玉米深加工过程废水处理及回用模式研究
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摘要
玉米深加工行业作为中国农业产业化的重点,存在着高能耗和高资源消耗、污染严重的节能和环保问题。如何有效实现生产过程中的废水循环利用,对玉米深加工产业的可持续发展具有很强的现实意义。然而,目前我国对玉米深加工行业废弃物资源化的技术开发与模式研究还很不全面,仅仅局限于一般性分析,缺乏对资源化技术和模式构建的深入探讨。
本研究以我国某典型玉米深加工企业为基本研究单元,利用产业生态学工具和高效厌氧好氧技术,对玉米深加工废水处理与回用技术进行研究。以厌氧数学模型ADM1和活性污泥数学模型ASM1为理论基础,建立了玉米深加工过程废水回用的数学模型。
利用物质流分析法(MFA)对典型玉米深加工企业生产引起的环境负荷进行了深入分析,明确了玉米深加工企业的物质流分析指标。根据得到的物质流模型构建结果与物质流分析指标,发现废水的资源化利用是企业环境管理的关键控制因素。得到物质需求总量强度账户TMR值为2.8118×107 t/a。
采用高效厌氧好氧技术“CSTR产酸发酵反应罐—UASBAF复合厌氧反应池—NMBR新型多级环流膜生物反应器”进行玉米深加工废水的中水回用中试研究,优化各个单元,使出水达到《生活杂用水水质标准》要求。CSTR产酸发酵反应罐启动成功后,平均COD去除率稳定在50%以上;BOD去除率平均值为49.1%。液相末端发酵产物以乙酸(800~1000 mg/L),丁酸(200~600 mg/L),丙酸(588 mg/L)和乙醇为主,为混合酸发酵类型。UASBAF复合厌氧反应池50d实现了快速启动,稳定运行期平均COD去除率为85.1%; BOD平均去除率达到84%;出水pH值稳定在6.5~7.0之间。NMBR新型多级环流膜生物反应器在HRT为18 h时,出水COD平均值是30.44 mg/L,BOD平均值是9.11 mg/L,pH平均值为6.85,氨氮平均值为15.01 mg/L,基本符合《生活杂用水水质标准》要求。整套玉米深加工废水中水回用工程建设总投资估算为7820.86元/吨水,去除单位COD的基建费用为940元/kg COD,吨水运行成本为2.38元/吨,每吨水收益为1.42元。
针对玉米深加工过程废水特点,以厌氧数学模型ADM1和活性污泥数学模型ASM1为理论基础,建立了玉米深加工过程废水回用的数学模型,模拟CSTR-UASBAF反应器和NMBR反应器的运行情况,确定了各反应器的适宜运行参数。
Corn deep processing industry, as focus of agricultural industrialization in China, not only is a high energy and resource consumption industry, but also is a seriously polluted industry. How to realize the waste resoure utilization, is very important to the sustainable development of corn deep processing industry. However, the research about waste resource utilization technology and mode of corn deep processing industry is underdevelopment.
This study was focus on treatment technologies of corn deep processing wastewater, using industry ecological tools and high effective aerobic and anaerobic technologies, and taking a corn deep processing plant located in China as basic unit. The mathematics model for resource recycling utilization of corn deep processing eco-industrial park wastewater was built, using anaerobic model ADM1 and active sludge model ASM1 as theoretical basis.
This study used material flow analysis (MFA) to analysis the pollution load of the typical enterprise. And MFA index was first determined in typical corn deep processing. That wastewater resource recycling utilization was the key controlling factor of enterprise environmental management was found by analyzing the obtained material flow mode and index. The TMR value of total material demands intensity account was 2.8118×107t/a.
A model project with“CSTR-UASBAF-NMBR”process was used for the resource recycling treatment of the corn deep processing wastewater. The effluent achieved“reused water quality standard”requests. After the start-up of Acidogenic phase finished, the average COD removal rate was above 50%, the average BOD removal rate was 49.1%. The aqueous terminal productions were acetic acid(800~1000mg/L), butyric acid(200~600mg/L), propionic acid(588mg/L) and ethanol. Fermentation type was the mixed acid type fermentation. After 50 days, the start-up of UASBAF finished, the average COD removal rate was above 85.1%, the average BOD removal rate was 84%, the average pH value was 6.5~7.0. When HRT is 18h, the average COD was 30.44mg/L, the average BOD was 9.11mg/L, the average pH value was 6.85, the average ammonia nitrogen was 15.01mg/L. The capital construction investment per COD removal was 940.007 Yuan /Kg COD; the operation cost was 2.38 Yuan per ton wastewater at formal operative period.
Based on the two phases anaerobic reactors and new membrane bioreactor process operations were simulated. The mathematics model for resource recycling utilization of corn deep processing eco-industrial park wastewater was built, using anaerobic model ADM1 and active sludge model ASM1 as theoretical basis.
本研究以我国某典型玉米深加工企业为基本研究单元,利用产业生态学工具和高效厌氧好氧技术,对玉米深加工废水处理与回用技术进行研究。以厌氧数学模型ADM1和活性污泥数学模型ASM1为理论基础,建立了玉米深加工过程废水回用的数学模型。
利用物质流分析法(MFA)对典型玉米深加工企业生产引起的环境负荷进行了深入分析,明确了玉米深加工企业的物质流分析指标。根据得到的物质流模型构建结果与物质流分析指标,发现废水的资源化利用是企业环境管理的关键控制因素。得到物质需求总量强度账户TMR值为2.8118×107 t/a。
采用高效厌氧好氧技术“CSTR产酸发酵反应罐—UASBAF复合厌氧反应池—NMBR新型多级环流膜生物反应器”进行玉米深加工废水的中水回用中试研究,优化各个单元,使出水达到《生活杂用水水质标准》要求。CSTR产酸发酵反应罐启动成功后,平均COD去除率稳定在50%以上;BOD去除率平均值为49.1%。液相末端发酵产物以乙酸(800~1000 mg/L),丁酸(200~600 mg/L),丙酸(588 mg/L)和乙醇为主,为混合酸发酵类型。UASBAF复合厌氧反应池50d实现了快速启动,稳定运行期平均COD去除率为85.1%; BOD平均去除率达到84%;出水pH值稳定在6.5~7.0之间。NMBR新型多级环流膜生物反应器在HRT为18 h时,出水COD平均值是30.44 mg/L,BOD平均值是9.11 mg/L,pH平均值为6.85,氨氮平均值为15.01 mg/L,基本符合《生活杂用水水质标准》要求。整套玉米深加工废水中水回用工程建设总投资估算为7820.86元/吨水,去除单位COD的基建费用为940元/kg COD,吨水运行成本为2.38元/吨,每吨水收益为1.42元。
针对玉米深加工过程废水特点,以厌氧数学模型ADM1和活性污泥数学模型ASM1为理论基础,建立了玉米深加工过程废水回用的数学模型,模拟CSTR-UASBAF反应器和NMBR反应器的运行情况,确定了各反应器的适宜运行参数。
Corn deep processing industry, as focus of agricultural industrialization in China, not only is a high energy and resource consumption industry, but also is a seriously polluted industry. How to realize the waste resoure utilization, is very important to the sustainable development of corn deep processing industry. However, the research about waste resource utilization technology and mode of corn deep processing industry is underdevelopment.
This study was focus on treatment technologies of corn deep processing wastewater, using industry ecological tools and high effective aerobic and anaerobic technologies, and taking a corn deep processing plant located in China as basic unit. The mathematics model for resource recycling utilization of corn deep processing eco-industrial park wastewater was built, using anaerobic model ADM1 and active sludge model ASM1 as theoretical basis.
This study used material flow analysis (MFA) to analysis the pollution load of the typical enterprise. And MFA index was first determined in typical corn deep processing. That wastewater resource recycling utilization was the key controlling factor of enterprise environmental management was found by analyzing the obtained material flow mode and index. The TMR value of total material demands intensity account was 2.8118×107t/a.
A model project with“CSTR-UASBAF-NMBR”process was used for the resource recycling treatment of the corn deep processing wastewater. The effluent achieved“reused water quality standard”requests. After the start-up of Acidogenic phase finished, the average COD removal rate was above 50%, the average BOD removal rate was 49.1%. The aqueous terminal productions were acetic acid(800~1000mg/L), butyric acid(200~600mg/L), propionic acid(588mg/L) and ethanol. Fermentation type was the mixed acid type fermentation. After 50 days, the start-up of UASBAF finished, the average COD removal rate was above 85.1%, the average BOD removal rate was 84%, the average pH value was 6.5~7.0. When HRT is 18h, the average COD was 30.44mg/L, the average BOD was 9.11mg/L, the average pH value was 6.85, the average ammonia nitrogen was 15.01mg/L. The capital construction investment per COD removal was 940.007 Yuan /Kg COD; the operation cost was 2.38 Yuan per ton wastewater at formal operative period.
Based on the two phases anaerobic reactors and new membrane bioreactor process operations were simulated. The mathematics model for resource recycling utilization of corn deep processing eco-industrial park wastewater was built, using anaerobic model ADM1 and active sludge model ASM1 as theoretical basis.
引文
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