纳米氧化锌复合粉体的制备及其光催化性能的研究
摘要
近年来,ZnO作为一种用途很广的半导体材料,因其活性高、稳定性好、对人体无毒、成本低且在光催化处理污染水和空气中已广泛应用,而成为最具潜力的光催化剂。然而由于ZnO其固有的缺陷——光生电子-空穴对容易复合,这降低了其光催化活性。因此,要提高ZnO的光催化活性,就应减少光生电子与空穴的复合。将ZnO与其它半导体氧化物复合是提高其光催化活性的途径之一。ZnO和某些半导体材料能级匹配,光生电子和空穴可发生有效的分离,使其复合几率减小,从而提高ZnO的光催化活性。本文主要研究内容如下:
(1)以Na_2CO_3和ZnSO_4为原料,采用直接沉淀法制备纯纳米ZnO光催化剂。通过实验确定其具有最佳光催化性能的制备条件:将Na_2CO_3溶液按摩尔比为1.5的比例逐滴加入到ZnSO_4溶液中,在80℃下反应0.5h后,中间产物经无水乙醇洗涤3次后经600℃煅烧1h制得的纳米ZnO具有最佳光催化性能。
(2)以Na_2CO_3、ZnSO_4和ZrOCl_2·8H_2O等为原料,采用直接沉淀法经700℃煅烧1h得到的掺锆量为1.0 %(摩尔比)的纳米ZnO复合光催化剂粉体的光催化活性最高。XRD分析说明:随着煅烧温度的升高,纯ZnO和掺锆后的纳米ZnO复合光催化剂晶粒粒径也随之变大,但掺锆可以起到细化晶粒的作用。掺锆以后的纳米ZnO光催化剂的粒径随煅烧温度增长的活化能为16.6kJ/mol,相对于纯纳米ZnO的12.5 kJ/mol有所增大。
(3)以Na_2CO_3、ZnSO_4和SnCl_4·5H_2O等为原料,采用直接沉淀法经600℃煅烧1h得到的掺锡量为5.0%(摩尔比)的纳米ZnO复合光催化剂粉体的光催化活性最高。XRD分析表明:随着煅烧温度的升高,纯ZnO和掺锡后的纳米ZnO复合光催化剂晶粒粒径也随之变大,掺锡也可以起到细化晶粒的作用。但与掺锆相比,掺锡细化晶粒粒径的作用更为明显。掺锡以后的纳米ZnO光催化剂的粒径随煅烧温度增长的活化能为6.592kJ/mol,相对于纯ZnO的12.5 kJ/mol减小近一半,这就表明煅烧温度对晶粒粒径大小的影响相对于掺锆而言有所减弱。
In recent years, zinc oxide (ZnO) has been a popular photocatalyst for the treatment of organic pollutants in water and air. However, ZnO photocatalysts have an inherent and obvious drawback, that is, the photogenerated charge carriers (hole-electron pairs) can recombine easy. Therefore, improvement of ZnO photocatalytic activity is important to decrease the recombination of photogenerated charge carriers. Coupling ZnO with other semiconductors can provide a beneficial solution in this aspect. The energy gaps of these two semi-conductors are match, which can prevent the recombination of photogenerated charge carriers, and show efficient photoactivity of ZnO. This dissertation consists of following contents:
1. The direct precipition method has been used to prepare pure nano-ZnO with Na_2CO_3、ZnSO_4 as raw materials. Determined through experiments with the best photocatalytic activities of the preparation conditions: the Na_2CO_3 solution was added into the ZnSO_4 solution at the ratio of 1.5, at 80℃, reaction for 0.5h, intermediate products were washed three times with ethanol, then calcined at 600℃for 1h. The ZnO nanoparticles showed was produced at this method had the best photocatalytic activity on above mentioned conditions.
2. The photocatalysts of Zr-doped ZnO can be synthesized by using the direct-precipition method. Primary optimum content of Zr doping in the samples and calcining temperature for the photocatalytic degradation of methylene blue were 1.0 Zr atom% and 700℃, respectively. X-ray diffraction was used to characterize the grain size of the pure ZnO and Zr-dped ZnO. The size of ZnO nanoparticles increased as calcining temperature. Doping Zr could retard growth of the grain size. Activity energy of the Zr-doped ZnO (1% molar ratio) growth as calcining temperature was 16.6 KJ/mol, bigger than pure ZnO nanoparticles(12.5 KJ/mol).
3. The photocatalysts of Sn-doped ZnO also can be synthesized by using the direct-precipition method. Primary optimum content of Sn doping in the samples and calcining temperature for the photocatalytic degradation of methylene blue were 5 atom% and 600℃, respectively, which was different from that of Zr-doped ZnO nanoparticles. X-ray diffraction (XRD), was also used to characterize the grain size of the pure ZnO and Sn-doped ZnO. Size of ZnO particles increased as calcining temperature. Results showed that doping Sn could play a role in reducing the grain size. The activation energy of the 5%Sn-doped ZnO particle size growth with the calcination temperature had been found 6.592 KJ/mol, almost half that of pure ZnO nanoparticles(12.5 KJ/mol), showing that the effect of calcinations temperature on the grain size was smaller compared to Zr-doping ZnO particles.
(1)以Na_2CO_3和ZnSO_4为原料,采用直接沉淀法制备纯纳米ZnO光催化剂。通过实验确定其具有最佳光催化性能的制备条件:将Na_2CO_3溶液按摩尔比为1.5的比例逐滴加入到ZnSO_4溶液中,在80℃下反应0.5h后,中间产物经无水乙醇洗涤3次后经600℃煅烧1h制得的纳米ZnO具有最佳光催化性能。
(2)以Na_2CO_3、ZnSO_4和ZrOCl_2·8H_2O等为原料,采用直接沉淀法经700℃煅烧1h得到的掺锆量为1.0 %(摩尔比)的纳米ZnO复合光催化剂粉体的光催化活性最高。XRD分析说明:随着煅烧温度的升高,纯ZnO和掺锆后的纳米ZnO复合光催化剂晶粒粒径也随之变大,但掺锆可以起到细化晶粒的作用。掺锆以后的纳米ZnO光催化剂的粒径随煅烧温度增长的活化能为16.6kJ/mol,相对于纯纳米ZnO的12.5 kJ/mol有所增大。
(3)以Na_2CO_3、ZnSO_4和SnCl_4·5H_2O等为原料,采用直接沉淀法经600℃煅烧1h得到的掺锡量为5.0%(摩尔比)的纳米ZnO复合光催化剂粉体的光催化活性最高。XRD分析表明:随着煅烧温度的升高,纯ZnO和掺锡后的纳米ZnO复合光催化剂晶粒粒径也随之变大,掺锡也可以起到细化晶粒的作用。但与掺锆相比,掺锡细化晶粒粒径的作用更为明显。掺锡以后的纳米ZnO光催化剂的粒径随煅烧温度增长的活化能为6.592kJ/mol,相对于纯ZnO的12.5 kJ/mol减小近一半,这就表明煅烧温度对晶粒粒径大小的影响相对于掺锆而言有所减弱。
In recent years, zinc oxide (ZnO) has been a popular photocatalyst for the treatment of organic pollutants in water and air. However, ZnO photocatalysts have an inherent and obvious drawback, that is, the photogenerated charge carriers (hole-electron pairs) can recombine easy. Therefore, improvement of ZnO photocatalytic activity is important to decrease the recombination of photogenerated charge carriers. Coupling ZnO with other semiconductors can provide a beneficial solution in this aspect. The energy gaps of these two semi-conductors are match, which can prevent the recombination of photogenerated charge carriers, and show efficient photoactivity of ZnO. This dissertation consists of following contents:
1. The direct precipition method has been used to prepare pure nano-ZnO with Na_2CO_3、ZnSO_4 as raw materials. Determined through experiments with the best photocatalytic activities of the preparation conditions: the Na_2CO_3 solution was added into the ZnSO_4 solution at the ratio of 1.5, at 80℃, reaction for 0.5h, intermediate products were washed three times with ethanol, then calcined at 600℃for 1h. The ZnO nanoparticles showed was produced at this method had the best photocatalytic activity on above mentioned conditions.
2. The photocatalysts of Zr-doped ZnO can be synthesized by using the direct-precipition method. Primary optimum content of Zr doping in the samples and calcining temperature for the photocatalytic degradation of methylene blue were 1.0 Zr atom% and 700℃, respectively. X-ray diffraction was used to characterize the grain size of the pure ZnO and Zr-dped ZnO. The size of ZnO nanoparticles increased as calcining temperature. Doping Zr could retard growth of the grain size. Activity energy of the Zr-doped ZnO (1% molar ratio) growth as calcining temperature was 16.6 KJ/mol, bigger than pure ZnO nanoparticles(12.5 KJ/mol).
3. The photocatalysts of Sn-doped ZnO also can be synthesized by using the direct-precipition method. Primary optimum content of Sn doping in the samples and calcining temperature for the photocatalytic degradation of methylene blue were 5 atom% and 600℃, respectively, which was different from that of Zr-doped ZnO nanoparticles. X-ray diffraction (XRD), was also used to characterize the grain size of the pure ZnO and Sn-doped ZnO. Size of ZnO particles increased as calcining temperature. Results showed that doping Sn could play a role in reducing the grain size. The activation energy of the 5%Sn-doped ZnO particle size growth with the calcination temperature had been found 6.592 KJ/mol, almost half that of pure ZnO nanoparticles(12.5 KJ/mol), showing that the effect of calcinations temperature on the grain size was smaller compared to Zr-doping ZnO particles.
引文
[1]王成艳.纳米氧化锌及复合粉体的制备及光催化性能研究[D],东北大学,2005.
[2] S. Sakthivel, B. Neppolian, M. V. Shankar, B. Arabindoo, M. Palanichamy, V. Murugesan. Solar photacatalytic degradation of aza dye:comparison of photocatalytic efficiency of ZnO and TiO_2[J]. Solar Energy &Solar Cells, 2003, 77: 65-82.
[3] K. Vinodgopal, Prashant V. Kamat. Enhanced Rates of Photocatalytic Degradation of an Azo Dye Using SnO_2/TiO_2 Coupled Semiconductor Thin films[J]. Environ. Sci. Technol., 1995, 29(3): 842-845.
[4] S. Anandan, A. Vinu, K.L.P Sheeja Lovely, N. Gokulakrishnan, P. Srinivasu, T. Mori, V. Murugesan, V. Sivamurugan, K. Ariga. Photocatalytic activity of La-doped ZnO for the degradation of monocrotophos in aqueous suspension[J]. Journal of Molecular Catalysis A:Chemical, 2007, 266: 149-157.
[5] S. Anandan, A. Vinu, T. Mori, N. Grokulakrishnan, P. Srinivasu, V. Murugesan, K. Ariga. Photocatalytic degradation of 2,4,6-trichlorophenol using lanthanum doped ZnO in aqueous solution[J]. Catalysis Communication, 2007, 8: 1377-1382.
[6] K. Tennakone, J. Bandara. Photocatalytic activity of dye-sensitized tin(Ⅵ) oxide nanocrystalline particles attached to zinc oxide particles: long distance electron transfer via ballistic transport of electrons across nanocrystallites[J]. Applied Catalysis A: General, 2001, 208: 335-341.
[7]周广.配位均匀沉淀法制备Ag/ZnO纳米复合材料及其应用研究[D],湘潭大学,2007.
[8]张金龙,陈锋等.光催化[M],华东理工大学出版社,2004.
[9]万益群,钟已未,郭岚,付敏恭.网络状纳米氧化锌光催化降解水中有机染料的研究[J].分析科学学报, 2007, 23(1): 48-50.
[10] WANG Biao,ZHAO YuDong,HU LiMing,CAO JunSheng,GAO FengLi,LIU Yun,WANG LiJun. Improved and excellent CO sensing properties of Cu-doped TiO_2 nanofibers[J]. Chinese Science Bulletin, 2010, 55(3): 228-232.
[11] N. Sobana, M. Swaminathan. Combination effect of ZnO and activated carbon for solar assisted photocatalytic degradation of Direct Blue 53[J] . Solar Energy Materials & Solar Cells, 2007, 91: 727–734.
[12] Di Li, Hajime Haneda. Enhancement of photocatalytic activity of sprayed nitrogen-containing ZnO powders by coupling with metal oxides during the acetaldehyde decomposition[J]. Chemosphere, 2004, 54: 1099-1110.
[13] Lirong Zheng,Yuanhui Zheng,Chongqi Chen,Yingying Zhan,Xingyi Lin,Qi Zheng,Kemei Wei, Jiefang Zhu. Network Structured SnO_2/ZnO Heterojunction Nanocatalyst with High Photocatalytic Activity[J]. Inorganic Chemistry, 2009, 48: 1819-1825.
[14] Weiwei Lu, Shuyan Gao, Jianji Wang. One-Pot Synthesis of Ag/ZnO Self-Assembled 3D Hollow Microspheres with Enhanced Photocatalytic Performance[J]. J. Phys. Chem. C, 2008, 112, 16792–16800.
[15] Fujishima A, Honda K. Electrochemical Photolysis of Water at a semiconductor Electrode[J]. Nature, 1972, 238(5358): 37.
[16] Bing-zhi LI, Xiang-yang XU, Liang ZHU. Catalytic ozonation-biological coupled processes for the treatment of industrial wastewater containing refractory chlorinated nitroaromatic compounds[J]. Journal of Zhejiang University-SCIENCE B (Biomedicine & Biotechnology), 2010, 11(3):177-189.
[17] S.K. Kansal a, M. Singh, D. Sud. Studies on photodegradation of two commercial dyes in aqueous phase using different photocatalysts[J]. Journal of Hazardous Materials , 2007, 141: 581–590.
[18]苏碧桃,胡常林,左显维,雷自强.纳米氧化锌的制备及其在太阳光下的光催化性能[J].无机化学学报, 2010, 26(1): 96-100.
[19] A. Akyol, H.C. Yatmaz, M. Bayramoglu. Photocatalytic decolorization of Remazol Red RR in aqueous ZnO suspensions[J]. Applied Catalysis B: Environmental, 2004, 54: 19–24.
[20] Liwu Zhang, Hanyun Cheng, Ruilong Zong, and Yongfa Zhu. Photocorrosion Suppression of ZnO Nanoparticles via Hybridization with Graphite-like Carbon and Enhanced Photocatalytic Activity[J]. J. Phys. Chem. C, 2009, 113, 2368–2374.
[21] Luyan Li, Weihua Wang, Hui Liu, Xindian Liu, Qinggong Song, Shiwei Ren. First PrinciplesCalculations of Electronic Band Structure and Optical Properties of Cr-Doped ZnO[J]. J. Phys. Chem. C, 2009, 113, 8460–8464.
[22]张茂林,安太成,胡晓洪,王存,王新明,盛国英,傅家谟.泡沫镍负载纳米ZnO-SnO_2光催化降解三氯乙烯[J].环境科学学报, 2005, 25(2): 259-263.
[23] Mingyuan Gao, Xi Zhang, Bai Yang, Feng Li, Jiacong Shen. Assembly of modified CdS particles /cationic polymer based on electrostatic interactions[J] . Thin Solid Films, 1996, 242-245.
[24]王铮,李凤亭.纳米氧化锆/氧化锌光催化降解酸性红B的研究[J].无机盐工业,2007,39(6):47-50.
[25]侯春燕. ZnO纳米材料的制备及其光催化降解有机废水的研究[D],大连海事大学,2006.
[26]夏荣花.锡钛复合氧化物光催化性能研究[D],山东师范大学,2007.
[27]申利春.纳米SnO_2/ZnO复合光催化剂的制备、表征及其光催化活性[D],贵州大学,2008:
[28] Di Li, Hajime Haneda. Synthesis of nitrogen-containing ZnO powders by spray pyrolysis and their visible-light photocatalysis in gas-phase acetaldehyde decomposition[J]. Journal of Photochemistry and Photobiology A:Chemistry, 2003, 155 :171–178.
[29] Jorge Villasenor, Hector D. Mansilla. Effect of temperature on kraft black liquor degradation by ZnO-photoassisted catalysis[J]. Journal of Photochemistry and Phtobiology A: Chemistry, 2006, 93: 205-209.
[30]倪星元,沈军等.纳米材料的理化特性与应用[M],化学工业出版社,2006.
[31]马正先,韩跃新,印万忠,王泽云,马云东.纳米氧化锌光催化氧化活性黄的研究[J].有色矿冶, 2005, 21(增刊): 123-128.
[32]刘守新,刘鸿.光催化剂光电催化基础与应用[M],化学工业出版社,2006.
[33] A. Akyol, M. Bayramoglu. Photocatalytic degradation of Remazol Red F3B using ZnO catalyst[J]. Journal of Hazardous Materials B, 2005, 124: 241–246.
[34]刘春艳.纳米光催化剂光催化环境净化材料[M],化学工业出版社,2008.
[35]邵金璐,卢秀萍.纳米ZnO的应用研究[J].浙江化工,2005,36(10):21-24.
[36]高振伟,周易,陈永娟.印染废水的光催化氧化研究现状及其进展[J].工业安全与环保, 2008, 34(6): 10-12.
[37]李镇江,岑伟,郭峰,孟阿兰. ZnO/Ag纳米复合抗菌剂的分散与性能研究[J].功能材料,2007, 38(增刊):3430-3432.
[38]韩绪军,张立波,冯悦,唐颖蕾,魏大巧,彭金辉,夏雪山.载ZnO /活性碳复合材料抗菌性能及安全性研究[J].生物技术通报, 2010, 1: 200-204.
[39]李镇江,郭峰,孟阿兰,李荣先,梁开明.工艺参数对ZnO/Ag合成纳米复合抗菌剂产率的影响[J].稀有金属材料与工程, 2007, 36(增刊): 293-295.
[40]吴佳卿,郑敏.氮掺杂ZnO纳米晶的防紫外和抗菌整理[J].印染, 2008, 10: 9-12.
[41]姜虎生,吴南.纳米氧化锌对废水中Cu~(2+)、Cd~(2+)吸附性能的研究[J].长春理工大学学报(自然科学版), 2008, 31(1): 139-141.
[42]周晓红,赵秀琴.氧化锌光催化降解六种可溶性染料的研究[J].安庆师范学院(自然科学版), 2003, 9(2): 4-6.
[43]宫江宁,廖莉玲,任绍成. SnO_2-TiO_2光催化剂的制备及其对两种染料废水降解作用的研究[J].贵州师范大学学报(自然科学版), 2009, 27(4): 37-40.
[44]顾晓梅,李淑华.半导体光催化效应在染料废水处理中的应用[J].纺织科技进展,2006,1: 22-24.
[45]钟已未,万益群,付敏恭,郭岚.纳米氧化锌光催化降解有机染料性能的研究[J].分析实验室, 2006, 25(12): 30-34.
[46]张江娜.纳米氧化锌的制备及其在水处理方面的应用[J].广州化工, 2009, 37(9): 190-191.
[47]刘亚兰,活性炭纤维负载二氧化钛光催化剂的制备及性能评价,东北林业大学博士学位论文[D],2009.
[48]王凯,周柞万,刘菁菁,李艳霞.一维纳米结构ZnO掺杂的研究进展[J].材料科学与工程学报, 2006, 24(3): 472-476.
[49] ZHOU Yin, WANG Yu, LU Shi-xiang, XU Wen-guo, SU Su. Photocatalytic Degradation of Reactive Brilliant Blue X-BR with La~(3+), Al~(3+) Co-doped ZnO nanoparticles[J]. Journal of synithetic crystals, 2009, 38(4): 998-1007.
[50]杨合,薛向欣,赵娜,左良,杨中东.半导体多相光催化技术研究进展[J].环境保护,2003, 6:22-24.
[51]黄苏萍,肖奇.可见光响应金属氧化物光催化剂的研究进展[J].材料导报,2009,23(1):28-32.
[52]韩兆慧,赵化侨.半导体多相光催化应用研究进展[J].化学进展, 1999, 11(1): 1-10.
[53] Chen Shifu,ZhaoWei ,Zhang Sujuan,LiuWei. Preparation, characterization and photocatalytic activity of N-containing ZnO powder[J]. Chemical Engineering Journal, 2009, 148: 263–269.
[54]赵铧,李韦,刘高斌,熊稳,王伟,郭富胜. ZnO纳米材料及掺杂ZnO材料的最新进展[J].材料导报, 2007, 21(9): 105-113.
[55]戴护民,桂阳海.气、光敏材料ZnO的掺杂改性研究[J].材料导报, 2006, 20(6): 21-23.
[56]刘红,刘潘,辜孔良,李晶,孙璇.锆改性纳米TiO_2的光催化性能研究[J].工业安全与环保, 2006, 32(7): 18-20.
[57]刘国光,郭小阳,郑立庆,毛小权,娄淑芳,张志军. Zr/TiO_2纳米管的制备及其光催化性能的初步研究[J].环境科学学报, 2008, 28(4):710-713.
[58]孟阿兰,岑伟,李镇江,李荣先. ZnO/Ag纳米复合材料光催化性能[J].稀有金属材料与工程, 2007, 36(2): 299-302.
[59]汪荣华,刘洪芳,许立铭,胡军辉,胡木林,谢长生. Ag~+/ZnO纳米晶的制备及对亚甲基蓝的异相光催化行为[J].华中师范大学学报(自然科学版),2003, 37(4): 510-513.
[60]刘宏芳,汪德顺,唐和清,张崎. H_2O_2增效Ag~+掺杂ZnO纳米晶光催化体系降解亚甲基蓝[J].华中科技大学学报(自然科学版),2007, 35(10): 101-104.
[61] Ronghua Wang, John Haozhong Xin, Yang Yang, Hongfang Liu, Liming Xu, Junhui Hu. The characteristics and photocatalytic activities of silver doped ZnO nanocrystallites[J]. Applied Surface Science, 2004, 227: 312–317
[62]张靖峰,杜志平,赵永红,台秀梅. Fe~(3+)改性纳米ZnO光催化降解壬基分聚氧乙烯醚[J].催化学报, 2007, 28(6): 561-566.
[63]刘英,梁英.水热合成Fe~(3+)掺杂ZnO复合材料及其光催化活性[J].应用化学,2009,26(10):1247-1249.
[64]李洪杰,杨凤珠,柳闽生,潘洁.铁掺杂氧化锌纳米晶的制备及其光催化性能的研究[J].化工时刊, 2009, 23(8): 16-19.
[65]朱斌,张明月,王莅,邹志军,张香文,米镇涛.镧掺杂ZnO/TiO_2催化降解冰片二烯异构化反应研究[J].中国稀土学报,2008,26(3):267-271.
[66]王智宇,郭晓瑞,唐培松,将玉龙,苏长胜. La~(3+)离子掺杂对纳米ZnO光催化性能的影响[J].材料导报, 2004, 18(7): 87-89.
[67]周艺,钟选斌,杨波,朱志平. Y~(3+)掺杂ZnO/TiO_2复合纳米光催化剂的研究[J].湖南师范大学自然科学报, 2008, 31(2): 87-90.
[68]周银,徐文国,卢士香,张光友.掺钕纳米氧化锌光催化降解偏二甲阱污水[J].北京理工大学学报, 2009, 29(3): 266-269.
[69] Xi Chen, Bing Yan. Induced synthesis of ZnO:Tb~(3+) green hybrid phosphors by the assembly of polyethylene glycol matrices[J]. Materials Letters, 2007, 61: 1707–1710.
[70]井立强,蔡伟民,孙晓君,侯海鸽,徐自立,杜尧国. Pd/ZnO和Ag/ZnO复合纳米粒子的制备、表征及光催化活性[J].催化学报, 2002, 23(4): 336-340.
[71]王建鑫,罗来涛. Au/ZnO,Pd/ZnO和Au-Pd/ZnO催化甲醇部分氧化[J].稀有金属,2009,33(2): 247-251.
[72]韩婧,施立毅,成荣明,陈奕卫,董鹏飞,邵启伟. Ag改性纳米ZnO薄膜及光催化活性[J].无机化学学报, 2008, 24(6): 950-955.
[73]素珺,张青红,李耀刚,王宏志.氧化锌、镁铝复合氧化物的制备及光催化性能[J].无机化学学报, 2009, 25(11): 1977-1981.
[74]徐甲强,高巧欢,王培义,向群.氧化锌/偏锡酸锌复合氧化物的制备与光催化性能[J].硅酸盐学报, 2007, 35(6): 741-745.
[75]娄向东,赵晓华,成庆堂.复合氧化物光催化研究进展[J].化学研究与应用, 2003, 15(4): 447-450.
[76] Chun Cheng, Kai Feng Yu, Yuan Cai, Kwok Kwong Fung, Ning Wang. Site-Specific Deposition of Titanium Oxide on Zinc Oxide Nanorods[J]. J. Phys. Chem. C, 2007, 111, 16712-16716.
[77]张灵灵,王艳华,白雪峰. CdS/ZnO复合光催化剂催化分解硫化氢制氢研究[J].化学与黏合, 2008, 30(6): 5-9.
[78]马占营,姚秉华,何仰清,范广. ZnO-PFD纳米复合材料的制备及其光催化性能[J].精细化工, 2009, 26(9): 838-843.
[79]胡利利,杜志平,邰秀梅,李秋小,赵永红.纳米V_2O_5/ZnO光催化剂对壬基酚聚氧乙烯醚降解的催化活性[J].催化学报, 2008, 29(6): 571-576.
[80]刘亚子,李新勇,孙成,杨绍贵,全燮.纳米复合ZnO-TiO_2晶体的制备及其光电催化性能的研究[J].环境污染治理技术与设备, 2005, 6(4): 36-43.
[81]赵子淇,张萍,李哲,邹佳宏.不同钛比对纳米碳酸锌(ZnO-TiO_2)体系成分的影响[J].材料导报, 2007, 21(8): 168-170.
[82] Da Chen,Hao Zhang,Song Hu,Jinghong Li. Preparation and Enhanced Photoelectrochemical Performance of Coupled Bicomponent ZnO-TiO_2 Nanocomposites[J]. J. Phys. Chem. C , 2008, 112, 117-122.
[83] Patricia Peralta-Zamora, Sandra Gomes de Moraes, Ronaldo Pelegrinir, Mariwalde Freire Jr.,Juan Reyes, Hector Mansilla, Nelson Duran. Evaluation of ZnO-TiO_2 and supported on the photoassisted remediation of black liquor, cellulose and textile mill effluents[J]. Chemosphere, 1998, 36(9): 2119-2133.
[84] S.K. Kansal, M. Singh, D. Sud. Studies on TiO_2/ZnO photocatalysed degradation of lignin[J]. Journal of Hazardous Materials, 2008, 153: 412–417.
[85]施利毅,古宏晨,李春忠,房鼎业,张怡,华彬. SnO_2-TiO_2复合光催化剂的制备和性能[J].催化学报, 1995, 20(3): 338-342.
[86]李顺华,郭海福,闫鹏. SnO_2/TiO_2复合氧化物制备及其光催化性能研究[J].广东化工,2009, 36(10): 31-33.
[87] ZHANG Jingchang,FENG Liye,WEI Jia,GUO Xuehua , CAO Weiliang. Synthesis of SnO_2/TiO_2 nanocomposite photocatalysts by supercritical fluid combination technology[J]. Chinese Science Bulletin, 2006, 51(17): 2050—2054.
[88]石照信,石亨达,王思林,孙剑飞.纳米ZnO/Al_2O_3复合氧化物的制备及其光催化性能[J].沈阳化工学院学报, 2008, 22(3): 193-199.
[89]周建伟,黄建新,王金娜,李洁.纳米ZnO/膨润土光催化降解亚甲基蓝研究[J].应用化工, 2008, 37(9): 1063-1066.
[90]张丽敏,陈清松,李晓燕,丁富传.竹炭-ZnO复合材料的制备及对苯酚的光催化降解作用[J].林产化学与工业, 2009, 29(1): 33-38.
[91]李镇江,郭峰,孟阿兰,李荣先,梁开明.工艺参数对合成ZnO/Ag纳米复合抗菌剂产率的影响[J].稀有金属材料与工程, 2007, 36(2): 293-295.
[92]夏璐.光催化光敏化氧化含酚含氯废水的研究[J].化学与生物工程,2004,5:16-18.
[93]张伟. TiO_2光敏化研究进展[J].广东化工, 2009, 36(199): 94-97.
[94]张璐璐,ZnO纳米粒子的制备、表面修饰及光催化性能的研究[D],哈尔滨工程大学,2007.
[95]周天亮,宋绵新,敬晓峰,边亮,王峰. TiO_2/沸石光催化性能的研究[J].太阳能学报, 2006, 27(12): 1270-1275.
[96]胡海,泡沫金属负载纳米TiO_2的制备、表征及其光催化性能的研究[D],上海交通大学,2007.
[97]林婷,刘国光. TiO_2光催化剂负载方式及气相反应器的研究[J].工业安全与环保,2008,34(4): 1-4.
[98]梁世强,穆筱梅,葛建芳.活性炭纤维负载纳米TiO_2在光反应器中降解空气中微量甲醛的研究[J].精细化工, 2006, 23(5): 456-459.
[99]王超,徐新,罗国华.纳米Au/ZnO/TiO_2催化剂对富氢气体中CO选择性氧化[J].石油化工高等学校校报, 2007, 20(1): 63-66.
[100]叶志镇,吕建国等.氧化锌半导体材料掺杂技术与应用[M],浙江大学出版社,2009.
[101] Zijie Yan, Yanwei Ma, Dongliang Wang, Junhong Wang, Zhaoshun Gao, Tao Song. Surfactant-Free Fabrication of ZnO Spheres and Pseudospherical Structures[J]. J. Phys. Chem. C, 2008, 112, 9219–9222 9219.
[102] Wei-De Zhang, Liao-Chuan Jiang, Jian-Shan Ye. Photoelectrochemical Study on Charge Transfer Properties of ZnO Nanowires Promoted by Carbon Nanotubes[J]. J. Phys. Chem. C, 2009, 113, 16247–16253.
[103]马书懿,毛雷鸣,马慧,史新福,周婷婷,丁继军. Cu掺杂对ZnO纳米薄膜的结构及其光学特性的影响[J].西北师范大学学报(自然科学版), 2010, 46(1): 37-42.
[104] Laiho, Yu.P.Stepanov, M.P.Vlasenko, L.S.Vlasenko. Persistent photoconductivity of ZnO[J]. Physica B, 2009, 404: 4787–4790.
[105]叶彩,陶慧波,宫丽红,武祥.液相法合成ZnO纳米材料的研究进展[J].陶瓷学报, 2009, 30(1): 124-128.
[106]廉红蕾,潘维成,贾明君,蒋大振,张文祥,吴通好. ZnO负载纳米金催化剂上的低温水煤气变换反应[J].催化学报, 2005, 26(11): 999-1004.
[107]苏彤.超细氧化锌应用拓展[J].化工中间体, 2003, 5: 21-22.
[108]杨凤霞,刘其丽,毕磊.纳米氧化锌的应用综述[J].安徽化工, 2006, 1: 13-17.
[109]张留成,蔡克峰.纳米氧化锌材料的最新研究和应用进展[J].材料导报, 2006, 20(6):13-23.
[110]马正先,韩跃新,郑龙熙,刘建彬.纳米氧化锌的应用研究[J].化工进展,2002,21(2):60-69.
[111]王久亮,刘宽,秦秀娟,邵光杰.纳米氧化锌的应用研究展望[J].哈尔滨工业大学学报, 2004, 36(2):226-230.
[112]方佑龄,赵文宽,陈兴凡.肤色超微粉末氧化锌的制备[J].涂料工业, 1991, 4: 4-7.
[113] Di Li, Hajime Haneda. Morphologies of zinc oxide particles and their effects on photocatalysis[J]. Chemosphere, 2003, 51: 129-137.
[114]徐波,王树林,李来强,李生娟.纳米Zn/ZnO复合结构的光催化活性[J].功能材料,2010, 41(2):307-310.
[115] Cristian Lizama, Juanita Freer, Jaime Baeza, Héctor D. Mansilla. Optimized photodegradation of Reactive Blue 19 on TiO_2 and ZnO suspensions[J]. Catalysis Today, 2002, 76: 235–246
[116]黄焱球,刘梅冬,李楚容,曾亦可,刘少波,夏冬林. ZnO陶瓷薄膜的制备及其低压压敏性质[J].压电与声光, 2001, 23(5): 384-386.
[117]周广,邓建成.配位均匀沉淀法制备Ag/ZnO纳米复合材料的研究[J].功能材料,2007,38(4): 665-668.
[118]孟庆明,马迪,李建章,钟俊波.沉淀法制备纳米ZnO及光催化甲基橙脱色研究[J].化学工程师, 2010, 1: 4-6.
[119]成庆堂,李峰,姚超,徐斌海.纳米氧化锌的制备[J].化工新型材料,2008, 36(2): 44-46.
[120]洪若瑜,徐丽萍,任志强,李忻,李洪钟.纳米氧化锌的制备及其光催化活性研究[J].化工环保, 2005, 25(3): 231-234.
[121]廖莉玲,刘吉平.纳米氧化锌制备方法比较[J].贵州化工, 2002, 27(3): 1-13.
[122]张永康,刘建本,易保华,陈德根,肖卓炳,陈上.常温固相法合成纳米氧化锌[J].精细化工, 2000, 17(6): 343-345.
[123]沈茹娟,贾殿增,梁凯,忻新泉,王疆英.纳米氧化锌的固相合成及其气敏特性[J].无机化学学报, 2000, 16(6): 906-910.
[124]赵新宇,郑柏存,李春忠,胡黎明,古宏晨.喷雾热解合成ZnO超细粒子工艺及机理研究[J].无机材料学报, 1996, 11(4) :611-616.
[125] El-Shall M S,Slack W,Vann W,Kenne D,Hanley D. Sythesis of nanoscale metal oxide partical using laser vaporization/condensation in a diffusion cloud chanmber[J],J. Phys. Chem. C, 1994, 98(12): 3067-3070.
[126]赵春,钟顺和. Cu/ZnO-TiO_2复合半导体光催化材料的制备与表征[J].无机化学学报, 2004, 20(9): 1131-1136.
[127]张月甫,李玉国,薛成山,张敬尧,崔传文.纳米氧化锌的制备技术及其应用前景[J].山东师范大学学报(自然科学版), 2008, 3(2): 39-42.
[128]郭书霞,张兴堂,赵慧玲,李蕴才,黄亚彬,杜祖亮.纳米氧化锌的制备及发光特性的研究[J].无机化学学报, 2006, 22(4): 724-728.
[129]关敏,李彦生.国内外纳米ZnO研究和制备概括[J].化工新型材料,2005,33(2) :18-21.
[130]冯洁.乳化-前驱物热分解法制备纳米氧化锌[J].光谱实验室, 2004, 21(3): 442-444.
[131]颜肖慈,余林颇,罗春霞,薛东波,罗明道.纳米氧化锌微乳液法的研究和表征[J].十堰职业技术学院学报, 2002, 15(2): 67-68.
[132]包小波,袁爱华.纳米ZnO的制备及其光催化降解酸性红B[J].当代化工, 2009, 38(6): 575-578.
[133]郝彦忠.花状纳米氧化锌的制备及其光电性能的研究[J].功能材料, 2008, 39(1):83-85.
[134]袁爱华,包小波,唐丽,周虎.水热法制备ZnO纳米棒及其光催化性能研究[J].化学研究与应用, 2008, 20(2): 122-125.
[135]刘春莲,林深,张晓凤,张晓勤,江菊琼.以PAMAM树形分子为模型纳米氧化锌的制备及其光催化性能研究[J].功能材料, 2007, 38(4): 672-675.
[136]关敏,李彦生.国内外纳米ZnO研究和制备概括[J].化工新型材料,2005,33(2): 18-21.
[137] Cristina Yeber, Jaime Rodr_(o¨)guez, Juanita Freer, Nelson Duran, Hector D. Mansilla a. Photocatalytic degradation of cellulose bleaching e.uent by supported TiO_2 and ZnO[J]. Chemosphere, 2000, 41: 1193-1197.
[138] Shunjun Li, Zichuan Ma, Jie Zhang, Yinsu Wu, Yamin Gong. A comparative study of photocatalytic degradation of phenol of TiO_2 and ZnO in the presence of manganese dioxides[J]. Catalysis Today, 2008, 139: 109–112.
[139] Liqiang Jing, Zili Xu, Xiaojun Sun, Jing Shang, Weimin Cai. The surface properties and photocatalytic activities of ZnO ultrafine particles[J]. Applied Surface Science, 2001, 180: 308-314.
[1] Changhui Ye,Yoshio Bando,Xiaosheng Fang,Guozhen Shen,Dmitri Golberg. Enhanced Field Emission Performance of ZnO Nanorods by Two Alternative Approaches[J]. J. Phys. Chem. C, 2007, 111, 12673-12676.
[2] Hao Zhang, Ruilong Zong, and Yongfa Zhu. Photocorrosion Inhibition and Photoactivity Enhancement for Zinc Oxide via Hybridization with Monolayer Polyaniline[J]. J. Phys. Chem. C , 2009, 113, 4605–4611.
[3] Nikolai Kislov, Jayeeta Lahiri, Himanshu Verma, D. Yogi Goswami, Elias Stefanakos, Matthias Batzill. Photocatalytic Degradation of Methyl Orange over Single CrystallineZnO: Orientation Dependence of Photoactivity and Photostability of ZnO[J]. Langmuir , 2009, 25, 3310-3315.
[4]吕红金,江萍,刘宇珊,李敏,彭天右.不同形貌纳米ZnO的合成及其光催化性能研究[J].功能材料, 2010, 41(2): 292-295.
[5]王幸宜.催化剂表征[M],华东理工大学出版社,2008.
[6]夏荣花.锡钛复合氧化物光催化性能研究[D],山东师范大学,2007.
[7] J.R.安德森等.催化剂表征与测试,烃加工出版社,1989,北京.
[8]刘俊,徐志兵,王燕群.纳米氧化锌的制备及其光催化性能研究[J].合肥工业大学学报(自然科学版), 2008, 31(6): 898-901.
[9]周广.配位均匀沉淀法制备Ag/ZnO纳米复合材料及其应用研究[D],湘潭大学,2007.
[10] ZHU Zhenqi, ZHOU Jian, LIU Guizhen, JIANG Yurong. Growth of ZnO Sub-millimeter Crystals by Microwave Heating[J]. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2010, 2: 94-98.
[11]张靖峰,杜志平,赵永红,台秀梅,冯春波.纳米氧化锌光催化降解壬基酚聚氧乙烯醚[J].日用化学工业, 2007, 37(1): 16-19.
[12]卫兵,陈剑松,廖静,宗俊.超声波直接沉淀法制备纳米氧化锌及改性研究[J].无机盐工业, 2008, 40(3): 20-29.
[13]刘家祥,丁德玲,王震,韩跃新.均匀沉淀法制备纳米氧化锌[J].有色金属, 2006, 58(1): 49-52.
[14]王振希,郑典模,李建敏,范敏,刘明,庄叶凯.直接沉淀法制备纳米氧化锌工艺研究[J].无机盐工业, 2006, 38(9): 40-42.
[15]辛显双,周百斌,邵纯红,徐学勤.纳米ZnO制备过程中的热处理条件分析[J].化学与粘合, 2002, 6: 261-266.
[16]黄焱球,刘梅冬,李楚容,曾亦可,刘少波,夏冬林. ZnO陶瓷薄膜的制备及其低压压敏性质[J].压电与声光, 2001, 23(5): 384-386.
[17]徐华军.纳米氧化锌的制备[D],无锡轻工业大学,2000.
[18]申利春.纳米SnO_2/ZnO复合光催化剂的制备、表征及其光催化活性[D],贵州大学,2008.
[19]苏苏,卢士香,徐文国.铝掺杂纳米ZnO颗粒光催化降解活性艳兰X-BR[J].过程工程学报, 2008, 8(1): 54-59.
[1] Di Li, Hajime Haneda. Enhancement of photocatalytic activity of sprayed nitrogen-containing ZnO powders by coupling with metal oxides during the acetaldehyde decomposition[J]. Chemosphere, 2004, 54: 1099-1110.
[2] Di Li, Hajime Haneda. Synthesis of nitrogen-containing ZnO powders by spray pyrolysis and their visible-light photocatalysis in gas-phase acetaldehyde decomposition[J]. Journal of Photochemistry and Photobiology A: Chemistry, 2003, 155: 171–178.
[3] Sohn Jong Rack,Lee Si Hoon. Acidic properties of nickel sulfate supported on TiO_2-ZrO2 and catalytic activity for acid catalysis[J]. Applied Catalysis A: General, 2004, 266(1): 89-97.
[4] Mao Dongsen,Lu Guanzhong,Chen Qingling. Influence of calcination temperature and preparation method of TiO_2-ZrO2 on conversion of cyclohexanone oxime to -caprolactam over B2O3/TiO_2-ZrO2 catalyst[J]. Applied Catalysis A: General, 2004, 263(1): 83-89.
[5]李莉,马禹,曹艳珍,张文治,郭伊荇.纳米复合光催化剂TiO_2-ZrO2的制备、表征及光催化活性[J].化学通报, 2009, 6: 529-533.
[6]李莉,陆丹,李恩帅.纳米材料ZrO_2微波增强光催化降解染料[J].齐齐哈尔大学学报, 2009, 6: 19-20.
[7]陈姗姗,李怀祥,曲丕丞.锆掺杂纳米ZnO粉体的制备及其光催化性能[J].纳米科技, 2009, 6(6): 16-20.
[8]张靖峰,杜志平,赵永红,台秀梅,冯春波.纳米氧化锌光催化降解壬基酚聚氧乙烯醚[J].日用化学工业, 2007, 37(1): 16-19.
[9] LIU Hang , ZHUANG Hui zhao , XUE Cheng-shan , WANG Jie , LI Jun-lin. Synthesis and Properties of Mg-doped ZnO Nanobelts[J]. Semiconductor Phtonics and Technology, 2009, 15(4): 225-228.
[10]师磊.掺杂工艺对Al-F共掺ZnO薄膜性能的影响[J].国外建材科技, 2008, 29(2): 56-63.
[11]张靖峰,杜志平,赵永红,台秀梅. Fe3+改性纳米ZnO光催化降解壬基分聚氧乙烯醚[J].催化学报, 2007, 28(6): 561-566.
[12]王铮.复合光催化剂的制备及其降解水中染料的应用研究[D],同济大学,2007.
[13]朱卫兵,陈剑松,廖静,宗俊.超声波直接沉淀法制备纳米氧化锌及改性研究[J].无机盐工业, 2008, 40(3): 20-29.
[14]刘家祥,丁德玲,王震,韩跃新.均匀沉淀法制备纳米氧化锌[J].有色金属, 2006, 58(1): 49-52.
[15]申利春.纳米SnO_2/ZnO复合光催化剂的制备、表征及其光催化活性[D],贵州大学, 2008.
[16]成莉燕,杨武,薛再兰,高锦章.坡缕石负载ZnO/SnO_2光催化剂的制备及光催化性能的研究[J].西北师范大学学报(自然科学版), 2008, 44(6): 86-90.
[17] HUAI-XIANG LI, RONG-HUA XIA, ZHENG-WEI JIANG,SHAN-SHAN CHEN, DE-ZHAN CHEN.Optical absorption property and photo-catalytic activity of tin dioxide-doped titanium dioxides [J]. Chinese journal of chemistry, 2008, 26, 1787-1792.
[18]周秉明,申利春,曹建新.纳米SnO_2/ZnO复合氧化物的制备及制备条件对光催化性能的影响[J].化学研究与应用, 2008, 20(6): 705-709.
[19]王智宇,郭晓瑞,唐培松,将玉龙,苏长胜. La~(3+)离子掺杂对纳米ZnO光催化性能的影响[J].材料导报, 2004, 18(7): 87-89.
[20]刘守新,孙承林.光催化剂TiO_2改性的研究进展[J].东北林业大学学报, 2003, 31(1): 53-56.
[21]毕怀庆,袁文辉,韦朝海.掺锆纳米TiO_2制备表征及其对光催化活性的影响[J].材料科学与工程学报, 2004 22(1): 98-101.
[22]夏宇正,朱也莉,石淑先,焦书科.纳米二氧化锆的制备及其光学性能研究[J].涂料工业, 2006, 36(8): 13-16.
[23] Zuo Xiang-Qing, Li Huai-Xiang, Chen Lu-Sheng, Zhou Hong-Wei, Xia Rong-Hua,Doping effect on the grain growth of spinel LiMn_2O_4 prepared by sol-gel methods[J],CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2007, 26(9): 1017-1022.
[24]何则强,熊利之.纳米SnO_2的非水溶剂溶胶-凝胶法制备与表征[J],无机化学学报, 2005, 21: 1691-1696.
[1]徐杰,鄂磊.半导体复合型ZnO/SnO_2光催化剂的制备[J].创新技术, 2009, 6: 19-20.
[2] Jiang Bin XIA, Fu You LI, Shu Ming YANG, Chun Hui HUANG. Composite Electrode SnO_2/TiO_2 for Dye-Sensitized Solar Cells[J]. Chinese Chemical Letters , 2004 ,15(5): 619-622.
[3]颜秀茹,李晓红,霍明亮,郭伟巍,巩永进.纳米SnO_2-TiO_2的制备及其光催化性能[J].物理化学学报, 2001, 17(1): 23-28.
[4]颜秀茹,白天,霍明亮,张月萍,郭秀盈.核-壳式纳米SnO_2/ TiO_2光催化剂的制备和性能[J].催化学报, 2004, 25(2): 120-124.
[5] Wang Cun, Zhao Jincai, Wang Xinming, Mai Bixian, Sheng Guoying, Peng Ping’an, Fu Jiamo. Preparation ,characterization and photocatalytic activity of nana-sized ZnO/SnO_2 coupled photocatalysts[J]. Applied CatayusisB:Environmented, 2002, 39: 269-279.
[6] J. Bandara, K. Tennakone, P.P.B. Jayatilaka. Composite Tin and Zinc oxide nanocrystalline particles for enhanced charge separation in sensitized degradation of dyed[J]. Chemosphere, 2002 ,49: 439-445.
[7] Lirong Zheng,Yuanhui Zheng,Chongqi Chen,Yingying Zhan,Xingyi Lin,Qi Zheng,Kemei Wei, Jiefang Zhu. Network Structured SnO_2/ZnO Heterojunction Nanocatalyst with High Photocatalytic Activity[J]. Inorganic Chemistry, 2009, 48: 1819 -1825.
[8]周秉明,申利春,曹建新.纳米SnO_2/ZnO复合氧化物的制备及制备条件对光催化性能的影响[J].化学研究与应用, 2008, 20(6): 705-709.
[9]王存,王鹏,徐柏庆. ZnO-SnO_2纳米复合氧化物光催化剂催化降解对硝基苯胺[J].催化学报, 2004, 259(12): 967-972.
[10]周秉明,申利春.复合纳米SnO_2/ZnO光催化降解酿酒废水的研究[J].酿酒科技, 2008, 6: 128-130.
[11]成莉燕,杨武,薛再兰,高锦章.坡缕石负载ZnO/SnO_2光催化剂的制备及光催化性能研究[J].西北师范大学学报(自然科学版), 2008, 44(4): 86-90.
[12]刘家祥,丁德玲,王震,韩跃新.均匀沉淀法制备纳米氧化锌[J].有色金属, 2006, 58(1): 49-52.
[13]张茂林,安太成,胡晓洪,王存,王新明,胜国英,傅家谟.泡沫镍负载ZnO-SnO_2光催化降解三氯乙烯[J].环境科学学报, 2005, 25(2): 259-263.
[14]程刚,周孝德,李艳,仝攀瑞,王理明.纳米ZnO-TiO_2复合半导体的La3+改性及其光催化性能的研究[J].催化学报, 2007, 28(10):885-889.
[15]申利春.纳米SnO_2/ZnO复合光催化剂的制备、表征及其光催化活性[D],贵州大学,2008.
[16]姜秀榕,温德才,胡志彪,童长青,周云龙,董雁. SnO_2/ZnO复合氧化物的制备及对亚甲基蓝的光催化性能研究[J].化学工程与设备, 2009, 11: 1-4.
[17] Eva M. Wong, John E. Bonevich, Peter C. Searson. Growth kinetics of nanocrystalline ZnO pariticles from Colloidal Suspensions[J]. J. Phys. Chem. B, 1998, 102: 7770-7775.
[18] Zuo Xiang-Qing, Li Huai-Xiang, Chen Lu-Sheng, Zhou Hong-Wei, Xia Rong-Hua,Doping effect on the grain growth of spinel LiMn_2O_4 prepared by sol-gel methods[J],CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2007,26(9): 1017-1022.
[19] HUAI-XIANG LI, RONG-HUA XIA, ZHENG-WEI JIANG,SHAN-SHAN CHEN, DE-ZHAN CHEN.Optical absorption property and photo-catalytic activity of tin dioxide-doped titanium dioxides [J]. Chinese journal of chemistry, 2008, 26, 1787-1792.
[2] S. Sakthivel, B. Neppolian, M. V. Shankar, B. Arabindoo, M. Palanichamy, V. Murugesan. Solar photacatalytic degradation of aza dye:comparison of photocatalytic efficiency of ZnO and TiO_2[J]. Solar Energy &Solar Cells, 2003, 77: 65-82.
[3] K. Vinodgopal, Prashant V. Kamat. Enhanced Rates of Photocatalytic Degradation of an Azo Dye Using SnO_2/TiO_2 Coupled Semiconductor Thin films[J]. Environ. Sci. Technol., 1995, 29(3): 842-845.
[4] S. Anandan, A. Vinu, K.L.P Sheeja Lovely, N. Gokulakrishnan, P. Srinivasu, T. Mori, V. Murugesan, V. Sivamurugan, K. Ariga. Photocatalytic activity of La-doped ZnO for the degradation of monocrotophos in aqueous suspension[J]. Journal of Molecular Catalysis A:Chemical, 2007, 266: 149-157.
[5] S. Anandan, A. Vinu, T. Mori, N. Grokulakrishnan, P. Srinivasu, V. Murugesan, K. Ariga. Photocatalytic degradation of 2,4,6-trichlorophenol using lanthanum doped ZnO in aqueous solution[J]. Catalysis Communication, 2007, 8: 1377-1382.
[6] K. Tennakone, J. Bandara. Photocatalytic activity of dye-sensitized tin(Ⅵ) oxide nanocrystalline particles attached to zinc oxide particles: long distance electron transfer via ballistic transport of electrons across nanocrystallites[J]. Applied Catalysis A: General, 2001, 208: 335-341.
[7]周广.配位均匀沉淀法制备Ag/ZnO纳米复合材料及其应用研究[D],湘潭大学,2007.
[8]张金龙,陈锋等.光催化[M],华东理工大学出版社,2004.
[9]万益群,钟已未,郭岚,付敏恭.网络状纳米氧化锌光催化降解水中有机染料的研究[J].分析科学学报, 2007, 23(1): 48-50.
[10] WANG Biao,ZHAO YuDong,HU LiMing,CAO JunSheng,GAO FengLi,LIU Yun,WANG LiJun. Improved and excellent CO sensing properties of Cu-doped TiO_2 nanofibers[J]. Chinese Science Bulletin, 2010, 55(3): 228-232.
[11] N. Sobana, M. Swaminathan. Combination effect of ZnO and activated carbon for solar assisted photocatalytic degradation of Direct Blue 53[J] . Solar Energy Materials & Solar Cells, 2007, 91: 727–734.
[12] Di Li, Hajime Haneda. Enhancement of photocatalytic activity of sprayed nitrogen-containing ZnO powders by coupling with metal oxides during the acetaldehyde decomposition[J]. Chemosphere, 2004, 54: 1099-1110.
[13] Lirong Zheng,Yuanhui Zheng,Chongqi Chen,Yingying Zhan,Xingyi Lin,Qi Zheng,Kemei Wei, Jiefang Zhu. Network Structured SnO_2/ZnO Heterojunction Nanocatalyst with High Photocatalytic Activity[J]. Inorganic Chemistry, 2009, 48: 1819-1825.
[14] Weiwei Lu, Shuyan Gao, Jianji Wang. One-Pot Synthesis of Ag/ZnO Self-Assembled 3D Hollow Microspheres with Enhanced Photocatalytic Performance[J]. J. Phys. Chem. C, 2008, 112, 16792–16800.
[15] Fujishima A, Honda K. Electrochemical Photolysis of Water at a semiconductor Electrode[J]. Nature, 1972, 238(5358): 37.
[16] Bing-zhi LI, Xiang-yang XU, Liang ZHU. Catalytic ozonation-biological coupled processes for the treatment of industrial wastewater containing refractory chlorinated nitroaromatic compounds[J]. Journal of Zhejiang University-SCIENCE B (Biomedicine & Biotechnology), 2010, 11(3):177-189.
[17] S.K. Kansal a, M. Singh, D. Sud. Studies on photodegradation of two commercial dyes in aqueous phase using different photocatalysts[J]. Journal of Hazardous Materials , 2007, 141: 581–590.
[18]苏碧桃,胡常林,左显维,雷自强.纳米氧化锌的制备及其在太阳光下的光催化性能[J].无机化学学报, 2010, 26(1): 96-100.
[19] A. Akyol, H.C. Yatmaz, M. Bayramoglu. Photocatalytic decolorization of Remazol Red RR in aqueous ZnO suspensions[J]. Applied Catalysis B: Environmental, 2004, 54: 19–24.
[20] Liwu Zhang, Hanyun Cheng, Ruilong Zong, and Yongfa Zhu. Photocorrosion Suppression of ZnO Nanoparticles via Hybridization with Graphite-like Carbon and Enhanced Photocatalytic Activity[J]. J. Phys. Chem. C, 2009, 113, 2368–2374.
[21] Luyan Li, Weihua Wang, Hui Liu, Xindian Liu, Qinggong Song, Shiwei Ren. First PrinciplesCalculations of Electronic Band Structure and Optical Properties of Cr-Doped ZnO[J]. J. Phys. Chem. C, 2009, 113, 8460–8464.
[22]张茂林,安太成,胡晓洪,王存,王新明,盛国英,傅家谟.泡沫镍负载纳米ZnO-SnO_2光催化降解三氯乙烯[J].环境科学学报, 2005, 25(2): 259-263.
[23] Mingyuan Gao, Xi Zhang, Bai Yang, Feng Li, Jiacong Shen. Assembly of modified CdS particles /cationic polymer based on electrostatic interactions[J] . Thin Solid Films, 1996, 242-245.
[24]王铮,李凤亭.纳米氧化锆/氧化锌光催化降解酸性红B的研究[J].无机盐工业,2007,39(6):47-50.
[25]侯春燕. ZnO纳米材料的制备及其光催化降解有机废水的研究[D],大连海事大学,2006.
[26]夏荣花.锡钛复合氧化物光催化性能研究[D],山东师范大学,2007.
[27]申利春.纳米SnO_2/ZnO复合光催化剂的制备、表征及其光催化活性[D],贵州大学,2008:
[28] Di Li, Hajime Haneda. Synthesis of nitrogen-containing ZnO powders by spray pyrolysis and their visible-light photocatalysis in gas-phase acetaldehyde decomposition[J]. Journal of Photochemistry and Photobiology A:Chemistry, 2003, 155 :171–178.
[29] Jorge Villasenor, Hector D. Mansilla. Effect of temperature on kraft black liquor degradation by ZnO-photoassisted catalysis[J]. Journal of Photochemistry and Phtobiology A: Chemistry, 2006, 93: 205-209.
[30]倪星元,沈军等.纳米材料的理化特性与应用[M],化学工业出版社,2006.
[31]马正先,韩跃新,印万忠,王泽云,马云东.纳米氧化锌光催化氧化活性黄的研究[J].有色矿冶, 2005, 21(增刊): 123-128.
[32]刘守新,刘鸿.光催化剂光电催化基础与应用[M],化学工业出版社,2006.
[33] A. Akyol, M. Bayramoglu. Photocatalytic degradation of Remazol Red F3B using ZnO catalyst[J]. Journal of Hazardous Materials B, 2005, 124: 241–246.
[34]刘春艳.纳米光催化剂光催化环境净化材料[M],化学工业出版社,2008.
[35]邵金璐,卢秀萍.纳米ZnO的应用研究[J].浙江化工,2005,36(10):21-24.
[36]高振伟,周易,陈永娟.印染废水的光催化氧化研究现状及其进展[J].工业安全与环保, 2008, 34(6): 10-12.
[37]李镇江,岑伟,郭峰,孟阿兰. ZnO/Ag纳米复合抗菌剂的分散与性能研究[J].功能材料,2007, 38(增刊):3430-3432.
[38]韩绪军,张立波,冯悦,唐颖蕾,魏大巧,彭金辉,夏雪山.载ZnO /活性碳复合材料抗菌性能及安全性研究[J].生物技术通报, 2010, 1: 200-204.
[39]李镇江,郭峰,孟阿兰,李荣先,梁开明.工艺参数对ZnO/Ag合成纳米复合抗菌剂产率的影响[J].稀有金属材料与工程, 2007, 36(增刊): 293-295.
[40]吴佳卿,郑敏.氮掺杂ZnO纳米晶的防紫外和抗菌整理[J].印染, 2008, 10: 9-12.
[41]姜虎生,吴南.纳米氧化锌对废水中Cu~(2+)、Cd~(2+)吸附性能的研究[J].长春理工大学学报(自然科学版), 2008, 31(1): 139-141.
[42]周晓红,赵秀琴.氧化锌光催化降解六种可溶性染料的研究[J].安庆师范学院(自然科学版), 2003, 9(2): 4-6.
[43]宫江宁,廖莉玲,任绍成. SnO_2-TiO_2光催化剂的制备及其对两种染料废水降解作用的研究[J].贵州师范大学学报(自然科学版), 2009, 27(4): 37-40.
[44]顾晓梅,李淑华.半导体光催化效应在染料废水处理中的应用[J].纺织科技进展,2006,1: 22-24.
[45]钟已未,万益群,付敏恭,郭岚.纳米氧化锌光催化降解有机染料性能的研究[J].分析实验室, 2006, 25(12): 30-34.
[46]张江娜.纳米氧化锌的制备及其在水处理方面的应用[J].广州化工, 2009, 37(9): 190-191.
[47]刘亚兰,活性炭纤维负载二氧化钛光催化剂的制备及性能评价,东北林业大学博士学位论文[D],2009.
[48]王凯,周柞万,刘菁菁,李艳霞.一维纳米结构ZnO掺杂的研究进展[J].材料科学与工程学报, 2006, 24(3): 472-476.
[49] ZHOU Yin, WANG Yu, LU Shi-xiang, XU Wen-guo, SU Su. Photocatalytic Degradation of Reactive Brilliant Blue X-BR with La~(3+), Al~(3+) Co-doped ZnO nanoparticles[J]. Journal of synithetic crystals, 2009, 38(4): 998-1007.
[50]杨合,薛向欣,赵娜,左良,杨中东.半导体多相光催化技术研究进展[J].环境保护,2003, 6:22-24.
[51]黄苏萍,肖奇.可见光响应金属氧化物光催化剂的研究进展[J].材料导报,2009,23(1):28-32.
[52]韩兆慧,赵化侨.半导体多相光催化应用研究进展[J].化学进展, 1999, 11(1): 1-10.
[53] Chen Shifu,ZhaoWei ,Zhang Sujuan,LiuWei. Preparation, characterization and photocatalytic activity of N-containing ZnO powder[J]. Chemical Engineering Journal, 2009, 148: 263–269.
[54]赵铧,李韦,刘高斌,熊稳,王伟,郭富胜. ZnO纳米材料及掺杂ZnO材料的最新进展[J].材料导报, 2007, 21(9): 105-113.
[55]戴护民,桂阳海.气、光敏材料ZnO的掺杂改性研究[J].材料导报, 2006, 20(6): 21-23.
[56]刘红,刘潘,辜孔良,李晶,孙璇.锆改性纳米TiO_2的光催化性能研究[J].工业安全与环保, 2006, 32(7): 18-20.
[57]刘国光,郭小阳,郑立庆,毛小权,娄淑芳,张志军. Zr/TiO_2纳米管的制备及其光催化性能的初步研究[J].环境科学学报, 2008, 28(4):710-713.
[58]孟阿兰,岑伟,李镇江,李荣先. ZnO/Ag纳米复合材料光催化性能[J].稀有金属材料与工程, 2007, 36(2): 299-302.
[59]汪荣华,刘洪芳,许立铭,胡军辉,胡木林,谢长生. Ag~+/ZnO纳米晶的制备及对亚甲基蓝的异相光催化行为[J].华中师范大学学报(自然科学版),2003, 37(4): 510-513.
[60]刘宏芳,汪德顺,唐和清,张崎. H_2O_2增效Ag~+掺杂ZnO纳米晶光催化体系降解亚甲基蓝[J].华中科技大学学报(自然科学版),2007, 35(10): 101-104.
[61] Ronghua Wang, John Haozhong Xin, Yang Yang, Hongfang Liu, Liming Xu, Junhui Hu. The characteristics and photocatalytic activities of silver doped ZnO nanocrystallites[J]. Applied Surface Science, 2004, 227: 312–317
[62]张靖峰,杜志平,赵永红,台秀梅. Fe~(3+)改性纳米ZnO光催化降解壬基分聚氧乙烯醚[J].催化学报, 2007, 28(6): 561-566.
[63]刘英,梁英.水热合成Fe~(3+)掺杂ZnO复合材料及其光催化活性[J].应用化学,2009,26(10):1247-1249.
[64]李洪杰,杨凤珠,柳闽生,潘洁.铁掺杂氧化锌纳米晶的制备及其光催化性能的研究[J].化工时刊, 2009, 23(8): 16-19.
[65]朱斌,张明月,王莅,邹志军,张香文,米镇涛.镧掺杂ZnO/TiO_2催化降解冰片二烯异构化反应研究[J].中国稀土学报,2008,26(3):267-271.
[66]王智宇,郭晓瑞,唐培松,将玉龙,苏长胜. La~(3+)离子掺杂对纳米ZnO光催化性能的影响[J].材料导报, 2004, 18(7): 87-89.
[67]周艺,钟选斌,杨波,朱志平. Y~(3+)掺杂ZnO/TiO_2复合纳米光催化剂的研究[J].湖南师范大学自然科学报, 2008, 31(2): 87-90.
[68]周银,徐文国,卢士香,张光友.掺钕纳米氧化锌光催化降解偏二甲阱污水[J].北京理工大学学报, 2009, 29(3): 266-269.
[69] Xi Chen, Bing Yan. Induced synthesis of ZnO:Tb~(3+) green hybrid phosphors by the assembly of polyethylene glycol matrices[J]. Materials Letters, 2007, 61: 1707–1710.
[70]井立强,蔡伟民,孙晓君,侯海鸽,徐自立,杜尧国. Pd/ZnO和Ag/ZnO复合纳米粒子的制备、表征及光催化活性[J].催化学报, 2002, 23(4): 336-340.
[71]王建鑫,罗来涛. Au/ZnO,Pd/ZnO和Au-Pd/ZnO催化甲醇部分氧化[J].稀有金属,2009,33(2): 247-251.
[72]韩婧,施立毅,成荣明,陈奕卫,董鹏飞,邵启伟. Ag改性纳米ZnO薄膜及光催化活性[J].无机化学学报, 2008, 24(6): 950-955.
[73]素珺,张青红,李耀刚,王宏志.氧化锌、镁铝复合氧化物的制备及光催化性能[J].无机化学学报, 2009, 25(11): 1977-1981.
[74]徐甲强,高巧欢,王培义,向群.氧化锌/偏锡酸锌复合氧化物的制备与光催化性能[J].硅酸盐学报, 2007, 35(6): 741-745.
[75]娄向东,赵晓华,成庆堂.复合氧化物光催化研究进展[J].化学研究与应用, 2003, 15(4): 447-450.
[76] Chun Cheng, Kai Feng Yu, Yuan Cai, Kwok Kwong Fung, Ning Wang. Site-Specific Deposition of Titanium Oxide on Zinc Oxide Nanorods[J]. J. Phys. Chem. C, 2007, 111, 16712-16716.
[77]张灵灵,王艳华,白雪峰. CdS/ZnO复合光催化剂催化分解硫化氢制氢研究[J].化学与黏合, 2008, 30(6): 5-9.
[78]马占营,姚秉华,何仰清,范广. ZnO-PFD纳米复合材料的制备及其光催化性能[J].精细化工, 2009, 26(9): 838-843.
[79]胡利利,杜志平,邰秀梅,李秋小,赵永红.纳米V_2O_5/ZnO光催化剂对壬基酚聚氧乙烯醚降解的催化活性[J].催化学报, 2008, 29(6): 571-576.
[80]刘亚子,李新勇,孙成,杨绍贵,全燮.纳米复合ZnO-TiO_2晶体的制备及其光电催化性能的研究[J].环境污染治理技术与设备, 2005, 6(4): 36-43.
[81]赵子淇,张萍,李哲,邹佳宏.不同钛比对纳米碳酸锌(ZnO-TiO_2)体系成分的影响[J].材料导报, 2007, 21(8): 168-170.
[82] Da Chen,Hao Zhang,Song Hu,Jinghong Li. Preparation and Enhanced Photoelectrochemical Performance of Coupled Bicomponent ZnO-TiO_2 Nanocomposites[J]. J. Phys. Chem. C , 2008, 112, 117-122.
[83] Patricia Peralta-Zamora, Sandra Gomes de Moraes, Ronaldo Pelegrinir, Mariwalde Freire Jr.,Juan Reyes, Hector Mansilla, Nelson Duran. Evaluation of ZnO-TiO_2 and supported on the photoassisted remediation of black liquor, cellulose and textile mill effluents[J]. Chemosphere, 1998, 36(9): 2119-2133.
[84] S.K. Kansal, M. Singh, D. Sud. Studies on TiO_2/ZnO photocatalysed degradation of lignin[J]. Journal of Hazardous Materials, 2008, 153: 412–417.
[85]施利毅,古宏晨,李春忠,房鼎业,张怡,华彬. SnO_2-TiO_2复合光催化剂的制备和性能[J].催化学报, 1995, 20(3): 338-342.
[86]李顺华,郭海福,闫鹏. SnO_2/TiO_2复合氧化物制备及其光催化性能研究[J].广东化工,2009, 36(10): 31-33.
[87] ZHANG Jingchang,FENG Liye,WEI Jia,GUO Xuehua , CAO Weiliang. Synthesis of SnO_2/TiO_2 nanocomposite photocatalysts by supercritical fluid combination technology[J]. Chinese Science Bulletin, 2006, 51(17): 2050—2054.
[88]石照信,石亨达,王思林,孙剑飞.纳米ZnO/Al_2O_3复合氧化物的制备及其光催化性能[J].沈阳化工学院学报, 2008, 22(3): 193-199.
[89]周建伟,黄建新,王金娜,李洁.纳米ZnO/膨润土光催化降解亚甲基蓝研究[J].应用化工, 2008, 37(9): 1063-1066.
[90]张丽敏,陈清松,李晓燕,丁富传.竹炭-ZnO复合材料的制备及对苯酚的光催化降解作用[J].林产化学与工业, 2009, 29(1): 33-38.
[91]李镇江,郭峰,孟阿兰,李荣先,梁开明.工艺参数对合成ZnO/Ag纳米复合抗菌剂产率的影响[J].稀有金属材料与工程, 2007, 36(2): 293-295.
[92]夏璐.光催化光敏化氧化含酚含氯废水的研究[J].化学与生物工程,2004,5:16-18.
[93]张伟. TiO_2光敏化研究进展[J].广东化工, 2009, 36(199): 94-97.
[94]张璐璐,ZnO纳米粒子的制备、表面修饰及光催化性能的研究[D],哈尔滨工程大学,2007.
[95]周天亮,宋绵新,敬晓峰,边亮,王峰. TiO_2/沸石光催化性能的研究[J].太阳能学报, 2006, 27(12): 1270-1275.
[96]胡海,泡沫金属负载纳米TiO_2的制备、表征及其光催化性能的研究[D],上海交通大学,2007.
[97]林婷,刘国光. TiO_2光催化剂负载方式及气相反应器的研究[J].工业安全与环保,2008,34(4): 1-4.
[98]梁世强,穆筱梅,葛建芳.活性炭纤维负载纳米TiO_2在光反应器中降解空气中微量甲醛的研究[J].精细化工, 2006, 23(5): 456-459.
[99]王超,徐新,罗国华.纳米Au/ZnO/TiO_2催化剂对富氢气体中CO选择性氧化[J].石油化工高等学校校报, 2007, 20(1): 63-66.
[100]叶志镇,吕建国等.氧化锌半导体材料掺杂技术与应用[M],浙江大学出版社,2009.
[101] Zijie Yan, Yanwei Ma, Dongliang Wang, Junhong Wang, Zhaoshun Gao, Tao Song. Surfactant-Free Fabrication of ZnO Spheres and Pseudospherical Structures[J]. J. Phys. Chem. C, 2008, 112, 9219–9222 9219.
[102] Wei-De Zhang, Liao-Chuan Jiang, Jian-Shan Ye. Photoelectrochemical Study on Charge Transfer Properties of ZnO Nanowires Promoted by Carbon Nanotubes[J]. J. Phys. Chem. C, 2009, 113, 16247–16253.
[103]马书懿,毛雷鸣,马慧,史新福,周婷婷,丁继军. Cu掺杂对ZnO纳米薄膜的结构及其光学特性的影响[J].西北师范大学学报(自然科学版), 2010, 46(1): 37-42.
[104] Laiho, Yu.P.Stepanov, M.P.Vlasenko, L.S.Vlasenko. Persistent photoconductivity of ZnO[J]. Physica B, 2009, 404: 4787–4790.
[105]叶彩,陶慧波,宫丽红,武祥.液相法合成ZnO纳米材料的研究进展[J].陶瓷学报, 2009, 30(1): 124-128.
[106]廉红蕾,潘维成,贾明君,蒋大振,张文祥,吴通好. ZnO负载纳米金催化剂上的低温水煤气变换反应[J].催化学报, 2005, 26(11): 999-1004.
[107]苏彤.超细氧化锌应用拓展[J].化工中间体, 2003, 5: 21-22.
[108]杨凤霞,刘其丽,毕磊.纳米氧化锌的应用综述[J].安徽化工, 2006, 1: 13-17.
[109]张留成,蔡克峰.纳米氧化锌材料的最新研究和应用进展[J].材料导报, 2006, 20(6):13-23.
[110]马正先,韩跃新,郑龙熙,刘建彬.纳米氧化锌的应用研究[J].化工进展,2002,21(2):60-69.
[111]王久亮,刘宽,秦秀娟,邵光杰.纳米氧化锌的应用研究展望[J].哈尔滨工业大学学报, 2004, 36(2):226-230.
[112]方佑龄,赵文宽,陈兴凡.肤色超微粉末氧化锌的制备[J].涂料工业, 1991, 4: 4-7.
[113] Di Li, Hajime Haneda. Morphologies of zinc oxide particles and their effects on photocatalysis[J]. Chemosphere, 2003, 51: 129-137.
[114]徐波,王树林,李来强,李生娟.纳米Zn/ZnO复合结构的光催化活性[J].功能材料,2010, 41(2):307-310.
[115] Cristian Lizama, Juanita Freer, Jaime Baeza, Héctor D. Mansilla. Optimized photodegradation of Reactive Blue 19 on TiO_2 and ZnO suspensions[J]. Catalysis Today, 2002, 76: 235–246
[116]黄焱球,刘梅冬,李楚容,曾亦可,刘少波,夏冬林. ZnO陶瓷薄膜的制备及其低压压敏性质[J].压电与声光, 2001, 23(5): 384-386.
[117]周广,邓建成.配位均匀沉淀法制备Ag/ZnO纳米复合材料的研究[J].功能材料,2007,38(4): 665-668.
[118]孟庆明,马迪,李建章,钟俊波.沉淀法制备纳米ZnO及光催化甲基橙脱色研究[J].化学工程师, 2010, 1: 4-6.
[119]成庆堂,李峰,姚超,徐斌海.纳米氧化锌的制备[J].化工新型材料,2008, 36(2): 44-46.
[120]洪若瑜,徐丽萍,任志强,李忻,李洪钟.纳米氧化锌的制备及其光催化活性研究[J].化工环保, 2005, 25(3): 231-234.
[121]廖莉玲,刘吉平.纳米氧化锌制备方法比较[J].贵州化工, 2002, 27(3): 1-13.
[122]张永康,刘建本,易保华,陈德根,肖卓炳,陈上.常温固相法合成纳米氧化锌[J].精细化工, 2000, 17(6): 343-345.
[123]沈茹娟,贾殿增,梁凯,忻新泉,王疆英.纳米氧化锌的固相合成及其气敏特性[J].无机化学学报, 2000, 16(6): 906-910.
[124]赵新宇,郑柏存,李春忠,胡黎明,古宏晨.喷雾热解合成ZnO超细粒子工艺及机理研究[J].无机材料学报, 1996, 11(4) :611-616.
[125] El-Shall M S,Slack W,Vann W,Kenne D,Hanley D. Sythesis of nanoscale metal oxide partical using laser vaporization/condensation in a diffusion cloud chanmber[J],J. Phys. Chem. C, 1994, 98(12): 3067-3070.
[126]赵春,钟顺和. Cu/ZnO-TiO_2复合半导体光催化材料的制备与表征[J].无机化学学报, 2004, 20(9): 1131-1136.
[127]张月甫,李玉国,薛成山,张敬尧,崔传文.纳米氧化锌的制备技术及其应用前景[J].山东师范大学学报(自然科学版), 2008, 3(2): 39-42.
[128]郭书霞,张兴堂,赵慧玲,李蕴才,黄亚彬,杜祖亮.纳米氧化锌的制备及发光特性的研究[J].无机化学学报, 2006, 22(4): 724-728.
[129]关敏,李彦生.国内外纳米ZnO研究和制备概括[J].化工新型材料,2005,33(2) :18-21.
[130]冯洁.乳化-前驱物热分解法制备纳米氧化锌[J].光谱实验室, 2004, 21(3): 442-444.
[131]颜肖慈,余林颇,罗春霞,薛东波,罗明道.纳米氧化锌微乳液法的研究和表征[J].十堰职业技术学院学报, 2002, 15(2): 67-68.
[132]包小波,袁爱华.纳米ZnO的制备及其光催化降解酸性红B[J].当代化工, 2009, 38(6): 575-578.
[133]郝彦忠.花状纳米氧化锌的制备及其光电性能的研究[J].功能材料, 2008, 39(1):83-85.
[134]袁爱华,包小波,唐丽,周虎.水热法制备ZnO纳米棒及其光催化性能研究[J].化学研究与应用, 2008, 20(2): 122-125.
[135]刘春莲,林深,张晓凤,张晓勤,江菊琼.以PAMAM树形分子为模型纳米氧化锌的制备及其光催化性能研究[J].功能材料, 2007, 38(4): 672-675.
[136]关敏,李彦生.国内外纳米ZnO研究和制备概括[J].化工新型材料,2005,33(2): 18-21.
[137] Cristina Yeber, Jaime Rodr_(o¨)guez, Juanita Freer, Nelson Duran, Hector D. Mansilla a. Photocatalytic degradation of cellulose bleaching e.uent by supported TiO_2 and ZnO[J]. Chemosphere, 2000, 41: 1193-1197.
[138] Shunjun Li, Zichuan Ma, Jie Zhang, Yinsu Wu, Yamin Gong. A comparative study of photocatalytic degradation of phenol of TiO_2 and ZnO in the presence of manganese dioxides[J]. Catalysis Today, 2008, 139: 109–112.
[139] Liqiang Jing, Zili Xu, Xiaojun Sun, Jing Shang, Weimin Cai. The surface properties and photocatalytic activities of ZnO ultrafine particles[J]. Applied Surface Science, 2001, 180: 308-314.
[1] Changhui Ye,Yoshio Bando,Xiaosheng Fang,Guozhen Shen,Dmitri Golberg. Enhanced Field Emission Performance of ZnO Nanorods by Two Alternative Approaches[J]. J. Phys. Chem. C, 2007, 111, 12673-12676.
[2] Hao Zhang, Ruilong Zong, and Yongfa Zhu. Photocorrosion Inhibition and Photoactivity Enhancement for Zinc Oxide via Hybridization with Monolayer Polyaniline[J]. J. Phys. Chem. C , 2009, 113, 4605–4611.
[3] Nikolai Kislov, Jayeeta Lahiri, Himanshu Verma, D. Yogi Goswami, Elias Stefanakos, Matthias Batzill. Photocatalytic Degradation of Methyl Orange over Single CrystallineZnO: Orientation Dependence of Photoactivity and Photostability of ZnO[J]. Langmuir , 2009, 25, 3310-3315.
[4]吕红金,江萍,刘宇珊,李敏,彭天右.不同形貌纳米ZnO的合成及其光催化性能研究[J].功能材料, 2010, 41(2): 292-295.
[5]王幸宜.催化剂表征[M],华东理工大学出版社,2008.
[6]夏荣花.锡钛复合氧化物光催化性能研究[D],山东师范大学,2007.
[7] J.R.安德森等.催化剂表征与测试,烃加工出版社,1989,北京.
[8]刘俊,徐志兵,王燕群.纳米氧化锌的制备及其光催化性能研究[J].合肥工业大学学报(自然科学版), 2008, 31(6): 898-901.
[9]周广.配位均匀沉淀法制备Ag/ZnO纳米复合材料及其应用研究[D],湘潭大学,2007.
[10] ZHU Zhenqi, ZHOU Jian, LIU Guizhen, JIANG Yurong. Growth of ZnO Sub-millimeter Crystals by Microwave Heating[J]. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2010, 2: 94-98.
[11]张靖峰,杜志平,赵永红,台秀梅,冯春波.纳米氧化锌光催化降解壬基酚聚氧乙烯醚[J].日用化学工业, 2007, 37(1): 16-19.
[12]卫兵,陈剑松,廖静,宗俊.超声波直接沉淀法制备纳米氧化锌及改性研究[J].无机盐工业, 2008, 40(3): 20-29.
[13]刘家祥,丁德玲,王震,韩跃新.均匀沉淀法制备纳米氧化锌[J].有色金属, 2006, 58(1): 49-52.
[14]王振希,郑典模,李建敏,范敏,刘明,庄叶凯.直接沉淀法制备纳米氧化锌工艺研究[J].无机盐工业, 2006, 38(9): 40-42.
[15]辛显双,周百斌,邵纯红,徐学勤.纳米ZnO制备过程中的热处理条件分析[J].化学与粘合, 2002, 6: 261-266.
[16]黄焱球,刘梅冬,李楚容,曾亦可,刘少波,夏冬林. ZnO陶瓷薄膜的制备及其低压压敏性质[J].压电与声光, 2001, 23(5): 384-386.
[17]徐华军.纳米氧化锌的制备[D],无锡轻工业大学,2000.
[18]申利春.纳米SnO_2/ZnO复合光催化剂的制备、表征及其光催化活性[D],贵州大学,2008.
[19]苏苏,卢士香,徐文国.铝掺杂纳米ZnO颗粒光催化降解活性艳兰X-BR[J].过程工程学报, 2008, 8(1): 54-59.
[1] Di Li, Hajime Haneda. Enhancement of photocatalytic activity of sprayed nitrogen-containing ZnO powders by coupling with metal oxides during the acetaldehyde decomposition[J]. Chemosphere, 2004, 54: 1099-1110.
[2] Di Li, Hajime Haneda. Synthesis of nitrogen-containing ZnO powders by spray pyrolysis and their visible-light photocatalysis in gas-phase acetaldehyde decomposition[J]. Journal of Photochemistry and Photobiology A: Chemistry, 2003, 155: 171–178.
[3] Sohn Jong Rack,Lee Si Hoon. Acidic properties of nickel sulfate supported on TiO_2-ZrO2 and catalytic activity for acid catalysis[J]. Applied Catalysis A: General, 2004, 266(1): 89-97.
[4] Mao Dongsen,Lu Guanzhong,Chen Qingling. Influence of calcination temperature and preparation method of TiO_2-ZrO2 on conversion of cyclohexanone oxime to -caprolactam over B2O3/TiO_2-ZrO2 catalyst[J]. Applied Catalysis A: General, 2004, 263(1): 83-89.
[5]李莉,马禹,曹艳珍,张文治,郭伊荇.纳米复合光催化剂TiO_2-ZrO2的制备、表征及光催化活性[J].化学通报, 2009, 6: 529-533.
[6]李莉,陆丹,李恩帅.纳米材料ZrO_2微波增强光催化降解染料[J].齐齐哈尔大学学报, 2009, 6: 19-20.
[7]陈姗姗,李怀祥,曲丕丞.锆掺杂纳米ZnO粉体的制备及其光催化性能[J].纳米科技, 2009, 6(6): 16-20.
[8]张靖峰,杜志平,赵永红,台秀梅,冯春波.纳米氧化锌光催化降解壬基酚聚氧乙烯醚[J].日用化学工业, 2007, 37(1): 16-19.
[9] LIU Hang , ZHUANG Hui zhao , XUE Cheng-shan , WANG Jie , LI Jun-lin. Synthesis and Properties of Mg-doped ZnO Nanobelts[J]. Semiconductor Phtonics and Technology, 2009, 15(4): 225-228.
[10]师磊.掺杂工艺对Al-F共掺ZnO薄膜性能的影响[J].国外建材科技, 2008, 29(2): 56-63.
[11]张靖峰,杜志平,赵永红,台秀梅. Fe3+改性纳米ZnO光催化降解壬基分聚氧乙烯醚[J].催化学报, 2007, 28(6): 561-566.
[12]王铮.复合光催化剂的制备及其降解水中染料的应用研究[D],同济大学,2007.
[13]朱卫兵,陈剑松,廖静,宗俊.超声波直接沉淀法制备纳米氧化锌及改性研究[J].无机盐工业, 2008, 40(3): 20-29.
[14]刘家祥,丁德玲,王震,韩跃新.均匀沉淀法制备纳米氧化锌[J].有色金属, 2006, 58(1): 49-52.
[15]申利春.纳米SnO_2/ZnO复合光催化剂的制备、表征及其光催化活性[D],贵州大学, 2008.
[16]成莉燕,杨武,薛再兰,高锦章.坡缕石负载ZnO/SnO_2光催化剂的制备及光催化性能的研究[J].西北师范大学学报(自然科学版), 2008, 44(6): 86-90.
[17] HUAI-XIANG LI, RONG-HUA XIA, ZHENG-WEI JIANG,SHAN-SHAN CHEN, DE-ZHAN CHEN.Optical absorption property and photo-catalytic activity of tin dioxide-doped titanium dioxides [J]. Chinese journal of chemistry, 2008, 26, 1787-1792.
[18]周秉明,申利春,曹建新.纳米SnO_2/ZnO复合氧化物的制备及制备条件对光催化性能的影响[J].化学研究与应用, 2008, 20(6): 705-709.
[19]王智宇,郭晓瑞,唐培松,将玉龙,苏长胜. La~(3+)离子掺杂对纳米ZnO光催化性能的影响[J].材料导报, 2004, 18(7): 87-89.
[20]刘守新,孙承林.光催化剂TiO_2改性的研究进展[J].东北林业大学学报, 2003, 31(1): 53-56.
[21]毕怀庆,袁文辉,韦朝海.掺锆纳米TiO_2制备表征及其对光催化活性的影响[J].材料科学与工程学报, 2004 22(1): 98-101.
[22]夏宇正,朱也莉,石淑先,焦书科.纳米二氧化锆的制备及其光学性能研究[J].涂料工业, 2006, 36(8): 13-16.
[23] Zuo Xiang-Qing, Li Huai-Xiang, Chen Lu-Sheng, Zhou Hong-Wei, Xia Rong-Hua,Doping effect on the grain growth of spinel LiMn_2O_4 prepared by sol-gel methods[J],CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2007, 26(9): 1017-1022.
[24]何则强,熊利之.纳米SnO_2的非水溶剂溶胶-凝胶法制备与表征[J],无机化学学报, 2005, 21: 1691-1696.
[1]徐杰,鄂磊.半导体复合型ZnO/SnO_2光催化剂的制备[J].创新技术, 2009, 6: 19-20.
[2] Jiang Bin XIA, Fu You LI, Shu Ming YANG, Chun Hui HUANG. Composite Electrode SnO_2/TiO_2 for Dye-Sensitized Solar Cells[J]. Chinese Chemical Letters , 2004 ,15(5): 619-622.
[3]颜秀茹,李晓红,霍明亮,郭伟巍,巩永进.纳米SnO_2-TiO_2的制备及其光催化性能[J].物理化学学报, 2001, 17(1): 23-28.
[4]颜秀茹,白天,霍明亮,张月萍,郭秀盈.核-壳式纳米SnO_2/ TiO_2光催化剂的制备和性能[J].催化学报, 2004, 25(2): 120-124.
[5] Wang Cun, Zhao Jincai, Wang Xinming, Mai Bixian, Sheng Guoying, Peng Ping’an, Fu Jiamo. Preparation ,characterization and photocatalytic activity of nana-sized ZnO/SnO_2 coupled photocatalysts[J]. Applied CatayusisB:Environmented, 2002, 39: 269-279.
[6] J. Bandara, K. Tennakone, P.P.B. Jayatilaka. Composite Tin and Zinc oxide nanocrystalline particles for enhanced charge separation in sensitized degradation of dyed[J]. Chemosphere, 2002 ,49: 439-445.
[7] Lirong Zheng,Yuanhui Zheng,Chongqi Chen,Yingying Zhan,Xingyi Lin,Qi Zheng,Kemei Wei, Jiefang Zhu. Network Structured SnO_2/ZnO Heterojunction Nanocatalyst with High Photocatalytic Activity[J]. Inorganic Chemistry, 2009, 48: 1819 -1825.
[8]周秉明,申利春,曹建新.纳米SnO_2/ZnO复合氧化物的制备及制备条件对光催化性能的影响[J].化学研究与应用, 2008, 20(6): 705-709.
[9]王存,王鹏,徐柏庆. ZnO-SnO_2纳米复合氧化物光催化剂催化降解对硝基苯胺[J].催化学报, 2004, 259(12): 967-972.
[10]周秉明,申利春.复合纳米SnO_2/ZnO光催化降解酿酒废水的研究[J].酿酒科技, 2008, 6: 128-130.
[11]成莉燕,杨武,薛再兰,高锦章.坡缕石负载ZnO/SnO_2光催化剂的制备及光催化性能研究[J].西北师范大学学报(自然科学版), 2008, 44(4): 86-90.
[12]刘家祥,丁德玲,王震,韩跃新.均匀沉淀法制备纳米氧化锌[J].有色金属, 2006, 58(1): 49-52.
[13]张茂林,安太成,胡晓洪,王存,王新明,胜国英,傅家谟.泡沫镍负载ZnO-SnO_2光催化降解三氯乙烯[J].环境科学学报, 2005, 25(2): 259-263.
[14]程刚,周孝德,李艳,仝攀瑞,王理明.纳米ZnO-TiO_2复合半导体的La3+改性及其光催化性能的研究[J].催化学报, 2007, 28(10):885-889.
[15]申利春.纳米SnO_2/ZnO复合光催化剂的制备、表征及其光催化活性[D],贵州大学,2008.
[16]姜秀榕,温德才,胡志彪,童长青,周云龙,董雁. SnO_2/ZnO复合氧化物的制备及对亚甲基蓝的光催化性能研究[J].化学工程与设备, 2009, 11: 1-4.
[17] Eva M. Wong, John E. Bonevich, Peter C. Searson. Growth kinetics of nanocrystalline ZnO pariticles from Colloidal Suspensions[J]. J. Phys. Chem. B, 1998, 102: 7770-7775.
[18] Zuo Xiang-Qing, Li Huai-Xiang, Chen Lu-Sheng, Zhou Hong-Wei, Xia Rong-Hua,Doping effect on the grain growth of spinel LiMn_2O_4 prepared by sol-gel methods[J],CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2007,26(9): 1017-1022.
[19] HUAI-XIANG LI, RONG-HUA XIA, ZHENG-WEI JIANG,SHAN-SHAN CHEN, DE-ZHAN CHEN.Optical absorption property and photo-catalytic activity of tin dioxide-doped titanium dioxides [J]. Chinese journal of chemistry, 2008, 26, 1787-1792.