福建生物能源树种的调查和筛选研究
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摘要
随着石油等非再生性化石能源不断枯竭,我国能源资源匮乏和能源结构不合理问题日益突出。我国已成为仅次于美国的世界第二大能源消耗国,能源对外依存度不断提高,石油安全问题十分突出,能源短缺已成为制约我国经济发展的瓶颈。因此,寻找可再生替代能源成为当前社会发展过程中急需解决的重大课题。生物能源是太阳能以化学能形式储存在生物中的一种能量形式,它是可再生的绿色生物能源,生物能源产业已成为近年来全球性的新兴产业。福建地处亚热带地区,能源植物资源丰富,但由于长期来缺乏对于能源植物资源的研究,导致对福建能源植物资源缺乏足够的了解,在生物能源开发中存在较大盲目性,极大地限制福建生物能源树种的开发。有鉴于此,本文通过对福建主要自然保护区的植物资源进行全面调查,研究福建油脂植物和薪炭树种的种类、数量、区域分布及利用状况;在此基础上,选择11种南方主要生物能源树种为研究对象,通过测定不同油脂植物种子形态、千粒重、含油率,油脂的折光率、水分及挥发物、酸值和脂肪酸组成等指标,进行南方主要生物能源树种的能源品质和能源成分的比较;然后采用层次分析法对南方主要生物能源树种进行综合评价,最终筛选出适合南方发展的生物能源树种,供南方地区推广应用。主要研究结果如下:
     1、通过调查发现:福建油脂植物资源共有87科217属320种,其中木本油脂植物占70.3%,主要集中在大戟科、樟科、木兰科、卫矛科、安息香科。含油率在40%以上的油脂植物有30科45属61种。木本植物是福建的主要油脂植物,在生物能源开发方面将发挥重要作用。其中竹柏、木腊树、猴欢喜、油茶、茶、三尖杉、草珊瑚、南五味子、深山含笑、瓜馥木、樟树等油脂植物在福建各地均有分布。
     2、通过调查发现:福建薪炭树种资源共有12科29种,主要集中在松科、桃金娘科、含羞草科、蝶形花科。在这些主要薪炭树种资源中,产量最高的是尾叶桉,最低的是湿地松;树高生长量最快的是窿缘桉,最慢的是木荷;轮伐期最长的是湿地松,最短的是桑树;热值最大的是马占相思,最小的是桑树。其中赤桉、栓皮栎、楝树、桑树适应范围较广,可在福建大范围栽种。
     3、南方不同油脂植物种子的物理特性存在明显差异。其中阴香种子的长径、乌桕种子的厚度、三年桐种子的短径变异系数的差异较大。11种不同油脂植物种子千粒重的大小排序为:三年桐>千年桐>麻疯树>竹柏>香樟>猴欢喜>阴香>山乌桕>乌桕>光皮树>黄连木,其中以三年桐、千年桐种子的千粒重较大,分别为3278.4g、2711.9g,黄连木种子的千粒重最低。不同油脂树种种子含油率的大小排序为:猴欢喜>阴香>竹柏>麻疯树>千年桐>山乌桕>黄连木>三年桐>乌桕>香樟>光皮树,其中以猴欢喜种子含油率最大,为65.94%,阴香次之,光皮树种子含油率最低。含油率是生物能源树种选择的首要目标,含油率高的植物在能源开发上具有较大发展潜力。
     4、南方不同油脂植物种实油的理化性质存在明显差异。其折光率大小排序为:乌桕舞>麻疯树>千年桐>竹柏>阴香>香樟>猴欢喜>山乌桕>三年桐>光皮树>黄连木;水分挥发物大小排序为:竹柏>香樟>三年桐>千年桐>麻疯树>猴欢喜>黄连木>阴香>乌桕>光皮树>山乌桕;酸值大小排序为:乌桕>麻疯树>三年桐>阴香>猴欢喜>山乌桕>香樟>竹柏>千年桐>光皮树>黄连木。
     5、南方不同油脂植物种实油的脂肪酸种类存在明显差异。其中脂肪酸种类最多的是光皮树,有13种,麻疯树和三年桐次之,均为11种,黄连木有10种,三乌桕和三年桐有9种,竹柏和猴欢喜7种,香樟和乌桕为6种,阴香最少,仅4种。不同油脂植物的主要能源成分明显不同,主要5种脂肪酸相对百分含量大小排序为:黄连木>麻疯树>千年桐>三年桐>光皮树>乌桕>山乌桕>竹柏>香樟>猴欢喜>阴香,其中黄连木高达80.95%,而且不同油脂植物种实油的碳链饱和度不同。竹柏的不饱和脂肪酸总量和单稀酸的相对含量均较高,分别为97.69%和96.57%;香樟、阴香和猴欢喜的不饱和脂肪酸总量较低,分别只有3.82%、2.26%、1.26%;乌桕的双稀酸和三稀酸含量较高,分别达到15.1%和16.4%,竹柏的双稀酸含量较少,为0.83%,山乌桕的三稀酸含量较少,只有0.07%。
     6、采用层次分析法分别从种子质量、含油品质、能源成分含量方面对南方不同生物能源树种进行综合评价,不同生物能源树种的综合得分排序为:黄连木>千年桐>麻疯树>光皮树>三年桐>山乌桕>乌桕>竹柏>阴香>猴欢喜>香樟。黄连木无论从种子的质量指标和含油品质,还是从能源成分含量来讲,均优于其他树种,因此黄连木较适合作为生物柴油树种;千年桐的综合评分排在第二,也适合作为生物柴油树种,但其种子油的饱和脂肪酸相对含量较高,油的黏度性较高,生产柴油会给加工带来一定难度;麻疯树和光皮树在含油品质和能源成分等方面也较好;山乌桕种子各方面的品质均符合生物柴油树种开发的要求,具有一定的发展潜力。乌桕种子的三稀酸含量较高,所生产的生物柴油氧化性较强,会导致油的稳定性较低;阴香、猴欢喜和香樟种实的主要能源成分较低,生物柴油开发潜力不高。因此根据以上研究结果,适合南方生产上应用的生物能源树种为黄连木、麻疯树、光皮树、山乌桕、千年桐、三年桐、乌桕,其中以黄连木、麻疯树和光皮树为首选树种。
Along with oil and other non-renewable fossil energy constantly exhausted,energy resources are scarce in China,energy irrational structure has become increasingly conspicuous. China has become the world's second largest energy consumption country after the United States,and our dependence on foreign energy continues to increase.At present,oil security is very conspicuous in China,and energy shortages have become the bottleneck which restrictes Chinese economic development.So finding clean alternative renewable energy has become the much-needed socio-economic development process of resolving the major issues.
     Bioenergy is form of chemical energy existing in biology,which is a kind of renewable green biological energy.Bioenergy is a new global industry in recent years.Fujian is situated in the subtropical area,and it is rich in energy plan resources.Because of the lack of study on bioenergy resources in the long-time,we have larger blindness in the development of biomass energy,and it has greatly restricted the development of bioenergy trees in Fujian.By the comprehensive system investigation of the plant resources in Fujian main nature protection areas,we study on counting the species,distribution area and utilization condition of the oil plant and firewood carbon tree in Fujian.After this,main 11 kinds of bioenergy trees in south China are chosen as objects of study,determines the seed physical form,1000-grain weight, oil content,the seed oil of water and volatile matter content,acid value and refractive index, composition of fatty acid of seed oil of these threes,comparatively study on energy quality and energy composition;Finally comprehendsive evaluation with analytical hierarchy process is carried on main bioenergy trees in south China which is suitable for the southern area for extension.The main research results are as follows:
     1.Through investigation,the resources of vegetable fat and oil plants belong to 87 families,217 genera and 320 species.Woody plants take 70.3%of them.They mainly concentrate in Euphorbiaceae,Lauraceae,Magnoliaceae,Celastraceae,Styracaceae.There are 30 families,45 genera and 61 species,the oil content of which is over 40%.Woody plants are the main vegetable fat and oil plants in Fujian Province and play an important role in the utilization of biological energy production.Some vegetable fat and oil plants are distributed over the whole Fujian,which are Podocarpus nagi,Toxicodendron sylvestre,Sloanea sinensis, Camellia oleifera,Camellia sinensis,Cephalotaxus fortunei,Sarcandra glabra,Kadsura longipe dunculata,Michelia,maudiae,Fissistigma,oldhami,Cinnamomum camphora.
     2.Through investigation,the species of fuel-forest trees belong to 12 families,29 species. They mainly concentrate in Pinaceae,Myrtaceae,mimosaceae,Papilionacea e.Among these main fuel-forest trees,the yield of Casuarina equisetifolia is the highest and Pinus elliottii is the lowest.The fastest annual growth of height are Melia azedarach and the slowest is Acacia crassicarpa.The longest rotation species is Pinus elliottii and the shortest is Morus alba. Calorific value of Acacia mangium is higest and Morus alba is the lowest.The wide adaptation range of them are Eucalyptus camaldulensis,Quercus variabilis,Melia azedarach, Morus alba,which can be planted in large range.
     3.Seeds of different vegetable fat and oil plants in South China,the variation coefficients among Cinnamomum burmannii'length-diameter,Sapium sebiferum'thickness and Vernicia fordii'short diameter on the physical characteristics are larger than others 1000-grain weight of sorting of different vegetable fat and oil plants is as follows:Vernicia fordii>Aleurites montana>Jatropha curcas>Podocarpus nagi>Cinnamomum camphora>Sloanea sinensis>Cinnamomum burmannii>Sapium discolor>Sapium sebiferum>Cornus wisoniana>Pistacia chinensis.Vernicia fordii and Vernicia montana have higher 1000-grain weight,3278.4 g for Vernicia fordii and 2711.9 g for Vernicia montana.1000-grain weight of Pistacia chinensis is the lowest.The oil content of different vegetable fat and oil plants makes a great difference. Sorting of the oil content is as follows:Sloanea sinensis>Cinnamomum burma nnii>Podocarpus nagi>Jatropha curcas>Aleurites montana>Sapium discolor>Pistacia chin ensis>Vernicia fordii>Sapium sebiferum>Cinnamomum camphora>Cornus wisoniana.The oil content of Sloanea sinensis is 65.94%as the maximum;The second one is Cinnamomum burmannii; The least one is Comus wisoniana.To the selection of biological energy tree species, oil content is the primary goal.Tree species with high oil content have a great potential for deve- lopment on energy utilization.
     4.Physicochemical property of variety of different vegetable fat and oil plants in South China exists obvious difference.Sorting of refractive index is as follows:Sapium sebiferum >Jatropha curcas>Aleurites montana>Podocarpus nagi>Cinnamomum burmannii>Cinnamomum camphora>Sloanea sinensis>Sapium discolor>Vernicia fordii>Cornus wisoniana>Pistacia chinensis.Sorting of water volatile compounds is as follows:Podoca rpusnagi>Cinnamomum camphora>Vernicia fordii>Aleurites montana>Jatropha curcas>Sloaneasinensis>Pistacia chinensis>Cinnamomum burmannii>Sapium sebiferum>Cornus wisoniana>Sapium discolor;Sorting of acid value is as follows:Sapium sebiferum>Jatropha curcas>Vernicia fordii>Cinnamomum burmannii>Sloanea sinensis>Sapium discolor>Podocarpus nagi>Aleurites montana>Cornus wisoniana>Pistacia chinensis.
     5.Fatty acids of variety of different vegetable fat and oil plants in South China exists obvious difference.Cornus wisoniana,which is the most one,has 13 kinds of fatty acids; Jatropha curcas and Vernicia fordii which both has 11 kinds are secondary;Pistacia chinensis has 10kinds.Sapium discolor and Aleurites montana have 9 kinds.Podocarpus nagi and Sloanea sinensis have 7 kinds.Cinnamomum camphora and Sapium sebiferum have 6 kinds. Cinnamomum burmannii has the least for 4 kinds.Energy composition of variety of different vegetable fat and oil plants is different.Sorting of the relative percentage content of the main 5 kinds of fatty acids is as follows:Pistacia chinensis>Jatropha curcas>Aleurites montana>Vernicia fordii>Cornus wisoniana>Sapium sebiferum>Sapium discolor>Podocarpus nagi>Cinnamomum camphora>Sloanea sinensis>Cinnamomum burmannii.Pistacia chinensis reaches a maximum of 80.95%.Carbon chain saturation of variety of different vegetable fat and oil plants is different.Relative percentage content of unsaturated fatty acid and monoenoic acid of Podocarpus nagi is 97.69%and 96.57%,which is higher.Total amount of unsaturated fatty acid of Cinnamomum camphora,Cinnamomum burmannii and Sloanea sinensis is merely 3.82%,2.26%,1.26%,which is lower.The content of Two-acid and three-acid is 15.1%,and 16.4%,which is higher.The content of two-acid of Podocarpus nagi is 0.83%,which is lower.The content of three-acid of Sapium discolor is merely 0.07%, which is lower.
     6.By analytic hierarchy process(AHP)from the view of seed quality,oil quality and energy compositioa content,we evaluated variety of bioenergy tree species in South China and got the sorting by the scores of different tree species as follows.Pistacia chinensis>Aleurites montana>Jatropha curcas>Cornus wisoniana>Vernicia fordii> Sapium discolor>Sapium sebiferum>Podocarpus nagi>Cinnamomum burmannii>Sloanea sinensis>Cinnamomum cam- phora.Pistacia chinensis is superior to other species no matter the seed and oil quality,or energy composition content.Thereby,it is suitable for biodiesel tree species.Jatropha curcas and Cornus wisoniana are nice in many aspects.Aleurites montana takes the second place and is also suitable for biodiesel tree species.Whereas saturated fatty acid and viscosity of oil of its seeds is high that will bring certain difficulty. The biodiesel produced from Sapium sebiferum is with high oxidation and low stability because of the three-acid of Sapium sebiferum.The main energy composition of biodiesel produced from Cinnamomum burmannii,Sloanea sinensis and Cinnamomum camphora is low and has low development potential.Quality of each aspects of Sapium discolor accord with the biodiesel require.According to the result of the research,screening results of bioenergy tree species suitable for biodiesel are Pistacia chinensis,Jatropha curcas,Cornus wisoniana,Sapium discolor,Aleurites montana and Vernicia fordii.Preferred tree species are Pistacia chinensis,Jatropha curcas and Cornus wisoniana.
引文
[1]沈珺珺,迟晓元,杨庆利,等.生物柴油的研究进展[J].中国生物工程杂志,2006,26(11):87-90.
    [2]吴鹏飞,马祥庆,王平.我国发展生物能源树种原料林的潜力和对策[J].亚热带农业研究,2007,3(2):125-128.
    [3]梁磊.能源植物的开发和利用[J].宁夏农林科技,2006,(5):75-76.
    [4]蒋剑春.生物质能源应用研究现状与发展前景[J].林产化学与工业,2002,22(2):76-80.
    [5]Biomass research and development technical advisory committee.Vision for bioenergy and biobased products in the United States[R].Prepared by U S.Department of Energy and U.S.Department of Agriculture,2002.
    [6]Martini W,Schell.Plant oils as fuels:Present State of Science and Future Development[M].New York:Springer Verlag Berin Heldeberg,1998,1-12.
    [7]Demirbas A.Energy balance,energy sources,energy policy,future developments and energy investments in Turkey[J].Energy Conversion and Management,2001,42(10):1239-1258.
    [8]王平,马祥庆.生物能源的开发利用及生产技术研究进展[J].亚热带农业研究,2007,3(4):313-316.
    [9]Hatje W,Ruhl M,Huttl R F,et al.Use of biomass for power and heat generation:possibilities and limits[A].Forests and energy.1st Hanover EXPO 2000 World Forest Forum Selected papers[C].Ecological-Engineeing International Forest Communicators Forum(ICIFC),2000.
    [10]Siren G,Mitchell C P.Forest energy and the fuelwood crisis[M].Meeting in Uppsala Sweden,1984,8.
    [11]Schafer A.Vegetable oil fatty acid methyl esters as alternative diesel fuels for commercial vehicles engines[J].Plant Oil Fuel Proc Syrup,1987,17(4):29-46.
    [12]郑传贵.世界石油地缘政治格局新态势与中国石油进口安全[J].北京石油管理干部学院学报,2007,(6):11-17.
    [13]董继斌.能源社会学[M].山西:书海出版社,2005,9.
    [14]顾钢,毛宗强,张晶,等.2004年世界能源发展总体态势[J].高科技与产业化,2005,(4):9-11.
    [15]陈惠.经济全球化背景下中国的国际能源战略和石油外交[J].中国报道,2006,(5):28-30.
    [16]皮庆.中石油安全呼唤石油外交[J].中国高科技与产业化,2005,(3):58-60.
    [17]郑勇奇.木质生物质能源的开发利用现状与展望[J].林业调查规划,2007,32(1):90-94.
    [18]Cook J,Beyea J.Bioenergy in the United States:progress and possibilities[J].Biomass and Bioenergy,2000,18(6):441.
    [19]Ayhan D.Biomass resource facilities and biomass conversion processing for fuels and chemical[J].Energy conversion and management,2001:1357-1378.
    [20]Calvin M.Petroleum plantations for fuel and materials[J].Bioscience,1979,29(9):533-538.
    [21]蒋建新,陈晓阳.能源林与林木生物转化能源化研究进展[J].世界林业研究,2005,18(6):39-44.
    [22]Antal M.Hydrogen production from high moisture content biomass in supercritical water[J].Proc USDOE Hydrogen Program Rev,1996,(1):499-511.
    [23]万劲,方升佐.能源林的发展概述[J].现代农业科技,2006,(10):14-17.
    [24]关百钧.世界森林能源现状与发展趋势[J].世界林业研究,2000,13(6):1-6.
    [25]汪大纲.世界生物质能利用的现状和展望[J].世界林业研究,1996,(6):64-69.
    [26]Arai K.Conversion of polymer sand biomass to chemical inter mediate switch supercritical water[J].Macromol,1998,(135):205-214.
    [27]Auiri M.Effect of catalyst addition on colique faction process of coal and biomass in wupercritical water[J].Sekitan Kagakn Kaigi Happyo Ronbunshu,1997,(34):69-72.
    [28]ConneiiI M G.Carbon sequestration and biomass energy offset:theoretical,potential and achievable capacities globally,in Europe and the UK[J].Biomass and Bioenergy,2003,24(2):97-116.
    [29]孙蔡盛,蒋家淡,周敦强,等.桉树的开发利用[J].武夷科学,2006,22(12):232-236.
    [30]陈苏根.树木石油异军突起[J].发明与创新,2004,(4):24.
    [31]宋永芳.能源植物的开发与利用进展[J].生物质化学工程,2006,40(6):51-53。
    [32]费世民,张旭东,杨灌英,等.国内外能源植物资源及其开发利用现状[J].四川林业科技,2005,26(3):20-26.
    [33]王涛.中国主要生物质燃料油木本能源植物资源概况与展望[J].科技导报,2005,23(5):12-14.
    [34]贾虎森,许亦农.生物柴油利用概况及其在中国的发展思路[J].植物生态学报,2006,30(2):221-230.
    [35]谷战英,谢碧霞.木质生物能源发展现状与前景的研究[J].经济林研究,2007,25(2):88-91.
    [36]盂凡清,王德民,张大年.生物柴油技术在国内的研究进展[J].上海化工,2003,(12):30.
    [37]钱伯章.生物柴油生产的现状及技术进展[J].节能环保,2006,(1):15-18.
    [38]陈晓阳.发挥灌木优势,推动我国能源林业的发展[J].北京林业大学学报(社会科学版),2006,5(3):65-68.
    [39]Willebrand E,Ledin S,Verwijst T.Willow coppice systems in short rotation forestry[J].Biomass and Bioenergy,1993,(4):323-331.
    [40]方升佐,黄宝龙.瑞典柳树能源林的研究及发展概况[J].世界林业研究,1997,(3):66-71.
    [41]尚华.瑞典可再生能源研究开发利用现状[J].全球科技经济瞭望,1999,(2):32-33.
    [42]何祯祥,王伟.中国能源林业研发现状与发展策略[J].林业科技开发,2006,20(4):8-11.
    [43]张建国.中国薪炭林培育技术[C].中国林业生物质能源发展研讨会论文集.北京:国家林业局,2006.
    [44]黄素逸,高伟.能源概论[M].北京:高等教育出版社,2004.
    [45]张志达,等.中国薪炭林发展战略[M].北京:中国林业出版社,1996.
    [46]杨克美,何小东,唐伟.生物质能在农村能源中的地位与薪炭林建设[J].安徽农业科学,2001,29(1):103-105.
    [47]杨克美.多用途薪炭林的经营与利用[J].林业科技通讯,1994,(8):23-24.
    [48]王文烂.中国薪材利用的影响因素分析农业资源与环境科学[J].中国农学通报,2007,23(12):386-390.
    [49]全国薪炭林研讨会文集[M].北京:中国林业出版社,1995:189-199.
    [50]张均.从农村能源结构的变化看薪炭林建设如何发展[J].农村能源,1997,(1):30-31.
    [51]林逸.中国薪炭林建设成效与基本经验[J].农村能源,1996,(4):21.
    [52]Cannell M G R.Short rotation forestry for biomass production[M].Enlyclopedia of forest science[C].Canada:Elsevier,2004:872-877.
    [53]红岩.世界生物质能发展情况一览[J].今日国土,2007,(5):20-22.
    [54]姜书,宋维明.芬兰的林木生物质能源概况[J].世界林业研究,2007,20(3):61-64.
    [55]McKendry P.Energy production from biomass(partl):overview of biomass[J].Bioresource technology,2002,83:37-46.
    [56]Eric D,Larson.Technology for Electricity and Fuels from Biomass[J].Annu Rev Energy Environ,1993,(18):567-630.
    [57]Ericsson K,Nilsson L.Assessment of the potential biomass supply in Europe using a resource-focused approach[J].Biomass and Bioenergy,2006,30(1):1-15.
    [58]Janet N.Biomass inenergy,especially in the state of Brandenburg,Germany[].Ecological Engineering,2000,16:103-110.
    [59]Patel A,Hossaert M,McKdy D.Ficus-pollinator research I India.Past,present and future[J].Current Science,1993,65(3):243-253.
    [60]康树珍,贾黎明,彭祚登,等.燃料能源林树种选育及培育技术研究进展[J].世界林业研究,2007,20(3):27-33.
    [61]韩伟.国能生物的速度和创新[J].关注,2007,8(12):98-99.
    [62]黄家铭,唐忠.福建林业产业发展若干问题的思考[J].中国林业产业,2006,(10):28-30.
    [63]徐益良,林雅秋,林宇,等.21世纪福建林业产业发展趋势与结构调整[J].林业经济问题,2001,21(4):193-196.
    [64]国家林业局森林资源管理司.全国森林资源统计(1994-1998)[R].2000.
    [65]林鹏,李振基,张健.福建君子峰自然保护区综合科学考察报[M].厦门:厦门大学出版社,2005.
    [66]林鹏.福建茫荡山自然保护区综合科学考察报告[M].厦门:厦门大学出版社,2003.
    [67]林鹏.福建省自然保护区综合科学考察系列报告[M].厦门:厦门大学出版社,2001.
    [68]林鹏.福建省南靖南亚热带雨林自然保护区科学考察报告[M].厦门:厦门大学出版社,1999.
    [69]林鹏.福建粱野山自然保护区综合科学考察报告[M].厦门:厦门大学出版社,2001.
    [70]林鹏.福建天宝岩自然保护区综合科学考察报告[M].厦门:厦门大学出版社,2002.
    [71]林鹏.福建闽江源自然保护区综合科学考察报告[M].厦门:厦门大学出版社,2003.
    [72]李振宇.龙栖山植物[M].北京:中国科学技术出版社,1994:64-77.
    [73]林鹏.福建戴云山自然保护区综合科学考察报告[M].厦门:厦门大学出版社,2003.
    [74]刘玉宝,陈世品.福建鸳鸯猕猴自然保护区经济植物资源调查[J].林业科技开发,2005,19(6):19-22.
    [75]陈瑞炎.福建永安经济植物资源及可持续发展对策[J].福建林学院学报,2002,22(4):381-384.
    [76]刘碧云.福建省国家重点保护野生植物的分布与保护对策[J].福建林业科技,2004,31(3):61-65.
    [77]郑成洋.福建武夷山自然保护区珍稀、濒危和特有植物及其分布[J].福建林业科技,2003,30(3):54-58.
    [78]郑世群,林向东,郑清芳.尤溪九阜山自然保护区珍稀濒危植物[J].福建林学院学报,2003,23(3):206-209.
    [79]刘剑秋,陈炳华、方玉霖,等.福建闽江源自然保护区野生经济植物资源[J].亚热带植物科学,2002,31(2):30-34.
    [80]周清炜.福建梅龙山国家级自然保护区种子植物区系研究[J].林业调查规划,2004,29(4):27-29.
    [81]林益明,郭启荣.林鹏.福建安溪云中山自然保护区植物区系地理研究[J].厦门大学学报(自然科学版),2002,41(5):565-569.
    [82]陈继军.雷公山自然保护区的保护植物[J].黔东南民族师范高等专科学校学报,2005,23(3):31-32.
    [83]黄传忠,翁友恒.浅谈福建省野生植物资源的保护与合理开发[J].中南林业调查规划,2001,20(3):31-33.
    [84]谢大显.福建牛姆林自然保护区野生油脂植物资源及其开发利用[J].亚热带植物科学,2007,36(1):59-62.
    [85]苏小青,郑世群.福建省的国家重点保护野生植物资源及其价值[J].国土与自然资源研究,2001,(2):79-80.
    [86]杨忠兰.福建省野生动植物资源的合理开发利用构想[J].林业勘察设计,2003,(1):30-32.
    [87]郑群瑞.万木林自然保护区珍稀特有野生植物[J].福建林学院学报,1999,19(1):69-72.
    [88]福建省科学技术委员会.武夷山自然保护区科学考察报告集[M].福州:福建科学技术出版社,1993:1-13.
    [89]福建省科学技术委员会.福建植物志(1-6卷)[M].福州:福建科学技术出版社,1985-1995.
    [90]林鹏.福建植被[M].福州:福建科学技术出版社,1990:51-252.
    [91]中国油脂植物编委会.中国油脂植物[M].北京:科学出版社,1987.
    [92]高尚武,马文元.中国主要能源树种[M].北京:中国林业出版社,1990.
    [93]林馗.福建天宝岩自然保护区植物资源的现状与保护对策[J].亚热带农业研究,2007,3(1):77-80.
    [94]巫淼鑫,邬国英,韩瑛,等.6种食用植物油及其生物柴油中脂肪酸成分的比较研究[J].中国油脂,2003,28(12):65-67.
    [95]Hastert R C,Baldwin A R.Proceeding of world conference on emerging technologies in the fats and oils industry[J].Chain Paign,1986,26(8):56-60.
    [96]Liu X M,Wang L S.A one-pot synthesis of oleic acid end-capped temperature and pH-sensitive phiphilic polymers[J].Biomaterials,2004,16(4):29-36.
    [97]于海芹,张天柱,魏春雁,等.3种碱蓬属植物种子含油量及其脂肪酸组成研究[J].西北植物学报,2005,25(10):2077-2082.
    [98]Schumacher L G,Borgelt S C,Fosseen D,et al.Heavy duty engine exhaust emission tests using methyl ester soybean oil/dieselfuel blends[J].Bioresource Technology,1996,57(1):31-36.
    [99]Alcantara R,Amores J,Canoira L,et al.Catalytic production of biodiesel from soybean oil,used frying oil and tallow[J].Biomass and Bioenergy,2000,18(6):515-527.
    [100]Antolin G,Tinaut F V,Briceno Y,et al.Optimization of biodiesel production by sunflower oil transesterification[J].Bioresource Technology,2002,83(2):111-114.
    [101]Mohamad I A W,All O A.Experimental evaluation of the transesterification of waste palm oil into biodiesel[J].Bioresource Technology,2002,85(3):253-256.
    [102]Saka S,Kusdiana D.Biodiesel fuel from rapeseed oil as prepared in supercritical methanol[J].Fuel,2001,80(2):225-231.
    [103]Mamoru I,Baoxue C,Masahi E,et al.Production of biodiesel fuel from triglyceride and alcohol using immobilized lipase[J].Journal of Molecular Catalysis B:Enzymatic,2001,16(1):53-58.
    [104]弓成林,郭爱民,汪小伟,等.灰色关联度和层次分析法在葡萄品质评价上的应用[J].西南农业学报,2002,15(1):79-82.
    [105]蒋文伟,向其柏.层次分析法在干旱区园林树木评选中的应用[J].南京林业大学学报,2000,24(6):63-67.
    [106]赵焕臣层次分析法——种简易的新决策方法[M].北京:科学出版社,1972:244-259.
    [107]舒卫萍,崔远来.层次分析法在灌区综合评价中的应用[J].中国农村水利水电,2005,(6):109-111.
    [108]郑德样,陈平留.层次分析法在防火树种选择中的应用[J].北华大学学报,2000,1(5):443-446.
    [109]韩中庚.数学建模方法及其应用[M].北京:高等教育出版社,2005.
    [110]姜启源,谢金星,叶俊.数学模型[M].北京:高等教育出版社,2003.
    [111]李昌珠,蒋丽娟,程树琪.生物柴油——绿色能源[M].北京:化学工业出版社,2005:197-223.
    [112]刘鸿声,李红敏.折光指数法测定掺伪油脂的含量[J].粮油仓储科技通讯,1999,(5):51-52.
    [113]郭登峰,盛梅,罗士平.气相色谱法测定生物柴油中多种脂肪酸甲酯[J].中国油脂,2004,29(4):44-46.
    [114]李玉芹,曾虹燕.生物柴油中脂肪酸甲酯成分的气相色谱法测定[J].海南大学学报自然科学版,2005,23(4):324-326.
    [115]刘友多.福建省发展油料能源林的对策研究[J].中南林业调查规划,2006,25(2):10-12.
    [116]Gryglewicz S.Rapeseed oil methyl esters preparation using heterogeneous catalysts[J].Bioresource Technology,1999,70:249-253.
    [117]王璇,冀星.国内外生物柴油技术进展[J].国际化工信息,2006,(4):13-17.
    [118]郭萍梅,黄凤洪,黄庆德.高酸值废弃油脂转化生物柴油的技术研究[J].中国油脂,2006,31(7):66-69.
    [119]黄小明,谢文磊,彭红,等.生物柴油的标准和质量控制[J].粮油食品科技,2005,(3):42-44.

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