铝箔亲水涂层底漆的研究
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摘要
本文采用半连续乳液聚合法制备了具有反应性微凝胶核的核/壳结构丙烯
酸酯乳胶底漆，着重考察了它的稳定性、耐碱性以及与面漆的协同性。研究了
乳化剂的种类、配比及用量对乳胶底漆稳定性的影响，确定出合适的配比及用
量，并采用复合引发剂来调节乳胶粒的形态结构；乳胶粘度的控制是不容忽视
的重要方面，因此，我们对影响乳液粘度的诸因素，如中和剂的选择、中和度、
壳层官能性单体的种类及含量等进行了研究，讨论了核内交联剂的种类、含量、
壳层单体组成等因素对丙烯酸酯微凝胶乳液底漆稳定性及物理化学性能的影
响，从对固化工艺参数的研究中筛选出理想的固化剂种类、固化温度和固化时
间；最后对底漆与亲水面漆的协同效应也进行了初步的探讨，为铝箔亲水涂层
体系的进一步开发开拓了研究思路。
In this paper, with semi-continuous emulsion polymerization, core-shell
structured acrylate emulsion primer with a reactive micro-gel structure was
synthesized. The stability and the alkali resistance of base coat, and also its
coordination with top coat were emphasized. The influences of the sort of
emulsifiers, their compounding ratio and their dosage on emulsion stability of base
coat were studied, and fitful emulsifiers dosage and compounding ratio were
established. The structure of emulsion colloid was adjusted by using compound
activators. Controlling over viscosity of emulsion should be given attention to. So,
the factors affecting the viscosity of emulsion, such as the choosing of
neutralization reagent, the neutralization extent, the sort and dosage of functional
monomer of the shell layer and so on, were taken into account. The choice and
dosage of crosslinkers of the core layer, the monomer composition of the shell layer
and curing condition, etc, which have effects on the stability and physicalehemistry
property of the acrylate micro-gel emulsion were also discussed here. how base coat
can coordinate with top coat having hydrophilic property was related to in the end,
which establishes the clew of further research on hydrophilic coat of aluminum
flake.
酸酯乳胶底漆，着重考察了它的稳定性、耐碱性以及与面漆的协同性。研究了
乳化剂的种类、配比及用量对乳胶底漆稳定性的影响，确定出合适的配比及用
量，并采用复合引发剂来调节乳胶粒的形态结构；乳胶粘度的控制是不容忽视
的重要方面，因此，我们对影响乳液粘度的诸因素，如中和剂的选择、中和度、
壳层官能性单体的种类及含量等进行了研究，讨论了核内交联剂的种类、含量、
壳层单体组成等因素对丙烯酸酯微凝胶乳液底漆稳定性及物理化学性能的影
响，从对固化工艺参数的研究中筛选出理想的固化剂种类、固化温度和固化时
间；最后对底漆与亲水面漆的协同效应也进行了初步的探讨，为铝箔亲水涂层
体系的进一步开发开拓了研究思路。
In this paper, with semi-continuous emulsion polymerization, core-shell
structured acrylate emulsion primer with a reactive micro-gel structure was
synthesized. The stability and the alkali resistance of base coat, and also its
coordination with top coat were emphasized. The influences of the sort of
emulsifiers, their compounding ratio and their dosage on emulsion stability of base
coat were studied, and fitful emulsifiers dosage and compounding ratio were
established. The structure of emulsion colloid was adjusted by using compound
activators. Controlling over viscosity of emulsion should be given attention to. So,
the factors affecting the viscosity of emulsion, such as the choosing of
neutralization reagent, the neutralization extent, the sort and dosage of functional
monomer of the shell layer and so on, were taken into account. The choice and
dosage of crosslinkers of the core layer, the monomer composition of the shell layer
and curing condition, etc, which have effects on the stability and physicalehemistry
property of the acrylate micro-gel emulsion were also discussed here. how base coat
can coordinate with top coat having hydrophilic property was related to in the end,
which establishes the clew of further research on hydrophilic coat of aluminum
flake.
引文
[1] 朱白度．江苏化工，1985，(3)：23．
[2] 虞兆年．涂料工艺(第二分册)，化学工业出版社，1996．
[3] 涂料工业，1984，(3)：30．
[4] 化工物资，1984，(3)：24．
[5] N.J. Abrecht, High Solid Coatings, 1982, Mar.:3.
[6] L.J. Carbo, High Solid Coatings, 1982, Sept.:15.
[7] 冉裕华，鲜祟元，李经．涂料工业，1983，(3)：1．
[8] 王永厚．涂料工业，1983，(3)：35．
[9] 洪啸吟，冯汉保编著．涂料化学，科学出版社，1997．
[10] 杉本俊夫．涂装涂料，1980，(324)：45．
[11] 涂料工业，1984，(3)：28．
[12] 张国铭译．涂料与应用，1989，18(2)：26．
[13] 刘淑霞，焦书科，高分子通报，1992，(1)：52．
[14] Takashi．特昭开，JP49-27407，1974．
[15] Hond,Hiroshi,Inafuku. 特昭开，JP55-25223,1980.
[16] 张子勇，李自法，梁华．涂料工业，1991，6：31．
[17] Proc. Water-Borne Highter solids Coat. Symp.,9.
[18] Proger. Org. Coat.,8,161-182.
[19] Gamer, Joseph L. US 3740367,1973.
[20] Kabushi, Kimiaki.特昭开,JP48-45529,1973.
[21] Peler, Alfred R.特昭开,JP52-14639,1977.
[22] Prog. in Organic Coatings, 1983, (11):205-218.
[23] Nippon Paint co. Ltd.特昭开,JP59-149914,1984.
[24] 焦书科，夏宇正，余鼎声．应用化学，1991，8(1)：60．
[25] Cheung Mo-fung. US 3919154,1974.
[26] Roqer M. Christenson. US 3079434,1958.
[27] 余樟清，李伯耿，潘祖仁．高分子通报，1999，(2)：22．
[28] Ceska G W. J Appl Polym Sci, 1974 Vol. 18(2):427.
[29] Journal of Applied Polymer Science, 1997(8):2343～2355.
[30] Greene B W. J Colloid and Interface Sci, 1973, Vol. 43(2):462.
[31] Greene B W.J Colloid and Interface Sci, 1973, Vol. 43(2):449.
[32] Guiziak L F. J Appl Polym Sci, 1963(7):2249.
[33] 刘淑霞，余鼎声，焦书科．高等学校化学学报，1992，9：1286．
[34] 林秀英，詹蟾龙，孙以实．涂料工业，1991，6：1．
[35] 钟安永，刘婷，陈德本等．高分子材料与工程，1995，11(5)：67．
[36] 黄继伟．涂料与应用，1994，1：14．
[37] 刘正平，刘风歧，罗晓韬等．涂料工业，1992，4：6．
[38] Lavric J,Sebenik A,Osredkar S.J coat Technol,1991,63(795):29.
[39] 李炎章，杨素英．涂料工业，1989，3：3．
[40] 王玲，王致禄，陈道义．黏合剂，1990，1：17．
[41] Magnet S,Guillot J,Guyot A,et al,Prog Org Coat,1992,20:73.
[42] 武利民，于在璋，李伯耿．涂料工业，1992，1：1．
[43] 陆荣，涂料工业，1986，6：10．
[44] 大森英三著．丙烯酸酯及聚合物一Ⅱ，化学工业出版社，1986．
[45] Min T J, Klein A, El-Aasser M S, et al.J Polym Sci Polym Chem Ed, 1983,21:2845.
[46] Ugelstad J, Mfutakama H R.J Polym Sci Polym Symp, 1985, 72:225.
[47] Markel M P, Dimonie V L, EL-Aasser M S, et al.J Polym Sci Polym Chem Ed, 1987,25:1419.
[48] EL-Aasser M S.J Polym Sci Polym Chem Ed, 1983,21:2363.
[49] Okubo M, Nakamura Y, Matsumoto T.J Polym Sci Polym Chem Ed, 1980,18:2451.
[50] 曹同玉，刘庆普，胡金生．聚合物乳液合成原理、性能及应用．化学工业出版社，1997，458—459．
[51] 潘祖仁．高分子化学，化学工业出版社．
[52] M.Okubo et al.,Jpolym.sci.pol Lett.Ed,20,45(1982).
[53] 徐德恒等译．功能性乳液乳胶，上海科学技术文献出版社，1989．
[54] Aihara T.et al.,prog.org.coat.,1986,14:103.
[55] 袁才登等．高分子通报，1999，1：66．
[56] 夏范武．涂料工业，1998，10．
[57] O.Hew.U.R.H and Walker T.,J.chem．soci，Febr.,1986,170,917.
[58] 恽魁宏主编．有机化学(第二版)，高等教育出版社．
[59] J.Coatings Technolog,1979,51(651),27.
[60] 清谷明弘，今井正也．住友轻金属技报，1989，30(1)：31．
[61] 赖德明，杨铮，陈德本．涂料工业，1989，3：2．
[2] 虞兆年．涂料工艺(第二分册)，化学工业出版社，1996．
[3] 涂料工业，1984，(3)：30．
[4] 化工物资，1984，(3)：24．
[5] N.J. Abrecht, High Solid Coatings, 1982, Mar.:3.
[6] L.J. Carbo, High Solid Coatings, 1982, Sept.:15.
[7] 冉裕华，鲜祟元，李经．涂料工业，1983，(3)：1．
[8] 王永厚．涂料工业，1983，(3)：35．
[9] 洪啸吟，冯汉保编著．涂料化学，科学出版社，1997．
[10] 杉本俊夫．涂装涂料，1980，(324)：45．
[11] 涂料工业，1984，(3)：28．
[12] 张国铭译．涂料与应用，1989，18(2)：26．
[13] 刘淑霞，焦书科，高分子通报，1992，(1)：52．
[14] Takashi．特昭开，JP49-27407，1974．
[15] Hond,Hiroshi,Inafuku. 特昭开，JP55-25223,1980.
[16] 张子勇，李自法，梁华．涂料工业，1991，6：31．
[17] Proc. Water-Borne Highter solids Coat. Symp.,9.
[18] Proger. Org. Coat.,8,161-182.
[19] Gamer, Joseph L. US 3740367,1973.
[20] Kabushi, Kimiaki.特昭开,JP48-45529,1973.
[21] Peler, Alfred R.特昭开,JP52-14639,1977.
[22] Prog. in Organic Coatings, 1983, (11):205-218.
[23] Nippon Paint co. Ltd.特昭开,JP59-149914,1984.
[24] 焦书科，夏宇正，余鼎声．应用化学，1991，8(1)：60．
[25] Cheung Mo-fung. US 3919154,1974.
[26] Roqer M. Christenson. US 3079434,1958.
[27] 余樟清，李伯耿，潘祖仁．高分子通报，1999，(2)：22．
[28] Ceska G W. J Appl Polym Sci, 1974 Vol. 18(2):427.
[29] Journal of Applied Polymer Science, 1997(8):2343～2355.
[30] Greene B W. J Colloid and Interface Sci, 1973, Vol. 43(2):462.
[31] Greene B W.J Colloid and Interface Sci, 1973, Vol. 43(2):449.
[32] Guiziak L F. J Appl Polym Sci, 1963(7):2249.
[33] 刘淑霞，余鼎声，焦书科．高等学校化学学报，1992，9：1286．
[34] 林秀英，詹蟾龙，孙以实．涂料工业，1991，6：1．
[35] 钟安永，刘婷，陈德本等．高分子材料与工程，1995，11(5)：67．
[36] 黄继伟．涂料与应用，1994，1：14．
[37] 刘正平，刘风歧，罗晓韬等．涂料工业，1992，4：6．
[38] Lavric J,Sebenik A,Osredkar S.J coat Technol,1991,63(795):29.
[39] 李炎章，杨素英．涂料工业，1989，3：3．
[40] 王玲，王致禄，陈道义．黏合剂，1990，1：17．
[41] Magnet S,Guillot J,Guyot A,et al,Prog Org Coat,1992,20:73.
[42] 武利民，于在璋，李伯耿．涂料工业，1992，1：1．
[43] 陆荣，涂料工业，1986，6：10．
[44] 大森英三著．丙烯酸酯及聚合物一Ⅱ，化学工业出版社，1986．
[45] Min T J, Klein A, El-Aasser M S, et al.J Polym Sci Polym Chem Ed, 1983,21:2845.
[46] Ugelstad J, Mfutakama H R.J Polym Sci Polym Symp, 1985, 72:225.
[47] Markel M P, Dimonie V L, EL-Aasser M S, et al.J Polym Sci Polym Chem Ed, 1987,25:1419.
[48] EL-Aasser M S.J Polym Sci Polym Chem Ed, 1983,21:2363.
[49] Okubo M, Nakamura Y, Matsumoto T.J Polym Sci Polym Chem Ed, 1980,18:2451.
[50] 曹同玉，刘庆普，胡金生．聚合物乳液合成原理、性能及应用．化学工业出版社，1997，458—459．
[51] 潘祖仁．高分子化学，化学工业出版社．
[52] M.Okubo et al.,Jpolym.sci.pol Lett.Ed,20,45(1982).
[53] 徐德恒等译．功能性乳液乳胶，上海科学技术文献出版社，1989．
[54] Aihara T.et al.,prog.org.coat.,1986,14:103.
[55] 袁才登等．高分子通报，1999，1：66．
[56] 夏范武．涂料工业，1998，10．
[57] O.Hew.U.R.H and Walker T.,J.chem．soci，Febr.,1986,170,917.
[58] 恽魁宏主编．有机化学(第二版)，高等教育出版社．
[59] J.Coatings Technolog,1979,51(651),27.
[60] 清谷明弘，今井正也．住友轻金属技报，1989，30(1)：31．
[61] 赖德明，杨铮，陈德本．涂料工业，1989，3：2．