by intercalation.” [J]Angew.Chem.Int.Ed.2003,42,3909-3913.
[18]Fujita,N.;Biradha,K.;Fujita,M.;Sakamoto,S.;Yamaguchi,K.“A porphyrin prism:Structural switching triggered by guest inclusion.” [J]Angew.Chem.Int.Ed.2001,40,1718-1721.
[19]Yamanoi,Y.;Sakamoto,Y.;Kusukawa,T.;Fujita,M;Sakamoto,S.;Yamaguchi,K.“Dynamic assembly of coordination boxes from (en)Pd(Ⅱ)unit and a rectangular panel-like ligand:NMR,CSI-MS,and X-ray studies.” [J]J.Am.Chem.Soc.2001,123,980-981.
[20]Aoyagi,M.;Biradha,K.;Fujita,M.“Quantitative formation of coordination nanotubes templated by rodlike guests.” [J]J.Am.Chem.Soc.1999,121,7457-7458.
[21]Tominaga,M.;Tashiro,S.;Aoyagi,M.;Fujita,M.“Dynamic aspects in host-guest complexation by coordination nanotubes.” [J]Chem.Commun.2002,2038-2039.
[22]Aoyagi,M.;Tashiro,S.;Tominaga,M.;Biradha,K.;Fujita,M.“Spectroscopic and crystallographic studies on the stability of selfassembled coordination nanotubes.”[J]Chem.Commun.2002,2036-2037.
[23]Tashiro,S.;Tominaga,M.;Kusukawa,T.;Kawano,M.;Sakamoto,S.;Yamaguchi,K.;Fujita,M.“Pd(Ⅱ)-directed dynamic assembly of a dodecapyridine ligand into end-capped and open tubes:The importance of kinetic control in self-assembly.”Angew.Chem.Int.Ed.2003,42,3267-3270.
[24](a)Fujita,M.“Metal-directed self-assembly of two-and threedimensional synthetic receptors.” [J]Chem.Soc.Rev.1998,27,417-425.(b)Fujita,M.;Umemoto,K.;Yoshizawa,M.;Fujita,N.;Kusukawa,T.;Biradha,K.“Molecular paneling via coordination.” [J]Chem.Commun.2001,509-518.
[25]Kumazawa,K.;Yamanoi,Y.;Yoshizawa,M.;Kusukawa,T.;Fujita,M.A “Palladium(Ⅱ)-clipped aromatic sandwich.”[J]Angew.Chem.Int.Ed.2004,43,5936-5940.
[26](a)Yoshizawa,M.;Takeyama,Y.;Kusukawa,T.;Fujita,M.“Cavitydirected,highly stereoselective [2+2]photodimerization of olefins within self-assembled coordination cages.” [J]Angew.Chem.Int.Ed.2002,41,1347-1349.(b)Yoshizawa,M.;Takeyama,Y.;Okano T.;Fujita,M.“Cavity-directed synthesis within a self-assembled coordination cage:highly selective [2+2]cross-photodimerization of olefins.” [J]J.Am.Chem.Soc.2003,125,3243-3247.
[27](a)Tashiro,S.;Tominaga,M.;Kawano,M.;Therrien,B.;Ozeki,T.;Fujita,M.“Sequence-Selective Recognition of Peptides within the Single Binding Pocket of a Self-Assembled Coordination Cage.” [J]J.Am.Chem.Soc.2005,127,4546-4547.(b)Yoshizawa,M.;Tamura,M.;Fujita,M.“Diels-Alder in Aqueous Molecular Hosts:Unusual Regioselectivity and Efficient Catalysis.” [J]Science 2006,312,251-254.(c)Nishioka,Y.;Yamaguchi,T.;Yoshizawa,M.;Fujita,M.“Unusual [2 + 4]and [2 + 2]Cycloadditions of Arenes in the Confined Cavity of Self-Assembled Cages.” [J]J.Am.Chem.Soc.2007,129,7000-7001.(d)Furusawa,T.;Kawano,M.;Fujita,M.“The Confined Cavity of a Coordination Cage Suppresses the Photocleavage of α-Diketones To Give Cyclization Products through Kinetically Unfavorable Pathways.” [J]Angew.Chem.Int.Ed.2007,46,5717-5719.(e)Yamaguchi,T.;Fujita,M.“Highly Selective Photomediated 1,4-Radical Addition to o-Quinones Controlled by a Self-Assembled Cage.” [J]Angew.Chem.Int.Ed.2008,47,2067-2069.
[28](a)Pluth,M.D.;Bergman,R.G.;Raymond,K.N.“Acid Catalysis in Basic Solution:A Supramolecular Host Promotes Orthoformate Hydrolysis.” [J]Science 2007,316,85-88.(b)Leung,D.H.;Bergman,R.G.;Raymond,K.N.“Highly Selective Supramolecular Catalyzed Allylic Alcohol Isomerization.” [J]J.Am.Chem.Soc.2007,129,2746-2747.(c)Fiedler,D.;Leung,D.H.;Bergman,R.G.;Raymond,K.N.“Selective Molecular Recognition,C-H Bond Activation,and Catalysis in Nanoscale Reaction Vessels.” [J]Acc.Chem.Res.2005,38,351-360.(d)Fiedler,D.;Bergman,R.G.;Raymond,K.N.“Stabilization of Reactive Organometallic Intermediates inside a Self-Assembled Nanoscale Host.” [J]Angew.Chem.Int.Ed.2006,45,745-748.
[29]Merlau,M.L.;del Pilar Mejia,M.;Nguyen,S.T.;Hupp,J.T.“Artificial Enzymes Formed through Directed Assembly of Molecular Square Encapsulated Epoxidation Catalysts.” [J]Angew.Chem.Int.Ed.2001,40,4239-4242.
[30](a)Farrell,J.R.;Mirkin,C.A.;Guzei,I.A.;Liable-Sands,L.M.;Rheingold,A.L.“The weak-link approach to the synthesis of inorganic macrocyles.” [J]Angew.Chem.Int.Ed.1998,37,465-467.(b)Holliday,B.J.;Farrell,J.R.;Mirkin,C.A.;Lam,K.-C;Rheingold,A.L.“Metal-directed assembly of triple-layered fluorescent metallcyclophanes.” [J]J.Am.Chem.Soc.1999,121,6316-6317.
[31](a)Liu,X.;Eisenberg,A.H.;Stern,C.L.;Mirkin,C.A.“Flexible redoxactive binuclear macrocycles formed via the weak-link approach and novel hemilabile ligands with N,N,N',N'-tetramethyl-1,4-phenylenediamine units.” [J]Inorg.Chem.2001,40,2940-2941.(b)Holliday,B.J.;Mirkin,C.A.Strategies for the Construction of Supramolecular Compounds through Coordination Chemistry.Angew.Chem.Int.Ed.2001,40,2022-2043.
[32]Ovchinnikov,M.V.;Holliday,B.J.;Mirkin,C.A.;Zakharov,L.N.;Rheingold,A.L.“Threefold symmetric trimetallic macrocycles formed via the weak-link approach.”[J]Proc.Natl.Acad.Sci.U.S.A.2002,99,4927-4931.
[33](a)Eisenberg,A.H.;Ovchinnikov,M.V.;Mirkin,C.A.“Stepwise formation of heterobimetallic macrocycles synthesized via the weak-link approach.” [J]J.Am.Chem.Soc.2003,125,2836-2837.(b)Gianneschi,N.C;Bertin,P.A.;Nguyen, S.T.;Mirkin,C.A.;Zakharov,L.N.;Rheingold,A.L.“A supramolecular approach to an allosteric catalyst.”J.Am.Chem.Soc.2003,125,10508-10509.
[34](a)Khoshbin,M.S.;Ovchinnikov,M.V.;Mirkin,C.A.;Zakharov,L.N.;Rheingold,A.L.“Binuclear ruthenium macrocycles formed via the weak-link approach.”Inorg.Chem.2005,44,496-501.(b)Brown,A.M.;Ovchinnikov,M.V.;Mirkin,C.A.“Heteroligated Rh(Ⅰ)tweezer complexes.” [J]Angew.Chem.Int.Ed.2005,44,4207-4209.
[35](a)Gianneschi,N.C;Masar,M.S.,Ⅲ;Mirkin,C.A.“Development of a Coordination Chemistry-Based Approach for Functional Supramolecular Structures.” [J]Acc.Chem.Res.2005,38,825-837.(b)Brown,A.M.;Ovchinnikov,M.V.;Stern,C.L.;Mirkin,C.A.“Tetrametallic Rectangular Box Complexes Assembled from Heteroligated Macrocycles.” [J]Chem.Commun.2006,4386-4388.(c)Brown,A.M.;Ovchinnikov,M.V.;Stern,C.L.;Mirkin,C.A.“Halide-Induced Supramolecular Ligand Rearrangement.” [J]J.Am.Chem.Soc.2004,726;14316-14317.
[36](a)Oliveri,C.G.;Gianneschi,N.C;Nguyen,S.T.;Mirkin,C.A.;Stern,C.L.;Wawrzak, Z.; Pink, M. “Supramolecular Allosteric Cofacial Porphyrin Complexes.” [J]J.Am.Chem.Soc.2006,128,16286-16296.(b)Oliveri,C.G.;Heo,J.;Nguyen,S.T.;Mirkin,C.A.;Wawrzak,Z.“A Convergent Coordination Chemistry-Based Approach to Dissymmetric Macrocyclic Cofacial Porphyrin Complexes.”[J]Inorg.Chem.2007,46,7716-7718.(c)Oliveri,C.G.;Nguyen,S.T.;Mirkin,C.A.“A Highly Modular and Convergent Approach for the Synthesis of Stimulant-Responsive Heteroligated Cofacial Porphyrin Tweezer Complexes.”[J]Inorg.Chem.2008,47,2755-2763.
[37](a)Angaridis,P.;Berry,J.F.B.;Cotton,F.A.;Murillo,C.A.;Wang,X.“Molecular Squares with Paramagnetic Diruthenium Corners: Synthetic and Crystallographic Challenges.”[J]J.Am.Chem.Soc.2003,125,10327-10334.(b)Cotton,F.A.;Lin,C;Murillo,C.A.“Supramolecular Arrays Based on Dimetal Building Units.”[J]Acc.Chem.Res.2001,34,759-771.
[38]Benkstein,K.D.;Hupp,J.T.;Stern,C.L.“Molecular Rectangles Based on Rhenium(Ⅰ)Coordination Chemistry.” [J]J.Am.Chem.Soc.1998,120,12982-12983.
[39]Lee,S.J.;Lin,W.“Chiral Metallocycles:Rational Synthesis and Novel Applications.”[J]Acc.Chem.Res.2008,41,521-537.
[40]Albrecht,M.'“Let's Twist Again”-Double-Stranded,Triple-Stranded,and Circular Helicates.”[J]Chem.Rev.2001,101,3457-3497.
[41]Chi,K.W.;Addicott,C;Stang,P.J.“Ambidentate Pyridyl-carboxylate Ligands in the Coordination-Driven Self-Assembly of 2D Pt Macrocycles:Self-Selection for a Single Isomer.” [J]J.Am.Chem.Soc.2004,126,16569-16574.
[42]Addicott,C;Das,N.;Stang,P.J.“Self-Recognition in the Coordination Driven Self-Assembly of 2-D Polygons.”[J]Inorg.Chem.2004,43,5335-5338.
[43]Olenyuk,B.;Whiteford,J.A.;Fechtenkotter,A.;Stang,P.J.“Self-Assembly of Nanoscale Cuboctahedra by Coordination Chemistry.”[J]Nature 1999,398,796-799.
[44]Olenyuk,B.;Levin,M.D.;Whiteford,J.A.;Shield,J.E.;Stang,P.J.“Self-Assembly of Nanoscopic Dodecahedra from 50 Predesigned Components”[J]J.Am.Chem.Soc.1999,121,10434-10435.
[45]Resendiz,M.J.E.;Noveron,J.C;Disteldorf,H.;Fischer,Sonja.;a Stang,P.J.“A Self-Assembled Supramolecular Optical Sensor for Ni(Ⅱ),Cd(Ⅱ),and Cr(Ⅲ)”[J]Org.Lett.2004,6,651-653.
[46]G.Oliveri,Pirmin A.Ulmann,Michael J.Wiester,and Chad A.Mirkin,“Heteroligated Supramolecular Coordination Complexes Formed via the Halide-Induced Ligand Rearrangement Reaction Christopher.” [J]Acc.Chem.Res.2008,47,1618-1629.
[47](a)Fish,R.H.“Bioorganometallic chemistry:synthesis,structure,and molecular recognition chemistry of (η~5-pentamethylcyclopentadienyl)-rhodium-DNA/RNA complexes in water.” [J]Coord.Chem.Rev.1999,185-186,569.(b)Fish,R.H.;Jaouen.G.“Bioorganometallic Chemistry:Structural Diversity of Organometallic Complexes with Bioligands and Molecular Recognition Studies of Several Supramolecular Hosts with Biomolecules,Alkali-Metal Ions,and Organometallic Pharmaceuticals.” [J]Organometallics 2003,22,2166-2177.
[48]Annen,P.;Schildberg,S.;Sheldrick,W.S.“(η~5-Pentamethylcyclopentadienyl)-iridium(Ⅲ)complexes of purine nucleobases and nucleotides:a comparison with (η~6-arene)ruthenium(Ⅱ)and (η~5-pentamethylcyclopentadienyl)rhodium(Ⅲ)species.” Inorg.Chim.Acta 2000,307,115-124.
[49](a)Yamanari,K.;Ito,R.;Yamamoto,S.;Konno,T.;Fuyuhiro,A.;Fujioka,K.;Arakawa,R.“Cyclic Tetramers Composed of Rhodium(Ⅲ),Iridium(Ⅲ),or Ruthenium(Ⅱ)Half-Sandwich and 6-Purinethiones.” [J]Inorg.Chem.2002,41, 6824-6830. (b) Yamanari, K.; Yamamoto, S.; Ito, R.; Kushi, Y.; Fuyuhiro, A.; Kubota, N.; Fukuo, T.; Arakawa, R. "Cyclic Hexamer with a Cubic Cavity: Crystal Structure of [{Rh(6-Purinethione Ribosido)(Cp~*)}_6](CF_3SO_3)_6." [J] Angew. Chem. Int. Ed. 2001, 40,2268 - 2271.
[50] Carmona, D.; Lamata, M. P.; Viguri, F.; Dobrinovich, I.; Lahoz, F. J.; Oro, L. A. "On the Sense of the Enantioselection in Hydrogen Transfer Reactions from 2-Propanol to Ketones." [J] Adv. Synth. Catal. 2002, 344,499 - 502.
[51] Katho, (?).; Carmona, D.; Viguri, F.; Remacha, C. D.; Kov(?)cs, J.; Jo(?), F.; Oro, L. A. "Enantioselective hydride transfer hydrogenation of ketones catalyzed by [(η~6-p-cymene)Ru(amino acidato)Cl] and [(η~6-p-cymene)Ru(amino acidato)]_3(BF_4)_3 complexes." [J] J. Organomet. Chem. 2000, 593-594, 299-306.
[52] Carmona, D.; Lahoz, F. J.; Atencio, R.; Oro, L. A.; Lamata, M. P.; Viguri, F.; Jos(?), E. S.; Vega, C.; Reyes, J.; Jo(?), F.; Kath(?), (?). "Trimerisation of the Cationic Fragments [(η-ring)M(Aa)]~+ ((η-ring) M=(η~5-C~5Me~5)Rh, (η~5-C~5Me~5)Ir, (η ~6-p-MeC_6H_4iPr)Ru; Aa= α-amino acidate) with Chiral Self-Recognition: Synthesis, Characterisation, Solution Studies and Catalytic Reactions of the Trimers [{η-ring)M(Aa)}_3](BF_4)_3." [J] Chem. Eur. J. 1999, 5,1544 -1564.
[53] Kramer, R.; Polborn, K.; Robl, C.; Beck, W. "Metal complexes of biologically important ligands. Part LXIV. Pentamethylcyclopentadienyl-rhodium(Ⅲ) complexes with a-amino acid derivatives as bridging ligands and with several chiral metal centers: synthesis and structure of [Cp~*Rh(μ- L -phenylalaninato)]_3(BF_4)_3 and [Cp~*Rh(μ-NHCOCH_2NCO_2CH_2Ph)]_2." [J] Inorg. Chim. Acta 1992, 198-200, 415 - 420.
[54] (a) Severin. K. "Supramolecular Chemistry with Organometallic Half-sandwich Complexes." [J] Chem. Comm. 2006, 3859 - 3867. (b) Severin K. "Self-Assembled Organometallic Receptors for Small Ions." [J] Coord. Chem.Rev. 2003,245, 3-10.
[55] (a) Grote, Z.; Scopelliti, R.; Severin, K. "Controlled Formation of Mixed-Metal Macrocycles Using Dynamic Exchange Processes and Steric Constraints." [J] Eur. J. Inorg. Chem. 2007, 694-700. (b) Olivier, C.; Solari, E.; Scopelliti, R.; Severin, K. "Breaking the Symmetry: Assembly of Cylindrical Nanostructures with a C_3-Symmetrical Ligand." [J] Inorg. Chem. 2008, 47,4454 - 4456.
[56] (a) Suzuki, H.; Tajima N.; Tatsumi, K.; Yamamoto, Y. "Molecular architecture via coordination: quasi-octahedral macrocycles of rhodium and iridium bearing a pentamethylcyclopentadienyl group." [J] Chem. Commun., 2000,1801 -1802. (b) Yamamoto, Y.; Suzuki, H.; Tajima N.; Tatsumi, K. Stepwise Formation of Quasi-Octahedral Macrocyclic Complexes of Rhodium(Ⅲ) and Iridium(Ⅲ) Bearing a Pentamethylcyclopentadienyl Group. Chem. -Eur. J. 2002, 8, 372 -379.
[57] Han, W. S.; Lee, S. W. "Various forms of linear dipyridyls in discrete rectangles, dinuclear rods, and one-dimensional networks containing (η~5-pentamethylcyclo- pentadienyl)rhodium(Ⅲ)" [J] Dalton Trans. 2004,2656 -1663.
[58] (a) Yan, H.; S(?)ss-Fink, G.; Neels A.; Stoeckli-Evans, H. "Mono-, Di- and Tetra-nuclear p-Cymeneruthenium Complexes Containing Oxalato Ligands." [J] Dalton Trans. 1997, 4345-4350. (b) Govindaswamy, P.; Linder, D.; Lacour, J.;Suss-Fink, G.; Therrien, B. "Chiral or Not Chiral? A Case Study of the Hexanuclear Metalloprisms Cp_6~*M_6(μ_3-tpt-kN)_2(μ-C_2O_4-kO)_3]~(6+) (M = Rh, Ir, tpt = 2,4,6-tri(pyridin-4-yl)-1,3,5-triazine)." [J] Dalton Trans. 2007, 4457-4463. (c) Govindaswamy, P.; Linder, D.; Lacour, J.; Suss-Fink, G.; Therrien, B. "Self-Assembled Hexanuclear Arene Ruthenium Metallo-Prisms with Unexpected Double Helical Chirality." [J] Chem. Commun. 2006, 4691-4693. (d) Govindaswamy, P.; S(?)ss-Fink, G.; Therrien, B. "Self-Assembled Chloro-Bridged (Arene)ruthenium Metallo-Prisms: Synthesis and Molecular Structure of Cationic Complexes of the Type [Ru_6(η~6-arene)_6(μ_3-tpt-κN)_2(μ-Cl)_6]~(6+)." [J] Organometallics 2007, 26, 915-924. (e) Therrien, B.; Siiss-Fink, G.; Govindaswamy, P.; Renfrew, A. K.; Dyson, P. J. "The "Complex-in-a-Complex" Cations [(acac)~2M(?)Ru~6(p-~iPrC_6H_4Me)_6(tpt)_2 (dhbq)_3]~(6+): A Trojan Horse for Cancer Cells." [J] Angew. Chem. Int. Ed. 2008,47, 3773 - 3776.
[59] Boyer, J. L.; Kuhlman, M. L.; Rauchfuss, T. B. "Evolution of Organo- Cyanometallate Cages: Supramolecular Architectures and New Cs~+-Specific Receptors." [J] Acc. Chem. Res. 2007,40, 233 - 242.
[60] (a) Wang, J.-Q.; Zhang, Z.; Weng, L.-H.; Jin, G.-X. "Synthesis and Characterization of Organometallic Macrocyclic Rhodium (Ⅲ) Complex with Pyrazine Ligangds." [J] Chin. Sci. Bull. 2004, 49, 1122-1125. (b) Wang, J.-Q.; Ren C.-X.; Jin, G.-X. "Synthesis and Structural Characterization of Macrocyclic Half-Sandwich Rhodium(Ⅲ) and Iridium(Ⅲ) Complexes Bearing Bipyridyl Derivatives and Terephthalate." [J] Organometallics 2006,25, 74 - 81.
[1] (a) Zhang, B.; Zhang, Y.; Zhang, J. B.; Li, J. C.; Zhu, D. B. "A neutral molecular-based layered magnet [Fe(C_2O_4)(CH_3OH)](n) exhibiting magnetic ordering at T-N approximate to 23 K." [J] Dalton Trans. 2008, 5037 - 5040. (b) Duan, Z. M.; Zhang, Y.; Zhang, B.; Zhu, D. B. "Co(C_2O_4)(HO(CH_2)_3OH): An Antiferromagnetic Neutral Zigzag Chain Compound Showing Long-Range Ordering of Spin Canting." [J] Inorg. Chem. 2008,47, 9152 - 9154.
[2] (a) Zhang, B.; Wang, Z. M.; Zhang, Y.; Takahashi, K.; Okano, Y.; Cui, H.; Kobayashi, H.; Inoue, K.; Kurmoo, M.; Pratt, F. L.; Zhu, D. B. "Hybrid organic-inorganic conductor with a magnetic chain anion: k-BETS_2[Fe~(Ⅲ)(C_2O_4)Cl_2] [BETS = bis(ethylenedithio)tetraselenafulvalene]." [J] Inorg. Chem. 2006, 45, 3275 - 3280. (b) Xu, H. B.; Wang, Z. M.; Liu, T.; Gao, S. "Synthesis, structure, and magnetic properties of (A)[Fe~(Ⅲ)(oxalate)Cl_2] (A = alkyl ammonium cations) with anionic 1D [Fe~(Ⅲ)(oxalate)Cl_2]~- chains." [J] Inorg. Chem. 2007, 46, 3089 - 3096.
[3] (a) Coronado, E.; Galan-Mascaros, J. R.; Marti-Gastaldo, C.; Martinez, A. M. "Heptacoordinated Mn-Ⅱ in oxalate-based bimetallic 2D magnets: synthesis and characterisation of [Mn(L)_6][Mn(CH_3OH)M~(Ⅲ)(ox)_3]_2 (M~(Ⅲ) = Cr, Rh; ox = oxalate dianion; L = H_2O, CH_3OH)." [J] Dalton Trans. 2006, 3294 - 3299. (b) Clemente -Leon, M.; Coronado, E.; Dias, J. C.; Soriano-Portillo, A.; Willett, R. "Synthesis, structure, and magnetic properties of [(S)-[PhCH(CH_3)N(CH_3)_3]] [Mn(CH_3CN)_(2/3)Cr(OX)_3]-(CH_3CN)_(solvate), a 2D chiral magnet containing a quaternary ammonium chiral cation." [J] Inorg. Chem. 2008, 47, 6458 - 6463.
[4] Decurtins, S.; Pellaux, R.; Antorrena, G.; Palacio, F. "Multifunctional coordination compounds: design and properties." [J] Coord. Chem. Rev. 1999, 192, 841 - 854.
[5] (a) Wang, X. Y.; Wang, Z. M.; Gao, S. "Constructing magnetic molecular solids by employing three-atom ligands as bridges." [J] Chem. Commun. 2008,281 - 294. (b) Zhiming Duan, Z. M.; Zhang, Y.; Zhang, B.; Pratt, F. L. "Two Homometallic Antiferromagnets Based on Oxalato-Bridged Honeycomb Assemblies:(A)_2[M~Ⅱ (C_2O_4)_3](A = Ammonium Salt Derived from Diethylenetriamine;M~Ⅱ = Fe~(2+),Co~(2+)).“ [J]Inorg.Chem.,2009,48,2140-2146.
[6](a)Hursthouse,M.B.;Light,M.E.;Price,D.J.“One-dimensional magnetism in anhydrous iron and cobalt ternary oxalates with rare trigonal-prismatic metal coordination environment.” [J]Angew.Chem.,Int.Ed.2004,43,472-475.(b)Li,L.L.;Lin,K.;Ho,C.J.;Sun,C.P.;Yang,H.D.“A coordination pi-pi framework exhibits spontaneous magnetization.”[J]Chem.Commun.2006,1286-1288.(c)Coronado,E.;Galan-Mascaros,J.R.;Marti-Gastaldo,C.“Single Chain Magnets Based on the Oxalate Ligand.” [J]J.Am.Chem.Soc.2008,130,14987-14989.
[7]Tamaki,H.;Zhang,Z.J.;Matusmoto,N.;Kida,S.;Koikawa,M.;Achiwa,N.;Hashimoto,Y.;Okawa,H.“Design of metal-complex magnets-syntheses and magnetic-properties of mixed-metal assemblies (NBU4[MCR(OX)_3])_x(NBU~(4+)=Tetra(Normal-Butyl)Ammonium Ion OX~(2-)= Oxalate Ion M= Mn~(2+),Fe~(2+),Co~(2+),Ni~(2+),Cu~(2+),Zn~(2+)).” [J] J.Am.Chem.Soc.1992,114,6974-6979.
[8](a)Hemandez-Molina,M.;Lloret,F.;Ruiz-Perez,C;Julve,M.“Weak ferromagnetism in chiral 3-dimensional oxalato-bridged cobalt(Ⅱ)compounds.Crystal structure of [Co(bpy)_3][Co_2(ox)_3]ClO_4.” [J]Inorg.Chem.1998,37,4131-4135.(b)Armentano,D.;Munno,G.D.;Mastropietro,T.F.;Lloret,G.;Julve,M.“A novel supramolecular assembly in an iron(Ⅲ)compound exhibiting magnetic ordering at 70 K.” [J]Chem.Commun.2004,1160-1161.(c)Armentano,D.;Munno,G.D.;Mastropietro,T.F.;Julve,M.;Lloret,F.“Intermolecular proton transfer in solid phase:A rare example of crystal-to-crystal transformation from hydroxo-to oxo-bridged iron(Ⅲ)molecule-based magnet.” [J]J.Am.Chem.Soc.2005,127,10778-10779.
[9](a)Coronado,E.;Galan-Mascaros,J.R.;Gomez-Garcia,C.J.;Laukhin,V.“Coexistence of ferromagnetism and metallic conductivity in a molecule-based layered compound.” [J]Nature 2000,408,447-449.(b)Ballester,G.;Coronado,E.;Giemenez-Saiz,C;Romero,F.M.“Nitroxide radicals as templating agents in the synthesis of magnets based on three-dimensional oxalato-bridged heterodimetallic networks.” [J]Angew.Chem.,Int.Ed.2001,40,792-795.(c)Alberola,A.;Coronado,E.;Galan-Mascaros,J.R.;Gimenez-Saiz,C;Gomez-Garcia,C.J.“A molecular metal ferromagnet from the organic donor bis(ethylenedithio)tetraselenafulvalene and bimetallic oxalate complexes.” [J]J. Am.Chem.Soc.2003,125,10774-10775.(d)Coronado,E.;Galan-Mascaros,J.R.;Marti-Gastaldo,C.“Synthesis and characterization of a soluble bimetallic oxalate-based bidimensional magnet:[K(18-crown-6)]_3[Mn_3(H_2O_4[Cr(ox)_3]_3].” [J]Inorg.Chem.2006,45,1882-1884.
[10](a)Cariati,E.;Macchi,R.;Roberto,D.;Ugo,R.;Galli,S.;Casati,N.;Macchi,P.;Sironi,A.;Bogani,L.;Caneschi,A.;Gatteschi,D.“Polyfunctional inorganic-organic hybrid materials:An unusual kind of NLO active layered mixed metal oxalates with tunable magnetic properties and very large seond harmonic generation.” [J]J.Am.Chem.Soc.2007,129,9410-9420.(b)Train,C;Gheorghe,R.;Krstic,V.;Chamoreau,L.;Ovanesyan,N.S.;Rikken,G.L.;Gruselle,M.;Verdaguer,M.“Strong magneto-chiral dichroism in enantiopure chiral ferromagnets.” [J]Nature Mater.2008,7,729-734.
[11]White C.,Yates A.,Maitlis,P.M.“η~5-pentamethylcyclopentadienyl Rhodium and Iridium compounds.” [J]Inorg.Synth.1992,29,228-230.
[12]Bennett M.A.,Smith A.K.,“Arene ruthenium(Ⅱ)complexes formed by dehydrogenation of cyclohexadienes with ruthenium(Ⅲ)trichloride.” [J]J.Chem.Soc,Dalton Trans.1974,233-241.
[13]Grotjahn,D.B.;Lo,H.C;Dinoso,J.;Adkins,C.D.;Li,C;Nolan,S.P.;Hubbard,J.L.“Studies of the Synthesis and Thermochemistry of Coordinatively Unsaturated Chelate Complexes (η~5-C_5Me_5)IrL_2 (L_2 = TsNCH_2CH_2NTs,TsNCH_2CO_2,CO_2CO_2).” [J]Inorg.Chem.2000,39,2493-2499.(b)Grotjahn,D.B.;Groy,T.L.“Formation of Coordinatively Unsaturated Cp~*Ir-Amino Acid Complexes and Their Highly Diastereoselective Complexation Reactions.” [J]J.Am.Chem.Soc.1994,116,6969-6970.(c)Grotjahn,D.B.;Groy,T.L.“Formation and Structure of Coordinatively Unsaturated CpIr-Amino Acid Complexes.Kinetic and Thermodynamic Control in Highly Diastereoselective Complexation Reactions.” [J]Organometallics 1995,14,3669-3682.
[14]Yan,H.;S(u|¨)ss-Fink,G.;Neels A.;Stoeckli-Evans,H.“Mono-,di-and tetra-nuclear p-cymeneruthenium complexes containing oxalato ligands.” [J]J.Chem.Soc.Dalton Trans.1997,4345-4350.
[15]J.-Q.Wang,C.-X.Ren,G.-X.Jin,“Route to multicluster containing ancillary ortho-carborane-1,2-dithiolato ligands.” [J]Chem.Comm.2005,4738-4740.
[16]Nakamoto,K.“Infrared and Raman Spectra of Inorganic and Coordination Compounds,Part B,5th ed.” Wiley:New York,1997;pp 74-77.
[17] (a) Coucouvanis, D.; Demadis, K. D.; Kim, C. G.; Dunham, R. W.; Kampf, J. W. "Single and double MoFe_3S_4 cubanes with Mo-coordinated polycarboxylate ligands - syntheses and structural characterization of (Et_(4n))_4([MoFe_3S_4Cl_4]_2 (μ-C_2O_4)) And (Et_(4n))_3[MoFe_3S_4Cl_4(C_2O_4)] clusters." [J] J. Am. Chem. Soc. 1993, 115, 3344 - 3345. (b) Castro, I.; Calatayud, M. L.; Sletten, J.; Lloret, F.; Julve, M. "Syntheses, crystal structures and magnetic properties of [Ni_2(C_2O_4)(tren)2][ClO_4]_2 and [Ni_2(C_4O_4)(tren)_2(H_2O)_2][ClO_4]_2 [tren equals tris(2-amino-ethyl)amine]." [J] J. Chem. Soc., Dalton Trans. 1997, 811 - 817. (c) Shinozaki, K.; Takahashi, N. "Molecular orbital calculations and spectroscopic study of the photochemical generation of bis(2,2'-bipyridine)rhodiuria(Ⅰ) from bis(2,2'-bipyridine)(oxalato)rhodium(Ⅲ." [J] Inorg. Chem. 1996, 35, 3917 -3924.
[18] Holloway, G. A.; Rauchfuss, T. B. "Direct observation of ligand-centered redox in Cp~*Rh_2(μ-C_2S_4)Cl_x (x=2, 0)." [J] Inorg. Chem. 1999, 38, 3018 - 3019.
[19] Grotjahn, D. B.; Lo, H. C.; Dinoso, J.; Adkins, C. D.; Li, C.; Nolan, S. P.; Hubbard, J. L. "Studies of the Synthesis and Thermochemistry of Coordinatively Unsaturated Chelate Complexes (η~5-C_5Me_5)IrL_2 (L_2 = TsNCH_2CH_2NTs, TsNCH_2CO_2, CO_2CO_2)." [J] Inorg. Chem. 2000, 39; 2493 - 2499.
[20] Wang, J.-Q.; Ren, C.-X.; Jin, G.-X. "Synthesis and structural characterization of macrocyclic half-sandwich rhodium(Ⅲ) and iridium(Ⅲ) complexes bearing bipyridyl derivatives and terephthalate." [J] Organometallics, 2006, 25, 74 - 81.
[21] (a) Toda, F. "Organic solid-state reactions with 100% yield." [J] Top. Curr. Chem., 2005, 254, 1 - 305.(b) Paradies J., Greger I., Kehr G., Erker G., Bergander K. and Fr(?)'hlich R. "Formation of an organometallic ladderane derivative by dynamic topochemical reaction control." [J] Angew. Chem. Int. Ed. 2006, 45, 7630 - 7633. (c) Mascitti V. and Corey E. J. "Total synthesis of (+/-)-pentacycloanammoxic acid." [J] J. Am. Chem. Soc. 2004,126, 15664 -15665. (d) Hopf H. "Step by step - From nonnatural to biological molecular ladders." [J] Angew. Chem. Int. Ed. 2003,42,2822 - 2825.
[22] (a) Bu(?)ar D.-K., Papaefstathiou G. S., Hamilton T. D., Chu Q., Georgiev I. G. and MacGillivray L. R. "Template-controlled reactivity in the organic solid state by principles of coordination-driven self-assembly." [J] Eur. J. Inorg. Chem. 2007, 4559 - 4568, and references there in.
[23] (a) Georgiev I. G. and MacGillivray L. R. "Metal-mediated reactivity in the organic solid state:from self-assembled complexes to metal-organic frameworks.” [J]Chem.Soc.Rev.2007,36,1239-1248.(b)Eubank J.F,Kravtsov V.C.and Eddaoudi M.“Synthesis of organic photodimeric cage molecules based on cycloaddition via metal-ligand directed assembly." [J]J.Am.Chem.Soc.2007,129,5820-5821.(c)Wang X.-Y,Wang Z.-M.;Gao S.“A pillared layer MOF with anion-tunable magnetic properties and photochemical [2+2]cycloaddition.” [J]Chem.Commun.2007,1127-1129.(d)Hill Y.and Briceno A.“Exploiting the use of hydrogen bonding and metal-coordination in the self-assembly of photoreactive multicomponent networks.” [J]Chem.Commun.2007,3930-3932.(f)Michaelides A.,Shoulika S.and Siskos M.G.“Assembly of a photoreactive coordination polymer containing rectangular grids” [J]Chem.Commun.2004,2418-2419.(g)Nagarathinam M.and Vittal J.J.“Anisotropic movements of coordination polymers upon desolvation:Solid-state transformation of a linear 1D coordination polymer to a ladderlike structure.”[J]Angew.Chem.,Int.Ed.2006,45,4337-4341.
[24](a)Suzuki,H.;Tajima,N.;Tatsumi,K.;Yamamoto,Y “Molecular architecture via coordination:quasi-octahedral macrocycles of rhodium and iridium bearing a pentamethylcyclopentadienyl group.” [J]Chem.Comm.2000,1801-1802.(b)Yamamotoa,Y.;Suzuki,H.;Tajima,N.;Tatsumi,K.“Stepwise Formation of Quasi-Octahedral Macrocyclic Complexes of Rhodium(Ⅲ)and Iridium(Ⅲ)Bearing a Pentamethylcyclopentadienyl Group.” [J]Chem.Eur.J.2002,8,372-379.
[25]Schmitt F.,Govindaswamy P.,Suss-Fink G.,Ang W.H.,Dyson P.J.,Juillerat-Jeanneret L.,Therrien B.“Ruthenium Porphyrin Compounds for Photodynamic Therapy of Cancer.” [J]J.Med.Chem.2008,51,1811-1816.
[26]Wang,J.-Q.;Ren,C.-X.;Jin,G-X.“Route to Multicluster Containing Ancillary ortho-Carborane-1,2-Dithiolato Ligands.” [J]Chem.Commun.2005,4738-4740.
[1] Kitagawa, S.; Kawata, S. "Coordination compounds of 1,4-dihydroxybenzo-quinone and its homologues. Structures and properties." [J] Coord. Chem. Rev.2002,224,11-34.
[2] Kabir, M. K.; Miyazaki; Kawata, N.; S.; Adachi, K.; Kumagai, H.; Inoue, K.; Kitagawa, S.; Iijima, K. "Novel layered structures constructed from iron-chloranilate compounds. " [J] Coord. Chem. Rev. 2000,198,157 -169.
[3] Yoshino, A.; Matsudaira, H.; Asato, E.; Koikawa, M.; Shiga, T.; Ohba, M.; Okawa, H. "Insertion of a strongly π-π stacked chloranilate pair into an M4 arrangement preorganized within a large macrocyclic ligand (M = Zn~(2+) and Cu~(2+))." [J] Chem. Commun. 2002,1258 -1259.
[4] Gregorio, S.; Jorge, V.; Gregorio, L.; Luis, S. J.; Luis, G.; Jose, P. "Exploring the Reactivity towards Acidic Protic Ligands of the Di--hydroxo Complex [NBu_4]_2[Pd_2{C_4(COOMe)_4}_2(μ-OH)_2]: A Convenient Precursor in the Preparation of New Palladacyclopentadiene Complexes." [J] Eur. J. Inorg. Chem. 2005, 12, 2360 - 2367.
[5] Prithwiraj, B. "Ruthenium-azoimine-chloranilates Synthesis, Spectra and Electrochemistry of Ruthenium(Ⅱ)-1-alkyl-2-(arylazo)imidazole-chloranilate Complexes." [J] Trans. Metal Chem. 2005,30,738.
[6]Luo,T.-T.;Liu,Y.-H.;Tsai,H.-L.;Su,C.-C;Ueng,C.-H.;Lu,K.-L.“A Novel Hybrid Supramolecular Network Assembled from Perfect π -π Stacking of an Anionic Inorganic Layer and a Cationic Hydronium-Ion-Mediated Organic Layer.” [J]Eur.J.Inorg.Chem.2004,21,4253-4258.
[7]Heinze,K.;Huttner,G.;Walter,O.“Metal-Metal Interactions in Dinuclear (triphos)Cobalt Complexes Exhibiting Mixed Valency.” [J]Eur.J.Inorg.Chem.1999,593-600.
[8]Carbonera,C;Dei,A.;Letard,J.-F.;Sangregorio,C;Sorace,L.“Thermally and Light-Induced Valence Tautomeric Transition in a Dinuclear Cobalt-Tetraoxolene Complex.” [J]Angew.Chem.,Int.Ed.2004,43,3136-3138.
[9]Tao,J.;Maruyama,H.;Sato,O.Valence Tautomeric Transitions with Thermal Hysteresis around Room Temperature and Photoinduced Effects Observed in a Cobalt-Tetraoxolene Complex.” [J]J.Am.Chem.Soc.2006,128,1790-1791.
[10]Gupta,P.;Das,A.;Basuli,F.;Castineiras,A.;Sheldrick,W.S.;Mayer-Figge,H.;Bhattacharya,S.“Variable Coordination Mode of Chloranilic Acid.Synthesis,Structure,and Electrochemical Properties of Some Osmium Complexes.” [J]Inorg.Chem.2005,44,2081-2088.
[11]Jasimuddin,S.;Byabartta,P.;Sinha,C;Mostafa,G.;Lu,T.H.“First example of ruthenium-azoimine-chloranilates: synthesis, structure, spectra and electrochemistry of ruthenium(Ⅱ)1-alkyl-2-(arylazo)imidazole chloranilates,and correlation of electronic properties with ZINDO calculation.”[J]Inorg.Chim.Acta 2004,357,2015-2026.
[12]Kawahara,M.;Kabir,M.K.;Yamada,K.;Adachi,K.;Kumagai,H.;Narumi,Y.;Kindo,K.;Kitagawa,S.;Kawata,S.“Module-Based Assembly of Copper(Ⅱ)Chloranilate Compounds: Syntheses, Crystal Structures, and Magnetic Properties of {[Cu_2(CA)(terpy)_2][Cu(CA)_2]}n and {[Cu_2(CA)(terpy)_2(dmso)_2][Cu(CA)_2(dmso)_2](EtOH)}_n (H_2CA = Chloranilic Acid,dmso = Dimethyl Sulfoxide).” [J]Inorg.Chem.2004,43,92-100.
[13]Nagayoshi,K.;Kabir,M.K.;Tobita,H.;Honda,K.;Kawahara,M.;Katada,M.;Adachi,K.;Nishikawa,H.;Ikemoto,I.;Kumagai,H.;Hosokoshi,Y.;Inoue,K.;Kitagawa,S.;Kawata,S.“Design of Novel Inorganic-Organic Hybrid Materials Based on Iron-Chloranilate Mononuclear Complexes: Characteristics of Hydrogen-Bond-Supported Layers toward the Intercalation of Guests.” [J]J.Am.Chem.Soc.2003,125,221-232.
[14] Min, K. S.; Rheingold, A. L.; DiPasdquale, A.; Miller, J. S. "Characterization of the Chloranilate(·3-) n Radical as a Strong Spin-Coupling Bridging Ligand." [J] Inorg. Chem. 2006,45, 6135 - 6137.
[15] Min, K. S.; DiPasdquale, A.; Goled, J. A.; Rheingold, A. L.; Miller, J. S. "Synthesis, Structure, and Magnetic Properties of Valence Ambiguous Dinuclear Antiferromagnetically Coupled Cobalt and Ferromagnetically Coupled Iron Complexes Containing the Chloranilate(2-) and the Significantly Stronger Coupling Chloranilate(·3-) Radical Trianion." [J] J. Am. Chem. Soc. 2007, 129, 2360 - 2368.
[16] Wang,J.-Q.; Ren, C.-X.; Jin, G.-X. "Synthesis and Structural Characterization of Macrocyclic Half-Sandwich Rhodium(Ⅲ) and Iridium(Ⅲ) Complexes Bearing Bipyridyl Derivatives and Terephthalate." [J] Organometallics 2006, 25,74 - 81.
[17] Han, W. S.; Lee, S. W. "Various forms of linear dipyridyls in discrete rectangles, dinuclear rods, and one-dimensional networks containing (η~5-pentamethylcyclopentadienyl)- rhodium(iii)." [J] Dalton Trans. 2004, 1656 -1663.
[18] Liao, R.-T.; Yang, W.-C.; Thanasekaran, P.; Tsai, C.-C.; Sathiyendiran, M.; Liu, Y.-H.; Rajendran, T.; Lin, H.-M.; Tseng, T.-W.; Lu, K.-L. "Rhenium-based molecular rectangular boxes with large inner cavity and high shape selectivity towards benzene molecule." [J] Chem. Commun. 2008, 27, 3175-3177.
[1] Alekseyeva, E. S.; Batsanov, A. S.; Boyd, L. A.; Fox, M. A.; Hibbert, T. G.; Howard, J. A. K.; Hugh, M. J. A.; Mackinnon, A.; Wade, K. "Intra- and inter-molecular carboranyl C-H … N hydrogen bonds in pyridyl-containing ortho-carboranes." [J] Dalton Trans. 2003,475 - 482.
[2] Abernethy, C. D.; Macdonald, C. L. B.; Cowley, A. H.; Clyburne, J. A. C. "A persistent C-H…C(π) T-stacked cation." [J] Chem. Commun. 2001, 61 - 62.
[3] Devic, T.; Evain, M.; Mo(?)lo, Y.; Canadell, E.; Auban-Senzier, P.; Fourmigu(?), M.; Batail, P. "Single Crystalline Commensurate Metallic Assemblages of π-slabs and CdI_2-Type Layers: Synthesis and Properties of β-(EDT-TTF-I_2)_2[Pb_(5/61/6)I_2]_3 and β-(EDT-TTF-I_2)_2[Pb_(2/3+x)Ag_(1/3-2xx)I_2]_3, x = 0.05." [J] J. Am. Chem. Soc. 2003, 125, 3295-3301.
[4] Khlobystov, A. N.; Blake, A. J.; Champness, N. R.; Lemenovskii, D. A.; Majouga, A. G.; Zyk, N. V.; Schr(?)der, M. "Supramolecular design of one-dimensional coordination polymers based on silver(Ⅰ) complexes of aromatic nitrogen-donor ligands." [J] Coord. Chem. Rev. 2001,222,155 -192.
[5] Pullen, A. E.; Olk, R. "The coordination chemistry of 1,3-dithiole-2-thione-4,5- dithiolate (dmit) and isologs." [J] Coord. Chem. Rev. 1999,188, 211 - 262.
[6] 洪茂椿,陈荣,梁文平“21世纪的无机化学”,北京:科学出版社,2005,283-285.
[7] Kasai, K.; Aoyagi, M.; Fujita, M. "Flexible Coordination Networks with Fluorinated Backbones. Remarkable Ability for Induced-Fit Enclathration of Organic Molecules." [J] J. Am. Chem. Soc. 2000,122,2140 - 2141.
[8] Raehm, L.; Mimassi, L.; Guyard-Duhayon, C.; Amouri, H. "Crucial Role of the Counteranion on the Templation of Metallomacrocycles and a 3D Network: Synthesis, Characterization, and Structural Analysis." [J] Inorg. Chem. 2003, 42, 5654 - 5659.
[9] Du, M.; Bu, X.-H.; Huang, Z.; Chen, S.-T.; Guo, Y.-M. "From Metallacyclophanes to 1-D Coordination Polymers: Role of Anions in Self-Assembly Processes of Copper(Ⅱ) and 2,5-Bis(3-pyridyl)-1,3,4-oxadiazole." [J] Inorg. Chem. 2003, 42, 552- 559.
[10] Oyaizu, K.; Tsuchida, E. "The First Oxovanadium Ring in [{O=V(salen)}_2(μ-F)] [VO(salen)][BF_4]·(CH_2Cl_2)_x Crystals." [J] J. Am. Chem. Soc. 2003, 125, 5630 -5631.
[11] Choi, H. J.; Suh, M. P. "Dynamic and Redox Active Pillared Bilayer Open Framework: Single-Crystal-to-Single-Crystal Transformations upon Guest Removal, Guest Exchange, and Framework Oxidation." [J] J. Am. Chem. Soc. 2004,126,15844-15851.
[12] Armentano, D.; Munno, G. D.; Mastropietro, T. F.; Julve, M.; Lioret, F. "Intermolecular Proton Transfer in Solid Phase: A Rare Example of Crystal-to-Crystal Transformation from Hydroxo- to Oxo-Bridged Iron(Ⅲ) Molecule-Based Magnet." [J] J. Am. Chem. Soc. 2005,127,10778 -10779.
[13] Chen, C.-L.; Goforth, A. M.; Smith, M. D.; Su, C.-Y.; zur Loye, H.-C. "Self-Assembly of Nanoparticles on Live Bacterium: An Avenue to Fabricate Electronic Devices." [J] Angew. Chem. Int. Ed. 2005, 44, 6673 - 6677.
[14] Wu, C.-D.; Lin, W.-B. "Highly Porous, Homochiral Metal-Organic Frameworks: Solvent-Exchange-Induced Single-Crystal to Single-Crystal Transformations." [J] Angew. Chem. Int. Ed. 2005, 44,1958-1961.
[15] Zhang, J.-P.; Lin, Y.-Y.; Zhang, W.-X.; Chen X.-M. "Temperature- or Guest-Induced Drastic Single-Crystal-to-Single-Crystal Transformations of a Nanoporous Coordination Polymer" [J] J. Am. Chem. Soc. 2005, 127, 14162 -14163.
[16] Takata, D.; Kitagawa, S. "Template Effects in Porous Coordination Polymers." [J] Chem. Mater. 2008, 20, 922 - 931 and references therein.
[17] Dong, Y.-B.; Zhang, Q.; Liu, L.-L.; Ma, J.-P; Tang, B.; Huang, R.-Q. "[Cu(C_(24)H_(22)N_4O_3)]·CH_2Cl_2: A Discrete Breathing Metallamacrocycle Showing Selective and Reversible Guest Adsorption with Retention of Single Crystallinity." [J] J. Am. Chem. Soc. 2007,129,1514 -1515.
[18] MacGillivray, L. R.; Papaefstathiou, G. S.; Fris￡i5, T.; Hamilton, T. D.; Bucar, D.-K.; Chu, Q.; Varshiney, D. B.; Georgiev, I. G. Supramolecular Control of Reactivity in the Solid State: From Templates to Ladderanes to Metal-Organic Frameworks." [J] Acc. Chem. Res. 2008,41,280 - 291.
[19] Han, Y.-F.; Lin, Y.-J.; Jia, W.-G.; Wang, G.-L.; Jin, G.-X., "Template-controlled topochemical photodimerization based on organometallic macrocycles through single-crystal to single-crystal transformation." [J] Chem. Commun. 2008, 1807 -1809.
[1] (a) Wilkinson G.; Stone, G. F. A.; Abel, E. W. Comprehensive Organometallic Chemistry. Pergamon Press, Oxford, 1982. (b) Cotton, F. A. Advanced inorganic chemistry. 6th ed. New York : John Wiley & Sons, Inc. 1999. (c) Stiefel, E. I.; Karlin, K. D. Progress in Inorganic Chemistry, John Wiley & Sons, Inc. 2004.
[2] (a) Dubois, M. R. "Catalytic applications of transition-metal complexes with sulfide ligands." [J] Chem. Rev. 1989, 89, 1-9. (b) L. C. Roof. J. W. Kolis. "New developments in the coordination chemistry of inorganic selenide and telluride ligands." [J] Chem. Rev. 1993, 93, 1037-1080.
[3] Margoshes, M. B.; Vallee, L. "A Cadmium protein from equine kidney cortex." [J] J. Am. Chem. Soc. 1957, 79,4813-4814.
[4] (a) Disalvo, F. J. "Solid-State Chemistry: A Rediscovered Chemical Frontier. Science 1990, 247, 649; (b) Tenne, R.; Argulis, L. M.; Genut, M. "Polyhedral and cylindrical structures of tungsten disulfide." [J] Nature 1992, 360,444 - 446.
[5] Beak, P., Fry Jr, F. S.; Lee, J.; Steele, F. "Equilibration studies. Protomeric equilibria of 2- and 4-hydroxypyridines, 2- and 4-hydroxypyrimidines, 2- and 4-mercaptopyridines, and structurally related compounds in the gas phase." [J] J. Am. Chem. Soc. 1976, 98,171-179.
[6] Castro, V. D.; Lima, G. M.; Porto, A. O.; Siebald, H. G. L.; Filho, J. D. S.; Ardisson, J. D.; Ayala, J. D.; Bombieri, G. "Synthesis, structural characterisation and thermal decomposition of [{Pt(dppf)(2-SPy)}{BF_4}] (dppr=1,1'-bisdiphenylphosfinoferrocene and 2-Spy =v2-mercaptopyridine) - a source for a Fe-Pt containing alloy." [J] Polyhedron 2004,23, 63 - 69.
[7] Reynolds, J. G.; Sendlinger, S. C.; Murray, A. M.; Huffman, J. C.; Christou, G. "Synthesis and Characterization of Vanadium(Ⅱ,Ⅲ,Ⅳ) Complexes of Pyridine-2-thiolate." [J] Inorg. Chem. 1995, 34, 5745 - 5752.
[8] Jung, O.-S.; Park, S. H.; Lee, Y.-A; Cho, Y.; Kim, K. M.; Lee, S.; Chae, H. K.; Sohn, Y. S. "Unique Intramolecular Interaction in Cyclotriphosphazene Molecule. Synthesis, Structure, and Properties of 1,1-Bis(pyridyl-2-thio)-3,3,5,5-tetrachlorocyclotriphosphazene." [J] Inorg. Chem. 1996, 55, 6899 -6901.
[9] Chen, Y.; Lin, F.; Shephered, R. E. "Stereochemically-rigid and fluxional pyrimidines within the bis-[Ru(hedta)(pym)2]- complex." [J] Inorg. Chim. Acta 1998, 268,287 - 295.
[10] Onaka, S.; Yaguchi, M.; Yamauchi, R.; Ozeki,T.; Ito, M.; Sunahara, T.; Sugiura, Y.; Shiotsuka, M.; Nunokawa, K.; Horibe, M.; Okazaki, K.; Iida, A.; Chiba, H.; Inoue, K.; Imai, H.; Sako, K. "The effect of carbon chain length of the diphosphine ligand on the aurophilic interaction. Synthesis and X-ray structural study for a series of Au(Ⅰ) compounds with Ph_P-R-PPh_2 and S-(CH_2)_n-py ligands." [J] J. Organomet. Chem. 2005, 690, 57 - 68.
[11] Han, Y.-F.; Huang, Y.-B.; Lin, Y.-J.; Jin, G.-X. "Synthesis, Characterization, and Norbornene Polymerization Behavior of the Half-Sandwich Complexes [Cp_3~*M_3(μ~3-L)Cl_3] and [Cp~*M(2-SPyH)Cl_2] (M = Ir, M = Rh, [L]~(3-) = 1,3,5-Triazine-2,4,6-trithiolato, 2-SPy = 2-Pyridinethione)." [J] Organometallics 2008,27,961-966.
[12] Raisanen, M. T.; Runeberg, N.; Klinga, M.; Nieger, M.; Bolte, M.; Pyykko, P.; Leskela, M.; Repo, T. "Coordination of Pyridinethiols in Gold(Ⅰ) Complexes." [J] Inorg. Chem. 2007,46, 9954 - 9960.
[13] Yamanari, K.; Fukuda, I.; Kawamoto, T.; Kushi, Y.; Fuyuhiro, A.; Kubota, N.; Fukuo, T.; Arakawa, R. "Self-Assembling Synthesis of Cyclic Tri- and Tetranucle ar Cobalt(Ⅲ) Complexes Bridged by Purine-6-thione and Their Characterization by Electrospray Mass Spectrometry and X-ray Crystal Analysis." [J] Inorg. Chem. 1998,37,5611-5618.
[14] Fish, R. H. "Bioorganometallic chemistry: synthesis, structure, and molecular recognition chemistry of (η~5-pentamethylcyclopentadienyl)rhodium-DNA/RNA complexes in water. Coord. Chem. Rev. 1999,185-186, 569-584.
[15] Severin, K. "Supramolecular chemistry with organometallic half-sandwich complexes." [J] Chem. Commun. 2006, 3859-3867.
[16] Severin, K. "Self-assembled organometallic receptors for small ions." [J] Coord. Chem. Rev. 2003, 245, 3-10.
[17] Sekioka, Y; Kaizaki, S.; Mayer, J. M.; Suzuki, T. "Structure and Reactivity of a Pyridine-1-imido-2-thiolato Complex of Iridium(Ⅲ), Cp~*Ir(1-N-2-Spy), Generated by Photolysis of the (Azido)(pyridine-2-thiolato) Complex, Cp~*Ir(2-Spy)(N_3)." [J] Inorg. Chem. 2005, 44, 8173-8175.
[18] Jung, O.-S.; Lee, Y.-A.; Kim, Y. T.; Chae, H. K. "An organometallic mercaptopyridine complex with unusual bond shift fluxionality: metal-mediated tautomerism of (pentamethylcyclopentadienyl)bis(pyridine-2-thiolato) rhodium(Ⅲ)." [J] Inorg. Chim. Acta 2000, 299,100 -103.
[19] (a) Herberhold, M.; Jin, G.-X.; Yan, H.; Milius, W.; Wrackmeyer, B. "16- and 18-Electron Cp~*Rh complexes with 1,2-dicarba-closo-dodecaborane(12)- 1,2-dichalcogenolato ligands, as studied by multinuclear magnetic resonance." [J] J. Organomet. Chem. 1999, 557, 252 - 257. (b) Bae, J. Y.; Park, Y I.; Ko, J.; Park, K. I.; Cho, S. I.; Kang, S. O. "Synthesis, X-ray crystal structure, and reactivity of the monomeric dithio-o-carboranyl indium complex [Ir(η~5-C_5Me_5)(η~2-S_2C_2B_(10)H_(10))]." [J] Inorg. Chim. Acta 1999, 289, 141 -148. (c)Jin, G.-X. "Advances in the chemistry of organometallic complexes with 1,2-dichalcogenolato-o-carborane ligands." [J] Coord. Chem. Rev. 2004, 248, 587 - 602; (d) Liu, S.; Han, Y. F.; Jin, G.-X. "Formation of direct metal-metal bonds from 16-electron "pseudo-aromatic" half-sandwich complexes Cp"M[E2C2(B10H10)]." [J] Chem. Soc. Rev. 2007,36,1543 -1560.
[20] Kettler, P. B.; Chang, Y.; Rose, D.; Zubieta, J.; Abrams, M. J. "Synthesis and structural characterization of complexes of the {Cp~*Rh} and MeRe cores with pyridine-2-thiol ligand types. Structures of MeReO(η~2-2-SC_5H_3N-3-SiMe)_2 and (η~5-Me_5C_5)Rh(η-2-SC_5H_3N-3-SiMe_3) if(η~1-2-SC_5H_3N-3-SiMe_3)." [J] Inorg. Chim. Acta 1996,244,199 -205.
[21] Perez-Torrente, J. J.; Casado, M. A.; Ciriano, M. A.; Lahoz, F. J.; Oro, L. A. "Synthesis of Rhodium, Indium, and Palladium Tetranuclear Complexes Directed by 2,6-Dimercaptopyridine. X-ray Crystal Structure of [Rh_4(μ-PyS_2)_2(cod)_4] (cod = 1,5-Cyclooctadiene)." [J] Inorg. Chem. 1996, 55, 1782-1791.
[22] Dorn, T.; Janiak, C.; Abu-Shandi, K. "Hydrogen-bonding, π-stacking and Cl-anion-π interactions of linear bipyridinium cations with phosphate, chloride and [CoCl4]2- anions." [J] Cryst. Eng. Comm. 2005, 7,633 - 641.
[23] (a) Matlock, M. M.; Henke, K. R.; Atwood, D. A.; Robertson, J. D. "Aqueous leaching properties and environmental implications of cadmium, lead and zinc Trimercaptotriazine (TMT) compounds." [J] Water Res. 2001, 35, 3649 - 3655;(b) Henke, K. R.; Robertson, D.; Krepps, M. K.; Atwood, D. A. "Chemistry and stability of precipitates from aqueous solutions of 2,4,6-trimercaptotriazine, trisodium salt, nonahydrate (TMT-55) and mercury(Ⅱ) chloride." [J] Water Res. 2000,34,3005-3013.
[24] (a) Kopel, P.; Dole(?)al, K.; Machal L.; Langer, V. "Synthesis, characterization and screening of biological activity of Zn(Ⅱ), Fe(Ⅱ) and Mn(Ⅱ) complexes with trithiocyanuric acid." [J] Polyhedron 2007, 26, 1583 - 1589. (b) Cecconi, F.; Ghilardi, C. A.; Midollini S.; Orlandini, A. "Organomercury derivatives of the 2,4,6-trimercaptotriazine (H_3TMT). X-ray crystal structure of (HgMe)_3(TMT)." [J] J. Organomet. Chem. 2002, 645, 101 - 104. (d) Bailey, J. R.; Hatfield, M. J.;Henke, K. R.; Krepps, M. K.; Morris, J. L.; Otieno, T.; Simonetti, K. D.; Wall, E. A.; Atwood, D. A. "Transition metal complexes of 2,4,6-trimercapto-1,3,5-triazine (TMT): potential precursors to nanoparticulate metal sulfides." [J] J. Organomet. Chem. 2001, 623, 185 - 190. (e) Haiduc, I.; Mahon, M. F.; Molloy K. C.; Venter, M. M. "Synthesis and spectral characterisation of organotin(Ⅳ) 1,3,5-triazine-2,4,6-trithiolato complexes, including the crystal structures of 1,3,5-(R_3Sn)_3C_3N_3S_3 (R=Me, Ph)." [J] J. Organomet. Chem. 2001, 627, 6-12.
[25] Ienco, A.; Midollini, S.; Orlandini, A.; Vacca, A. "Complexes formed from 2,4,6-trimercaptotriazine (H_3TMT): synthesis and structural characterization of [M(PhP(CH_2CH_2P(Ph)_2)_2(HTMT)], M=Ni(Ⅱ), Pd(Ⅱ), Pt(Ⅱ)." [J] Inorg. Chim. Acta 2004, 357, 2615 -2623.
[26] (a) Yamanari, K.; Kushi, Y.; Yamamoto, M.; Fuyuhiro, A.; Kaizaki, S.; Kawamoto, T.; Kushi, Y. "Photochemical-synthesis and crystal-structures of tetrakis(ethane-1,2-diamine)dicobalt(Ⅲ) complexes bridged by 1,3,5-trlazine-2,4,6-trithionate and 4-oxo-1,3,5-triazine-2,6-dithionate." [J] Dalton Trans. 1993, 3715 - 3721. (b) Clegg, W.; Davies, J. E.; Elsegood, M. R. J.; Lamb, E.; Longridge, J. J.; Rawson, J. M.; Snaith, R.; Wheatley, A. E. H. "The first structural studies on trithiocyanuric acid: the solid state structures of its HMPA adduct and its mono-lithiated HMPA complex." [J] Inorg. Chem. Commun. 1998, 1, 58 - 60.
[27] (a) Kar, S.; Miller, T. A.; Chakraborty, S.; Sarkar, B.; Pradhan, B.; Sinha, R. K.; Kundu, T.; Ward, M. D.; Lahiri, G. K. "Synthesis, mixed valence aspects and non-linear optical properties of the triruthenium complexes [{(bpy)_2Ru~(Ⅱ)}_3(L)]~(3+) and [{(phen)_2RuII}_3(L)]~(3+) (bpy = 2,2'-bipyridine, phen = 1,10-phenanthroline and L~(3-) = 1,3,5-triazine-2,4,6-trithiol)." [J] Dalton Trans. 2003, 2591 - 2596. (b) Kar, S.; Pradhan, B.; Sinha, R. K.; Kundu, T.; Kodgire, P.; Rao, K. K.; Puranik, V. G.; Lahiri, G. K. "Synthesis, structure, redox, NLO and DNA interaction aspects of [{(L'-L"')_2Ru~(Ⅱ)}_3(μ_3-L)]~(3+) and [(L')_2Ru~(Ⅱ)(NC_5H_4S-)]~+ [L~(3-) = 1,3,5-triazine- 2,4,6-trithiolato, L'-L'"= arylazopyridine]." [J] Dalton Trans. 2004,1752 -1760.
[1] Moulton, B. M.; Zaworotko, J. "From Molecules to Crystal Engineering: Supramolecular Isomerism and Polymorphism in Network Solids." [J] Chem. Rev. 2001,101,1629 -1658.
[2] Brammer, L. "Developments in inorganic crystal engineering." [J] Chem. Soc. Rev. 2004, 33,476 - 489.
[3] Dong, Y.-B.; Ma, J.-P.; Huang, R.-Q.; Smith, M.D.; zur Loye, H.-C. "Synthesis and Characterization of New Coordination Polymers Generated from Oxadiazole-Containing Organic Ligands and Inorganic Silver(I) Salts." [J] Inorg. Chem. 2003, 42, 294 - 300.
[4] Plater, M. J.; Foreman, M. R. St. J.; Gelbrich, T.; Hursthouse, M. B. "One-dimensional structures of nickel(Ⅱ) and cobalt(Ⅱ) coordination complexes {[ML_2(H_2O)_2]·L·H_2O·(ClO_4)_2} (M=Co or Ni; L=1,3-bis(4-pyridyl)propane)." [J] Inorg. Chim. Acta 2001, 318,171 -174.
[5] Hou, H.; Song, Y.; Fan, Y.; Zhang, L.; Du, C.; Zhu, Y. "A novel coordination polymer [Co(NCS)_2(bpms)_2]_n (bpms=1,2-bis(4-pyridylmethyl)disulfenyl): synthesis, crystal structure and third-order nonlinear optical properties." Inorg. Chim. Ada 2001, 316,140 -144.
[6] Horikoshi, R; Mochida, T. "Metal complexes of 4,4 '-dipyridyldisulfide-structural diversity derived from a twisted ligand with axial chirality." [J] Coord. Chem. Rev. 2006,250, 2595 - 2609.
[7] Carballo, R.; Covelo, B.; Fernandez-Hermida, N. "Solid state coordination chemistry of copper(Ⅱ) lactate complexes with the twisted ligands 4,4-dipyridyldisulfide and bis(4-pyridylthio)methane." [J] J. Mol. Strud. 2008, 892, 427 - 432.
[8] Carballo, R.; Covelo, B.; Fernandez-Hermida, N. "Structural versatility in copper(Ⅱ) alpha-hydroxycarboxylate complexes with the twisted ligands 4,4'-dipyridyldisulfide and bis(4-pyridylthio)methane: From molecular compounds to two-dimensional coordination polymers." [J] Cryst. Growth Des. 2008,5,995-1004.
[9] Wang, J.; Zhang, Y. H.; Li, H. X. "Construction of pyridinethiolate-bridged 2D and 3D coordination networks of d(10)metal halides via solvothermal in situ disulfide cleavage reactions.” [J]Cryst.Growth Des.2007,7,2352-2360.
[10]Aragoni,M.C;Arca,M.;Crespo,M.“Predictable and unpredictable reactions between 4,4 '-dipyridyldisulfide and phosphonodithioato/dithiophosphato Ni-Ⅱ complexes:novel coordination polymers and the unique example of 4,4'-dipyridyltrisulfide.” [J]Cryst.Eng.Comm.2007,9,873-878.
[11]Wang,J.;Zheng,S.L.;Hu,S.;et al.“New in situ cleavage of both S-S and S-C(sp(2))bonds and rearrangement reactions toward the construction of copper(Ⅰ)cluster-based coordination networks.” [J]Inorg.Chem.2007,46,795-800.
[12]Tabellion,F.M.;Seidel,S.R.;Arif,A.M.;Stang,P.J.“Discrete Supramolecular Architecture vs Crystal Engineering:The Rational Design of a Platinum-Based Bimetallic Assembly with a Chairlike Structure and Its Infinite,Copper Analogue.”[J]J.Am.Chem.Soc.2001,123,7740-7741.
[13]Horikoshi,R.;Mochida,T.;Kurihara,M.;Mikuriya,M.“Supramolecular Isomerism in Self-Assembled Complexes from 4,4'-Dipyridyl Disulfide and M(hfac)_2:Coordination Polymers (M = Mn)and Metallamacrocycles (M = Co,Ni)." Cryst.Growth Des.2005,5,243-249.
[14]Yu,X.-Y.;Maekawa,M.;Morita,T.;Chang,H.-C;Kitagawa,S.;Jin,G.-X.“Solvent-dependent formation of di-and trinuclear rhodiurn and iridium complexes bridged by N,N'-donor ligands.” [J]Bull.Chem.Soc.Jpn.2002,75,267-275.
[1] Crossley, I. R.; Hill, A. F.; Humphrey, E. R.; Willis, A. C. "The First Bimetallic Metallaboratrane: [Rh_2{B(mt)_3}_2{κ~2-S,S'-HB(mt)_3}]Cl and Its Synthesis from the Fluxional Rhodaboratrane Salt [Rh{B(mt)_3}(η~4-C_8H_(12))]Cl, (Rh→B, mt =Methimazolyl)" [J] Organometallics 2005, 24,4083-4086.
[2] Dodds, C. A.; Garner, M.; Reglinski, J.; Spicer, M. D. "Early Metal Di- and Tricyanometalates: Useful Building Blocks for Constructing Magnetic Clusters" [J] Inorg. Chem. 2006, 45, 2733-2741.
[3] Kuan, S. L.; Leong, W. K.; Goh, L. Y. "Redox-Dependent Isomerization of Organometallic Ru~(Ⅱ)/Ru~(Ⅲ) Compounds Containing the Hydrotris(methimazolyl)borate Ligand: An Electrochemical Square Scheme Mechanism" [J] Organometallics 2005,24, 4639-4648.
[4] Crossley, I. R.; Hill, A. F.; Willis, A. C. "Metallaboratranes: Tris(methimazolyl)borane Complexes of Rhodium(I)" [J] Organometallics 2006, 25, 289-299.
[5] Morlok, M. M; Janak, K. E.; Zhu, G.; Quarless, D. A.; Parkin, G. "Intramolecular N-H…S Hydrogen Bonding in the Zinc Thiolate Complex [Tm~(Ph)]ZnSCH_2C(O)NHPh: A Mechanistic Investigation of Thiolate Alkylation as Probed by Kinetics Studies and by Kinetic Isotope Effects" [J] J. Am. Chem. Soc. 2005,127,14039-14050.
[6] Dodds, C. A.; Lehmann, M. A.; Ojo, J. F.; Reglinski, J.; Spicer, M. D. "Cobalt Half-Sandwich, Sandwich, and Mixed Sandwich Complexes with Soft Tripodal Ligands" [J] Inorg. Chem. 2004, 43,4927-4934.
[7] Hill, A. F.; Rae, A. D.; Smith, M. K. "Niobium and Tantalum Tris(methimazolyl)borate Complexes [M(=NC_6H_3~iPr_2-2,6)Cl_2 {HB(mt)_3}] (M = Nb, Ta; mt = Methimazolyl" [J] Inorg. Chem. 2005, 44, 7316-7318.
[8] Landry, V. K.; Melnick, J. G.; Buccella, D.; Pang, K. L.; Ulichny, J. C.; Parkin, G. "Synthesis and Structural Characterization of [κ~3-B,S,S-B(mim~R)_3]Ir(CO)(PPh_3)H (R = Bu~t, Ph) and [κ~4-B(mim~(But))_3]M(PPh_3)Cl (M = Rh, Ir): Analysis of the Bonding in Metal Borane Compounds" [J] Inorg. Chem. 2006, 45, 2588-2597.
[9] Pang, K. L.; Quan, S. M.; Parkin, G. "Palladium complexes with Pd→B dative bonds: Analysis of the bonding in the palladaboratrane compound [κ~4-B(mim~(But))_3]Pd(PMe_3)" [J] Chem. Commun. 2006, 5015-5017;
[10] Crossley, I. R; Hill, A. F.; Willis, A. C. "Poly(methimazolyl)borate Complexes of Platinum" [J] Organometallics 2005, 24,4889-4892.
[11] Kuan, S. L.; Leong, W. K.; Goh, L. Y.; Webster, R. D. "HMB and Cp~* ruthenium(Ⅱ) complexes containing bis- and tris-(mercaptomethimazolyl)borate ligands: Synthetic, X-ray structural and electrochemical studies (HMB = η~6-C_6Me_6, Cp~* =η~5-C_5Me_5)" [J] J. Organomet. Chem. 2006, 691,907-915.
[12] Crossley, I. R; Hill, A. F.; Willis, A. C. "Formation of Metallaboratranes: The Missing Link. The First Iridaboratranes, [IrH(CO)(PPh_3){κ~3-B,S,S'-B(mt)_2R}](Ir→B) (mt = Methimazolyl, R = mt, H)" [J] Organometallics 2005, 24,1062-1064.
[13]Bao,M.;Hayashi,T.;Shimada,S.“Synthesis and structural characterisation of a cationic trinuclear organobismuth complex with an unprecedented coordination mode of hydrotris(2-mercaptoimidazolyl)borate ligands” [J]Dalton Trans.2004,2055-2056.
[14]Alvarez,H.M.;Gillespie,P.A.;Gause,C.D.;Rheingold,A.L.;Golen,J.A.;Rabinovich,D.“Thallium(Ⅰ)bis(mercaptoimidazolyl)borate” [J]Polyhedron 2004,23,617-622.
[15]Minoura,M.;Landry,V.K.;Melnick,J.G;Pang,K.L.;Marchio,L.;Parkin,G.“Synthesis and structural characterization of tris(2-seleno-1-mesitylimidazolyl)hydroborato complexes:a new type of strongly electron donating tripodal selenium ligand” [J]Chem.Commun.2006,38,3990-3992.
[16]Landry,V.K.;Buccella,D.;Pang,K.L.;Parkin,G.“Tetrahedral nickel nitrosyl complexes with tripodal [N_3]and [Se_3]donor ancillary ligands:structural and computational evidence that a linear nitrosyl is a trivalent ligand” [J]Dalton.Trans.2007,820-824.
[17]Landry,V.K.;Buccella,D.;Pang,K.L.;Parkin,G.“Bis-and tris(2-seleno-1-methylimidazolyl)hydroborato complexes,{[BseMe]ZnX}_2 (X =Cl,I),[BseMe]_2Zn and [TseMe]Re(CO)_3:Structural evidence that the [BseMe]ligand is not merely a heavier version of the sulfur counterpart [BmMe]” [J]Dalton.Trans.2007,866-870;
[18]Jia,W.-G.;Huang,Y.-B.;Lin,Y.-J.Jin,G.-X.Syntheses and structures of half-sandwich iridium(Ⅲ)and rhodium(Ⅲ)complexes with organochalcogen (S,Se)ligands bearing N-methylimidazole and their use as catalysts for norbornene polymerization,Dalton Trans.2008,41,5612-5620.
[19]Jia,W.-G.;Huang,Y.-B.;Lin,Y-J.;Wang,G.-L.;Jin,G.-X.Novel nickel complexes and cobalt coordination polymers with organochalcogen (S,Se)ligands bearing N-methylimidazole:synthesis,structures and properties study,Eur.J.Inorg.Chem.2008,26,4063-4073.
[20]Williams,D.J.;Vanderveer,D.;Jones,R.L.;Menaldino,D.S.“Main group metal halide complexes with sterically hindered thioureas Ⅺ.Complexes of antimony(Ⅲ)and bismuth(Ⅲ)chlorides with a new bidentate thiourea-1,1'-methylenebis(3-methyl-2H-imidazole-2-thione)” [J]Inorg.Chim.Acta 1989,165,173-178.
[1] (a) Jin, G.-X. "Advances in the Chemistry of Organometallic Complexes with 1,2-Dichalcogenolato- o-Carborane Ligands." [J] Coord. Chem. Rev. 2004, 248, 587 - 602; (b) Liu, S.; Han, Y.-F.; Jin, G.-X. "Metal-Metal Bonding Formation from 16-Electron "Pseudo-Aromatic" Half-sandwich Complexes Cp"M[E_2C_2(B_(10)H_(10))]." Chem. Soc. Rev. 2007, 36, 1543 - 1560; (c) Plesek, J. "Potential applications of the boron cluster compounds." [J] Chem. Rev. 1992, 92, 269 - 278; (d) Bregadze, V. I. "Dicarba-closo-dodecaboranes C_2B_(10)H_(12) and their derivatives." [J] Chem. Rev. 1992, 92, 209 - 223; (e) Hawthorne, M. F.; Maderna, A. "Applications of Radiolabeled Boron Clusters to the Diagnosis and Treatment of Cancer." [J] Chem. Rev. 1999, 99, 3421 - 3434; (f) Xie, Z. "Cyclopentadienyl-Carboranyl Hybrid Compounds: A New Class of Versatile Ligands for Organometallic Chemistry." [J] Acc. Chem. Res. 2003, 36,1 - 9.
[2] (a) Wang, J. -Q.; Ren,C. -X.; Weng, L. -H.; Jin, G. -X. "Porphyrin-carborane organometallic assemblies based on 1, 2-dicarba-closo-dodecaborane (12) ligands." [J] Chem. Commun. 2006, 162 - 165. (b) Wang, J. -Q.; Ren,C. -X.; Jin, G. -X. "Route to Multicluster Containing Ancillary ortho-Carborane-1,2-Dithiolato Ligands." [J] Chem. Commun. 2005, 4738 - 4740; (c) Liu, S.; Wang, G.-L.; Jin, G.-X. "Multinuclear Self-assembly via Half-sandwich Complexes Cp~*M[S_2C_2(B_(10)H_(10))] and Pyridine based ligands." [J] Dalton Trans. 2008, 425 -432.
[3] (a) Vicente, M. G. H.; Nurco, D. J.; Shetty, S. J.; Medforth, C. J.; Smith, K. M. "First structural characterization of a covalently bonded porphyrin-carborane system." [J] Chem. Commun. 2001, 483 - 484; (b) Lauceri, R.; Purrello, R.; Shetty, S. J.; Vicente, M. G. H. "Interactions of Anionic Carboranylated Porphyrins with DNA." [J] J. Am. Chem. Soc. 2001,123, 5835 - 5836; (c) Isaac, M. F.; Kahl, S. B. "Synthesis of ether- and carbon-linked polycarboranyl porphyrin dimers for cancer therapies." [J] J. Organomet. Chem. 2003, 680, 232 - 243; (d) Hao, E.; Vicente, M. G. H. "Expeditious synthesis of porphyrin-cobaltacarborane conjugates." [J] Chem. Commun. 2005,1306 - 1308.
[4] (a) Guo, D.; Duan, C. Y.; Lu, F.; Hasegawa, Y.; Meng, Q.-J.; Yanagida, S. "Lanthanide heterometallic molecular squares Ru_2-Ln_2 exhibiting sensitized near-infrared emission." [J] Chem. Commun. 2004, 1486 -1487; (b) Bignozzi, C. A.; Argazzi, R.; Kleverlaan, C. J. "Molecular and supramolecular sensitization of nanocrystalline wide band-gap semiconductors with mononuclear and polynuclear metal complexes." [J] Chem. Soc. Rev. 2000, 87 - 96; (c) Sun, L.; Hammarstr(?)m, L.; Akermark, B; Styring, S. "Towards artificial photosynthesis: ruthenium-manganese chemistry for energy production." [J] Chem. Soc. Rev. 2001, 36 - 49.
[5] Haider, G. J.; Kepert, C. J. In Situ Single-Crystal X-ray Diffraction Studies of Desorption and Sorption in a Flexible Nanoporous Molecular Framework Material. J. Am. Chem. Soc. 2005,127, 7891 -7 900.
[6] (a) Zhang, Q.-F.; Adams, R. D.; Leung, W.-H. "Syntheses, spectroscopic properties and crystal structures of two organoruthenium (Ⅱ) complexes of bipyridines: [{Cp~*Ru(2,2'-bipy)}_2(μ-Cl)][PF_6] and [{(η~6-p-cymene)Ru}_2(μ-OH)_2 (4,4'-bipy)]_2[BF_4]_4." [J] Inorg. Chim. Acta 2006, 359, 978 - 983; (b) Furukawa, S.; Ohba, M.; Kitagawa, S. "Rational synthesis of a two-dimensional honeycomb structure based on a paramagnetic paddlewheel diruthenium complex." [J] Chem. Commun. 2005, 865 - 867; (c) Kinnunen, T. J.; Haukka, M.; Pesonen, E.; Pakkanen, T. A. "Ruthenium complexes with 2,2'-, 2,4'- and 4,4'-bipyridine ligands: The role of bipyridine coordination modes and halide ligands." [J] J. Organomet. Chem. 2002, 655, 31 - 38; (d) Yan, H.; Suss-Fink, G.; Neels, A.; Stoeckli-Evans, H. "Mono-, di- and tetra-nuclear p-cymeneruthenium complexes containing oxalato ligands." [J] Dalton Trans. 1997,4345 - 4350.
[7] (a) Griffiths, J.-P.; Brown, R. J.; Day, P.; Matthews, C. J.; Vital, B.; Wallis, J. D. "Synthesis of bis(ethylenedithio)tetrathiafulvalene derivatives with metal ion ligating centres." Tetrahedron Lett. 2003, 44, 3127 - 3131; (b) Moore, A. J.; Batsanov, A.S.; Bryce, M. R.; Howard, J. A. K.; Khodorkovsky, V.; Shapiro, L.; Shames, A. "Activation of C-H Bonds in Five-Membered Heterocycles by a Half-Sandwich Yttrium Alkyl Complex." [J] Eur. J. Org. Chem. 2001, 73 - 75; (c) Liu, S.-X.; Dolder, S.; Pilkington, M.; Decurtins, S. Facile Synthesis of Novel Functionalized Bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) Derivatives. J. Org. Chem. 2002, 67, 3160 - 3162; (d) Campagna, S.; Serroni, S.; Puntoriero, F.; Loiseau, F.; De Cola, L.; Kleverlaan, C. J.; Becher, J.; Sorensen, A. P.; Hascoat, P.; Thorup, N. "Coupling of Metal-Based Light-Harvesting Antennas and Electron-Donor Subunits: Trinuclear Ruthenium(Ⅱ) Complexes Containing Tetrathiafulvalene-Substituted Polypyridine Ligands." [J] Chem. Eur. J. 2002, 5, 4461-4469; (e) Devic, T.; Avarvari, N.; Batail, P. "A Series of Redox Active, Tetrathiafulvalene-Based Amidopyridines and Bipyridines Ligands: Syntheses, Crystal Structures, a Radical Cation Salt and Group 10 Transition-Metal Complexes." [J] Chem. Eur. J. 2004,10, 3697 - 3707.
[8] Levi, O. P.; Becker, J. Y.; Ellern, A.; Khodorkovsky, V. "Synthesis of 2,3-dimethylthio-6-pyridyl tetrathiafulvalene: a precursor for a new system involving a direct linkage between a strong donor (D) and a strong acceptor (A)." [J] Tetrahedron Lett. 2001, 42,1571 -1573.
[9] Kim, S. H.; Huh, H. S.; Lee, S. W. Cobalt(Ⅱ) coordination polymers based on dicarboxylates and dipyridyl-type ligands: [CoL_(1.5)(NO_3)_2], [Co_(1.5)(bpdc)_(1.5)(dma)]· (dma)·(EtOH), [Co_(1.5)(ndc)_(1.5)(dma)_2], [Co_3(ndc)_3(dmf)_4], and [CoL(bpdc)]·(EtOH) (bpdcH_2 = biphenyl-4,4'-dicarboxylic acid, ndcH_2 = 2,6-naphthalene dicarboxylic acid, L = py-CH=N-C_(10)H_6-N=CH-py), J. Mol. Struct. 2007, 841, 78 - 87.
[1] 化学学科进展,张礼和,北京:化学工业出版社,2005.6.
[2] Ritleng, V.; Sirlin, C.; Pfeffer, M. Ru-, Rh-, and Pd-Catalyzed C－C Bond Formation Involving C－H Activation and Addition on Unsaturated Substrates: Reactions and Mechanistic Aspects." [J] Chem. Rev. 2002,102,1731-1770.
[3] Godula, K.; Sames, D. Science 2006, 312, 67.
[4] Alberico, D.; Scott, M. E.; Lautens, M. Aryl-Aryl Bond Formation by Transition-Metal-Catalyzed Direct Arylation." [J] Chem. Rev. 2007,107, 174.
[5] Dick, A. R.; Hull, K. L.; Sanford, M. S. A Highly Selective Catalytic Method for the Oxidative Functionalization of C-H Bonds." [J] J. Am. Chem. Soc. 2004,126, 2300-2301.
[6] Desai, L. V.; Stowers, K. J.; Sanford, M. S. Insights into Directing Group Ability in Palladium-Catalyzed C-H Bond Functionalization." [J] J. Am. Chem. Soc. 2008, 130, 13285-13293.
[7] Kalyani, D.; Dick, A. R.; Anani, W. Q.; Sanford, M. S. A Simple Catalytic Method for the Regioselective Halogenation of Arenes." [J] Org. Lett. 2006, 8, 2523-2526.
[8] Wan, X. B.; Ma, Z. X.; Li, B. J.; Zhang, K. Y.; Cao, S. K.; Zhang, S. W.; Shi, Z. J. Highly Selective C-H Functionalization/Halogenation of Acetanilide." [J] J. Am. Chem. Soc. 2006,128,7416-7417.
[9] Chen, X.; Hao, X.-S.; Goodhue, C. E.; Yu, J.-Q. Cu(Ⅱ)-Catalyzed Functionalizations of Aryl C-H Bonds Using O_2 as an Oxidant." [J] J. Am. Chem. Soc. 2006,128,6190-6191.
[10] Mei, T.-S.; Giri, R.; Maugel, N.; Yu, J.-Q. Pd~(Ⅱ)-Catalyzed Monoselective ortho Halogenation of C-H Bonds Assisted by Counter Cations: A Complementary Method to Directed ortho-Lithiation." [J] Angew. Chem., Int. Ed. 2008, 47,5215-5219.
[11] Dipannita, K.; Deprez, N. R.; Deprez, L. V.; Sanford, M. S. Oxidative C－H Activation / C-C Bond Forming Reactions: Synthetic Scope and Mechanistic Insights." [J] J. Am. Chem. Soc. 2005,127, 7330-7331.
[12] Chiong, H. A.; Pham, Q.-N.; Daugulis, 0. Two Methods for Direct ortho-Arylation of Benzoic Acids." [J] J. Am. Chem. Soc. 2007,129, 9879-9884.
[13] Deng, G. J.; Zhao, L.; Li, C.-J. Ruthenium-Catalyzed Oxidative Cross-Coupling of Chelating Arenes and Cycloalkanes." [J] Angew. Chem., Int. Ed. 2008, 47, 6278-6282.
[14] Zhao, X. D.; Yu, Z. K. Rhodium-Catalyzed Regioselective C-H Functionalization via Decarbonylation of Acid Chlorides and C-H Bond Activation under Phosphine-Free Conditions." [J] J. Am. Chem. Soc. 2008, 130,8136-8137.
[15] Tsai, A. S.; Bergman, R. G.; Ellman, J. A. Asymmetric Synthesis of (-)-Incarvillateine Employing an Intramolecular Alkylation via Rh-Catalyzed Olefinic C－H Bond Activation." [J] J. Am. Chem. Soc. 2008,130, 6316-6317.
[16] Giri, R.; Yu, J.-Q. Synthesis of 1,2- and 1,3-Dicarboxylic Acids via Pd(Ⅱ)-Catalyzed Carboxylation of Aryl and Vinyl C－H Bonds." [J] J. Am. Chem. Soc. 2008,130, 14082-14083.
[17] Campeau, L.-C.; Schipper, D. J.; Fagnou, K. C. Site-Selective sp~2 and Benzylic sp~3 Palladium-Catalyzed Direct Arylation." [J] J. Am. Chem. Soc. 2008, 130, 3266-3267.
[18] Thu, H.-Y.; Yu, W.-Y.; Che, C.-M. Intermolecular Amidation of Unactivated sp~2 and sp~3 C-H Bonds via Palladium-Catalyzed Cascade C-H Activation/Nitrene Insertion." [J] J. Am. Chem. Soc. 2006,128, 9048-9049.
[19] Bandgar, B. P.; Bettigeri, S. V.; Phopase, J. Unsymmetrical Diaryl Sulfones through Palladium-Catalyzed Coupling of Aryl Boronic Acids and Arylsulfonyl Chlorides." [J] Org. Lett. 2004, 6, 2105-2108.
[20] Zhu, W.; Ma, D. W. Synthesis of Aryl Sulfones via (?)-Proline-Promoted CuI-Catalyzed Coupling Reaction of Aryl Halides with Sulfinic Acid Salts." [J] J. Org. Chem. 2005, 70, 2696.
[21] Kar, A.; Sayyed,I. A.; Lo, W. F.; Kaiser, H. M.; Beller, M.; Tse, M. K. A General Copper-Catalyzed Sulfonylation of Arylboronic Acids." [J] Org. Lett. 2007, 9, 3405-3408.
[22] Huggins, J. M.; Bergman, R. G. Mechanism, regiochemistry, and stereochemistry of the insertion reaction of alkynes with methyl(2,4-pentanedionato)(triphenyl- phosphine)nickel. A cis insertion that leads to trans kinetic products." [J] J. Am. Chem. Soc. 1981,103, 3002-3011.
[23] Reddy, K. R.; Surekha, K.; Lee, G.-H.; Peng, S.-M.; Liu, S.-T. Single and Multiple Insertion of Alkynes into Pd-Acyl and Pd-Aryl Bonds in Cationic Palladium Complexes with Phosphine-Imine (P - N) Ligands." [J] Organometallics 2001,20, 5557-5563.
[24] Ferstl, W.; Sakodinskaya, I. K.; Beydoun-Sutter, N.; Borgne, G. L.; Pfeffer, M.; Ryabov, A. D. Mechanism of Alkyne Insertion into the Ru-C Bonds of Orthoruthenated Compounds Featuring Similarity of the Ru(Ⅱ) and Pd(Ⅱ) Reactions." [J] Organometallics 1997,16,411-418.
[25] Maassarani, F.; Pfeffer, M.; Borgne, G. L. Reaction of cyclopalladated compounds Part 16. Stepwise insertion of one, two, and three alkyne molecules into the palladium-carbon bond of a six-membered palladocycle. One-pot synthesis of spirocyclic compounds." [J] Organometallics 1987, 6, 2043-2053.
[26] Li, L.; Brennessel, W. W.; Jones, W. D. An Efficient Low-Temperature Route to Polycyclic Isoquinoline Salt Synthesis via C-H Activation with [Cp~*MCl_2]_2 (M = Rh, Ir)." [J] J. Am. Chem. Soc. 2008,130,12414-12419.
[2]Cram,D.J.;Cram,J.M.“Host-Guest Chemistry-Complexes between Organic Compound Simulate the Substrate Selectivity of Enzymes.” [J]Science 1974,183,803 - 805.
[3]J.-M.Lehn,“Cryptates:inclusion complexes of macropolycyclic receptor molecules.” [J]Pure Appl.Chem.1978,50,871 - 875.
[4]J.-M.Lehn,“Supermolecular Chemistry Scope and Perspectives of Molecules,Supramolecules,and Molecular Devices.”[J]Angew.Chem.Int.Ed.1988,27,89-112.
[5]J.-M.Lehn,“Design of organic complexing agents.Strategies towards properties.” [J]Struct.Bonding 1973,16,1 - 9.
[6]James,S.L.“Metal-organic Frameworks.”[J]Chem.Soc.Rev.2003,32,276 - 288.
[7]Fujita,M.;Yazaki,J.;Ogura,K.“Preparation of a macrocyclic polynuclear complex,[(en)Pd(4,4'-bpy)]4(N03)8 (en = ethylenediamine,bpy = bipyridine),which recognizes an organic molecule in aqueous media.”[J]J.Am.Chem.Soc,1990,112,5645 - 5647
[8](a) Stang,P.J.;Olenyuk,B.“Self-assembly,symmetry,and molecular architecture:Coordination as the motif in the rational design of supramolecular metallacyclic polygons and polyhedra.”[J]Acc.Chem.Res.1997,30,502 - 518;(b) Leininger,S.;Olenyuk,B.;Stang,P.J.“Self-Assembly of Discrete Cyclic Nanostructures Mediated by Transition Metals.”[J]Chem.Rev.2000,100,853 - 907.(c) Seidel,S.R.;Stang,P.J.“High-Symmetry Coordination Cages via Self-Assembly.”[J]Acc.Chem.Res.2002,35,972 - 983.
[9]Cho,Y.L.;Uh,H.;Chang,S.-Y.;Chang,H.-Y.;Choi,M.-G.;Shin,I.;Jeong,K.-S.“A Double-Walled Hexagonal Supermolecule Assembled by Guest Binding.”[J]J.Am.Chem.Soc.2001,123,1258 -1259
[10]Fujita,M.;Tominaga,M.;Hori,A.;Therrien,B.“Coordination Assemblies from a Pd(Ⅱ)-Cornered Square Complex.”[J]Acc.Chem.Res.2005,38,369 - 378.
[11](a) Fujita,M.;Oguro,D.;Miyazawa,M.;Oka,H.;Yamaguchi,K.;Ogura,K."Self-assembly of ten molecules into a nanometer-sized organic host frameworks.”[J]Nature 1995,578,469 - 471.(b) Takeda,N.;Umemoto,K.;Yamaguchi K.;Fujita,M.“A nanometersized hexahedral coordination capsule assembled from 24 components.” [J]Nature 1999,398,794-796.
[12](a)Kusukawa,T.;Fujita,M.“Encapsulation of large,neutral molecules in a self-assembled nanocage incorporating six palladium(Ⅱ)ions.” [J]Angew.Chem.Int.Ed.1998,37,3142-3144.(b) Kusukawa,T.;Fujita,M.'“Ship-in-a-bottle” formation of stable hydrophobic dimers of cis-azobenzene and-stilbene derivatives in a self-assembled coordination nanocage.” [J]J.Am.Chem.Soc.1999,121,1397-1398.
[13]Kusukawa,T.;Yoshizawa,M.;Fujita,M.“Probing guest geometry and dynamics through host-guest interactions.” [J]Angew.Chem.Int.Ed.2001,40,1879-1884.
[14]Kusukawa,T.;Fujita,M.“Self-assembled M_6L_4-type coordination nanocage with 2,2'-bipyridine ancillary ligands.Facile crystallization and X-ray analysisof shape-selective enclathration of neutral guests in the cage.” [J]J.Am.Chem.Soc.2002,124,13576-13582.
[15]Ito,H.;Kusukawa,T.;Fujita,M.“Wacker oxidation in an aqueous phase through the reverse phase-transfer catalysis of a selfassembled nanocage.” [J]Chem.Lett.2000,598-599.
[16]Umemoto,K.;Yamaguchi,K.;Fujita,M.“Molecular paneling via coordination:Guest-controlled assembly of open cone and tetrahedron structures from eight metals and four ligands.” [J]J.Am.Chem.Soc.2000,122,7150-7151.
[17]Kumazawa, K.; Biradha, K.; Kusukawa, T.; Okano, T.; Fujita, M.“Multicomponent assembly of a pyrazine-pillared coordination cage that selectively binds planar guests by intercalation.” [J]Angew.Chem.Int.Ed.2003,42,3909-3913.
[18]Fujita,N.;Biradha,K.;Fujita,M.;Sakamoto,S.;Yamaguchi,K.“A porphyrin prism:Structural switching triggered by guest inclusion.” [J]Angew.Chem.Int.Ed.2001,40,1718-1721.
[19]Yamanoi,Y.;Sakamoto,Y.;Kusukawa,T.;Fujita,M;Sakamoto,S.;Yamaguchi,K.“Dynamic assembly of coordination boxes from (en)Pd(Ⅱ)unit and a rectangular panel-like ligand:NMR,CSI-MS,and X-ray studies.” [J]J.Am.Chem.Soc.2001,123,980-981.
[20]Aoyagi,M.;Biradha,K.;Fujita,M.“Quantitative formation of coordination nanotubes templated by rodlike guests.” [J]J.Am.Chem.Soc.1999,121,7457-7458.
[21]Tominaga,M.;Tashiro,S.;Aoyagi,M.;Fujita,M.“Dynamic aspects in host-guest complexation by coordination nanotubes.” [J]Chem.Commun.2002,2038-2039.
[22]Aoyagi,M.;Tashiro,S.;Tominaga,M.;Biradha,K.;Fujita,M.“Spectroscopic and crystallographic studies on the stability of selfassembled coordination nanotubes.”[J]Chem.Commun.2002,2036-2037.
[23]Tashiro,S.;Tominaga,M.;Kusukawa,T.;Kawano,M.;Sakamoto,S.;Yamaguchi,K.;Fujita,M.“Pd(Ⅱ)-directed dynamic assembly of a dodecapyridine ligand into end-capped and open tubes:The importance of kinetic control in self-assembly.”Angew.Chem.Int.Ed.2003,42,3267-3270.
[24](a)Fujita,M.“Metal-directed self-assembly of two-and threedimensional synthetic receptors.” [J]Chem.Soc.Rev.1998,27,417-425.(b)Fujita,M.;Umemoto,K.;Yoshizawa,M.;Fujita,N.;Kusukawa,T.;Biradha,K.“Molecular paneling via coordination.” [J]Chem.Commun.2001,509-518.
[25]Kumazawa,K.;Yamanoi,Y.;Yoshizawa,M.;Kusukawa,T.;Fujita,M.A “Palladium(Ⅱ)-clipped aromatic sandwich.”[J]Angew.Chem.Int.Ed.2004,43,5936-5940.
[26](a)Yoshizawa,M.;Takeyama,Y.;Kusukawa,T.;Fujita,M.“Cavitydirected,highly stereoselective [2+2]photodimerization of olefins within self-assembled coordination cages.” [J]Angew.Chem.Int.Ed.2002,41,1347-1349.(b)Yoshizawa,M.;Takeyama,Y.;Okano T.;Fujita,M.“Cavity-directed synthesis within a self-assembled coordination cage:highly selective [2+2]cross-photodimerization of olefins.” [J]J.Am.Chem.Soc.2003,125,3243-3247.
[27](a)Tashiro,S.;Tominaga,M.;Kawano,M.;Therrien,B.;Ozeki,T.;Fujita,M.“Sequence-Selective Recognition of Peptides within the Single Binding Pocket of a Self-Assembled Coordination Cage.” [J]J.Am.Chem.Soc.2005,127,4546-4547.(b)Yoshizawa,M.;Tamura,M.;Fujita,M.“Diels-Alder in Aqueous Molecular Hosts:Unusual Regioselectivity and Efficient Catalysis.” [J]Science 2006,312,251-254.(c)Nishioka,Y.;Yamaguchi,T.;Yoshizawa,M.;Fujita,M.“Unusual [2 + 4]and [2 + 2]Cycloadditions of Arenes in the Confined Cavity of Self-Assembled Cages.” [J]J.Am.Chem.Soc.2007,129,7000-7001.(d)Furusawa,T.;Kawano,M.;Fujita,M.“The Confined Cavity of a Coordination Cage Suppresses the Photocleavage of α-Diketones To Give Cyclization Products through Kinetically Unfavorable Pathways.” [J]Angew.Chem.Int.Ed.2007,46,5717-5719.(e)Yamaguchi,T.;Fujita,M.“Highly Selective Photomediated 1,4-Radical Addition to o-Quinones Controlled by a Self-Assembled Cage.” [J]Angew.Chem.Int.Ed.2008,47,2067-2069.
[28](a)Pluth,M.D.;Bergman,R.G.;Raymond,K.N.“Acid Catalysis in Basic Solution:A Supramolecular Host Promotes Orthoformate Hydrolysis.” [J]Science 2007,316,85-88.(b)Leung,D.H.;Bergman,R.G.;Raymond,K.N.“Highly Selective Supramolecular Catalyzed Allylic Alcohol Isomerization.” [J]J.Am.Chem.Soc.2007,129,2746-2747.(c)Fiedler,D.;Leung,D.H.;Bergman,R.G.;Raymond,K.N.“Selective Molecular Recognition,C-H Bond Activation,and Catalysis in Nanoscale Reaction Vessels.” [J]Acc.Chem.Res.2005,38,351-360.(d)Fiedler,D.;Bergman,R.G.;Raymond,K.N.“Stabilization of Reactive Organometallic Intermediates inside a Self-Assembled Nanoscale Host.” [J]Angew.Chem.Int.Ed.2006,45,745-748.
[29]Merlau,M.L.;del Pilar Mejia,M.;Nguyen,S.T.;Hupp,J.T.“Artificial Enzymes Formed through Directed Assembly of Molecular Square Encapsulated Epoxidation Catalysts.” [J]Angew.Chem.Int.Ed.2001,40,4239-4242.
[30](a)Farrell,J.R.;Mirkin,C.A.;Guzei,I.A.;Liable-Sands,L.M.;Rheingold,A.L.“The weak-link approach to the synthesis of inorganic macrocyles.” [J]Angew.Chem.Int.Ed.1998,37,465-467.(b)Holliday,B.J.;Farrell,J.R.;Mirkin,C.A.;Lam,K.-C;Rheingold,A.L.“Metal-directed assembly of triple-layered fluorescent metallcyclophanes.” [J]J.Am.Chem.Soc.1999,121,6316-6317.
[31](a)Liu,X.;Eisenberg,A.H.;Stern,C.L.;Mirkin,C.A.“Flexible redoxactive binuclear macrocycles formed via the weak-link approach and novel hemilabile ligands with N,N,N',N'-tetramethyl-1,4-phenylenediamine units.” [J]Inorg.Chem.2001,40,2940-2941.(b)Holliday,B.J.;Mirkin,C.A.Strategies for the Construction of Supramolecular Compounds through Coordination Chemistry.Angew.Chem.Int.Ed.2001,40,2022-2043.
[32]Ovchinnikov,M.V.;Holliday,B.J.;Mirkin,C.A.;Zakharov,L.N.;Rheingold,A.L.“Threefold symmetric trimetallic macrocycles formed via the weak-link approach.”[J]Proc.Natl.Acad.Sci.U.S.A.2002,99,4927-4931.
[33](a)Eisenberg,A.H.;Ovchinnikov,M.V.;Mirkin,C.A.“Stepwise formation of heterobimetallic macrocycles synthesized via the weak-link approach.” [J]J.Am.Chem.Soc.2003,125,2836-2837.(b)Gianneschi,N.C;Bertin,P.A.;Nguyen, S.T.;Mirkin,C.A.;Zakharov,L.N.;Rheingold,A.L.“A supramolecular approach to an allosteric catalyst.”J.Am.Chem.Soc.2003,125,10508-10509.
[34](a)Khoshbin,M.S.;Ovchinnikov,M.V.;Mirkin,C.A.;Zakharov,L.N.;Rheingold,A.L.“Binuclear ruthenium macrocycles formed via the weak-link approach.”Inorg.Chem.2005,44,496-501.(b)Brown,A.M.;Ovchinnikov,M.V.;Mirkin,C.A.“Heteroligated Rh(Ⅰ)tweezer complexes.” [J]Angew.Chem.Int.Ed.2005,44,4207-4209.
[35](a)Gianneschi,N.C;Masar,M.S.,Ⅲ;Mirkin,C.A.“Development of a Coordination Chemistry-Based Approach for Functional Supramolecular Structures.” [J]Acc.Chem.Res.2005,38,825-837.(b)Brown,A.M.;Ovchinnikov,M.V.;Stern,C.L.;Mirkin,C.A.“Tetrametallic Rectangular Box Complexes Assembled from Heteroligated Macrocycles.” [J]Chem.Commun.2006,4386-4388.(c)Brown,A.M.;Ovchinnikov,M.V.;Stern,C.L.;Mirkin,C.A.“Halide-Induced Supramolecular Ligand Rearrangement.” [J]J.Am.Chem.Soc.2004,726;14316-14317.
[36](a)Oliveri,C.G.;Gianneschi,N.C;Nguyen,S.T.;Mirkin,C.A.;Stern,C.L.;Wawrzak, Z.; Pink, M. “Supramolecular Allosteric Cofacial Porphyrin Complexes.” [J]J.Am.Chem.Soc.2006,128,16286-16296.(b)Oliveri,C.G.;Heo,J.;Nguyen,S.T.;Mirkin,C.A.;Wawrzak,Z.“A Convergent Coordination Chemistry-Based Approach to Dissymmetric Macrocyclic Cofacial Porphyrin Complexes.”[J]Inorg.Chem.2007,46,7716-7718.(c)Oliveri,C.G.;Nguyen,S.T.;Mirkin,C.A.“A Highly Modular and Convergent Approach for the Synthesis of Stimulant-Responsive Heteroligated Cofacial Porphyrin Tweezer Complexes.”[J]Inorg.Chem.2008,47,2755-2763.
[37](a)Angaridis,P.;Berry,J.F.B.;Cotton,F.A.;Murillo,C.A.;Wang,X.“Molecular Squares with Paramagnetic Diruthenium Corners: Synthetic and Crystallographic Challenges.”[J]J.Am.Chem.Soc.2003,125,10327-10334.(b)Cotton,F.A.;Lin,C;Murillo,C.A.“Supramolecular Arrays Based on Dimetal Building Units.”[J]Acc.Chem.Res.2001,34,759-771.
[38]Benkstein,K.D.;Hupp,J.T.;Stern,C.L.“Molecular Rectangles Based on Rhenium(Ⅰ)Coordination Chemistry.” [J]J.Am.Chem.Soc.1998,120,12982-12983.
[39]Lee,S.J.;Lin,W.“Chiral Metallocycles:Rational Synthesis and Novel Applications.”[J]Acc.Chem.Res.2008,41,521-537.
[40]Albrecht,M.'“Let's Twist Again”-Double-Stranded,Triple-Stranded,and Circular Helicates.”[J]Chem.Rev.2001,101,3457-3497.
[41]Chi,K.W.;Addicott,C;Stang,P.J.“Ambidentate Pyridyl-carboxylate Ligands in the Coordination-Driven Self-Assembly of 2D Pt Macrocycles:Self-Selection for a Single Isomer.” [J]J.Am.Chem.Soc.2004,126,16569-16574.
[42]Addicott,C;Das,N.;Stang,P.J.“Self-Recognition in the Coordination Driven Self-Assembly of 2-D Polygons.”[J]Inorg.Chem.2004,43,5335-5338.
[43]Olenyuk,B.;Whiteford,J.A.;Fechtenkotter,A.;Stang,P.J.“Self-Assembly of Nanoscale Cuboctahedra by Coordination Chemistry.”[J]Nature 1999,398,796-799.
[44]Olenyuk,B.;Levin,M.D.;Whiteford,J.A.;Shield,J.E.;Stang,P.J.“Self-Assembly of Nanoscopic Dodecahedra from 50 Predesigned Components”[J]J.Am.Chem.Soc.1999,121,10434-10435.
[45]Resendiz,M.J.E.;Noveron,J.C;Disteldorf,H.;Fischer,Sonja.;a Stang,P.J.“A Self-Assembled Supramolecular Optical Sensor for Ni(Ⅱ),Cd(Ⅱ),and Cr(Ⅲ)”[J]Org.Lett.2004,6,651-653.
[46]G.Oliveri,Pirmin A.Ulmann,Michael J.Wiester,and Chad A.Mirkin,“Heteroligated Supramolecular Coordination Complexes Formed via the Halide-Induced Ligand Rearrangement Reaction Christopher.” [J]Acc.Chem.Res.2008,47,1618-1629.
[47](a)Fish,R.H.“Bioorganometallic chemistry:synthesis,structure,and molecular recognition chemistry of (η~5-pentamethylcyclopentadienyl)-rhodium-DNA/RNA complexes in water.” [J]Coord.Chem.Rev.1999,185-186,569.(b)Fish,R.H.;Jaouen.G.“Bioorganometallic Chemistry:Structural Diversity of Organometallic Complexes with Bioligands and Molecular Recognition Studies of Several Supramolecular Hosts with Biomolecules,Alkali-Metal Ions,and Organometallic Pharmaceuticals.” [J]Organometallics 2003,22,2166-2177.
[48]Annen,P.;Schildberg,S.;Sheldrick,W.S.“(η~5-Pentamethylcyclopentadienyl)-iridium(Ⅲ)complexes of purine nucleobases and nucleotides:a comparison with (η~6-arene)ruthenium(Ⅱ)and (η~5-pentamethylcyclopentadienyl)rhodium(Ⅲ)species.” Inorg.Chim.Acta 2000,307,115-124.
[49](a)Yamanari,K.;Ito,R.;Yamamoto,S.;Konno,T.;Fuyuhiro,A.;Fujioka,K.;Arakawa,R.“Cyclic Tetramers Composed of Rhodium(Ⅲ),Iridium(Ⅲ),or Ruthenium(Ⅱ)Half-Sandwich and 6-Purinethiones.” [J]Inorg.Chem.2002,41, 6824-6830. (b) Yamanari, K.; Yamamoto, S.; Ito, R.; Kushi, Y.; Fuyuhiro, A.; Kubota, N.; Fukuo, T.; Arakawa, R. "Cyclic Hexamer with a Cubic Cavity: Crystal Structure of [{Rh(6-Purinethione Ribosido)(Cp~*)}_6](CF_3SO_3)_6." [J] Angew. Chem. Int. Ed. 2001, 40,2268 - 2271.
[50] Carmona, D.; Lamata, M. P.; Viguri, F.; Dobrinovich, I.; Lahoz, F. J.; Oro, L. A. "On the Sense of the Enantioselection in Hydrogen Transfer Reactions from 2-Propanol to Ketones." [J] Adv. Synth. Catal. 2002, 344,499 - 502.
[51] Katho, (?).; Carmona, D.; Viguri, F.; Remacha, C. D.; Kov(?)cs, J.; Jo(?), F.; Oro, L. A. "Enantioselective hydride transfer hydrogenation of ketones catalyzed by [(η~6-p-cymene)Ru(amino acidato)Cl] and [(η~6-p-cymene)Ru(amino acidato)]_3(BF_4)_3 complexes." [J] J. Organomet. Chem. 2000, 593-594, 299-306.
[52] Carmona, D.; Lahoz, F. J.; Atencio, R.; Oro, L. A.; Lamata, M. P.; Viguri, F.; Jos(?), E. S.; Vega, C.; Reyes, J.; Jo(?), F.; Kath(?), (?). "Trimerisation of the Cationic Fragments [(η-ring)M(Aa)]~+ ((η-ring) M=(η~5-C~5Me~5)Rh, (η~5-C~5Me~5)Ir, (η ~6-p-MeC_6H_4iPr)Ru; Aa= α-amino acidate) with Chiral Self-Recognition: Synthesis, Characterisation, Solution Studies and Catalytic Reactions of the Trimers [{η-ring)M(Aa)}_3](BF_4)_3." [J] Chem. Eur. J. 1999, 5,1544 -1564.
[53] Kramer, R.; Polborn, K.; Robl, C.; Beck, W. "Metal complexes of biologically important ligands. Part LXIV. Pentamethylcyclopentadienyl-rhodium(Ⅲ) complexes with a-amino acid derivatives as bridging ligands and with several chiral metal centers: synthesis and structure of [Cp~*Rh(μ- L -phenylalaninato)]_3(BF_4)_3 and [Cp~*Rh(μ-NHCOCH_2NCO_2CH_2Ph)]_2." [J] Inorg. Chim. Acta 1992, 198-200, 415 - 420.
[54] (a) Severin. K. "Supramolecular Chemistry with Organometallic Half-sandwich Complexes." [J] Chem. Comm. 2006, 3859 - 3867. (b) Severin K. "Self-Assembled Organometallic Receptors for Small Ions." [J] Coord. Chem.Rev. 2003,245, 3-10.
[55] (a) Grote, Z.; Scopelliti, R.; Severin, K. "Controlled Formation of Mixed-Metal Macrocycles Using Dynamic Exchange Processes and Steric Constraints." [J] Eur. J. Inorg. Chem. 2007, 694-700. (b) Olivier, C.; Solari, E.; Scopelliti, R.; Severin, K. "Breaking the Symmetry: Assembly of Cylindrical Nanostructures with a C_3-Symmetrical Ligand." [J] Inorg. Chem. 2008, 47,4454 - 4456.
[56] (a) Suzuki, H.; Tajima N.; Tatsumi, K.; Yamamoto, Y. "Molecular architecture via coordination: quasi-octahedral macrocycles of rhodium and iridium bearing a pentamethylcyclopentadienyl group." [J] Chem. Commun., 2000,1801 -1802. (b) Yamamoto, Y.; Suzuki, H.; Tajima N.; Tatsumi, K. Stepwise Formation of Quasi-Octahedral Macrocyclic Complexes of Rhodium(Ⅲ) and Iridium(Ⅲ) Bearing a Pentamethylcyclopentadienyl Group. Chem. -Eur. J. 2002, 8, 372 -379.
[57] Han, W. S.; Lee, S. W. "Various forms of linear dipyridyls in discrete rectangles, dinuclear rods, and one-dimensional networks containing (η~5-pentamethylcyclo- pentadienyl)rhodium(Ⅲ)" [J] Dalton Trans. 2004,2656 -1663.
[58] (a) Yan, H.; S(?)ss-Fink, G.; Neels A.; Stoeckli-Evans, H. "Mono-, Di- and Tetra-nuclear p-Cymeneruthenium Complexes Containing Oxalato Ligands." [J] Dalton Trans. 1997, 4345-4350. (b) Govindaswamy, P.; Linder, D.; Lacour, J.;Suss-Fink, G.; Therrien, B. "Chiral or Not Chiral? A Case Study of the Hexanuclear Metalloprisms Cp_6~*M_6(μ_3-tpt-kN)_2(μ-C_2O_4-kO)_3]~(6+) (M = Rh, Ir, tpt = 2,4,6-tri(pyridin-4-yl)-1,3,5-triazine)." [J] Dalton Trans. 2007, 4457-4463. (c) Govindaswamy, P.; Linder, D.; Lacour, J.; Suss-Fink, G.; Therrien, B. "Self-Assembled Hexanuclear Arene Ruthenium Metallo-Prisms with Unexpected Double Helical Chirality." [J] Chem. Commun. 2006, 4691-4693. (d) Govindaswamy, P.; S(?)ss-Fink, G.; Therrien, B. "Self-Assembled Chloro-Bridged (Arene)ruthenium Metallo-Prisms: Synthesis and Molecular Structure of Cationic Complexes of the Type [Ru_6(η~6-arene)_6(μ_3-tpt-κN)_2(μ-Cl)_6]~(6+)." [J] Organometallics 2007, 26, 915-924. (e) Therrien, B.; Siiss-Fink, G.; Govindaswamy, P.; Renfrew, A. K.; Dyson, P. J. "The "Complex-in-a-Complex" Cations [(acac)~2M(?)Ru~6(p-~iPrC_6H_4Me)_6(tpt)_2 (dhbq)_3]~(6+): A Trojan Horse for Cancer Cells." [J] Angew. Chem. Int. Ed. 2008,47, 3773 - 3776.
[59] Boyer, J. L.; Kuhlman, M. L.; Rauchfuss, T. B. "Evolution of Organo- Cyanometallate Cages: Supramolecular Architectures and New Cs~+-Specific Receptors." [J] Acc. Chem. Res. 2007,40, 233 - 242.
[60] (a) Wang, J.-Q.; Zhang, Z.; Weng, L.-H.; Jin, G.-X. "Synthesis and Characterization of Organometallic Macrocyclic Rhodium (Ⅲ) Complex with Pyrazine Ligangds." [J] Chin. Sci. Bull. 2004, 49, 1122-1125. (b) Wang, J.-Q.; Ren C.-X.; Jin, G.-X. "Synthesis and Structural Characterization of Macrocyclic Half-Sandwich Rhodium(Ⅲ) and Iridium(Ⅲ) Complexes Bearing Bipyridyl Derivatives and Terephthalate." [J] Organometallics 2006,25, 74 - 81.
[1] (a) Zhang, B.; Zhang, Y.; Zhang, J. B.; Li, J. C.; Zhu, D. B. "A neutral molecular-based layered magnet [Fe(C_2O_4)(CH_3OH)](n) exhibiting magnetic ordering at T-N approximate to 23 K." [J] Dalton Trans. 2008, 5037 - 5040. (b) Duan, Z. M.; Zhang, Y.; Zhang, B.; Zhu, D. B. "Co(C_2O_4)(HO(CH_2)_3OH): An Antiferromagnetic Neutral Zigzag Chain Compound Showing Long-Range Ordering of Spin Canting." [J] Inorg. Chem. 2008,47, 9152 - 9154.
[2] (a) Zhang, B.; Wang, Z. M.; Zhang, Y.; Takahashi, K.; Okano, Y.; Cui, H.; Kobayashi, H.; Inoue, K.; Kurmoo, M.; Pratt, F. L.; Zhu, D. B. "Hybrid organic-inorganic conductor with a magnetic chain anion: k-BETS_2[Fe~(Ⅲ)(C_2O_4)Cl_2] [BETS = bis(ethylenedithio)tetraselenafulvalene]." [J] Inorg. Chem. 2006, 45, 3275 - 3280. (b) Xu, H. B.; Wang, Z. M.; Liu, T.; Gao, S. "Synthesis, structure, and magnetic properties of (A)[Fe~(Ⅲ)(oxalate)Cl_2] (A = alkyl ammonium cations) with anionic 1D [Fe~(Ⅲ)(oxalate)Cl_2]~- chains." [J] Inorg. Chem. 2007, 46, 3089 - 3096.
[3] (a) Coronado, E.; Galan-Mascaros, J. R.; Marti-Gastaldo, C.; Martinez, A. M. "Heptacoordinated Mn-Ⅱ in oxalate-based bimetallic 2D magnets: synthesis and characterisation of [Mn(L)_6][Mn(CH_3OH)M~(Ⅲ)(ox)_3]_2 (M~(Ⅲ) = Cr, Rh; ox = oxalate dianion; L = H_2O, CH_3OH)." [J] Dalton Trans. 2006, 3294 - 3299. (b) Clemente -Leon, M.; Coronado, E.; Dias, J. C.; Soriano-Portillo, A.; Willett, R. "Synthesis, structure, and magnetic properties of [(S)-[PhCH(CH_3)N(CH_3)_3]] [Mn(CH_3CN)_(2/3)Cr(OX)_3]-(CH_3CN)_(solvate), a 2D chiral magnet containing a quaternary ammonium chiral cation." [J] Inorg. Chem. 2008, 47, 6458 - 6463.
[4] Decurtins, S.; Pellaux, R.; Antorrena, G.; Palacio, F. "Multifunctional coordination compounds: design and properties." [J] Coord. Chem. Rev. 1999, 192, 841 - 854.
[5] (a) Wang, X. Y.; Wang, Z. M.; Gao, S. "Constructing magnetic molecular solids by employing three-atom ligands as bridges." [J] Chem. Commun. 2008,281 - 294. (b) Zhiming Duan, Z. M.; Zhang, Y.; Zhang, B.; Pratt, F. L. "Two Homometallic Antiferromagnets Based on Oxalato-Bridged Honeycomb Assemblies:(A)_2[M~Ⅱ (C_2O_4)_3](A = Ammonium Salt Derived from Diethylenetriamine;M~Ⅱ = Fe~(2+),Co~(2+)).“ [J]Inorg.Chem.,2009,48,2140-2146.
[6](a)Hursthouse,M.B.;Light,M.E.;Price,D.J.“One-dimensional magnetism in anhydrous iron and cobalt ternary oxalates with rare trigonal-prismatic metal coordination environment.” [J]Angew.Chem.,Int.Ed.2004,43,472-475.(b)Li,L.L.;Lin,K.;Ho,C.J.;Sun,C.P.;Yang,H.D.“A coordination pi-pi framework exhibits spontaneous magnetization.”[J]Chem.Commun.2006,1286-1288.(c)Coronado,E.;Galan-Mascaros,J.R.;Marti-Gastaldo,C.“Single Chain Magnets Based on the Oxalate Ligand.” [J]J.Am.Chem.Soc.2008,130,14987-14989.
[7]Tamaki,H.;Zhang,Z.J.;Matusmoto,N.;Kida,S.;Koikawa,M.;Achiwa,N.;Hashimoto,Y.;Okawa,H.“Design of metal-complex magnets-syntheses and magnetic-properties of mixed-metal assemblies (NBU4[MCR(OX)_3])_x(NBU~(4+)=Tetra(Normal-Butyl)Ammonium Ion OX~(2-)= Oxalate Ion M= Mn~(2+),Fe~(2+),Co~(2+),Ni~(2+),Cu~(2+),Zn~(2+)).” [J] J.Am.Chem.Soc.1992,114,6974-6979.
[8](a)Hemandez-Molina,M.;Lloret,F.;Ruiz-Perez,C;Julve,M.“Weak ferromagnetism in chiral 3-dimensional oxalato-bridged cobalt(Ⅱ)compounds.Crystal structure of [Co(bpy)_3][Co_2(ox)_3]ClO_4.” [J]Inorg.Chem.1998,37,4131-4135.(b)Armentano,D.;Munno,G.D.;Mastropietro,T.F.;Lloret,G.;Julve,M.“A novel supramolecular assembly in an iron(Ⅲ)compound exhibiting magnetic ordering at 70 K.” [J]Chem.Commun.2004,1160-1161.(c)Armentano,D.;Munno,G.D.;Mastropietro,T.F.;Julve,M.;Lloret,F.“Intermolecular proton transfer in solid phase:A rare example of crystal-to-crystal transformation from hydroxo-to oxo-bridged iron(Ⅲ)molecule-based magnet.” [J]J.Am.Chem.Soc.2005,127,10778-10779.
[9](a)Coronado,E.;Galan-Mascaros,J.R.;Gomez-Garcia,C.J.;Laukhin,V.“Coexistence of ferromagnetism and metallic conductivity in a molecule-based layered compound.” [J]Nature 2000,408,447-449.(b)Ballester,G.;Coronado,E.;Giemenez-Saiz,C;Romero,F.M.“Nitroxide radicals as templating agents in the synthesis of magnets based on three-dimensional oxalato-bridged heterodimetallic networks.” [J]Angew.Chem.,Int.Ed.2001,40,792-795.(c)Alberola,A.;Coronado,E.;Galan-Mascaros,J.R.;Gimenez-Saiz,C;Gomez-Garcia,C.J.“A molecular metal ferromagnet from the organic donor bis(ethylenedithio)tetraselenafulvalene and bimetallic oxalate complexes.” [J]J. Am.Chem.Soc.2003,125,10774-10775.(d)Coronado,E.;Galan-Mascaros,J.R.;Marti-Gastaldo,C.“Synthesis and characterization of a soluble bimetallic oxalate-based bidimensional magnet:[K(18-crown-6)]_3[Mn_3(H_2O_4[Cr(ox)_3]_3].” [J]Inorg.Chem.2006,45,1882-1884.
[10](a)Cariati,E.;Macchi,R.;Roberto,D.;Ugo,R.;Galli,S.;Casati,N.;Macchi,P.;Sironi,A.;Bogani,L.;Caneschi,A.;Gatteschi,D.“Polyfunctional inorganic-organic hybrid materials:An unusual kind of NLO active layered mixed metal oxalates with tunable magnetic properties and very large seond harmonic generation.” [J]J.Am.Chem.Soc.2007,129,9410-9420.(b)Train,C;Gheorghe,R.;Krstic,V.;Chamoreau,L.;Ovanesyan,N.S.;Rikken,G.L.;Gruselle,M.;Verdaguer,M.“Strong magneto-chiral dichroism in enantiopure chiral ferromagnets.” [J]Nature Mater.2008,7,729-734.
[11]White C.,Yates A.,Maitlis,P.M.“η~5-pentamethylcyclopentadienyl Rhodium and Iridium compounds.” [J]Inorg.Synth.1992,29,228-230.
[12]Bennett M.A.,Smith A.K.,“Arene ruthenium(Ⅱ)complexes formed by dehydrogenation of cyclohexadienes with ruthenium(Ⅲ)trichloride.” [J]J.Chem.Soc,Dalton Trans.1974,233-241.
[13]Grotjahn,D.B.;Lo,H.C;Dinoso,J.;Adkins,C.D.;Li,C;Nolan,S.P.;Hubbard,J.L.“Studies of the Synthesis and Thermochemistry of Coordinatively Unsaturated Chelate Complexes (η~5-C_5Me_5)IrL_2 (L_2 = TsNCH_2CH_2NTs,TsNCH_2CO_2,CO_2CO_2).” [J]Inorg.Chem.2000,39,2493-2499.(b)Grotjahn,D.B.;Groy,T.L.“Formation of Coordinatively Unsaturated Cp~*Ir-Amino Acid Complexes and Their Highly Diastereoselective Complexation Reactions.” [J]J.Am.Chem.Soc.1994,116,6969-6970.(c)Grotjahn,D.B.;Groy,T.L.“Formation and Structure of Coordinatively Unsaturated CpIr-Amino Acid Complexes.Kinetic and Thermodynamic Control in Highly Diastereoselective Complexation Reactions.” [J]Organometallics 1995,14,3669-3682.
[14]Yan,H.;S(u|¨)ss-Fink,G.;Neels A.;Stoeckli-Evans,H.“Mono-,di-and tetra-nuclear p-cymeneruthenium complexes containing oxalato ligands.” [J]J.Chem.Soc.Dalton Trans.1997,4345-4350.
[15]J.-Q.Wang,C.-X.Ren,G.-X.Jin,“Route to multicluster containing ancillary ortho-carborane-1,2-dithiolato ligands.” [J]Chem.Comm.2005,4738-4740.
[16]Nakamoto,K.“Infrared and Raman Spectra of Inorganic and Coordination Compounds,Part B,5th ed.” Wiley:New York,1997;pp 74-77.
[17] (a) Coucouvanis, D.; Demadis, K. D.; Kim, C. G.; Dunham, R. W.; Kampf, J. W. "Single and double MoFe_3S_4 cubanes with Mo-coordinated polycarboxylate ligands - syntheses and structural characterization of (Et_(4n))_4([MoFe_3S_4Cl_4]_2 (μ-C_2O_4)) And (Et_(4n))_3[MoFe_3S_4Cl_4(C_2O_4)] clusters." [J] J. Am. Chem. Soc. 1993, 115, 3344 - 3345. (b) Castro, I.; Calatayud, M. L.; Sletten, J.; Lloret, F.; Julve, M. "Syntheses, crystal structures and magnetic properties of [Ni_2(C_2O_4)(tren)2][ClO_4]_2 and [Ni_2(C_4O_4)(tren)_2(H_2O)_2][ClO_4]_2 [tren equals tris(2-amino-ethyl)amine]." [J] J. Chem. Soc., Dalton Trans. 1997, 811 - 817. (c) Shinozaki, K.; Takahashi, N. "Molecular orbital calculations and spectroscopic study of the photochemical generation of bis(2,2'-bipyridine)rhodiuria(Ⅰ) from bis(2,2'-bipyridine)(oxalato)rhodium(Ⅲ." [J] Inorg. Chem. 1996, 35, 3917 -3924.
[18] Holloway, G. A.; Rauchfuss, T. B. "Direct observation of ligand-centered redox in Cp~*Rh_2(μ-C_2S_4)Cl_x (x=2, 0)." [J] Inorg. Chem. 1999, 38, 3018 - 3019.
[19] Grotjahn, D. B.; Lo, H. C.; Dinoso, J.; Adkins, C. D.; Li, C.; Nolan, S. P.; Hubbard, J. L. "Studies of the Synthesis and Thermochemistry of Coordinatively Unsaturated Chelate Complexes (η~5-C_5Me_5)IrL_2 (L_2 = TsNCH_2CH_2NTs, TsNCH_2CO_2, CO_2CO_2)." [J] Inorg. Chem. 2000, 39; 2493 - 2499.
[20] Wang, J.-Q.; Ren, C.-X.; Jin, G.-X. "Synthesis and structural characterization of macrocyclic half-sandwich rhodium(Ⅲ) and iridium(Ⅲ) complexes bearing bipyridyl derivatives and terephthalate." [J] Organometallics, 2006, 25, 74 - 81.
[21] (a) Toda, F. "Organic solid-state reactions with 100% yield." [J] Top. Curr. Chem., 2005, 254, 1 - 305.(b) Paradies J., Greger I., Kehr G., Erker G., Bergander K. and Fr(?)'hlich R. "Formation of an organometallic ladderane derivative by dynamic topochemical reaction control." [J] Angew. Chem. Int. Ed. 2006, 45, 7630 - 7633. (c) Mascitti V. and Corey E. J. "Total synthesis of (+/-)-pentacycloanammoxic acid." [J] J. Am. Chem. Soc. 2004,126, 15664 -15665. (d) Hopf H. "Step by step - From nonnatural to biological molecular ladders." [J] Angew. Chem. Int. Ed. 2003,42,2822 - 2825.
[22] (a) Bu(?)ar D.-K., Papaefstathiou G. S., Hamilton T. D., Chu Q., Georgiev I. G. and MacGillivray L. R. "Template-controlled reactivity in the organic solid state by principles of coordination-driven self-assembly." [J] Eur. J. Inorg. Chem. 2007, 4559 - 4568, and references there in.
[23] (a) Georgiev I. G. and MacGillivray L. R. "Metal-mediated reactivity in the organic solid state:from self-assembled complexes to metal-organic frameworks.” [J]Chem.Soc.Rev.2007,36,1239-1248.(b)Eubank J.F,Kravtsov V.C.and Eddaoudi M.“Synthesis of organic photodimeric cage molecules based on cycloaddition via metal-ligand directed assembly." [J]J.Am.Chem.Soc.2007,129,5820-5821.(c)Wang X.-Y,Wang Z.-M.;Gao S.“A pillared layer MOF with anion-tunable magnetic properties and photochemical [2+2]cycloaddition.” [J]Chem.Commun.2007,1127-1129.(d)Hill Y.and Briceno A.“Exploiting the use of hydrogen bonding and metal-coordination in the self-assembly of photoreactive multicomponent networks.” [J]Chem.Commun.2007,3930-3932.(f)Michaelides A.,Shoulika S.and Siskos M.G.“Assembly of a photoreactive coordination polymer containing rectangular grids” [J]Chem.Commun.2004,2418-2419.(g)Nagarathinam M.and Vittal J.J.“Anisotropic movements of coordination polymers upon desolvation:Solid-state transformation of a linear 1D coordination polymer to a ladderlike structure.”[J]Angew.Chem.,Int.Ed.2006,45,4337-4341.
[24](a)Suzuki,H.;Tajima,N.;Tatsumi,K.;Yamamoto,Y “Molecular architecture via coordination:quasi-octahedral macrocycles of rhodium and iridium bearing a pentamethylcyclopentadienyl group.” [J]Chem.Comm.2000,1801-1802.(b)Yamamotoa,Y.;Suzuki,H.;Tajima,N.;Tatsumi,K.“Stepwise Formation of Quasi-Octahedral Macrocyclic Complexes of Rhodium(Ⅲ)and Iridium(Ⅲ)Bearing a Pentamethylcyclopentadienyl Group.” [J]Chem.Eur.J.2002,8,372-379.
[25]Schmitt F.,Govindaswamy P.,Suss-Fink G.,Ang W.H.,Dyson P.J.,Juillerat-Jeanneret L.,Therrien B.“Ruthenium Porphyrin Compounds for Photodynamic Therapy of Cancer.” [J]J.Med.Chem.2008,51,1811-1816.
[26]Wang,J.-Q.;Ren,C.-X.;Jin,G-X.“Route to Multicluster Containing Ancillary ortho-Carborane-1,2-Dithiolato Ligands.” [J]Chem.Commun.2005,4738-4740.
[1] Kitagawa, S.; Kawata, S. "Coordination compounds of 1,4-dihydroxybenzo-quinone and its homologues. Structures and properties." [J] Coord. Chem. Rev.2002,224,11-34.
[2] Kabir, M. K.; Miyazaki; Kawata, N.; S.; Adachi, K.; Kumagai, H.; Inoue, K.; Kitagawa, S.; Iijima, K. "Novel layered structures constructed from iron-chloranilate compounds. " [J] Coord. Chem. Rev. 2000,198,157 -169.
[3] Yoshino, A.; Matsudaira, H.; Asato, E.; Koikawa, M.; Shiga, T.; Ohba, M.; Okawa, H. "Insertion of a strongly π-π stacked chloranilate pair into an M4 arrangement preorganized within a large macrocyclic ligand (M = Zn~(2+) and Cu~(2+))." [J] Chem. Commun. 2002,1258 -1259.
[4] Gregorio, S.; Jorge, V.; Gregorio, L.; Luis, S. J.; Luis, G.; Jose, P. "Exploring the Reactivity towards Acidic Protic Ligands of the Di--hydroxo Complex [NBu_4]_2[Pd_2{C_4(COOMe)_4}_2(μ-OH)_2]: A Convenient Precursor in the Preparation of New Palladacyclopentadiene Complexes." [J] Eur. J. Inorg. Chem. 2005, 12, 2360 - 2367.
[5] Prithwiraj, B. "Ruthenium-azoimine-chloranilates Synthesis, Spectra and Electrochemistry of Ruthenium(Ⅱ)-1-alkyl-2-(arylazo)imidazole-chloranilate Complexes." [J] Trans. Metal Chem. 2005,30,738.
[6]Luo,T.-T.;Liu,Y.-H.;Tsai,H.-L.;Su,C.-C;Ueng,C.-H.;Lu,K.-L.“A Novel Hybrid Supramolecular Network Assembled from Perfect π -π Stacking of an Anionic Inorganic Layer and a Cationic Hydronium-Ion-Mediated Organic Layer.” [J]Eur.J.Inorg.Chem.2004,21,4253-4258.
[7]Heinze,K.;Huttner,G.;Walter,O.“Metal-Metal Interactions in Dinuclear (triphos)Cobalt Complexes Exhibiting Mixed Valency.” [J]Eur.J.Inorg.Chem.1999,593-600.
[8]Carbonera,C;Dei,A.;Letard,J.-F.;Sangregorio,C;Sorace,L.“Thermally and Light-Induced Valence Tautomeric Transition in a Dinuclear Cobalt-Tetraoxolene Complex.” [J]Angew.Chem.,Int.Ed.2004,43,3136-3138.
[9]Tao,J.;Maruyama,H.;Sato,O.Valence Tautomeric Transitions with Thermal Hysteresis around Room Temperature and Photoinduced Effects Observed in a Cobalt-Tetraoxolene Complex.” [J]J.Am.Chem.Soc.2006,128,1790-1791.
[10]Gupta,P.;Das,A.;Basuli,F.;Castineiras,A.;Sheldrick,W.S.;Mayer-Figge,H.;Bhattacharya,S.“Variable Coordination Mode of Chloranilic Acid.Synthesis,Structure,and Electrochemical Properties of Some Osmium Complexes.” [J]Inorg.Chem.2005,44,2081-2088.
[11]Jasimuddin,S.;Byabartta,P.;Sinha,C;Mostafa,G.;Lu,T.H.“First example of ruthenium-azoimine-chloranilates: synthesis, structure, spectra and electrochemistry of ruthenium(Ⅱ)1-alkyl-2-(arylazo)imidazole chloranilates,and correlation of electronic properties with ZINDO calculation.”[J]Inorg.Chim.Acta 2004,357,2015-2026.
[12]Kawahara,M.;Kabir,M.K.;Yamada,K.;Adachi,K.;Kumagai,H.;Narumi,Y.;Kindo,K.;Kitagawa,S.;Kawata,S.“Module-Based Assembly of Copper(Ⅱ)Chloranilate Compounds: Syntheses, Crystal Structures, and Magnetic Properties of {[Cu_2(CA)(terpy)_2][Cu(CA)_2]}n and {[Cu_2(CA)(terpy)_2(dmso)_2][Cu(CA)_2(dmso)_2](EtOH)}_n (H_2CA = Chloranilic Acid,dmso = Dimethyl Sulfoxide).” [J]Inorg.Chem.2004,43,92-100.
[13]Nagayoshi,K.;Kabir,M.K.;Tobita,H.;Honda,K.;Kawahara,M.;Katada,M.;Adachi,K.;Nishikawa,H.;Ikemoto,I.;Kumagai,H.;Hosokoshi,Y.;Inoue,K.;Kitagawa,S.;Kawata,S.“Design of Novel Inorganic-Organic Hybrid Materials Based on Iron-Chloranilate Mononuclear Complexes: Characteristics of Hydrogen-Bond-Supported Layers toward the Intercalation of Guests.” [J]J.Am.Chem.Soc.2003,125,221-232.
[14] Min, K. S.; Rheingold, A. L.; DiPasdquale, A.; Miller, J. S. "Characterization of the Chloranilate(·3-) n Radical as a Strong Spin-Coupling Bridging Ligand." [J] Inorg. Chem. 2006,45, 6135 - 6137.
[15] Min, K. S.; DiPasdquale, A.; Goled, J. A.; Rheingold, A. L.; Miller, J. S. "Synthesis, Structure, and Magnetic Properties of Valence Ambiguous Dinuclear Antiferromagnetically Coupled Cobalt and Ferromagnetically Coupled Iron Complexes Containing the Chloranilate(2-) and the Significantly Stronger Coupling Chloranilate(·3-) Radical Trianion." [J] J. Am. Chem. Soc. 2007, 129, 2360 - 2368.
[16] Wang,J.-Q.; Ren, C.-X.; Jin, G.-X. "Synthesis and Structural Characterization of Macrocyclic Half-Sandwich Rhodium(Ⅲ) and Iridium(Ⅲ) Complexes Bearing Bipyridyl Derivatives and Terephthalate." [J] Organometallics 2006, 25,74 - 81.
[17] Han, W. S.; Lee, S. W. "Various forms of linear dipyridyls in discrete rectangles, dinuclear rods, and one-dimensional networks containing (η~5-pentamethylcyclopentadienyl)- rhodium(iii)." [J] Dalton Trans. 2004, 1656 -1663.
[18] Liao, R.-T.; Yang, W.-C.; Thanasekaran, P.; Tsai, C.-C.; Sathiyendiran, M.; Liu, Y.-H.; Rajendran, T.; Lin, H.-M.; Tseng, T.-W.; Lu, K.-L. "Rhenium-based molecular rectangular boxes with large inner cavity and high shape selectivity towards benzene molecule." [J] Chem. Commun. 2008, 27, 3175-3177.
[1] Alekseyeva, E. S.; Batsanov, A. S.; Boyd, L. A.; Fox, M. A.; Hibbert, T. G.; Howard, J. A. K.; Hugh, M. J. A.; Mackinnon, A.; Wade, K. "Intra- and inter-molecular carboranyl C-H … N hydrogen bonds in pyridyl-containing ortho-carboranes." [J] Dalton Trans. 2003,475 - 482.
[2] Abernethy, C. D.; Macdonald, C. L. B.; Cowley, A. H.; Clyburne, J. A. C. "A persistent C-H…C(π) T-stacked cation." [J] Chem. Commun. 2001, 61 - 62.
[3] Devic, T.; Evain, M.; Mo(?)lo, Y.; Canadell, E.; Auban-Senzier, P.; Fourmigu(?), M.; Batail, P. "Single Crystalline Commensurate Metallic Assemblages of π-slabs and CdI_2-Type Layers: Synthesis and Properties of β-(EDT-TTF-I_2)_2[Pb_(5/61/6)I_2]_3 and β-(EDT-TTF-I_2)_2[Pb_(2/3+x)Ag_(1/3-2xx)I_2]_3, x = 0.05." [J] J. Am. Chem. Soc. 2003, 125, 3295-3301.
[4] Khlobystov, A. N.; Blake, A. J.; Champness, N. R.; Lemenovskii, D. A.; Majouga, A. G.; Zyk, N. V.; Schr(?)der, M. "Supramolecular design of one-dimensional coordination polymers based on silver(Ⅰ) complexes of aromatic nitrogen-donor ligands." [J] Coord. Chem. Rev. 2001,222,155 -192.
[5] Pullen, A. E.; Olk, R. "The coordination chemistry of 1,3-dithiole-2-thione-4,5- dithiolate (dmit) and isologs." [J] Coord. Chem. Rev. 1999,188, 211 - 262.
[6] 洪茂椿,陈荣,梁文平“21世纪的无机化学”,北京:科学出版社,2005,283-285.
[7] Kasai, K.; Aoyagi, M.; Fujita, M. "Flexible Coordination Networks with Fluorinated Backbones. Remarkable Ability for Induced-Fit Enclathration of Organic Molecules." [J] J. Am. Chem. Soc. 2000,122,2140 - 2141.
[8] Raehm, L.; Mimassi, L.; Guyard-Duhayon, C.; Amouri, H. "Crucial Role of the Counteranion on the Templation of Metallomacrocycles and a 3D Network: Synthesis, Characterization, and Structural Analysis." [J] Inorg. Chem. 2003, 42, 5654 - 5659.
[9] Du, M.; Bu, X.-H.; Huang, Z.; Chen, S.-T.; Guo, Y.-M. "From Metallacyclophanes to 1-D Coordination Polymers: Role of Anions in Self-Assembly Processes of Copper(Ⅱ) and 2,5-Bis(3-pyridyl)-1,3,4-oxadiazole." [J] Inorg. Chem. 2003, 42, 552- 559.
[10] Oyaizu, K.; Tsuchida, E. "The First Oxovanadium Ring in [{O=V(salen)}_2(μ-F)] [VO(salen)][BF_4]·(CH_2Cl_2)_x Crystals." [J] J. Am. Chem. Soc. 2003, 125, 5630 -5631.
[11] Choi, H. J.; Suh, M. P. "Dynamic and Redox Active Pillared Bilayer Open Framework: Single-Crystal-to-Single-Crystal Transformations upon Guest Removal, Guest Exchange, and Framework Oxidation." [J] J. Am. Chem. Soc. 2004,126,15844-15851.
[12] Armentano, D.; Munno, G. D.; Mastropietro, T. F.; Julve, M.; Lioret, F. "Intermolecular Proton Transfer in Solid Phase: A Rare Example of Crystal-to-Crystal Transformation from Hydroxo- to Oxo-Bridged Iron(Ⅲ) Molecule-Based Magnet." [J] J. Am. Chem. Soc. 2005,127,10778 -10779.
[13] Chen, C.-L.; Goforth, A. M.; Smith, M. D.; Su, C.-Y.; zur Loye, H.-C. "Self-Assembly of Nanoparticles on Live Bacterium: An Avenue to Fabricate Electronic Devices." [J] Angew. Chem. Int. Ed. 2005, 44, 6673 - 6677.
[14] Wu, C.-D.; Lin, W.-B. "Highly Porous, Homochiral Metal-Organic Frameworks: Solvent-Exchange-Induced Single-Crystal to Single-Crystal Transformations." [J] Angew. Chem. Int. Ed. 2005, 44,1958-1961.
[15] Zhang, J.-P.; Lin, Y.-Y.; Zhang, W.-X.; Chen X.-M. "Temperature- or Guest-Induced Drastic Single-Crystal-to-Single-Crystal Transformations of a Nanoporous Coordination Polymer" [J] J. Am. Chem. Soc. 2005, 127, 14162 -14163.
[16] Takata, D.; Kitagawa, S. "Template Effects in Porous Coordination Polymers." [J] Chem. Mater. 2008, 20, 922 - 931 and references therein.
[17] Dong, Y.-B.; Zhang, Q.; Liu, L.-L.; Ma, J.-P; Tang, B.; Huang, R.-Q. "[Cu(C_(24)H_(22)N_4O_3)]·CH_2Cl_2: A Discrete Breathing Metallamacrocycle Showing Selective and Reversible Guest Adsorption with Retention of Single Crystallinity." [J] J. Am. Chem. Soc. 2007,129,1514 -1515.
[18] MacGillivray, L. R.; Papaefstathiou, G. S.; Fris￡i5, T.; Hamilton, T. D.; Bucar, D.-K.; Chu, Q.; Varshiney, D. B.; Georgiev, I. G. Supramolecular Control of Reactivity in the Solid State: From Templates to Ladderanes to Metal-Organic Frameworks." [J] Acc. Chem. Res. 2008,41,280 - 291.
[19] Han, Y.-F.; Lin, Y.-J.; Jia, W.-G.; Wang, G.-L.; Jin, G.-X., "Template-controlled topochemical photodimerization based on organometallic macrocycles through single-crystal to single-crystal transformation." [J] Chem. Commun. 2008, 1807 -1809.
[1] (a) Wilkinson G.; Stone, G. F. A.; Abel, E. W. Comprehensive Organometallic Chemistry. Pergamon Press, Oxford, 1982. (b) Cotton, F. A. Advanced inorganic chemistry. 6th ed. New York : John Wiley & Sons, Inc. 1999. (c) Stiefel, E. I.; Karlin, K. D. Progress in Inorganic Chemistry, John Wiley & Sons, Inc. 2004.
[2] (a) Dubois, M. R. "Catalytic applications of transition-metal complexes with sulfide ligands." [J] Chem. Rev. 1989, 89, 1-9. (b) L. C. Roof. J. W. Kolis. "New developments in the coordination chemistry of inorganic selenide and telluride ligands." [J] Chem. Rev. 1993, 93, 1037-1080.
[3] Margoshes, M. B.; Vallee, L. "A Cadmium protein from equine kidney cortex." [J] J. Am. Chem. Soc. 1957, 79,4813-4814.
[4] (a) Disalvo, F. J. "Solid-State Chemistry: A Rediscovered Chemical Frontier. Science 1990, 247, 649; (b) Tenne, R.; Argulis, L. M.; Genut, M. "Polyhedral and cylindrical structures of tungsten disulfide." [J] Nature 1992, 360,444 - 446.
[5] Beak, P., Fry Jr, F. S.; Lee, J.; Steele, F. "Equilibration studies. Protomeric equilibria of 2- and 4-hydroxypyridines, 2- and 4-hydroxypyrimidines, 2- and 4-mercaptopyridines, and structurally related compounds in the gas phase." [J] J. Am. Chem. Soc. 1976, 98,171-179.
[6] Castro, V. D.; Lima, G. M.; Porto, A. O.; Siebald, H. G. L.; Filho, J. D. S.; Ardisson, J. D.; Ayala, J. D.; Bombieri, G. "Synthesis, structural characterisation and thermal decomposition of [{Pt(dppf)(2-SPy)}{BF_4}] (dppr=1,1'-bisdiphenylphosfinoferrocene and 2-Spy =v2-mercaptopyridine) - a source for a Fe-Pt containing alloy." [J] Polyhedron 2004,23, 63 - 69.
[7] Reynolds, J. G.; Sendlinger, S. C.; Murray, A. M.; Huffman, J. C.; Christou, G. "Synthesis and Characterization of Vanadium(Ⅱ,Ⅲ,Ⅳ) Complexes of Pyridine-2-thiolate." [J] Inorg. Chem. 1995, 34, 5745 - 5752.
[8] Jung, O.-S.; Park, S. H.; Lee, Y.-A; Cho, Y.; Kim, K. M.; Lee, S.; Chae, H. K.; Sohn, Y. S. "Unique Intramolecular Interaction in Cyclotriphosphazene Molecule. Synthesis, Structure, and Properties of 1,1-Bis(pyridyl-2-thio)-3,3,5,5-tetrachlorocyclotriphosphazene." [J] Inorg. Chem. 1996, 55, 6899 -6901.
[9] Chen, Y.; Lin, F.; Shephered, R. E. "Stereochemically-rigid and fluxional pyrimidines within the bis-[Ru(hedta)(pym)2]- complex." [J] Inorg. Chim. Acta 1998, 268,287 - 295.
[10] Onaka, S.; Yaguchi, M.; Yamauchi, R.; Ozeki,T.; Ito, M.; Sunahara, T.; Sugiura, Y.; Shiotsuka, M.; Nunokawa, K.; Horibe, M.; Okazaki, K.; Iida, A.; Chiba, H.; Inoue, K.; Imai, H.; Sako, K. "The effect of carbon chain length of the diphosphine ligand on the aurophilic interaction. Synthesis and X-ray structural study for a series of Au(Ⅰ) compounds with Ph_P-R-PPh_2 and S-(CH_2)_n-py ligands." [J] J. Organomet. Chem. 2005, 690, 57 - 68.
[11] Han, Y.-F.; Huang, Y.-B.; Lin, Y.-J.; Jin, G.-X. "Synthesis, Characterization, and Norbornene Polymerization Behavior of the Half-Sandwich Complexes [Cp_3~*M_3(μ~3-L)Cl_3] and [Cp~*M(2-SPyH)Cl_2] (M = Ir, M = Rh, [L]~(3-) = 1,3,5-Triazine-2,4,6-trithiolato, 2-SPy = 2-Pyridinethione)." [J] Organometallics 2008,27,961-966.
[12] Raisanen, M. T.; Runeberg, N.; Klinga, M.; Nieger, M.; Bolte, M.; Pyykko, P.; Leskela, M.; Repo, T. "Coordination of Pyridinethiols in Gold(Ⅰ) Complexes." [J] Inorg. Chem. 2007,46, 9954 - 9960.
[13] Yamanari, K.; Fukuda, I.; Kawamoto, T.; Kushi, Y.; Fuyuhiro, A.; Kubota, N.; Fukuo, T.; Arakawa, R. "Self-Assembling Synthesis of Cyclic Tri- and Tetranucle ar Cobalt(Ⅲ) Complexes Bridged by Purine-6-thione and Their Characterization by Electrospray Mass Spectrometry and X-ray Crystal Analysis." [J] Inorg. Chem. 1998,37,5611-5618.
[14] Fish, R. H. "Bioorganometallic chemistry: synthesis, structure, and molecular recognition chemistry of (η~5-pentamethylcyclopentadienyl)rhodium-DNA/RNA complexes in water. Coord. Chem. Rev. 1999,185-186, 569-584.
[15] Severin, K. "Supramolecular chemistry with organometallic half-sandwich complexes." [J] Chem. Commun. 2006, 3859-3867.
[16] Severin, K. "Self-assembled organometallic receptors for small ions." [J] Coord. Chem. Rev. 2003, 245, 3-10.
[17] Sekioka, Y; Kaizaki, S.; Mayer, J. M.; Suzuki, T. "Structure and Reactivity of a Pyridine-1-imido-2-thiolato Complex of Iridium(Ⅲ), Cp~*Ir(1-N-2-Spy), Generated by Photolysis of the (Azido)(pyridine-2-thiolato) Complex, Cp~*Ir(2-Spy)(N_3)." [J] Inorg. Chem. 2005, 44, 8173-8175.
[18] Jung, O.-S.; Lee, Y.-A.; Kim, Y. T.; Chae, H. K. "An organometallic mercaptopyridine complex with unusual bond shift fluxionality: metal-mediated tautomerism of (pentamethylcyclopentadienyl)bis(pyridine-2-thiolato) rhodium(Ⅲ)." [J] Inorg. Chim. Acta 2000, 299,100 -103.
[19] (a) Herberhold, M.; Jin, G.-X.; Yan, H.; Milius, W.; Wrackmeyer, B. "16- and 18-Electron Cp~*Rh complexes with 1,2-dicarba-closo-dodecaborane(12)- 1,2-dichalcogenolato ligands, as studied by multinuclear magnetic resonance." [J] J. Organomet. Chem. 1999, 557, 252 - 257. (b) Bae, J. Y.; Park, Y I.; Ko, J.; Park, K. I.; Cho, S. I.; Kang, S. O. "Synthesis, X-ray crystal structure, and reactivity of the monomeric dithio-o-carboranyl indium complex [Ir(η~5-C_5Me_5)(η~2-S_2C_2B_(10)H_(10))]." [J] Inorg. Chim. Acta 1999, 289, 141 -148. (c)Jin, G.-X. "Advances in the chemistry of organometallic complexes with 1,2-dichalcogenolato-o-carborane ligands." [J] Coord. Chem. Rev. 2004, 248, 587 - 602; (d) Liu, S.; Han, Y. F.; Jin, G.-X. "Formation of direct metal-metal bonds from 16-electron "pseudo-aromatic" half-sandwich complexes Cp"M[E2C2(B10H10)]." [J] Chem. Soc. Rev. 2007,36,1543 -1560.
[20] Kettler, P. B.; Chang, Y.; Rose, D.; Zubieta, J.; Abrams, M. J. "Synthesis and structural characterization of complexes of the {Cp~*Rh} and MeRe cores with pyridine-2-thiol ligand types. Structures of MeReO(η~2-2-SC_5H_3N-3-SiMe)_2 and (η~5-Me_5C_5)Rh(η-2-SC_5H_3N-3-SiMe_3) if(η~1-2-SC_5H_3N-3-SiMe_3)." [J] Inorg. Chim. Acta 1996,244,199 -205.
[21] Perez-Torrente, J. J.; Casado, M. A.; Ciriano, M. A.; Lahoz, F. J.; Oro, L. A. "Synthesis of Rhodium, Indium, and Palladium Tetranuclear Complexes Directed by 2,6-Dimercaptopyridine. X-ray Crystal Structure of [Rh_4(μ-PyS_2)_2(cod)_4] (cod = 1,5-Cyclooctadiene)." [J] Inorg. Chem. 1996, 55, 1782-1791.
[22] Dorn, T.; Janiak, C.; Abu-Shandi, K. "Hydrogen-bonding, π-stacking and Cl-anion-π interactions of linear bipyridinium cations with phosphate, chloride and [CoCl4]2- anions." [J] Cryst. Eng. Comm. 2005, 7,633 - 641.
[23] (a) Matlock, M. M.; Henke, K. R.; Atwood, D. A.; Robertson, J. D. "Aqueous leaching properties and environmental implications of cadmium, lead and zinc Trimercaptotriazine (TMT) compounds." [J] Water Res. 2001, 35, 3649 - 3655;(b) Henke, K. R.; Robertson, D.; Krepps, M. K.; Atwood, D. A. "Chemistry and stability of precipitates from aqueous solutions of 2,4,6-trimercaptotriazine, trisodium salt, nonahydrate (TMT-55) and mercury(Ⅱ) chloride." [J] Water Res. 2000,34,3005-3013.
[24] (a) Kopel, P.; Dole(?)al, K.; Machal L.; Langer, V. "Synthesis, characterization and screening of biological activity of Zn(Ⅱ), Fe(Ⅱ) and Mn(Ⅱ) complexes with trithiocyanuric acid." [J] Polyhedron 2007, 26, 1583 - 1589. (b) Cecconi, F.; Ghilardi, C. A.; Midollini S.; Orlandini, A. "Organomercury derivatives of the 2,4,6-trimercaptotriazine (H_3TMT). X-ray crystal structure of (HgMe)_3(TMT)." [J] J. Organomet. Chem. 2002, 645, 101 - 104. (d) Bailey, J. R.; Hatfield, M. J.;Henke, K. R.; Krepps, M. K.; Morris, J. L.; Otieno, T.; Simonetti, K. D.; Wall, E. A.; Atwood, D. A. "Transition metal complexes of 2,4,6-trimercapto-1,3,5-triazine (TMT): potential precursors to nanoparticulate metal sulfides." [J] J. Organomet. Chem. 2001, 623, 185 - 190. (e) Haiduc, I.; Mahon, M. F.; Molloy K. C.; Venter, M. M. "Synthesis and spectral characterisation of organotin(Ⅳ) 1,3,5-triazine-2,4,6-trithiolato complexes, including the crystal structures of 1,3,5-(R_3Sn)_3C_3N_3S_3 (R=Me, Ph)." [J] J. Organomet. Chem. 2001, 627, 6-12.
[25] Ienco, A.; Midollini, S.; Orlandini, A.; Vacca, A. "Complexes formed from 2,4,6-trimercaptotriazine (H_3TMT): synthesis and structural characterization of [M(PhP(CH_2CH_2P(Ph)_2)_2(HTMT)], M=Ni(Ⅱ), Pd(Ⅱ), Pt(Ⅱ)." [J] Inorg. Chim. Acta 2004, 357, 2615 -2623.
[26] (a) Yamanari, K.; Kushi, Y.; Yamamoto, M.; Fuyuhiro, A.; Kaizaki, S.; Kawamoto, T.; Kushi, Y. "Photochemical-synthesis and crystal-structures of tetrakis(ethane-1,2-diamine)dicobalt(Ⅲ) complexes bridged by 1,3,5-trlazine-2,4,6-trithionate and 4-oxo-1,3,5-triazine-2,6-dithionate." [J] Dalton Trans. 1993, 3715 - 3721. (b) Clegg, W.; Davies, J. E.; Elsegood, M. R. J.; Lamb, E.; Longridge, J. J.; Rawson, J. M.; Snaith, R.; Wheatley, A. E. H. "The first structural studies on trithiocyanuric acid: the solid state structures of its HMPA adduct and its mono-lithiated HMPA complex." [J] Inorg. Chem. Commun. 1998, 1, 58 - 60.
[27] (a) Kar, S.; Miller, T. A.; Chakraborty, S.; Sarkar, B.; Pradhan, B.; Sinha, R. K.; Kundu, T.; Ward, M. D.; Lahiri, G. K. "Synthesis, mixed valence aspects and non-linear optical properties of the triruthenium complexes [{(bpy)_2Ru~(Ⅱ)}_3(L)]~(3+) and [{(phen)_2RuII}_3(L)]~(3+) (bpy = 2,2'-bipyridine, phen = 1,10-phenanthroline and L~(3-) = 1,3,5-triazine-2,4,6-trithiol)." [J] Dalton Trans. 2003, 2591 - 2596. (b) Kar, S.; Pradhan, B.; Sinha, R. K.; Kundu, T.; Kodgire, P.; Rao, K. K.; Puranik, V. G.; Lahiri, G. K. "Synthesis, structure, redox, NLO and DNA interaction aspects of [{(L'-L"')_2Ru~(Ⅱ)}_3(μ_3-L)]~(3+) and [(L')_2Ru~(Ⅱ)(NC_5H_4S-)]~+ [L~(3-) = 1,3,5-triazine- 2,4,6-trithiolato, L'-L'"= arylazopyridine]." [J] Dalton Trans. 2004,1752 -1760.
[1] Moulton, B. M.; Zaworotko, J. "From Molecules to Crystal Engineering: Supramolecular Isomerism and Polymorphism in Network Solids." [J] Chem. Rev. 2001,101,1629 -1658.
[2] Brammer, L. "Developments in inorganic crystal engineering." [J] Chem. Soc. Rev. 2004, 33,476 - 489.
[3] Dong, Y.-B.; Ma, J.-P.; Huang, R.-Q.; Smith, M.D.; zur Loye, H.-C. "Synthesis and Characterization of New Coordination Polymers Generated from Oxadiazole-Containing Organic Ligands and Inorganic Silver(I) Salts." [J] Inorg. Chem. 2003, 42, 294 - 300.
[4] Plater, M. J.; Foreman, M. R. St. J.; Gelbrich, T.; Hursthouse, M. B. "One-dimensional structures of nickel(Ⅱ) and cobalt(Ⅱ) coordination complexes {[ML_2(H_2O)_2]·L·H_2O·(ClO_4)_2} (M=Co or Ni; L=1,3-bis(4-pyridyl)propane)." [J] Inorg. Chim. Acta 2001, 318,171 -174.
[5] Hou, H.; Song, Y.; Fan, Y.; Zhang, L.; Du, C.; Zhu, Y. "A novel coordination polymer [Co(NCS)_2(bpms)_2]_n (bpms=1,2-bis(4-pyridylmethyl)disulfenyl): synthesis, crystal structure and third-order nonlinear optical properties." Inorg. Chim. Ada 2001, 316,140 -144.
[6] Horikoshi, R; Mochida, T. "Metal complexes of 4,4 '-dipyridyldisulfide-structural diversity derived from a twisted ligand with axial chirality." [J] Coord. Chem. Rev. 2006,250, 2595 - 2609.
[7] Carballo, R.; Covelo, B.; Fernandez-Hermida, N. "Solid state coordination chemistry of copper(Ⅱ) lactate complexes with the twisted ligands 4,4-dipyridyldisulfide and bis(4-pyridylthio)methane." [J] J. Mol. Strud. 2008, 892, 427 - 432.
[8] Carballo, R.; Covelo, B.; Fernandez-Hermida, N. "Structural versatility in copper(Ⅱ) alpha-hydroxycarboxylate complexes with the twisted ligands 4,4'-dipyridyldisulfide and bis(4-pyridylthio)methane: From molecular compounds to two-dimensional coordination polymers." [J] Cryst. Growth Des. 2008,5,995-1004.
[9] Wang, J.; Zhang, Y. H.; Li, H. X. "Construction of pyridinethiolate-bridged 2D and 3D coordination networks of d(10)metal halides via solvothermal in situ disulfide cleavage reactions.” [J]Cryst.Growth Des.2007,7,2352-2360.
[10]Aragoni,M.C;Arca,M.;Crespo,M.“Predictable and unpredictable reactions between 4,4 '-dipyridyldisulfide and phosphonodithioato/dithiophosphato Ni-Ⅱ complexes:novel coordination polymers and the unique example of 4,4'-dipyridyltrisulfide.” [J]Cryst.Eng.Comm.2007,9,873-878.
[11]Wang,J.;Zheng,S.L.;Hu,S.;et al.“New in situ cleavage of both S-S and S-C(sp(2))bonds and rearrangement reactions toward the construction of copper(Ⅰ)cluster-based coordination networks.” [J]Inorg.Chem.2007,46,795-800.
[12]Tabellion,F.M.;Seidel,S.R.;Arif,A.M.;Stang,P.J.“Discrete Supramolecular Architecture vs Crystal Engineering:The Rational Design of a Platinum-Based Bimetallic Assembly with a Chairlike Structure and Its Infinite,Copper Analogue.”[J]J.Am.Chem.Soc.2001,123,7740-7741.
[13]Horikoshi,R.;Mochida,T.;Kurihara,M.;Mikuriya,M.“Supramolecular Isomerism in Self-Assembled Complexes from 4,4'-Dipyridyl Disulfide and M(hfac)_2:Coordination Polymers (M = Mn)and Metallamacrocycles (M = Co,Ni)." Cryst.Growth Des.2005,5,243-249.
[14]Yu,X.-Y.;Maekawa,M.;Morita,T.;Chang,H.-C;Kitagawa,S.;Jin,G.-X.“Solvent-dependent formation of di-and trinuclear rhodiurn and iridium complexes bridged by N,N'-donor ligands.” [J]Bull.Chem.Soc.Jpn.2002,75,267-275.
[1] Crossley, I. R.; Hill, A. F.; Humphrey, E. R.; Willis, A. C. "The First Bimetallic Metallaboratrane: [Rh_2{B(mt)_3}_2{κ~2-S,S'-HB(mt)_3}]Cl and Its Synthesis from the Fluxional Rhodaboratrane Salt [Rh{B(mt)_3}(η~4-C_8H_(12))]Cl, (Rh→B, mt =Methimazolyl)" [J] Organometallics 2005, 24,4083-4086.
[2] Dodds, C. A.; Garner, M.; Reglinski, J.; Spicer, M. D. "Early Metal Di- and Tricyanometalates: Useful Building Blocks for Constructing Magnetic Clusters" [J] Inorg. Chem. 2006, 45, 2733-2741.
[3] Kuan, S. L.; Leong, W. K.; Goh, L. Y. "Redox-Dependent Isomerization of Organometallic Ru~(Ⅱ)/Ru~(Ⅲ) Compounds Containing the Hydrotris(methimazolyl)borate Ligand: An Electrochemical Square Scheme Mechanism" [J] Organometallics 2005,24, 4639-4648.
[4] Crossley, I. R.; Hill, A. F.; Willis, A. C. "Metallaboratranes: Tris(methimazolyl)borane Complexes of Rhodium(I)" [J] Organometallics 2006, 25, 289-299.
[5] Morlok, M. M; Janak, K. E.; Zhu, G.; Quarless, D. A.; Parkin, G. "Intramolecular N-H…S Hydrogen Bonding in the Zinc Thiolate Complex [Tm~(Ph)]ZnSCH_2C(O)NHPh: A Mechanistic Investigation of Thiolate Alkylation as Probed by Kinetics Studies and by Kinetic Isotope Effects" [J] J. Am. Chem. Soc. 2005,127,14039-14050.
[6] Dodds, C. A.; Lehmann, M. A.; Ojo, J. F.; Reglinski, J.; Spicer, M. D. "Cobalt Half-Sandwich, Sandwich, and Mixed Sandwich Complexes with Soft Tripodal Ligands" [J] Inorg. Chem. 2004, 43,4927-4934.
[7] Hill, A. F.; Rae, A. D.; Smith, M. K. "Niobium and Tantalum Tris(methimazolyl)borate Complexes [M(=NC_6H_3~iPr_2-2,6)Cl_2 {HB(mt)_3}] (M = Nb, Ta; mt = Methimazolyl" [J] Inorg. Chem. 2005, 44, 7316-7318.
[8] Landry, V. K.; Melnick, J. G.; Buccella, D.; Pang, K. L.; Ulichny, J. C.; Parkin, G. "Synthesis and Structural Characterization of [κ~3-B,S,S-B(mim~R)_3]Ir(CO)(PPh_3)H (R = Bu~t, Ph) and [κ~4-B(mim~(But))_3]M(PPh_3)Cl (M = Rh, Ir): Analysis of the Bonding in Metal Borane Compounds" [J] Inorg. Chem. 2006, 45, 2588-2597.
[9] Pang, K. L.; Quan, S. M.; Parkin, G. "Palladium complexes with Pd→B dative bonds: Analysis of the bonding in the palladaboratrane compound [κ~4-B(mim~(But))_3]Pd(PMe_3)" [J] Chem. Commun. 2006, 5015-5017;
[10] Crossley, I. R; Hill, A. F.; Willis, A. C. "Poly(methimazolyl)borate Complexes of Platinum" [J] Organometallics 2005, 24,4889-4892.
[11] Kuan, S. L.; Leong, W. K.; Goh, L. Y.; Webster, R. D. "HMB and Cp~* ruthenium(Ⅱ) complexes containing bis- and tris-(mercaptomethimazolyl)borate ligands: Synthetic, X-ray structural and electrochemical studies (HMB = η~6-C_6Me_6, Cp~* =η~5-C_5Me_5)" [J] J. Organomet. Chem. 2006, 691,907-915.
[12] Crossley, I. R; Hill, A. F.; Willis, A. C. "Formation of Metallaboratranes: The Missing Link. The First Iridaboratranes, [IrH(CO)(PPh_3){κ~3-B,S,S'-B(mt)_2R}](Ir→B) (mt = Methimazolyl, R = mt, H)" [J] Organometallics 2005, 24,1062-1064.
[13]Bao,M.;Hayashi,T.;Shimada,S.“Synthesis and structural characterisation of a cationic trinuclear organobismuth complex with an unprecedented coordination mode of hydrotris(2-mercaptoimidazolyl)borate ligands” [J]Dalton Trans.2004,2055-2056.
[14]Alvarez,H.M.;Gillespie,P.A.;Gause,C.D.;Rheingold,A.L.;Golen,J.A.;Rabinovich,D.“Thallium(Ⅰ)bis(mercaptoimidazolyl)borate” [J]Polyhedron 2004,23,617-622.
[15]Minoura,M.;Landry,V.K.;Melnick,J.G;Pang,K.L.;Marchio,L.;Parkin,G.“Synthesis and structural characterization of tris(2-seleno-1-mesitylimidazolyl)hydroborato complexes:a new type of strongly electron donating tripodal selenium ligand” [J]Chem.Commun.2006,38,3990-3992.
[16]Landry,V.K.;Buccella,D.;Pang,K.L.;Parkin,G.“Tetrahedral nickel nitrosyl complexes with tripodal [N_3]and [Se_3]donor ancillary ligands:structural and computational evidence that a linear nitrosyl is a trivalent ligand” [J]Dalton.Trans.2007,820-824.
[17]Landry,V.K.;Buccella,D.;Pang,K.L.;Parkin,G.“Bis-and tris(2-seleno-1-methylimidazolyl)hydroborato complexes,{[BseMe]ZnX}_2 (X =Cl,I),[BseMe]_2Zn and [TseMe]Re(CO)_3:Structural evidence that the [BseMe]ligand is not merely a heavier version of the sulfur counterpart [BmMe]” [J]Dalton.Trans.2007,866-870;
[18]Jia,W.-G.;Huang,Y.-B.;Lin,Y.-J.Jin,G.-X.Syntheses and structures of half-sandwich iridium(Ⅲ)and rhodium(Ⅲ)complexes with organochalcogen (S,Se)ligands bearing N-methylimidazole and their use as catalysts for norbornene polymerization,Dalton Trans.2008,41,5612-5620.
[19]Jia,W.-G.;Huang,Y.-B.;Lin,Y-J.;Wang,G.-L.;Jin,G.-X.Novel nickel complexes and cobalt coordination polymers with organochalcogen (S,Se)ligands bearing N-methylimidazole:synthesis,structures and properties study,Eur.J.Inorg.Chem.2008,26,4063-4073.
[20]Williams,D.J.;Vanderveer,D.;Jones,R.L.;Menaldino,D.S.“Main group metal halide complexes with sterically hindered thioureas Ⅺ.Complexes of antimony(Ⅲ)and bismuth(Ⅲ)chlorides with a new bidentate thiourea-1,1'-methylenebis(3-methyl-2H-imidazole-2-thione)” [J]Inorg.Chim.Acta 1989,165,173-178.
[1] (a) Jin, G.-X. "Advances in the Chemistry of Organometallic Complexes with 1,2-Dichalcogenolato- o-Carborane Ligands." [J] Coord. Chem. Rev. 2004, 248, 587 - 602; (b) Liu, S.; Han, Y.-F.; Jin, G.-X. "Metal-Metal Bonding Formation from 16-Electron "Pseudo-Aromatic" Half-sandwich Complexes Cp"M[E_2C_2(B_(10)H_(10))]." Chem. Soc. Rev. 2007, 36, 1543 - 1560; (c) Plesek, J. "Potential applications of the boron cluster compounds." [J] Chem. Rev. 1992, 92, 269 - 278; (d) Bregadze, V. I. "Dicarba-closo-dodecaboranes C_2B_(10)H_(12) and their derivatives." [J] Chem. Rev. 1992, 92, 209 - 223; (e) Hawthorne, M. F.; Maderna, A. "Applications of Radiolabeled Boron Clusters to the Diagnosis and Treatment of Cancer." [J] Chem. Rev. 1999, 99, 3421 - 3434; (f) Xie, Z. "Cyclopentadienyl-Carboranyl Hybrid Compounds: A New Class of Versatile Ligands for Organometallic Chemistry." [J] Acc. Chem. Res. 2003, 36,1 - 9.
[2] (a) Wang, J. -Q.; Ren,C. -X.; Weng, L. -H.; Jin, G. -X. "Porphyrin-carborane organometallic assemblies based on 1, 2-dicarba-closo-dodecaborane (12) ligands." [J] Chem. Commun. 2006, 162 - 165. (b) Wang, J. -Q.; Ren,C. -X.; Jin, G. -X. "Route to Multicluster Containing Ancillary ortho-Carborane-1,2-Dithiolato Ligands." [J] Chem. Commun. 2005, 4738 - 4740; (c) Liu, S.; Wang, G.-L.; Jin, G.-X. "Multinuclear Self-assembly via Half-sandwich Complexes Cp~*M[S_2C_2(B_(10)H_(10))] and Pyridine based ligands." [J] Dalton Trans. 2008, 425 -432.
[3] (a) Vicente, M. G. H.; Nurco, D. J.; Shetty, S. J.; Medforth, C. J.; Smith, K. M. "First structural characterization of a covalently bonded porphyrin-carborane system." [J] Chem. Commun. 2001, 483 - 484; (b) Lauceri, R.; Purrello, R.; Shetty, S. J.; Vicente, M. G. H. "Interactions of Anionic Carboranylated Porphyrins with DNA." [J] J. Am. Chem. Soc. 2001,123, 5835 - 5836; (c) Isaac, M. F.; Kahl, S. B. "Synthesis of ether- and carbon-linked polycarboranyl porphyrin dimers for cancer therapies." [J] J. Organomet. Chem. 2003, 680, 232 - 243; (d) Hao, E.; Vicente, M. G. H. "Expeditious synthesis of porphyrin-cobaltacarborane conjugates." [J] Chem. Commun. 2005,1306 - 1308.
[4] (a) Guo, D.; Duan, C. Y.; Lu, F.; Hasegawa, Y.; Meng, Q.-J.; Yanagida, S. "Lanthanide heterometallic molecular squares Ru_2-Ln_2 exhibiting sensitized near-infrared emission." [J] Chem. Commun. 2004, 1486 -1487; (b) Bignozzi, C. A.; Argazzi, R.; Kleverlaan, C. J. "Molecular and supramolecular sensitization of nanocrystalline wide band-gap semiconductors with mononuclear and polynuclear metal complexes." [J] Chem. Soc. Rev. 2000, 87 - 96; (c) Sun, L.; Hammarstr(?)m, L.; Akermark, B; Styring, S. "Towards artificial photosynthesis: ruthenium-manganese chemistry for energy production." [J] Chem. Soc. Rev. 2001, 36 - 49.
[5] Haider, G. J.; Kepert, C. J. In Situ Single-Crystal X-ray Diffraction Studies of Desorption and Sorption in a Flexible Nanoporous Molecular Framework Material. J. Am. Chem. Soc. 2005,127, 7891 -7 900.
[6] (a) Zhang, Q.-F.; Adams, R. D.; Leung, W.-H. "Syntheses, spectroscopic properties and crystal structures of two organoruthenium (Ⅱ) complexes of bipyridines: [{Cp~*Ru(2,2'-bipy)}_2(μ-Cl)][PF_6] and [{(η~6-p-cymene)Ru}_2(μ-OH)_2 (4,4'-bipy)]_2[BF_4]_4." [J] Inorg. Chim. Acta 2006, 359, 978 - 983; (b) Furukawa, S.; Ohba, M.; Kitagawa, S. "Rational synthesis of a two-dimensional honeycomb structure based on a paramagnetic paddlewheel diruthenium complex." [J] Chem. Commun. 2005, 865 - 867; (c) Kinnunen, T. J.; Haukka, M.; Pesonen, E.; Pakkanen, T. A. "Ruthenium complexes with 2,2'-, 2,4'- and 4,4'-bipyridine ligands: The role of bipyridine coordination modes and halide ligands." [J] J. Organomet. Chem. 2002, 655, 31 - 38; (d) Yan, H.; Suss-Fink, G.; Neels, A.; Stoeckli-Evans, H. "Mono-, di- and tetra-nuclear p-cymeneruthenium complexes containing oxalato ligands." [J] Dalton Trans. 1997,4345 - 4350.
[7] (a) Griffiths, J.-P.; Brown, R. J.; Day, P.; Matthews, C. J.; Vital, B.; Wallis, J. D. "Synthesis of bis(ethylenedithio)tetrathiafulvalene derivatives with metal ion ligating centres." Tetrahedron Lett. 2003, 44, 3127 - 3131; (b) Moore, A. J.; Batsanov, A.S.; Bryce, M. R.; Howard, J. A. K.; Khodorkovsky, V.; Shapiro, L.; Shames, A. "Activation of C-H Bonds in Five-Membered Heterocycles by a Half-Sandwich Yttrium Alkyl Complex." [J] Eur. J. Org. Chem. 2001, 73 - 75; (c) Liu, S.-X.; Dolder, S.; Pilkington, M.; Decurtins, S. Facile Synthesis of Novel Functionalized Bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) Derivatives. J. Org. Chem. 2002, 67, 3160 - 3162; (d) Campagna, S.; Serroni, S.; Puntoriero, F.; Loiseau, F.; De Cola, L.; Kleverlaan, C. J.; Becher, J.; Sorensen, A. P.; Hascoat, P.; Thorup, N. "Coupling of Metal-Based Light-Harvesting Antennas and Electron-Donor Subunits: Trinuclear Ruthenium(Ⅱ) Complexes Containing Tetrathiafulvalene-Substituted Polypyridine Ligands." [J] Chem. Eur. J. 2002, 5, 4461-4469; (e) Devic, T.; Avarvari, N.; Batail, P. "A Series of Redox Active, Tetrathiafulvalene-Based Amidopyridines and Bipyridines Ligands: Syntheses, Crystal Structures, a Radical Cation Salt and Group 10 Transition-Metal Complexes." [J] Chem. Eur. J. 2004,10, 3697 - 3707.
[8] Levi, O. P.; Becker, J. Y.; Ellern, A.; Khodorkovsky, V. "Synthesis of 2,3-dimethylthio-6-pyridyl tetrathiafulvalene: a precursor for a new system involving a direct linkage between a strong donor (D) and a strong acceptor (A)." [J] Tetrahedron Lett. 2001, 42,1571 -1573.
[9] Kim, S. H.; Huh, H. S.; Lee, S. W. Cobalt(Ⅱ) coordination polymers based on dicarboxylates and dipyridyl-type ligands: [CoL_(1.5)(NO_3)_2], [Co_(1.5)(bpdc)_(1.5)(dma)]· (dma)·(EtOH), [Co_(1.5)(ndc)_(1.5)(dma)_2], [Co_3(ndc)_3(dmf)_4], and [CoL(bpdc)]·(EtOH) (bpdcH_2 = biphenyl-4,4'-dicarboxylic acid, ndcH_2 = 2,6-naphthalene dicarboxylic acid, L = py-CH=N-C_(10)H_6-N=CH-py), J. Mol. Struct. 2007, 841, 78 - 87.
[1] 化学学科进展,张礼和,北京:化学工业出版社,2005.6.
[2] Ritleng, V.; Sirlin, C.; Pfeffer, M. Ru-, Rh-, and Pd-Catalyzed C－C Bond Formation Involving C－H Activation and Addition on Unsaturated Substrates: Reactions and Mechanistic Aspects." [J] Chem. Rev. 2002,102,1731-1770.
[3] Godula, K.; Sames, D. Science 2006, 312, 67.
[4] Alberico, D.; Scott, M. E.; Lautens, M. Aryl-Aryl Bond Formation by Transition-Metal-Catalyzed Direct Arylation." [J] Chem. Rev. 2007,107, 174.
[5] Dick, A. R.; Hull, K. L.; Sanford, M. S. A Highly Selective Catalytic Method for the Oxidative Functionalization of C-H Bonds." [J] J. Am. Chem. Soc. 2004,126, 2300-2301.
[6] Desai, L. V.; Stowers, K. J.; Sanford, M. S. Insights into Directing Group Ability in Palladium-Catalyzed C-H Bond Functionalization." [J] J. Am. Chem. Soc. 2008, 130, 13285-13293.
[7] Kalyani, D.; Dick, A. R.; Anani, W. Q.; Sanford, M. S. A Simple Catalytic Method for the Regioselective Halogenation of Arenes." [J] Org. Lett. 2006, 8, 2523-2526.
[8] Wan, X. B.; Ma, Z. X.; Li, B. J.; Zhang, K. Y.; Cao, S. K.; Zhang, S. W.; Shi, Z. J. Highly Selective C-H Functionalization/Halogenation of Acetanilide." [J] J. Am. Chem. Soc. 2006,128,7416-7417.
[9] Chen, X.; Hao, X.-S.; Goodhue, C. E.; Yu, J.-Q. Cu(Ⅱ)-Catalyzed Functionalizations of Aryl C-H Bonds Using O_2 as an Oxidant." [J] J. Am. Chem. Soc. 2006,128,6190-6191.
[10] Mei, T.-S.; Giri, R.; Maugel, N.; Yu, J.-Q. Pd~(Ⅱ)-Catalyzed Monoselective ortho Halogenation of C-H Bonds Assisted by Counter Cations: A Complementary Method to Directed ortho-Lithiation." [J] Angew. Chem., Int. Ed. 2008, 47,5215-5219.
[11] Dipannita, K.; Deprez, N. R.; Deprez, L. V.; Sanford, M. S. Oxidative C－H Activation / C-C Bond Forming Reactions: Synthetic Scope and Mechanistic Insights." [J] J. Am. Chem. Soc. 2005,127, 7330-7331.
[12] Chiong, H. A.; Pham, Q.-N.; Daugulis, 0. Two Methods for Direct ortho-Arylation of Benzoic Acids." [J] J. Am. Chem. Soc. 2007,129, 9879-9884.
[13] Deng, G. J.; Zhao, L.; Li, C.-J. Ruthenium-Catalyzed Oxidative Cross-Coupling of Chelating Arenes and Cycloalkanes." [J] Angew. Chem., Int. Ed. 2008, 47, 6278-6282.
[14] Zhao, X. D.; Yu, Z. K. Rhodium-Catalyzed Regioselective C-H Functionalization via Decarbonylation of Acid Chlorides and C-H Bond Activation under Phosphine-Free Conditions." [J] J. Am. Chem. Soc. 2008, 130,8136-8137.
[15] Tsai, A. S.; Bergman, R. G.; Ellman, J. A. Asymmetric Synthesis of (-)-Incarvillateine Employing an Intramolecular Alkylation via Rh-Catalyzed Olefinic C－H Bond Activation." [J] J. Am. Chem. Soc. 2008,130, 6316-6317.
[16] Giri, R.; Yu, J.-Q. Synthesis of 1,2- and 1,3-Dicarboxylic Acids via Pd(Ⅱ)-Catalyzed Carboxylation of Aryl and Vinyl C－H Bonds." [J] J. Am. Chem. Soc. 2008,130, 14082-14083.
[17] Campeau, L.-C.; Schipper, D. J.; Fagnou, K. C. Site-Selective sp~2 and Benzylic sp~3 Palladium-Catalyzed Direct Arylation." [J] J. Am. Chem. Soc. 2008, 130, 3266-3267.
[18] Thu, H.-Y.; Yu, W.-Y.; Che, C.-M. Intermolecular Amidation of Unactivated sp~2 and sp~3 C-H Bonds via Palladium-Catalyzed Cascade C-H Activation/Nitrene Insertion." [J] J. Am. Chem. Soc. 2006,128, 9048-9049.
[19] Bandgar, B. P.; Bettigeri, S. V.; Phopase, J. Unsymmetrical Diaryl Sulfones through Palladium-Catalyzed Coupling of Aryl Boronic Acids and Arylsulfonyl Chlorides." [J] Org. Lett. 2004, 6, 2105-2108.
[20] Zhu, W.; Ma, D. W. Synthesis of Aryl Sulfones via (?)-Proline-Promoted CuI-Catalyzed Coupling Reaction of Aryl Halides with Sulfinic Acid Salts." [J] J. Org. Chem. 2005, 70, 2696.
[21] Kar, A.; Sayyed,I. A.; Lo, W. F.; Kaiser, H. M.; Beller, M.; Tse, M. K. A General Copper-Catalyzed Sulfonylation of Arylboronic Acids." [J] Org. Lett. 2007, 9, 3405-3408.
[22] Huggins, J. M.; Bergman, R. G. Mechanism, regiochemistry, and stereochemistry of the insertion reaction of alkynes with methyl(2,4-pentanedionato)(triphenyl- phosphine)nickel. A cis insertion that leads to trans kinetic products." [J] J. Am. Chem. Soc. 1981,103, 3002-3011.
[23] Reddy, K. R.; Surekha, K.; Lee, G.-H.; Peng, S.-M.; Liu, S.-T. Single and Multiple Insertion of Alkynes into Pd-Acyl and Pd-Aryl Bonds in Cationic Palladium Complexes with Phosphine-Imine (P - N) Ligands." [J] Organometallics 2001,20, 5557-5563.
[24] Ferstl, W.; Sakodinskaya, I. K.; Beydoun-Sutter, N.; Borgne, G. L.; Pfeffer, M.; Ryabov, A. D. Mechanism of Alkyne Insertion into the Ru-C Bonds of Orthoruthenated Compounds Featuring Similarity of the Ru(Ⅱ) and Pd(Ⅱ) Reactions." [J] Organometallics 1997,16,411-418.
[25] Maassarani, F.; Pfeffer, M.; Borgne, G. L. Reaction of cyclopalladated compounds Part 16. Stepwise insertion of one, two, and three alkyne molecules into the palladium-carbon bond of a six-membered palladocycle. One-pot synthesis of spirocyclic compounds." [J] Organometallics 1987, 6, 2043-2053.
[26] Li, L.; Brennessel, W. W.; Jones, W. D. An Efficient Low-Temperature Route to Polycyclic Isoquinoline Salt Synthesis via C-H Activation with [Cp~*MCl_2]_2 (M = Rh, Ir)." [J] J. Am. Chem. Soc. 2008,130,12414-12419.