聚合物改性水泥基修补材料研究
|
摘要
水泥混凝土路面因其强度高,耐久性优良,成为我国公路路面两大类型之一,由于国民经济的发展和交通量的急剧增加,水泥混凝土路面破损也日益严重,尤其是路面裂缝最为普遍,混凝土路面裂缝不仅仅影响路面工程的美观,还严重影响路面行车安全及舒适；因此,对水泥混凝土路面裂缝进行修补,具有重要的意义。
结合国内外混凝土路面裂缝修补材料的研究进展,本课题通过聚合物乳液对水泥基材进行改性,来修补路面裂缝,以恢复路面使用功能。本文的主要研究内容与结论如下：
1、首先采用正交试验,以5min粘度及7d抗压强度为控制指标,通过三因素四水平正交表,利用四种聚合物乳液SBR、EAV、CB、SD对水泥基材料改性,初选改性乳液。羧基丁苯胶乳SBR改性后的水泥基材料,其5min粘度最小,7d抗压强度最高,改性效果最佳。通过正交试验,确定修补材料的初始配合比,在性能研究的基础上优化其配合比。结果表明：水灰比为0.42～0.45,聚合物掺量为5%～20%时,改性净浆的粘度随着聚合物掺量的增加先增大后减小,随时间的延长逐渐增大。聚合物的掺入能有效改善水泥浆体的可灌性,但对改性浆体的凝结时间有滞缓作用。
2、在优化修补材料配比的基础上,系统研究了聚合物掺量、水灰比等因素对性能的影响。研究表明：聚合物改性水泥砂浆的抗压强度随聚合物乳液掺量的增加而减小,抗折强度则先增大后减小。聚合物的加入能有效改善水泥砂浆的韧性,提高水泥砂浆的抗氯离子渗透性。
3、聚合物的掺入能降低水泥砂浆的干缩。改性水泥砂浆与普通水泥砂浆干缩变化趋势相似,前期收缩较大,后期逐渐平缓。改性水泥砂浆的收缩随着聚合物掺量的增加先减小后增大,聚合物掺量为10%时,改性水泥砂浆的收缩最小。
4、聚合物改性水泥净浆与水泥砂浆的粘结强度均高于普通水泥净浆与水泥砂浆,且随着聚合物掺量的增加均先增大后减小。当水灰比为0.42,聚合物掺量为10%时,改性浆体28d粘结强度较7d粘结强度增长达52%,同样比普通水泥浆体28d粘结强度提高达28%；对于改性水泥砂浆,聚合物掺量为5%～10%时,28d粘结强度较7d粘结强度增长了36%～38%,表明聚合物乳液能明显增加水泥基材料的粘结性能。
5、研究了五种不同的养护方式对聚合物改性水泥砂浆强度的影响,结果表明：聚合物改性砂浆的水养护时间不宜过长。先水养护3d,然后在干燥条件下养护对强度发展最为有利。
For high strength and good durability, cement concrete pavement has been one of two main types high way pavements in China. As a result of the national economys rapid development and the sharp growth of traffic volume, the breakage of centmet concrete pavement is in-creasingly serious, especially for the crack. The crack not merely affects the appearance of the pavement, but also the security and the comfortableness of driving. As a result, the repairing on cement concrete pavement is so significant in practice.
By Studying the crack filling material in concrete pavement at home and abroad, this paper takes polymer emulsion to modify cement, to repair the cracks in pavement and restore the pavement features. The main research contents and conclusions of this paper are as follows:
1. As the viscosity in 5min and compressive strength in 7d of crack filling material for controlling indicators, through orthogonal experiment, the paper at first selected the optimum modified cement-based material by three-factor and four-level from four Polymer emulsions:SRB、VAE、CB、SD. The results showed that:the best one was when cement modified with carboxylated SBR latex by orthogonal test, the viscosity in 5min was minimum and compressive strength in 7d maximum, and gotten the initial mixture proportion, based on the text of workability of the repair material to optimize the mixture proportion. The results showed that:The W/C was from 0.42 to 0.45 and the polymer content from 5% to 20%, the modified paste viscosity increased and then decreased with P/C increasing and increased with development of time. polymer emulsion could improve groutlbliity but stagnate the the setting time of modified paste.
2. Based on optimized mixture proportion of repair materials, this paper systematically studied the factors affecting the properties of repair material from polymer content,W/C and so on. The results showed that: the compressive strength of polymer modified mortar decreased with P/C increasing, the flexural strength at first rised and then decreased; and polymer emulsion could improve flexibility and resistance to chloride ion permeability of mortar.
3. Polymer emulsion can decrease the contraction of cement mortar, polymer modified mortar's shrinkage trends was similar to ordinary mortar, the pre-contraction was larger, and later steady, with increasing the polymer emulsion content, the contraction of modified mortar decreased first and then increased, when the P/C= 10%, the shrinkage of modified mortar was minimum.
4. From the research of interfacial bond strength on repair materials, it reveals that:the interfacial bond strength of polymer modified cement paste and mortar were higher than ordinary cement paste and mortar, with the increasing of polymer content polymer modified cement and mortar's interfacial bond strength increased first and then decreased. When the W/C=0.42, P/C=10%; the bond strength of modified cement paste increased up to 52% in 28d comparing with in 7d, up to 28% for reference cement paste in 28d; for modified mortar, when P/C increased from 5% to 10%, the bond strength in 28d increases from 36% to 38% than in 7d. It indicated that the polymer emulsion can improve the bonded performance of cement substrate significantly.
5. Researched five different curing system for polymer modified cement mortar's strength, the results showed that:the water-curing time of polymer modified mortar should not be too long, the best pre-conservation in water was 3d, the post-curing could be in dry conditions, so that it was best for the strength development of polymer modified mortar.
结合国内外混凝土路面裂缝修补材料的研究进展,本课题通过聚合物乳液对水泥基材进行改性,来修补路面裂缝,以恢复路面使用功能。本文的主要研究内容与结论如下：
1、首先采用正交试验,以5min粘度及7d抗压强度为控制指标,通过三因素四水平正交表,利用四种聚合物乳液SBR、EAV、CB、SD对水泥基材料改性,初选改性乳液。羧基丁苯胶乳SBR改性后的水泥基材料,其5min粘度最小,7d抗压强度最高,改性效果最佳。通过正交试验,确定修补材料的初始配合比,在性能研究的基础上优化其配合比。结果表明：水灰比为0.42～0.45,聚合物掺量为5%～20%时,改性净浆的粘度随着聚合物掺量的增加先增大后减小,随时间的延长逐渐增大。聚合物的掺入能有效改善水泥浆体的可灌性,但对改性浆体的凝结时间有滞缓作用。
2、在优化修补材料配比的基础上,系统研究了聚合物掺量、水灰比等因素对性能的影响。研究表明：聚合物改性水泥砂浆的抗压强度随聚合物乳液掺量的增加而减小,抗折强度则先增大后减小。聚合物的加入能有效改善水泥砂浆的韧性,提高水泥砂浆的抗氯离子渗透性。
3、聚合物的掺入能降低水泥砂浆的干缩。改性水泥砂浆与普通水泥砂浆干缩变化趋势相似,前期收缩较大,后期逐渐平缓。改性水泥砂浆的收缩随着聚合物掺量的增加先减小后增大,聚合物掺量为10%时,改性水泥砂浆的收缩最小。
4、聚合物改性水泥净浆与水泥砂浆的粘结强度均高于普通水泥净浆与水泥砂浆,且随着聚合物掺量的增加均先增大后减小。当水灰比为0.42,聚合物掺量为10%时,改性浆体28d粘结强度较7d粘结强度增长达52%,同样比普通水泥浆体28d粘结强度提高达28%；对于改性水泥砂浆,聚合物掺量为5%～10%时,28d粘结强度较7d粘结强度增长了36%～38%,表明聚合物乳液能明显增加水泥基材料的粘结性能。
5、研究了五种不同的养护方式对聚合物改性水泥砂浆强度的影响,结果表明：聚合物改性砂浆的水养护时间不宜过长。先水养护3d,然后在干燥条件下养护对强度发展最为有利。
For high strength and good durability, cement concrete pavement has been one of two main types high way pavements in China. As a result of the national economys rapid development and the sharp growth of traffic volume, the breakage of centmet concrete pavement is in-creasingly serious, especially for the crack. The crack not merely affects the appearance of the pavement, but also the security and the comfortableness of driving. As a result, the repairing on cement concrete pavement is so significant in practice.
By Studying the crack filling material in concrete pavement at home and abroad, this paper takes polymer emulsion to modify cement, to repair the cracks in pavement and restore the pavement features. The main research contents and conclusions of this paper are as follows:
1. As the viscosity in 5min and compressive strength in 7d of crack filling material for controlling indicators, through orthogonal experiment, the paper at first selected the optimum modified cement-based material by three-factor and four-level from four Polymer emulsions:SRB、VAE、CB、SD. The results showed that:the best one was when cement modified with carboxylated SBR latex by orthogonal test, the viscosity in 5min was minimum and compressive strength in 7d maximum, and gotten the initial mixture proportion, based on the text of workability of the repair material to optimize the mixture proportion. The results showed that:The W/C was from 0.42 to 0.45 and the polymer content from 5% to 20%, the modified paste viscosity increased and then decreased with P/C increasing and increased with development of time. polymer emulsion could improve groutlbliity but stagnate the the setting time of modified paste.
2. Based on optimized mixture proportion of repair materials, this paper systematically studied the factors affecting the properties of repair material from polymer content,W/C and so on. The results showed that: the compressive strength of polymer modified mortar decreased with P/C increasing, the flexural strength at first rised and then decreased; and polymer emulsion could improve flexibility and resistance to chloride ion permeability of mortar.
3. Polymer emulsion can decrease the contraction of cement mortar, polymer modified mortar's shrinkage trends was similar to ordinary mortar, the pre-contraction was larger, and later steady, with increasing the polymer emulsion content, the contraction of modified mortar decreased first and then increased, when the P/C= 10%, the shrinkage of modified mortar was minimum.
4. From the research of interfacial bond strength on repair materials, it reveals that:the interfacial bond strength of polymer modified cement paste and mortar were higher than ordinary cement paste and mortar, with the increasing of polymer content polymer modified cement and mortar's interfacial bond strength increased first and then decreased. When the W/C=0.42, P/C=10%; the bond strength of modified cement paste increased up to 52% in 28d comparing with in 7d, up to 28% for reference cement paste in 28d; for modified mortar, when P/C increased from 5% to 10%, the bond strength in 28d increases from 36% to 38% than in 7d. It indicated that the polymer emulsion can improve the bonded performance of cement substrate significantly.
5. Researched five different curing system for polymer modified cement mortar's strength, the results showed that:the water-curing time of polymer modified mortar should not be too long, the best pre-conservation in water was 3d, the post-curing could be in dry conditions, so that it was best for the strength development of polymer modified mortar.
引文
[1]钟世云,袁华.聚合物在混凝土中的应用[M].第一版.北京：化学工业出版社,2003.
[2]Cresson, L. Improved manufacture of rubber roadfacing, rubb-flooring, rubber tiling or other rubber-lining. Brithish Patent 191 474,12 Jan 1923.
[3]Lefebure, V., Improvments in or relating to concrete,cement,plasters and the like. British Pantent 217 279,5 June 1924.
[4]Bend, Polymer Modified Mortars and Cnoeretes. Brithish Patent 321489,15 Feb 1932.
[5]Rodwell, Internationaler Kongress Polymere and Beton,Darmstadt,British Pantent 285 326,8 June 1939.
[6]孙继成.高性能聚合物改性水泥基胶结材料的研究,[硕士学位论文],武汉：华中科技大学.2004,4.
[7]熊剑平,聚合物改性水泥混凝土路用性能研究.[硕士学位论文],西安：长安大学,2005,6.
[8]钟世云著,聚合物在混凝土中的应用技术[M],化学工业出版社.2003.10.
[9]沈春林,聚合物水泥防水砂浆[M].化学工业出版社.北京,2007.
[10]Isenberg, J.E.Nanderhoff, J. W.."Hypotgesis for reinforcement of potland Cement by polymer latexes", J.Amer. Ceram, Soe.1994,57(6):242-245.
[11]美国Simpson Strong-Tie公司,裂缝修补材料研究应用.
[12]Fi.O. Blank N al. Development of polymer concrete with polybutadiene matrix. Cement and Concrete Composites,1996,18,437-444.
[13]美国FSI公司,裂缝快速修补材料应用.
[14]日本混凝土工程协会编.混凝土工程裂缝调查及补强加固技术研究,地震出版社,1992.
[15]擢海潮等.粘结与表面粘涂技术[M].北京,化学工业出版社,1997.
[16]Ke-Ru Wu, Dong Zhang, Jun-Mei Song. Properties of polymer-modified cement mortar using pre-enveloping method. Cement and Concrete Research,2002, (32): 425-429.
[17]K.E.Hassan,P.C.Robery,L.Al-Alawi,Effect of hot-dry curing enviornment on the intrinsic properties of repair materials:Cement&Concrete Composites 2000,22: 453-458.
[18]Etsuo Sakai and Jun Sugita,COMPOSITE MECHANISM OF POLYMER MODIFIED CEMENT,Cement and Concrete Research,1995,27(1):157-165.
[19]Sakai E,Sugita J.Composite mechanism of polymer modified cement. Cement and concrete Research,1995,25(1):127-135.
[20]De Belie,Handbook of water-soluble gums, and resins. McGraw-Hill Book Co.,1998.
[21]Schulze J.Influence of water-cement ratio and cement content on the properties of ploymer-modified mortars.Cement and concrete Research,1999,29:909～915.
[22]Cabrera J.G., Hassan K E G. Assessment of the effectiveness of surface treatment against the ingress of chloride into mortars and concretes. In:Swamy R N ed.,Proc of inter conf on corrosion and corrosion Protection of Steel in Concrete.UK:Univ of Shiefield,1994,1028～1043.
[23]Tanikawa S,Swamy R N.Protection of stell in chloride contaminated concrete using a acrylic rubber surface coating.In:Swamy R N ed.,Proc of In nter conf on corrosion and corrosion Protection of Steel in Concrete. UK:Univ of Shiefield, 1994,1055～1068.
[24]Umathy C T, Dharakumar M, Saroja Devi M, et al. Modification of cement mortars by polymer latex. J Appl Polym Sci,1997,63:1251.
[25]Kim J H, Robertson R E. Prevention of air void formation in polymer-modified cement mortar by pre-weting. Cem Concr Res,1997,27:171.
[26]Colak A. Properties of plain and latex modified Portland cement pastes and concretes with and without superplasticizer. Cem Concr Res,2005,35:1510.
[27]李保红.水泥混凝土路面局部破损快速修补材料的研究.[硕士学位论文].长沙：湖南大学,2004,6.
[28]中国建筑材料科学研究院.WWX-Ⅱ型混凝土裂缝修补材料研究[R].
[29]孙振平,蒋正武.水泥基桥面裂缝修补材料研究.同济大学材料科学与工程学院.[R].
[30]同济大学.混凝土裂缝灌浆修补材料研究.[R].
[31]浙江大学,宝山钢铁股份有限公司.耐蚀抗渗水泥基修补材料研究.[R].
[32]山东建材学院.SCQ-251型混凝土路面裂缝补缝剂研究.[R]
[33]方萍.丙苯乳液改性聚合物水泥力学性能和内部结构研究[J].混凝土,2001,(3)：46-48.
[34]杨正宏,尹义林等.道路用聚合物改性水泥砂浆修补材料的研制[J].新型建筑材料,2006,(2)：1-4.
[35]尹健.高性能快速修补混凝土的研究与应用.[博士论文].长沙：中南大学,2003,7.
[36]申爱琴,朱建辉.聚合物改性超细水泥修补混凝土结构物微裂缝的性能及机理 [J].中国公路学报,2006,19(14)：46-51.
[37]钟世云,刘应刁,王培铭.聚合物改性特种水泥灌浆料的性能[J].建筑材料学报,2004,7(1)：102-108.
[38]李云超,芦令超,王守德,叶正茂,程新.聚合物改性硫铝酸盐水泥防腐抗渗性能的研究[J].硅酸盐通报,2008,27(5)：1014-1017.
[39]张金喜,金珊珊,张江,王德志.聚合物乳液改性水泥砂浆基本性能研究[J].北京工业大学学报,2009,35(8)：1062-1068.
[40]梅迎军,王培铭,李志勇,梁乃兴.SBR乳液改性砂浆与水泥基体界面粘结性能[J]西安建筑科技大学学报,2009,41(3)：404-408.
[41]朱建辉,田宇宏等.聚合物改性超细水泥灌浆材料性能研究[J].安建筑科技大学学报,2008,40(6)：759-763.
[42]彭全敏,聚氨醋材料快速修补机场跑道的试验研究.[硕士论文],天津：天津大学,2004,12.
[43]张明飞,聚合物改性硫铝酸盐水泥修补砂浆的研究.[硕士论文],武汉：武汉理工大学,2006,12.
[44]Yoshihiko Ohama Polymer-based Admixtures ement and Concrete Composites 20 1998,189-212.
[45]Koinetzko A. Polymerspeziifsche Auswerkungen auf das Tragverhalten modifizierter zementgebundener Beton(PCC). Dissertation.Braunschweig,1988.
[46]龙军,俞坷,李国鼎,聚合物与水泥水化产物间的相互作用[J],混凝土,1995,3：35-37.
[47]Park Choonkeun Cho Dongwon Oh Heegap,硅酸盐水泥基无大孔胶凝材料中金属离子的作用[J],硅酸盐学报,1996,24(4)：382-388.
[48]杨月林,朱均超,编著《水工建筑物水泥灌浆施工技术》[M],长江出版社2005.
[49]《水工建筑物水泥灌浆施工技术规范》(DLT 5148-2001)
[50]何忠明,裂隙岩体复合防渗堵水桨液试验及作用机理研究,[博士学位论文],长沙：中南大学,2007,5.
[51]地基处理手册编写委员会.地基处理手册[M].北京：中国建筑工业出版社,1994.
[52]陈旭荣.湿磨细水泥浆材的制备及灌浆技术的研究[J].长江科学院院报.1994(4)：38-45.
[53]詹美礼,速宝玉.灌浆参数优化设计分析及理论探讨[J].水利发电,1998(2)：34-37.
[54]KomiyaK, SogaK, AkagiH, etal.Soil consolidation associated with grouting during shield tunnelling in soft clayey ground.Geotechnique,2001,51(10): 835-846.
[55]肖建波.油井水泥浆流变模型选择[J].钻采工艺,1998(3)：71-73.
[56]马海龙,杨敏.对基于渗透注浆理论公式的探讨.工业建筑,2000(2)：47-51
[57]J.S.Lee, C.S.Bang, Y.J.Mok, S.H.John.Numerical and experiment alanalysis of Penetration grouting in jointed roek masses. Intenational Journal of Roek Meehanies& Mining science,2000,37,1027-1037
[58]胡尚清.影响灌浆浆液渗透性的材料特性分析[J].黑龙江水利科技,1999(4)：49-50.
[59]胡曙光,管学茂,丁庆军.超细水泥基灌浆材料研究动向及发展方向[J],水泥,2001(1)：11-13.
[60]张金接.稳定性水泥浆体在岩体裂隙中的流动性能及灌浆技术[J].水利学报.1993(7)：19-24.
[61]赵志给.泵送混凝土[M].中国建筑出版社.1985：68-117.
[62]郝永真.水泥浆主要流变参数的确定与分析[J].水利水电科技进展,2000(4)：32-35.
[63]王子明,黄大能,谢尧生.新拌水泥浆体的流变特性及其可灌性的研究[J],中国建筑材料科学研究院学报.1990,6(2)：1-6.
[64]朱建辉,聚合物改性超细水泥在混凝土路面裂缝修补中的应用研究.长安大学,[硕士学位论文],2004年5月.
[65]申爱琴,水泥混凝土路面裂缝修补材料研究.,[博士学位论文],西安：长安大学,2004,12.
[66]契尔金斯基IO G.《聚合物水泥混凝土》[M]张留城,夏巨敏译.北京：中国建筑工业出版社,1987.
[67]王茹,培铭,丁苯乳液和乳胶粉对水泥水化产物形成的影响[J],硅酸盐学报,2008(7),36(7)：912-926.
[68]李祝龙,梁乃兴.丁苯类聚合物乳液对水泥水化硬化的影响[J].建筑材料学报,1999(3),2(1)：6-10.
[69]钟世云,王培铭,聚合物改性砂浆和混凝土的微观形貌[J],建筑材料学报,第7卷第2期,2004年6月：168-173.
[70]刘志勇.低掺量乳胶粉和矿粉复合改性聚合物水泥砂浆的性能[J].新型建筑材料,1993(3)：20-23.
[71]沈如,李敏,邹斌.高强混凝土聚合物增韧研究[J].四川建筑科学研究,2000,26(1)：55-56.
[72]涂云霞,水泥基聚合物混凝土抗裂性能的试验研究,[硕士论文].扬州：扬州大 学,2007,5.
[73]姚红云,梁乃兴等.羧基丁苯聚合物改性混凝土性能及其机理[J],建筑材料学报2005,8(1)：30-36.
[74]沈如,李敏,邹斌.高强混凝土聚合物增韧研究[J].四川建筑科学研究,2000,26(1)：55-56.
[75]解灵霞,王长华,黄振国.钢筋混凝土防腐蚀方法综述[J].郑州工业大学学报,1997,18(1)：89-94.
[76]张誉.基于碳化机理的混凝土碳化深度实用数学模型[J].工业建筑,1998(1)：16-19.
[77]Zhang Minhong and Gjorv O E.Permeability of High Strength Lightweight Concrete. ACI Materials Journal.1991.88:463-469.
[78]孟云芳.粉煤灰橡胶粉改善混凝土抗裂性能研究[J].混凝土,200(6)：49-55.
[79]梁乃兴.聚合物改性水泥混凝土[M].北京,人民交通出版社,1995.
[80]安明颉.高性能混凝土自收缩研究,[博士学位论文].北京,清华大学土木工程系,1991
[81]C.Hua,P. Acker&A.Ehrlacher. Analysis and Models of the Autogenous shrinkage of Hardening Cemnet Paste I Modeling at Macroscopic Scale[J]. Cement and concrete Research,1995,25(7):1475-1479.
[82]黄国兴,惠荣炎.混凝土的收缩[M].北京：中国铁道出版社.1990.
[83]杨医博,吴笑梅,樊粤明.浅谈混凝土的干燥收缩[J].广州建材.1999(7)：9-11.
[84]肖瑞敏,张雄,乐嘉麟.胶凝材料对混凝土干缩影响的研究[J].混凝土与水泥制品,2003(5)：11-13.
[85]孙道胜.高强混凝土早期收缩的机理与特点[J].安徽建筑工业学院学报,1998(1)：43-47.
[86]姜洪义,殷仲梅.NBS乳液-水泥砂浆共混体系的研究[J].2002,2(2)：23-28.
[87]李顺凯,水泥砂浆的干缩研究,[硕士学位论文],南京工业大学,2004,4.
[88]沈威,黄文熙,闵盘荣.水泥工艺学[M].武汉工业大学出版社,1990.
[89]涂云霞,水泥基聚合物混凝土抗裂性能的试验研究,[硕士论文],扬州：扬州大学,2007,5.
[90]梅迎军,李志勇,王培铭,梁乃兴.SBR乳液对水泥砂浆长期收缩性能影响及机理分析[J].土木建筑与环境工程,2009(6),31(3)：142-146.
[91]梅迎军.纤维聚合物水泥基复合材料性能及机理研究[D].上海：同济大学,2006(5)：78-82.
[92]OLLITRAULT-FICHET R, GAUTHIERC CLAMENG, et al.Micro-structural aspects in polymer modifiedcement [J]. Cement and Concrete Research,1998, 28(12):1687-1693.
[93]OHAMA Y, DEMURA K, KOBAYASHI Y. Pore sizedistribution and oxygen diffusion resistance of polymermodified mortar [J]. Cement and Concrete Research,1991(21):309-315.
[94]BEELDENS A, VAN GEMERT D, SCHORN H, etal. From microstructure to macrostructure:anintegrated model of structure formation in polymer-modified concrete [J].Materials and Structures,2005,38(6):601-607.
[95]DIN 18555-5,Prafung von Morteln mit mineraif hen Bmdcmit Frtd Bestl mmung der Hafzugfestigkeit. [S].
[96]Emmons,P.H.et al,Concrete repair in the furture turn of the century-any Problem Concrete International,March,1994.
[97]赵志方,新老混凝土粘结机理和测试方法,[博士论文].大连：大连理工大学,1998.
[98]李庚英,谢慧才,熊光晶,混凝土修补界面的微观结构及与宏观力学性能的关系[J],混凝土,1999(6)：13-18.
[99]M.H.Fiebrich, Scientific aspects of adhesion Phenomena in the interface mineral substrate-Polymers, Adherence of Young on Old Conerete, edited by F.H. Wittmann,1994.
[100]J.Bilen, T.Salet,Adherence of young concrete to old concrete-development of tools for engineering,Adherence of Young on old Conerete, edited by F.H. Wittmann,1994.
[101]胡高平.金属用胶粘剂及粘接技术[M].北京：化学工业出版社,2003.
[102]彭勃,金智迪,单远铭,水泥复合砂浆的粘结性能研究,建筑结构,第40卷增刊2010(6)：431-433.
[103]李芳,杨玉颖,吴建国,等.养护制度对桥面用聚合物改性水泥砂浆力学性能的影响[J].建材技术与应用,2002,16(5)：7-9.
[104]钟世云,袁华.聚合物在混凝土中的应用[M].北京：化学工业出版社,2003.
[105]钟世云,王培铭.聚合物改性砂浆和混凝土的微观形貌[J],建筑材料学报,第7卷第2期,2004(6)：168-173.
[106]I. Adachi, K.Hashimoto, T.Nishimura.Construction joint of concrete structures using shot-blasting technique.Transactions of the Japan concrete Institute, 1983,11(5):61-68.
[107]杨钱荣,盛慧芳,陈志源.不饱和聚酯砂浆与水泥砂浆界面粘结性能的研究[J], 混凝土.2001,10：33-36.
[108]王培铭,张国防.干混砂浆的发展和聚合物干粉的作用[J].中国水泥,2004,(1)：45-47.
[109]王晓峰,张量.采用粉末聚合物改性的混凝土修补砂浆[J].新型建筑材料,2007,(3)：29-32.
[110]Harmuth H.Investigation of the adherence and the fracture behaviors of the polymer cement concrete.Cement and Concrete Research,1995,25(3):497～502.
[111]王涛,许仲梓.聚合物改性水泥砂浆性能的影响因素[J],混凝土与水泥制品.1996(5)10：23-26.
[112]买淑芳,徐素华.混凝土聚合物复合材料及其应用[M],科学技术文献出版社,1996.
[113]张庆兴.聚合物特种水泥基复合材料的研究,[硕士学位论文].天津：天津轻工业学院,2000,12.
[2]Cresson, L. Improved manufacture of rubber roadfacing, rubb-flooring, rubber tiling or other rubber-lining. Brithish Patent 191 474,12 Jan 1923.
[3]Lefebure, V., Improvments in or relating to concrete,cement,plasters and the like. British Pantent 217 279,5 June 1924.
[4]Bend, Polymer Modified Mortars and Cnoeretes. Brithish Patent 321489,15 Feb 1932.
[5]Rodwell, Internationaler Kongress Polymere and Beton,Darmstadt,British Pantent 285 326,8 June 1939.
[6]孙继成.高性能聚合物改性水泥基胶结材料的研究,[硕士学位论文],武汉：华中科技大学.2004,4.
[7]熊剑平,聚合物改性水泥混凝土路用性能研究.[硕士学位论文],西安：长安大学,2005,6.
[8]钟世云著,聚合物在混凝土中的应用技术[M],化学工业出版社.2003.10.
[9]沈春林,聚合物水泥防水砂浆[M].化学工业出版社.北京,2007.
[10]Isenberg, J.E.Nanderhoff, J. W.."Hypotgesis for reinforcement of potland Cement by polymer latexes", J.Amer. Ceram, Soe.1994,57(6):242-245.
[11]美国Simpson Strong-Tie公司,裂缝修补材料研究应用.
[12]Fi.O. Blank N al. Development of polymer concrete with polybutadiene matrix. Cement and Concrete Composites,1996,18,437-444.
[13]美国FSI公司,裂缝快速修补材料应用.
[14]日本混凝土工程协会编.混凝土工程裂缝调查及补强加固技术研究,地震出版社,1992.
[15]擢海潮等.粘结与表面粘涂技术[M].北京,化学工业出版社,1997.
[16]Ke-Ru Wu, Dong Zhang, Jun-Mei Song. Properties of polymer-modified cement mortar using pre-enveloping method. Cement and Concrete Research,2002, (32): 425-429.
[17]K.E.Hassan,P.C.Robery,L.Al-Alawi,Effect of hot-dry curing enviornment on the intrinsic properties of repair materials:Cement&Concrete Composites 2000,22: 453-458.
[18]Etsuo Sakai and Jun Sugita,COMPOSITE MECHANISM OF POLYMER MODIFIED CEMENT,Cement and Concrete Research,1995,27(1):157-165.
[19]Sakai E,Sugita J.Composite mechanism of polymer modified cement. Cement and concrete Research,1995,25(1):127-135.
[20]De Belie,Handbook of water-soluble gums, and resins. McGraw-Hill Book Co.,1998.
[21]Schulze J.Influence of water-cement ratio and cement content on the properties of ploymer-modified mortars.Cement and concrete Research,1999,29:909～915.
[22]Cabrera J.G., Hassan K E G. Assessment of the effectiveness of surface treatment against the ingress of chloride into mortars and concretes. In:Swamy R N ed.,Proc of inter conf on corrosion and corrosion Protection of Steel in Concrete.UK:Univ of Shiefield,1994,1028～1043.
[23]Tanikawa S,Swamy R N.Protection of stell in chloride contaminated concrete using a acrylic rubber surface coating.In:Swamy R N ed.,Proc of In nter conf on corrosion and corrosion Protection of Steel in Concrete. UK:Univ of Shiefield, 1994,1055～1068.
[24]Umathy C T, Dharakumar M, Saroja Devi M, et al. Modification of cement mortars by polymer latex. J Appl Polym Sci,1997,63:1251.
[25]Kim J H, Robertson R E. Prevention of air void formation in polymer-modified cement mortar by pre-weting. Cem Concr Res,1997,27:171.
[26]Colak A. Properties of plain and latex modified Portland cement pastes and concretes with and without superplasticizer. Cem Concr Res,2005,35:1510.
[27]李保红.水泥混凝土路面局部破损快速修补材料的研究.[硕士学位论文].长沙：湖南大学,2004,6.
[28]中国建筑材料科学研究院.WWX-Ⅱ型混凝土裂缝修补材料研究[R].
[29]孙振平,蒋正武.水泥基桥面裂缝修补材料研究.同济大学材料科学与工程学院.[R].
[30]同济大学.混凝土裂缝灌浆修补材料研究.[R].
[31]浙江大学,宝山钢铁股份有限公司.耐蚀抗渗水泥基修补材料研究.[R].
[32]山东建材学院.SCQ-251型混凝土路面裂缝补缝剂研究.[R]
[33]方萍.丙苯乳液改性聚合物水泥力学性能和内部结构研究[J].混凝土,2001,(3)：46-48.
[34]杨正宏,尹义林等.道路用聚合物改性水泥砂浆修补材料的研制[J].新型建筑材料,2006,(2)：1-4.
[35]尹健.高性能快速修补混凝土的研究与应用.[博士论文].长沙：中南大学,2003,7.
[36]申爱琴,朱建辉.聚合物改性超细水泥修补混凝土结构物微裂缝的性能及机理 [J].中国公路学报,2006,19(14)：46-51.
[37]钟世云,刘应刁,王培铭.聚合物改性特种水泥灌浆料的性能[J].建筑材料学报,2004,7(1)：102-108.
[38]李云超,芦令超,王守德,叶正茂,程新.聚合物改性硫铝酸盐水泥防腐抗渗性能的研究[J].硅酸盐通报,2008,27(5)：1014-1017.
[39]张金喜,金珊珊,张江,王德志.聚合物乳液改性水泥砂浆基本性能研究[J].北京工业大学学报,2009,35(8)：1062-1068.
[40]梅迎军,王培铭,李志勇,梁乃兴.SBR乳液改性砂浆与水泥基体界面粘结性能[J]西安建筑科技大学学报,2009,41(3)：404-408.
[41]朱建辉,田宇宏等.聚合物改性超细水泥灌浆材料性能研究[J].安建筑科技大学学报,2008,40(6)：759-763.
[42]彭全敏,聚氨醋材料快速修补机场跑道的试验研究.[硕士论文],天津：天津大学,2004,12.
[43]张明飞,聚合物改性硫铝酸盐水泥修补砂浆的研究.[硕士论文],武汉：武汉理工大学,2006,12.
[44]Yoshihiko Ohama Polymer-based Admixtures ement and Concrete Composites 20 1998,189-212.
[45]Koinetzko A. Polymerspeziifsche Auswerkungen auf das Tragverhalten modifizierter zementgebundener Beton(PCC). Dissertation.Braunschweig,1988.
[46]龙军,俞坷,李国鼎,聚合物与水泥水化产物间的相互作用[J],混凝土,1995,3：35-37.
[47]Park Choonkeun Cho Dongwon Oh Heegap,硅酸盐水泥基无大孔胶凝材料中金属离子的作用[J],硅酸盐学报,1996,24(4)：382-388.
[48]杨月林,朱均超,编著《水工建筑物水泥灌浆施工技术》[M],长江出版社2005.
[49]《水工建筑物水泥灌浆施工技术规范》(DLT 5148-2001)
[50]何忠明,裂隙岩体复合防渗堵水桨液试验及作用机理研究,[博士学位论文],长沙：中南大学,2007,5.
[51]地基处理手册编写委员会.地基处理手册[M].北京：中国建筑工业出版社,1994.
[52]陈旭荣.湿磨细水泥浆材的制备及灌浆技术的研究[J].长江科学院院报.1994(4)：38-45.
[53]詹美礼,速宝玉.灌浆参数优化设计分析及理论探讨[J].水利发电,1998(2)：34-37.
[54]KomiyaK, SogaK, AkagiH, etal.Soil consolidation associated with grouting during shield tunnelling in soft clayey ground.Geotechnique,2001,51(10): 835-846.
[55]肖建波.油井水泥浆流变模型选择[J].钻采工艺,1998(3)：71-73.
[56]马海龙,杨敏.对基于渗透注浆理论公式的探讨.工业建筑,2000(2)：47-51
[57]J.S.Lee, C.S.Bang, Y.J.Mok, S.H.John.Numerical and experiment alanalysis of Penetration grouting in jointed roek masses. Intenational Journal of Roek Meehanies& Mining science,2000,37,1027-1037
[58]胡尚清.影响灌浆浆液渗透性的材料特性分析[J].黑龙江水利科技,1999(4)：49-50.
[59]胡曙光,管学茂,丁庆军.超细水泥基灌浆材料研究动向及发展方向[J],水泥,2001(1)：11-13.
[60]张金接.稳定性水泥浆体在岩体裂隙中的流动性能及灌浆技术[J].水利学报.1993(7)：19-24.
[61]赵志给.泵送混凝土[M].中国建筑出版社.1985：68-117.
[62]郝永真.水泥浆主要流变参数的确定与分析[J].水利水电科技进展,2000(4)：32-35.
[63]王子明,黄大能,谢尧生.新拌水泥浆体的流变特性及其可灌性的研究[J],中国建筑材料科学研究院学报.1990,6(2)：1-6.
[64]朱建辉,聚合物改性超细水泥在混凝土路面裂缝修补中的应用研究.长安大学,[硕士学位论文],2004年5月.
[65]申爱琴,水泥混凝土路面裂缝修补材料研究.,[博士学位论文],西安：长安大学,2004,12.
[66]契尔金斯基IO G.《聚合物水泥混凝土》[M]张留城,夏巨敏译.北京：中国建筑工业出版社,1987.
[67]王茹,培铭,丁苯乳液和乳胶粉对水泥水化产物形成的影响[J],硅酸盐学报,2008(7),36(7)：912-926.
[68]李祝龙,梁乃兴.丁苯类聚合物乳液对水泥水化硬化的影响[J].建筑材料学报,1999(3),2(1)：6-10.
[69]钟世云,王培铭,聚合物改性砂浆和混凝土的微观形貌[J],建筑材料学报,第7卷第2期,2004年6月：168-173.
[70]刘志勇.低掺量乳胶粉和矿粉复合改性聚合物水泥砂浆的性能[J].新型建筑材料,1993(3)：20-23.
[71]沈如,李敏,邹斌.高强混凝土聚合物增韧研究[J].四川建筑科学研究,2000,26(1)：55-56.
[72]涂云霞,水泥基聚合物混凝土抗裂性能的试验研究,[硕士论文].扬州：扬州大 学,2007,5.
[73]姚红云,梁乃兴等.羧基丁苯聚合物改性混凝土性能及其机理[J],建筑材料学报2005,8(1)：30-36.
[74]沈如,李敏,邹斌.高强混凝土聚合物增韧研究[J].四川建筑科学研究,2000,26(1)：55-56.
[75]解灵霞,王长华,黄振国.钢筋混凝土防腐蚀方法综述[J].郑州工业大学学报,1997,18(1)：89-94.
[76]张誉.基于碳化机理的混凝土碳化深度实用数学模型[J].工业建筑,1998(1)：16-19.
[77]Zhang Minhong and Gjorv O E.Permeability of High Strength Lightweight Concrete. ACI Materials Journal.1991.88:463-469.
[78]孟云芳.粉煤灰橡胶粉改善混凝土抗裂性能研究[J].混凝土,200(6)：49-55.
[79]梁乃兴.聚合物改性水泥混凝土[M].北京,人民交通出版社,1995.
[80]安明颉.高性能混凝土自收缩研究,[博士学位论文].北京,清华大学土木工程系,1991
[81]C.Hua,P. Acker&A.Ehrlacher. Analysis and Models of the Autogenous shrinkage of Hardening Cemnet Paste I Modeling at Macroscopic Scale[J]. Cement and concrete Research,1995,25(7):1475-1479.
[82]黄国兴,惠荣炎.混凝土的收缩[M].北京：中国铁道出版社.1990.
[83]杨医博,吴笑梅,樊粤明.浅谈混凝土的干燥收缩[J].广州建材.1999(7)：9-11.
[84]肖瑞敏,张雄,乐嘉麟.胶凝材料对混凝土干缩影响的研究[J].混凝土与水泥制品,2003(5)：11-13.
[85]孙道胜.高强混凝土早期收缩的机理与特点[J].安徽建筑工业学院学报,1998(1)：43-47.
[86]姜洪义,殷仲梅.NBS乳液-水泥砂浆共混体系的研究[J].2002,2(2)：23-28.
[87]李顺凯,水泥砂浆的干缩研究,[硕士学位论文],南京工业大学,2004,4.
[88]沈威,黄文熙,闵盘荣.水泥工艺学[M].武汉工业大学出版社,1990.
[89]涂云霞,水泥基聚合物混凝土抗裂性能的试验研究,[硕士论文],扬州：扬州大学,2007,5.
[90]梅迎军,李志勇,王培铭,梁乃兴.SBR乳液对水泥砂浆长期收缩性能影响及机理分析[J].土木建筑与环境工程,2009(6),31(3)：142-146.
[91]梅迎军.纤维聚合物水泥基复合材料性能及机理研究[D].上海：同济大学,2006(5)：78-82.
[92]OLLITRAULT-FICHET R, GAUTHIERC CLAMENG, et al.Micro-structural aspects in polymer modifiedcement [J]. Cement and Concrete Research,1998, 28(12):1687-1693.
[93]OHAMA Y, DEMURA K, KOBAYASHI Y. Pore sizedistribution and oxygen diffusion resistance of polymermodified mortar [J]. Cement and Concrete Research,1991(21):309-315.
[94]BEELDENS A, VAN GEMERT D, SCHORN H, etal. From microstructure to macrostructure:anintegrated model of structure formation in polymer-modified concrete [J].Materials and Structures,2005,38(6):601-607.
[95]DIN 18555-5,Prafung von Morteln mit mineraif hen Bmdcmit Frtd Bestl mmung der Hafzugfestigkeit. [S].
[96]Emmons,P.H.et al,Concrete repair in the furture turn of the century-any Problem Concrete International,March,1994.
[97]赵志方,新老混凝土粘结机理和测试方法,[博士论文].大连：大连理工大学,1998.
[98]李庚英,谢慧才,熊光晶,混凝土修补界面的微观结构及与宏观力学性能的关系[J],混凝土,1999(6)：13-18.
[99]M.H.Fiebrich, Scientific aspects of adhesion Phenomena in the interface mineral substrate-Polymers, Adherence of Young on Old Conerete, edited by F.H. Wittmann,1994.
[100]J.Bilen, T.Salet,Adherence of young concrete to old concrete-development of tools for engineering,Adherence of Young on old Conerete, edited by F.H. Wittmann,1994.
[101]胡高平.金属用胶粘剂及粘接技术[M].北京：化学工业出版社,2003.
[102]彭勃,金智迪,单远铭,水泥复合砂浆的粘结性能研究,建筑结构,第40卷增刊2010(6)：431-433.
[103]李芳,杨玉颖,吴建国,等.养护制度对桥面用聚合物改性水泥砂浆力学性能的影响[J].建材技术与应用,2002,16(5)：7-9.
[104]钟世云,袁华.聚合物在混凝土中的应用[M].北京：化学工业出版社,2003.
[105]钟世云,王培铭.聚合物改性砂浆和混凝土的微观形貌[J],建筑材料学报,第7卷第2期,2004(6)：168-173.
[106]I. Adachi, K.Hashimoto, T.Nishimura.Construction joint of concrete structures using shot-blasting technique.Transactions of the Japan concrete Institute, 1983,11(5):61-68.
[107]杨钱荣,盛慧芳,陈志源.不饱和聚酯砂浆与水泥砂浆界面粘结性能的研究[J], 混凝土.2001,10：33-36.
[108]王培铭,张国防.干混砂浆的发展和聚合物干粉的作用[J].中国水泥,2004,(1)：45-47.
[109]王晓峰,张量.采用粉末聚合物改性的混凝土修补砂浆[J].新型建筑材料,2007,(3)：29-32.
[110]Harmuth H.Investigation of the adherence and the fracture behaviors of the polymer cement concrete.Cement and Concrete Research,1995,25(3):497～502.
[111]王涛,许仲梓.聚合物改性水泥砂浆性能的影响因素[J],混凝土与水泥制品.1996(5)10：23-26.
[112]买淑芳,徐素华.混凝土聚合物复合材料及其应用[M],科学技术文献出版社,1996.
[113]张庆兴.聚合物特种水泥基复合材料的研究,[硕士学位论文].天津：天津轻工业学院,2000,12.