脱硫石膏对碱化土壤改良的研究
详细信息    本馆镜像全文|  推荐本文 |  |   获取CNKI官网全文
摘要
盐碱土是地球广泛分布的一种土壤类型,约占陆地总面积的25%,总计约10亿公顷。我国约有盐碱地0.27亿公顷,盐碱地分布广泛,土壤含盐量高,盐份主要以氯化物为主,结构性差,肥力低,极大地限制了土地资源的有效利用。随着我国经济的持续发展,以及国家对“两控区”(酸雨控制区和二氧化硫控制区)内燃煤电厂烟气脱硫计划的实施,脱硫石膏的产量也将持续上升。作为煤燃烧产物,脱硫石膏的综合利用,不仅可以减少燃煤电场脱硫产物的堆放场地,减少二次污染,而且可以减少天然石膏的开采量,保护天然石膏资源,增加脱硫石膏产品销售额,符合我国可持续发展战略和循环经济理念,具有重要的现实意义。
     通过分析在不同脱硫副产物施用量下土壤理化性质的变化规律,对脱硫副产物改良碱化土壤进行理论研究,探寻改良碱化土壤的优化利用模式。采用宁夏银川和鄂尔多斯的四种土样,每种土样分别加入四个水平(即施用量为0.5wt%、1.0wt%、1.5wt%、2.0wt%)的脱硫副产物,观察其改良效果。研究结果表明,脱硫副产物能降低土壤pH和碱化度,改善土壤理化性质,从而达到改良碱化土壤的作用;碱化土壤的改良效果在一定的范围内(0~2.0wt%)与脱硫副产物的用量呈正相关,超过这一范围,不但不能提高改良效果,而且还会有大量的盐分累积,增加改良的难度;脱硫副产物改良碱化土壤的最佳用量范围为0.5wt%~1.0wt%。
The saline soil that is an important land resource extensively distributed on the earth, it's area total about 1 billion hectares, which is about 25 percent of land area. There is approximately 27 million ha saline-alkali soil land in our country. The saline soil is distributed extensively, which the main salt content is the chloride, the structural property and fertility is poor, Therefore it is difficult to increase agricultural production.Along with continuous and rapid development of Chinese economy, as well as implementing of the project of flue gas desulfurization(FGD)of coal-burning powerplants in "Twain Control Zone"-the zone of acid rain controlling and the zone of sulfur dioxide(SO_2)controlling, the outputs of FGD gypsum is going to rise continuously. As coal combuistion products, multipurpose use of FGD gypsum, it not only reduce the mining quanlity of nature gypsum and pertect the natural gypsum resource, increase the saleroom of FGD gypsum products, answer for sustainable development stratagem of China, and it possesses important real significance.
     The change of soil physical and chemical properties with different amount of by-product from flue gas (FGD) applied is researched .The effect of sodic soils reclamation was investigated using by-product from FGD and searched for the optimal quantity of soil amendment due to the improvement of sodic soils. The effect of soil reclamation was observed by using four soil samples from Yinchuan of Ningxia and Ordos of Inner Mongolia at four levels (i.e. the amount of by-product from FGD is 0.5wt%, 1.0wt%, 1.5wt%, and 2.0 wt%). As a result, soil pH and ESP decreased and this result indicates that by-product from FGD has the effect of improving sodic soil physical and chemical properties. In the certain range (0~2.0 wt%), the amelioration effect of sodic soil presents positive correlation with the applied amount of by-product from FGD. If the amount exceeds the range, the better effect of the soil reclamation could not be attained and a great deal of salt will be accumulated in soil and it will be more difficult to improve the sodic soil. In terms of this experiment result, the optimum range of applied amount is 0.5wt%~1.0wt%.
引文
[1]王金满,杨培岭,石懿,等.脱硫副产物对改良碱化土壤的理化性质与作物生长的影响[J].水土保持学报,2005,19(3):34-37.
    [2]祁晨华,吕志远,杨培岭,等.脱硫副产物改良碱化土壤综述[J].内蒙古农业大学学报,2007,28(1):201-203.
    [3]王方群,原永涛,齐立强.脱硫石膏性能及其综合利用[J].粉煤灰综合利用,2004,(1):41-44.
    [4]Frenke H,Gerstle Z,Alperovitch N.Exchange-induced dissolution of gypsum and the reclamation of sodic soils[J].Soil Science,1989,(40):599-611.
    [5]白由路,李保国,石元春.基于GIS的黄淮海平原土壤盐分分布与管理研究[J].资源科学,1997,2(4):66-70.
    [6]Clark R B.Growth of forages legumes and grasses in acidic soil amended with flue gas desulfurization products[J].Communications in Soil Science and Plant Analysis,2003,34(1/2):157-180.
    [7]Crews J T.Liming acid forest soils with flue gas desulfurization by-product:growth of Northern red oak and leach ate water quality[J].Environmental Pollution,1998,103(1):55-61.
    [8]Chun S,Nishiyama M,Matsumoto S.Sodic soils reclaimed with by-product from flue gas desulfurization:corn production and soil quality[J].Environmental Pollution,2001,114(1):453-459.
    [9]Yuji Sakai,Satoshi Matsumoto,Yoshitaka Nitta,et al.Alkali soil reclamation in China using gypsum produced in flue gas desulfurization process[J].Journal of Global Environment Engineering,2002,8(11):55-66.
    [10]Yuji Sakai,Satoshi Matsumoto,Masayoshi Sadakata.Alkali soil reclamation with flue gas desulfurization gypsum in China and assessment of metal content in corn grains [J].Soil and Sediment Contamination,2004,13(1):65-80.
    [11]Chartres C J,Greene R S,Ford G W,et al.The effect of gypsum on macro porosity and crusting of two red duplex soils[J].Soil Research,1985,23:467-479.
    [12]Wu L G,Zhao J H.The study of the physical and chemical processes in improvement of sodic soil with gypsum The Inner Mongolia Agriculture university master's degree paper[D].Inner Mongolia Agriculture University,2001.
    [13]Iyas M,Miller R W,Qureshi R H.Hyudraulic conductivity of saline-soil after gypsum application and cropping soil[J].Science Society of America Journal,1993,57(6):1580-1585.
    [14]Batra L,Kumar A,Manna M C,et al.Microbiological and chemical amelioration of alkaline soil by growing Kamal grass and gypsum application[J].Experiment Agriculture,1997,33(4):389-397.
    [15]孙毅,高玉山,闫孝贡,等.石膏改良苏打盐碱土研究[J].土壤通报,2001,97:97-98.
    [16]Lebron I,Suarez D L,Yoshida T.Gypsum effect on the aggregate size and geometry of three sodic soils under reclamation[J].Soil Science Society of America Journal.2002,66(1):92-98.
    [17]巴逢辰,赵羿.中国海涂土壤资源[J].土壤学报,1997,28(2):49-51.
    [18]李建东,郑慧莹.松嫩平原盐碱化草地治理及其生物生态机理,北京:科学出版社,1997.
    [19]王遵亲.中国盐渍土,北京:科学出版社,1993.
    [20]黑龙江土地管理局.黑龙江土壤.哈尔滨:哈尔滨农业出版社,1992.
    [21]赵可夫,李法曾.中国盐生植物.北京:科学出版社,1999.
    [22]王春娜,宫伟光.盐碱地改良的研究进展[J].防护林科技,2004,(5):38-41.
    [23]郑慧莹,李建东.松嫩平原的草地植被及其利用保护,科学出版社,1993.
    [24]阎秀峰,孙国荣.星星草生理生态学研究,北京:科学出版社,2000.
    [25]任继周,朱兴运.河西走廊盐碱地的生物改良与优化生产模式,科学出版社,1998.
    [26]克脑夫公司:Heiner HAMM著.排烟脱硫石膏的应用:欧洲石膏工业的任务[J].建筑人造板,1998,(1):40-41,43.
    [27]Davina White.世界石膏生产应用及其前景[J].江苏地矿信息,1998,(4):43-44.
    [28]张荫济,徐强,叶蓓红,等.湿法“石灰石—石膏”烟气脱硫(FGD)技术及烟气脱硫石膏应用的分析研究[J].粉煤灰,2003(2):22-24.
    [29]张方,马彦涛,胡将军,等.国内外火电厂烟气脱硫石膏的特点利用及处置[J].粉煤狄综合利用,2003(4):50-51.
    [30]陈云嫩.烟气脱硫副产物的综合利用[J].环境科学技术,2003,23(6):43-45.
    [31]从钢,邢世健,张沪.脱硫石膏性能研究[J].新型建筑材料,1997,(12):10-12.
    [32]李阳,周保卫.以脱硫石膏为早强剂的混凝土凝胶材料[P].中国专利:CN1640845,2005-07-20.
    [33]吴忠标,吴晓琴,程常杰,等.常压盐溶液法制取α-半水脱硫石膏工艺[P].中国专利:CN1513766,2004-07-21.
    [34]卢忠远,方荣利,腾元成,等.化工石膏陶瓷[P].中国专利:CN1066438,1992-11-25.
    [35]许兴富.一种高强耐水石膏空心条板[P].中国专利:CN1188087,1998.07-22.
    [36]Eyal,Aharon Meir.Process for the preparation of fertilizers and sulfur compounds[P],USP6,344,066,February 5,2002.
    [37]Piasecki,Robert J,Kingston,et al.Method and apparatus for continuously calcining gypsum[P],USP6,083,465.July4,2000.
    [38]Weyand,Thomas E,Koshinski,et al.Methord of making building blocks from coal combustion waste and related products[P],USP6,068,803,May 30,2000.
    [39]Kroehl,Paul,Lindner,et al.Methord for calcinning moist gypsum[P],USP 5,437,850,August 1,1995.
    [40]孙步,尹维新,刘红宇.脱硫石膏对低质粉煤灰的活性影响研究[J].粉煤灰综合利用,2006(8):21-23.
    [41]Clark,Ralph B.Growth of forages on acid soil amended with flue gas desulfurization by-products[J].Fuel,1997,76(8):771-775.
    [42]Wendell R R.High-calcium flue gas desulfurization products reduce aluminum toxicity in an Appalachian soil[J].Journal of Environment Quality,1996,25(6):1401-1410.
    [43]Stout W L.Use of flue gas desulfurization(FGD) by-product gypsum on alfalfa[J].Communications in Soil Science and Plant Analysis,1996,27(9/10):2419-2432.
    [44]Chen L W A,Dick S Nelson.Flue gas desulfurization by-products additions to acid soil:alfalfa productivity and environment quality[J].Environ Pollute,2001,114(2):161-168.
    [45]Stehouwer R C,SuRon P,Dick W A.Transport and plan t upmke of soil-applied dry flue gas desufufizafion by-products[J].Soil Science,1996,161:562-574.
    [46]徐胜光,李淑仪,蓝佩玲,等.燃煤烟气脱硫副产物对花生作物营养效应及其机理[J].生态环境,2003,12(4):415-418.
    [47]徐胜光,李淑仪,蓝佩玲,等.燃煤烟气脱硫副产物对萝卜营养的作用及其机理研究[J].生态科学,2003,22(3):232-236.
    [48]徐胜光,李淑仪,蓝佩玲,等.燃煤烟气脱硫副产物用于桉树的效果及机理[J].浙江林学院学报,2004,21(1):15-21.
    [49]李淑仪,蓝佩玲,徐胜光等.燃煤烟气脱硫副产物在酸性土壤的农业资源化利用[J].生态科学,2003,22(3):222-226.
    [50]李淑仪,蓝佩玲,徐胜光,等.燃煤烟气脱硫副产物在酸性土壤上施用的效果[J].生态环境,2003,12(3):263-268.
    [51]徐胜光,蓝佩玲,廖新荣,等.燃煤烟气脱硫副产物的重金属环境行为[J].生态环境,2005,14(1):38-42.
    [52]吕二福良,乌力更.石膏不同施用方法改良碱化土壤效果浅析[J].内蒙古农业大学学报,2003,24(4):130-133.
    [53]Choudharya O P,Josana A S,Bajwaa M S,et al.Efect of sustained sodic and saline-sodic irrigation andapplication of gypsum an d farmyard manure on yield and quality of sugarcan e under semi-arid conditions[J].Field Crops Research,2004,(87):103-116.
    [54]Qadir M,Qureshi R H,Ahmad N.Reclamation of a saline-sodic soil by gy psum and Leptochloa fusca[J].Geoderma,1996,(74):207-217.
    [55]R B Clark,K D Ritchey,V C Baligar.Benefits and constraints for use of FGD products on agricultural land[J].Fuel,2001,(80):821-828.
    [56]S Chun,M Nishiyama,S Matsumoto.Sodic soils reclaimed with by-product from flue gas desulfurization,corn production and soil quality[J].Environmental Pollution,2001,(114):453-459.
    [57]Matsumoto S.Distribution and amelioration of alkali soils in northeast China.In:Challenge of Plant and Agricultural Sciences to the Crisis of Biosphere on the Earth in the 21 st Century,Proceeding of the Toyota Conference,12th,Shizuoka,Japan,1998:113-121.
    [58]王金满,杨培岭,任树梅,等.烟气脱硫副产物改良碱性土壤过程中化学指标变化规律的研究[J].土壤学报,2005,42(1):98-105.
    [59]李焕珍,徐玉佩,杨伟奇,等.脱硫石膏改良强度苏打盐渍土效果的研究[J].生态学杂志,1999,18(1):25-29.
    [60]Sloan J J,Dowdy R H,Rehm G W.Plant and soil responses to field-applied flue gas desulphurization residue[J].Fuel,1999,78:169-174.
    [61]Mace J E,Amrhein C,Oster J D.Comparison of Gypsum and Sulfuric Acid for Sodic Soil Reclamation[J].Arid Soil Research and Rehabilitation,1999,13:171-188.
    [62]陈欢,王淑娟,陈昌和,等.烟气脱硫废弃物在碱化土壤改良中的应用及效果[J].干旱地区农业研究,2005,23(4):38-42.
    [63]李晓娜,张强,陈明昌,等.不同改良剂对苏打碱土磷有效性影响的研究[J].水土保持学报,2005,19(1):71-74.
    [64]詹尼著,李孝芳译.土壤资源的起源与性状[M].北京:科学出版社,1988:394-399.
    [65]高斯塔耶夫著,杨景辉译。盐渍土改良[M].上海:上海科学技术出版社,1964:25-31.
    [66]Loveday J.Relative significance of electrolyte and cation exchange effects when gypsum is applied to a sodic clay Ⅱ[J].Soil Research,1976,14:361-371.
    [67]安基波夫-卡拉塔耶夫.碱土改良中的物理化学研究[M].北京:科学出版社,1958:412-430.
    [68]卡庆斯基,安基波夫.苏联土壤科学研究的最新进展[M].北京:科学出版社,1958:421-437.
    [69]李述刚,王周琼.荒漠碱土.乌鲁木齐:新疆人民出版社,1988.
    [70]凯莱W P.盐碱土.北京:科学出版社,1959:2-10.
    [71]Frenkel H.Effect of exchangeable gypsum on sodic soil reclamation[J].The Journal of Soil Science,1989,2(3):165-177.
    [72]Russo D,Bresler E.Effect of mixed Na/Ca solutions on the hydraulic properties of unsaturated soils[J].Soil Science,1977,41:713-717.
    [73]Valles V.The research for quality of gypsum on sodic soil reclamation[J].Arid Soil Research andreha-bilatation,1989,2(3):165-177.
    [74]Hussain G.There is no gypsum in saline and sodic soil on soil reclamation[J].Arid Soil Research andReha-bilatation,1988,2(1):29-47.
    [75]Etshout V D.低品位石膏在钠质土壤改良上的适用性:实验室试验[J].Soil Seienee.1990,149(4):228-234.
    [76]Li S Y,Lan P L,Xu S G,et al.A preliminary study on agricultural utilization of desulphurised byproducts on acid soil[J].Chinese Journal of Soil Science,2004,(35):441-448.
    [77]Xu S G,Lan P L,Liao X R,et al.Study on the environmental behaviors of heavy metals in desulfurization byproduct[J].Ecology and Environment,2005,(14):38-42.
    [78]桑以琳.内蒙古河套区碱(化)土壤的发生原因和特性[J].土壤学报,1996,(11):398-404.
    [79]俞仁培,杨道平.土壤碱化及其防治[M].北京:农业出版社,1984-172-173.
    [80]程发良,常慧.环境保护基础[M].北京:清华大学出版社,2002.

© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号

地址:北京市海淀区学院路29号 邮编:100083

电话:办公室:(+86 10)66554848;文献借阅、咨询服务、科技查新:66554700