生态环境中痕量金属元素分析及硒的生态行为研究
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摘要
生命离不开环境元素，对环境元素的分析检测技术和生态行为研究具有极重要的意义。首次分别为氢化物发生原子吸收常规信号和导数信号建立了数学模型和动力学方程，提出了氢化物发生-导数原子吸收分析新技术，其检出限和灵敏度均显著优于氢化物发生-原子吸收光谱法，并具有良好的精密度，成功应用于环境和生物样品中七种痕量元素的测定。建立了流动注射-蒸气发生-导数原子吸收光谱法测定粮食样品中痕量镉的新方法。建立了流动注射在线还原-氢化物发生-导数原子吸收光谱法及曲线转换法测定环境水体硒的形态分析新方法，并用于水样和土壤浸出液中硒的形态分析。
将建立的痕量分析技术和生态学相结合，研究土壤—作物—动物这个生物链中硒的生态行为。探讨了硒对植物生长的影响，发现不同价态的硒在低浓度对植物生长均有促进作用(如萝卜种子，Se~(4+)浓度＜0.5μg ml~(-1)，洋葱种子S~(4+)浓度＜5μgml~(-1)，但超过一定范围后又会产生毒害。不同的植物对硒的耐受力也不一样，在所讨论的植物中，蒜对环境硒的耐受能力和富集能力最强。硒还能缓解镉对植物的毒害作用。对土壤硒的研究中发现，不同的提取剂所提取的硒形态不同，其对植物生长的作用存在差异，以NaHCO_3提取态与植物含硒量相关性最好。在动物实验中发现，每日补充无机硒后可以提高血清中硒的含量，尤其能够改善肝损伤所引起的血清低硒水平的状况，为肝病的预防和临床用药提供指导。
Lite is associated with environmental elements. The study of the trace analysis and the Eco-Bchavior of these elements play an important role. The mathematical model and kinetic formula of conventional and derivative signal for hydride generation-atomic absorption spectrometry were established for the first time. The method of hydride generation-derivative atomic absorption spectrometry was advanced, which provided improved sensitivity and detection limit and also good reproducibility. The proposed method was applied successfully to the analysis of seven trace elements in the environmental and biological system. The How injection-vapor generation-derivative atomic absorption spectrometry was proposed for the determination of cadmium in foodstuff. The flow injection-online reduction-hydride generation-derivative atomic absorption spectrometry and transformational curve speetrophotometry were proposed to realize the selenium speciation analysis in water and soil extraction samples.
The Eco-Behavior of selenium in the biological chain of soil-plant-animal was studied by combining the trace analysis technique with ecology. Selenium in a narrow content range accelerates the growth of the plant (Se4+content<0.5ug ml-1 for radish, and Se4+content<0.5ug ml-1 for onion ). but plants exhibit symptoms of injury when exposed to high concentrations of Se in their root medium. The damage threshold doses of different kind of plants differ greatly. Garlic could tolerate and accumulate
much higher concentration of selenium than other plants involved in this study. And selenium can reduce the toxicity of cadmium to plants. Different regent was tested to extract different species of selenium from soil, the results show that the NaHCO3-Se is correlative well with the concentration of selenium intake by the plants, so the NaHCO3-Se may be regarded as an index for appraising available selenium in soil. In animal studies, it is concluded that the selenium supplementation could improve the low serum selenium level of rats with liver disease, which may contribute to the prophylactic and clinic medicine research.
将建立的痕量分析技术和生态学相结合，研究土壤—作物—动物这个生物链中硒的生态行为。探讨了硒对植物生长的影响，发现不同价态的硒在低浓度对植物生长均有促进作用(如萝卜种子，Se~(4+)浓度＜0.5μg ml~(-1)，洋葱种子S~(4+)浓度＜5μgml~(-1)，但超过一定范围后又会产生毒害。不同的植物对硒的耐受力也不一样，在所讨论的植物中，蒜对环境硒的耐受能力和富集能力最强。硒还能缓解镉对植物的毒害作用。对土壤硒的研究中发现，不同的提取剂所提取的硒形态不同，其对植物生长的作用存在差异，以NaHCO_3提取态与植物含硒量相关性最好。在动物实验中发现，每日补充无机硒后可以提高血清中硒的含量，尤其能够改善肝损伤所引起的血清低硒水平的状况，为肝病的预防和临床用药提供指导。
Lite is associated with environmental elements. The study of the trace analysis and the Eco-Bchavior of these elements play an important role. The mathematical model and kinetic formula of conventional and derivative signal for hydride generation-atomic absorption spectrometry were established for the first time. The method of hydride generation-derivative atomic absorption spectrometry was advanced, which provided improved sensitivity and detection limit and also good reproducibility. The proposed method was applied successfully to the analysis of seven trace elements in the environmental and biological system. The How injection-vapor generation-derivative atomic absorption spectrometry was proposed for the determination of cadmium in foodstuff. The flow injection-online reduction-hydride generation-derivative atomic absorption spectrometry and transformational curve speetrophotometry were proposed to realize the selenium speciation analysis in water and soil extraction samples.
The Eco-Behavior of selenium in the biological chain of soil-plant-animal was studied by combining the trace analysis technique with ecology. Selenium in a narrow content range accelerates the growth of the plant (Se4+content<0.5ug ml-1 for radish, and Se4+content<0.5ug ml-1 for onion ). but plants exhibit symptoms of injury when exposed to high concentrations of Se in their root medium. The damage threshold doses of different kind of plants differ greatly. Garlic could tolerate and accumulate
much higher concentration of selenium than other plants involved in this study. And selenium can reduce the toxicity of cadmium to plants. Different regent was tested to extract different species of selenium from soil, the results show that the NaHCO3-Se is correlative well with the concentration of selenium intake by the plants, so the NaHCO3-Se may be regarded as an index for appraising available selenium in soil. In animal studies, it is concluded that the selenium supplementation could improve the low serum selenium level of rats with liver disease, which may contribute to the prophylactic and clinic medicine research.
引文
[1] J. March, New Edinburgh Phil. J., 1836, 229
[2] G. R.Kingsley, Am. J. Med. Technol., 1951, 16, 247-253
[3] V.Vasak, V.Sedivee, Collection Czechoslov Chem. Communs., 1952, 18, 64-72
[4] W. Holak., Gas-sampling technique for arsenic determination by atomic absorption spectrophotometry, Anal. Chem., 969, 41, 12, 1712-1713
[5] B. L. Huang, Recent studies on inductively coupled plasma sample introduction-1: Hydride generation, Pages 381-389 Spectromica Acta, Part B, 1988, 43,381-389
[6] P. Verrept, C. Vandecasteele, G. Windels and R. Dams, Use of a refractor plate for automatic background correction in electrothermal vaporization inductively coupled plasma atomic emission spectrometry, Spectromica Acta, Part B, 1991, 46, 99-102
[7] X. W. Guo, X. M. Guo, Shanghai Enviromental Sciences, 1995, 375, 14, 28～31
[8] E. F. Dolton, A. Malanoski, At. Absorpt. Newsl., 1971,10, 92
[9] K. C. Thompson, D. R. Thomerson, Analyst, 1974,99,595
[10] H. C. Freeman, J. F. Uthe, At. Absorpt. Newsl.,1976,13: 75
[11] R. S. Braman, L. L. Justen, C. C. Foreback, Direct volatilization-spectral emission type detection system for nanogram amounts of arsenic and antimony. Anal.Chem., 1972, 44, 13, 2195-2199
[12] A. J. Bard, R. Parsons, J. Jordan(Eds.), Standard Potentials, 1966,Butterworth-Heinemann, Oxford
[13] W. B. Robbins, J. A. Caruso, Development of hydride generation method for atomic spectroscopic analysis, Anal. Chem., 1979, 51, 889A-899A
[14] R. G. Godden, D. R. Thomerson, Generation of covalent hydrides in atomic absorption spectrometry, Analyst, 1980, 105, 1137-1156
[15] T. Nakahara, Prog. Analyt. Atom. Spectrosc., 1983, 6, 163-223
[16] J. Dedina, D. L. Tsalev, Hydride Generation Absorption Spectrometry, Wiley,
Chichester, 1995, 19
[17] F. Laborda, E. Bolea, M. T. Baranguan, J. R. Castillo, Hydride generation in analytical chemistry and nascent hydrogen:when is it going to be over? 797-802
[18] O. Astrom, Flow injection analysis for the determination of bismuth by atornic absorption spectrometry with hydride generation, Anal. Chem., 1982, 54, 2,190-193
[19] 王秀、方肇伦，分析化学，氢化物发生—原子吸收流动注射分析法测定环境样品中痕量硒，分析化学，14，10，1987，．738～743
[20] B. Welz, M. Melcher, Decomposition of marine biological tissues for determination of arsenic, selenium, and mercury using hydride-generation and cold-vapor atomic absorption spectrometries, Anal Chem 1985 Feb 57: 427-31
[21] P.P. Chou, P.K. Jaynes, J.L. Bailey Determination of bismuth in urine by atomic absorption with hydride generation, J Anal Toxicol 1984, 8, 158-60
[22] J.R.Castillo, J.Lanaja,J.Aznarez, determination of selenium in biological samples by hydride generation and atomic absorption spectroscopy, Analyst, 1982, 107,89-94
[23] A. John, R.Michelle, Preservation of arsenic(Ⅲ) and Arsenic(Ⅴ) in samples of sediment interstitial water, Analyst, 1987, 112, 153-156
[24] C. P. Tsai, A. Sahil, J. M. McGuire, B. L. Karger, Paul Vouros;High-performance liquid chromatographic mass spectrometric determination of volatile carboxylic acids using ion-pair extraction and thermally introduced alkyl alkylation, Anal.Chem., 1986, 58, 1, 2-6
[25] 张燕红，夏正斌，头发中硒的流动注射．氢化物发生原子吸收光谱法测定，分析测试学报，2002，01，25-28
[26] 区红，何华煜，氢化物发生原子吸收分光光度法测定食盐中铅，分析试验室 2002，04，96-98
[27] 陈天裕，汪正，流动注射氢化物发生-原子吸收光谱法测定镍基合金中的硒和锡，分析试验室，2001，02，14-16，
[28] 张友爱，氢化物发生．原子吸收光谱法测定食品中无机砷，中国公共卫生
2002, 08, 982-983
[29] Y. PeTIT de Pena O. Vielma J.L. Burguera M. Burguera C. Rondon R Carrero,On-line determination of antimony(Ⅲ) and antimony(Ⅴ) in liver tissue andwhole blood by flow injection-hydride generation-atomic absorption spectrometry,Talanta, 2001, 55, 4,743-754
[30] M. Gallignani, Sequential determination of Se(Ⅳ) and Se(Ⅵ) by flow injection-hydridegeneration-atomic absorption spectrometry with HCl/HBr microwave aided per-reduction of Se(Ⅵ) to Se(Ⅳ), Talanta, 2000, 52, 6,1015-1024
[31] O. Munoz, R.Montoro, A.Arroyo, M. Zamorano, D Velez,. Determination of inorganic arsenic As(Ⅲ) plus As(Ⅴ) in water samples bymicrowave assisted distillation and hydride generation atomic absorption spectrometry, Journal of Analytical atomic spectrometry, 2000, 15, 6, 711-714
[32] A.Korez, M.Volkan OY., AE.Eroglu, Speciation and preconcentration of inorganic tellurium from waters using amercaptosilica microcolumn and determination by hydride generation atomic absorption spectrometry, Journal of Analytical atomic spectrometry, 2000, 15,12, 1599-1605
[33] C.Kabengera, P.Bodart, P. Hubert, L. Thunus, Optimization and validation of arsenic determination in foods by hydridegeneration flame atomic absorption spectrometry, Journal of AOAC International, 2002, 85, 1, 122-127
[34] A. Schwingel, R.Marco, A. Zezzi, Determination of bismuth in metallurgical materials using a quartz tubeatomizer with tungsten coil and flow injection-hydride-generation atomic absorption spectrometry, Spectrochimica Acta.Part B, atomic Spectroscopy, 2002, 57B, 2113-2120
[35] M. Krachler, H.Emons, M.Burow, Development and evaluation of an analytical procedure for the determinationof antimony in plant materials by hydride generation atomic absorption spectrometry, The Analyst, 1999, 124, 5,777-782,
[36] W.R. Mindak, S.R Dolan, Determination of arsenic and selenium in food using a microwave digestion -dry ash preparation and flow injection hydride generation
atomic absorption spectrometry, Journal of food composition and analysis, 1999,12, 2, 111-122
[37] S.Y. Chen, Z. F. Zheng, H. M. Yu, Determination of trace bismuth by flow injection-hydride generationcollection-atomic absorption spectrometry,Analytical and Bioanalytical Chemistry, 2002, 374, 1, 126-130
[38] 姚敏德，陈小芒，李绍南，氢化物发生—电加热石英管原子吸收法测定环 境水样中痕量铅的研究，中国环境监测，2002，03，13-15
[39] H.M. Liu, S.Y. Chen, RH. Chang, Determination of bismuth, selenium and tellurium in nickel-based alloys andpure copper by flow-injection hydride generation atomic absorption spectrometry-with ascorbic acidprereduction and cupferron chelation-extraction, Analytica chimica acta, 2002, 459, 1,161-168
[40] Przemyslaw Niedzielski Jerzy Siepak, Determination of Antimony in Natural Waters by Atomic AbsorptionSpectrometry with Flow-Injection hydride generation, Chemia analityczna, 2001, 46, 1, 51-57
[41] 陈继强，刘树森，谢连宏，李凤萍，空气中铅的氢化物发生．原子吸收光谱测定法，中华劳动卫生职业病杂志 2001，02，154-155
[42] 孙锡丽，应海松，余青，流动注射．氢化物发生原子吸收法测定铁矿中砷、锑、铋含量，光谱实验室，2000，17，1，121-123
[43] 刘德宗，靳志华，张天慧，氢化物发生—原子吸收分光光度法测定食品中微量锡，齐齐哈尔轻工学院学报，1997，13，4，86-88
[44] 王升章，龚楚舒，长缝石英管氢化物．火焰原子吸收光谱法测定化探样品及铅锭中微量锡，理化检验．化学分册1994，6，329-330
[45] 马玉平，韩益清，阿依古丽，氢化物-原子吸收石墨炉原子吸收光谱法应用研究，分析化学，1994，22，6，586-589
[46] C.Ctrsser, J.Anal. Atom. Spectrometry, 5,11R, 1990
[47] 童开源，郭小伟，连续流动氢化物发生—原子吸收光谱法测定镍合金中硒及碲，冶金分析 1996，6，4-6
[48] H.L.Kahn, At.Absorpt. Newsl.,1971,10, 58
[49] D.L.Tsalev, P. B. Mandjukov, J.A.Stratis,At. Spectrom., 1987, 2, 135
[50] C.Reamer, C.Veillon, ET.Tokousbalides, Radiotracer techniques for evaluation of selenium hydride generation systems, Anal. Chem., 1981, 53, 2, 245-248
[51] K.Krivan, Petrick, Fresenius'Z.Anal.Chem., 1990, 336, 6, 480
[52] G.Drasch,L.V.Kauert, Auwendung der gtaphitrohrkuvette Zur Arsenbestimmung in biologischen prober mitder hydride-AAS-Technik, Fresenius'Z. Anal. Chem., 1980,304, 2/3,141-145
[53] S.N.Willie, R.E.Sturgeon, S.S.Berman, Hydride generation atomic absorption determination of selenium in marine sediments, tissues and seawater with in-situ concentration in a graphite furnace, Anal. Chem., 1986, 58, 6, 1140-1143
[54] R.E.Sturgeon,S.N.Willie,S.S.Berman, Fresenius'Z Anal.Chem.,1986,323, 7,788
[55] R. E. Sturgeon, S. N. Willie, S. S. Berman, Hydride generation-atomic absorption determination of antimony in seawater with in situ concentration in a graphite furnace, Anal. Chem., 1985, 57, 12, 2311-2314
[56] 严德忠，万体智，氢化物-墨炉原位富集原子吸收光谱法测定痕量锑，光谱实验室，1997，14，4，34
[57] 罗小玲，熊伟，李冀新，流动注射氢化物石墨炉法测定鱼、香梨中的痕量汞，光谱实验室 1994，11，03，19
[58] L.Liang, S.Lazoff, C. Chan, M.Horvat, J.S.Woods,Determination of antimony in wine by hydride generation graphite furnace atomic absorption spectrometry, Talanta, 1998,47,569
[59] W.Lund Anne-MarieWifladt GretheWibetoe, Fresenius" Journal of Analytical Chemistry, 1997, 357, 1
[60] J. M. Pieiro, P.L. Mahía, S. M. Lorenzo, E, Direct As, Bi, Ge, Hg and Se(Ⅳ)cold vapor/hydride generation from coal fly ash slurry samples and determination by electrothermal atomic absorption spectrometry, Spectrochimica Acta Part B: Atomic Spectroscopy, 2002, 57, 5,31,883-895
[61] I.S.Busheina, and J. B. Headridge. Determination of indium by hydride generation and atomic-absorption spectrometry. Talanta, 1982, 29, 6, 519-520
[62] 廖一平，李安模．铟氢化物发生原子吸收法研究．分析化学，1994，22，1，19-22
[63] C.Vargastrazo, J.F.Tyson, Fresenius' Journal of Analytical Chemistry, Determination of cadmium by flow injection-chemical vapor generation-atomic absorption spectrometry, 2000, 366, 2, 182-190
[64] X. W. Guo, X. M. Guo. Studies on the reaction between cadmium and potassium tetrahydroborate in aqueous solutions and its application in atomic fluorescence spectrometry. Anal. Chim. Acta, 1995, 310, 2, 377-385
[65] X.W. Guo, X.M. Guo. Determination of cadmium at ultra-trace levels by cold vapor atomic absorption spectrometry. J. Anal. At. Spectrom., 1995,10, 11,987-991
[66] X.M.. Guo, Z.H. Sun, B.L.Huang, Co-hydride enhancement effects in cadmium, zinc and thallium hydride generation measurements. Chemical Research in Chinese Universities, 1999, 20(Supplement), 83-93
[67] M.C. Valdés-Heviay Temprano, M. R. Fernández de la Campa, and A. Sanz-Medel. Generation of volatile cadmium species with sodium tetrahydroborate from organized media: Application to cadmium determination by induvtively coupled plasma atomic emission spectrometry. J. Anal. At. Spectrom., 1993, 8, 9, 847-852
[68] A. Sanz-Medel, M. C. Valdés-Hevia y Temprano, N. Bordet García, and M. R. Fernández de la Campa. Generation of cadmium atoms at room temperature using vesicles and its application to cadmium determination by cold vapor atomic spetrometry. Anal. Chem., 1995, 67, 13, 2216-2223
[69] H.W. Sun, R. Suo,, Y. K.Lu. Determination of zinc in food using atomic fluorescence spectrometry by hydride generation from organized media. Anal.Chim. Acta, 2002, 457, 2, 305-310
[70] R. E. Sturgeon, J. Liu, V. J. Boyko, and V. T. Luong. Determination of copper in environmental matrices following vapor generation. Anal. Chem., 1996, 68, 11,1883-1887
[71] A. S. Luna, R.C.Campos R.E. Sturgeon, Chemical vapor generation: Atomic absorption by Ag, Au, Cu, and Zn following reduction of aquo ions with sodium tetrahydroborate(Ⅲ), Analytical chemistry, 2000, 72, 15,3523-3531
[72] M. Julieta, S. Patricia. Evaluation of vapor generation for the determination of nickel by inductively coupled plasma-atomic emission spectrometry. Analytical and Bioanalytical Chemistry, 2002, 374, 2, 196-202
[73] V.I.Rigin, G.N.Verkhoturov, Zh. Anal. Khim., 1977, 33, 1966-1971
[74] Y.H.Lin,Z.X.Zhuang,X.R.Wang,B.L.Huang, Proceeding of international Third Beijing Conference and Exhibitionon Instrumental Analysis, Beijing China,1989,22,112-15
[75] H.Lin,X.R.Wang,D.X.Yuan,P.Y.Yang,B.L.Huang,Z.X.Zhuang,J.Anal.At. Spectrom.,1992, 7, 287-289
[76] 陈德芳，李师鹊，戚苓，金念祖，汤国才，分析试验室，1990，9，63-65
[77] Y.H.Lin,Z.X.Zhuang,X.R.Wang,B.L.Huang,Proceeding of international Third Beijing Conference and Exhibitionon Instrumental Analysis, Beijing, China,1989,22, 112～15
[78] L..Lin,X.R.Wang,X.Yuan,P.Y.Yang,B.L.Huang,Z.X.Zhuang,. Anal.At.Spectrom.,1992,7, 287
[79] D. Schaumlfel, B. Neidhart, Fresenius' J.Anal.Chem., 1996,354, 866
[80] A. Brockman, C.Nonn, A.Golloch, J.Anal. At.Spetrom., 1993,8,397
[81] 孙汉文，原子光谱分析，2001，高等教育出版社
[82] H.W.Sun, J.Ha, J.M.Sun, D.Q.Zhang, L.L.Yang, Hydride generation for the direct determination of trace anf ultra-trace level of arsenic and antimony in waters using derivative atomic absorption spectrometry, Anal Bioanal Chem, 2002, 374,526-529
[83] H.W.Sun, J.Ha, J.M.Sun, Application of hydride generation atomic absorption spectrometry with derivative signal processing to direct determination of sub-parts-per billion level of bismuth and tin in water samples, Chemical Journal on Internet, 2003, 5, 26-31
[84] H.W.Sun, J.Ha, J.M.Sun, Derivative hydride generation spectrometry atomic absorption spectrometry and determination of lead traces in waters, Fresenius' J Anal Chem, 2001, 371, 1154-1157
[85] H.W.Sun, J.Ha, D.Q.Zhang, Determination of trace in urine by derivative generation atomic absorption spectrometry, Analytical Sciences, 2002, 18, 603-605
[86] J.Ha, H.W.Sun, J.M.Sun, Determination of tellurium in urine by hydride generation atomic absorption spectrometry with derivative signal processing, Analytica ChimicaActa, 2001, 448, 145-149
[87] R.W.Wood,, Phil. Mag., 1912, 23, 696-701
[88] A. L. L Hufhes,., A. R.Thomas, phys. Rev., 1927, 30, 466-472
[89] W. Ronald Hatch, L. Ott Welland, Determination of submicrogram quantities of mercury by atomic absorption spectrophotometry Anal. Chem., 1968; 40, 14,2085-2087
[90] J.Cacho, I.Beltran,, and C. Nerin,, J. Anal. At. Spectrom., 1989, 4, 661
[91] M. C. Valdés-Hevia y Temprano, M. R. Fernández de la Campa, and A. Sanz-Medel. Generation of volatile cadmium species with sodium tetrahydroborate from organized media: Application to cadmium determination by induvtively coupled plasma atomic emission spectrometry. J. Anal. At. Spectrom., 1993, 8, 9,847-852
[92] A.Sanz-Medel, MR Fernandez de la Campa, Valde's- Hevia MC, 1995, Anal Proc.,32, 49-54
[93] A. Sanz-Medel, M. C. Valdés-Hevia y Temprano, N. Bordel García, and M. R. Fernandez de la Campa. Generation of cadmium atoms at room temperature using vesicles and its application to cadmium determination by cold vapor atomic spetrometry. Anal. Chem., 1995, 67, 13, 2216-2223
[94] X.W. Guo, X.M. Guo. Determination of cadmium at ultra-trace levels by cold vapor atomic absorption spectrometry. J. Anal. At. Spectrom., 1995,10, 11, 987-991
[95] X. W. Guo, X. M. Guo. Studies on the reaction between cadmium and potassium tetrahydroborate in aqueous solutions and its application in atomic fluorescence spectrometry. Anal. Chim. Acta, 1995, 310, 2, 377-385
[96] T. J.Hwang, S. J. Jiang, Determination of Cadmium by Flow Injection Isotope
Dilution Inductively Coupled Plasma Mass Spectrometry With Vapour Generation Sample Introduction, J. Anal. At. Spectrom., 1997, 12, 579-584.
[97] 周焕英，徐淑坤，方肇伦，流动注射蒸气发生原子吸收光谱测定痕量铜，光谱学与光谱分析，2000，20，525-528．
[98] X. G. Du, S.K. Xu, Flow-injection chemical vapor-generating procedure for the determination of Au by atomic absorption spectrometry, Fresenius' J Anal Chem,2001, 370, 1065-1070
[99] 徐淑坤，刘梅英，徐章润，方肇伦，银的流动注射蒸气发生原子吸收光谱分析初步研究，1999，岩矿测试，18，15-18
[1] A.Walsh, Spectrom. Acta, 1955, 7, 108
[2] J.H. Watkinson, Fluorometric Determination of Selenium in Biological Material with 2,3-Diaminonaphthalene. Anal. Chem., 1966, 38, 92-97
[3] J. E. Allan, Spectrochim. Acta, 1962, 18,259
[4] S. Sprague, D. C. Manning and W. Slavin, At. Abs. Newsl., 1964, 20, 27
[5] C. S. Rann, A. N. Hambly, The determination of selenium by atomic absorption spectrophotometry, Anal. Chim. Acta, 1965, 32,346-354
[6] J. E. Allan, 4th Australian Spectroscopy Conference, Auguest, 1964
[7] W. B. Barnett, At. Abs. Newsl., 1973, 12, 142
[8] J. E. Allan, 4th Australian Spectroscopy Conference, Auguest, 1964
[9] W. B. Barnett, At. Abs. Newsl., 1973, 12, 142
[10] H. L. Kahn, J. E. Schallis, At. Abs. Newsl, 1968, 7, 5
[11] C. L. Chakrabarti, The atomic absorption spectroscopy of selenium, 1968, Anal.Chim. Acta, 42,379-387
[12] G. F. Kirkbrifht, L. Ranson, Use of the nitrous oxide-aceytlene flame for determination of arsenic and selenium by atomic absorption spectrometry, Anal.Chem., 1971, 43, 1238-1241
[13] S. Ng, M. Munroe, W. Mcsharry, J. Assoc. Off. Anal. Chemists, 1974, 57, 1260
[14] B. C. Severne, R. R. Brooks, Rapid determination of selenium and tellurium by atomic-absorption spectrophotometry, Talanta, 1972, 19, 1467-1470
[15] 华南师范大学学报(自然科学版)2000，1，77
[16] Simeonova S et al., Fresenius' Journal of Anal. Chem., 1986, 325(5), 478
[17] 刘锋，李玉环，刘群，萃取火焰原子吸收法测定高梁种皮中的硒，光谱学与光谱分析，2002，22，6，485-486
[18] J．E．坎特尔编，黄德玲等译，原子吸收光谱，科学文献出版社，267，1990
[19] Y.Z. Liang, M. Li, Z. Rao, Nickel and Strontium Nitrates as Modifier for the Determination of Selenium in Urine by Zeeman Platform Graphite-Furnace Atomic Absorption Spectrometry, Anal Sci, 1996, 12, 629-633
[20] Y.Z. Liang, M. Li, Z. Rao, Long-term sampling system for the measurement of ambient air concentrations of mercury at a contaminated site Fresenius' Journal of Analytical Chemistry, 1997, 357, 1, 112-116
[21] D. Ryszard, Determination of selenium in Solis by Slurry-Sampling Graphite-FurnaceAtomic-Absorption Spectrometry with Polytetrafluoroethylene as Silica Modifier, Fresenius' Journal of Analytical Chemistry, 2001,370, 7, 850-854
[22] P. Liu, L Wei., K. Matsumoto, K.Fuwa, Enhancement Effect of Palladium Addition in the Determination of Selenium in Organic-Matrix Solutions by Electrically Heated Carbon Furnace Atomic Absorption Spectrometry, Anal.Sci., 1985, 1, 3,257-261
[23] Norbert Szoboszlai, Erzsebet Andrasi, Zsolt Ajtony, Mikrochimica Acta, 2001,137, 1-2, 81-86
[24] 陈晋苏，药物分析杂志，1999年06期414
[25] Osamu Kujirai, Takeshi Kobayash, Talanta, 1983, 30(1): 9
[26] 潘娟瑛，王志伟，陈恒武，锌作为基体改进剂石墨炉原子吸收法测定废水中的硒，光谱学与光谱分析，1996，03，111-115
[27] 陈良壁，廖一平，光谱学与光谱分析，3(1)，58-59，1983
[28] 田笠卿，黄振中，陈逸君，环境化学，1989，8(4)，41
[29] 王和悦，华佩冬，杨英，重庆大学学报，10(2)，122-126，1987
[30] 章春星，氢化物-石墨炉原子吸收光谱法测定环境水样的痕量硒，厦门科技 2000m，S1，51-53
[31] B.Welz, G.Bosai, Sperling, M., J. Anal. At. Spectrom., 1992, 7, 505
[32] Deaker, M. Maher, W., J. Anal. At. Spectrom., 1995, 10, 423
[33] 谢文斌，姚金玉，马戈，光谱学与光谱分析，1998，18(6)，700
[34] 中国现代应药医学杂志，1998，15(6)，52
[35] 微波消解石墨炉原子吸收法测定食品中硒 吕建民，王向纯 中国公共卫生 2000年09期 800
[36] 杨锦发，苏瑞芳，理化检验(化学分册)，26(1)，36-37，1990
[37] Julijana Cvetkovi, Traje Stafilov, Dragan Mihajlovi, Fresenius J Anal Chem(2001) 370: 1077-1081
[38] 周世兴，林天立，钱军，林柱友，氢化物-电热原子吸收法测定人血清硒，环境监测管理与技术，1997，9，06，32-33
[39] 张宝贵，王燕，李桂春，魏红梅，王立世，冯建兴，南开大学学报(自然科学版)，1997，01，108-110
[40] O.Astrom, Anal.Chem., 54, 190, 1982
[41] 王秀，方肇伦，分析化学，14，738，1986
[42] H. Robberecht, R. Van Grieken, Talanta, 1982, 29,823
[43] Z. Fang, S. Xu, X. Wang and S. Zhang, Anal.Chim. Acta, 1986, 179, 325
[44] B.Welz, P.Stauss, Spectrochim. Acta, Part B, 48, 951, 1993
[45] A.Larraya, M.G. Cobo-Femandez, M.A. Palacios, C.Camara, Fresenius' Journal of Analytical Chemistry, 350, 12, 1994, 667-670
[46] 章开源，郭小伟，连续流动氢化物发生—原子吸收光谱法测定地质样品中痕量硒，分析试验室，1997，16，02，51-54
[47] R.E.Sturgeon, S.N.Willie, S.S. Berman, Anal. Chem., 57, 2311, 1985
[48] Zang,L., Ni,Z.M.,Shan,X.Q.,Spectrochim.Acta., 1989, 44B, 3,339
[49] 马玉平，流动注射氢化物石墨炉原子吸收法测定铅碲合金中微量硒，理化检验(化学分册)，1994，30，1，
[50] Effect of high salt concentrations on the determination of arsenic and selenium by
flow injection hydride generation electrothermal atomic absorption spectrometry,Robert Ⅰ. Ellis, Nils G.Sundin, Julian F. Tyson, et al., Analyst, 1998, 123,1697-1701
[51] Fernando Barbosa Jr., Samuel Simio de Souza and Francisco J. Krug, In situ trapping of selenium hydride in rhodium-coated tungsten coil electrothermal atomic absorption spectrometry, J. Anal. At. Spectrom., 2002, 17, 4, 382-388
[52] D.Q.Zhang, H.W.Sun, L.L.Yang, Fresenius' Journal of Analytical Chemistry, 1997,359, 6, 492-496
[53] R. Allabashi, J.Rendl, Validation of three atomic absorption'spectrometry methods for the determination of selenium-a comparative evaluation of performance characteristics, Fresenius' J Anal Chem, 357,1024-1028, 1997
[54] H.Narasaki, Determination of arsenic and selenium in fat materials and petroleum products by oxygen bomb combustion and automated atomic absorption spectrometry with hydride generation, Anal Chem. 1985,57, 13,2481-6
[55] M.R Rayman, F.R.Abou-Shakra, N.I.Ward, J.Anal.At. Spectrom., 1996, 11, 61,
[56] W.T. Buckley, J.J. Budac, D.V. Godfrey, K.M. Koenig, Determination of selenium by inductively coupled plasma mass spectrometry utilizing a new hydride generation sample introduction system, Anal Chem. 1992, 1,64,724-9.
[57] M.Gloria Cobo Fernandez, A.Maria, Flow-injection and continuous-flow systems fot the determination of Se (Ⅵ) and Se (Ⅳ) by hydride generation atomic absorption spectrometry with on-line prereduction of Se(Ⅵ) to Se (Ⅳ), Analytica Chimica Acta, 1993, 283,386-392
[58] J.Piwonka, G.Kaiser, G.Tolg, Determination of selenium at ng/g and pg/g levels by hydride generation atomic absorption spectrometry in biotic materials, Fresenius Z Anal Chem, 1985, 321,225-234
[59] M.Ohata, T.Ichinase, S.Atsuka, M.Chiba, N.Furuta, Isotope dilution analysis of Se in human blood serum by using high-power nitrogen microwave-induced plasma mass spectrometry coupled with a hydride generation technique, Anal Chem,1998, 70, 13, 2726-30.
[60] B.Welz, M.Melcher, Decomposition of marine biological tissues for determination of arsenic, selenium, and mercury using hydride-generation and cold-vapor atomic absorption spectrometries, Anal Chem, 1985, 57, 2, 427-31
[61] V.Krivan, J.Anal.At.Spetrom. 1992, 7,155
[62] L.Pitts, P.J.Worsfold, S.J.Hill, Analyst, 1994,119, 2785
[63] P.B.Stockwell, W.T.Corns, Analyst, 1994, 119,1641
[64] D.W.Bryce, A.Izquierdo, M.D.Luque de Castro, Analyst, 1995, 120, 2171
[65] J.M.G.Lafuente, M.L.F.Sánchez, A.Sanz-Medel, J.Anal.At Spectrom, 1996, 11,1163
[66] L.Pitts, A.Fisher, P.Worsfold, S.Hill, J.Anal.At.Spectrom. 1995, 10, 519
[67] R.M.Olivas, D.F.X.Donard, Microwave assisted reduction of SeⅥ to SeⅣ and determination by HG/FI-ICP/MS for inorganic selenium speciation, Talanta,1998,45, 1023-29
[68] D.L.Tsalev, M.Sperling, B.Welz, Analyst, 1992, 117,1729
[69] J.L.Burguera, P. Carrero, M.Burguera, C.Rondón, M;L.Brunetto, M.Gallignoni, Flow injection for the determination of Se(Ⅳ) and Se(Ⅵ) by hydride generation atomic absorption spectrometry with microwave oven on-line prereduction of Se(Ⅵ) to Se(Ⅳ), Spectrochim.Acta, PartB51, 1996, 1837-47
[70] 孙汉文，原子吸收光谱分析技术，中国科学技术出版社，北京，119
[71] B.Welz, M.Schubert,5ColloquiumAtomspektrometrischeSpurenanalytik(collected papers),B.Welz,Editor, Bodenseewerk Perkin-Elmer, 1989, 327
[72] 中国预防医学科学院劳动卫生与职业病研究所主编．车间空气监测检验方法，第3版，北京，人民卫生出版社，1990．180
[74] 陈俐娟，刘黎，李晖，用高灵敏度分光光度法测定海豚肝脏中的微量硒，四川大学学报(自然科学版)，2000，37，2，288-292
[73] J.L.Bemal, M.J.Del Nozal, L.J.Deban, Modification of the methylene blue method for spectrometric selenium determination, Talanta, 1990, 37, 931-6
[74] 陈思钦，傅毅华，曾希建，催化动力学光度法测定痕量硒，江西大学学报(自然科学版)，1989，13，3，36-40
[75] 刘锡钧，朱杰航，催化显色反应确定硒含量的探讨，海峡药学，2000，12，4，31-33
[76] 方文焕，吴绍祖，铁-硫氰酸盐-结晶紫体系离心光度法测定血清中铁分析化学，1996，24，12，1045-1048
[77] 方文焕，林志勇，吴绍祖．离心光度法测定酒中微量Zn的方法研究[J]．华侨大学学报(自然科学版)，1996，17，2，144-146
[78] 朱五瑞，任杰，江万权．萃取浮选光度法测定微量钼的研究及应用[J]．中国科学技术大学学报，1991，21，4，465-468
[79] 刘志明，刘嘉敏，李文辉．剂浮选吸光光度法测定痕量Au[J]．理化检验(化学分册)，1991，27，1，34-36
[80] 刘嘉敏，江惊奇，张敏，溶剂浮选吸光光度法测油品中痕量砷，理化检验(化学分册)，1999，35，9，428-430
[81] 杨开安，结晶紫萃取光度法测定催化裂化催化剂中微量锑，理化检验(化学分册)，1993，29，6，63-65
[82] 唐祖芬，施晰昕，铁(Ⅲ)的缔合型三元配合物显色反应的研究，华东冶金学院学报，1990，7，3，81-83
[83] 陈戈，范慧例，温美娟．硒(Ⅳ)-KI-结晶紫显色体系的研究，冶金分析，1998，18，3，9-12
[84] 裴世桥，陈友伟．结晶紫．锗钼酸流动注射光度法测定地质样品中锗，分析化学，1995，23，6，739-739
[85] 刘绍璞，刘忠芳．钒-硫氰酸盐-碱性三芳基甲烷染料的显色反应研究，高等学校化学学报，1989，10，8，800-801
[86] 冯胜，张学明．在增溶剂存在下硫氰酸盐-结晶紫光度法测定微量钨，分析化学，1989，17，9，820-22
[87] 陈兰化，陈新，IO~(-3)-I--结晶紫-阿拉伯胶体系分光光度法测定生物样品中的碘，分析科学学报，1996，12，4，329-32
[88] 吴亮船，高温合金中磷的测定磷锑钼杂多酸-结晶紫-PVA光度法，光谱实验室，1996，13，4，27-28
[89] 沈含熙，凌蓉．双显色剂高灵敏协同显色反应的研究：钴-亚硝基R盐-结晶紫体
体系，分析化学，1990，18，8，700-702
[90] 朱展才．以结晶紫与亚硝基R盐吸光光度法测定镍[J]．分析化学，1995，23，12，1444-46
[91] 朱展才，王杨春，胡建华．藉铋-亚硝基R盐-结晶紫反应高灵敏分光光度法测定痕量铋[J]．分析化学，1996，24，11，1269-71
[92] 陶慧林．聚乙烯醇和阿拉伯胶存在下用分光光度法测定铌[J]．桂林工学院学报，1995．15，4，392-5
[93] W. Holak, J. Specchio.Determination of selenium in food supplements by differential-pulse cathodic stripping voltammetry in the presence of added copper.Analyst. 1994,119, 10, 2179-82
[94] 夏静，檀华蓉，蔬菜中微量硒的比色测定，安徽农业科学 1997，25，3，278-279．
[95] A.G.Milovanovic, B.R. Petronijevic, M. M. Cakar, Kinetic Determination of Trace Levels of Selenium(Ⅳ) and Total Selenium by Nile Blue A/Hydrogen Peroxide Method, Mikrochimica Acta, 1998, 128, 1-2, 43-48
[96] L Johann. Fischer, Electothermal atomization of palladium stabilized selenium in the presence of phosphate, Spectrochimica Acta. Part B, Atomic Spectroscopy,2002, 57B, 3,. 525-533
[97] Q.H. Hu, L.C. Chen, J. Xu, determination of selenium concentration in rice and the effect of foliarapplication of Se-enriched fertiliser or sodium selenite on the selenium content of rice, Journal of the Science of Food and Agriculture,2002, 82, 8. 869-872
[98] W. Lei, G. Parul, H. Robert, Determination of Ultratrace Selenium and Arsenic at Parts-per-Trillion Levels in Environmental and Biological Samplesby Atomic Fluorescence Spectrometry with Flow InjectionHydride Generation Technique,Microchemical Journal, 1999, 62, 83-98
[99] L. Ga'miz-Gracia, M.D. Luque de Castro, Determination of selenium in nutritional supplements and shampoos by flow injection-hydride generation-atomic fluorescence spectrometry, Talanta, 1999, 50, 875-880
[100] R. Sabé, R. Rubio, Selenium determination in urine with atomic fluorescence detection, Analytica Chimica Acta, 2001,436, 215-221
[1] W. H. Allaway. E. E.Cary. The environmental background of selenium deficiency diseases-Foodstuffs. 1966, 38, 62-66
[2] P.R.Caffrey, G. D.Frankel, Selenite cytotoxicity in drug resistant and nonresistant human ovarian tumor cells, Cancer Res, 1992, 1, 52, 17, 4812-6
[3] V.N. Gladyshev, S.V.Khangulov, T.C. Stadtman. Properties of the selenium-and molybdenum-containing nicotinic acid hydroxylase from Clostridium barkeri.,Biochemistry. 1996,9, 35, 1, 212-23.
[4] S. C. Low., M. J. Berry, Knowing when not to stop: selenocysteine incorporation in eukaryotes, Trends Biochem Sci., 1996, 21, 6, 203-8
[5] 张克明，白遵彬，中国“硒与健康”数据库应用研究，环境科学学包，1989，9，1，42-49
[6] C.A.Girling, Selenium in agriculture and enbironment, Agriculture, Ecosystem, Enbironment. 1984, 11, 37-65
[7] 中国矿物岩石地球化学学会环境地质化学学会编，环境化学与健康，地震出版社，1990，222-225
[8] 王子健，彭安，分析化学，1988
[9] 彭安，王子健，P．D．Whanger等编，戏的环境生物无机化学，中国环境科学出版社，北京，1995，3-44
[10] 徐辉碧，黄开勋，硒的化学、生物化学及其在生命科学中的应用，华中理工大学出版社，1994，268-283
[11] 施和平，张英聚，刘振声，番茄对硒的吸收、分布和转化，植物学报，1993，35，7，541-547
[12] M.M. Abrams, C. Shennan, R.J. Zasoski, Selenomethionine uptake by wheat seedlings. Agron J, 1990, 82, 1127-1130
[13] A.Kabata, H.Pendias, Elements of group-Ⅵ.-In trace element in soils and plants,
CRC press, 1992, 217-225
[14] E.A.H,Pilon, S. Hwang, C.M.Lytle, Overexpression of ATP sulfurylase in Indian mustard leads to increased selenate uptake, reduction, and tolerance, Plant Physiol,1999, 119, 123-132
[15] D.C. Eustice, F.J. Kull, A.Shrift, Selenium toxicity: aminoacylation and peptide bond formation with selenomethionine, Plant Physiol, 1981, 67, 1054-58
[16] T.A. Brown, A. Shrift. Exclusion of selenium from proteins in selenium-tolerant Astragalus species, Plant Physiol, 1981, 67, 1951-53
[17] 冯昭扬，张英聚，中山大学硕士研究生毕业论文，1991
[18] J.T.Roruck. A.L.Pope, H.E.Ganther,, Selenium: biochemical role as a component of glutathione peroxidase, Science, 1973, 35, 2, 151-154
[19] J.Parizek, I.Ostadalova, The protective effects of small amounts of selenite in sublimate intoxication-Experientia, 1967, 23, 142-143
[20] 彭双清，刘世杰．镉对心肌细胞动作电位的影响及硒的保护作用．中华劳动卫生职业病杂志，1998，16，1，34-36
[21] 彭双清，刘世杰．镉对心肌细胞Ca~(2+) 通道的阻带作用及硒的保护效应．中华劳动卫生职业病杂志，1999，17，3，161-163
[22] 连祥霖，陈新春．硒对氯化汞免疫毒性的影响及其机理．卫生毒理学杂志，1998，12，2．89
[23] 李金有，刘志艳，孙天佑等，硒拮抗砷致小鼠微核率改变的剂量效应特征．中国地方病学杂志，1999，18，1，5-7
[24] R.L.Mikkelsen,H.F.wan,The effect of selenium on sulfur uptake by barelyandrice,Plant Soil, 1990, 121,151-153
[25] M.R Arvy, Selenate and selenite uptake and translocation in bean plants (Phaseolus vulgaris). J. Exp. Bot. 1993, 44, 1083-87
[26] E.E.Cary, Effect of selenium and cadmium additions to soil on their concentration in lettuce and wheat, J.Agron, 1981, 73,703-708
[27] 谭周磁，陈嘉勤，薛海霞，硒对降低水稻重金属Pb，Cd，Cr污染的研究，湖南师范大学(自然科学学报)，2000，23，3，80-83
[28] L.Tommy, G.Maria, Influence of selenium on uptake and toxicity of copper and cadmium in pea and wheat, Physiologia Plantarum, 1994, 90, 637-644
[29] Greene,J.C.etal. Protocols for short-term toxicity screening of hazardous waste sites[S]. US Environmental Protection Agency(EPA), 1998, 600/3-88/029
[30] International Or ganization for Standardization (ISO). Soil quality determination of the effects of pollutants on soil flora. Partl: method for the measurement of inhibition of root growth [S], ISO, 11269-11993
[31] OECD (Organization for Economic Cooperation and Development). OECD guide lines for testing of chemicals [S]. Paris. France: European Committee,1984.208-209.
[32] 孙赛初，王焕校，李启任，水生维管束植物受镉污染后的生理变化及受害机制初探，植物生理学报，1985，11，2，113-121
[33] 刘东华，蒋悟生，镉对洋葱根生长和细胞分裂的影响，环境科学学报，1992，12，4，439-446
[34] 段昌群，王焕校，重会属对蚕豆的细胞遗传学毒理作用和对蚕豆根尖微核技术的探讨，植物学报，1995，37，1，14-24
[35] 刘东华，蒋悟生，李懋学．镉对洋葱根生长和细胞分裂的影响．环境科学学报，1992，12，4，439-446
[36] 陈桂珠 重会属对黄瓜籽苗发育影响的研究，植物学通报，1990，7，1，34-39
[37] 龚雨松，李振国，余叔文，小麦幼苗镉螯合素，植物生理学报，1990，16，1，19-25
[38] M. Bartolf, E.Brennan, C.A.Price, Partical characterization of cadmium-binding protein from the root of cadmium treated tomato, Plant Physiol, 1980,66,434-441
[39] J.L.Casterliine, N.M.Barnett, Isolation and characterization of cadmium-binding components in soybean plants, Plant Physiol, 1977, 59, 5-124
[40] 赵博生，莫华，镉对蒜根生长的毒害及抗坏血酸、铁盐的解毒效应，武汉植物学研究，1997，15，2，167-172
[41] 柴之芳，祝汉民，微量元素化学概论，北京，原子能出版社，1994 268-270，112-115
[42] 中国科学院地理研究所环境与地方病组，营养学报，1982，4，3，85，103，209-214
[43] L.B Siburg, T, Mattern, J D Folts, U. M. Wiesgerber, M. B. Katan, Tea falvonoids and cardiovascular diseases, A review. J. Crit Rev Food Sci Nutr., 1997, 37,761-770
[44] H.Mukhtar, N. Ahmad, Green tea in chemoprevention of cancer. Toxocal Sci. 1999,52. 111-117
[45] Wang Z.Y, Agarwal R, Klan W.A., Mukhtar H., Carcinogenesis, 1992, 8,1491-1494
[46] 于新蕊，曲军，丛月珠等．茶叶的化学成分及药理作用研究进展，中草药，1995，26，4，219-221
[47] A.Finger, Chromatography of tes constituents, J. Chromatography, 1992, 624,293-296
[48] M.Simon, L.Horovaskal, Antihemolytic effect of rooibos tes on redblood cells of Japanese quails, ,Gen Physiol Biophys, 2000, 19, 4, 365-369
[49] 黄育华，张建军，晏雪生，等．富硒珍珠茶对人肝癌细胞株Bel-7402诱导分化的实验研究．中医研究，2000，13，2，25～28
[50] 阮宇成，茶叶中的硒及其与人体健康，中国茶叶，1987，5，10-11
[51] 陈宗憨，也谈茶硒素与人体健康，中国茶叶，1988，4，14-15
[52] 方兴汉，吴彩，沈星荣，从我国茶叶含硒量状况谈我国高硒茶的开发应用，中国茶叶，1990，6，6-8
[53] S.K.Lam, 9th Seah Cheng Siang Memotia Lecture: gastric cancer-where are we now? Ann Acad Med Singapore, 1999, 28, 6, 881-883
[54] 杜琪珍，沈星荣，方兴汉．茶叶中的硒成分分析，茶叶科学，1991，11，2，133～137
[55] I.Harrison, D.Littlejohn, G.S.Fell, Improved molecular fluorescence method for the determination of selenium in biological samples Analyst, 1996, 121, 1641
[56] V.Ducros, D.Ruffieux, N.Belin, A.Favier, Comparison of two digestion methods for the determination of selenium in biological samples. Analyst, 119, 1994, 1715
[57] R.Lobinski, Z. Marczenko, Comprehensive Analitical Cehrnistry Spectrochemical
Trace Analysis for Metals and Metalloids, Elsvier, Amsterdam, 1996, 649
[58] H.T.Delves. I.L.Shuttler, Atomic Absorption spectrometry, Elsevier. Amsterdam.1991,400
[59] R.Sabé, R Rubio, L.García-Beltrán, Study and comparison of several chemical modifiers for selenium determination in human serum by Zeeman electrothermal atomic absorption spectrometry, Analytica Chimica Acta, 1999. 398.2-3, 22.279-282
[60] Hernández-Caraballo, Edwin A.; Burguera, Marcela; Burguera, José L., Evaluation of ammonia as diluent for serum sample preparation and determination of selenium by graphite furnace atomic absorption spectrometry, Spectrochimica Acta Part B: Atomic Spectroscopy, 2002, 57, 2, 2159-2163
[61] H. J,Robberecht H.A Deelstra. Factors influencing blood seleniumconcentration values: a literature review. J Trace ElemElectrol Health Dis 1994, 8, 129-143
[62] Aaseth J, Smith-Kieland A, Thomassen Y. Selenium alcohol and liver diseases. Ann Clin Res 1986, 18, 43-47
[2] G. R.Kingsley, Am. J. Med. Technol., 1951, 16, 247-253
[3] V.Vasak, V.Sedivee, Collection Czechoslov Chem. Communs., 1952, 18, 64-72
[4] W. Holak., Gas-sampling technique for arsenic determination by atomic absorption spectrophotometry, Anal. Chem., 969, 41, 12, 1712-1713
[5] B. L. Huang, Recent studies on inductively coupled plasma sample introduction-1: Hydride generation, Pages 381-389 Spectromica Acta, Part B, 1988, 43,381-389
[6] P. Verrept, C. Vandecasteele, G. Windels and R. Dams, Use of a refractor plate for automatic background correction in electrothermal vaporization inductively coupled plasma atomic emission spectrometry, Spectromica Acta, Part B, 1991, 46, 99-102
[7] X. W. Guo, X. M. Guo, Shanghai Enviromental Sciences, 1995, 375, 14, 28～31
[8] E. F. Dolton, A. Malanoski, At. Absorpt. Newsl., 1971,10, 92
[9] K. C. Thompson, D. R. Thomerson, Analyst, 1974,99,595
[10] H. C. Freeman, J. F. Uthe, At. Absorpt. Newsl.,1976,13: 75
[11] R. S. Braman, L. L. Justen, C. C. Foreback, Direct volatilization-spectral emission type detection system for nanogram amounts of arsenic and antimony. Anal.Chem., 1972, 44, 13, 2195-2199
[12] A. J. Bard, R. Parsons, J. Jordan(Eds.), Standard Potentials, 1966,Butterworth-Heinemann, Oxford
[13] W. B. Robbins, J. A. Caruso, Development of hydride generation method for atomic spectroscopic analysis, Anal. Chem., 1979, 51, 889A-899A
[14] R. G. Godden, D. R. Thomerson, Generation of covalent hydrides in atomic absorption spectrometry, Analyst, 1980, 105, 1137-1156
[15] T. Nakahara, Prog. Analyt. Atom. Spectrosc., 1983, 6, 163-223
[16] J. Dedina, D. L. Tsalev, Hydride Generation Absorption Spectrometry, Wiley,
Chichester, 1995, 19
[17] F. Laborda, E. Bolea, M. T. Baranguan, J. R. Castillo, Hydride generation in analytical chemistry and nascent hydrogen:when is it going to be over? 797-802
[18] O. Astrom, Flow injection analysis for the determination of bismuth by atornic absorption spectrometry with hydride generation, Anal. Chem., 1982, 54, 2,190-193
[19] 王秀、方肇伦，分析化学，氢化物发生—原子吸收流动注射分析法测定环境样品中痕量硒，分析化学，14，10，1987，．738～743
[20] B. Welz, M. Melcher, Decomposition of marine biological tissues for determination of arsenic, selenium, and mercury using hydride-generation and cold-vapor atomic absorption spectrometries, Anal Chem 1985 Feb 57: 427-31
[21] P.P. Chou, P.K. Jaynes, J.L. Bailey Determination of bismuth in urine by atomic absorption with hydride generation, J Anal Toxicol 1984, 8, 158-60
[22] J.R.Castillo, J.Lanaja,J.Aznarez, determination of selenium in biological samples by hydride generation and atomic absorption spectroscopy, Analyst, 1982, 107,89-94
[23] A. John, R.Michelle, Preservation of arsenic(Ⅲ) and Arsenic(Ⅴ) in samples of sediment interstitial water, Analyst, 1987, 112, 153-156
[24] C. P. Tsai, A. Sahil, J. M. McGuire, B. L. Karger, Paul Vouros;High-performance liquid chromatographic mass spectrometric determination of volatile carboxylic acids using ion-pair extraction and thermally introduced alkyl alkylation, Anal.Chem., 1986, 58, 1, 2-6
[25] 张燕红，夏正斌，头发中硒的流动注射．氢化物发生原子吸收光谱法测定，分析测试学报，2002，01，25-28
[26] 区红，何华煜，氢化物发生原子吸收分光光度法测定食盐中铅，分析试验室 2002，04，96-98
[27] 陈天裕，汪正，流动注射氢化物发生-原子吸收光谱法测定镍基合金中的硒和锡，分析试验室，2001，02，14-16，
[28] 张友爱，氢化物发生．原子吸收光谱法测定食品中无机砷，中国公共卫生
2002, 08, 982-983
[29] Y. PeTIT de Pena O. Vielma J.L. Burguera M. Burguera C. Rondon R Carrero,On-line determination of antimony(Ⅲ) and antimony(Ⅴ) in liver tissue andwhole blood by flow injection-hydride generation-atomic absorption spectrometry,Talanta, 2001, 55, 4,743-754
[30] M. Gallignani, Sequential determination of Se(Ⅳ) and Se(Ⅵ) by flow injection-hydridegeneration-atomic absorption spectrometry with HCl/HBr microwave aided per-reduction of Se(Ⅵ) to Se(Ⅳ), Talanta, 2000, 52, 6,1015-1024
[31] O. Munoz, R.Montoro, A.Arroyo, M. Zamorano, D Velez,. Determination of inorganic arsenic As(Ⅲ) plus As(Ⅴ) in water samples bymicrowave assisted distillation and hydride generation atomic absorption spectrometry, Journal of Analytical atomic spectrometry, 2000, 15, 6, 711-714
[32] A.Korez, M.Volkan OY., AE.Eroglu, Speciation and preconcentration of inorganic tellurium from waters using amercaptosilica microcolumn and determination by hydride generation atomic absorption spectrometry, Journal of Analytical atomic spectrometry, 2000, 15,12, 1599-1605
[33] C.Kabengera, P.Bodart, P. Hubert, L. Thunus, Optimization and validation of arsenic determination in foods by hydridegeneration flame atomic absorption spectrometry, Journal of AOAC International, 2002, 85, 1, 122-127
[34] A. Schwingel, R.Marco, A. Zezzi, Determination of bismuth in metallurgical materials using a quartz tubeatomizer with tungsten coil and flow injection-hydride-generation atomic absorption spectrometry, Spectrochimica Acta.Part B, atomic Spectroscopy, 2002, 57B, 2113-2120
[35] M. Krachler, H.Emons, M.Burow, Development and evaluation of an analytical procedure for the determinationof antimony in plant materials by hydride generation atomic absorption spectrometry, The Analyst, 1999, 124, 5,777-782,
[36] W.R. Mindak, S.R Dolan, Determination of arsenic and selenium in food using a microwave digestion -dry ash preparation and flow injection hydride generation
atomic absorption spectrometry, Journal of food composition and analysis, 1999,12, 2, 111-122
[37] S.Y. Chen, Z. F. Zheng, H. M. Yu, Determination of trace bismuth by flow injection-hydride generationcollection-atomic absorption spectrometry,Analytical and Bioanalytical Chemistry, 2002, 374, 1, 126-130
[38] 姚敏德，陈小芒，李绍南，氢化物发生—电加热石英管原子吸收法测定环 境水样中痕量铅的研究，中国环境监测，2002，03，13-15
[39] H.M. Liu, S.Y. Chen, RH. Chang, Determination of bismuth, selenium and tellurium in nickel-based alloys andpure copper by flow-injection hydride generation atomic absorption spectrometry-with ascorbic acidprereduction and cupferron chelation-extraction, Analytica chimica acta, 2002, 459, 1,161-168
[40] Przemyslaw Niedzielski Jerzy Siepak, Determination of Antimony in Natural Waters by Atomic AbsorptionSpectrometry with Flow-Injection hydride generation, Chemia analityczna, 2001, 46, 1, 51-57
[41] 陈继强，刘树森，谢连宏，李凤萍，空气中铅的氢化物发生．原子吸收光谱测定法，中华劳动卫生职业病杂志 2001，02，154-155
[42] 孙锡丽，应海松，余青，流动注射．氢化物发生原子吸收法测定铁矿中砷、锑、铋含量，光谱实验室，2000，17，1，121-123
[43] 刘德宗，靳志华，张天慧，氢化物发生—原子吸收分光光度法测定食品中微量锡，齐齐哈尔轻工学院学报，1997，13，4，86-88
[44] 王升章，龚楚舒，长缝石英管氢化物．火焰原子吸收光谱法测定化探样品及铅锭中微量锡，理化检验．化学分册1994，6，329-330
[45] 马玉平，韩益清，阿依古丽，氢化物-原子吸收石墨炉原子吸收光谱法应用研究，分析化学，1994，22，6，586-589
[46] C.Ctrsser, J.Anal. Atom. Spectrometry, 5,11R, 1990
[47] 童开源，郭小伟，连续流动氢化物发生—原子吸收光谱法测定镍合金中硒及碲，冶金分析 1996，6，4-6
[48] H.L.Kahn, At.Absorpt. Newsl.,1971,10, 58
[49] D.L.Tsalev, P. B. Mandjukov, J.A.Stratis,At. Spectrom., 1987, 2, 135
[50] C.Reamer, C.Veillon, ET.Tokousbalides, Radiotracer techniques for evaluation of selenium hydride generation systems, Anal. Chem., 1981, 53, 2, 245-248
[51] K.Krivan, Petrick, Fresenius'Z.Anal.Chem., 1990, 336, 6, 480
[52] G.Drasch,L.V.Kauert, Auwendung der gtaphitrohrkuvette Zur Arsenbestimmung in biologischen prober mitder hydride-AAS-Technik, Fresenius'Z. Anal. Chem., 1980,304, 2/3,141-145
[53] S.N.Willie, R.E.Sturgeon, S.S.Berman, Hydride generation atomic absorption determination of selenium in marine sediments, tissues and seawater with in-situ concentration in a graphite furnace, Anal. Chem., 1986, 58, 6, 1140-1143
[54] R.E.Sturgeon,S.N.Willie,S.S.Berman, Fresenius'Z Anal.Chem.,1986,323, 7,788
[55] R. E. Sturgeon, S. N. Willie, S. S. Berman, Hydride generation-atomic absorption determination of antimony in seawater with in situ concentration in a graphite furnace, Anal. Chem., 1985, 57, 12, 2311-2314
[56] 严德忠，万体智，氢化物-墨炉原位富集原子吸收光谱法测定痕量锑，光谱实验室，1997，14，4，34
[57] 罗小玲，熊伟，李冀新，流动注射氢化物石墨炉法测定鱼、香梨中的痕量汞，光谱实验室 1994，11，03，19
[58] L.Liang, S.Lazoff, C. Chan, M.Horvat, J.S.Woods,Determination of antimony in wine by hydride generation graphite furnace atomic absorption spectrometry, Talanta, 1998,47,569
[59] W.Lund Anne-MarieWifladt GretheWibetoe, Fresenius" Journal of Analytical Chemistry, 1997, 357, 1
[60] J. M. Pieiro, P.L. Mahía, S. M. Lorenzo, E, Direct As, Bi, Ge, Hg and Se(Ⅳ)cold vapor/hydride generation from coal fly ash slurry samples and determination by electrothermal atomic absorption spectrometry, Spectrochimica Acta Part B: Atomic Spectroscopy, 2002, 57, 5,31,883-895
[61] I.S.Busheina, and J. B. Headridge. Determination of indium by hydride generation and atomic-absorption spectrometry. Talanta, 1982, 29, 6, 519-520
[62] 廖一平，李安模．铟氢化物发生原子吸收法研究．分析化学，1994，22，1，19-22
[63] C.Vargastrazo, J.F.Tyson, Fresenius' Journal of Analytical Chemistry, Determination of cadmium by flow injection-chemical vapor generation-atomic absorption spectrometry, 2000, 366, 2, 182-190
[64] X. W. Guo, X. M. Guo. Studies on the reaction between cadmium and potassium tetrahydroborate in aqueous solutions and its application in atomic fluorescence spectrometry. Anal. Chim. Acta, 1995, 310, 2, 377-385
[65] X.W. Guo, X.M. Guo. Determination of cadmium at ultra-trace levels by cold vapor atomic absorption spectrometry. J. Anal. At. Spectrom., 1995,10, 11,987-991
[66] X.M.. Guo, Z.H. Sun, B.L.Huang, Co-hydride enhancement effects in cadmium, zinc and thallium hydride generation measurements. Chemical Research in Chinese Universities, 1999, 20(Supplement), 83-93
[67] M.C. Valdés-Heviay Temprano, M. R. Fernández de la Campa, and A. Sanz-Medel. Generation of volatile cadmium species with sodium tetrahydroborate from organized media: Application to cadmium determination by induvtively coupled plasma atomic emission spectrometry. J. Anal. At. Spectrom., 1993, 8, 9, 847-852
[68] A. Sanz-Medel, M. C. Valdés-Hevia y Temprano, N. Bordet García, and M. R. Fernández de la Campa. Generation of cadmium atoms at room temperature using vesicles and its application to cadmium determination by cold vapor atomic spetrometry. Anal. Chem., 1995, 67, 13, 2216-2223
[69] H.W. Sun, R. Suo,, Y. K.Lu. Determination of zinc in food using atomic fluorescence spectrometry by hydride generation from organized media. Anal.Chim. Acta, 2002, 457, 2, 305-310
[70] R. E. Sturgeon, J. Liu, V. J. Boyko, and V. T. Luong. Determination of copper in environmental matrices following vapor generation. Anal. Chem., 1996, 68, 11,1883-1887
[71] A. S. Luna, R.C.Campos R.E. Sturgeon, Chemical vapor generation: Atomic absorption by Ag, Au, Cu, and Zn following reduction of aquo ions with sodium tetrahydroborate(Ⅲ), Analytical chemistry, 2000, 72, 15,3523-3531
[72] M. Julieta, S. Patricia. Evaluation of vapor generation for the determination of nickel by inductively coupled plasma-atomic emission spectrometry. Analytical and Bioanalytical Chemistry, 2002, 374, 2, 196-202
[73] V.I.Rigin, G.N.Verkhoturov, Zh. Anal. Khim., 1977, 33, 1966-1971
[74] Y.H.Lin,Z.X.Zhuang,X.R.Wang,B.L.Huang, Proceeding of international Third Beijing Conference and Exhibitionon Instrumental Analysis, Beijing China,1989,22,112-15
[75] H.Lin,X.R.Wang,D.X.Yuan,P.Y.Yang,B.L.Huang,Z.X.Zhuang,J.Anal.At. Spectrom.,1992, 7, 287-289
[76] 陈德芳，李师鹊，戚苓，金念祖，汤国才，分析试验室，1990，9，63-65
[77] Y.H.Lin,Z.X.Zhuang,X.R.Wang,B.L.Huang,Proceeding of international Third Beijing Conference and Exhibitionon Instrumental Analysis, Beijing, China,1989,22, 112～15
[78] L..Lin,X.R.Wang,X.Yuan,P.Y.Yang,B.L.Huang,Z.X.Zhuang,. Anal.At.Spectrom.,1992,7, 287
[79] D. Schaumlfel, B. Neidhart, Fresenius' J.Anal.Chem., 1996,354, 866
[80] A. Brockman, C.Nonn, A.Golloch, J.Anal. At.Spetrom., 1993,8,397
[81] 孙汉文，原子光谱分析，2001，高等教育出版社
[82] H.W.Sun, J.Ha, J.M.Sun, D.Q.Zhang, L.L.Yang, Hydride generation for the direct determination of trace anf ultra-trace level of arsenic and antimony in waters using derivative atomic absorption spectrometry, Anal Bioanal Chem, 2002, 374,526-529
[83] H.W.Sun, J.Ha, J.M.Sun, Application of hydride generation atomic absorption spectrometry with derivative signal processing to direct determination of sub-parts-per billion level of bismuth and tin in water samples, Chemical Journal on Internet, 2003, 5, 26-31
[84] H.W.Sun, J.Ha, J.M.Sun, Derivative hydride generation spectrometry atomic absorption spectrometry and determination of lead traces in waters, Fresenius' J Anal Chem, 2001, 371, 1154-1157
[85] H.W.Sun, J.Ha, D.Q.Zhang, Determination of trace in urine by derivative generation atomic absorption spectrometry, Analytical Sciences, 2002, 18, 603-605
[86] J.Ha, H.W.Sun, J.M.Sun, Determination of tellurium in urine by hydride generation atomic absorption spectrometry with derivative signal processing, Analytica ChimicaActa, 2001, 448, 145-149
[87] R.W.Wood,, Phil. Mag., 1912, 23, 696-701
[88] A. L. L Hufhes,., A. R.Thomas, phys. Rev., 1927, 30, 466-472
[89] W. Ronald Hatch, L. Ott Welland, Determination of submicrogram quantities of mercury by atomic absorption spectrophotometry Anal. Chem., 1968; 40, 14,2085-2087
[90] J.Cacho, I.Beltran,, and C. Nerin,, J. Anal. At. Spectrom., 1989, 4, 661
[91] M. C. Valdés-Hevia y Temprano, M. R. Fernández de la Campa, and A. Sanz-Medel. Generation of volatile cadmium species with sodium tetrahydroborate from organized media: Application to cadmium determination by induvtively coupled plasma atomic emission spectrometry. J. Anal. At. Spectrom., 1993, 8, 9,847-852
[92] A.Sanz-Medel, MR Fernandez de la Campa, Valde's- Hevia MC, 1995, Anal Proc.,32, 49-54
[93] A. Sanz-Medel, M. C. Valdés-Hevia y Temprano, N. Bordel García, and M. R. Fernandez de la Campa. Generation of cadmium atoms at room temperature using vesicles and its application to cadmium determination by cold vapor atomic spetrometry. Anal. Chem., 1995, 67, 13, 2216-2223
[94] X.W. Guo, X.M. Guo. Determination of cadmium at ultra-trace levels by cold vapor atomic absorption spectrometry. J. Anal. At. Spectrom., 1995,10, 11, 987-991
[95] X. W. Guo, X. M. Guo. Studies on the reaction between cadmium and potassium tetrahydroborate in aqueous solutions and its application in atomic fluorescence spectrometry. Anal. Chim. Acta, 1995, 310, 2, 377-385
[96] T. J.Hwang, S. J. Jiang, Determination of Cadmium by Flow Injection Isotope
Dilution Inductively Coupled Plasma Mass Spectrometry With Vapour Generation Sample Introduction, J. Anal. At. Spectrom., 1997, 12, 579-584.
[97] 周焕英，徐淑坤，方肇伦，流动注射蒸气发生原子吸收光谱测定痕量铜，光谱学与光谱分析，2000，20，525-528．
[98] X. G. Du, S.K. Xu, Flow-injection chemical vapor-generating procedure for the determination of Au by atomic absorption spectrometry, Fresenius' J Anal Chem,2001, 370, 1065-1070
[99] 徐淑坤，刘梅英，徐章润，方肇伦，银的流动注射蒸气发生原子吸收光谱分析初步研究，1999，岩矿测试，18，15-18
[1] A.Walsh, Spectrom. Acta, 1955, 7, 108
[2] J.H. Watkinson, Fluorometric Determination of Selenium in Biological Material with 2,3-Diaminonaphthalene. Anal. Chem., 1966, 38, 92-97
[3] J. E. Allan, Spectrochim. Acta, 1962, 18,259
[4] S. Sprague, D. C. Manning and W. Slavin, At. Abs. Newsl., 1964, 20, 27
[5] C. S. Rann, A. N. Hambly, The determination of selenium by atomic absorption spectrophotometry, Anal. Chim. Acta, 1965, 32,346-354
[6] J. E. Allan, 4th Australian Spectroscopy Conference, Auguest, 1964
[7] W. B. Barnett, At. Abs. Newsl., 1973, 12, 142
[8] J. E. Allan, 4th Australian Spectroscopy Conference, Auguest, 1964
[9] W. B. Barnett, At. Abs. Newsl., 1973, 12, 142
[10] H. L. Kahn, J. E. Schallis, At. Abs. Newsl, 1968, 7, 5
[11] C. L. Chakrabarti, The atomic absorption spectroscopy of selenium, 1968, Anal.Chim. Acta, 42,379-387
[12] G. F. Kirkbrifht, L. Ranson, Use of the nitrous oxide-aceytlene flame for determination of arsenic and selenium by atomic absorption spectrometry, Anal.Chem., 1971, 43, 1238-1241
[13] S. Ng, M. Munroe, W. Mcsharry, J. Assoc. Off. Anal. Chemists, 1974, 57, 1260
[14] B. C. Severne, R. R. Brooks, Rapid determination of selenium and tellurium by atomic-absorption spectrophotometry, Talanta, 1972, 19, 1467-1470
[15] 华南师范大学学报(自然科学版)2000，1，77
[16] Simeonova S et al., Fresenius' Journal of Anal. Chem., 1986, 325(5), 478
[17] 刘锋，李玉环，刘群，萃取火焰原子吸收法测定高梁种皮中的硒，光谱学与光谱分析，2002，22，6，485-486
[18] J．E．坎特尔编，黄德玲等译，原子吸收光谱，科学文献出版社，267，1990
[19] Y.Z. Liang, M. Li, Z. Rao, Nickel and Strontium Nitrates as Modifier for the Determination of Selenium in Urine by Zeeman Platform Graphite-Furnace Atomic Absorption Spectrometry, Anal Sci, 1996, 12, 629-633
[20] Y.Z. Liang, M. Li, Z. Rao, Long-term sampling system for the measurement of ambient air concentrations of mercury at a contaminated site Fresenius' Journal of Analytical Chemistry, 1997, 357, 1, 112-116
[21] D. Ryszard, Determination of selenium in Solis by Slurry-Sampling Graphite-FurnaceAtomic-Absorption Spectrometry with Polytetrafluoroethylene as Silica Modifier, Fresenius' Journal of Analytical Chemistry, 2001,370, 7, 850-854
[22] P. Liu, L Wei., K. Matsumoto, K.Fuwa, Enhancement Effect of Palladium Addition in the Determination of Selenium in Organic-Matrix Solutions by Electrically Heated Carbon Furnace Atomic Absorption Spectrometry, Anal.Sci., 1985, 1, 3,257-261
[23] Norbert Szoboszlai, Erzsebet Andrasi, Zsolt Ajtony, Mikrochimica Acta, 2001,137, 1-2, 81-86
[24] 陈晋苏，药物分析杂志，1999年06期414
[25] Osamu Kujirai, Takeshi Kobayash, Talanta, 1983, 30(1): 9
[26] 潘娟瑛，王志伟，陈恒武，锌作为基体改进剂石墨炉原子吸收法测定废水中的硒，光谱学与光谱分析，1996，03，111-115
[27] 陈良壁，廖一平，光谱学与光谱分析，3(1)，58-59，1983
[28] 田笠卿，黄振中，陈逸君，环境化学，1989，8(4)，41
[29] 王和悦，华佩冬，杨英，重庆大学学报，10(2)，122-126，1987
[30] 章春星，氢化物-石墨炉原子吸收光谱法测定环境水样的痕量硒，厦门科技 2000m，S1，51-53
[31] B.Welz, G.Bosai, Sperling, M., J. Anal. At. Spectrom., 1992, 7, 505
[32] Deaker, M. Maher, W., J. Anal. At. Spectrom., 1995, 10, 423
[33] 谢文斌，姚金玉，马戈，光谱学与光谱分析，1998，18(6)，700
[34] 中国现代应药医学杂志，1998，15(6)，52
[35] 微波消解石墨炉原子吸收法测定食品中硒 吕建民，王向纯 中国公共卫生 2000年09期 800
[36] 杨锦发，苏瑞芳，理化检验(化学分册)，26(1)，36-37，1990
[37] Julijana Cvetkovi, Traje Stafilov, Dragan Mihajlovi, Fresenius J Anal Chem(2001) 370: 1077-1081
[38] 周世兴，林天立，钱军，林柱友，氢化物-电热原子吸收法测定人血清硒，环境监测管理与技术，1997，9，06，32-33
[39] 张宝贵，王燕，李桂春，魏红梅，王立世，冯建兴，南开大学学报(自然科学版)，1997，01，108-110
[40] O.Astrom, Anal.Chem., 54, 190, 1982
[41] 王秀，方肇伦，分析化学，14，738，1986
[42] H. Robberecht, R. Van Grieken, Talanta, 1982, 29,823
[43] Z. Fang, S. Xu, X. Wang and S. Zhang, Anal.Chim. Acta, 1986, 179, 325
[44] B.Welz, P.Stauss, Spectrochim. Acta, Part B, 48, 951, 1993
[45] A.Larraya, M.G. Cobo-Femandez, M.A. Palacios, C.Camara, Fresenius' Journal of Analytical Chemistry, 350, 12, 1994, 667-670
[46] 章开源，郭小伟，连续流动氢化物发生—原子吸收光谱法测定地质样品中痕量硒，分析试验室，1997，16，02，51-54
[47] R.E.Sturgeon, S.N.Willie, S.S. Berman, Anal. Chem., 57, 2311, 1985
[48] Zang,L., Ni,Z.M.,Shan,X.Q.,Spectrochim.Acta., 1989, 44B, 3,339
[49] 马玉平，流动注射氢化物石墨炉原子吸收法测定铅碲合金中微量硒，理化检验(化学分册)，1994，30，1，
[50] Effect of high salt concentrations on the determination of arsenic and selenium by
flow injection hydride generation electrothermal atomic absorption spectrometry,Robert Ⅰ. Ellis, Nils G.Sundin, Julian F. Tyson, et al., Analyst, 1998, 123,1697-1701
[51] Fernando Barbosa Jr., Samuel Simio de Souza and Francisco J. Krug, In situ trapping of selenium hydride in rhodium-coated tungsten coil electrothermal atomic absorption spectrometry, J. Anal. At. Spectrom., 2002, 17, 4, 382-388
[52] D.Q.Zhang, H.W.Sun, L.L.Yang, Fresenius' Journal of Analytical Chemistry, 1997,359, 6, 492-496
[53] R. Allabashi, J.Rendl, Validation of three atomic absorption'spectrometry methods for the determination of selenium-a comparative evaluation of performance characteristics, Fresenius' J Anal Chem, 357,1024-1028, 1997
[54] H.Narasaki, Determination of arsenic and selenium in fat materials and petroleum products by oxygen bomb combustion and automated atomic absorption spectrometry with hydride generation, Anal Chem. 1985,57, 13,2481-6
[55] M.R Rayman, F.R.Abou-Shakra, N.I.Ward, J.Anal.At. Spectrom., 1996, 11, 61,
[56] W.T. Buckley, J.J. Budac, D.V. Godfrey, K.M. Koenig, Determination of selenium by inductively coupled plasma mass spectrometry utilizing a new hydride generation sample introduction system, Anal Chem. 1992, 1,64,724-9.
[57] M.Gloria Cobo Fernandez, A.Maria, Flow-injection and continuous-flow systems fot the determination of Se (Ⅵ) and Se (Ⅳ) by hydride generation atomic absorption spectrometry with on-line prereduction of Se(Ⅵ) to Se (Ⅳ), Analytica Chimica Acta, 1993, 283,386-392
[58] J.Piwonka, G.Kaiser, G.Tolg, Determination of selenium at ng/g and pg/g levels by hydride generation atomic absorption spectrometry in biotic materials, Fresenius Z Anal Chem, 1985, 321,225-234
[59] M.Ohata, T.Ichinase, S.Atsuka, M.Chiba, N.Furuta, Isotope dilution analysis of Se in human blood serum by using high-power nitrogen microwave-induced plasma mass spectrometry coupled with a hydride generation technique, Anal Chem,1998, 70, 13, 2726-30.
[60] B.Welz, M.Melcher, Decomposition of marine biological tissues for determination of arsenic, selenium, and mercury using hydride-generation and cold-vapor atomic absorption spectrometries, Anal Chem, 1985, 57, 2, 427-31
[61] V.Krivan, J.Anal.At.Spetrom. 1992, 7,155
[62] L.Pitts, P.J.Worsfold, S.J.Hill, Analyst, 1994,119, 2785
[63] P.B.Stockwell, W.T.Corns, Analyst, 1994, 119,1641
[64] D.W.Bryce, A.Izquierdo, M.D.Luque de Castro, Analyst, 1995, 120, 2171
[65] J.M.G.Lafuente, M.L.F.Sánchez, A.Sanz-Medel, J.Anal.At Spectrom, 1996, 11,1163
[66] L.Pitts, A.Fisher, P.Worsfold, S.Hill, J.Anal.At.Spectrom. 1995, 10, 519
[67] R.M.Olivas, D.F.X.Donard, Microwave assisted reduction of SeⅥ to SeⅣ and determination by HG/FI-ICP/MS for inorganic selenium speciation, Talanta,1998,45, 1023-29
[68] D.L.Tsalev, M.Sperling, B.Welz, Analyst, 1992, 117,1729
[69] J.L.Burguera, P. Carrero, M.Burguera, C.Rondón, M;L.Brunetto, M.Gallignoni, Flow injection for the determination of Se(Ⅳ) and Se(Ⅵ) by hydride generation atomic absorption spectrometry with microwave oven on-line prereduction of Se(Ⅵ) to Se(Ⅳ), Spectrochim.Acta, PartB51, 1996, 1837-47
[70] 孙汉文，原子吸收光谱分析技术，中国科学技术出版社，北京，119
[71] B.Welz, M.Schubert,5ColloquiumAtomspektrometrischeSpurenanalytik(collected papers),B.Welz,Editor, Bodenseewerk Perkin-Elmer, 1989, 327
[72] 中国预防医学科学院劳动卫生与职业病研究所主编．车间空气监测检验方法，第3版，北京，人民卫生出版社，1990．180
[74] 陈俐娟，刘黎，李晖，用高灵敏度分光光度法测定海豚肝脏中的微量硒，四川大学学报(自然科学版)，2000，37，2，288-292
[73] J.L.Bemal, M.J.Del Nozal, L.J.Deban, Modification of the methylene blue method for spectrometric selenium determination, Talanta, 1990, 37, 931-6
[74] 陈思钦，傅毅华，曾希建，催化动力学光度法测定痕量硒，江西大学学报(自然科学版)，1989，13，3，36-40
[75] 刘锡钧，朱杰航，催化显色反应确定硒含量的探讨，海峡药学，2000，12，4，31-33
[76] 方文焕，吴绍祖，铁-硫氰酸盐-结晶紫体系离心光度法测定血清中铁分析化学，1996，24，12，1045-1048
[77] 方文焕，林志勇，吴绍祖．离心光度法测定酒中微量Zn的方法研究[J]．华侨大学学报(自然科学版)，1996，17，2，144-146
[78] 朱五瑞，任杰，江万权．萃取浮选光度法测定微量钼的研究及应用[J]．中国科学技术大学学报，1991，21，4，465-468
[79] 刘志明，刘嘉敏，李文辉．剂浮选吸光光度法测定痕量Au[J]．理化检验(化学分册)，1991，27，1，34-36
[80] 刘嘉敏，江惊奇，张敏，溶剂浮选吸光光度法测油品中痕量砷，理化检验(化学分册)，1999，35，9，428-430
[81] 杨开安，结晶紫萃取光度法测定催化裂化催化剂中微量锑，理化检验(化学分册)，1993，29，6，63-65
[82] 唐祖芬，施晰昕，铁(Ⅲ)的缔合型三元配合物显色反应的研究，华东冶金学院学报，1990，7，3，81-83
[83] 陈戈，范慧例，温美娟．硒(Ⅳ)-KI-结晶紫显色体系的研究，冶金分析，1998，18，3，9-12
[84] 裴世桥，陈友伟．结晶紫．锗钼酸流动注射光度法测定地质样品中锗，分析化学，1995，23，6，739-739
[85] 刘绍璞，刘忠芳．钒-硫氰酸盐-碱性三芳基甲烷染料的显色反应研究，高等学校化学学报，1989，10，8，800-801
[86] 冯胜，张学明．在增溶剂存在下硫氰酸盐-结晶紫光度法测定微量钨，分析化学，1989，17，9，820-22
[87] 陈兰化，陈新，IO~(-3)-I--结晶紫-阿拉伯胶体系分光光度法测定生物样品中的碘，分析科学学报，1996，12，4，329-32
[88] 吴亮船，高温合金中磷的测定磷锑钼杂多酸-结晶紫-PVA光度法，光谱实验室，1996，13，4，27-28
[89] 沈含熙，凌蓉．双显色剂高灵敏协同显色反应的研究：钴-亚硝基R盐-结晶紫体
体系，分析化学，1990，18，8，700-702
[90] 朱展才．以结晶紫与亚硝基R盐吸光光度法测定镍[J]．分析化学，1995，23，12，1444-46
[91] 朱展才，王杨春，胡建华．藉铋-亚硝基R盐-结晶紫反应高灵敏分光光度法测定痕量铋[J]．分析化学，1996，24，11，1269-71
[92] 陶慧林．聚乙烯醇和阿拉伯胶存在下用分光光度法测定铌[J]．桂林工学院学报，1995．15，4，392-5
[93] W. Holak, J. Specchio.Determination of selenium in food supplements by differential-pulse cathodic stripping voltammetry in the presence of added copper.Analyst. 1994,119, 10, 2179-82
[94] 夏静，檀华蓉，蔬菜中微量硒的比色测定，安徽农业科学 1997，25，3，278-279．
[95] A.G.Milovanovic, B.R. Petronijevic, M. M. Cakar, Kinetic Determination of Trace Levels of Selenium(Ⅳ) and Total Selenium by Nile Blue A/Hydrogen Peroxide Method, Mikrochimica Acta, 1998, 128, 1-2, 43-48
[96] L Johann. Fischer, Electothermal atomization of palladium stabilized selenium in the presence of phosphate, Spectrochimica Acta. Part B, Atomic Spectroscopy,2002, 57B, 3,. 525-533
[97] Q.H. Hu, L.C. Chen, J. Xu, determination of selenium concentration in rice and the effect of foliarapplication of Se-enriched fertiliser or sodium selenite on the selenium content of rice, Journal of the Science of Food and Agriculture,2002, 82, 8. 869-872
[98] W. Lei, G. Parul, H. Robert, Determination of Ultratrace Selenium and Arsenic at Parts-per-Trillion Levels in Environmental and Biological Samplesby Atomic Fluorescence Spectrometry with Flow InjectionHydride Generation Technique,Microchemical Journal, 1999, 62, 83-98
[99] L. Ga'miz-Gracia, M.D. Luque de Castro, Determination of selenium in nutritional supplements and shampoos by flow injection-hydride generation-atomic fluorescence spectrometry, Talanta, 1999, 50, 875-880
[100] R. Sabé, R. Rubio, Selenium determination in urine with atomic fluorescence detection, Analytica Chimica Acta, 2001,436, 215-221
[1] W. H. Allaway. E. E.Cary. The environmental background of selenium deficiency diseases-Foodstuffs. 1966, 38, 62-66
[2] P.R.Caffrey, G. D.Frankel, Selenite cytotoxicity in drug resistant and nonresistant human ovarian tumor cells, Cancer Res, 1992, 1, 52, 17, 4812-6
[3] V.N. Gladyshev, S.V.Khangulov, T.C. Stadtman. Properties of the selenium-and molybdenum-containing nicotinic acid hydroxylase from Clostridium barkeri.,Biochemistry. 1996,9, 35, 1, 212-23.
[4] S. C. Low., M. J. Berry, Knowing when not to stop: selenocysteine incorporation in eukaryotes, Trends Biochem Sci., 1996, 21, 6, 203-8
[5] 张克明，白遵彬，中国“硒与健康”数据库应用研究，环境科学学包，1989，9，1，42-49
[6] C.A.Girling, Selenium in agriculture and enbironment, Agriculture, Ecosystem, Enbironment. 1984, 11, 37-65
[7] 中国矿物岩石地球化学学会环境地质化学学会编，环境化学与健康，地震出版社，1990，222-225
[8] 王子健，彭安，分析化学，1988
[9] 彭安，王子健，P．D．Whanger等编，戏的环境生物无机化学，中国环境科学出版社，北京，1995，3-44
[10] 徐辉碧，黄开勋，硒的化学、生物化学及其在生命科学中的应用，华中理工大学出版社，1994，268-283
[11] 施和平，张英聚，刘振声，番茄对硒的吸收、分布和转化，植物学报，1993，35，7，541-547
[12] M.M. Abrams, C. Shennan, R.J. Zasoski, Selenomethionine uptake by wheat seedlings. Agron J, 1990, 82, 1127-1130
[13] A.Kabata, H.Pendias, Elements of group-Ⅵ.-In trace element in soils and plants,
CRC press, 1992, 217-225
[14] E.A.H,Pilon, S. Hwang, C.M.Lytle, Overexpression of ATP sulfurylase in Indian mustard leads to increased selenate uptake, reduction, and tolerance, Plant Physiol,1999, 119, 123-132
[15] D.C. Eustice, F.J. Kull, A.Shrift, Selenium toxicity: aminoacylation and peptide bond formation with selenomethionine, Plant Physiol, 1981, 67, 1054-58
[16] T.A. Brown, A. Shrift. Exclusion of selenium from proteins in selenium-tolerant Astragalus species, Plant Physiol, 1981, 67, 1951-53
[17] 冯昭扬，张英聚，中山大学硕士研究生毕业论文，1991
[18] J.T.Roruck. A.L.Pope, H.E.Ganther,, Selenium: biochemical role as a component of glutathione peroxidase, Science, 1973, 35, 2, 151-154
[19] J.Parizek, I.Ostadalova, The protective effects of small amounts of selenite in sublimate intoxication-Experientia, 1967, 23, 142-143
[20] 彭双清，刘世杰．镉对心肌细胞动作电位的影响及硒的保护作用．中华劳动卫生职业病杂志，1998，16，1，34-36
[21] 彭双清，刘世杰．镉对心肌细胞Ca~(2+) 通道的阻带作用及硒的保护效应．中华劳动卫生职业病杂志，1999，17，3，161-163
[22] 连祥霖，陈新春．硒对氯化汞免疫毒性的影响及其机理．卫生毒理学杂志，1998，12，2．89
[23] 李金有，刘志艳，孙天佑等，硒拮抗砷致小鼠微核率改变的剂量效应特征．中国地方病学杂志，1999，18，1，5-7
[24] R.L.Mikkelsen,H.F.wan,The effect of selenium on sulfur uptake by barelyandrice,Plant Soil, 1990, 121,151-153
[25] M.R Arvy, Selenate and selenite uptake and translocation in bean plants (Phaseolus vulgaris). J. Exp. Bot. 1993, 44, 1083-87
[26] E.E.Cary, Effect of selenium and cadmium additions to soil on their concentration in lettuce and wheat, J.Agron, 1981, 73,703-708
[27] 谭周磁，陈嘉勤，薛海霞，硒对降低水稻重金属Pb，Cd，Cr污染的研究，湖南师范大学(自然科学学报)，2000，23，3，80-83
[28] L.Tommy, G.Maria, Influence of selenium on uptake and toxicity of copper and cadmium in pea and wheat, Physiologia Plantarum, 1994, 90, 637-644
[29] Greene,J.C.etal. Protocols for short-term toxicity screening of hazardous waste sites[S]. US Environmental Protection Agency(EPA), 1998, 600/3-88/029
[30] International Or ganization for Standardization (ISO). Soil quality determination of the effects of pollutants on soil flora. Partl: method for the measurement of inhibition of root growth [S], ISO, 11269-11993
[31] OECD (Organization for Economic Cooperation and Development). OECD guide lines for testing of chemicals [S]. Paris. France: European Committee,1984.208-209.
[32] 孙赛初，王焕校，李启任，水生维管束植物受镉污染后的生理变化及受害机制初探，植物生理学报，1985，11，2，113-121
[33] 刘东华，蒋悟生，镉对洋葱根生长和细胞分裂的影响，环境科学学报，1992，12，4，439-446
[34] 段昌群，王焕校，重会属对蚕豆的细胞遗传学毒理作用和对蚕豆根尖微核技术的探讨，植物学报，1995，37，1，14-24
[35] 刘东华，蒋悟生，李懋学．镉对洋葱根生长和细胞分裂的影响．环境科学学报，1992，12，4，439-446
[36] 陈桂珠 重会属对黄瓜籽苗发育影响的研究，植物学通报，1990，7，1，34-39
[37] 龚雨松，李振国，余叔文，小麦幼苗镉螯合素，植物生理学报，1990，16，1，19-25
[38] M. Bartolf, E.Brennan, C.A.Price, Partical characterization of cadmium-binding protein from the root of cadmium treated tomato, Plant Physiol, 1980,66,434-441
[39] J.L.Casterliine, N.M.Barnett, Isolation and characterization of cadmium-binding components in soybean plants, Plant Physiol, 1977, 59, 5-124
[40] 赵博生，莫华，镉对蒜根生长的毒害及抗坏血酸、铁盐的解毒效应，武汉植物学研究，1997，15，2，167-172
[41] 柴之芳，祝汉民，微量元素化学概论，北京，原子能出版社，1994 268-270，112-115
[42] 中国科学院地理研究所环境与地方病组，营养学报，1982，4，3，85，103，209-214
[43] L.B Siburg, T, Mattern, J D Folts, U. M. Wiesgerber, M. B. Katan, Tea falvonoids and cardiovascular diseases, A review. J. Crit Rev Food Sci Nutr., 1997, 37,761-770
[44] H.Mukhtar, N. Ahmad, Green tea in chemoprevention of cancer. Toxocal Sci. 1999,52. 111-117
[45] Wang Z.Y, Agarwal R, Klan W.A., Mukhtar H., Carcinogenesis, 1992, 8,1491-1494
[46] 于新蕊，曲军，丛月珠等．茶叶的化学成分及药理作用研究进展，中草药，1995，26，4，219-221
[47] A.Finger, Chromatography of tes constituents, J. Chromatography, 1992, 624,293-296
[48] M.Simon, L.Horovaskal, Antihemolytic effect of rooibos tes on redblood cells of Japanese quails, ,Gen Physiol Biophys, 2000, 19, 4, 365-369
[49] 黄育华，张建军，晏雪生，等．富硒珍珠茶对人肝癌细胞株Bel-7402诱导分化的实验研究．中医研究，2000，13，2，25～28
[50] 阮宇成，茶叶中的硒及其与人体健康，中国茶叶，1987，5，10-11
[51] 陈宗憨，也谈茶硒素与人体健康，中国茶叶，1988，4，14-15
[52] 方兴汉，吴彩，沈星荣，从我国茶叶含硒量状况谈我国高硒茶的开发应用，中国茶叶，1990，6，6-8
[53] S.K.Lam, 9th Seah Cheng Siang Memotia Lecture: gastric cancer-where are we now? Ann Acad Med Singapore, 1999, 28, 6, 881-883
[54] 杜琪珍，沈星荣，方兴汉．茶叶中的硒成分分析，茶叶科学，1991，11，2，133～137
[55] I.Harrison, D.Littlejohn, G.S.Fell, Improved molecular fluorescence method for the determination of selenium in biological samples Analyst, 1996, 121, 1641
[56] V.Ducros, D.Ruffieux, N.Belin, A.Favier, Comparison of two digestion methods for the determination of selenium in biological samples. Analyst, 119, 1994, 1715
[57] R.Lobinski, Z. Marczenko, Comprehensive Analitical Cehrnistry Spectrochemical
Trace Analysis for Metals and Metalloids, Elsvier, Amsterdam, 1996, 649
[58] H.T.Delves. I.L.Shuttler, Atomic Absorption spectrometry, Elsevier. Amsterdam.1991,400
[59] R.Sabé, R Rubio, L.García-Beltrán, Study and comparison of several chemical modifiers for selenium determination in human serum by Zeeman electrothermal atomic absorption spectrometry, Analytica Chimica Acta, 1999. 398.2-3, 22.279-282
[60] Hernández-Caraballo, Edwin A.; Burguera, Marcela; Burguera, José L., Evaluation of ammonia as diluent for serum sample preparation and determination of selenium by graphite furnace atomic absorption spectrometry, Spectrochimica Acta Part B: Atomic Spectroscopy, 2002, 57, 2, 2159-2163
[61] H. J,Robberecht H.A Deelstra. Factors influencing blood seleniumconcentration values: a literature review. J Trace ElemElectrol Health Dis 1994, 8, 129-143
[62] Aaseth J, Smith-Kieland A, Thomassen Y. Selenium alcohol and liver diseases. Ann Clin Res 1986, 18, 43-47