镁铝层状双金属氢氧化物作为杀菌剂载体及其表面修饰杂化物的制备与表征
|
摘要
层状双金属氢氧化物(LDHs)是一类带有永久正电荷的新型无机材料,层间存在可交换的阴离子,层间空间可调,可以将药物分子嵌入层间形成药物-LDHs纳米杂化物。LDHs广泛应用于催化剂、抗酸剂、废水处理、抗絮凝剂、药物载体、阴离子交换剂以及流变改性剂等领域。
将不能电离、难溶于水的杀菌剂包裹到阴离子表面活性剂的胶束内,分别采用共沉淀法、结构重建法和离子交换法将带负电的胶束嵌入到LDHs层中,合成了两种杀菌剂己唑醇和三唑醇的LDHs杂化物。采用粉末X射线衍射(PXRD)、透射电镜(TEM)和傅里叶变换红外光谱(FT-IR)对杀菌剂-LDHs纳米杂化物进行表征。由X射线衍射图可知杀菌剂-LDHs的层间距比纯LDHs的层间距明显增大,并且003峰向低2θ值移动,说明带负电的胶束将通道内原有的阴离子取代。红外光谱图证明了杀菌剂-LDHs中杀菌剂的存在,成功的合成了杀菌剂-LDHs.紫外-可见分光光度(UV-Vis)检测显示杀菌剂-LDHs具有一定的缓释性能,杀菌剂-LDHs杂化物是一种有潜力的药物缓释系统。
CO3-LDHs分别和柠檬酸,萘乙酸,1-羟基环己基甲酸的丙酮溶液反应,进行表面修饰。产物用粉末X射线衍射、傅里叶变换红外光谱和透射电镜进行表征。PXRD谱图显示修饰后的CO3-LDHs层间距没有增大,在红外谱图上可以观察到所修饰剂的特征基团吸收峰。TEM照片显示CO3-LDHs修饰前后粒子尺寸没有改变,修饰后的CO3-LDHs层片连接在一起,说明其表面连接上了修饰剂,证明成功制备了表面修饰的CO3-LDHs.
LDHs are a family of layered inorganic materials with structurally positively charged layers and interlayer balancing anions. The anions between the interlayer can be exchanged by the other anions and the space can be adjusted. LDHs nanohybirds can be prepared by intercalate anions into interlayer space. LDHs nanocomplexes were widely applied in various aspects such as catalyst, antiacid, waste water treatment, antiflocculant agent, drug carrier, anion exchanger and rheological modification.
Two bactericides-LDHs nanocomplexes hexaconazole-LDHs and triadmenol-LDHs were prepared by following procedures: bactericides that were nonionic and difficult to dissolve in water were first incorporated into micelles derived from negatively charged surfactants, and the negatively charged micelles were then intercalated in nanoparticles of LDHs by coprecipitation, ion exchange and reconstruction method respectively. The bactericides-LDHs nanohybirds were characterized by PXRD, TEM and FT-IR. The PXRD patterns indicated that the basal spacing of bactericides-LDHs was obviously larger than pristine LDHs, and 003 peak was shifted to the low 2θvalue, which indicated that the originated anions between the interlayer were replaced by the micelles containing bactericides. The successful synthesis of bactericides-LDHs were also proved by the FT-IR spectra, which indicated the existence of hexaconazole and triadimenol. The bactericides-LDHs were successfully synthesized. UV-Vis results showed that bactericides can be slowly released from the bactericides-LDHs nanohybirds, so bactericides-LDHs are a potential system in the bactericides slow release.
CO3-LDHs reacted with citric acid (CA), naphthyl acetic acid (NAA) and 1-hydroxycyclohexane carboxylic acid (HCCA) dissolved in acetone respectively to prepare surface modified LDHs. The resulting complexes were characterized by PXRD, FT-IR and TEM. The results of PXRD patterns indicated that the basal spacing values of modified complexes didn’t change from the pristine CO3-LDHs. The functional groups of organic vibration modes can be observed in the FT-IR spectra. TEM images of modified CO3-LDHs indicated that the size of particals were not varied. But the particals stacked together, which indicated that organism were joined on the surface of CO3-LDHs. The surface modification CO3-LDHs were successfully prepared.
将不能电离、难溶于水的杀菌剂包裹到阴离子表面活性剂的胶束内,分别采用共沉淀法、结构重建法和离子交换法将带负电的胶束嵌入到LDHs层中,合成了两种杀菌剂己唑醇和三唑醇的LDHs杂化物。采用粉末X射线衍射(PXRD)、透射电镜(TEM)和傅里叶变换红外光谱(FT-IR)对杀菌剂-LDHs纳米杂化物进行表征。由X射线衍射图可知杀菌剂-LDHs的层间距比纯LDHs的层间距明显增大,并且003峰向低2θ值移动,说明带负电的胶束将通道内原有的阴离子取代。红外光谱图证明了杀菌剂-LDHs中杀菌剂的存在,成功的合成了杀菌剂-LDHs.紫外-可见分光光度(UV-Vis)检测显示杀菌剂-LDHs具有一定的缓释性能,杀菌剂-LDHs杂化物是一种有潜力的药物缓释系统。
CO3-LDHs分别和柠檬酸,萘乙酸,1-羟基环己基甲酸的丙酮溶液反应,进行表面修饰。产物用粉末X射线衍射、傅里叶变换红外光谱和透射电镜进行表征。PXRD谱图显示修饰后的CO3-LDHs层间距没有增大,在红外谱图上可以观察到所修饰剂的特征基团吸收峰。TEM照片显示CO3-LDHs修饰前后粒子尺寸没有改变,修饰后的CO3-LDHs层片连接在一起,说明其表面连接上了修饰剂,证明成功制备了表面修饰的CO3-LDHs.
LDHs are a family of layered inorganic materials with structurally positively charged layers and interlayer balancing anions. The anions between the interlayer can be exchanged by the other anions and the space can be adjusted. LDHs nanohybirds can be prepared by intercalate anions into interlayer space. LDHs nanocomplexes were widely applied in various aspects such as catalyst, antiacid, waste water treatment, antiflocculant agent, drug carrier, anion exchanger and rheological modification.
Two bactericides-LDHs nanocomplexes hexaconazole-LDHs and triadmenol-LDHs were prepared by following procedures: bactericides that were nonionic and difficult to dissolve in water were first incorporated into micelles derived from negatively charged surfactants, and the negatively charged micelles were then intercalated in nanoparticles of LDHs by coprecipitation, ion exchange and reconstruction method respectively. The bactericides-LDHs nanohybirds were characterized by PXRD, TEM and FT-IR. The PXRD patterns indicated that the basal spacing of bactericides-LDHs was obviously larger than pristine LDHs, and 003 peak was shifted to the low 2θvalue, which indicated that the originated anions between the interlayer were replaced by the micelles containing bactericides. The successful synthesis of bactericides-LDHs were also proved by the FT-IR spectra, which indicated the existence of hexaconazole and triadimenol. The bactericides-LDHs were successfully synthesized. UV-Vis results showed that bactericides can be slowly released from the bactericides-LDHs nanohybirds, so bactericides-LDHs are a potential system in the bactericides slow release.
CO3-LDHs reacted with citric acid (CA), naphthyl acetic acid (NAA) and 1-hydroxycyclohexane carboxylic acid (HCCA) dissolved in acetone respectively to prepare surface modified LDHs. The resulting complexes were characterized by PXRD, FT-IR and TEM. The results of PXRD patterns indicated that the basal spacing values of modified complexes didn’t change from the pristine CO3-LDHs. The functional groups of organic vibration modes can be observed in the FT-IR spectra. TEM images of modified CO3-LDHs indicated that the size of particals were not varied. But the particals stacked together, which indicated that organism were joined on the surface of CO3-LDHs. The surface modification CO3-LDHs were successfully prepared.
引文
[1] Aamir I. Khan and Dermot O’Hare, Intercalation chemistry of layered double hydroxides: recent developments and applications [J]. J Mater Chem., 2002, 12: 3191–3198.
[2] Kok-Hui Goh, Teik-Thye Lim, Zhili Dong, Application of layered double hydroxides for removal of oxyanions: A review [J]. Water Reaearch, 2008, 42:1343–1368.
[3] H.Chris Greenwel, A one-pot synthesis of hybrid organo-layered double hydroxide catalyst precursors [J]. Green Chem., 2006, 8:1067–1072.
[4] Jin-Ho Choy, Seo-Young Kwak, Jong-Sang Park et al., Cellular uptake behavior of [c-32P] labeled ATP–LDH nanohybrids [J]. J Mater Chem, 2001, 11:1671–1674.
[5] Fabrice Leroux, Mariko Adachi-Pagano, Mourad Intissar, et al., Delamination and restacking of layered double hydroxides [J]. J Mater Chem., 2001, 11:105-112.
[6] Toshiyuki Hibino, and Mikio Kobayashi, Delamination of layered double hydroxides in water [J]. J Mater Chem., 2005, 15:653–656.
[7] Lv Liang and Luo Li, Adsorption behavior of calcined layered double hydroxides towards removal of iodide contaminants [J]. J Radioanal Nucl Chem., 2007, 273:221-226.
[8] Wan-Guo Hou and Zhi-Lin Jin, Synthesis and characterization of Naproxen intercalated Zn–Al layered double hydroxides [J]. Colloid Polym Sci, 2007,285:1449–1454.
[9] Hongting Zhao and Kathryn L. Nagy, Dodecyl sulfate–hydrotalcite nanocomposites for trapping chlorinated organic pollutants in water [J]. J Colloid Interface Sci., 2004, 274:613-624.
[10] Bert F. Sels, Dirk E. De Vos, Piet J. Grobet, et al., Molybdate- and Tungstate-Exchanged Layered Double Hydroxides as Catalysts for 1O2 Formation: Characterization of Reactive Oxygen Species and a Critical Evaluation of 1O2 Detection Methods [J]. J Phys Chem B, 1999, 103:11114-11123.
[11] H. Chris Greenwell, Stephen Stackhouse, Peter V. Coveney and William Jones, A Density Functional Theory Study of Catalytic trans-Esterification by tert-Butoxide MgAl Anionic Clays [J]. J Phys Chem B, 2003, 107:3476-3485.
[12] Federica Prinetto, Giovanna Ghiotti, Robert Durand and Didier Tichit, Investigation of Acid-Base Properties of Catalysts Obtained from Layered Double Hydroxides [J]. J Phys Chem. B, 2000, 104:11117-11126.
[13] Guo-An Wang, Cheng-Chien Wang and Chuh-Yung Chen, Preparation and Characterization of Layered Double Hydroxides PMMA Nanocomposites by Solution Polymerization [J] JInorg Organomet Polym, 2005, 15:239-251.
[14] Choy J. H., Kwak S. Y., Park J. S., Intercalative nanohybrids of nucleoside monophosphates and DNA in layered metal hydroxide.[J] J. Am. Chem. Soc., 1999, 121:1399-1400.
[15] Choy J. H., Kwak S. Y.; Jeong Y. J., Park J.S., Inorganic layered double hydroxides as nonviral vectors. [J]. Angew. Chem. Int. Ed. Engl., 2000, 39:4042-4045.
[16] Choy J.H., Kwak S.Y., Park J.S., Cellular uptake behavior of [γ-32P] labeled ATP-LDH nanohybrids. [J]. J. Mater. Chem., 2001, 11:1671-1674.
[17] Kwak S.Y., Jeong Y. J., Park J.S., Choy J.H., Bio-LDH Nanohybrid for Gene Therapy [J]. Solid State Ionics., 2002, 151:229-234.
[18] Khan A.I., Norquist A.J., O’Hare D., Intercalation and Controlled Release of Pharmaceutically Active Compounds from a Layered Double Hydroxide. [J].Chem. Commun., 2001, 22 :2342-2343.
[19] Darder M., Lopez-Blanco M., Aranda P., Leroux F., Ruiz-Hitzky E., Bio-Nanocomposites Based on Layered Double Hydroxides. [J].Chem. Mater., 2005, 17:1969-1977.
[20] Wei M., Yuan Q., Evans D. G., Wang Z., Duan X., Layered solids as a“molecular container”for pharmaceutical agents: L-tyrosine-intercalated layered double hydroxides. [J].J. Mater. Chem., 2005, 15:1197-1203.
[21] Gerstel P., Hoffmann R.C., Lipowsky P., Jeurgens L.P.H., Bill J., Aldinger F., Mineralization from Aqueous Solutions of Zinc Salts Directed by Amino Acids and Peptides. [J].Chem. Mater., 2006, 18 (1):179–186.
[22] Mohanambe L., Vasudevan S., Anionic Clays Containing Anti-Inflammatory Drug Molecules: Comparison of Molecular Dynamics Simulation and Measurements. [J]. J. Phys. Chem. B., 2005, 109:15651-15658.
[23] Ambrogi V., Fardella G., Grandolini G., Intercalation compounds of hydrotalcite-like anionic clays with antiinflammatory agents-I. Intercalation and in vitro release of ibuprofen. [J].Int. J. Pharm., 2001, 220:23-32.
[24] Choy J.H., Jung J.S., Oh J.M., Park M., Jeong J., Kang Y.K., Han O.J., Layered double hydroxide as an efficient drug reservoir for folate derivatives. [J].Biomaterials, 2004, 25 (15):3059-3064.
[25] Steven P. Newman and William Jones, Synthesis, characterization and applications oflayered double hydroxides containing organic guests [J]. New J Chem., 1998, 105-115.
[26] Fabrice Leroux and Christine Taviot-Gue′ho, Fine tuning between organic and inorganic hoststructure : new trends in layered double hydroxide hybrid assemblies [J]. J Mater Chem., 2005, 15:3628-3642.
[27] Jin-Ho Choy,Soo-Jin Choi, Jae-Min Oh, Taeun Park, Clay minerals and layered double hydroxides for novel biological applications [J]. Applied Clay Science, 2007, 36:122–132.
[28] Gareth R. Williams and Dermot O’Hare, Towards understanding, control and application of layered double hydroxide chemistry [J]. J Mater Chem., 2006 ,16:3065-3074.
[29] L.A. Utracki, M. Sepehr and E. Boccaleri, Synthetic, layered nanoparticles for polymeric nanocomposites (PNCs) [J]. Polym Adv Technol, 2007, 18:1-37.
[30] Vicente Rives* and Srinivasan Kannanb, Layered double hydroxides with the hydrotalcite type structure containing Cu2+, Ni2+ and Al3+[J]. J Mater Chem., 2000, 10:489-495.
[31] Vanessa Pre?vot, Blanca Casal and Eduardo Ruiz-Hitzky, Intracrystalline alkylation of benzoate ions into layered double hydroxides [J]. J. Mater. Chem., 2001, 11:554-560.
[32] G. Fornasari, M. Gazzzano, D. Mateuzzi., F. Trifro, A. Vaccari, Structure and reactivity of high-surface-area Ni/Mg/Al mixed oxides[J] Appl. Clay Sci., 1995, 10: 69-82.
[33] V. R. L. Constantino, T. Pinnavaia, Basic properties of Mg2+1-xAl3+x layered double hydroxides intercalated by carbonate, hydroxide, chloride, and sulfate anions [J]. Inorg. Chem., 1995, 34: 883-892.
[34] F. Millange, R.I. Walton, D.O'Hare, Time-resolved in-Situ X-ray diffraction study of the liquid-phase reconstruction of Mg-Al-Carbonate Hydrotalcite-like compounds[J]. Mater. Chem., 2000, 10: 1713-1720.
[35] M. A. Aramendia,Y.Aviles,V.Vorau, Thermal decomposition of Mg/Al and Mg/Ga layered-double hydroxides: a spectroscopic study [J] J. Mater. Chem., 1999, 9: 1603-1607.
[36] S. H. Han, C. G. Zhang, W. G. Hou, D. J. Sun, G. T.Wang , Study on the preparation and structure of positive sol composed of mixed metal hydroxide[J] Colloid Polym. Sci.,1996, 274: 860-865.
[37] W. T. Reichle, Synthesis of anionic clay minerals (mixed metal hydroxide, hydrotalcite)[J] Solid State Ionics, 1986, 22:135-141.
[38] M. R. Weir, R. A. Kydd, Synthesis of heteropolyoxometalate-pillared Mg/Al, Mg/Ga, and Zn/Al layered double hydroxides via LDH-Hydroxide Precursors[J] Inorg. Chem., 1998, 37: 5619-5624.
[39] K. R. Kottapalli, G. Monique, Activation of Mg-Al hydrotalcite catalysts for aldol condensation reactions[J] J. Catalysis, 1998, 173: 115-121.
[40] P. Federica, T. Didier, Mg-and Ni-containing layered double hydroxides as soda substitutes in the aldol condensation of acetone [J].Chem. Commun., 2000, 55: 103-116.
[41] N. S. Puttaswamy, P. V. Kamath, Reversible thermal behaviour of layered double hydroxides:a thermogravimetric study [J] J. Mater. Chem., 1997, 7: 1941.
[42] J. Rocha, M. del Arco, V. Rives, M. A. Ulibarri, Combustion synthesis and properties of strontium substituted lanthanum manganites La1–xSrxMnO3 [J]. J. Mater. Chem., 1999, 9:2499.
[43] S. K. Pramod, S. V. Jaime, C. F. Fran, Modified Mg–Al hydrotalcite: a highly active heterogeneous base catalyst for cyanoethylation of alcohols [J] Chem. Commun., 1998, 1091-1092.
[44] E. Abdelali, L. Ahmed, De R. André, P. B. Jean, Shape and size determination for zinc–aluminium–chloride layered double hydroxide crystallites by analysis of X-ray diffraction line broadening [J] J. Mater. Chem., 2000, 10: 2337-2341.
[45] H. C. B. Hansen, R. M. Taylor, Formation of synthetic analogues of double metal-hydroxycarbonate minerals under controlled pH conditions:The synthesis of desautelsite [J] Clay Miner., 1991, 26: 507.
[46] I. Pausch, H. H. Lohse, K. Schurmann, R. Allmann, Synthesis of disordered and Al-rich hydrotalcite-like compounds [J] Clays Clay Miner., 1986, 34: 507.
[47]谢晖,矫庆泽,段雪,镁铝型水滑石水热合成[J].应用化学, 2001, 18: 70-72.
[48] P. Federica, G. Giovanna, G. Patrick, et al., Synthesis and characterization of sol-gel Mg/Al and Ni/Al layered double hydroxides and comparison with co-precipitated samples [J]. Microporous Mesoporous Mater., 2000, 39: 229-247.
[49] G. W. Brindley, S. Kikkawa, A crystal-chemical study of Mg,A1 and Ni,AI hydroxy-perchlorates and. hydroxy-carbonates [J]. Am. Miner.,1979, 64: 836.
[50] I. Di Cosimo, V. K. Diez, C. R. Apesteguia, Synthesis ofα,β-unsaturated ketones over thermally activated Mg-Al hydrotalcites [J]. Appl. Clay Sci., 1998, 13: 433-449.
[51] E. C. Kruissink, L. L. van Reijen, J. R. H. Ross, Coprecipitated nickel-alumina catalysts for methanation at high temperature, Part 1. Chemical composition and structure of the precipitates [J]. J. Chem. Soc. Faraday Trans., 1981, 77: 649.
[52]郭军,孙铁,硅钨系列三元杂多阴离子柱撑水滑石的合成、表征及其酸碱催化性能[J]高等化学学报,1995, 3: 346-550.
[53]刘继广,郭军,杂多阴离子组成水滑石类层柱材料中层柱相互作用研究[J]高等化学学报,1995, 9: 1329.
[54] M. del Arco, P. Malet, R. Trujillano, Synthesis and characterization of hydrotalcites containing Ni(II) and Fe(III) and their calcination products [J]. Chem. Mater., 1999, 11: 624-633.
[55] X. W. You, H. T. Zhao, C. F. Vaccari, Surfactant-enhance adsorption of organic compounds by layered double hydroxides [J].Colloid surf., A 2002, 205: 161.
[56] X. W. You, H. T. Zhao, C. F. Vaccari, hybrids organic-inorganic derivatives of layered double hydroxides and dodecylbenzenesulfonate: Preparation and adsorption characteristics [J]. J. Mater. Sci., 2002, 12: 907.
[57] S. P. Newman, W. Jones, Synthesis, characterization and applications of layered double hydroxides containing organic guests [J]. New J. Chem., 1998, 22: 105-115.
[58] J. T. Kloprogge, R. L. Frost, Infrared emission spectroscopic study of the thermal transformation of Mg-, Ni- and Co-hydrotalcite catalysts. [J]. Appl. Catal. A: 1999, 184: 61-71.
[59] J. T. Kloprogge, R. L. Frost. Infrared emission spectroscopic study of the dehydroxylation of synthetic Mg/Al and Mg/Zn/Al-hydrotalcites [J]. Phys. Chem. Chem. Phys., 1999, 1: 1641-1647.
[60] S. Miyata, The sythesis of hydrotalcite-like compounds and their structures andphysico-chemical properties [J] Clays Clay Miner., 1975, 23: 369-375.
[61] D. L. Bish, G. W. Brindley, Amer. Min., 1977, 25: 14.
[62] G. J. Ross, H. Kodama, Amer. Min., 1967, 52: 1037.
[63] G. Mascolo, O. marino, A new synthesis and. characterization of magnesium -aluminum hydroxides [J]. Miner. Mag., 1980, 43: 619.
[64] V. A. Drits, New members of the hydrotalcite-manasseite group [J]. Clays Clay Miner., 1987, 35: 401.
[65] R. A. Vaia, K. D. Jandt, Microstructural evolution of melt intercalated polymer-organically modified layered silicates nanocomposites[J]. Chem. Mater., 1996, 8: 2628-2635.
[66] R. V. Prikhod’ko, M. V. Sychev, I. M. Astrelin, K. Erdmann, A. Mangel, R. A. van Santen Russian, Synthesis and structural transformations of hydrotalcite- like materials Mg3Al and Zn3Al [J].J. Appl. Chem., 2001, 74: 231.
[67] D. Tichit, M. N. Bennani, F. Figueras, J. R. Ruiz, Decomposition processes and characterization of the surface basicity of Cl- and CO32- hydrotalcites [J]. Langmuir, 1998, 14:2086-2091.
[68] Khan A.I., Norquist A.J., O’Hare D., Intercalation and Controlled Release of Pharmaceutically Active Compounds from a Layered Double Hydroxide [J]. Chem. Commun., 2001, 22 (11): 2342-2343.
[69] Aisawa S., Takahashi S., Ogasawara W.Y., Narita E., Direct intercalation of amino acids into layered double hydroxides by coprecipitation.[J] J. Solid State Chem., 2001, 162:52-62.
[70] Leroux F., Adachi-Pagano M., Intissar M., Chauviere S., Forano C., Besse J.P., Delamination and restacking of layered double hydroxides.[J] J. Mater. Chem., 2001, 11:105-112.
[71] Hibino T., Jones W.,New approach to the delamination of layered double hydroxides. [J]. J. Mater. Chem., 2001, 11 (5):1321-1323.
[72] Ogawa M., Asai S., Hydrothermal synthesis of layered double hydroxide-deoxycolate. intercalation compounds.[J]. Chem. Mater., 2000, 12 (11):3253-3255.
[73] Nakayama H., Wada N., Tsuhako M., Intercalation of amino acids and peptides into Mg-Al layered double hydroxide by reconstruction method [J]. Int. J. Pharm., 2004, 269 (2):469-478.
[74]段雪,张法智等,插层组装与功能材料.北京化学工业出版社, 2007, 57-58.
[75] Mohanambe L., Vasudevan S.,Aromatic molecules in restricted geometries: Photophysis of naphthalene of included in a cyclodextrin functionalized layerd solid. [J].J. Phys. Chem. B, 2005, 109:22523-22529.
[76] Schenck R. T., Buzas A. J., U S Patent 2958626, 1960.
[77] Kumura T., Imataki N., Hasui T. K., Inoue T., U S Patent 3539306, 1970.
[78] Schneider M., Knecht, A., U S Patent 4482542, 1984.
[79] Miyata S., Takamatsu-shi., U S Patent 4514389, 1985.
[80] Katherine M. Tyner, Scott R. Schiffman, Emmanuel P. Giannelis, Nanobiohybrids as delivery vehicles for camptothecin [J]. Journal of Controlled Release. 2004, 95:501-514.
[81] Choy J. H., Kwak S. Y., Park J. S., Intercalative nanohybrids of nucleoside monophosphates and DNA in layered metal hydroxide. [J].J. Am. Chem. Soc., 1999, 121:1399-1400.
[82] Choy J. H., Kwak S. Y.; Jeong Y. J., Park J.S., Inorganic layered double hydroxides as nonviral vectors. [J]. Angew. Chem. Int. Ed. Engl., 2000, 39: 4042-4045.
[83] Kwak S.Y., Jeong Y. J., Park J.S., Choy J.H., Bio-LDH Nanohybrid for Gene Therapy. [J].Solid State Ionics., 2002, 151: 229-234.
[84] Hwang S. H., Han Y. S., Choy J. H., Intercalation of functional organic molecules with pharmaceutical, cosmeceutical and nutraceutical functions into layered double hydroxides and zinc basic salts. [J]. Bull. Korean. Chem. Soc., 2001, 22(9):1019-1022.
[85] Kwak S. Y., Kriven W. M., Wallig M. A., Choy J. H., Inorganic delivery vector for intravenous. injection. [J]. Biomaterials, 2004, 25 (28):5995-6001.
[86] Hoyo C.D., Layered double hydroxides and human health: An overview [J]. Applied Clay Science, 2007, 36:103-121.
[87] V. Ambrogi, G. Fardella, G. Grandolini, Intercalation compounds of hydrotalcite -like anionic clays with anti-inflammatory agents-I. Intercalation and in vitro release of ibuprofen [J]. Int. J. Pharm. 2001, 220: 23-32.
[88] B. Li, J. He, D.G. Evans, X. Duan, Inorganic layered double hydroxides as a drug delivery system - intercalation and in vitro release of fenbufen [J]. Appl. Clay Sci., 2004, 27: 199-207.
[89] A. I. Khan, L. Lei, A. J. Norquist, D. O’Hare, Intercalation and controlled release of pharmaceutically active compounds from a layered double hydroxide [J]. Chem. Commun., 2001: 2342-2343.
[90]孙辉,张慧,Evans, D.G.,段雪,磁性药物-无机纳米复合材料的结构设计与表征.[J].科学通报,2004, 49:2525-2530.
[91]邵建华,一种农药缓释营养剂及其生产方法,中国,发明专利,1451639,2003.
[92]袁青梅,原位聚合法制备鱼藤酮微胶囊,[J].应用化学,2006, 23:382-385.
[93]关家玉,欧晓斌,一种粘土纳米复合缓释农药及其制备方法和用途,中国,发明专利,101292652,2008.
[94] Lucelena P. Cardoso,Rafael Celis, Juan Cornejo, And Joao B. Valim, Layered Double Hydroxides as Supports for the Slow Release of Acid Herbicides, [J]. J. Agric. Food Chem. 2006, 54:5968-5975.
[95] M. Del Arco, S. Gutiérrez, C. Martín, V. Rives, J. Rocha, Synthesis and characterization of layered double hydroxides (LDH) intercalated with non- steroidal anti-inflammatory drugs (NSAID) [J]. J. Solid State Chem. 2004, 177: 3954-3962.
[96] Na Du, Wan-Guo Hou and Shu-E Song, A Novel Composite: Layered Double Hydroxides Encapsulated in Vesicles [J]. J. Phys. Chem. B C, 2007, 111 (50):13909–13913.
[97] M. K. Ram Reddy, Max Lu, et al. A one - pot synthesis of hybrid organo– layered double hydroxide catalyst precursors [J]. Ind. Eng. Chem. Res. 2006, 45(12): 7504~7509.
[98] S, Miyata, The sytheses of hydrotalcite-like compounds and their structures and physico-chemical properties [J]. Clays Clay Miner, 1975, 23: 369.
[99] Kopka H., Beneke K., Lagaly G., Anionic surfactants between double metal hydroxide layers. [J].J.Colloid Interface Sci., 1988, 123:427-436.
[100] Vicente R., Srinivasan K., Layered double hydroxides with the hydrotalcite-type structure containing Cu2+, Ni2+ and Al3+. [J].J. Mater. Chem., 2000, 10:489-495.
[101]侯万国,张春光,孙德军,氢氧化镁铝正电溶胶制备及性能研究.[J]高等学校化学学报, 1995, 16 (8):1292-1294.
[102] F. Cavani, F. Trifiro, A. Vaccari, Hydrotalcite-type anionic clays: preparation, properties and applications [J]. Catal. Today, 1991, 11: 173–301.
[103] Xu Z P, Zeng H C, [J]. J. Phys. Chem. B. 2001, 105:1743-1749.
[104] Xu Z P, Braterman P S [J]. J Mater. Chem. 2003,13:268-273.
[105] For R-SO3M and p. 5 for CH3 and CH2 stretching vibrations, see: Simons, W. W. (Ed.) The Sadtler Handbook of Infrared Spectra; Sadtler Research Laboratories, Inc.: PA, 1978; 377.
[106] Zhi Ping Xu, and Paul S. Braterman, [J]. J. Phys. Chem. C. 2007, 111:4021-4026.
[107] Ambrogi V, Fardella G, Grandolini G, Perioli L [J]. Tiralti MC AAPS Pharm Sci Tech. 2002,3:26-31.
[108] Bhaskar R, Murthy S RS, Miglani BD, Viswanathan K, Int J Pharm. 1986, 28:59-66.
[2] Kok-Hui Goh, Teik-Thye Lim, Zhili Dong, Application of layered double hydroxides for removal of oxyanions: A review [J]. Water Reaearch, 2008, 42:1343–1368.
[3] H.Chris Greenwel, A one-pot synthesis of hybrid organo-layered double hydroxide catalyst precursors [J]. Green Chem., 2006, 8:1067–1072.
[4] Jin-Ho Choy, Seo-Young Kwak, Jong-Sang Park et al., Cellular uptake behavior of [c-32P] labeled ATP–LDH nanohybrids [J]. J Mater Chem, 2001, 11:1671–1674.
[5] Fabrice Leroux, Mariko Adachi-Pagano, Mourad Intissar, et al., Delamination and restacking of layered double hydroxides [J]. J Mater Chem., 2001, 11:105-112.
[6] Toshiyuki Hibino, and Mikio Kobayashi, Delamination of layered double hydroxides in water [J]. J Mater Chem., 2005, 15:653–656.
[7] Lv Liang and Luo Li, Adsorption behavior of calcined layered double hydroxides towards removal of iodide contaminants [J]. J Radioanal Nucl Chem., 2007, 273:221-226.
[8] Wan-Guo Hou and Zhi-Lin Jin, Synthesis and characterization of Naproxen intercalated Zn–Al layered double hydroxides [J]. Colloid Polym Sci, 2007,285:1449–1454.
[9] Hongting Zhao and Kathryn L. Nagy, Dodecyl sulfate–hydrotalcite nanocomposites for trapping chlorinated organic pollutants in water [J]. J Colloid Interface Sci., 2004, 274:613-624.
[10] Bert F. Sels, Dirk E. De Vos, Piet J. Grobet, et al., Molybdate- and Tungstate-Exchanged Layered Double Hydroxides as Catalysts for 1O2 Formation: Characterization of Reactive Oxygen Species and a Critical Evaluation of 1O2 Detection Methods [J]. J Phys Chem B, 1999, 103:11114-11123.
[11] H. Chris Greenwell, Stephen Stackhouse, Peter V. Coveney and William Jones, A Density Functional Theory Study of Catalytic trans-Esterification by tert-Butoxide MgAl Anionic Clays [J]. J Phys Chem B, 2003, 107:3476-3485.
[12] Federica Prinetto, Giovanna Ghiotti, Robert Durand and Didier Tichit, Investigation of Acid-Base Properties of Catalysts Obtained from Layered Double Hydroxides [J]. J Phys Chem. B, 2000, 104:11117-11126.
[13] Guo-An Wang, Cheng-Chien Wang and Chuh-Yung Chen, Preparation and Characterization of Layered Double Hydroxides PMMA Nanocomposites by Solution Polymerization [J] JInorg Organomet Polym, 2005, 15:239-251.
[14] Choy J. H., Kwak S. Y., Park J. S., Intercalative nanohybrids of nucleoside monophosphates and DNA in layered metal hydroxide.[J] J. Am. Chem. Soc., 1999, 121:1399-1400.
[15] Choy J. H., Kwak S. Y.; Jeong Y. J., Park J.S., Inorganic layered double hydroxides as nonviral vectors. [J]. Angew. Chem. Int. Ed. Engl., 2000, 39:4042-4045.
[16] Choy J.H., Kwak S.Y., Park J.S., Cellular uptake behavior of [γ-32P] labeled ATP-LDH nanohybrids. [J]. J. Mater. Chem., 2001, 11:1671-1674.
[17] Kwak S.Y., Jeong Y. J., Park J.S., Choy J.H., Bio-LDH Nanohybrid for Gene Therapy [J]. Solid State Ionics., 2002, 151:229-234.
[18] Khan A.I., Norquist A.J., O’Hare D., Intercalation and Controlled Release of Pharmaceutically Active Compounds from a Layered Double Hydroxide. [J].Chem. Commun., 2001, 22 :2342-2343.
[19] Darder M., Lopez-Blanco M., Aranda P., Leroux F., Ruiz-Hitzky E., Bio-Nanocomposites Based on Layered Double Hydroxides. [J].Chem. Mater., 2005, 17:1969-1977.
[20] Wei M., Yuan Q., Evans D. G., Wang Z., Duan X., Layered solids as a“molecular container”for pharmaceutical agents: L-tyrosine-intercalated layered double hydroxides. [J].J. Mater. Chem., 2005, 15:1197-1203.
[21] Gerstel P., Hoffmann R.C., Lipowsky P., Jeurgens L.P.H., Bill J., Aldinger F., Mineralization from Aqueous Solutions of Zinc Salts Directed by Amino Acids and Peptides. [J].Chem. Mater., 2006, 18 (1):179–186.
[22] Mohanambe L., Vasudevan S., Anionic Clays Containing Anti-Inflammatory Drug Molecules: Comparison of Molecular Dynamics Simulation and Measurements. [J]. J. Phys. Chem. B., 2005, 109:15651-15658.
[23] Ambrogi V., Fardella G., Grandolini G., Intercalation compounds of hydrotalcite-like anionic clays with antiinflammatory agents-I. Intercalation and in vitro release of ibuprofen. [J].Int. J. Pharm., 2001, 220:23-32.
[24] Choy J.H., Jung J.S., Oh J.M., Park M., Jeong J., Kang Y.K., Han O.J., Layered double hydroxide as an efficient drug reservoir for folate derivatives. [J].Biomaterials, 2004, 25 (15):3059-3064.
[25] Steven P. Newman and William Jones, Synthesis, characterization and applications oflayered double hydroxides containing organic guests [J]. New J Chem., 1998, 105-115.
[26] Fabrice Leroux and Christine Taviot-Gue′ho, Fine tuning between organic and inorganic hoststructure : new trends in layered double hydroxide hybrid assemblies [J]. J Mater Chem., 2005, 15:3628-3642.
[27] Jin-Ho Choy,Soo-Jin Choi, Jae-Min Oh, Taeun Park, Clay minerals and layered double hydroxides for novel biological applications [J]. Applied Clay Science, 2007, 36:122–132.
[28] Gareth R. Williams and Dermot O’Hare, Towards understanding, control and application of layered double hydroxide chemistry [J]. J Mater Chem., 2006 ,16:3065-3074.
[29] L.A. Utracki, M. Sepehr and E. Boccaleri, Synthetic, layered nanoparticles for polymeric nanocomposites (PNCs) [J]. Polym Adv Technol, 2007, 18:1-37.
[30] Vicente Rives* and Srinivasan Kannanb, Layered double hydroxides with the hydrotalcite type structure containing Cu2+, Ni2+ and Al3+[J]. J Mater Chem., 2000, 10:489-495.
[31] Vanessa Pre?vot, Blanca Casal and Eduardo Ruiz-Hitzky, Intracrystalline alkylation of benzoate ions into layered double hydroxides [J]. J. Mater. Chem., 2001, 11:554-560.
[32] G. Fornasari, M. Gazzzano, D. Mateuzzi., F. Trifro, A. Vaccari, Structure and reactivity of high-surface-area Ni/Mg/Al mixed oxides[J] Appl. Clay Sci., 1995, 10: 69-82.
[33] V. R. L. Constantino, T. Pinnavaia, Basic properties of Mg2+1-xAl3+x layered double hydroxides intercalated by carbonate, hydroxide, chloride, and sulfate anions [J]. Inorg. Chem., 1995, 34: 883-892.
[34] F. Millange, R.I. Walton, D.O'Hare, Time-resolved in-Situ X-ray diffraction study of the liquid-phase reconstruction of Mg-Al-Carbonate Hydrotalcite-like compounds[J]. Mater. Chem., 2000, 10: 1713-1720.
[35] M. A. Aramendia,Y.Aviles,V.Vorau, Thermal decomposition of Mg/Al and Mg/Ga layered-double hydroxides: a spectroscopic study [J] J. Mater. Chem., 1999, 9: 1603-1607.
[36] S. H. Han, C. G. Zhang, W. G. Hou, D. J. Sun, G. T.Wang , Study on the preparation and structure of positive sol composed of mixed metal hydroxide[J] Colloid Polym. Sci.,1996, 274: 860-865.
[37] W. T. Reichle, Synthesis of anionic clay minerals (mixed metal hydroxide, hydrotalcite)[J] Solid State Ionics, 1986, 22:135-141.
[38] M. R. Weir, R. A. Kydd, Synthesis of heteropolyoxometalate-pillared Mg/Al, Mg/Ga, and Zn/Al layered double hydroxides via LDH-Hydroxide Precursors[J] Inorg. Chem., 1998, 37: 5619-5624.
[39] K. R. Kottapalli, G. Monique, Activation of Mg-Al hydrotalcite catalysts for aldol condensation reactions[J] J. Catalysis, 1998, 173: 115-121.
[40] P. Federica, T. Didier, Mg-and Ni-containing layered double hydroxides as soda substitutes in the aldol condensation of acetone [J].Chem. Commun., 2000, 55: 103-116.
[41] N. S. Puttaswamy, P. V. Kamath, Reversible thermal behaviour of layered double hydroxides:a thermogravimetric study [J] J. Mater. Chem., 1997, 7: 1941.
[42] J. Rocha, M. del Arco, V. Rives, M. A. Ulibarri, Combustion synthesis and properties of strontium substituted lanthanum manganites La1–xSrxMnO3 [J]. J. Mater. Chem., 1999, 9:2499.
[43] S. K. Pramod, S. V. Jaime, C. F. Fran, Modified Mg–Al hydrotalcite: a highly active heterogeneous base catalyst for cyanoethylation of alcohols [J] Chem. Commun., 1998, 1091-1092.
[44] E. Abdelali, L. Ahmed, De R. André, P. B. Jean, Shape and size determination for zinc–aluminium–chloride layered double hydroxide crystallites by analysis of X-ray diffraction line broadening [J] J. Mater. Chem., 2000, 10: 2337-2341.
[45] H. C. B. Hansen, R. M. Taylor, Formation of synthetic analogues of double metal-hydroxycarbonate minerals under controlled pH conditions:The synthesis of desautelsite [J] Clay Miner., 1991, 26: 507.
[46] I. Pausch, H. H. Lohse, K. Schurmann, R. Allmann, Synthesis of disordered and Al-rich hydrotalcite-like compounds [J] Clays Clay Miner., 1986, 34: 507.
[47]谢晖,矫庆泽,段雪,镁铝型水滑石水热合成[J].应用化学, 2001, 18: 70-72.
[48] P. Federica, G. Giovanna, G. Patrick, et al., Synthesis and characterization of sol-gel Mg/Al and Ni/Al layered double hydroxides and comparison with co-precipitated samples [J]. Microporous Mesoporous Mater., 2000, 39: 229-247.
[49] G. W. Brindley, S. Kikkawa, A crystal-chemical study of Mg,A1 and Ni,AI hydroxy-perchlorates and. hydroxy-carbonates [J]. Am. Miner.,1979, 64: 836.
[50] I. Di Cosimo, V. K. Diez, C. R. Apesteguia, Synthesis ofα,β-unsaturated ketones over thermally activated Mg-Al hydrotalcites [J]. Appl. Clay Sci., 1998, 13: 433-449.
[51] E. C. Kruissink, L. L. van Reijen, J. R. H. Ross, Coprecipitated nickel-alumina catalysts for methanation at high temperature, Part 1. Chemical composition and structure of the precipitates [J]. J. Chem. Soc. Faraday Trans., 1981, 77: 649.
[52]郭军,孙铁,硅钨系列三元杂多阴离子柱撑水滑石的合成、表征及其酸碱催化性能[J]高等化学学报,1995, 3: 346-550.
[53]刘继广,郭军,杂多阴离子组成水滑石类层柱材料中层柱相互作用研究[J]高等化学学报,1995, 9: 1329.
[54] M. del Arco, P. Malet, R. Trujillano, Synthesis and characterization of hydrotalcites containing Ni(II) and Fe(III) and their calcination products [J]. Chem. Mater., 1999, 11: 624-633.
[55] X. W. You, H. T. Zhao, C. F. Vaccari, Surfactant-enhance adsorption of organic compounds by layered double hydroxides [J].Colloid surf., A 2002, 205: 161.
[56] X. W. You, H. T. Zhao, C. F. Vaccari, hybrids organic-inorganic derivatives of layered double hydroxides and dodecylbenzenesulfonate: Preparation and adsorption characteristics [J]. J. Mater. Sci., 2002, 12: 907.
[57] S. P. Newman, W. Jones, Synthesis, characterization and applications of layered double hydroxides containing organic guests [J]. New J. Chem., 1998, 22: 105-115.
[58] J. T. Kloprogge, R. L. Frost, Infrared emission spectroscopic study of the thermal transformation of Mg-, Ni- and Co-hydrotalcite catalysts. [J]. Appl. Catal. A: 1999, 184: 61-71.
[59] J. T. Kloprogge, R. L. Frost. Infrared emission spectroscopic study of the dehydroxylation of synthetic Mg/Al and Mg/Zn/Al-hydrotalcites [J]. Phys. Chem. Chem. Phys., 1999, 1: 1641-1647.
[60] S. Miyata, The sythesis of hydrotalcite-like compounds and their structures andphysico-chemical properties [J] Clays Clay Miner., 1975, 23: 369-375.
[61] D. L. Bish, G. W. Brindley, Amer. Min., 1977, 25: 14.
[62] G. J. Ross, H. Kodama, Amer. Min., 1967, 52: 1037.
[63] G. Mascolo, O. marino, A new synthesis and. characterization of magnesium -aluminum hydroxides [J]. Miner. Mag., 1980, 43: 619.
[64] V. A. Drits, New members of the hydrotalcite-manasseite group [J]. Clays Clay Miner., 1987, 35: 401.
[65] R. A. Vaia, K. D. Jandt, Microstructural evolution of melt intercalated polymer-organically modified layered silicates nanocomposites[J]. Chem. Mater., 1996, 8: 2628-2635.
[66] R. V. Prikhod’ko, M. V. Sychev, I. M. Astrelin, K. Erdmann, A. Mangel, R. A. van Santen Russian, Synthesis and structural transformations of hydrotalcite- like materials Mg3Al and Zn3Al [J].J. Appl. Chem., 2001, 74: 231.
[67] D. Tichit, M. N. Bennani, F. Figueras, J. R. Ruiz, Decomposition processes and characterization of the surface basicity of Cl- and CO32- hydrotalcites [J]. Langmuir, 1998, 14:2086-2091.
[68] Khan A.I., Norquist A.J., O’Hare D., Intercalation and Controlled Release of Pharmaceutically Active Compounds from a Layered Double Hydroxide [J]. Chem. Commun., 2001, 22 (11): 2342-2343.
[69] Aisawa S., Takahashi S., Ogasawara W.Y., Narita E., Direct intercalation of amino acids into layered double hydroxides by coprecipitation.[J] J. Solid State Chem., 2001, 162:52-62.
[70] Leroux F., Adachi-Pagano M., Intissar M., Chauviere S., Forano C., Besse J.P., Delamination and restacking of layered double hydroxides.[J] J. Mater. Chem., 2001, 11:105-112.
[71] Hibino T., Jones W.,New approach to the delamination of layered double hydroxides. [J]. J. Mater. Chem., 2001, 11 (5):1321-1323.
[72] Ogawa M., Asai S., Hydrothermal synthesis of layered double hydroxide-deoxycolate. intercalation compounds.[J]. Chem. Mater., 2000, 12 (11):3253-3255.
[73] Nakayama H., Wada N., Tsuhako M., Intercalation of amino acids and peptides into Mg-Al layered double hydroxide by reconstruction method [J]. Int. J. Pharm., 2004, 269 (2):469-478.
[74]段雪,张法智等,插层组装与功能材料.北京化学工业出版社, 2007, 57-58.
[75] Mohanambe L., Vasudevan S.,Aromatic molecules in restricted geometries: Photophysis of naphthalene of included in a cyclodextrin functionalized layerd solid. [J].J. Phys. Chem. B, 2005, 109:22523-22529.
[76] Schenck R. T., Buzas A. J., U S Patent 2958626, 1960.
[77] Kumura T., Imataki N., Hasui T. K., Inoue T., U S Patent 3539306, 1970.
[78] Schneider M., Knecht, A., U S Patent 4482542, 1984.
[79] Miyata S., Takamatsu-shi., U S Patent 4514389, 1985.
[80] Katherine M. Tyner, Scott R. Schiffman, Emmanuel P. Giannelis, Nanobiohybrids as delivery vehicles for camptothecin [J]. Journal of Controlled Release. 2004, 95:501-514.
[81] Choy J. H., Kwak S. Y., Park J. S., Intercalative nanohybrids of nucleoside monophosphates and DNA in layered metal hydroxide. [J].J. Am. Chem. Soc., 1999, 121:1399-1400.
[82] Choy J. H., Kwak S. Y.; Jeong Y. J., Park J.S., Inorganic layered double hydroxides as nonviral vectors. [J]. Angew. Chem. Int. Ed. Engl., 2000, 39: 4042-4045.
[83] Kwak S.Y., Jeong Y. J., Park J.S., Choy J.H., Bio-LDH Nanohybrid for Gene Therapy. [J].Solid State Ionics., 2002, 151: 229-234.
[84] Hwang S. H., Han Y. S., Choy J. H., Intercalation of functional organic molecules with pharmaceutical, cosmeceutical and nutraceutical functions into layered double hydroxides and zinc basic salts. [J]. Bull. Korean. Chem. Soc., 2001, 22(9):1019-1022.
[85] Kwak S. Y., Kriven W. M., Wallig M. A., Choy J. H., Inorganic delivery vector for intravenous. injection. [J]. Biomaterials, 2004, 25 (28):5995-6001.
[86] Hoyo C.D., Layered double hydroxides and human health: An overview [J]. Applied Clay Science, 2007, 36:103-121.
[87] V. Ambrogi, G. Fardella, G. Grandolini, Intercalation compounds of hydrotalcite -like anionic clays with anti-inflammatory agents-I. Intercalation and in vitro release of ibuprofen [J]. Int. J. Pharm. 2001, 220: 23-32.
[88] B. Li, J. He, D.G. Evans, X. Duan, Inorganic layered double hydroxides as a drug delivery system - intercalation and in vitro release of fenbufen [J]. Appl. Clay Sci., 2004, 27: 199-207.
[89] A. I. Khan, L. Lei, A. J. Norquist, D. O’Hare, Intercalation and controlled release of pharmaceutically active compounds from a layered double hydroxide [J]. Chem. Commun., 2001: 2342-2343.
[90]孙辉,张慧,Evans, D.G.,段雪,磁性药物-无机纳米复合材料的结构设计与表征.[J].科学通报,2004, 49:2525-2530.
[91]邵建华,一种农药缓释营养剂及其生产方法,中国,发明专利,1451639,2003.
[92]袁青梅,原位聚合法制备鱼藤酮微胶囊,[J].应用化学,2006, 23:382-385.
[93]关家玉,欧晓斌,一种粘土纳米复合缓释农药及其制备方法和用途,中国,发明专利,101292652,2008.
[94] Lucelena P. Cardoso,Rafael Celis, Juan Cornejo, And Joao B. Valim, Layered Double Hydroxides as Supports for the Slow Release of Acid Herbicides, [J]. J. Agric. Food Chem. 2006, 54:5968-5975.
[95] M. Del Arco, S. Gutiérrez, C. Martín, V. Rives, J. Rocha, Synthesis and characterization of layered double hydroxides (LDH) intercalated with non- steroidal anti-inflammatory drugs (NSAID) [J]. J. Solid State Chem. 2004, 177: 3954-3962.
[96] Na Du, Wan-Guo Hou and Shu-E Song, A Novel Composite: Layered Double Hydroxides Encapsulated in Vesicles [J]. J. Phys. Chem. B C, 2007, 111 (50):13909–13913.
[97] M. K. Ram Reddy, Max Lu, et al. A one - pot synthesis of hybrid organo– layered double hydroxide catalyst precursors [J]. Ind. Eng. Chem. Res. 2006, 45(12): 7504~7509.
[98] S, Miyata, The sytheses of hydrotalcite-like compounds and their structures and physico-chemical properties [J]. Clays Clay Miner, 1975, 23: 369.
[99] Kopka H., Beneke K., Lagaly G., Anionic surfactants between double metal hydroxide layers. [J].J.Colloid Interface Sci., 1988, 123:427-436.
[100] Vicente R., Srinivasan K., Layered double hydroxides with the hydrotalcite-type structure containing Cu2+, Ni2+ and Al3+. [J].J. Mater. Chem., 2000, 10:489-495.
[101]侯万国,张春光,孙德军,氢氧化镁铝正电溶胶制备及性能研究.[J]高等学校化学学报, 1995, 16 (8):1292-1294.
[102] F. Cavani, F. Trifiro, A. Vaccari, Hydrotalcite-type anionic clays: preparation, properties and applications [J]. Catal. Today, 1991, 11: 173–301.
[103] Xu Z P, Zeng H C, [J]. J. Phys. Chem. B. 2001, 105:1743-1749.
[104] Xu Z P, Braterman P S [J]. J Mater. Chem. 2003,13:268-273.
[105] For R-SO3M and p. 5 for CH3 and CH2 stretching vibrations, see: Simons, W. W. (Ed.) The Sadtler Handbook of Infrared Spectra; Sadtler Research Laboratories, Inc.: PA, 1978; 377.
[106] Zhi Ping Xu, and Paul S. Braterman, [J]. J. Phys. Chem. C. 2007, 111:4021-4026.
[107] Ambrogi V, Fardella G, Grandolini G, Perioli L [J]. Tiralti MC AAPS Pharm Sci Tech. 2002,3:26-31.
[108] Bhaskar R, Murthy S RS, Miglani BD, Viswanathan K, Int J Pharm. 1986, 28:59-66.