吡唑的缓蚀作用及协同效应的研究
摘要
本文综述了铜缓蚀剂的研究进展、缓蚀机理以及其协同作用。通过旋转圆盘的循环伏安曲线法、X-射线光电子能谱法、旋转挂片法等研究了在强酸性介质(0.5mol/L硫酸溶液)和弱碱性介质(0.05mol/L碳酸氢钠溶液、1.00mol/L碳酸钾+0.8mol/L碳酸氢钾溶液)中吡唑(Pz)对紫铜的缓蚀作用及机理,讨论了氯离子、次氯酸钠对吡唑缓蚀作用的影响。并吡唑与苯并三氮唑(BTA)和巯基苯并噻唑(MBT)的协同作用进行了研究。得出以下结论:
1、在含吡唑的0.5 mol/L硫酸溶液中,紫铜的阳极溶解速度受电化学步骤和扩散步骤混合控制。
2、吡唑在0.05mol/L碳酸氢钠溶液中在紫铜表面的吸附属于Frumkin等温吸附,紫铜的阳极溶解速度受电化学步骤控制。
吡唑在紫铜表面形成的吸附膜主要是有Cu(II)、O、N和C,组成可能主要是Pz- Cu(II)。
3、在0.05mol/L碳酸氢钠溶液中氯离子加速了紫铜的腐蚀速度。而一定浓度的次氯酸钠能使紫铜表面钝化,减慢紫铜的腐蚀速率。
4、BTA、MBT在0.05mol/L碳酸氢钠溶液中在紫铜表面的吸附也遵从Frumkin等温吸附,紫铜的阳极溶解速度受电化学步骤和扩散步骤混合控制。
5、吡唑与BTA、吡唑与MBT之间有一定的协同作用。前者在紫铜表面的吸附属于特殊等温吸附,后者在紫铜表面的吸附也遵从Frumkin等温吸附。
吡唑与BTA协同时,紫铜表面膜层含有Cu(I)、Cu(II)、O、N和C,膜的组成可能为Cu-BTA-Pz的混合物。吡唑与MBT协同时,紫铜表面膜层含有Cu(I)、S、O、N和C,膜的组成可能为Cu-MBT-Pz的混合物。
The literatures of copper corrosion inhibitors were reviewed. The inhibitors(pyrazole(Pz)、benzotriazole(BTA)、2-mercaptbenzothiazole(MBT)) effect on the corrosion behavior of copper in 0.5mol/L H2SO4 solution 、0.05mol/L NaHCO3 and 1.00mol/L K2CO3+0.80mol/L KHCO3 solutions were studied and evaluated by cyclic voltammetry curves measurement 、XPS surface analysis technique and rotating disk electrode , and the synergistic effects among them. The influence of chloride、NaClO on pyrazole also were investigated. It was found that :
The anodic dissolution of copper in 0.5mol/L H2SO4 solution contained pyrazole is determined (or controlled) by both the electrochemical step and diffusion step .
The pyrazole adsorption on copper in 0.05mol/L NaHCO3 solution obeys the Frumkin adsorption isotherm, the anodic dissolution of copper is determined by the electrochemical.
The out layer of the protective film formed by pyrazole on the surface of copper comprised Cu(II)、O、N and C. The protective film probably formed by Pz- Cu(II) and the inner CuO film.
3、The chlorine ion accelerates the corrosion of copper in 0.05mol/L NaHCO3 solution. But the hypochlorite passives the copper and inhibits the corrosion.
4、The BTA and MBT adsorption on copper in 0.05mol/L NaHCO3 solution also obeys the Frumkin adsorption isotherm, the anodic dissolution of copper is determined by both the electrochemical step and diffusion step .
5、There was a synergistic effect between pyazole and BTA, their adsorption on copper in 0.05mol/L NaHCO3 solution obeys certain adsorption isotherm. There was a synergistic effect between pyazole and MBT, their adsorption on copper in 0.05mol/L
NaHCO3 solution obeys Frumkin adsorption isotherm.
The out layer of the protective film formed by pyazole and BTA on surface of copper comprised Cu(II)、Cu(I)、O、N and C. The protective film probably formed by the compound of Cu-BTA-Pz. The out layer of the protective film formed by pyazole and MBT on surface of copper comprised Cu(I)、S、O、N and C. The protective film probably formed by the compound of Cu-MBT-Pz.
1、在含吡唑的0.5 mol/L硫酸溶液中,紫铜的阳极溶解速度受电化学步骤和扩散步骤混合控制。
2、吡唑在0.05mol/L碳酸氢钠溶液中在紫铜表面的吸附属于Frumkin等温吸附,紫铜的阳极溶解速度受电化学步骤控制。
吡唑在紫铜表面形成的吸附膜主要是有Cu(II)、O、N和C,组成可能主要是Pz- Cu(II)。
3、在0.05mol/L碳酸氢钠溶液中氯离子加速了紫铜的腐蚀速度。而一定浓度的次氯酸钠能使紫铜表面钝化,减慢紫铜的腐蚀速率。
4、BTA、MBT在0.05mol/L碳酸氢钠溶液中在紫铜表面的吸附也遵从Frumkin等温吸附,紫铜的阳极溶解速度受电化学步骤和扩散步骤混合控制。
5、吡唑与BTA、吡唑与MBT之间有一定的协同作用。前者在紫铜表面的吸附属于特殊等温吸附,后者在紫铜表面的吸附也遵从Frumkin等温吸附。
吡唑与BTA协同时,紫铜表面膜层含有Cu(I)、Cu(II)、O、N和C,膜的组成可能为Cu-BTA-Pz的混合物。吡唑与MBT协同时,紫铜表面膜层含有Cu(I)、S、O、N和C,膜的组成可能为Cu-MBT-Pz的混合物。
The literatures of copper corrosion inhibitors were reviewed. The inhibitors(pyrazole(Pz)、benzotriazole(BTA)、2-mercaptbenzothiazole(MBT)) effect on the corrosion behavior of copper in 0.5mol/L H2SO4 solution 、0.05mol/L NaHCO3 and 1.00mol/L K2CO3+0.80mol/L KHCO3 solutions were studied and evaluated by cyclic voltammetry curves measurement 、XPS surface analysis technique and rotating disk electrode , and the synergistic effects among them. The influence of chloride、NaClO on pyrazole also were investigated. It was found that :
The anodic dissolution of copper in 0.5mol/L H2SO4 solution contained pyrazole is determined (or controlled) by both the electrochemical step and diffusion step .
The pyrazole adsorption on copper in 0.05mol/L NaHCO3 solution obeys the Frumkin adsorption isotherm, the anodic dissolution of copper is determined by the electrochemical.
The out layer of the protective film formed by pyrazole on the surface of copper comprised Cu(II)、O、N and C. The protective film probably formed by Pz- Cu(II) and the inner CuO film.
3、The chlorine ion accelerates the corrosion of copper in 0.05mol/L NaHCO3 solution. But the hypochlorite passives the copper and inhibits the corrosion.
4、The BTA and MBT adsorption on copper in 0.05mol/L NaHCO3 solution also obeys the Frumkin adsorption isotherm, the anodic dissolution of copper is determined by both the electrochemical step and diffusion step .
5、There was a synergistic effect between pyazole and BTA, their adsorption on copper in 0.05mol/L NaHCO3 solution obeys certain adsorption isotherm. There was a synergistic effect between pyazole and MBT, their adsorption on copper in 0.05mol/L
NaHCO3 solution obeys Frumkin adsorption isotherm.
The out layer of the protective film formed by pyazole and BTA on surface of copper comprised Cu(II)、Cu(I)、O、N and C. The protective film probably formed by the compound of Cu-BTA-Pz. The out layer of the protective film formed by pyazole and MBT on surface of copper comprised Cu(I)、S、O、N and C. The protective film probably formed by the compound of Cu-MBT-Pz.
引文
[1] R.Gasparac and E.Stupnisek-Lisac. Corrosion Protection on Copper by Imidazole and Derivatives[J]. Corrosion 1999,54(9):131～139
[2] R.Gasparac,C.R.Martin,and E.Stupnisek-Lisac In Situ Studies of Imidazole and Its Derivatives as Copper Corrosion Inhibitors[J]. Journal of The Electrochemical Society 2000,147(2):548～551
[3] E.Stupnisek-Lisac, A.Loncaric, and I.Cafuk Low-Toxicity Copper Corrosion Inhibitors[J]. CORROSION 1998,54(9):713～720
[4] 旷富贵,张传飞,姚禄安等. Cu电极上咪唑与苯并三唑共吸附的SERS研究[J]. 腐蚀科学与防护技术. 1997,9(2):126～127
[5] 史志龙,庞正智. 新型铜酸洗缓蚀剂烷基苯并咪唑的研究[J]. 北京化工大学学报. 2002,29(2):52～54
[6] E.Geler, D.S.Azambuja Corrosion inhibition of copper in chloride solutions by pyrazole[J]. Corrosion Science. 2000(42):631～643
[7] 张大全,高立新,周国定等. HCl溶液中巯基杂环化合物对铜的缓蚀作用[J]. 应用化学. 2002,19(6):535～538
[8] 章荣玲,杜爱玲,李廷芳. 2-十一烷基-1-(双硫脲)乙基-咪唑啉在铜表面上的成膜作用[J]. 山东师大学报. 1994,9 (4):36～39
[9] 陆嘉星,胡福建,宋丽萍等. 动电位法研究酸性溶液中CTAB对Cu的缓蚀作用[J]. 华东师范大学学报. 2000,2(2):65～68
[10] S.L.Li, H.Y.Ma, S.b.Lei et al Inhibition of copper corrosion with schhiff base derived from 3-methoxysalicyladehyde and o-phenyldiamine in chloride media[J]. Corrosion 1998,54(12):947～954
[11] E.Stupnisek-Lisac,A.Brnada,A.D.Mance Secondary amines as copper corrosion inhibitors in acid media[J]. Corrosion Science 2000(42):243～257
[12] L.Horner und E.Pliefke Inhibitoren der Korrosion 29 (1).Vergleichende Untersuchung weiterer Inhibitoren der Korrosion des Kupfers unter
Standardbedingungen[J]. Werkstoffe und Korrosion 1982(33):454～461
[13] L.Horner und E.Pliefke Inhibitors of corrosion 28(1).2-Aminopyrimidine(2-AP) as an inhibitor of the corrosion of copper in salt solutions under oxygen[J]. Werkstoffe und Korrosion1982(33):189～193
[14] M.M.El-Naggar Bis-aminoazoles. Corrosion inhibitors for copper in 4.0 M HNO3 solutions[J]. Corrosion Science.2000(42):773～784
[15] 于萍,罗运柏. 有机铜缓蚀剂研究现状与进展[J]. 化学清洗. 1999,15(1):31～37
[16] A.S.Fouda and A.K.Mohamed Substituted phenols as corrosion inhibitors or copper in nitric acid[J]. Werkstoffe und Korrosion 1988(39):23～26
[17] S.A.Abd El-Maksoud,A.A.El-Shafei,H.A.Mostafa et al Inhibition of copper corrosion in 1M nitric acid with benzoyl benzaldehyde hydrazone derivatives[J]. Materials and Corrosion 1995(46) :468～472
[18] Y.Ling, Y.Guan and K.N.Han. Corrosion Inhibiton of Copper with Benzotriazole and Other Organic Surfactants[J]. Corrosion. 1995,51 (5):367～375
[19] V.Otieno-Alego, N.Huynh, T.Notoya et al. Inhibitive effect of 4- and 5-carboxybenzotriazole on copper corrosion in acidic sulphate and hydrogen sulphide solutions[J]. Corrosion Science 1998(41):685～697
[20] N.Huynh, S.E.Bottle, T.Notoya et al Inhibitive action of the octyl estrs of 4- and 5-carboxybenzotriazole for copper corrosion in sulphate solutions[J]. Corrosion Science 2000(42):259～274
[21] D.P.Schweinsberg, S.E.Bottle, V.Otieno-Alego. A near-infrared FT-Raman(SERS) and electrochemical study of the synergistic effect of 1-[(1’,2’-dicarboxy)ethyl-benzotriazole and KI on the dissolution of copper in aerated sulfuric acid[J]. Journal of Applied Electrochemistry 1997(27):161～168
[22] Gamal K.Gomma. Effect of azole compounds on corrosion of copper in acid medium[J]. Materials Chemistry and Physics 1998(56):27～34
[23] G.Quartrarone, A.Zingales, T.Bellomi et al Study of inhibition mechanism and efficiency of indole-5-carboxylic acid on corrosion of copper in aerated 0.5M H2SO4[J]. British Corrosion Journal. 2000,35(4):304～310
[24] J.M.Bastidas and E.Otero A comparative study of benzotriazole and 2-amino-5-mercapto-1,3,4-thiadiazole as copper corrosion inhibitors in acid media[J]. Materials and Corrosion 1996(47):333～337
[25] 傅海涛,李瑛,魏无际等. AMT在青铜-柠檬酸体系中的缓蚀行为及其机理[J]. 物理化学学报. 2001,17(7):604～608
[26] G.P.Cicileo, B.M.Rosales, F.E.Varela, et al Comparative study of roganic inhibitors of copper corrosion[J]. Corrosion Science.1999(41):1359～1375
[27] G.P.Cicileo, B.M.Rosales, F.E.Varela et al Inhibitory Action of The Ccopper Corrosion Process[J] Corrosion Science 1998,40(11):1915～1926
[29] Fabrizo Zucchi, Micaela Fonsati and Giordano Trabanelli. Influence of The Heat Exchange on The Inhibiting Efficiency of Some Heterocyclic Derives Against Copper Corrosion in 3.5% NaCl Solutions[J]. Corrosion Science 1998,40(11):1927～1937
[29] 张大全,徐群杰,陆柱. 苯并三唑和咪唑分子内缓蚀协同作用的研究[J]. 中国腐蚀与防护学报. 1999,19(5):280～284
[30] 高立新,张大全,陆柱等. 含苯并三唑和噻二唑单元的铜缓蚀剂制备和缓蚀作用[J]. 华东理工大学学报 2001,27(1):84～88
[31] 严川伟,林海潮,曹楚南等. 2-巯基苯并恶唑(MBO)在铜表面缓蚀膜研究[J]. 中国腐蚀与防护学报. 1999,19(6):368～370
[32] 陈刚,杨植震,郑成法. 某些杂环化合物对青铜的缓蚀作用[J]. 复旦学报(自然科学版). 1996,35(3):295～304
[33] R.Tremont, H.De.Jesus-Cardona, J.GarciaARCIA-Orozco et al. 3-Mercaptopropyltrimethoxysilane as a Cu corrosion inhibitor in KCl solution[J]. Journal of Applied Electrochemistry 2000(30):737～743
[34] G..Petkova,P.Lvanov,E.Sokolva et al Inhibiting Action of α-
yrophthalone in Copper Corrosion[J], Werkstoffe und Korrosion 1993(44):187～192
[35] 朱一帆,李大刚,施兵兵等. AMT保护青铜的研究[J]. 材料保护. 1998,31(5):3～5
[36] 甘复兴,戴忠旭,汪的华等. 中性介质中铜缓蚀剂的成膜过程[J]. 应用化学. 1998,15(4):45～48
[37] 扈显琦,彭乔,张明嘉. 海水中铜缓蚀剂研究[J]. 四川化工与腐蚀控制. 1999 ,2(3):4～8
[38] 童泉玉,陈号卫,杨从贵等. 羧酸类铜缓蚀剂的制备及性能测试[J]. 材料保护. 2001,34(3):49～50
[39] G.Lewis. The corrosion inhibition of copper by benzomidazole[J]. Corrosion Science. 1982,22(6):579～584
[40] Y.Feng, K.S.Siow, W.K.Teo et al. Synergistic Effects Between Sodium Tripolyphosphate and Zinc Sulfate in Corrosion Inhibition for Copper in Neutral Tap Water[J]. Corrosion. 1997,53(7):546～555
[41] E.Guilminot, J-J.Rameau, F.Dalard et al. Benzotriazole as inhibitor for copper with and without corrosion products in aqueous polyethylene glycol[J]. Journal of Applied Electrochemistry 2000(30):21～28
[42] W.Qagsaoui, Ch.Blanc, J.Roques et al. Pitting corrosion in sulphate solutions: inhibitive effect of different triazole derivative inhibitors[J]. Journal of Applied Electrochemistry 2001(31):223～231
[43] W.Qafsoui, Ch.Blanc, N.Pebere et al. Study of different triazole derivative inhibitors to protect copper against pitting corrosion[J]. Journal of Applied Electrochemistry 2000(30):959～966
[44] 旷亚非,陈曙,林志成. 2-巯基苯并噻唑对NaCl溶液中铜的缓蚀行为[J]. 中国腐蚀与防护学报 1995,15(2):129～133
[45] S.Sankarapapavinasam, M.F.Ahed. Benzenethiols as inhibitors for the corrosion of copper[J]. Journal of Applied Electrochemistry 1992(22):390～395
[46] E.Otero and J.M.Bastidas Study of two new aqueous alkaline copper
cleaning solutions and comparison with a conventional bath[J]. Werkstoffe und Korrosion 1996(47):511～515
[47] 黄乃宝,梁成浩. 高温高浓度溴化锂溶液中磷脱氧铜耐蚀性能研究[J]. 大连理工大学学报. 2001,41(6):667～670
[48] K.P.Fitzgerald, J.Nairn and A.Atrens. The Chemistry of Copper Patination[J]. Corrosion Science. 1998,40 (12):2029～2050
[49] M.Fleischmann, I.R.Hill, G.Mengoli et al. The synergetic effct of benzylamine on the corrosion inhibition of copper by benzotriazole[J]. Ekectrochimica Acta 28(10):1325~1333
[50] P.G.Fox, G.Lewis, P.J.Boden. Some chemical aspects of the corrosion inhibition of copper by bentriazole[J]. Corrosion science 1979(19):457~467
[51] M.Metikos-Hukovic,K.Furic, R.Babic et al. Surface-enhanced Raman Scattering(SERS) of Benzotriazole Derivative Corrosion Inhibitor Prepared in Aqueous Media[J]. Surface and Interface Analysis 1999(27):1016～1025
[52] O.H.ollander and R.C.May. The chemistry of azole copper corrosion inhibitors in cooling water[J]. corrosion 1985,41(1), 39~45
[53] R.Babic, M.Metikos-Hukovic. Spectroelectrochemical studies of protective surface films against copper corrosion[J]. Thin Solid Films 2000(359):88~94
[54] P.G..Fox, G..Lewist and P.J.Boden. Some Chemical Aspects of The Corrosion Inhibitor of Copper by Benztriazole[J]. Corrosion Science.1979,19 (7):457~468
[55] 旷亚非,陈曙,林志成. 苯并三氮唑、2-巯基苯并噻唑协同缓蚀作用机理探讨[J]. 材料保护. 1994,27(8):11~15
[56] A.D.Modestov, G..D.Zhou, Y.P.Wu et al. A Study of The Electrochemical Formation of Cu(I)-BTA Films on Copper electrodes and The Mechanism of Copper Corrosion Inhibition in Aqueous Chloride/benzotriazole Solutions[J]. Corrosion Science. 1994,36(11):1931~1349
[57] 陈刚,杨植震,郑成法. 某些杂环化合物对青铜的缓蚀作用[J]. 复旦学报
2>
(自然科学版). 1996,35(3):295~304
[58] 钟文英,郑朝华 光谱电化学研究α-巯基苯并噻唑对铜的缓蚀机理[J]. 无机化学学报 1999,15(6):756~760
[59] S.A.Abd El-Maksoud,A.A.El-Shafei,H.A.Mostafa et al Inhibition of copper corrosion in 1M nitric acid with benzoyl benzaldehyde hydrazone derivatives[J] Materials and Corrosion 1995(46) :468~472
[60] E.M.M.Sutter, F.Ammeloot, M.J.Pouet et al Heterocyclic compounds used as corrosion inhibitors :correlation between 13C and 1H NMR spectroscopy and inhibition efficiency[J]. Corrosion Science 1999(41):105~115
[61] 李风亭,张冰如. 2-巯基苯并噻唑在铜表面的吸附状态[J]. 腐蚀与防护 2002,23(8):343~345
[62] Y.C Wu, P.Zhang, H.W.Pickerring et al Effect of KI on Improving Copper Corrsion Inhibition Efficiency of Benzotriazole in Sulfuric[J]. J.Electrochem.Soc.,1993,140(10):2791~2800
[63] 罗胜联,陈金华,陈凡等. 卤素离子与苯并三氮唑协同成膜动力学的体声波传感技术研究[J]. 2002,29(1):52~57
[64] 徐群杰,刘小华,刘月丽等. Na2WO4和BTA复配对铜缓蚀性能的研究[J]. 腐蚀与防护. 2001,22(10)424~425
[65] 徐群杰,周国定,陆柱等. 复方钨酸盐对铜缓蚀协同作用的光电化学和SERS研究[J]. 化学学报. 2001,59(6):950~955
[66] 旷亚非,陈曙,林志成. 苯并三氮唑、2-巯基苯并噻唑协同缓蚀作用机理探讨[J]. 材料保护. 1994,27(8):11~15
[67] A.jaiswal, R.A.Sing, and R.S.Dubey. Inhibition of Copper Corrosion in Aqueous Sodium Chloride Solution by N-Octadacylbenzidine/1-Docosanol Mixed Langmuir-Blodgett Films[J]. Corrosion 2001,57 (4):307~312
[68] 查全性 电极过程动力学导论(第二版)[M] 北京:科学出版社 1987:162~163
[69] C C Chang, T C Wen Kinetics of oxygen reduction at RuO2-coated titanium electrode in alkaline solution[J]. Journal of Applied Electrochemistry 1997(27):355~360
[70] P.B.Mathur and T.Vausdevan Reaction rate studies for the corrosion of metals in acids-I,iron in mineral acids[J]. corrosion, 1982,38(3) :171~178
[71] G.Lewis. The Corrosion Inhibition of Copper by Benzimidazole[J]. Corrosion Science 1982,22(6):579~584
[72] R.Babic, M.Metikos-Hukovic. Spectroelectrochemical studies of protective surface films against copper corrosion[J]. Thin Solid Films 2000(359):88~94
[73] M.Metikos-Hukovic, K.Furic,R.Babic et al. Surface-enhanced Raman Scattering(SERS) of Benzotriazole Derivative Corrosion Inhibitor Prepared in Aqueous Media[J]. Surface and Interface Analysis 1999(27):1016~1025
[74] Gladius Lewis. Adsorption Isotherm for the Copper-Benzotriazole System[J]. J. British corrosion 1981,16 (3):169~171
[75] 张祖训, 汪尔康 . 电化学原理和方法[M]. 北京:科学出版社 2000:520～530
[76] 江逢霖等译 基础物理化学[M] 上海:复旦大学出版社 1992:111～129
[77] 程龙春 新型抗卤素铜缓蚀剂材料的开发研究[C] 2003: 117～129
[78] M.Metikos-Hukovic, R.Babic and I.Paic. Copper corrosion at various PH values with and the inhibitor[J]. Journal of Applied Electrochemistry 2000(30):617~624
[79] 王建祺、吴文辉、冯大明等 电子能谱学引论(第一版)[M] 北京:科学出版社1992:476~481
[80] Y.Feng, K.S.Siow, W.K.Teo et al Synergistic Effects Between Sodium Tripolyphosphate and Zinc Sulfate in Corrosion Inhibition for Copper in Neutral Tap Water[J]. Corrosion 1997,53(7):546~555
[81] W.Qagsoui, Ch.Blanc, J.Roques et al. Pitting corrosion in sulphate solutions: inhibitive effect of different triazole derivative inhibitors[J]. Journal of Applied Electrochemistry 2001(31):223~231
[82] 朱埗瑶、赵振国 界面化学基础[M]. 北京:化学工业出版社 1996:41～59
[2] R.Gasparac,C.R.Martin,and E.Stupnisek-Lisac In Situ Studies of Imidazole and Its Derivatives as Copper Corrosion Inhibitors[J]. Journal of The Electrochemical Society 2000,147(2):548～551
[3] E.Stupnisek-Lisac, A.Loncaric, and I.Cafuk Low-Toxicity Copper Corrosion Inhibitors[J]. CORROSION 1998,54(9):713～720
[4] 旷富贵,张传飞,姚禄安等. Cu电极上咪唑与苯并三唑共吸附的SERS研究[J]. 腐蚀科学与防护技术. 1997,9(2):126～127
[5] 史志龙,庞正智. 新型铜酸洗缓蚀剂烷基苯并咪唑的研究[J]. 北京化工大学学报. 2002,29(2):52～54
[6] E.Geler, D.S.Azambuja Corrosion inhibition of copper in chloride solutions by pyrazole[J]. Corrosion Science. 2000(42):631～643
[7] 张大全,高立新,周国定等. HCl溶液中巯基杂环化合物对铜的缓蚀作用[J]. 应用化学. 2002,19(6):535～538
[8] 章荣玲,杜爱玲,李廷芳. 2-十一烷基-1-(双硫脲)乙基-咪唑啉在铜表面上的成膜作用[J]. 山东师大学报. 1994,9 (4):36～39
[9] 陆嘉星,胡福建,宋丽萍等. 动电位法研究酸性溶液中CTAB对Cu的缓蚀作用[J]. 华东师范大学学报. 2000,2(2):65～68
[10] S.L.Li, H.Y.Ma, S.b.Lei et al Inhibition of copper corrosion with schhiff base derived from 3-methoxysalicyladehyde and o-phenyldiamine in chloride media[J]. Corrosion 1998,54(12):947～954
[11] E.Stupnisek-Lisac,A.Brnada,A.D.Mance Secondary amines as copper corrosion inhibitors in acid media[J]. Corrosion Science 2000(42):243～257
[12] L.Horner und E.Pliefke Inhibitoren der Korrosion 29 (1).Vergleichende Untersuchung weiterer Inhibitoren der Korrosion des Kupfers unter
Standardbedingungen[J]. Werkstoffe und Korrosion 1982(33):454～461
[13] L.Horner und E.Pliefke Inhibitors of corrosion 28(1).2-Aminopyrimidine(2-AP) as an inhibitor of the corrosion of copper in salt solutions under oxygen[J]. Werkstoffe und Korrosion1982(33):189～193
[14] M.M.El-Naggar Bis-aminoazoles. Corrosion inhibitors for copper in 4.0 M HNO3 solutions[J]. Corrosion Science.2000(42):773～784
[15] 于萍,罗运柏. 有机铜缓蚀剂研究现状与进展[J]. 化学清洗. 1999,15(1):31～37
[16] A.S.Fouda and A.K.Mohamed Substituted phenols as corrosion inhibitors or copper in nitric acid[J]. Werkstoffe und Korrosion 1988(39):23～26
[17] S.A.Abd El-Maksoud,A.A.El-Shafei,H.A.Mostafa et al Inhibition of copper corrosion in 1M nitric acid with benzoyl benzaldehyde hydrazone derivatives[J]. Materials and Corrosion 1995(46) :468～472
[18] Y.Ling, Y.Guan and K.N.Han. Corrosion Inhibiton of Copper with Benzotriazole and Other Organic Surfactants[J]. Corrosion. 1995,51 (5):367～375
[19] V.Otieno-Alego, N.Huynh, T.Notoya et al. Inhibitive effect of 4- and 5-carboxybenzotriazole on copper corrosion in acidic sulphate and hydrogen sulphide solutions[J]. Corrosion Science 1998(41):685～697
[20] N.Huynh, S.E.Bottle, T.Notoya et al Inhibitive action of the octyl estrs of 4- and 5-carboxybenzotriazole for copper corrosion in sulphate solutions[J]. Corrosion Science 2000(42):259～274
[21] D.P.Schweinsberg, S.E.Bottle, V.Otieno-Alego. A near-infrared FT-Raman(SERS) and electrochemical study of the synergistic effect of 1-[(1’,2’-dicarboxy)ethyl-benzotriazole and KI on the dissolution of copper in aerated sulfuric acid[J]. Journal of Applied Electrochemistry 1997(27):161～168
[22] Gamal K.Gomma. Effect of azole compounds on corrosion of copper in acid medium[J]. Materials Chemistry and Physics 1998(56):27～34
[23] G.Quartrarone, A.Zingales, T.Bellomi et al Study of inhibition mechanism and efficiency of indole-5-carboxylic acid on corrosion of copper in aerated 0.5M H2SO4[J]. British Corrosion Journal. 2000,35(4):304～310
[24] J.M.Bastidas and E.Otero A comparative study of benzotriazole and 2-amino-5-mercapto-1,3,4-thiadiazole as copper corrosion inhibitors in acid media[J]. Materials and Corrosion 1996(47):333～337
[25] 傅海涛,李瑛,魏无际等. AMT在青铜-柠檬酸体系中的缓蚀行为及其机理[J]. 物理化学学报. 2001,17(7):604～608
[26] G.P.Cicileo, B.M.Rosales, F.E.Varela, et al Comparative study of roganic inhibitors of copper corrosion[J]. Corrosion Science.1999(41):1359～1375
[27] G.P.Cicileo, B.M.Rosales, F.E.Varela et al Inhibitory Action of The Ccopper Corrosion Process[J] Corrosion Science 1998,40(11):1915～1926
[29] Fabrizo Zucchi, Micaela Fonsati and Giordano Trabanelli. Influence of The Heat Exchange on The Inhibiting Efficiency of Some Heterocyclic Derives Against Copper Corrosion in 3.5% NaCl Solutions[J]. Corrosion Science 1998,40(11):1927～1937
[29] 张大全,徐群杰,陆柱. 苯并三唑和咪唑分子内缓蚀协同作用的研究[J]. 中国腐蚀与防护学报. 1999,19(5):280～284
[30] 高立新,张大全,陆柱等. 含苯并三唑和噻二唑单元的铜缓蚀剂制备和缓蚀作用[J]. 华东理工大学学报 2001,27(1):84～88
[31] 严川伟,林海潮,曹楚南等. 2-巯基苯并恶唑(MBO)在铜表面缓蚀膜研究[J]. 中国腐蚀与防护学报. 1999,19(6):368～370
[32] 陈刚,杨植震,郑成法. 某些杂环化合物对青铜的缓蚀作用[J]. 复旦学报(自然科学版). 1996,35(3):295～304
[33] R.Tremont, H.De.Jesus-Cardona, J.GarciaARCIA-Orozco et al. 3-Mercaptopropyltrimethoxysilane as a Cu corrosion inhibitor in KCl solution[J]. Journal of Applied Electrochemistry 2000(30):737～743
[34] G..Petkova,P.Lvanov,E.Sokolva et al Inhibiting Action of α-
yrophthalone in Copper Corrosion[J], Werkstoffe und Korrosion 1993(44):187～192
[35] 朱一帆,李大刚,施兵兵等. AMT保护青铜的研究[J]. 材料保护. 1998,31(5):3～5
[36] 甘复兴,戴忠旭,汪的华等. 中性介质中铜缓蚀剂的成膜过程[J]. 应用化学. 1998,15(4):45～48
[37] 扈显琦,彭乔,张明嘉. 海水中铜缓蚀剂研究[J]. 四川化工与腐蚀控制. 1999 ,2(3):4～8
[38] 童泉玉,陈号卫,杨从贵等. 羧酸类铜缓蚀剂的制备及性能测试[J]. 材料保护. 2001,34(3):49～50
[39] G.Lewis. The corrosion inhibition of copper by benzomidazole[J]. Corrosion Science. 1982,22(6):579～584
[40] Y.Feng, K.S.Siow, W.K.Teo et al. Synergistic Effects Between Sodium Tripolyphosphate and Zinc Sulfate in Corrosion Inhibition for Copper in Neutral Tap Water[J]. Corrosion. 1997,53(7):546～555
[41] E.Guilminot, J-J.Rameau, F.Dalard et al. Benzotriazole as inhibitor for copper with and without corrosion products in aqueous polyethylene glycol[J]. Journal of Applied Electrochemistry 2000(30):21～28
[42] W.Qagsaoui, Ch.Blanc, J.Roques et al. Pitting corrosion in sulphate solutions: inhibitive effect of different triazole derivative inhibitors[J]. Journal of Applied Electrochemistry 2001(31):223～231
[43] W.Qafsoui, Ch.Blanc, N.Pebere et al. Study of different triazole derivative inhibitors to protect copper against pitting corrosion[J]. Journal of Applied Electrochemistry 2000(30):959～966
[44] 旷亚非,陈曙,林志成. 2-巯基苯并噻唑对NaCl溶液中铜的缓蚀行为[J]. 中国腐蚀与防护学报 1995,15(2):129～133
[45] S.Sankarapapavinasam, M.F.Ahed. Benzenethiols as inhibitors for the corrosion of copper[J]. Journal of Applied Electrochemistry 1992(22):390～395
[46] E.Otero and J.M.Bastidas Study of two new aqueous alkaline copper
cleaning solutions and comparison with a conventional bath[J]. Werkstoffe und Korrosion 1996(47):511～515
[47] 黄乃宝,梁成浩. 高温高浓度溴化锂溶液中磷脱氧铜耐蚀性能研究[J]. 大连理工大学学报. 2001,41(6):667～670
[48] K.P.Fitzgerald, J.Nairn and A.Atrens. The Chemistry of Copper Patination[J]. Corrosion Science. 1998,40 (12):2029～2050
[49] M.Fleischmann, I.R.Hill, G.Mengoli et al. The synergetic effct of benzylamine on the corrosion inhibition of copper by benzotriazole[J]. Ekectrochimica Acta 28(10):1325~1333
[50] P.G.Fox, G.Lewis, P.J.Boden. Some chemical aspects of the corrosion inhibition of copper by bentriazole[J]. Corrosion science 1979(19):457~467
[51] M.Metikos-Hukovic,K.Furic, R.Babic et al. Surface-enhanced Raman Scattering(SERS) of Benzotriazole Derivative Corrosion Inhibitor Prepared in Aqueous Media[J]. Surface and Interface Analysis 1999(27):1016～1025
[52] O.H.ollander and R.C.May. The chemistry of azole copper corrosion inhibitors in cooling water[J]. corrosion 1985,41(1), 39~45
[53] R.Babic, M.Metikos-Hukovic. Spectroelectrochemical studies of protective surface films against copper corrosion[J]. Thin Solid Films 2000(359):88~94
[54] P.G..Fox, G..Lewist and P.J.Boden. Some Chemical Aspects of The Corrosion Inhibitor of Copper by Benztriazole[J]. Corrosion Science.1979,19 (7):457~468
[55] 旷亚非,陈曙,林志成. 苯并三氮唑、2-巯基苯并噻唑协同缓蚀作用机理探讨[J]. 材料保护. 1994,27(8):11~15
[56] A.D.Modestov, G..D.Zhou, Y.P.Wu et al. A Study of The Electrochemical Formation of Cu(I)-BTA Films on Copper electrodes and The Mechanism of Copper Corrosion Inhibition in Aqueous Chloride/benzotriazole Solutions[J]. Corrosion Science. 1994,36(11):1931~1349
[57] 陈刚,杨植震,郑成法. 某些杂环化合物对青铜的缓蚀作用[J]. 复旦学报
(自然科学版). 1996,35(3):295~304
[58] 钟文英,郑朝华 光谱电化学研究α-巯基苯并噻唑对铜的缓蚀机理[J]. 无机化学学报 1999,15(6):756~760
[59] S.A.Abd El-Maksoud,A.A.El-Shafei,H.A.Mostafa et al Inhibition of copper corrosion in 1M nitric acid with benzoyl benzaldehyde hydrazone derivatives[J] Materials and Corrosion 1995(46) :468~472
[60] E.M.M.Sutter, F.Ammeloot, M.J.Pouet et al Heterocyclic compounds used as corrosion inhibitors :correlation between 13C and 1H NMR spectroscopy and inhibition efficiency[J]. Corrosion Science 1999(41):105~115
[61] 李风亭,张冰如. 2-巯基苯并噻唑在铜表面的吸附状态[J]. 腐蚀与防护 2002,23(8):343~345
[62] Y.C Wu, P.Zhang, H.W.Pickerring et al Effect of KI on Improving Copper Corrsion Inhibition Efficiency of Benzotriazole in Sulfuric[J]. J.Electrochem.Soc.,1993,140(10):2791~2800
[63] 罗胜联,陈金华,陈凡等. 卤素离子与苯并三氮唑协同成膜动力学的体声波传感技术研究[J]. 2002,29(1):52~57
[64] 徐群杰,刘小华,刘月丽等. Na2WO4和BTA复配对铜缓蚀性能的研究[J]. 腐蚀与防护. 2001,22(10)424~425
[65] 徐群杰,周国定,陆柱等. 复方钨酸盐对铜缓蚀协同作用的光电化学和SERS研究[J]. 化学学报. 2001,59(6):950~955
[66] 旷亚非,陈曙,林志成. 苯并三氮唑、2-巯基苯并噻唑协同缓蚀作用机理探讨[J]. 材料保护. 1994,27(8):11~15
[67] A.jaiswal, R.A.Sing, and R.S.Dubey. Inhibition of Copper Corrosion in Aqueous Sodium Chloride Solution by N-Octadacylbenzidine/1-Docosanol Mixed Langmuir-Blodgett Films[J]. Corrosion 2001,57 (4):307~312
[68] 查全性 电极过程动力学导论(第二版)[M] 北京:科学出版社 1987:162~163
[69] C C Chang, T C Wen Kinetics of oxygen reduction at RuO2-coated titanium electrode in alkaline solution[J]. Journal of Applied Electrochemistry 1997(27):355~360
[70] P.B.Mathur and T.Vausdevan Reaction rate studies for the corrosion of metals in acids-I,iron in mineral acids[J]. corrosion, 1982,38(3) :171~178
[71] G.Lewis. The Corrosion Inhibition of Copper by Benzimidazole[J]. Corrosion Science 1982,22(6):579~584
[72] R.Babic, M.Metikos-Hukovic. Spectroelectrochemical studies of protective surface films against copper corrosion[J]. Thin Solid Films 2000(359):88~94
[73] M.Metikos-Hukovic, K.Furic,R.Babic et al. Surface-enhanced Raman Scattering(SERS) of Benzotriazole Derivative Corrosion Inhibitor Prepared in Aqueous Media[J]. Surface and Interface Analysis 1999(27):1016~1025
[74] Gladius Lewis. Adsorption Isotherm for the Copper-Benzotriazole System[J]. J. British corrosion 1981,16 (3):169~171
[75] 张祖训, 汪尔康 . 电化学原理和方法[M]. 北京:科学出版社 2000:520～530
[76] 江逢霖等译 基础物理化学[M] 上海:复旦大学出版社 1992:111～129
[77] 程龙春 新型抗卤素铜缓蚀剂材料的开发研究[C] 2003: 117～129
[78] M.Metikos-Hukovic, R.Babic and I.Paic. Copper corrosion at various PH values with and the inhibitor[J]. Journal of Applied Electrochemistry 2000(30):617~624
[79] 王建祺、吴文辉、冯大明等 电子能谱学引论(第一版)[M] 北京:科学出版社1992:476~481
[80] Y.Feng, K.S.Siow, W.K.Teo et al Synergistic Effects Between Sodium Tripolyphosphate and Zinc Sulfate in Corrosion Inhibition for Copper in Neutral Tap Water[J]. Corrosion 1997,53(7):546~555
[81] W.Qagsoui, Ch.Blanc, J.Roques et al. Pitting corrosion in sulphate solutions: inhibitive effect of different triazole derivative inhibitors[J]. Journal of Applied Electrochemistry 2001(31):223~231
[82] 朱埗瑶、赵振国 界面化学基础[M]. 北京:化学工业出版社 1996:41～59