我国电气石资源潜力分析及综合开发利用研究
|
摘要
电气石是一种可供利用的天然非金属矿产资源,也是一种极为重要的新型功能矿物材料。因电气石存在自发电极,在其微粒周围存在静电场现象、能发射远红外线、释放负离子等可供开发利用的特性,所以,电气石的开发利用已成为21世纪新型功能矿物材料研发热点之一。虽然我国电气石矿产资源很丰富,但对可供利用电气石资源储量、分布等情况还不甚清楚,针对电气石矿物特性的应用基础理论和综合利用研究起步较晚,特别是电气石在农业上的应用研究及产品开发还是空白。
本论文运用地质、生物和材料等多学科知识及前沿理论,对我国电气石的矿床特征、时空分布、成矿规律及国内外电气石资源及开发利用状况开展了系统研究和总结,并通过大量的实验研究,成功研制出电气石复合硼肥制作技术和工艺,申请并获得发明专利授权。论文的主要研究成果及创新性认识体现在以下几个方面:
1、全面分析总结了我国电气石矿床的形成和分布规律。首次根据成矿作用、成矿方式、成矿物质来源及时空分布特点将我国电气石矿床划分为:花岗伟晶岩型、岩浆热液型、火山—次火山(热液)型、热水沉积型和表生沉积型五种类型,并对各类型矿床的特征进行了阐述;通过实地调研并充分利用现有资料,结合我国大地构造特点,编制了我国第一张1:400万的《中国电气石矿产资源分布图》。
2、以硼元素含量为参数,以不同产地的电气石为研究对象,以现代先进测试技术(电子探针、能谱、扫描电镜、X射线衍射、ICP光谱等)为手段,以理论和实测数据为基础,首次对不同种类、不同产地电气石的含硼情况,进行了分析、对比研究,研究结果不仅印证了电气石理论上含硼高的特点,还为我国含硼高的电气石的利用打下良好基础。尤其是本文实验选用的江西白云山电气石,其B含量达到3.43%(B_2O_3含量为11.06%),含硼量较高,具有较好的代表性。
3、通过对国内外电气石开发利用现状的全面研究,提出将电气石应用于农业生产的意义、设想及开发前景;并通过对我国土壤含硼和耕地缺硼情况以及硼元素作用于农作物的生理机制及效用的深入探讨,结合我国硼肥资源紧缺现状,首次提出了利用电气石独特的物理性质和含硼高的化学特性,替代硼砂用于制作电气石硼肥的思路。
4、通过深入的理论和实验研究,首次提出了以高温焙烧法和化学法(添加酸、碱活化剂)相结合的电气石活化处理法,有效地将硼从电气石晶体结构中分离并溶于水而被农作物吸收;根据溶硼效果、经济性、安全性及环保性等因素综合选定用Na_2CO_3作为化学活化剂效益最大,并有利于产业化生产。
5、创立了将活化处理的电气石粉与未经处理的电气石粉混匀制成高活性电气石硼肥的硼肥制作方法,充分利用了电气石含硼高的化学特征和独特的物理性质,使电气石硼肥除具有一般硼肥的功效外,还具有抗土壤氧化、刺激植物生长,并能吸附土壤中的部分重金属及残留农药,净化植物生长环境等环保特性;并根据需要在高活性硼肥中加入其它农作物所需的有关元素及矿物原料,制备不同功能的电气石复合肥料的最佳配方及工艺流程等创新性成果。
6、本文研究成果已于2008年4月23日获得中国发明专利证书(专利号为:ZL200610021331.9,专利名称为“电气石活化处理方法及用该方法制备的高活性电气石硼肥”)。
As a kind of natural nonmetallic mineral resource that can be applied to daily life, tourmaline is also a very important new type of functional mineral material. Considering the characteristics as its spontaneous electrode, electrostatic field around its particles, emitting far infrared ray, releasing anion etc. that can be developed and utilized, the development and utilization of tourmaline has been one of the hot spots about studying new type of functional mineral materials in 21st century. China is very rich in tourmaline resources; however, the tourmaline reserves that can be used and the distribution in China are still questions, and the research about basic theory of application and comprehensive utilization of tourmaline mineral features was focused on too late, especially the application study and products exploitation for agriculture is still blank in China.
By applying lots of subjects including geological, biological and material science as well as frontier theories, the study has systematically studied and concluded the following factors about Chinese tourmaline, that are the characteristics of tourmaline deposits, temporal and spacial distribution, ore-forming regularity, the tourmaline resources in China and other countries and the exploitation with utilization status. Through a large amount of experimental research, the study has successfully worked out the manufacturing techniques and crafts about tourmaline compound boron fertilizer with the patent being authorized. The main research fingings and creative cognition of the study are presented as follows:
1. The study has comprehensively analyzed and concluded the formation and distribution regularities of tourmaline in China. This is the first time that Chinese tourmaline deposits have been classified into five types as granite pegmatite-host deposits, magmatic hydrothermal deposits, volcanic-subvolcanic (hydrothermal) deposits, hot water sediment-host deposits and supergene sediment-host deposits according to the ore-forming processes, ore-forming patterns, ore-forming matters sources and the temporal and spacial distribution characters of tourmaline resources in China, with the characteristics of each kind of deposits being expounded in the paper. Based on the field survey and existing data about tourmaline resources, combined with the tectonic characteristics of China, the study has worked out the first map as Tourmaline mineral resources distributed in China in the scale of 1:4,000,000.
2. Taking boron concentration as the major parameter, with kinds of tourmalines from different places as studying objects, using advanced modern testing technology (electro probe, energy spectrum, SEM, X-ray diffraction, ICP spectrum and so on) as testing methods, on the basis of theoretical and testing data, the paper has analyzed and comparatively studied the boron concentrations contained by different kinds of tourmalines that are from different places. The studying results have not only confirmed that tourmaline has high boron concentration, but also built a favorable foundation for the application of tourmaline resources with high boron concentration in China. The boron concentration contained by tourmalines chosen as testing samples from Baiyunshan in Jiangxi is even reached 3.43% (B_2O_3 concentration as 11.06%). Since the Baiyunshan tourmaline has high boron concentration, it may be better tourmalines at present in China.
3. Through overall study about the development and utilization of tourmaline resources in China and other countries, the paper has proposed the significance, imagination and exploitation foreground about applying tourmalines to agriculture. In addition, considering the shortage of boron fertilizer in China, the paper has first put forward the idea of using tourmaline to replace borax and manufacture boron fertilizer by utilizing particular physical properties of tourmaline and its chemical properties of high boron concentration, through deep discussing about boron-bearing status and boron-lacking status of Chinese soil, and the physiological mechanism and effects about how boron element affecting crops.
4. Through deep research of theories and experiments, the study has first proposed the treatment of activating tourmaline with calcinations and chemical methods ( eg. adding acid or alkali activator ) being combined, which will effectively separate boron from tourmaline crystal structure and make it dissolved in water to be absorbed by crops. According to boron solution effect, economic factors, safety, and environmental protection consideration, etc., the study has chosen Na_2CO_3 as chemical activator because of the maximum benefit, and its character of being favorable to industrializing production.
5. The study has also create a boron fertilizer manufacturing method by mixing tourmaline powder treated by activating and tourmaline powder without any treatment to form highly active tourmaline boron fertilizer. This method has fully utilized the chemical property of high boron concentration and particular physical property of tourmaline, and not only made tourmaline boron fertilizer had virtues of general boron fertilizer, but also bring the environmental protection characters including antioxidation of soil, promoting the growth of plants, absorbing a part of heavy metals and pesticide residues, as well as purifying plants' growing environment to tourmaline boron fertilizer. Moreover, the study has also worked out the best prescription and technic with other creative fruits about how to manufacture different compound tourmaline fertilizer with different function by adding related elements and mineral materials that are required by crops to high active fertilizer.
6. The studying achievement described in the paper has already gained Chinese invention patent on April.23rd of 2008 (Patent Number: ZL200610021331.9, Patent Name: Tourmaline activating treatment and high active tourmaline boron fertilizer manufactured by this method.).
本论文运用地质、生物和材料等多学科知识及前沿理论,对我国电气石的矿床特征、时空分布、成矿规律及国内外电气石资源及开发利用状况开展了系统研究和总结,并通过大量的实验研究,成功研制出电气石复合硼肥制作技术和工艺,申请并获得发明专利授权。论文的主要研究成果及创新性认识体现在以下几个方面:
1、全面分析总结了我国电气石矿床的形成和分布规律。首次根据成矿作用、成矿方式、成矿物质来源及时空分布特点将我国电气石矿床划分为:花岗伟晶岩型、岩浆热液型、火山—次火山(热液)型、热水沉积型和表生沉积型五种类型,并对各类型矿床的特征进行了阐述;通过实地调研并充分利用现有资料,结合我国大地构造特点,编制了我国第一张1:400万的《中国电气石矿产资源分布图》。
2、以硼元素含量为参数,以不同产地的电气石为研究对象,以现代先进测试技术(电子探针、能谱、扫描电镜、X射线衍射、ICP光谱等)为手段,以理论和实测数据为基础,首次对不同种类、不同产地电气石的含硼情况,进行了分析、对比研究,研究结果不仅印证了电气石理论上含硼高的特点,还为我国含硼高的电气石的利用打下良好基础。尤其是本文实验选用的江西白云山电气石,其B含量达到3.43%(B_2O_3含量为11.06%),含硼量较高,具有较好的代表性。
3、通过对国内外电气石开发利用现状的全面研究,提出将电气石应用于农业生产的意义、设想及开发前景;并通过对我国土壤含硼和耕地缺硼情况以及硼元素作用于农作物的生理机制及效用的深入探讨,结合我国硼肥资源紧缺现状,首次提出了利用电气石独特的物理性质和含硼高的化学特性,替代硼砂用于制作电气石硼肥的思路。
4、通过深入的理论和实验研究,首次提出了以高温焙烧法和化学法(添加酸、碱活化剂)相结合的电气石活化处理法,有效地将硼从电气石晶体结构中分离并溶于水而被农作物吸收;根据溶硼效果、经济性、安全性及环保性等因素综合选定用Na_2CO_3作为化学活化剂效益最大,并有利于产业化生产。
5、创立了将活化处理的电气石粉与未经处理的电气石粉混匀制成高活性电气石硼肥的硼肥制作方法,充分利用了电气石含硼高的化学特征和独特的物理性质,使电气石硼肥除具有一般硼肥的功效外,还具有抗土壤氧化、刺激植物生长,并能吸附土壤中的部分重金属及残留农药,净化植物生长环境等环保特性;并根据需要在高活性硼肥中加入其它农作物所需的有关元素及矿物原料,制备不同功能的电气石复合肥料的最佳配方及工艺流程等创新性成果。
6、本文研究成果已于2008年4月23日获得中国发明专利证书(专利号为:ZL200610021331.9,专利名称为“电气石活化处理方法及用该方法制备的高活性电气石硼肥”)。
As a kind of natural nonmetallic mineral resource that can be applied to daily life, tourmaline is also a very important new type of functional mineral material. Considering the characteristics as its spontaneous electrode, electrostatic field around its particles, emitting far infrared ray, releasing anion etc. that can be developed and utilized, the development and utilization of tourmaline has been one of the hot spots about studying new type of functional mineral materials in 21st century. China is very rich in tourmaline resources; however, the tourmaline reserves that can be used and the distribution in China are still questions, and the research about basic theory of application and comprehensive utilization of tourmaline mineral features was focused on too late, especially the application study and products exploitation for agriculture is still blank in China.
By applying lots of subjects including geological, biological and material science as well as frontier theories, the study has systematically studied and concluded the following factors about Chinese tourmaline, that are the characteristics of tourmaline deposits, temporal and spacial distribution, ore-forming regularity, the tourmaline resources in China and other countries and the exploitation with utilization status. Through a large amount of experimental research, the study has successfully worked out the manufacturing techniques and crafts about tourmaline compound boron fertilizer with the patent being authorized. The main research fingings and creative cognition of the study are presented as follows:
1. The study has comprehensively analyzed and concluded the formation and distribution regularities of tourmaline in China. This is the first time that Chinese tourmaline deposits have been classified into five types as granite pegmatite-host deposits, magmatic hydrothermal deposits, volcanic-subvolcanic (hydrothermal) deposits, hot water sediment-host deposits and supergene sediment-host deposits according to the ore-forming processes, ore-forming patterns, ore-forming matters sources and the temporal and spacial distribution characters of tourmaline resources in China, with the characteristics of each kind of deposits being expounded in the paper. Based on the field survey and existing data about tourmaline resources, combined with the tectonic characteristics of China, the study has worked out the first map as Tourmaline mineral resources distributed in China in the scale of 1:4,000,000.
2. Taking boron concentration as the major parameter, with kinds of tourmalines from different places as studying objects, using advanced modern testing technology (electro probe, energy spectrum, SEM, X-ray diffraction, ICP spectrum and so on) as testing methods, on the basis of theoretical and testing data, the paper has analyzed and comparatively studied the boron concentrations contained by different kinds of tourmalines that are from different places. The studying results have not only confirmed that tourmaline has high boron concentration, but also built a favorable foundation for the application of tourmaline resources with high boron concentration in China. The boron concentration contained by tourmalines chosen as testing samples from Baiyunshan in Jiangxi is even reached 3.43% (B_2O_3 concentration as 11.06%). Since the Baiyunshan tourmaline has high boron concentration, it may be better tourmalines at present in China.
3. Through overall study about the development and utilization of tourmaline resources in China and other countries, the paper has proposed the significance, imagination and exploitation foreground about applying tourmalines to agriculture. In addition, considering the shortage of boron fertilizer in China, the paper has first put forward the idea of using tourmaline to replace borax and manufacture boron fertilizer by utilizing particular physical properties of tourmaline and its chemical properties of high boron concentration, through deep discussing about boron-bearing status and boron-lacking status of Chinese soil, and the physiological mechanism and effects about how boron element affecting crops.
4. Through deep research of theories and experiments, the study has first proposed the treatment of activating tourmaline with calcinations and chemical methods ( eg. adding acid or alkali activator ) being combined, which will effectively separate boron from tourmaline crystal structure and make it dissolved in water to be absorbed by crops. According to boron solution effect, economic factors, safety, and environmental protection consideration, etc., the study has chosen Na_2CO_3 as chemical activator because of the maximum benefit, and its character of being favorable to industrializing production.
5. The study has also create a boron fertilizer manufacturing method by mixing tourmaline powder treated by activating and tourmaline powder without any treatment to form highly active tourmaline boron fertilizer. This method has fully utilized the chemical property of high boron concentration and particular physical property of tourmaline, and not only made tourmaline boron fertilizer had virtues of general boron fertilizer, but also bring the environmental protection characters including antioxidation of soil, promoting the growth of plants, absorbing a part of heavy metals and pesticide residues, as well as purifying plants' growing environment to tourmaline boron fertilizer. Moreover, the study has also worked out the best prescription and technic with other creative fruits about how to manufacture different compound tourmaline fertilizer with different function by adding related elements and mineral materials that are required by crops to high active fertilizer.
6. The studying achievement described in the paper has already gained Chinese invention patent on April.23rd of 2008 (Patent Number: ZL200610021331.9, Patent Name: Tourmaline activating treatment and high active tourmaline boron fertilizer manufactured by this method.).
引文
[1]夏冬明.土壤肥料学[M].上海:上海交通大学出版社,2007.
[2]陆景陵.植物营养学(上册)[M].北京:中国农业大学出版社,2003.
[3]胡霭堂.植物营养学(下册)[M].北京:中国农业大学出版社,2003.
[4]陈国达.地洼学说—活化构造及成矿理论体系概论[M].长沙:中南大学出版社,1996.
[5]马鸿文.工业矿物与岩石[M].北京:地质出版社,2002(8):115-181
[6]褚天铎.化肥科学使用指南[M].北京:金盾出版社,2002(6):124-187
[7]沈阿林.新编肥料实用手册[M].河南:中原农民出版社,2004(5):78-130
[8]张福学,孙慷.压电学[M].北京:国防工业出版社,1984(9):17-67
[9]姚顶山.环保与健康新材料—托玛琳[M].上海:中国纺织大学出版社,2001.6
[10]涂光炽.地球化学[M].上海:上海科学技术出版社,1982,43-180
[11]陈春云,姚尧.环境功能负离子涂料的制备及抗菌性能研究[J].中山大学学报:自然科学版,2007,46(B06):171-172.
[12]袁昌来,刘心宇.天然矿物电气石产生空气负离子性能研究[J],功能材料,2007,(A09):3317-3319.
[13]李文龙,张占平等.电气石矿物材料的特性[J].功能材料,2007年A09期.
[14]高如琴,郑水林等.电气石对硅藻土基多孔陶瓷结构和性能的影响[J].功能材料,2007年A06期.
[15]杨如增,徐礼新.电气石的化学成分与其晶格常数的关系[J].同济大学学报.自然科学版,2007,35(10):1425-1429
[16]张志湘,余丽秀等.电气石深加工与应用技术研究现状[J].中国建材科技,2007(5):41-45.
[17]王光华,董发勤.电气石的功能属性及应用[J].中国非金属矿工业导刊,2007(5):9-11,31.
[18]姚志通,叶瑛等.电气石在水产养殖水处理中的应用[J].渔业现代化,2007(5):18-19.
[19]李双建,石永红等.白垩纪以来库车坳陷碎屑重矿物组成变化[J].地质科学,2007(4):709-721.
[20]姚志通 夏枚生 张红梅 胡彩虹.电气石对硝化菌生长和生物膜形成、熟化的影响[J].水产科学,2007,26(8):461-464.
[21]无.油墨与相关技术[J].涂料技术与文摘,2007,28(7):52-52.
[22]谢静,丁仲礼.中国东北部沙地重矿物组成及沙源分析[J],中国科学:D辑,2007(8):9-45
[23]蒋侃,马放等.电气石对好氧反硝化菌株反硝化特性的影响[J].硅酸盐学报,2007(8):78-82
[24]王敏,张尚坤,赵鹏大.国内外电气石研究进展[J].山东国土资源,2007,23(6):16-20
[25]谭敦民.“保健凉席”真有保障作用吗?[J].科学养生,2007(8):4-5.
[26]梁岩,商平,孙恩呈等.电气石粉对油田采出废水处理效果实验研究[J].岩石矿物学杂志,2007,26(4):375-380
[27]朱红梅,邢宝石,朱杰.电气石的开发前景广阔[J].山东陶瓷,2007,30(3):45-46.
[28]无.无机涂料[J].涂料技术与文摘,2007,28(5):28-28.
[29]廖忠礼,莫宣学,潘桂棠等.藏南过铝花岗岩中电气石的矿物化学特征及成因意义[J].现代地质,2007,21(2):291-295
[30]李奋平、梁金生等.电气石/树脂复合材料对柴油锅炉油耗及排污的影响[J].硅酸盐学报,2007(4):23-27
[31]无.快乐中威健康未来[J].记者摇篮,2007(4):F0004-F0004.
[32]胥焕岩,王鹏,毛桂洁等.电气石在环境领域的最新应用研究:处理雅格素蓝BF-BR染料废水[J].环境工程学报,2007,1(4):65-69.
[33]李芳芳.电气石的性质及应用展望[J].矿业快报,2007(3):14-20
[34]呼振峰,贾木欣.电气石微粉气流磨生产工艺[J].有色金属,2007,59(2):62-65
[35]张凯,黄春保,黄晓敏.矿物粉体对水体的活化作用[J].湖北农业科学,2007,46(2):225-227.
[36]许明罡.落入人间的彩虹仙子——碧玺[J].大众理财顾问,2007(4):62-62.
[37]吴丽娜,王新伟,李青山.负离子塑料的制备与研究[J].塑料制造,2007(3):43-46.
[38]曹慧玲,张力,吕广镛.电气石吸附降解亚甲基蓝等有机染料的研究[J].广东化工,2007,34(1):30-34.
[39]甄刚.电气石保健行业的瑰宝[J].知识经济,2007(1):26-27.
[40]薛建玲,许虹,高一鸣等.辽宁后仙峪硼矿床中电气石的矿物学特征及其成岩成矿意义[J].中国地质,2006,33(6):1386-1392.
[41]邹中云,管俊芳等.电气石粉吸附Pb 2+的实验研究[J].江苏环境科技,2006,6:87-91
[42]卢宗柳.电气石硼肥制作技术的试验研究[J].矿产与地质,2006,20(6):702-705.
[43]管登高,陈善华,唐科等.电气石微粉的研制及其在环境功能材料中的应用[J].矿产综合利用,2006(6):43-46.
[44]王连军,刘方.PET负离子纤维的制备及其性能研究[J].合成纤维工业,2006,29(6):12-14.
[45]呼振峰.电气石超细粉体的制备及粒度检测[J].矿冶,2006,15(4):17-20.
[46]陈丽芸,钱蕙春,王瑛等.负离子铸铁搪瓷的研制[J].玻璃与搪瓷,2006,34(6):10-14.
[47]杨伟军,葛明桥,李永贵等.负离子织物负离子发生能力的影响因素[J].纺织学报,2006,27(12):88-91.
[48]王连军,刘方.聚酯负离子纤维的制备及其性能研究[J].聚酯工业,2006,19(6):14-17.
[49]杜亚利,丁浩.电气石粉体的机械力化学法表面有机化改性研究[J].中国非金属矿工业导刊,2006(5):33-35.
[50]杨菁,丁永良,胡伯成.一体化纳米过滤净水设备研究[J].渔业现代化,2006(5):12-14.
[51]潘艳芬,梁金生,欧秀芹等,电气石远红外辐射对水表面张力的影响[J].硅酸盐学报,2006,34(5):580-584.
[52]吕世静,李梅.负离子远红外功能整理剂及其在纺织业中的应用[J].印染助剂,2006,23(9):25-27.
[53]巫静,吴春龙,黄绳纪等.电气石性能与环保领域的产品开发应用[J].广州化工,2006,34(4):69-72.
[54]焦晓宁,程博闻,裘康等.远红外熔喷保暖絮片的光蓄热性能[J].纺织学报,2006,27(8):76-79.
[55]黄凤萍,李贺军,李克智等.电气石/无机抗菌剂复合型中空活性碳纤维研究[J],非金属矿,2006,29(4):22-24,45.
[56]李强,余钢,刘方明等.环境友好型改性功能粉体的开发及其生态环境学评价[J].中国建材科技,2006,15(3):93-98.
[57]于晓明.有趣的东非珠宝小城[J].世界文化,2006(8):36-37.
[58]袁昌来,董发勤.电气石复合Nd/TiO2材料光催化活性研究[J].矿物学报,2006,26(2):233-237.
[59]无.似花非花 卡地亚全新兰花珠宝系列面市[J].中国新时代,2006(7):130-130.
[60]徐巧飞.巧用液晶显示器上的偏振片[J].物理通报,2006(6):58-59.
[61]徐腾.电气石纳米材料在纸页上的应用[J].天津造纸,2006,28(2):19-20.
[62]冀志江,金宗哲,梁金生等.极性晶体电气石颗粒的电极性观察[J]人工晶体学报,2002(05):17-20.
[63]张晓晖,吴瑞华,马鸿文.亚微米级ZnO/电气石粉体表面包覆研究[J].非金属矿,2006,29(3):3-5.
[64]孟庆杰,张兴祥,王学晨等.不同结构电气石微粉对酸溶液和碱溶液性质的影[J].硅酸盐学报,2006(4):,36-39
[65]无.电气石基网眼多孔陶瓷的制备[J].中国非金属矿工业导刊,2006(2):13-13.
[66]王进军,陶晓风,王武军.聚类方法在电气石颜色成因研究中的应用[J].东华理工学院学报,2006,29(1):38-42.
[67]展杰,郝霄鹏,刘宏等.天然矿物功能晶体材料电气石的研究进展[J].功能材料,2006(4):28-30
[68]康卫民,程博闻,焦晓宁等.纳米电气石/聚丙烯驻极熔喷非织造布的研制[J].合成纤维,2006,35(3):20-23.
[69]赵鹏,朱红.环境矿物资源对高分子吸水材料几种性能的影响[J].橡塑资源利用,2006(1):3-7.
[70]何登良,董发勤.电气石的环境功能属性及应用研究动态[J].中国非金属矿工业导刊,2006(1):10-14.
[71]黄凤萍,李缨.负离子环保陶瓷的研究[J].佛山陶瓷,2006,16(1):4-7.
[72]孙宁.多彩的电气石[J].钟表,2006(1):88-89.
[73]关有俊,何唯平,谭亮.电气石在内墙涂料中的应用研究进展[J].应用化工,2006,35(2):81-83,88.
[74]卢填,张晓晖,吴瑞华等.电气石粉体电磁屏蔽性能研究[J].非金属矿,2006,29(1):5-7.
[75]无.HTB:高科技功能复合新材料[J].云南节能通讯,2006(1):12-12.
[76]王进军,赵枫.电气石的化学特征与相关矿床的关系[J].地质找矿论丛,2002,17(3):161-163,174.
[77]王实等.中国宝玉石资源大全[M].北京:科学技术文献出版社,1999.1
[78]王永坤,张学全.西藏玉龙斑岩型铜钼矿床的成矿分带特征[J].西藏地质,1992(2):71-78.
[79]王敏,王领法,张增奇等.鲁西柳家电气石矿矿物学特征及成矿机理探讨[J].山东地质,2001,17(1):35-39.
[80]王登红,陈毓川.广西大厂电气石的成分与成因初探[J].岩石矿物学杂志,1996,15(3):280-287.
[81]毛景文,宋叔和,陈毓川.桂北地区火山岩系列和锡金属矿床成矿系列[M].北京:北京科学技术出版社,1988.
[82]毛景文,王平安,王登红等.电气石对成岩成矿环境的示踪性及应用条件[J].地质论评,1993,39(6):497-507.
[83]陶维屏,高锡芬,孙祁等.中国非金属矿床成矿系列[M].北京:地质出版社,1994
[84]四○八队.大义山岩体东南部铜多金属矿地质特征及成矿规律[J].湖南地质科技情报,1981(1).
[85]邓燕华.宝(玉)石矿床[M].北京:北京工业大学出版社,1992.
[86]邓瑞华.江西兴峰坡锡矿床的成因探讨[J].江西地质,1989,3(1):16-20
[87]叶松,孔东军,朱勤文.山西省中条山铜矿田电气石与电气石岩的研究[J].矿物岩石学杂志,1997,16(2):160-169.
[88]卢宇,陈炳才,邹文学.江西德安培家垅锡铜矿蚀变矿化特征及控矿因素的初步认识[J].锡矿地质参考资料(四).
[89]史·格·萨哈玛等.论电气石[J].华北冶金地质,1982(2):5-9
[90]任飞,韩跃新,印万忠等.湿式强磁选提纯黑电气石的试验研究[J],金属矿山,2005(5):31-33.
[91]江富建.钙镁电气石检测特征探析[J].南阳师范学报,2002,1(2):75-77.
[92]刘强,陈衍夏,施亦东等.电气石纳米材料在卫生保健纺织领域的应用[J].印染,2004(7).
[93]刘丹阳.内蒙东部克旗沙胡同次火山岩与锡矿[J].地质参考资料,1986(1):43-48
[94]刘锦新等.云南个旧锡矿的特点及成矿规律[J].锡矿地质参考资料(四),矿床地质,1980(7):56-62
[95]刘少昌,袁志.江西曾家垅锡矿床地质特征[J].江西地质,1987,1(2):101-105
[96]朱炳玉.新疆阿尔泰可可托海稀有金属及宝石伟晶岩[J].新疆地质,1997,15(2):16-20
[97]林善园,蔡克勤等.电气石族矿物学研究的新进展[J].中国非金属工业导刊,2004(6):21-24.
[98]林善园,蔡克勤等.电气石矿物学研究的新进展[J].中国非金属工业导刊,2005(1):20-23.
[99]向天秀,雍永源,贾保江.西藏赛北弄锡矿锡石的成因矿物学研究[J].西藏地质,1992(1):56-60
[100]吕宗凯.吉林省集安县高台沟硼矿地质特征及其成因[J].吉林地质,1984(3):34-80
[101]吕伯西,沈敢富,段建中等.云南西盟佤山电英岩之研究[J],科学通报.
[102]西南冶金地质勘探公司三一○队,云龙锡矿床地质特征[J].西南冶金地质,1981(1):23-98
[103]沈敢富,姚鹏.电英质火山岩—西藏岩的发现[J].矿物岩石地球化学通报,1999,18(3):8-13
[104]沈敢富,姚鹏.藏东西藏岩的电气石[J].高校地质学报,2000,6(2):67-69
[105]沈敢富.电英岩的多成因论[J].地质前缘,1999,6(2):67-71
[106]沈建忠,韩发.电气石岩—一种和矿化有关的岩石类型[J].矿床地质,1992,11(4):384-388.
[107]苏文宁,于树升.腾冲白华山地区的混合伟晶岩及其含矿性[J].云南地质科技情报,1981(3):43-80
[108]吴瑞华,汤云晖,张晓晖.电气石的电场效应及其在环境领域中的应用前景[J].岩石矿物杂志.2001,20(4):12-16
[109]邹仕庭.哀牢山南段宝石矿产的初步认识[J].云南区域地质,1988(6):56-60
[110]李赋屏,彭光菊,卢宗柳等.我国电气石资源分布、地质特征及其开发利用前景分析[J].矿产与地质,2004,18(5):493-497.
[111]李献,杨文艺,杨振龙.电气石功能肥料及其制作方法[P],发明专利申请公开说明书,申请号01113963.3.
[112]李秀华,周云霞,陈尚迪.新疆沙尔布拉克金矿床中的层状电气石特征及成因[J].成都理工学院学报,1996,23(1):1-7.
[113]李锦武.云凤地区找锡地质条件的认识[J].地质情报资料,1984(2):43-48
[114]陈建华.新疆阿尔泰山宝石矿物的产出特征[J].珠宝,1990(1):13-67
[115]陈毓川,毛景文等.桂北地区矿床成矿系列和成矿历史演化轨迹[M].南宁:广西科学技术出版社,1995(3):35-49
[116]陈志强,郭拥军.广西某地绿碧玺的发现与鉴定[J],广西地质,1994,7(1):37-40.
[117]汤云晖,马喆生,吴瑞华等.Mg-Fe电气石的热膨胀与相变[J],矿物学报,2002,22(4):383-386.
[118]电气石矿物分析值数据(内部资料),冶金工业部地质研究所,1978.
[119]杨永义.滇西高黎贡山变质岩带的碧玺矿床[J].云南地质科技情报,1998(1):28-30.
[120]杨如增,杨满珍等.天然黑色电气石红外辐射特性研究[J].同济大学学报:自然科学版,2002,30(2):183-188.
[121]杨如增,陈海生.天然黑色电气石热释电特性的研究[J].宝石和宝石学杂志,2000,2(1):34-38.
[122]师文耀,段锦荪.石屏龙潭钨矿地质特征及伴生组分的研究[J].云南地质科技情报,1980(2):23-28
[123]张华,徐星佩.电气石的磁选提纯试验研究[J].矿冶工程,2004,24(4):38-40.
[124]张志湘,冯安生.电气石的自发极化效应在环境与健康领域的应用[J].中国非金属矿工业导刊,2003(1):47-49.
[125]张开永,成学海,曲鸿鲁.国内外电气石开发研究现状及应用前景展望[J].矿冶,2004,13(1):97-100.
[126]张开永,曲鸿鲁,成学海.邹城电气石选矿试验研究[J].有色金属:选矿部分,2004,32(2):23-25.
[127]张晓晖,吴瑞华,汤云晖.电气石的自发电极性在水质净化和改善领域的应用研究[J].中国非金属矿工业导刊,2004(3):39-42.
[128]张志兰.秦东稀有元素花岗伟晶岩中电气石及其红外光谱[J].成都地质学院学报,1980(2):8-45
[129]张志兰,秦岭伟晶岩中电气石比磁化率的研究[J].矿物岩石,1988,8(1):16-21
[130]张学凯.云南优质碧玺产区及其特征[J].珠宝科技,1993,5(1):60-61.
[131]张华.地台型层控钨矿的重要类型浅变质砂页岩系中的黑钨浸染型矿床[J].华东冶金地质,1981(1):67-70
[132]郑水林,杜高翔,李杨,黄云龙.超细电气石粉体的制备和负离子释放性能研究[J].矿冶,2004,13(4):50-53.
[133]武广来.大兴安岭次火山岩型矿床特征[J].地质参考资料,1986(2):23-26
[134]郭力.电气石多功能环境健康新材料[J].中国非金属工业导刊,2004,10(5):16-21
[135]郭进学.鄂东南发现的含钒镁电气石及其意义[J].中南地质科技情报,1974(2):8-12
[136]孙海田,葛朝华.中条山层控铜矿床条纹状电气石岩及容矿富硼化学沉积岩系的发现 及意义[J].科学通报,1988(18):17-21
[137]孙超.珲春东部地区金铜矿成矿地质特征及找矿方向[J],黑龙江有色金属地质,1996(2):56-61
[138]崔斌华.铜矿峪铜矿蚀变矿物地球化学及其与成矿的关系[J].山西地质,1993,8(1):37-48.
[139]黄云龙,郑水林,李杨,常新安.电气石的加工应用现状及发展前景[J].中国非金属矿工业导刊,2003(4):18-21.
[140]夏学惠,郭玉亭.辽东裂谷带硫化物矿床内电气石系列矿物学与找矿关系[J].矿物岩石,1995,15(4):62-71.
[141]夏学惠.辽东地区硫铁矿床中电气石岩热水沉积剖面结构序列[J]岩石学报,1997,13(2):67-71
[142]聂凤军,孙浩.内蒙古别鲁乌图铜矿区电气石岩的发现及其意义[J].地质论评,1990,36(5):467-472.
[143]鲁德石,马万昌.萝北伟晶岩田矿产赋存规律及其地质特征[J].黑龙江地质,1981(1):78-81
[144]鲁德石,马万昌.林口勃利伟晶岩田稀有金属成矿地质特征[J].黑龙江地质,1980(4):8-12
[145]鲁德实.佳木斯中间地块伟晶岩类型的划分及找矿标志[J].黑龙江地质,1992,3(2):21-30.
[146]潘兆橹.结晶学与矿物学(下册)[M],北京:地质出版社,1985.
[147]潘洪彪.广东某地发现形态少见的鳞片—纤维状电气石[J].广东区测,1980(2):8-12
[148]薛春纪,蒋少涌.东秦岭泥盆纪山阳—柞水成矿区电气石矿物化学和硼同位素组成[J].地球化学,1997,26(1):36-44.
[149]谭光裕.甘肃龙得岗爆发角砾岩构造特征及成因探讨[J].甘肃地质,1988(8):23-27
[150]虞钟琪,廖国新.广东省长埔锡石硫化物矿床成矿地质条件和矿床成因类型探讨[J].广东地质科学研究所汇刊,1986(3):18-23
[151]谢抡司,孙邦东.广西贵港市龙头山火山次火山岩型金矿床地质特征[J].广西地质,1993,6(4):7-11
[152]韩跃新,任飞,印万忠等.内蒙古东部黑电气石释放负离子特性研究[J].矿冶,2004,13(1):34-37
[153]冀志江,金宗哲,梁金生等.电气石对水体pH值的影响[J].中国环境科学,2002,22(6):515-519.
[154]魏健,刘渝燕,张开永.电气石应用专属性研究[J].非金属矿,2003,26(1):34-36.
[155]栾秉璈.中国宝石和玉石[M].乌鲁木齐:新疆人民出版社,1989.
[156]黄汲清,任纪舜,姜春发等.中国大地构造及演化[M].北京:科学出版社,1980.
[157]骆靖中.电气石的特性及其在健康与环保领域的新用途[J].中国非金属矿工业导刊,2007(6):17-19.
[158]赵琼译.巴西的电气石和海蓝宝石矿床[J].Ccsar-Mendes,Jet.宝石和宝石学杂志,2001(2):3-36.
[159]Tourmaline group ergslals reaction with water[J],Nakamura T and Kubo T,Ferroelectrics,1992(137):13-15
[160]Reactivity of Tourmaline by Quantum Chemical Calculations[J],ZHOU YONS….武汉理工大学学报:材料科学英文版,2007(4):101-105
[161]Occurrences of Excess^40Ar in Hydrothermal Tourmaline:Interpretations from^40Ar-^39Ar Dating Results by Stepwise Heating[J],QIU Huaning…,地质学报:英文版,2007(3):7-9
[162]梁金生、孟军平.Preparation and photocatalytic activity of composite films containing clustered TiO2 particles and mineral tourmaline powders[J],中国有色金属学会会刊:英文版,2006年BO2期
[163]孟军平,梁多生.Effects of tourmaline on microstructures and photocatalytic activity of TiO2/SiO2 Composite Powders[J].中国有色金属学会会刊:英文版,2006年BO2期
[164]Adsorption characteristics of copper,lead,zinc and cadmium ions by tourmaline JIANG Kan[J],环境科学学报:英文版,2006年6期
[165]Treatment of phenol wastewater by modified tourmaline Huanyan XU…,中国地球化学学报:英文版,2006年BO8期
[166]卢宗柳.我国电气石矿产资源开发前景分析[J].矿产与地质,2008,22(6):562-565
[167]卢宗柳.我国电气石矿床类型及其地质特征[J].矿产与地质,2008,22(2):174-178
[168]卢宗柳.电气石中硼的溶出机制初探[J].广西大学学报(自然科学版),2009,34(3):300-306.
[2]陆景陵.植物营养学(上册)[M].北京:中国农业大学出版社,2003.
[3]胡霭堂.植物营养学(下册)[M].北京:中国农业大学出版社,2003.
[4]陈国达.地洼学说—活化构造及成矿理论体系概论[M].长沙:中南大学出版社,1996.
[5]马鸿文.工业矿物与岩石[M].北京:地质出版社,2002(8):115-181
[6]褚天铎.化肥科学使用指南[M].北京:金盾出版社,2002(6):124-187
[7]沈阿林.新编肥料实用手册[M].河南:中原农民出版社,2004(5):78-130
[8]张福学,孙慷.压电学[M].北京:国防工业出版社,1984(9):17-67
[9]姚顶山.环保与健康新材料—托玛琳[M].上海:中国纺织大学出版社,2001.6
[10]涂光炽.地球化学[M].上海:上海科学技术出版社,1982,43-180
[11]陈春云,姚尧.环境功能负离子涂料的制备及抗菌性能研究[J].中山大学学报:自然科学版,2007,46(B06):171-172.
[12]袁昌来,刘心宇.天然矿物电气石产生空气负离子性能研究[J],功能材料,2007,(A09):3317-3319.
[13]李文龙,张占平等.电气石矿物材料的特性[J].功能材料,2007年A09期.
[14]高如琴,郑水林等.电气石对硅藻土基多孔陶瓷结构和性能的影响[J].功能材料,2007年A06期.
[15]杨如增,徐礼新.电气石的化学成分与其晶格常数的关系[J].同济大学学报.自然科学版,2007,35(10):1425-1429
[16]张志湘,余丽秀等.电气石深加工与应用技术研究现状[J].中国建材科技,2007(5):41-45.
[17]王光华,董发勤.电气石的功能属性及应用[J].中国非金属矿工业导刊,2007(5):9-11,31.
[18]姚志通,叶瑛等.电气石在水产养殖水处理中的应用[J].渔业现代化,2007(5):18-19.
[19]李双建,石永红等.白垩纪以来库车坳陷碎屑重矿物组成变化[J].地质科学,2007(4):709-721.
[20]姚志通 夏枚生 张红梅 胡彩虹.电气石对硝化菌生长和生物膜形成、熟化的影响[J].水产科学,2007,26(8):461-464.
[21]无.油墨与相关技术[J].涂料技术与文摘,2007,28(7):52-52.
[22]谢静,丁仲礼.中国东北部沙地重矿物组成及沙源分析[J],中国科学:D辑,2007(8):9-45
[23]蒋侃,马放等.电气石对好氧反硝化菌株反硝化特性的影响[J].硅酸盐学报,2007(8):78-82
[24]王敏,张尚坤,赵鹏大.国内外电气石研究进展[J].山东国土资源,2007,23(6):16-20
[25]谭敦民.“保健凉席”真有保障作用吗?[J].科学养生,2007(8):4-5.
[26]梁岩,商平,孙恩呈等.电气石粉对油田采出废水处理效果实验研究[J].岩石矿物学杂志,2007,26(4):375-380
[27]朱红梅,邢宝石,朱杰.电气石的开发前景广阔[J].山东陶瓷,2007,30(3):45-46.
[28]无.无机涂料[J].涂料技术与文摘,2007,28(5):28-28.
[29]廖忠礼,莫宣学,潘桂棠等.藏南过铝花岗岩中电气石的矿物化学特征及成因意义[J].现代地质,2007,21(2):291-295
[30]李奋平、梁金生等.电气石/树脂复合材料对柴油锅炉油耗及排污的影响[J].硅酸盐学报,2007(4):23-27
[31]无.快乐中威健康未来[J].记者摇篮,2007(4):F0004-F0004.
[32]胥焕岩,王鹏,毛桂洁等.电气石在环境领域的最新应用研究:处理雅格素蓝BF-BR染料废水[J].环境工程学报,2007,1(4):65-69.
[33]李芳芳.电气石的性质及应用展望[J].矿业快报,2007(3):14-20
[34]呼振峰,贾木欣.电气石微粉气流磨生产工艺[J].有色金属,2007,59(2):62-65
[35]张凯,黄春保,黄晓敏.矿物粉体对水体的活化作用[J].湖北农业科学,2007,46(2):225-227.
[36]许明罡.落入人间的彩虹仙子——碧玺[J].大众理财顾问,2007(4):62-62.
[37]吴丽娜,王新伟,李青山.负离子塑料的制备与研究[J].塑料制造,2007(3):43-46.
[38]曹慧玲,张力,吕广镛.电气石吸附降解亚甲基蓝等有机染料的研究[J].广东化工,2007,34(1):30-34.
[39]甄刚.电气石保健行业的瑰宝[J].知识经济,2007(1):26-27.
[40]薛建玲,许虹,高一鸣等.辽宁后仙峪硼矿床中电气石的矿物学特征及其成岩成矿意义[J].中国地质,2006,33(6):1386-1392.
[41]邹中云,管俊芳等.电气石粉吸附Pb 2+的实验研究[J].江苏环境科技,2006,6:87-91
[42]卢宗柳.电气石硼肥制作技术的试验研究[J].矿产与地质,2006,20(6):702-705.
[43]管登高,陈善华,唐科等.电气石微粉的研制及其在环境功能材料中的应用[J].矿产综合利用,2006(6):43-46.
[44]王连军,刘方.PET负离子纤维的制备及其性能研究[J].合成纤维工业,2006,29(6):12-14.
[45]呼振峰.电气石超细粉体的制备及粒度检测[J].矿冶,2006,15(4):17-20.
[46]陈丽芸,钱蕙春,王瑛等.负离子铸铁搪瓷的研制[J].玻璃与搪瓷,2006,34(6):10-14.
[47]杨伟军,葛明桥,李永贵等.负离子织物负离子发生能力的影响因素[J].纺织学报,2006,27(12):88-91.
[48]王连军,刘方.聚酯负离子纤维的制备及其性能研究[J].聚酯工业,2006,19(6):14-17.
[49]杜亚利,丁浩.电气石粉体的机械力化学法表面有机化改性研究[J].中国非金属矿工业导刊,2006(5):33-35.
[50]杨菁,丁永良,胡伯成.一体化纳米过滤净水设备研究[J].渔业现代化,2006(5):12-14.
[51]潘艳芬,梁金生,欧秀芹等,电气石远红外辐射对水表面张力的影响[J].硅酸盐学报,2006,34(5):580-584.
[52]吕世静,李梅.负离子远红外功能整理剂及其在纺织业中的应用[J].印染助剂,2006,23(9):25-27.
[53]巫静,吴春龙,黄绳纪等.电气石性能与环保领域的产品开发应用[J].广州化工,2006,34(4):69-72.
[54]焦晓宁,程博闻,裘康等.远红外熔喷保暖絮片的光蓄热性能[J].纺织学报,2006,27(8):76-79.
[55]黄凤萍,李贺军,李克智等.电气石/无机抗菌剂复合型中空活性碳纤维研究[J],非金属矿,2006,29(4):22-24,45.
[56]李强,余钢,刘方明等.环境友好型改性功能粉体的开发及其生态环境学评价[J].中国建材科技,2006,15(3):93-98.
[57]于晓明.有趣的东非珠宝小城[J].世界文化,2006(8):36-37.
[58]袁昌来,董发勤.电气石复合Nd/TiO2材料光催化活性研究[J].矿物学报,2006,26(2):233-237.
[59]无.似花非花 卡地亚全新兰花珠宝系列面市[J].中国新时代,2006(7):130-130.
[60]徐巧飞.巧用液晶显示器上的偏振片[J].物理通报,2006(6):58-59.
[61]徐腾.电气石纳米材料在纸页上的应用[J].天津造纸,2006,28(2):19-20.
[62]冀志江,金宗哲,梁金生等.极性晶体电气石颗粒的电极性观察[J]人工晶体学报,2002(05):17-20.
[63]张晓晖,吴瑞华,马鸿文.亚微米级ZnO/电气石粉体表面包覆研究[J].非金属矿,2006,29(3):3-5.
[64]孟庆杰,张兴祥,王学晨等.不同结构电气石微粉对酸溶液和碱溶液性质的影[J].硅酸盐学报,2006(4):,36-39
[65]无.电气石基网眼多孔陶瓷的制备[J].中国非金属矿工业导刊,2006(2):13-13.
[66]王进军,陶晓风,王武军.聚类方法在电气石颜色成因研究中的应用[J].东华理工学院学报,2006,29(1):38-42.
[67]展杰,郝霄鹏,刘宏等.天然矿物功能晶体材料电气石的研究进展[J].功能材料,2006(4):28-30
[68]康卫民,程博闻,焦晓宁等.纳米电气石/聚丙烯驻极熔喷非织造布的研制[J].合成纤维,2006,35(3):20-23.
[69]赵鹏,朱红.环境矿物资源对高分子吸水材料几种性能的影响[J].橡塑资源利用,2006(1):3-7.
[70]何登良,董发勤.电气石的环境功能属性及应用研究动态[J].中国非金属矿工业导刊,2006(1):10-14.
[71]黄凤萍,李缨.负离子环保陶瓷的研究[J].佛山陶瓷,2006,16(1):4-7.
[72]孙宁.多彩的电气石[J].钟表,2006(1):88-89.
[73]关有俊,何唯平,谭亮.电气石在内墙涂料中的应用研究进展[J].应用化工,2006,35(2):81-83,88.
[74]卢填,张晓晖,吴瑞华等.电气石粉体电磁屏蔽性能研究[J].非金属矿,2006,29(1):5-7.
[75]无.HTB:高科技功能复合新材料[J].云南节能通讯,2006(1):12-12.
[76]王进军,赵枫.电气石的化学特征与相关矿床的关系[J].地质找矿论丛,2002,17(3):161-163,174.
[77]王实等.中国宝玉石资源大全[M].北京:科学技术文献出版社,1999.1
[78]王永坤,张学全.西藏玉龙斑岩型铜钼矿床的成矿分带特征[J].西藏地质,1992(2):71-78.
[79]王敏,王领法,张增奇等.鲁西柳家电气石矿矿物学特征及成矿机理探讨[J].山东地质,2001,17(1):35-39.
[80]王登红,陈毓川.广西大厂电气石的成分与成因初探[J].岩石矿物学杂志,1996,15(3):280-287.
[81]毛景文,宋叔和,陈毓川.桂北地区火山岩系列和锡金属矿床成矿系列[M].北京:北京科学技术出版社,1988.
[82]毛景文,王平安,王登红等.电气石对成岩成矿环境的示踪性及应用条件[J].地质论评,1993,39(6):497-507.
[83]陶维屏,高锡芬,孙祁等.中国非金属矿床成矿系列[M].北京:地质出版社,1994
[84]四○八队.大义山岩体东南部铜多金属矿地质特征及成矿规律[J].湖南地质科技情报,1981(1).
[85]邓燕华.宝(玉)石矿床[M].北京:北京工业大学出版社,1992.
[86]邓瑞华.江西兴峰坡锡矿床的成因探讨[J].江西地质,1989,3(1):16-20
[87]叶松,孔东军,朱勤文.山西省中条山铜矿田电气石与电气石岩的研究[J].矿物岩石学杂志,1997,16(2):160-169.
[88]卢宇,陈炳才,邹文学.江西德安培家垅锡铜矿蚀变矿化特征及控矿因素的初步认识[J].锡矿地质参考资料(四).
[89]史·格·萨哈玛等.论电气石[J].华北冶金地质,1982(2):5-9
[90]任飞,韩跃新,印万忠等.湿式强磁选提纯黑电气石的试验研究[J],金属矿山,2005(5):31-33.
[91]江富建.钙镁电气石检测特征探析[J].南阳师范学报,2002,1(2):75-77.
[92]刘强,陈衍夏,施亦东等.电气石纳米材料在卫生保健纺织领域的应用[J].印染,2004(7).
[93]刘丹阳.内蒙东部克旗沙胡同次火山岩与锡矿[J].地质参考资料,1986(1):43-48
[94]刘锦新等.云南个旧锡矿的特点及成矿规律[J].锡矿地质参考资料(四),矿床地质,1980(7):56-62
[95]刘少昌,袁志.江西曾家垅锡矿床地质特征[J].江西地质,1987,1(2):101-105
[96]朱炳玉.新疆阿尔泰可可托海稀有金属及宝石伟晶岩[J].新疆地质,1997,15(2):16-20
[97]林善园,蔡克勤等.电气石族矿物学研究的新进展[J].中国非金属工业导刊,2004(6):21-24.
[98]林善园,蔡克勤等.电气石矿物学研究的新进展[J].中国非金属工业导刊,2005(1):20-23.
[99]向天秀,雍永源,贾保江.西藏赛北弄锡矿锡石的成因矿物学研究[J].西藏地质,1992(1):56-60
[100]吕宗凯.吉林省集安县高台沟硼矿地质特征及其成因[J].吉林地质,1984(3):34-80
[101]吕伯西,沈敢富,段建中等.云南西盟佤山电英岩之研究[J],科学通报.
[102]西南冶金地质勘探公司三一○队,云龙锡矿床地质特征[J].西南冶金地质,1981(1):23-98
[103]沈敢富,姚鹏.电英质火山岩—西藏岩的发现[J].矿物岩石地球化学通报,1999,18(3):8-13
[104]沈敢富,姚鹏.藏东西藏岩的电气石[J].高校地质学报,2000,6(2):67-69
[105]沈敢富.电英岩的多成因论[J].地质前缘,1999,6(2):67-71
[106]沈建忠,韩发.电气石岩—一种和矿化有关的岩石类型[J].矿床地质,1992,11(4):384-388.
[107]苏文宁,于树升.腾冲白华山地区的混合伟晶岩及其含矿性[J].云南地质科技情报,1981(3):43-80
[108]吴瑞华,汤云晖,张晓晖.电气石的电场效应及其在环境领域中的应用前景[J].岩石矿物杂志.2001,20(4):12-16
[109]邹仕庭.哀牢山南段宝石矿产的初步认识[J].云南区域地质,1988(6):56-60
[110]李赋屏,彭光菊,卢宗柳等.我国电气石资源分布、地质特征及其开发利用前景分析[J].矿产与地质,2004,18(5):493-497.
[111]李献,杨文艺,杨振龙.电气石功能肥料及其制作方法[P],发明专利申请公开说明书,申请号01113963.3.
[112]李秀华,周云霞,陈尚迪.新疆沙尔布拉克金矿床中的层状电气石特征及成因[J].成都理工学院学报,1996,23(1):1-7.
[113]李锦武.云凤地区找锡地质条件的认识[J].地质情报资料,1984(2):43-48
[114]陈建华.新疆阿尔泰山宝石矿物的产出特征[J].珠宝,1990(1):13-67
[115]陈毓川,毛景文等.桂北地区矿床成矿系列和成矿历史演化轨迹[M].南宁:广西科学技术出版社,1995(3):35-49
[116]陈志强,郭拥军.广西某地绿碧玺的发现与鉴定[J],广西地质,1994,7(1):37-40.
[117]汤云晖,马喆生,吴瑞华等.Mg-Fe电气石的热膨胀与相变[J],矿物学报,2002,22(4):383-386.
[118]电气石矿物分析值数据(内部资料),冶金工业部地质研究所,1978.
[119]杨永义.滇西高黎贡山变质岩带的碧玺矿床[J].云南地质科技情报,1998(1):28-30.
[120]杨如增,杨满珍等.天然黑色电气石红外辐射特性研究[J].同济大学学报:自然科学版,2002,30(2):183-188.
[121]杨如增,陈海生.天然黑色电气石热释电特性的研究[J].宝石和宝石学杂志,2000,2(1):34-38.
[122]师文耀,段锦荪.石屏龙潭钨矿地质特征及伴生组分的研究[J].云南地质科技情报,1980(2):23-28
[123]张华,徐星佩.电气石的磁选提纯试验研究[J].矿冶工程,2004,24(4):38-40.
[124]张志湘,冯安生.电气石的自发极化效应在环境与健康领域的应用[J].中国非金属矿工业导刊,2003(1):47-49.
[125]张开永,成学海,曲鸿鲁.国内外电气石开发研究现状及应用前景展望[J].矿冶,2004,13(1):97-100.
[126]张开永,曲鸿鲁,成学海.邹城电气石选矿试验研究[J].有色金属:选矿部分,2004,32(2):23-25.
[127]张晓晖,吴瑞华,汤云晖.电气石的自发电极性在水质净化和改善领域的应用研究[J].中国非金属矿工业导刊,2004(3):39-42.
[128]张志兰.秦东稀有元素花岗伟晶岩中电气石及其红外光谱[J].成都地质学院学报,1980(2):8-45
[129]张志兰,秦岭伟晶岩中电气石比磁化率的研究[J].矿物岩石,1988,8(1):16-21
[130]张学凯.云南优质碧玺产区及其特征[J].珠宝科技,1993,5(1):60-61.
[131]张华.地台型层控钨矿的重要类型浅变质砂页岩系中的黑钨浸染型矿床[J].华东冶金地质,1981(1):67-70
[132]郑水林,杜高翔,李杨,黄云龙.超细电气石粉体的制备和负离子释放性能研究[J].矿冶,2004,13(4):50-53.
[133]武广来.大兴安岭次火山岩型矿床特征[J].地质参考资料,1986(2):23-26
[134]郭力.电气石多功能环境健康新材料[J].中国非金属工业导刊,2004,10(5):16-21
[135]郭进学.鄂东南发现的含钒镁电气石及其意义[J].中南地质科技情报,1974(2):8-12
[136]孙海田,葛朝华.中条山层控铜矿床条纹状电气石岩及容矿富硼化学沉积岩系的发现 及意义[J].科学通报,1988(18):17-21
[137]孙超.珲春东部地区金铜矿成矿地质特征及找矿方向[J],黑龙江有色金属地质,1996(2):56-61
[138]崔斌华.铜矿峪铜矿蚀变矿物地球化学及其与成矿的关系[J].山西地质,1993,8(1):37-48.
[139]黄云龙,郑水林,李杨,常新安.电气石的加工应用现状及发展前景[J].中国非金属矿工业导刊,2003(4):18-21.
[140]夏学惠,郭玉亭.辽东裂谷带硫化物矿床内电气石系列矿物学与找矿关系[J].矿物岩石,1995,15(4):62-71.
[141]夏学惠.辽东地区硫铁矿床中电气石岩热水沉积剖面结构序列[J]岩石学报,1997,13(2):67-71
[142]聂凤军,孙浩.内蒙古别鲁乌图铜矿区电气石岩的发现及其意义[J].地质论评,1990,36(5):467-472.
[143]鲁德石,马万昌.萝北伟晶岩田矿产赋存规律及其地质特征[J].黑龙江地质,1981(1):78-81
[144]鲁德石,马万昌.林口勃利伟晶岩田稀有金属成矿地质特征[J].黑龙江地质,1980(4):8-12
[145]鲁德实.佳木斯中间地块伟晶岩类型的划分及找矿标志[J].黑龙江地质,1992,3(2):21-30.
[146]潘兆橹.结晶学与矿物学(下册)[M],北京:地质出版社,1985.
[147]潘洪彪.广东某地发现形态少见的鳞片—纤维状电气石[J].广东区测,1980(2):8-12
[148]薛春纪,蒋少涌.东秦岭泥盆纪山阳—柞水成矿区电气石矿物化学和硼同位素组成[J].地球化学,1997,26(1):36-44.
[149]谭光裕.甘肃龙得岗爆发角砾岩构造特征及成因探讨[J].甘肃地质,1988(8):23-27
[150]虞钟琪,廖国新.广东省长埔锡石硫化物矿床成矿地质条件和矿床成因类型探讨[J].广东地质科学研究所汇刊,1986(3):18-23
[151]谢抡司,孙邦东.广西贵港市龙头山火山次火山岩型金矿床地质特征[J].广西地质,1993,6(4):7-11
[152]韩跃新,任飞,印万忠等.内蒙古东部黑电气石释放负离子特性研究[J].矿冶,2004,13(1):34-37
[153]冀志江,金宗哲,梁金生等.电气石对水体pH值的影响[J].中国环境科学,2002,22(6):515-519.
[154]魏健,刘渝燕,张开永.电气石应用专属性研究[J].非金属矿,2003,26(1):34-36.
[155]栾秉璈.中国宝石和玉石[M].乌鲁木齐:新疆人民出版社,1989.
[156]黄汲清,任纪舜,姜春发等.中国大地构造及演化[M].北京:科学出版社,1980.
[157]骆靖中.电气石的特性及其在健康与环保领域的新用途[J].中国非金属矿工业导刊,2007(6):17-19.
[158]赵琼译.巴西的电气石和海蓝宝石矿床[J].Ccsar-Mendes,Jet.宝石和宝石学杂志,2001(2):3-36.
[159]Tourmaline group ergslals reaction with water[J],Nakamura T and Kubo T,Ferroelectrics,1992(137):13-15
[160]Reactivity of Tourmaline by Quantum Chemical Calculations[J],ZHOU YONS….武汉理工大学学报:材料科学英文版,2007(4):101-105
[161]Occurrences of Excess^40Ar in Hydrothermal Tourmaline:Interpretations from^40Ar-^39Ar Dating Results by Stepwise Heating[J],QIU Huaning…,地质学报:英文版,2007(3):7-9
[162]梁金生、孟军平.Preparation and photocatalytic activity of composite films containing clustered TiO2 particles and mineral tourmaline powders[J],中国有色金属学会会刊:英文版,2006年BO2期
[163]孟军平,梁多生.Effects of tourmaline on microstructures and photocatalytic activity of TiO2/SiO2 Composite Powders[J].中国有色金属学会会刊:英文版,2006年BO2期
[164]Adsorption characteristics of copper,lead,zinc and cadmium ions by tourmaline JIANG Kan[J],环境科学学报:英文版,2006年6期
[165]Treatment of phenol wastewater by modified tourmaline Huanyan XU…,中国地球化学学报:英文版,2006年BO8期
[166]卢宗柳.我国电气石矿产资源开发前景分析[J].矿产与地质,2008,22(6):562-565
[167]卢宗柳.我国电气石矿床类型及其地质特征[J].矿产与地质,2008,22(2):174-178
[168]卢宗柳.电气石中硼的溶出机制初探[J].广西大学学报(自然科学版),2009,34(3):300-306.