环境中有机污染物的有机地球化学及其光催化降解研究
详细信息    本馆镜像全文|  推荐本文 |  |   获取CNKI官网全文
摘要
多环芳烃(Polycyclic aromatic hydrocarbons, PAHs)类物质具有“三致”作用,是环境中普遍存在的有机污染物之一,因而被列为环境中的优先控制污染物。PAHs可以通过食物链或呼吸空气进入人体,并在人体内蓄积,从而对人体产生危害。煤炭作为主要战略能源在开采和利用的过程中向环境中释放了大量PAHs。本文应用地球化学基本原理,从煤炭能源入手,以PAHs在原煤、燃煤电厂飞灰和底灰以及矿区土壤中的赋存规律、迁移富集为主线,形成了对PAHs较为系统的有机地球化学研究。通过实验分析找到PAHs在来自中国和美国的不同煤中的赋存机制,对煤中PAHs的地球化学理论进行了拓展和补充;揭示了从原煤到底灰、飞灰和燃煤过程中,PAHs的迁移变化规律和化学过程,探索了PAHs在不同粒度灰中的赋存机制;进而以矿区不同环境介质为研究载体,探讨了在矿区矿业相关的活动影响下,PAHs在表层土壤环境中的迁移、富集等地球化学特征。
     持久性有机污染物的去除在当前是一个全球性的难题,半导体光催化剂有望能够利用太阳能进行光催化降解,为了更好的利用阳光和室内灯光,合成出可以被可见光激发的光催化剂成为众多研究者的研究目标,基于这一目标,我们首次合成了经掺杂改性后在可见光下(λ>420nmm)具有较高活性的掺氮铌酸钾纳米方块和掺镧钽酸银纳米片光催化剂,对有机染料(如橙黄G,甲基蓝,罗丹明B等)和有机污染物(如双酚A,五氯联苯等)在可见光下(λ>420nmm)具有很高的光催化降解活性,从而为有机污染物的去除提供了一个新途径。
     通过研究主要得出:(1)针对中国和美国具有代表性的4个煤种14个煤样为研究对象,定量的揭示了随着煤化程度的提高,煤中PAHs与致癌性PAHs含量呈现先升高后降低的趋势,在6个烟煤样品中最高(12.11~55.63μg/g),而在天然焦中最低(0.31~0.38μg/g)。煤中优控PAHs的分布随着煤化程度的提高也呈现规律性的变化趋势:低环PAHs与PAHs总量的比值随着变质程度的升高而降低,高环PAHs与PAHs,总量的比值随着变质程度的升高而降低。煤中硫含量也是影响煤中PAHs赋存的重要因素,本研究中高硫煤样品主要受海相沉积环境的影响,低硫煤样品受陆相淡水沉积环境的影响,因此我们推断煤的沉积环境是影响PAHs在煤中赋存的重要因素。(2)电厂底灰中PAHs和致癌性PAHs含量高于飞灰和土地使用的PAHs限制标准,因此对电厂底灰的环境影响更应该引起重视。电厂煤灰的粒径和总有机碳含量等特征是影响PAHs含量和分布的重要因素:PAHs在飞灰中的分布随着粒径的变小呈现增加的趋势,而总有机碳含量较高则是造成底灰中PAHs含量,尤其是致癌性PAHs含量较高的重要因素。(3)两淮煤矿区在矿业相关活动影响下受到较强的PAHs污染,表层土壤中优控PAHs的浓度为0.13μg/g~3.54μg/g,平均值为0.84μg/g;致癌性PAHs浓度为0.05μg/g~1.33μg/g,平均值为0.36μg/g。煤矸石的堆放和煤的洗选是矿区土壤中PAHs的主要点源,PAHs在表生土壤环境中的水平迁移范围大于350m,在土壤坡面中随深度增加未形成明显的积累,说明PAHs纵向迁移能力不强。通过毒性评价可知,矿区土壤污染贡献最大的是苯并[a]芘,其TEQ达25%~53.5%。(4)首次成功制备出可将光(λ>420nm)下有较高活性的掺氮铌酸钾纳米方块,并将其用于水中染料和有害有机物质的降解,结果表明,N-KNbO3在可见光下对橙黄G、五氯联苯和双酚A的降解速率为Ti02的1.38-2.09倍,主要是由于N2p轨道比02p轨道的能带位置更高,经过掺氮改性后KNbO3纳米方块的能隙变窄,从而实现对光谱吸收的红移。此外,比表面积的增大也是造成其光催化活性增大的重要原因。(5)首次成功制备出可将光(λ>420nm)下有较高活性的钽酸银纳米片,并发现镧的掺杂可以提高其催化活性。在可见光下对罗丹明B和五氯联苯的降解结果发现,镧离子的掺杂量是影响其光催化活性的关键因素。钽酸银纳米片经过镧掺杂改性后光催化性能提高的原因主要是由于镧离子的掺杂导致大量纳米线的生成,因而更进一步的促进了光生载流子的分离效率。
Polycyclic aromatic hydrocarbons (PAHs) belong to a class of organic contaminants of great environmental concern. They have grasped much attention due to their carcinogenic potential and ubiquitous presence in the environment. Various forms of PAHs in coals or from coal combustion may affect human, especially indoor coal combustion. In the meantime, PAHs in raw coal can reduce or even poison the activity of catalysts in the refinery, making the stockpile of liquid product unstable. Many literatures concluded that most of the PAHs come from fossil-fuel combustion. However, their pollution from raw coal were usually neglected.
     The abundances of sixteen polycyclic aromatic hydrocarbons (PAHs) on the priority list of U.S. Environmental Protection Agency (USEPA) have been determined in fourteen Chinese and American coals. The ranks of the samples range from lignite, bituminous coal, anthracite to natural coke. The results show that the total PAHs content ranged from0.31to57.6μg/g coal (on a dry basis). It varied with coal rank and is highest in the maturity range of bituminous coal rank. High-molecular-weight (HMW) PAHs are predominant in low-rank coals, but low-molecular-weight (LMW) PAHs are predominant in high-rank coals. The Low-sulfur coals have a higher PAHs content than high S coals. It may be explained by an increasing connection between disulfide bonds and PAHs in high-S coal. In addition, it leads us to conclude that the PAH content of coals may be related to the depositional environment. Fly ash and bottom ash samples were collected from a coal-fired power plant located in Anhui province, China. In the fly ashes, the Σ16PAH (total amount of16PAHs) and the CPAHs (total amount of eight carcinogenic PAHs) levels varied from0.93to2.08μg/g,0.26to0.87μg/g, respectively. In the bottom ashes, Σ16PAH and the CPAHs levels varied from2.83to5.32μg/g,1.76to3.76μg/g, respectively. The CPAHs levels of some ashes, especially for the bottom ashes, are above the limits regulated by several countries, indicating that this type of coal combustion product need special treatment before landfill. Fly ashes were dominated by medium molecular weight (MMW)PAHs and low molecular weight (LMW) PAHs, while bottom ashes were abundant in the5-and6-ring PAHs species. Thirty-three soil samples were collected from the Luling, Liuer, and Zhangji coal mines, in the Huaibei and Huainan areas, Anhui Province, China, in2007. The sum of16US-EPA PAHs ranged from0.13to3.54μg/g (dry weight basis) with a mean concentration of0.84μg/g. Among the three sampling sites selected around the coal mines, the site at the Luling Coal Mine revealed maximum concentration of PAHs, while minimum concentration was observed at the site at Zhangji Coal Mine. In general, low molecular weight PAHs were predominant. Gob pile and coal preparation plant are the sources of PAHs pollution in surface soils in the vicinity of coal mines. The crops in rice paddies may adsorb some PAHs and reduces the PAHs content in soils from paddyfields. Vertical distribution of PAHs in two soil profiles indicates that PAHs contamination in soil profiles tends to occur high in the surface soils and markedly decreases with soil depth. For all depths, PAHs showed a similar distribution pattern, which is an indicator of a similar origin. Total B[a]P equivalent concentration (B[a]Peq) was found to be maximum at the Luling area, while it was minimum at Liuer zones.
     Organic pollutants in water have been causing serious environmental problems. Photocatalytic degradation of these pollutants using solar energy is an attractive solution to this global problem. We propose to develop a series of highly efficient visible light nano-photocatalyst of niobates and tantalates as well as improving their photo-activity by doping.
     Based on this viewpoint, nitrogen doped KNbO3micro/nanostructures was synthesized. Photocatalytic experiment results showed that1) different morphology and particle size of KNbO3can cause the change of recombination rate of photogenerated chargers and specific surface area, thus have a significant influence on the photocatalytic activity;2) The as prepared N-cube exhibited greatly enhanced activity in the visible-light photocatalytic degradation of varies of organic contaminants and photocatalytic reduction and oxidation of water for H2and O2 generation, which were mainly attributed to the improved surface area and increased optical absorption properties arises from the N2p levels above the O2p levels of the valence band. A mechanism for the photodegradation of organic contaminants by the N-cube photocatalyst under visible light is also proposed. The visible-light-sensitive photocatalyst of Ag1.4K0.6Ta4O11nanoplates was synthesized by a facile molten-salt method. The Ag1.4K0.6Ta4011nanoplates exhibited high photocatalytic activity on photodegradation of PCP and RhB. In addition, the activity of the Ag1.4K0.3Ta4O11nanoplates is improved significantly by the modification with lanthanum ions. The optimal modifying content is lmol%corresponding to the highest photodegradation percentages for photodegradation. On the other hand, the5%La3+modifying content exhibited highest photocatalytic activity for H2evolution. The enhancement of photocatalytic activity after La3+modification is attributed to the formation of nanowires, which further promote charge separation and transfer capability in the La3+modified Ag1.4K0.6Ta4O11nanocomposites.
引文
Abe R., Higashi M., Zou Z.G., Sayama K., Arakawa H.2004, Photocatalytic water splitting ito H2 and O2 over R3Ta07 (R=Y, Yb, Gd, La):effect of crystal structure on photocatalytic activity. The Journal of Physical Chemistry B,108,811-814.
    Abe R., Higashi M, Sayama K., Abe Y., Sugihara H.2006, Photocatalytic activity of R3MO7 and R2Ti207 (R=Y, Gd, La; M=Nb, Ta) for water splitting into H2 and O2. The Journal of Physical Chemistry B,110,2219-2226.
    Achten C., Hofmann T.2010, Environmental impact of native polycyclic aromatic hydrocarbons from hard coals. Grundwasser,15,5-18.
    Adachi M., Murata Y., Takao J., Jiu J., Sakamoto N., Wang F.J.2004, Highly efficient dye-sensitized solar cells with a titania thin-film electrode composed of a network structure of single-crystal-like TiO2 nanowires made by the "oriented attachment mechanism. Journal of the American Chemical Society,126,14943-14949.
    Agarwal T., Khillare P.S., Shridhar V., Ray S.,2009. Pattern, sources and toxic potential of PAHs in the arriculture soils of Delhi, India. Journal of Hazardous Materials,163, 1033-1039.
    Ahrens M.J., Morrisey D.J.2005, Biological effects of unburnt coal in the marine environment. Oceanography and Marine Biology:An Annual Review,43,69-122.
    Akyiiz M., Cabuk H.2010, Gas-particle partitioning and seasonal variation of polycyclic aromatic hydrocarbons in the atmosphere of Zonguldak, Turkey. Science of the Total Environment,408,5550-5558.
    Alivisatos A.P.1996, Semiconductor clusters, nanocrystals, and quantum dots. Science,271, 933-937.
    Arditsoglou A., Petaloti Ch., Terzi E., Sofoniou M., Samara C.2004, Size distribution of trace elements and polycyclic aromatic hydrocarbons in fly ashes generated in Greek lignite-fired power plants. Science of the Total Environment,323,153-167.
    Asahi R., Morikawa T.2007, Nitrogen complex species and its chemical nature in TiO2 for visible-light sensitized photocatalysis. Chemical Physics,339,57-63.
    Baek S.O., Goldstone M.E., Kirk P.W.W., Lester J.N., Pery R.1991, Concentrations of particulate and gaseous polycyclic aromatic hydrocarbons in London air following a reduction in the Lead content of petrol in the United Kingdom. Science of the Total Environment,11,169-199.
    Bakker M.I., Casado B., Koerselman J.W., Tolls J., Kolloffel C.2000, Polycyclic aromatic hydrocarbons in soil and plant samples from the vicinity of an oil refinery. Science of the Total Environment,263,91-100.
    Baran S., Bielinska J.E., Oleszczuk P.2004, Enzymatic activity in an airfield soil polluted with polycyclic aromatic hydrocarbons. Geoderma,118,221-232.
    Baxter J.B., Aydil E.S.2005, Nanowire based dye sensitized solar cells. Applied Physics Letters,86,053114.
    Bodzek D., Luks-Betlej K., Warzecha L.1993, Determination of particle-associated polycyclic aromatic hydrocarbons in ambient air samples from the Upper Silesia region of Poland. Atmospheric Environment Part A-General Topics,27,759-764.
    Boffetta P., Jourenkova N., Gustavsson P.1997, Cancer risk from occupational and environmental exposure to polycyclic aromatic hydrocarbons. Cancer Causes Control,8, 444-472
    Broman D., Naef C., Zeburch Y.1991, Long-term high-and-low volume air sampling of polychlorinated dibenzo-p-dioxins and dibenzofurans and polycyclic aromatic hydrocarbons along a transect from urban to remote areas on the Swedish Baltic coast. Environmental Science & Technology,25,1841-1850.
    Bucheli T.D., Blum F., Desaules A., Gustafsson O.2004, Polycyclic aromatic hydrocarbons, black carbon, and molecular markers in soils of Switzerland. Chemosphere,56, 1061-1076.
    Burda C., Lou Y., Chen X., Samia A.C.S., Stout J., Gole J.L.2003, Enhanced nitrogen doping in TiO2 nanoparticles. Nano Letters,3,1049-1051.
    Cai Q.Y., Mo C.H., Li Y.H., Zeng Q.Y., Katsoyiannis A., Wu Q.T., Ferard J.F.2007, Occurrence and assessment of polycyclic aromatic hydrocarbons in soils from vegetable fields of the Pearl River Delta, South China. Chemosphere,68,159-168.
    Cai Q.Y., Mo C.H., Wu Q.T., Katsoyiannis A., Zeng Q.Y.2008, The status of soil contamination by semivolatile organic chemicals (SVOCs) in China:A review. Science of the Total Environment,389,209-224.
    Callen M.S., de la Cruz M.T., Lopez J.M., Mastral A.M.2011, PAH in airborne particulate matter. Carcinogenic character of PM10 samples and assessment of the energy generation impact. Fuel Processing and Technology,92,176-182.
    Calmano W., Ahlf W., Feorstner U.1996, Sediment quality assessment:chemical and biological approaches. In:Calmano W, Forstner U (eds) Sediments and toxic substances. Springer, Berlin, pp 1-35.
    Carey J.H., Lawrence J., Tosine H.W.1976, Photodechlorination of PCBs in the presence of titanium dioxide in aqueous suspension. Bulletin of Environmental Contamination and Toxicology,16,697-701.
    Carp O., Huisman C.L., Reller A.2004, Photo-induced reactivity of titanium dioxide. Progress in Solid State Chemistry,32,33-177.
    CCME (Canadian council of ministers of the environment). Interim Canadian environmental quality criteria for contaminated sites. Report CCME EPC-CS34,1-20. Canada: Manitoba; 1991.
    Chen B., Xuan X., Zhu L., Wang J., Gao Y., Yang K., Shen X.Y., Lou B.F.2004, Distributions of polycyclic aromatic hydrocarbons in surface waters, sediments and soils of Hangzhou City, China. Water Research,38,3558-3568.
    Chen D., Ye J.H.2009, Selective-synthesis of high-performance single-crystalline Sr2Nb207 nanoribbon and SrNb2O6 nanorod photocatalysts. Chemistry of Materials,21, 2327-2333.
    Chen G.S., Schramm K.W., Klimm C., Xu Y., Zhang Y.Y., Kettrup A.1997, Polycyclic aromatic hydrocarbons in Ya-Er Lake (Hubei, China):sources and distribution. Fresenius Journal of Analytical Chemistry,359,280-284.
    Chen L., Ran Y., Xing B., Mai B., He J., Wei X., Fu J., Sheng G.2005a, Contents and sources of polycyclic aromatic hydrocarbons and organochlorine pesticides in vegetable soils of Guangzhou, China. Chemosphere,60,879-890.
    Chen X., Lou Y., Samia A.C.S., Burda C., Gole J.L.2005, Formation of oxynitride as the photocatalytic enhancing site in nitrogen-doped titania nanocatalysts:comparison to a commercial nanopowder. Advanced Functional Materials,15,41-49.
    Chen Y., Bi X., Mai B., Sheng G., Fu J.2004, Emission characterization of particulate/gaseous phases and size association for PAHs from residential coal combustion. Fuel,83,781-790.
    Chen Y., Wang C, Wang Z.2005b, Residues and source identification of persistent organic pollutants in farmland soils irrigated by effluents from biological treatment plants. Environmental International,31,778-783.
    Chiang T.A., Wu P.F., Ko Y.C.1999, Identification of carcinogens in cooking oil fumes. Environmental Research,81,18-22.
    Cho I.S., Lee S.W., Noh J.H., Kim D.W., Lee D.K., Jung H.S., Kim D.W., Hong K.S.2010, SrNb2O6 naonotubes with enhanced photocatalytic activity. Journal of Material Chemistry,20,3979-3983.
    Chou C.L.1990, Geochemistry of sulfur in coal. In geochemistry of sulfur in fossil fuels; Orr, W. L., White, C. M., Eds.; American Chemical Society (ACS):Washington, D.C., ACS Symposium Series, Vol.429, Chapter 2, pp 30-52.
    Chung K.H., Park D.C.1998, Photocatalytic decomposition of water over cesium-loaded potassium niobate photocatalysts. Journal of molecular catalysis A-Chemical,129, 53-59.
    Chung M.K., Hu R., Cheung K.C., Wong M.H.2007, Pollutants in Hong Kong soils: polycyclic aromatic hydrocarbons. Chemosphere,67,464-473.
    Chu S.G., Liu H., Ma L.L., Xu X.B.2003, Polycyclic aromatic hydrocarbons in soil adjacent to highways in Beijing, People's Republic of China. Bulletin of Environmental Contamination and Toxicology,70,972-977.
    Collins J.F., Brown J.P., Alexeeff G.V., Salmon A.G.1998, Potency equivalency factors for some polycyclic aromatic hydrocarbons and polycyclic aromatic hydrocarbon derivatives. Regulatory Toxicology and Pharmacology,28,45-54.
    Cook J.W., Hewett C.L., Hieger I.1933, The isolation of a cancer-producing hydrocarbon from coal tar. Parts Ⅰ,Ⅱ and Ⅲ. Jouranl of the Chemical Society,24,395-405.
    Council Directive 80/778/EEC of 15 July 1980, Relating to the quality of water intended for human consumption official. J L 229,30 August 1980, pp.0011-0029 (http://www.europa.eu.int.)
    Davies I.W., Harrison R.W., Perry R., Ratnayaka D., Wellings R.A.1976, Municipal incinerator as a source of polynuclear aromatic hydrocarbons in environment, Environmental Science & Technology,10,451-453.
    De La Torre-Roche R.J., Lee W.Y., Campos-Diaz S.I.2009. Soil-borne polycyclic aromatic hydrocarbons in El Paso, Texas:analysis of a potential problem in the United States/Mexico border region. Journal of Hazardous Materials,163,946-958.
    Domen K.2002, Photocatalysis-heterogeneous. In:Horvath IT. Encyclopedia of catalysis. John Wiey & Sons, Inc.
    Domen K., Kudo A., Shinozaki A., Tanaka A., Maruya K.I., Onishi T.1986, Photodecomposition of water and hydrogen evolution from aqueous methanol solution over novel niobate photocatalysts. Journal of the Chemical Society-Chemical Communications,356-357.
    Domen K., Kudo A., Shibata M., Tanaka A., Maruya K., Onishi T.1986, Novel photocatalysts, ion-exchanged K4Nb6O17, with a layer structure. Journal of the Chemical Society Chemical Communication,1706-1707.
    Domen K., Kudo A., Tanaka A., Onishi T.1990, Overall photodecomposition of water on a layered niobate catalyst. Catalysis Today,8,77-84.
    Dong F., Zhao W.R., Wu Z.B., Guo S.2009, Band structure and visible light photocatalytic activity of multi-type nitrogen doped TiO2 nanoparticles prepared by thermal decomposition. Journal of Hazardous Materials,162,763-770.
    Dugenest S., Casabianca H., Grenier-Loustalot M.F.1999, Municipal solid waste incineration bottom ash:physicochemical characterization of organic matter. Analysis,27,75-80.
    Ebina Y., Sakai N., Sasaki T.2005, Photocatalyst of lamellar aggregates of RuOx-loaded perovskite nanosheets for overall water splitting. The Journal of Physical Chemistry B, 109,17212-17216.
    Edwarde N.T.,1983. Polycyclic aromatic hydrocarbons in the terestrial environment review. Journal of Environmental Quality,12,427-443.
    Enell A., Fuhrman F., Lundin L., Warfvinge P., Thelin G.2008, Polycyclic aromatic hydrocarbons in ash:determination of total and leachable concentrations. Environmental Pollution,152,285-292.
    Environment Canada.2003, Canadian Soil Quality Guidelines. Canada:Environment Canada.
    Evans K.M., Gill R.A., Robotham P.W.J.1990, The PAH and organic content of sediment particle size fractions. Water Air and Soil Pollution,51,13-31.
    Fang G.C., Wu Y.S., Chen M.H., Ho T.T., Huang S.H., Rau J.Y.2004a, Polycyclic aromatic hydrocarbons study in Taichung, Taiwan, during 2002-2003. Atmospheric Environment, 38,3385-3391.
    Fang G.C., Chang K.F., Lu C., Bai H.2004b, Estimation of PAHs dry deposition and BaP toxic equivalency factors (TEFs) study at urban, industry park and rural sampling sites in central Taiwan, Taichung. Chemosphere,55,787-796.
    Fang G.C., Wu Y.S., Fu P.C., Yang I.L., Chen M.H.2004c, Polycyclic aromatic hydrocarbons in the ambient air of suburban and industrial regions of central Taiwan. Chemosphere,54, 443-452.
    Fujishima A., Honda K.1972, Electrochemical photolysis of water at a semiconductor electrode. Nature,238,37-38.
    Fujishuma A., Rao T.N., Tryk D.A.2000, Titanium doxide photocatalysis. Journal of Photochemistry and Photobiology C,1,1-21.
    Given P.H.1987, The mobile phase in coals:its nature and modes of release. Final Report-Part 2 Prepared for the US Department of Energy.
    Haenel M.W.1992, Recent progress in coal structure research. Fuel,71,1211-1223.
    Hao R., Wan H.F., Song Y.T., Jiang H., Peng S.L.2007, Polycyclic aromatic hydrocarbons in agricultural soils of the southern subtropics, China. Pedosphere,17,673-680.
    Hayatsu R., Winans R.E., Scott R.G., Moore L.P., Studies M.H.1978, Trapped organic compounds and aromatic units in coals. Fuel,57,541-548.
    Herrmann J.M.1999, Heterogeneous photocatalysis:fundamentals and applications to the removal of various types of aqueous pollutants. Catalysis Today,53,115-129.
    Hoffmann M.R., Martin S.T., Choi W., Bahenemann D.W.1995, Environmental applications of semiconductor photocatalysis. Chemical Reviews,95,69-96.
    Hosteller F.D., Pereira W.E., Kvenvolden K.A.1999, A record of hydrocarbon input to San Francisco Bay as traced by biomarker profiles in surface sediment and sediment cores. Marine Chemistry,64,115-127.
    Howsam M., Jones K.C., Ineson P.2000, PAHs associated with the leaves of three deciduous tree species. I:concentrations and profiles. Environmental Pollution,108,413-424.
    Howsam M., Jones K.C., Ineson P.2001, PAHs associated with the leaves of three deciduous tree species. II:uptake during a growing season. Chemosphere,44,155-164.
    Ikeda S., Fubuki M., Takahara Y.K., Matsumura M.2006, Photocatalytic activity of hydrothermally synthesized tantalate pyrochlores for overall water splitting. Applied Catalysis A,300,186-190.
    Ikeda S., Tanaka A., Shinohara K., Hara M., Kondo J.N., Maruya K., Domen K.1997, Effect of the particle size for photocatalytic decomposition of water on Ni-loaded K4Nb6O17. Microporous and Mesoporous Materials,9,1063-1064.
    Ishihara T., Nishiguchi H., Fukamachi K., Takita Y.1999, Effects of acceptor doping to KTaO3 on photocatalytic decomposition of pure H2O. The Journal of Physical Chemistry B,103,1-3.
    Ishihara T., Baik N.S., Ono N., Nishiguchi H., Takita Y.2004, Effects of crystal structure on photolysis of H2O on K-Ta mixed oxide. Journal of Photochemistry and Photobiology A: Chemistry,167,149-157.
    Iwase A., Kato H., Kudo A.2006, Nanosized Au particles as an efficient cocatalyst for photocatalytic overall water splitting. Catalysis Letters,108,7-10.
    Iwase A., Kato H., Okutomi H., Kudo A.2004, Formation of surface nano-step structures and improvement of photocatalytic activities of NaTaO3 by doping of alkaline earth metal ions. Chemistry Letters,33,1260-1261.
    Johansson I., Bavel B.V.2003a, Levels and patterns of polycyclic aromatic hydrocarbons in incineration ashes. Science of the Total Environment,311,221-331.
    Johansson I., Bavel B.V.2003b, Polycyclic aromatic hydrocarbons in weathered bottom ash from incineration of municipal solid waste. Chemosphere,53,123-128.
    Kakareka S.V., Kukharchyk T.I.2003. PAH emission from the open burning of agricultural debris. Science of the Total Environment,308,257-261.
    Kato H., Kudo A.1998, New tantalate photocatalysts for water decomposition into H2 and O2. Chemical Physics Letters,295,487-492.
    Kato H., Kudo A.2001, Water splitting into H2 and O2 on alkali tantalate photocatalysts ATaO3 (A=Li, Na, and K). The Journal of Physical Chemistry B,105,4285-4292.
    Kato H., Kobayashi H., Kudo A.2002, Role of Ag+ions for band structures and photocatalytic properties of AgMO3 (M:Ta and Nb) with the perovskite structure. The Journal of Physical Chemistry B,106,12441-12447.
    Kato H., Kudo A.2001, Energy structure and photocatalytic activity for water splitting of Sr2(Ta1-xNbx)2O7 solid solution. Journal of Photochemistry and Photobiology A: Chemistry,145,129-133.
    Kato H., Asakura K., Kudo A.2003, Highly efficient water splitting into H2 and O2 over lanthanum-doped NaTaO3 photocatalysts with high crystallinity and surface nano-structure. Journal of the American Chemical Society,125,3082-3089.
    Kato H., Kudo A.1999, Photocatalytic decomposition of pure water into H2 and O2 over SrTa2O6. Chemistry Letters,28,1207-1208.
    Katsoyiannis A., Terzi E., Cai Q.Y.2007, On the use of PAH molecular diagnostic ratios in sewage sludge for the understanding of the PAH sources. Is this use appropriate? Chemosphere,69,1337-1339.
    Kennaway E.L.,1930, Further experiments on cancer-producing substances. Biochemistry Journal,24,497-504.
    Khan S.U.M., Mofareh A.S., William B.I.J.2002, Efficient photochemical water splitting by a chemically modified n-TiO2. Science,297,2243-2245.
    Kim H.G., Hwang D.W., Kim J., Kim Y.G., Lee J.S.1999, Highly donor-doped (110) layered perovskite materials as novel photocatalysts for overall water splitting. Chemical Communications,1077-1078.
    Kostas K., Kostas M.2006, Soil risk assessment of As and Zn contamination in a coal mining region using geostatistics. Science of the Total Environment,371,190-196.
    Kottler B.D., Alexander M.2001, Relationship of properties of polycyclic aromatic hydrocarbons to sequestration in soil. Environmental Pollution,113,293-298.
    Krauss M., Wilcke W., Zech W.2000, Polycyclic aromatic hydrocarbons and polychlorinated biphenyls in forest soils:depth distribution as indicator of different fate. Environmental Pollution,110,79-88.
    Krauss M., Wilcke W.2003, Polychlorinated naphthalenes in urban soils:analysis, concentrations, and relation to other persistent organic pollutants. Environmental Pollution,122,75-89.
    Kruge M.A.2000, Determination of thermal maturity and organic matter type by principal components analysis of the distributions of polycyclic aromatic compounds. International Journal of Coal Geology,43,27-51.
    Kudo A.2003, Photocatalyst materials for water splitting. Catalysis Surveys from Asia,7, 31-38.
    Kudo A., Okutomi H., Kato H.2000, Photocatalytic water splitting into H2 and O2 over K2LnTa5O15 powder. Chemistry Letters,29,1212-1213.
    Kudo A., Kato H.1997, Photocatalytic decomposition of water into H2 and O2 over novel photocatalyst K3Ta3Si2O13 with pollared structure consisting of three TaO6 chains. Chemistry Letters,26,867-868.
    Kudo A., Tanaka A., Domen K., Maruya K., Aika K., Onishi T.1988, Photocatalystic decomposition of water over NiO-K4Nb6O17 catalyst. Journal of Catalysis,111,67-76.
    Kudo A., Sayama K., Tanaka A., Asakura K., Domen K., Maruya K., Onishi T.1989, Nickel-loaded K4Nb6O17 photocatalyst for the decomposition of H2O and O2 into H2 and O2:structure and reaction mechanism. Journal of Catalysis,120,337-352.
    Kudo A., Kato H.2000, Effect of lanthanide-doping into NaTaO3 photocatalysts for efficient water splitting. Chemical Physics Letters,331,373-377.
    Kudo A., Kato H., Nakagawa S.2000, Water splitting into H2 and O2 on new Sr2M2O7 (M= Nb and Ta) photocatalysts with layered perovskite structure-factors affecting the photocatalytic activity. The Journal of Physical Chemistry B,104,571-575.
    Kudo A., Nakagawa S., Kato H.1999, Overall water splitting into H2 and O2 under UV irradiation on NiO-loaded ZnNb2O6 consisting of d10 and d0 ions. Chemistry Letters,28, 1197-1198.
    Kuo C.Y., Cheng Y.W., Chen Y.W., Lee H.1998, Correlation between the amounts of polycyclic aromatic hydrocarbons and mutagenicity of airborne particulate samples from Taichung City, Taiwan. Environmental Research,78,43-49.
    Kurihara T., Okutomi H., Miseki Y., Kato H., Kudo A.2006, Highly efficient water splitting over K3Ta3B2O12 photocatalyst without loading cocatalysts. Chemistry Letters,35, 274-275.
    Kondo J.N., Uchida M., Nakajima K., Daling L., Hara M., Domen K.2004, Synthesis, mesostructure, and photocatalysis of a highly ordered and thermally stable mesoporous Mg and Ta mixed oxide. Chemistry of Materials,16,4304-4310.
    Kruge M.A.2000, Determination of thermal maturity and organic matter type by principal components analysis of the distributions of polycyclic aromatic compounds. International Journal of Coal Geology,43,27-51.
    Kruge M.A., Bensley D.F.1994, Flash pyrolysis-gas chromatography/mass spectrometry of Lower Kittanning vitrinites:changes in the distributions of polyaromatic hydrocarbons as a function of coal rank. In:Mukhophadyay PK, Dow WG, editors. Vitrinite reflectance as a maturity parameter:applications and limitations. American Chemical Society Symposium Series; p.136-148.
    Kudo A., Miseki Y.2009, Heterogeneous photocatalyst materials for water splitting. Chemical Society Reviews,38,253-278.
    Laumann S., Micic V., Kruge M.A., Achten C., Sachsenhofer R.F., Schwarzbauer J., Hofmann T.2011, Variations in concentrations and compositions of polycyclic aromatic hydrocarbons (PAHs) in coals related to the coal rank and origin. Environmental Pollution,159,2690-2697.
    Lee W.M., Yen S.Y., Chen J.C.1993, The relation between polycyclic aromatic hydrocarbons and organic carbon in fly ash from a municipal incinerator. Journal of Environmental Science and Health, Part A-Toxic/Hazardous Substances & Environmental Engineering, 28,1495-1506.
    Levendis Y.A., Atal A., Carlson J.B.2001, PAH and soot emissions from burning components of medical waste:examination/surgical gloves and cotton pads. Chemosphere,42,775-783.
    Li F.B., Li X.Z., Hou M.F.2004, The photocatalytic degradation of 2-mercaptobenzothiazole in aqueous La3+TiO2 suspension for odour control. Applied catalysis B-Environmental, 48,185-194.
    Li K., Christensen E.R., van Camp R.P., Imamoglu I.2001, PAHs in dated sediments of ashtabula river, Ohio, USA. Environmental Science & Technology,35,2896-2902.
    Li Y., Chen G., Zhou C., Li Z.2008, Photocatalytic water splitting over a protonated layered perovskite tantalate H1.81Sr0.81Bi0.19Ta2O7. Catalysis Letters,123,80-83.
    Liu K.L., Han W.J., Pan W.P., Riley J.T.2001, Polycyclic aromatic hydrocarbon (PAH) emissions from a coal-fired pilot FBC system. Journal of Hazardous Materials,84, 175-188.
    Liu G.J., Niu Z.Y., Niekerk D.V., Xue J., Zheng L.G. Polycyclic aromatic hydrocarbons (PAHs) from coal combustion:emissions, analysis, and toxicology. Reviews of Environmental Contamination and Toxicology,2008,192,1-28.
    Liu Y.J., Zhu L.Z., Shen X.Y.2001, Polycyclic aromatic hydrocarbons (PAHs) in indoor and outdoor air of Hangzhou, China. Environmental Science & Technology,35,840-844.
    Machida M., Yabunaka J., Kijima T.1999, Efficient photocatalytic decomposition of water with the novel layered tantalate RbNdTa2O7. Chemical Communications,1939-1940.
    Machida M., Yabunaka J., Kijima T.2000, Synthesis and photocatalytic property of layered perovskite tantalates, RbLnTa2O7 (Ln=La, Pr, Nd, and Sm). Chemistry of Materials,12, 812-817.
    Machida M., Miyazaki K., Matsushita S., Arai M.2003, Photocatalytic properties of layered perovskite tantalates, MlnTa2O7 (M=Cs, Rb, Na, and H; Ln=La, Pr, Nd, and Sm). Journal of Materials Chemistry,13,1433-1437.
    Maliszewska-Kordybach B.1996, Polycyclic aromatic hydrocarbons in agricultural soils in Poland:preliminary proposals for criteria to evaluate the level of soil contamination. Applied Geochemistry,11,121-127.
    Ma L.L., Chu S.G., Xu X.B.2003, Organic contamination in the greenhouse soils from Beijing suburbs, China. Journal of Environmental Monitoring,5,786-790.
    Ma L.L., Chu S.G., Wang X.T., Cheng H.X., Liu X.F., Xu X.B.2005, Polycyclic aromatic hydrocarbons in the surface soils from outskirts of Beijing, China. Chemosphere,58, 1355-1363.
    Maeda K., Domen K.2007, New non-oxide photocatalysts designed for overall water splitting under visible light. Journal of Physical Chemistry C,111,7851-7861.
    Manoli E., Samara C.1999, Polycyclic aromatic hydrocarbons in natural waters:sources, occurrence and analysis. Trends in Analytical Chemistry,18,717-428.
    Masclet P., Bresson M.A., Mouvier G.1987, Polycyclic aromatic hydrocarbons emitted by power stations, and influence of combustion conditions. Fuel,66,556-562.
    Maskaoui K., Hu Z., Zhou J.L., Han Y.L.2006, Levels of polycyclic aromatic hydrocarbons in some agricultural, industrial and urban areas along Xiamen coastal waters, China. Journal of Environmental Science,18,318-322.
    Massachusetts Institute of Technology. The future of coal-an interdisciplinary MIT study; 2007. free access at http://web.mit.edu/coal/.
    Mastral A.M., Callen M.S.,2000, A review on polycyclic aromatic hydrocarbon (PAH) emissions from energy generation. Environmental Science & Technology,34, 3051-3056.
    Mastral A.M., Callen M.S., Garcia T.1999, Polycyclic aromatic hydrocarbons and Oorganic matter associated to particulate matter emitted from AFBC combustion. Environmental Science & Technology,33,3177-3184.
    Mastral A.M., Callen M.S., Murillo R.1996, Assessment of PAHs emissions as a function of coal combustion variables. Fuel,13,1533-1536.
    Menzie C.A., Potocki B.B., Santodonato J.1992, Exposure to carcinogenic PAHs in the environment. Environmental Science & Technology,26,1278-1284.
    Mielke H.W., Wang G.D., Gonzales C.R., Le B., Quach V.N., Mielke P.W.2001, PAH and metal mixtures in New Orleans soils and sediments. Science of the Total Environment, 281,217-227.
    Miseki Y., Kato H., Kudo A.2006, Water splitting into H2 and O2 over Ba5Nb4O15 photocatalysts with layered perovskite structure prepared by polymerizable complex method. Chemistry Letters,35,1052-1053.
    Miseki Y., Kato H., Kudo A.2005, Water splitting into H2 and O2 over Cs2Nb4O11 photocatalyst. Chemistry Letters,34,54-55.
    Mitsui C, Nishiguchi H., Fukamachi K., Ishihara T., Takita Y.1999, Photocatalytic decomposition of pure water over NiO supported on Kta(M)O3 (M=Ti4+, Hf4+, Zr4+) perovskite oxide. Chemistry Letters,28,1327-1328.
    Mitsuyama T., Tsutsui A., Hara T., Ikeue K., Machida M.2008, Enhanced photocatalytic water splitting of hydrous LiCa2Ta3O10 prepared by hydrothermal treatment. Bulletin of the Chemical Society Japan,81,401-406.
    Moret S., Conte L.S.2000, Polycyclic aromatic hydrocarbons in edible fats and oils: occurrence and analytical methods. Journal of Chromatography A,882,245-253.
    Miiller J.F., Hawker D.W., Connel D.W.1998, Polycyclic aromatic hydrocarbons in the atmospheric environment of Brisbane, Australia. Chemosphere,37,1369-1383.
    Nagaveni K., Hegde M.S., Ravishankar N., Subbanna G.N., Madras G.2004, Synthesis and structure of nanocrystalline TiO2 with lower band gap Showing high photocatalytic activity. Langmuir,20,2900-2907.
    Nam J.J., Song B.H., Eom K.C., Lee S.H., Smith A.2003, Distribution of PAHs in agricultural soils in South Korea. Chemosphere,50,1281-1289.
    Nisbet C., Lagoy P.1992, Toxic equivalency factors (TEFs) for polycyclic aromatic hydrocarbons (PAHs). Regulatory Toxicology and Pharmacology,16,290-300.
    OEHHA (The office of environmental health hazard assessment),2001, Prioritization of toxic air contaminant-children's environmental health protection act,30.
    Opuene K., Agbozu I.E., Adegboro O.O.2009, A critical appraisal of PAH indices as indicators of PAH source and composition in Elelenwo Creek, southern Nigeria. Environmentalist,29,47-55.
    Otsuka H., Kim K., Kouzu A., Takimoto I., Fujimori H., Sakata Y., Imamura H., Matsumoto T., Toda K.2005, Photocatalytic performance of Ba5Ta4O15 to decomposition of H2O into H2 and O2. Chemistry Letters,34,822-823.
    Palo C.D., Stefanis P.D., Massa M., Montani R.1996, Emission of polycyclic aromatic hydrocarbons (PAH) from solid waste incinerator equipped with an after-combustion chamber. Polycyclic Aromatic Compounds,9,45-51.
    Papp J., Soled S., Dwight K.,1994. Surface acidity and photocatalytic activity of TiO2, WO3/TiO2, and MoO3/TiO2 photocatalysts. Chemistry of Materials,6,496-500.
    Park S.S., Kim Y.J., Kang C.H.2002, Atmospheric polycyclic aromatic hydrocarbons in Seoul, Korea. Atmospheric Environment,36,2917-2924.
    Pies C., Hoffmann B., Petrowsky J., Yang Y., Ternes T.A., Hofmann T.2008. Characterization and source identification of polycyclic aromatic hydrocarbons (PAHs) in river bank soils. Chemosphere,72,1594-1601.
    Ping L.F., Luo Y.M., Zhang H.B., Li Q.B., Wu L.H.2006, Distribution of polycyclic aromatic hydrocarbons in thirty typical soil profiles in the Yangtze river delta region, east China. Environmental Pollution,147,358-365.
    Puttmann W., Villar H.1987, Occurrence and geochemical significance of 1,2,5,6-tetramethylnaphthalene. Geochimica et Cosmochimca Acta,51,3023-3029.
    Puttmann W.1988, Analysis of polycyclic aromatic hydrocarbons in solid sample material using a desorption device coupled to a GC/MS system. Chromatography,26,171-177.
    Qiu X.F., Burda C.2007, Chemically synthesized nitrogen-doped metal oxide nanoparticles. Chemical Physics,339,1-10.
    Radke M., Welte D.H., Willsch H. Geochemical study on a well in the western Canada basin: relation of the aromatic distribution pattern to maturity of organic matter. Geochimica et Cosmochimica Acta,1982a,46,1-10.
    Radke M., Welte D.H.1981, The Methylphenanthrene Index (MPI):a maturity parameter based on aromatic hydrocarbons. Advances in Organic Geochemistry,504-512.
    Radke M., Willsch H., Leythaeuser D.1982, Aromatic compounds of coal:relation of distribution pattern to rank. Geochimica et Cosmochimica Acta,46,1831-1848.
    Radke M., Willsch H., Teichmuller M.1990, Generation and distribution of aromatic hydrocarbons in coals of low rank. Organic Geochemistry,15,539-563.
    Ravindra K., Bencs L., Wauters E., de Hoog J., Deutsch F., Roekens E., Bleux N., Bergmans P., Van Grieken R.2006, Seasonal and site-specific variation in vapor and aerosol phase PAHs over Flanders (Belgium) and their relation with anthropogenic activities. Atmospheric Environment,40,771-785.
    Ravindra K., Sokhi R., Van Grieken R.2008a. Atmospheric polycyclic aromatic hydrocarbons:source attribution, emission factors and regulation. Atmospheric Environment,42,2895-2921.
    Ravindra K., Wauters E., Van Grieken R.2008b. Variation in particulate PAHs levels and their relation with the transboundary movement of the air masses. Science of the Total Environment,396,100-110.
    Ray S., Khillare P.S., Agarwal T., Shridhar V.2008, Assessment of PAHs in soil around the international airport in delhi, India. Journal of Hazardous Materials,156,9-16.
    Reddy B.M., Sreekanth P.M., Reddy E.P., Yamada Y., Xu Q., Sakurai H., Kobayashi T.2002, Surface characterization of La2O3-TiO2 and V2O5/La2O3-TiO2 catalysts. Journal of Physical Chemistry B,106,5695-5700.
    Ribeiro J., Silver T., Filho J.G.M., Flores D.2012, Polycyclic aromatic hydrocarbons (PAHs) in burning and non-burning coal waste piles. Journal of Hazardous Materials,199-200, 105-110.
    Rockafellow E.M., Haywood J.M., Witte T., Houk R.S., Jenks W.S.2010, Selenium-modified TiO2 and its impact on photocatalysis. Langmuir.26,19052-19059.
    Rockens E., Dumollin J., Matheeussen C.2000, PM10 dust and chemical characterisation of aerosols in Flanders, Belgium. Advanced Air Pollution,8,699-707.
    Rose N.L., Rippey B.2002, The historical record of PAH, PCB, trace metal and fly ash particle deposition at a remote lake in northwest Scotland. Environmental Pollution,117, 121-132.
    Sahu S.K., Bhangare R.C., Ajmal P.Y., Sharma S., Pandit G.G., Puranik V.D.2009, Characterization and quantification of persistent organic pollutants in fly ash from coal fueled thermal power stations in India. Microchemical Journal,92,92-96.
    Salomons W.1995, Long-term strategies for handling contaminated sites and large-scale areas. In:Salomons W, Stigliani W (eds) Biogeodynamics of pollutants in soils and sediments. Springer, Berlin, pp 1-30
    Sayama K., Yase K., Arakawa H., Asakura K., Tanaka A., Domen K., Onishi T.1998, Photocatalytci activity and reaction mechanism of Pt-intercalated K4Nb6O17 catalyst on the water splitting in carbonate salt aqueous solution. Journal of Photochemistry and Photobiology A:Chemistry,114,125-135.
    Sayama K., Arakawa H., Domen K.1996, Photocatalytic water splitting on nickel intercalated A4TaxNb6-xO17 (A=K, Rb). Catalysis Today,28,175-182.
    Sayama K., Tanaka A., Domen K., Maruya K., Onishi T.1991, Photocatalytic decomposition of water over plantinum-intercalated K4Nb6O17. Physical Inorganic chemistry,95, 1345-1348.
    Sayama K., Tanaka A., Domen K., Maruya K., Onishi T.1990, Improvement of nickel-loaded K4Nb6O17 photocatalyst for the decomposition of H2O. Catalysis Letters,4,217-222.
    Sayama K., Arakawa H.1994, Effect of Na2CO3 addition on photocatalytic decomposition of liquid water over various semiconductor catalysts. Journal of Photochemistry and Photobiology A,77,243-247.
    Shen C.F., Tang X.J., Yao J., Shi D.Z., Fang J., Khan M.I., Cheema S.A., Chen Y.X.2010, Levels and patterns of polycyclic aromatic hydrocarbons and polychlorinated biphenyls in municipal waste incinerator bottom ash in Zhejiang province, China. Journal of Hazardous Materials,179,197-202.
    Shimizu K.I., Tsuji Y., Hatamachi T., Toda K., Kodama T., Sato M., Kitayama Y.2004, Photocatalytic water splitting on hydrated layered perovskite tantalate A2SrTa2O7-nH2O (A=H,K, and Rb). Physical Chemistry Chemical Physics.6,1064-1069.
    Shimizu K., Itoh S., Hatamachi T., Kodama T., Sato M., Toda K.2005, Photocatalytic water splitting on Ni-intercalated ruddlesden-popper tantalate H2La2/3Ta2O7. Chemistry of Materials,17,5161-5166.
    Skrbic B., Miljevic N.2002, An evaluation of residues at an oil refinery site following fires. Journal of Environmental Science and Health, Part A,37,1029-1039.
    Song Y.F., Wilke B.M., Song X.Y., Gong P., Zhou Q.X., Yang G.F.2006, Polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs) and heavy metals (HMs) as well as their genotoxicity in soil after long-term wastewater irrigation. Chemosphere,65,1859-1868.
    Spiker E.C., Pierce B.S., Bates A.L., Stanton R.W.1994, Isotopic evidence for the source of sulfur in the upper freeport coal bed (west-central Pennsylvania, USA). Chemical Geology,114,115-130.
    Stach E., Mackowsky M.T.H., Teichmuller M.1982, Stach's textbook of coal petrology.3rd ed. Stuttgart, Germany:Borntraeger.
    Stalikas C.D., Chaidou C.I., Pilidis G.A.1997, Enrichment of PAHs and heavy metals in soils in the vicinity of the lignite-fired power plants of West Macedonia. Science of the Total Environment,204,135-146.
    Stolyhwo A., SikorSki Z.E.2005, Polycyclic aromatic hydrocarbons in smoked fish-a critical review. Food Chemistry,91,303-311.
    Stout S.A., Emsbo-Mattingly S., Uhler A.D., McCarthy K.2002a, Environmental forensics particulate coal in soils and sediments-recognition and potential influences on hydrocarbon fingerprinting and concentration. AEHS Magazine-Soil Sediment & Water (Environmental Forensics) June; p.12-5.
    Stout S.A., Uhler A.D., McCarthy K.J., Mattingly S.E.2002b, Chemical fingerprinting of hydrocarbons. In:Murphy BL, Morrison RD, editors. Introduction to environmental forensics. Amsterdam, Netherlands:Elsevier Academic Press; p.137-260.
    Stout S.A., Emsbo-Mattingly S.D.2008, Concentration and character of PAHs and other hydrocarbons in coals of varying rank-implications for environmental studies of soils and sediments containing particulate coal. Organic Geochemistry,39,801-819.
    Sun P., Weavers L.K., Taerakul P., Walker H.W.2006, Characterization of polycyclic aromatic hydrocarbons (PAHs) on lime spray dryer (LSD) ash using different extraction methods. Chemophere,62,265-274.
    Takahara Y., Kondo J.N., Takata T., Lu D., Domen K.2001, Mesoporous tantalum oxide,1. characterization and photocatalytic activity for the overall water decomposition. Chemistry of Materials,13,1194-1199.
    Tan B., Wu Y.2006, Dye-sensitized solar cells based on anatase TiO2 nanoparticle/nanowire composites. The Journal of Physical Chemistry B,110,15932-15938.
    Tang D., Fermont W.J., Zhigui R., Puttmann W., Yang Q.1991, Extraction yields and GC/MS characteristics of extracts from high rank coals and anthracites. Proceedings of the International Conference on Coal Science,16-20 September. U.K.:University of Newcastle-upon-Tyne.
    Tang X.Y., Tang L., Zhu Y., Xing B., Duan J., Zheng M.2006, Assessment of the bioaccessibility of polycyclic aromatic hydrocarbons in soils from Beijing using an in vitro test. Environmental Pollution,140,279-85.
    Tao S., Cui Y.H., Xu F.L., Li B.G., Cao J., Liu W.X., Schmitt G., Wang X.J., Shen W.R., Qing B.P., Sun R.2004, Polycyclic aromatic hydrocarbons (PAHs) in agricultural soil and vegetables from Tianjin. Science of the Total Environment,320,11-24.
    Taylor G.H., Teichmuller M., Davis A.C.F.K., Littke R., Robert P.1998, Organic Petrology. Gebruder Borntraeger, Berlin-Stuttgart.
    Thielemann T., Schmidt S., Gerling C.2007, Lignite and hard coal:energy suppliers for world needs until the year 2100-an outlook. International Journal of Coal Geology,72,1-14.
    Trapido M.1999, Polycyclic aromatic hydrocarbons in estonian soil:contamination and profiles. Environmental Pollution,105,67-74.
    US EPA, Environmental Criteria and Assessment Office.1984, EPA 549/1-86-013 Health effects assessments for polycyclic aromatic hydrocarbons (PAHs) [S]. Cincinnati:US Environmental Protection Agency.
    U.S. Environmental Protection Agency Technology transfer network 1999 national-scale air toxics assessment. http://www.epa.gov/ttn/atw/natal999/(May,2007).
    Valerie S., Clare M.M.S., Aoife D.,2003, Microwave digestion of sediment, soils and urban particulate matter for trace metal analysis. Talanta,60,715-723.
    Vane C.H., Harrison I., Kim A.W.2007, Polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) in sediments from the Mersey Estuary, U.K. Science of the Total Environment,374,112-126.
    Van Kooten G.K., Short J.W., Kolak J.J.2002, Low-maturity Kulthieth Formation coal:a possible source of polycyclic aromatic hydrocarbons in benthic sediment of the northern gulf of Alaska. Environmental Forensics,3,227-341.
    Vidal A., Diaz A.I., Hraiki A.E.I., Romero M., Muguruza I., Senhaji F., Gonzalez J.1999, Solar photocatalysis for detoxification and disinfection of contaminated water:pilot plant studies. Catalysis Today,54,283-290.
    Viguli J., Verde J., Irabien A.2002, Environmental assessment of polycyclic aromatic hydrocarbons (PAHs) in surface sediments of the Santander Bay, Northern Spain. Chemosphere,48,157-165.
    Wania F., Haugen J.E., Lei Y.D., Mackay D.1998, Temperature dependence of atmospheric concentrations of semivolatile organic compounds. Environmental Science & Technology,32,1013-1021
    Wang G.Z., Selbach S.M., Yu Y.D., Zhang X.T., Grande T., Einarsrud M.A.2009a, Hydrothermal synthesis and characterization of KNbO3 nanorods. CrstEngCommunity, 11,1958-1963.
    Wang J., Tafen D.N., Lewis J.P., Hong Z.L., Manivannan A., Zhi M.J., Li M., Wu N.Q.2009b, Origin of photocatalytic activity of nitrogen-doped TiO2 nanobelts. Journal of the American Chemical Society,131,12290-12297.
    Wang P., Huang B., Qin X., Zhang X., Dai Y., Whangbo M.2009, Ag/AgBr/WO3-H2O: visible-light photocatalysts for bacteria destruction. Inorganic Chemistry,48, 10697-10702.
    Wang P., Huang B., Lou Z., Zhang X., Qin X., Dai Y., Zheng Z., Wang X.2010, Synthesis of highly efficient Ag@AgCl plasmonic photocatalysts with various structures. Chemistry-A European Journal,16,538-544.
    Wang P., Huang B., Zhang Q., Zhang X., Qin X., Dai Y., Zhan J., Yu J., Liu H., Lou Z.2010, Highly efficient visible light plasmonic photocatalyst Ag@Ag (Br,I). Chemistry-A European Journal,16,10042-10047.
    Wang R., Hashimoto K., Fujishima A., Chikuni M., Kojima E., Kitamura A., Shimohigoshi M., Watanabe T.1997, Light-induced amphiphilic surfaces. Nature,388,431-432.
    Wang R.W., Liu G.J., Chou C.L., Liu J.J., Zhang J.M.2010, Environmental assessment of PAHs in soils around the Anhui coal district, China. Archives of Environmental Contamination and Toxicology,59,62-70.
    Wang R.W., Liu G.J., Zhang J.M., Chou C.L., Liu J.J.2010, Abundances of polycyclic aromatic hydrocarbons (PAHs) in 14 chinese and american coals and their relation to coal rank and weathering. Energy Fuels,24,6061-6066.
    Wang X.J., Zheng Y., Liu R.M., Li B.G., Cao J., Tao S.2003, Medium scale spatial structures of polycyclic aromatic hydrocarbons in the topsoil of Tianjin area. Journal of Environmental Science and Health, Part B,38,327-335.
    Wang X.L., Tao S., Dawson R.W., Xu F.L.2002, Characterizing and comparing risks of polycyclic aromatic hydrocarbons in a Tianjin wastewater-irrigated area. Environmental Research,90,201-206.
    Wang Z., Chen J., Yang P., Qiao X., Tian F.2007, Polycyclic aromatic hydrocarbons in Dalian soils:distribution and toxicity assessment. Jouranl of Environmental Monitoring, 9,199-204.
    Weiss P., Riss A., Gschmeidler E., Schentz H.1994, Investigation of heavy metal, PAH, PCB patterns and PCDD/F profiles of soil samples from an industrialized urban area (Linz, Upper Austria) with multivariate statistical methods. Chemosphere,29,2223-2236.
    White C.M., Lee M.L.1980, Identification and geochemical significance of some aromatic components of coal. Geochimica et Cosmochimica Acta,44,1825-1832.
    Wheatley A.D., Sadhra S.2004, Polycyclic aromatic hydrocarbons in solid residues from waste incineration. Chemosphere,55,743-749.
    Wilcke W.2000, Polycyclic aromatic hydrocarbons (PAHs) in soil-a review. Journal of Soil Science and Plant Nutrition,163,229-248.
    Willett K.L., Gardinali P.R., SericanoJ.L., Wade T.L., Safe S.H.1997, Characterization of the H4IIE rat hepatoma cell bioassay for evalution of environmental samples containing polynuclear aromatic hydrocarbons (PAHs). Achieves of Environmental Contamination and Toxicology,32,442-448.
    Willsch H., Radke M.1995, Distribution of polycyclic aromatic compounds in coals of high rank. Polycyclic Aromatic Compounds,7,231-251.
    World Coal Institute.2004; 2007, Top ten hard coal producinig countries worldwide. http://www.worldcoal.org.
    Wu N.Q., Zhao M., Zheng J.G., Jiang C., Myers B., Chyu M., Li S., Mao S.X.2005, Porous CuO-ZnO nanocomposites for sensing electrode of high-temperature CO solid-state electrochemical sensor. Nanotechnology,16,2878-2881.
    Wu T.X., Liu G.M., Zhao J.C.1998, Photoassisted Degradation of Dye Pollutants. V. Self-photosensitized oxidative transformation of rhodamine B under visible light irradiation in aqueous TiO2 dispersition. Journal of Physical Chemistry B,102, 5845-5851.
    Xu X.C., Chen C.H., Qi H.Y., He R., You C.F., Xiang G.M.2000, Development of coal combustion pollution control for SO2 and Nox in China. Fuel Processing Technology,62, 153-160.
    Xue J., Liu G.J., Niu Z.Y., Chou C.L., Qi C.C., Zheng L.G., Zhang H.Y.2007, Factors that influence the extraction of polycyclic aromatic hydrocarbons from coal. Energy Fuels, 21,881-890.
    Xu S., Liu W., Tao S.2006, Emission of polycyclic aromatic hydrocarbons in China. Environmental Science & Technology,40,702-708.
    Yamashita N., Kannan K., Imagawa T., Villeneuve D.L., Hashimoto S., Miyazaki A., Giesy J.P.2000, Vertical profile of polychlorinated dibenzo-p-dioxins, dibenzofurans, naphthalenes, biphenyls, polycyclic aromatic hydrocarbons, and alkyphenols in a sediment core from Tokyo Bay, Japan. Environmental Science & Technology,34, 3560-3567.
    Yan J.H., You X.F., Li X.D., Ni M.J., Yin X.F., Cen K.F.2004, Performance of PAHs emission from bituminous coal combustion. Journal of Zhejiang University SCIENCE,5, 1554-1564.
    Yan B., Abrajano T.A., Bopp R.F., Chaky D.A., Benedict L.A., Chillrud S.N.2005. Molecular tracers of saturated and polycyclic aromatic hydrocarbon inputs into central park lake, New York city. Environmental Science & Technology,39,7012-7019.
    Yang G., Zhang T., Guo Z., Wan H., Luo W., Gao Y.2007, The source and distribution characteristics of polycycclic aromatic hydrocarbons in agricultural soils in the Pearl River Delta. Environmental Science,28,60-67.
    Yang H.H, Lai S.O, Hsieh L.T, Hsueh H.J, Chi T.W.2002, Profiles of PAH emission from steel and iron industries. Chemosphere.48,1061-1074.
    Yao W., Ye J.2007, Photocatalytic properties of a new photocatalyst K2Sr1.5Ta3O10.Chemical Physics Letters,435,96-99.
    Yoshino M., Kakihana M., Cho W.S., Kato H., Kudo A.2002, Polymerizable complex synthesis of pure Sr2NbxTa2-xO7 solid solutions with high photocatalytic activities for water decomposition into H2 and O2. Chemistry Materials,14,3369-3376.
    Yoshioka K., Petrykin V., Kakihana M., Kato H., Kudo A.2005, The relationship between photocatalytic activity and crystal structure in strontium. Journal of Catalysis,232, 102-107.
    You X.F.2008, Polycyclic aromatic hydrocarbon (PAH) emission from co-firing municipal solid waste (MSW) and coal in a fluidized bed incinerator. Waste Management,28, 1543-1551.
    Yu X.Z., Gao Y., Wu S.C., Zhang H.B., Cheung K.C., Wong M.H.2006, Distribution of polycyclic aromatic hydrocarbons in soils at Guiyu area of China, affected by recycling of electronic waste using primitive technologies. Chemosphere,65,1500-1509.
    Yunker M.B., Macdonald R.W., Vingarzan R., Mitchell R.H., Goyette D., Sylvestre S.2002, PAHs in the Fraser River basin:a critical appraisal of PAH ratios as indicators of PAH source and composition. Organic Geochemistry,33,489-515.
    Zhang G.K., Zou X., Gong J., He F.S., Zhang H., Ouyang S.X., Liu H.X., Zhang Q., Liu Y., Yang X., Hu B.2006, Characterization and photocatalytic activity of Cu-doped K2Nb4O11. Journal of Molecular Catalysis A:Chemical,255,109-116.
    Zhang H., Fan X.F., Quan X., Chen S., Yu H.T.2011, Graphene sheets grafted Ag@AgCl hybrid with enhanced plasmonic photocatalytic activity under visible light. Environmental Science & Technology,45,5731-5736.
    Zhang H.B., Luo Y.M., Wong M.H., Zhao Q.G., Zhang G.L.2006, Distributions and concentrations of PAHs in Hong Kong soils. Environmental Pollution,141,107-114.
    Zhang W., Zhang S., Wan C., Yue D., Ye Y., Wang X.,2008, Source diagnostics of polycyclic aromatic hydrocarbons in urban road runoff, dust, rain and canopy throughfall. Environmental Pollution,153,594-601.
    Zhang X.L., Tao S., Liu W.X., Yang Y., Zuo Q., Liu S.Z.2005, Source diagnostics of polycyclic aromatic hydrocarbons based on species ratios:a multimedia approach. Environmental Science & Technology,39,9109-9114.
    Zhang Y.W., Liu C., Pang G.S., Jiao S.H., Zhu S.Y., Wang D., Liang D.X., Feng S.H.2010, Hydrothermal synthesis of a CaNb2O6 hierarchical micro/nanostructure and its enhanced photocatalytic activity. European Journal of Inorganic Chemistry,8,1275-1282.
    Zhang Z.L., Hong H.S., Zhou J.L., Yu G.2004, Phase association of polycyclic aromatic hydrocarbons in the Minjiang River Estuary, China. Science of the Total Environment, 323,71-86.
    Zhao Z.B., Liu K., Xie W., Pan W.P., Riley J.T.2000, Soluble polycyclic aromatic hydrocarbons in raw coals. Journal of Hazardous Materials,73,77-85.
    Zhao L.J., Zhang F.S., Hao Z.P., Wang H.L.2008, Levels of polycyclic aromatic hydrocarbons in different types of hospital waste incinerator ashes. Science of the Total Environment,397,24-30.
    Zhao L.J., Zhang F.S., Chen M.J., Liu Z.G., Bo D., Wu J.Z.2010, Typical pollutants in bottom ashes from a typical medical waste incinerator. Journal of Hazardous Materials,173, 181-185.
    Zhou M.H., Yu J.G., Cheng B.,2006, Effects of Fe-doping on the photocatalytic activity of mesoporous TiO2 powders prepared by an ultrasonic method. Journal of Hazardous Materials,137,1838-1847.
    Zhou X., Chen Y, Mei H., Hu Z.L., Fan Y.Q.2008, A facile route for the preparation of morphology controlled NaTaO3 films. Applied Surface Science,255,2803-2807.
    Zhu H.Y., Zheng Z.F., Gao X.P., Huang Y.N., Yan Z.M., Zou J., Yin H.M., Zou Q.D., Kable S.H., Zhao J.C., Xi Y.F., Martens W.N., Frost R.L.2006, Structure evolution in a hydrothermal reaction between Nb2O5 and NaOH solution:from Nb2O5 grains to microporous Na2Nb2O6-2/3 H2O fibers and NaNbO3 cubes. Journal of the American Chemical Society,128,2373-2384.
    Zhu K., Neale, N.R., Miedaner A., Frank A.J.2007, Removing structural disorder from oriented TiO2 nanotube arrays:reducing the dimensionality of transport and recombunation in dye-sensitized solar cells. Nano Letters,7,3769-3774.
    Zhu L., Chen Y., Zhou R.2007, Distribution of polycyclic aromatic hydrocarbons in water, sediment and soil in drinking water resource of Zhejiang Province, China. Journal of Hazardous Materials,150,308-316.
    Zhu L., Wang J.2003, Sources and patterns of polycyclic aromatic hydrocarbons pollution in kitchen air, China. Chemosphere,50,611-618.
    Zhu M.S., Chen P.L., Liu M.H.2011, Graphene oxide enwrapped Ag/AgX (X=Br, Cl) nanocomposite as a highly efficient visible-light plasmonic photocatalyst. ACSNANO,5, 4529-4536.
    陈皓,刘颖,刘海玲,袁园,肖乾芬.2008,超高效液相色谱法检测土壤中的多环芳烃.色谱,11,769-771.[Chen H., Liu Y., Liu H.L., Yuan Y, Xiao Q.F.2008, Determination of polycyclic aromatic hydrocarbons in soil by ultra performance liquid chromatography. Chinese Journal of Chromatography,11,769-771.]
    杜雪晴,王新明,唐建辉,丁翔,林海涛,李忠,盛国英,傅家谟.2006,我国主要市售香烟主流烟气中多环芳烃的分析.环境化学,25,785-788[Du X.Q., Wang X.M., Tang J.H., Ding X., Lin H.T., Li Z., Sheng G.Y., Fu J.M.2006, Polycyclic aromatic hydrocarbons in mainstream smokes from major cigarette brands sold in China. Environmental Chemistry,25,785-788.]
    段永红,陶澍,王学军,李本纲,徐福留,刘文薪,曹军,朱利中,骆永明.2005,天津表土中多环芳烃含量的空间分布特征与来源.土壤学报,42,942-947[Duan Y.H., Tao S., Wang X.J., Li B.G., Xu F.L., Liu W.X., Cao J., Zhu L.Z., Luo Y.M.2005, Spatial distribution and sources of PAHs in Tianjin's topsoil. Acta Pedologica Sinica,42, 942-947.]
    方世杰,徐明霞,张玉珍.二氧化钛光催化降解作用的研究综述.材料导报.2001,15,32-34. [Fang S.J., Xu M.X., Zhang Y.Z.2001, Photocatalytic degradation of TiO2. Materials Review,15,32-34.]
    冯春波,杜志平,赵永红,台秀梅,李秋小.2006,Au改性纳米Ti02材料对NPE-10光催化降解的活性.物理化学学报.22,953-957,[Feng C.B., Du Z.P., Zhao Y.H., Tai X.M., Li Q.X.2006, Acta Physico-Chimica Sinica,22,953-957.]
    傅家谟,盛国英.1996,环境有机地球化学初探.地学前缘.1-2,127-132[Fu J.M., Sheng G.Y.1996, Preliminary study on environmental organic geochemistry. Earth Science Frontiers,1-2,127-132.]
    郭崇涛.1992,煤化学[M].北京:化学工业出版社,[Guo C.T.1992, Chemistry of Coal[M]. Beijing:Chemical Industry Press.]
    韩菲.2007,多环芳烃来源与分布及迁移规律研究概述.气象与环境学报,4,57-61[Han F.2007, Review on origin, distribution and translocation of polycyclic aromatic hydrocarbons (PAHs). Journal of Meteorology and Environment,4,57-61.]
    郝蓉,彭少麟,宋艳暾,杨国义,万洪富,2004.汕头经济特区土壤中优控PAHs的分布.生态学,13,323-326[Hao R., Peng S.L., Song Y.T., Yang G.Y., Wan H.F.,2004. Distribution of priority polycyclic aromatic hydrocarbons in soils in Shantou specific economic zone. Ecology and Environment,13,323-326.]
    郝永梅,李春雷,罗孝俊,麦碧娴,盛国英,傅家谟.2006,澳门南湾湖钻孔沉积物中自由态和束缚态的多环芳烃.环境科学,27,235-240[Hao Y.M, Li C.L, Luo X.J, Mai B.X, Sheng G.Y, Fu J.M.2006, Free and bound PAHs in a sediment core from Nam Van artificial lake of Macao. Chinese Journal of Environmental Science,27,235-240.]
    胡学玉,艾天成.2006,鄂东(北)茶园土壤及茶叶中的农药残留.农业环境科学学报,25,61-64. [Hu X.Y., Ai T.C.2006, Pesticide Residues in Tea and Soils in East (Northeast) Hubei. Journal of Agro-Environment Science,25,61-64.]
    金保升,周宏仓,仲兆平,肖睿,党小剑.2004,三种不同中国煤中多环芳烃的分布特征研究.锅炉技术,35,1-4[Jin B.S., Zhou H.C., Zhong Z.P., Xiao R., Dang X.J.2004, Study on distribution of polycyclic aromatic hydrocarbons in three different raw coals in China. Boiler Technology,35,1-4.]
    李剑,乔敏,崔青,马梅,王子健.2006,测定5种高环多环芳烃毒性当量因子并应用于太湖梅梁湾表层沉积物分析.生态毒理学报,1,12-16[Li Jian., Qiao Min., Cui Qing., Ma Mei., Wang Zijian.2006, Detection of toxicity equivalent factors for five PAHs and studies on its usage in the sediment of Meiliang Bay, Taihu Lake. Asian Journal of Ecotoxicology,1,12-16.]
    刘大锰,刘志华,李运勇.煤中有害物质及其对环境的影响研究进展.地球科学进展,17, 840-847. [Liu D.M., Liu Z.H., Li Y.Y.2002, Advances in studies of harmful substances in coal and their impact on the environment. Advance in Earth Sciences,17,840-847.]
    刘桂建,彭子成,王桂梁,杨萍月,Chou Chenglin.2002,煤中微量元素研究进展.地球科学进展,17,53-62.[Liu G.J., Peng Z.C., Wang G.L., Yang P.Y., Chou C.L. Study on trace elements in coal. Advance in Earth Sciences,17,53-62.]
    刘慧永,徐旭常,姚强,张爱云.2001,燃煤电厂飞灰碳含量与PAHs有机污染物吸附量之间相关性研究.热能动力工程,16,359-362[Liu H.Y., Xu X.C., Yao Q., Zhang A.Y. 2001, A study of the correlation between the carbon content in fly ash of coal fired power plants and adsorption quantity of PAHs organic pollutants. Journal of Engineering for Thermal Energy and Power,16,359-362.]
    刘继景.2010,新型纳米金属氧化物光催化材料的制备与性能研究.硕士学位论文.河北工业大学[Liu Jijing.2010, Preparation and properties of photocatalytic nanomaterials of new metal oxide. Master thesis. Hebei Unversity of Technology, Hebei province, China.]
    刘守新,刘鸿.2005,光催化及光电催化基础与应用.北京:化学工业出版社,208[Liu S.X., Liu H.2005, Fundamental and application of photocatalysis & electro-photocatalysis. Beijing:Chemical Industry Press,208.]
    陆胜勇,王丽英,李晓东,尤孝方,严建华,谷月玲,倪明江,岑可法.2002,烟煤中多环芳烃分布特征的初步研究.环境科学研究,14,7-9. [Lu S.Y., Wang L.Y., Li X.D., You X.F., Yan J.H, Gu Y.L., Ni M.J., Cen K.F.2002, Study on polycyclic aromatic hydrocarbons distribution in bituminous coal. Research of Environmental Science,14, 7-9.]
    刘长城,陈红,孙元宝,王晓华,曹景沛,魏贤勇.2004,煤的分级萃取及组成.吉林大学学报(理学版),42,442-446[Liu C.C., Chen H., Sun Y.B., Wang X.H., Cao J.P., Wei X.Y. 2004, Fractionated extraction and composition of coal. Journal of Jilin University (Science Edition).42,442-446.]
    刘桂建,彭子成,王桂梁,杨萍月,Chou C.L,2002煤中微量元素研究进展.地球科学进展,17,53-62[Liu G.J., Peng Z.C., Wang G.L., Yang P.Y., Chou C.L.2002, Study on trace elements in coal. Advance in Earth Science,17,53-62.]
    刘国卿,彭先芝,张干,祁士华,邹世春,李向东.2007,南岭山地湖泊多环芳烃的大气沉降历史记录.地球化学,36,357-362[Liu G.Q., Peng X.Z., Zhang G., Qi S.H., Zou S.C., Li X.D.2007, Sedimentary records of atmospheric deposition of polycyclic aromatic hydrocarbons in a reservoir in Nanling mountains, south China. Geochimica,36, 357-362.]
    刘建华,祁士华,张干,张伟玲.2003,拉萨市拉鲁湿地多环芳烃污染及其来源.物探与化探.27,490-492[Liu J., Qi S., Zhang G., Zhang W.2003, Polycyclic aromatic hydrocarbons in Lalu wetland of Lhasa city and their sources. Geophysical and Geochemical Exploration,27,490-492.]
    罗孝俊,陈社军,麦碧娴,曾永平.2006,珠江三角洲地区水体表层沉积物中多环芳烃的来源、迁移及生态风险评价.生态毒理学报,1,17-24[Luo X.J., Chen S.J., Mai B.X., Zeng E.Y.2006, Source, transport and risk assessment of PAHs in surface sediments from pearl river delta. Asian Journal of Ecotoxicology,1,17-24.]
    彭林,曾凡刚,陈名墚,刘裕明.2003,太原市大气总悬浮颗粒物正构烷烃和多环芳烃空间分布及来源分析.岩矿测试,22,206-210[Peng Lin, Zeng Fan-gang, Chen Ming-liang, Liu Y.M.2003, Distribution characteristics and source analysis of n-alkanes and PAHs in total suspended particulates in urban area of Taiyuan city. Rock and Mineral Analysis,22,206-210.]
    齐翠翠.2010,锑在中国煤及典型矿区中的环境地球化学研究.博士学位论文.中国科学技术大学[Qi C.C.2010, Environmental geochemistry of antimony in Chinese coals and two typical mines. PhD thesis. University of Science and Technology of China, China.]
    王继忠.2008,珠珠江八大入海口水体中烃类和甾醇:潜在指示区域污染状况与全球贡献.博士学位论文.中国科学院广州地球化学研究所[Wang J.Z.2008, Hydrocarbon and fecal steroids in riverine runoff of the Pear River Delta (China):assessment of water quality and contributions of organic pollution to the global environment. PhD thesis. Guangzhou Institute of Geochemistry, Graduate School of Chinese Academy of Sciences, China.]
    王淑娟,周翔,许宜平,马梅,刘文利,李太山.2007,北方某城市饮用水中多环芳烃的来源及其在水处理过程中的行为研究.环境工程学报,8,52-56[Wang S.J., Zhou X., Xu Y.P., Ma M., Liu W.L., Li T.B. Study on source of polycyclic aromatic hydrocarbons and its behavior in drinking water treatment process in a city of north China. Chinese Journal of Environmental Engineering,8,52-56.]
    王欣心,金银龙.2010,多环芳烃遗传毒性研究进展.环境与健康杂志,2,174-]76[Wang X.X., Jin Y.L.2010, Research progress on genotoxity of polycylcic aromatic hydrocarbons. Journal of Environment Health,2,174-176.]
    王小萍,姚檀栋,丛志远,燕新梁,康世昌,张勇.2006,珠穆朗玛峰地区土壤和植被中多环芳烃的含量及海拔梯度分析.科学通报,51,2571-2525.
    姚艳,严建华,陆胜勇,李晓东,尤孝方,谷月玲,岑可法.2003,原煤中多环芳烃含量特性的初步研究.热力发电,32,5-8[Yao Y., Yan J.H., Lu S.Y., Li X.D., You X.F., Gu Y.L., Cen K.F.2003, A primary study on the behavior of PAH content in raw coals of China. Thermal Power Generation,32,5-8.]
    徐旭,陆胜勇,傅刚,葛俊,李晓东,严建华,池勇,岑可法.2002,不同工况飞灰重金属和PAHs特性实验研究.燃烧科学与技术,8,145-149[Xu X., Lu S.Y., Fu G., Ge J., Li X.D., Yan J.H., Chi Y., Cen K.F.2002, Experimental study on heavy metal and PAHs of circulated fluidized bed boiler ESP Ash. Journal of combustion science and technology,8, 145-149.
    杨国义,张天彬.2007,珠江三角洲典型区域农业土壤中多环芳烃的含量分布特征及其污染源.环境科学,28,2350-2354[Yang G.Y., Zhang T.B.2007, Source and distribution characteristics of polycyclic aromatic hydrocarbons in agricultural soils in the pearl river delta. Chinese Journal of Environmental Science,28,2350-2354.]
    姚艳,严建华,陆胜勇,李晓东,尤孝方,谷月玲,岑可法.2003,原煤中多环芳烃含量特性的初步研究.热力发电,32,5-8[Yao Y, Yan J.H., Lu S.Y., Li X.D, You X.F, Gu Y.L, Cen K.F.2003, A primary study on the behavior of PAH content in raw coals of China. Thermal Power Generation,32,5-8.]
    余刚,黄俊,张彭义.2001,持久性有机污染物:备受关注的全球性环境问题.环境保护, 4,37-39. [Yu G., Huang J., Zhang P.Y.2001, Persistent organic pollutants:one of the important global environmental problems. Environmental Protection,4,37-39.]
    禹果,吴文勇,刘洪禄,肖睿洋,王春霞,王子健.利用化学分析和生物检测方法比较研究污染土壤中芳烃手提效应物质的积累.环境科学,2006,27,1820-1824[Yu G., Wu W.Y., Liu H.L., Xiao R.Y., Wang Z.J.2006, Comparative study on accumulation of Ah-receptor agonists in contaminated soil based on EROD bioassay and chemical analysis. Environmental Science,27,1820-1824.]
    岳敏,谷学新,邹洪,朱若华,苏文斌.2003,多环芳烃的危害与防治.首都师范大学学报.24,40-45[Yue ML, Gu X.X., Zou H., Zhu R.H., Su W.B.2003, Killer of health polycyclic aromatic hydrocarbons. Journal of Capital Normal University,24,40-45.]
    张丽珠,刘永庆,陈文琳.1996,中国煤中多环芳烃的测定-氧化铝柱预分离高效液相色谱法.岩矿测试,15,161-167[Zhang L.Z., Liu Y.Q., Chen W.L.1996, Determination of polycyclic aromatic hydrocarbons in raw coals in China by HPLC after preseparation using aluminum oxide layer column chromatography. Rock and Mineral Analysis,15, 161-167.]
    曾永平,倪宏刚.2010.常见有机污染物分析方法[M].科学出版社.
    赵文昌,程金平,谢海簧,马英歌,王文华.2006,环境中多环芳烃(PAHs)的来源与监测分析方法.环境科学与技术.3,105-107[Zhao W.C., Cheng J.P., Xie H.Y., Ma Y.G., Wang W.H.2006, PAHs:sources, pathway and their monitoring and analysis. Environmental Science & Technology,3,105-107.]
    邹志刚,赵进才,付贤智,张彭义,陈军,朱鸿民,叶金华.2004,光催化太阳能转换及环境净化材料的现状和发展趋势.功能材料,35,83-88[Zou Z.G., Zhao J.C., Fu X.Z., Zhang P.Y., Chen J., Zhu H.M., Ye J.H.2004, Development on solar energy conversion and environmental applications of photocatalysis. Journal of Functional Materials,35, 83-88.]
    朱凡,田大伦,闫文德,梁小翠,郑威.2007,多环芳烃在土壤-植物系统中的修复研究进展.中南林业科技大学学报,27,112-116[Zhu F., Tian D.L., Yan W.D., Liang X.C., Zheng W. Research progress of polycyclic aromatic hydrocarbons'remedy in a soil-plant system. Journal of Central South University of Forestry & Technology,27,112-116.]
    周宏仓,金保升,仲兆平,李锋,黄亚继,2003,燃煤电厂多环芳烃的生成与控制.环境污染治理技术与设备,4,50-53[Zhou H.C., Jin B.S., Zhong Z.P., Li F., Huang Y.J. 2003, Generation and control of polycyclic aromatic hydrocarbons (PAHs) in coal-fired power plants. Techniques and Equipment for Environmental Pollution Control,4,50-53.]

© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号

地址:北京市海淀区学院路29号 邮编:100083

电话:办公室:(+86 10)66554848;文献借阅、咨询服务、科技查新:66554700