枞酸热力学特性及其热分解动力学
|
摘要
松香是松脂经蒸馏获得的天然可再生资源,松香的主要成分枞酸具有生物活性,它在表面活性剂、医药、农药和其它精细化学品的制备中具有广泛的用途。但由于枞酸是以同分异构体的形式存在于松香中,采用传统的方法单离枞酸存在选择性低、步骤多、成本高等缺点而无法实现工业上的应用,因此需要开发新的生产方法,以提高枞酸单离纯度和得率。然而枞酸的单离需要进行结晶操作以获得高纯度的产品,作为结晶过程基础数据之一—枞酸的溶解度数据鲜有文献报道。因此需要测定枞酸在相关溶剂中的溶解度数据,采用合适的分子热力学模型对数据进行关联,获得其模型参数,为枞酸分离纯化过程开发提供基础数据和理论依据。本论文采用超声波强化异构和胺化反应-结晶耦合的方法单离枞酸并对其热力学特性和热分解动力学进行研究。主要获得了以下几个方面的研究结果。
采用本课题组开发的超声波强化异构和胺化反应-结晶耦合单离松香树脂酸的方法单离枞酸。以异构松香和乙醇胺为原料,95%乙醇为重结晶剂,考察了反应温度、反应时间、搅拌速度、超声波功率、重结晶次数对枞酸单离纯度和得率的影响,获得枞酸单离的适宜条件为：反应温度30℃,反应时间40min,搅拌速度400rpm,超声波强度300W,胺盐冷冻结晶3次。按照此条件进行试验,枞酸单离纯度和得率分别为98.52%和54.93%。测定了枞酸产品的熔点和比旋光度,并经GC、GC-MS、UV、FTIR、NMR进行分析与鉴定,证实所得产品为高纯度枞酸,为进行枞酸热力学特性和热分解动力学研究提供了高纯度和足够量的枞酸产品。
研究了枞酸的热力学特性及其热分解动力学。采用氧弹式量热计测定了枞酸的恒容燃烧热为-11441.46kJ·mol-1,获得其标准摩尔燃烧焓和标准摩尔生成焓分别为-11457.57kJ·mol-1和-701.85kJ·mol-1。采用差示扫描量热仪测定了枞酸的摩尔熔化焓为19.44kJ·mol-1,获得其摩尔熔化熵为43.11J·mol-1·k-1。分别研究了枞酸在空气和氩气气氛中的热分解过程,枞酸在两种气氛中均为一步分解。采用微分法和积分相结合对枞酸非等温热分解过程进行研究,获得动力学三因子,并推断了相应的热分解机理。其中在空气气氛中枞酸的热分解反应机理为随机成核和随后生长,机理函数的微分形式为f(a)=2(1-a)[-ln(1-a)]1/2,积分形式为G(a)=[-ln(1-a)]1/2.在氩气气氛中枞酸的热分解机理服从反应级数为3/2的Mampel Power法则,机理函数的微分形式和积分形式分别为f(a)=2/3a-1/2和G(a)=a3/2。
采用激光监视法测定了常压下枞酸在异丙醇、异丁醇、戊醇、异戊醇四种醇类溶剂中的溶解度,温度范围为288.57K～328.43K,为枞酸的分离纯化过程开发提供了基础数据。分别采用简化模型(两参数方程和三参数方程)、Wilson、NRTL、λh方程关联了所测定的溶解度数据,结果表明,各模型均可以用于关联枞酸在实验温度和浓度范围内上述溶剂中的溶解度数据,关联结果令人满意。各模型总平均相对误差分别为1.02%、0.59%、0.88%、0.93%和0.94%。
采用激光监视法测定了常压下枞酸常压下在不同乙醇水溶液中的溶解度,温度范围为286.65K～323.85K。分别使用简化模型和λh方程对溶解度数据进行关联。结果显示各模型的平均相对误差都较小,均可以用来关联枞酸在实验温度和浓度范围内乙醇水溶液的溶解度数据,各模型总的平均相对误差分别为1.67%、1.02%和1.74%；同时,基于拟一元的思想,将乙醇水二元混合溶剂作拟一元溶剂处理,使用二元活度系数模型Wilson和NRTL方程研究枞酸在乙醇水混合溶剂中的固液相平衡,关联结果令人满意,计算值与实验值非常吻合。总平均相对误差分别为1.16%和1.42%。使用λh方程的h参数对实验体系的溶解热进行了预测,为枞酸的分离纯化过程开发提供了热力学基础数据。
Rosin is a natural renewable product which is obtained directly by the distillation of pine oleoresin. Abietic acid, one of the primary components of rosin, is a substance with biological activity, and can be widely used in many industries such as surfactants, medicine, pesticide, and finechemicals. However, due to the fact that abietic acid is contained in rosin as the mixture of isomers, the traditional method for preparation of abietic acid exists some disadvantages, such as low selectivity, longer process flow, and high cost etc., which restrict its application in industry on large scale. So, it is vital to develop a new production method to increase the purity and yield of abietic acid. The isolation of abietic acid from rosin involves preparation of derivatives of abietic acid in the crude mixture, purification of these derivatives by crystallization procedures and regeneration of the acid. Pure abietic acid can be obtained after further purification by means of crystallization. Unfortunately, the solubility of abietic acid is scarce. Therefore, it is necessary to measure the solubility of abietic acid in certain solvents. And then correlated the solubility data with suitable molecular thermodynamic models, obtained their model parameter. The results might provide important basic data and theoretical support for the development of purification processes of abietic acid. In this thesis, abietic acid was isolated by means of isomerization and amination reaction-crystallization coupled with ultrasonic wave, and its thermodynamic properties and thermal decomposition kinetics have been investigated systematically. The main results are as follow.
Abietic acid was isolated by means of isomerization and amination reaction-crystallization coupled with ultrasonic wave, which is a novel method developed by our research group. Isomerization rosin and ethanolamine were used as raw materials,95%ethanol as recrystallization solvent, the effects of reaction temperature, reaction time, agitating velocity, ultrasound intensity and recrystallization times on the purity and yield of abietic acid were investigated. The suitable isolation conditions were obtained as follow:reaction temperature30℃, reaction time40min, agitating velocity400rpm, ultrasound intensity300W and freeze crystallization of amine salt three times. The purity and yield of abietic acid were98.52%and54.93%when the suitable conditions was used. And it was then characterization by its melting point, specific rotation, GC, GC-MS, UV, FTIR and NMR, all evidence indicated that the purification product was abietic acid which provided high purity and enough abietic acid for the investigation of thermodynamic properties and thermal decomposition kinetics.
The thermodynamic property and thermal decomposition kinetics of abietic acid have been studied. The constant-volume combustion heat of abietic acid was determined as-11441.46kJ·mol-1by means of oxygen bomb calorimeter, and the standard molar combustion enthalpy and standard molar enthalpy of formation have been calculated as-11457.57kJ·mol-1and-701.85kJ·mol-1based on the thermodynamic principle. The molar fusion enthalpy of abietic acid was determined as19.44kJ·mol-1via differential scanning calorimetry (DSC), and the molar fusion entropy of abietic acid was calculated as43.11J·mol-1·K-1according to thermodynamic principle. The thermal decomposition of abietic acid in static state air and argon were investigated, and the results showed that decomposition occurs in a single step in these two atmospheres. The non-isothermal decomposition kinetics of abietic acid was studied by using the differential method combined with integral method, kinetic triplets and the corresponding thermal decomposition mechanisms were obtained as well. And the results show that the thermal decomposition mechanism of abietic acid in air is nucleation and growth, the differential and integral forms of mechanism function are f(a)=2(1-a)[-ln(1-a)1/2and G (a)=[-In (1-a)]1/2. For argon atmosphere, the thermal decomposition mechanism follows Mampel Power law with n=3/2, whose differential and integral forms are f(a)=-2/3a-1/2and G(a)=a3/2.
Using the laser monitoring observation technique, the solubility of abietic acid in alcohols (isopropanol, isobutanol,1-pentanol, isopentanol) have been measured by a synthetic method in the temperature range of288.57K-328.43K at atmospheric pressure, which can be employed in the development of purification processes of abietic acid. Experimental solubility data were correlated by means of the simplified models (two-parameter and three-parameter equations), Wilson, NRTL and λh equations. And the results show that the above models are suitable for description of the solubility data of abietic acid in the investigated solvents under the experimental temperature and concentration. The average relative standard deviations are1.02%,0.59%,0.88%,0.93%and0.94%, for the two-parameter, three-parameter, Wilson, NRTL and λh equations, respectively.
Using the laser monitoring observation technique, the solubility of abietic acid in ethanol and water mixtures was measured at the temperatures ranging from286.65K-323.85K by a synthetic method at atmospheric pressure. The solubility data were correlated by means of the simplified models (two-parameter and three-parameter equations) and λh equations, the results show that average relative deviations of three models are all small, which indicates that these models are suitable for description of the solubility data of abietic acid in the investigated solvents under the experimental temperature and concentration. And the average relative standard deviations are1.72%、1.12%and1.84%, for the two-parameter, three-parameter, and λh equations, respectively. Based on the quasi-unitary idea, the mixtures of ethanol+water was considered as one new solvent, the experimental solubility has been also correlated by the Wilson and NRTL equations, the calculated values are in good agreement with the experimental values. And the average relative standard deviations are1.19%and1.43%for the Wilson and NRTL equations, respectively. The excess enthalpy of abietic acid in the experimental systems have been forcasted by λh equations, which can be regarded as basic thermodynamic data for the development of isolation process.
采用本课题组开发的超声波强化异构和胺化反应-结晶耦合单离松香树脂酸的方法单离枞酸。以异构松香和乙醇胺为原料,95%乙醇为重结晶剂,考察了反应温度、反应时间、搅拌速度、超声波功率、重结晶次数对枞酸单离纯度和得率的影响,获得枞酸单离的适宜条件为：反应温度30℃,反应时间40min,搅拌速度400rpm,超声波强度300W,胺盐冷冻结晶3次。按照此条件进行试验,枞酸单离纯度和得率分别为98.52%和54.93%。测定了枞酸产品的熔点和比旋光度,并经GC、GC-MS、UV、FTIR、NMR进行分析与鉴定,证实所得产品为高纯度枞酸,为进行枞酸热力学特性和热分解动力学研究提供了高纯度和足够量的枞酸产品。
研究了枞酸的热力学特性及其热分解动力学。采用氧弹式量热计测定了枞酸的恒容燃烧热为-11441.46kJ·mol-1,获得其标准摩尔燃烧焓和标准摩尔生成焓分别为-11457.57kJ·mol-1和-701.85kJ·mol-1。采用差示扫描量热仪测定了枞酸的摩尔熔化焓为19.44kJ·mol-1,获得其摩尔熔化熵为43.11J·mol-1·k-1。分别研究了枞酸在空气和氩气气氛中的热分解过程,枞酸在两种气氛中均为一步分解。采用微分法和积分相结合对枞酸非等温热分解过程进行研究,获得动力学三因子,并推断了相应的热分解机理。其中在空气气氛中枞酸的热分解反应机理为随机成核和随后生长,机理函数的微分形式为f(a)=2(1-a)[-ln(1-a)]1/2,积分形式为G(a)=[-ln(1-a)]1/2.在氩气气氛中枞酸的热分解机理服从反应级数为3/2的Mampel Power法则,机理函数的微分形式和积分形式分别为f(a)=2/3a-1/2和G(a)=a3/2。
采用激光监视法测定了常压下枞酸在异丙醇、异丁醇、戊醇、异戊醇四种醇类溶剂中的溶解度,温度范围为288.57K～328.43K,为枞酸的分离纯化过程开发提供了基础数据。分别采用简化模型(两参数方程和三参数方程)、Wilson、NRTL、λh方程关联了所测定的溶解度数据,结果表明,各模型均可以用于关联枞酸在实验温度和浓度范围内上述溶剂中的溶解度数据,关联结果令人满意。各模型总平均相对误差分别为1.02%、0.59%、0.88%、0.93%和0.94%。
采用激光监视法测定了常压下枞酸常压下在不同乙醇水溶液中的溶解度,温度范围为286.65K～323.85K。分别使用简化模型和λh方程对溶解度数据进行关联。结果显示各模型的平均相对误差都较小,均可以用来关联枞酸在实验温度和浓度范围内乙醇水溶液的溶解度数据,各模型总的平均相对误差分别为1.67%、1.02%和1.74%；同时,基于拟一元的思想,将乙醇水二元混合溶剂作拟一元溶剂处理,使用二元活度系数模型Wilson和NRTL方程研究枞酸在乙醇水混合溶剂中的固液相平衡,关联结果令人满意,计算值与实验值非常吻合。总平均相对误差分别为1.16%和1.42%。使用λh方程的h参数对实验体系的溶解热进行了预测,为枞酸的分离纯化过程开发提供了热力学基础数据。
Rosin is a natural renewable product which is obtained directly by the distillation of pine oleoresin. Abietic acid, one of the primary components of rosin, is a substance with biological activity, and can be widely used in many industries such as surfactants, medicine, pesticide, and finechemicals. However, due to the fact that abietic acid is contained in rosin as the mixture of isomers, the traditional method for preparation of abietic acid exists some disadvantages, such as low selectivity, longer process flow, and high cost etc., which restrict its application in industry on large scale. So, it is vital to develop a new production method to increase the purity and yield of abietic acid. The isolation of abietic acid from rosin involves preparation of derivatives of abietic acid in the crude mixture, purification of these derivatives by crystallization procedures and regeneration of the acid. Pure abietic acid can be obtained after further purification by means of crystallization. Unfortunately, the solubility of abietic acid is scarce. Therefore, it is necessary to measure the solubility of abietic acid in certain solvents. And then correlated the solubility data with suitable molecular thermodynamic models, obtained their model parameter. The results might provide important basic data and theoretical support for the development of purification processes of abietic acid. In this thesis, abietic acid was isolated by means of isomerization and amination reaction-crystallization coupled with ultrasonic wave, and its thermodynamic properties and thermal decomposition kinetics have been investigated systematically. The main results are as follow.
Abietic acid was isolated by means of isomerization and amination reaction-crystallization coupled with ultrasonic wave, which is a novel method developed by our research group. Isomerization rosin and ethanolamine were used as raw materials,95%ethanol as recrystallization solvent, the effects of reaction temperature, reaction time, agitating velocity, ultrasound intensity and recrystallization times on the purity and yield of abietic acid were investigated. The suitable isolation conditions were obtained as follow:reaction temperature30℃, reaction time40min, agitating velocity400rpm, ultrasound intensity300W and freeze crystallization of amine salt three times. The purity and yield of abietic acid were98.52%and54.93%when the suitable conditions was used. And it was then characterization by its melting point, specific rotation, GC, GC-MS, UV, FTIR and NMR, all evidence indicated that the purification product was abietic acid which provided high purity and enough abietic acid for the investigation of thermodynamic properties and thermal decomposition kinetics.
The thermodynamic property and thermal decomposition kinetics of abietic acid have been studied. The constant-volume combustion heat of abietic acid was determined as-11441.46kJ·mol-1by means of oxygen bomb calorimeter, and the standard molar combustion enthalpy and standard molar enthalpy of formation have been calculated as-11457.57kJ·mol-1and-701.85kJ·mol-1based on the thermodynamic principle. The molar fusion enthalpy of abietic acid was determined as19.44kJ·mol-1via differential scanning calorimetry (DSC), and the molar fusion entropy of abietic acid was calculated as43.11J·mol-1·K-1according to thermodynamic principle. The thermal decomposition of abietic acid in static state air and argon were investigated, and the results showed that decomposition occurs in a single step in these two atmospheres. The non-isothermal decomposition kinetics of abietic acid was studied by using the differential method combined with integral method, kinetic triplets and the corresponding thermal decomposition mechanisms were obtained as well. And the results show that the thermal decomposition mechanism of abietic acid in air is nucleation and growth, the differential and integral forms of mechanism function are f(a)=2(1-a)[-ln(1-a)1/2and G (a)=[-In (1-a)]1/2. For argon atmosphere, the thermal decomposition mechanism follows Mampel Power law with n=3/2, whose differential and integral forms are f(a)=-2/3a-1/2and G(a)=a3/2.
Using the laser monitoring observation technique, the solubility of abietic acid in alcohols (isopropanol, isobutanol,1-pentanol, isopentanol) have been measured by a synthetic method in the temperature range of288.57K-328.43K at atmospheric pressure, which can be employed in the development of purification processes of abietic acid. Experimental solubility data were correlated by means of the simplified models (two-parameter and three-parameter equations), Wilson, NRTL and λh equations. And the results show that the above models are suitable for description of the solubility data of abietic acid in the investigated solvents under the experimental temperature and concentration. The average relative standard deviations are1.02%,0.59%,0.88%,0.93%and0.94%, for the two-parameter, three-parameter, Wilson, NRTL and λh equations, respectively.
Using the laser monitoring observation technique, the solubility of abietic acid in ethanol and water mixtures was measured at the temperatures ranging from286.65K-323.85K by a synthetic method at atmospheric pressure. The solubility data were correlated by means of the simplified models (two-parameter and three-parameter equations) and λh equations, the results show that average relative deviations of three models are all small, which indicates that these models are suitable for description of the solubility data of abietic acid in the investigated solvents under the experimental temperature and concentration. And the average relative standard deviations are1.72%、1.12%and1.84%, for the two-parameter, three-parameter, and λh equations, respectively. Based on the quasi-unitary idea, the mixtures of ethanol+water was considered as one new solvent, the experimental solubility has been also correlated by the Wilson and NRTL equations, the calculated values are in good agreement with the experimental values. And the average relative standard deviations are1.19%and1.43%for the Wilson and NRTL equations, respectively. The excess enthalpy of abietic acid in the experimental systems have been forcasted by λh equations, which can be regarded as basic thermodynamic data for the development of isolation process.
引文
[1]安鑫南.林产化学工艺学[M].北京：中国林业出版社,2002.34,41
[2]陈素文.松香松节油深度加工技术与利用[M].北京：中国林业出版社,1997.23
[3]王琳琳.松香、松节油及松脂中分子间氢转移催化反应的研究[D].南宁：广西大学,2007
[4]Ellingson E O. On abietic acid and some of its salts[J]. Journal of the American Chemical Society,1914,36(2):325-335
[5]Gubelmann I, Henke C O, Lee H R. Process of preparing abietic acid[P]. US:US 1846639 (A),1932.2.23
[6]Steele L L. Abietic acid and certain metal abietatesl[J]. Journal of the American Chemical Society,1922,44(6):1333-1341
[7]Palkin S, Harris T H. The Preparation of 1-abietic acid (Schulz) and properties of some of its salts[J]. Journal American Chemical Society,1934,56(9):1935-1937
[8]Harris G C, Sanderson T F. Resin acids. I. An improved method of isolation of resin acids; the isolation of a new abietic-type acid, neoabietic acid[J]. Journal American Chemical Society,1948,70(1):334-339
[9]王文军,戴乾圜.(-)-7,13-二烯-18-枞酸的提取与纯化及其结构鉴定[J].北京工业大学学报,2000,26(4)：77-79
[10]韩春蕊,宋湛谦,商士斌.提纯枞酸的新方法[J].林产化学与工业,2007,27(4)：42-46
[11]姚兴东,聂园梅,蓝丽红,等.一种枞酸的制备方法[P].中国：CN101020630A,2007.8.22
[12]高艺美,廖晨伊,韦小杰,等.松香树脂酸异构化反应研究[J].化学研究与应用,2009,21(11)：1533-1538
[13]高艺美,廖晨伊,韦小杰,等.超声波强化胺盐法单离枞酸的研究[J].高校化学工程学报,2009,23(4)：725-728
[14]刘红军,周永红.一种枞酸的制备方法[P]. CN101219949A,2008.7.16
[15]Jin Z M, Pan Y J, Liu J G, et al. Separation of rosin acids by molecular recognition: crystal structure of the complex of neoabietic acid with 2-amino-6-methyl-pyridine[J]. Journal of Chemical Crystallography,2000,30(3):195-198
[16]金志敏,尚四华.新枞酸与2-氨基-6-甲基-吡啶的共晶识别[J].中草药,2000,31(11)：811-812
[17]Luong J H T, Rigby T, Male K B, et al. Separation of resin acids using cyclodextrin-modified capillary electrophoresis[J]. Electrophotesis,1999,20(7): 1546-1554
[18]Osete-Cortina L, Domenech-Carbo M T, Mateo-Castro R, et al. Identification of diterpenes in canvas painting varnishes by gas chromatography-mass spectrometry with combined derivatisation[J]. Journal of Chromatography A,2004,1024(1-2): 187-194
[19]Lee B L, Koh D, Ong H Y, et al. High-performance liquid chromatographic determination of dehydroabietic and abietic acids in traditional Chinese medications[J]. Journal of Chromatography A,1997,763:221-226
[20]McMartin D W, Headley J V, Winkler M, et al. Evaluation of liquid chromatography-negative ion electrospray mass spectrometry for the determination of selected resin acids in river water[J]. Journal of Chromatography A,2002,952: 289-293
[21]Aya Y, Yoichiro E, Kohtaro M, et al. Supercritical fluid chromatography of free resin acids on an ODS-silica gel column[J]. Journal of Chromatography A,1995,709: 345-349
[22]Lin C H, Chuang H S. Use of abietic acid or derivative thereof for modulation permeability of plasma membrane[P]. US:US2004063788(A1),2004.04.01
[23]Nobuyuki T, Teruo K, Tsuyoshi G, et al. Abietic acid activates peroxisome proliferator-activated receptor-γ(PPARγ) in RAW264.7 macrophages and 3T3-L1 adipocytes to regulate gene expression involved in inflammation and lipid metabolism[J]. FEBS Lett,2003,550:190-194
[24]Morkhade D M, Nande V S, Barabde U V, et al. PEGylated rosin derivatives:Novel microencapsulating materials for sustained drug delivery[J]. AAPS PharmSciTech, 2007,8(2):E134-E142
[25]Fulzele S V, Satturwar P M, Dorle A K. Novel biopolymers as implant matrix for the delivery of ciprofloxacin:Biocompatibility, degradation, and in vitro antibiotic release[J]. Journal of pharmaceutical sciences,2007,96(1):132-144
[26]Tohoku, Kyodo, Kagakukogyo, et al. Compositions pour usages agricoles[P]. FR: FR1381645(A),1964.12.14
[27]Koushi M, Fujii R, Ishihara K, et al. Agricultural fungicide[P]. JP:JP57088102(A), 1982.06.01
[28]Yadav J S, Baishya G, Dash U. Synthesis of (+)-amberketal and its analog from 1-abietic acid[J]. Tetrahedron,2007,63:9896-9902
[29]Alvarez-Manzaneda E, Chahboun R, Cabrera E, et al. First synthesis of picealactone C. A new route toward taxodione-related terpenoids from abietic acid[J]. Tetrahedron Letters,2007,48(6):989-992
[30]Santos C D, Zukerman-Schpector J, Imamura P M. Chemical transformation of abietic acid to new chiral derivatives [J]. Journal of the Brazilian Chemical Society,2003,14: 998-1004
[31]Gigante B, Santos C, Silva A M, et al. Catechols from abietic acid:synthesis and evaluation as bioactive compounds[J]. Bioorganic & Medicinal Chemistry,2003,11(8): 1631-1638
[32]Wang H H, Liu B, Liu X Q, et al. Synthesis of biobased epoxy and curing agents using rosin and the study of cure reactions[J]. Green Chemistry,2008,10(11):1190-1196
[33]Liu X Q, Xin W B, Zhang J W. Rosin-based acid anhydrides as alternatives to petrochemical curing agents[J]. Green Chemistry,2009,11(7):1018-1025
[34]Joerg K, Hermann H, Detlef H, et al. Hair conditioner for improving the dry combability of fine hair[P]. DE:DE4438115(A1),1996.05.02
[35]Miyamoto N, Ikeuchi T. Hair cosmetic composition[P]. JP:JP60001112(A), 1985.01.07
[36]Sato K. Pigment surface-treated with abietic ester, and cosmetic containing same[P]. JP:JP2000095966(A),2000.04.04
[37]Zhang X W, Yin Q X, Gong J B, et al. Solubility of 5-Amino-N,N'-bis(2,3-dihydroxypropyl)-2,4,6-triiodobenzene-1,3-dicarboxamide in Ethanol+Water Mixtures[J]. Journal of Chemical & Engineering Data,2010,55(6): 2355-2357
[38]Li R R, Zhao H K, Jiang S N, et al. Solubility of 1,6-naphthalene disulfonic acid disodium in binary sodium chloride+water, sodium sulfate+water, and ethanol+ water solvent mixtures at elevated temperatures [J]. Journal of Chemical & Engineering Data,2011,56(5):2692-2695
[39]周彩荣.由环己烯制备1,2-环己二醇的研究[D].郑州：郑州大学,2003
[40]Domanska U, Marciniak M. Experimental (solid+liquid) phase equilibria of (alkan-1-ol+benzonitrile), (amine+benzonitrile) binary mixtures, and (decan-1-ol+decylamine+benzonitrile) ternary mixtures[J]. Fluid Phase Equilibria, 2007,251(2):161-166
[41]Liu Y, Wang J K, Wang X B, et al. Solubility of valsartan in different organic solvents and ethanol+water binary mixtures from (278.15 to 313.15) K[J]. Journal of Chemical & Engineering Data,2009,54(3):986-988
[42]高玉国.反式-1,2-环己二醇三元体系固液相平衡研究[D].郑州：郑州大学,2006
[43]孙晓波.混合二元酸综合利用工程基础研究[D].郑州：郑州大学,2007
[44]Li D Q, Liu J C, Liu D Z, et al. Solubilities of terephthalaldehydic, p-toluic, benzoic, terephthalic and isophthalic acids in N,N-dimethylformamide from 294.75 to 370.45 K[J]. Fluid Phase Equilibria,2002,200(11):69-74
[45]Hu Y H, Chen X, Yang W G, et al. Measurement and correlation of the solubility of urea 1-tartaric acid in aqueous ethanol solution[J]. Thermochimica Acta,2009, 484(1-2):38-40
[46]王静康陈慧萍,尹秋响,等.维生素C结晶物系相图的测定[J].化学工业与工程,1999,16(1)：11-14
[47]叶青,裘兆蓉,王车礼,等.DDHI-DIPP二元体系固液平衡数据的测定和关联[J].高校化学工程学报,2001,15(3)：262-265
[48]魏东炜,姜浩锡,袁继堂,等.4-羟基苯甲醛及其溴代物固液平衡数据测定与关联[J].化工学报,2003,54(10)：1459-1462
[49]Wei D W, Jin K X. (Solid+liquid) equilibria of (naphthalene+isomeric dichlorobenzenes)[J]. The Journal of Chemical Thermodynamics,2009,41(2): 145-149
[50]Carareto N D D, Costa M C, Rolemberg M P, et al. The solid-liquid phase diagrams of binary mixtures of even saturated fatty alcohols[J]. Fluid Phase Equilibria,2011, 303(2):191.el-191.e8
[51]曲红梅,周立山,杨志才,等.有机物系固-液相平衡理论研究评述[J].天然气化工,2004,29(6)：57-60
[52]黎文超,宣爱国,吴元欣,等.固液平衡的研究进展[J].石油化工,2007,36(10)：1067-1073
[53]黎文超.合成碳酸二苯酯相关体系固液平衡研究[D].武汉：武汉工程大学,2008
[54]Hino T, Prausnitz J M. Solid-liquid equilibria for solutions of binary globular-protein mixtures[J]. AIChE Journal,1999,45(3):622-632
[55]Deng T, Horiuchi S, Roy L E, et al. Solubility of anthracene in ternary 2-butoxyethanol +alkane+propanol solvent mixtures[J]. Journal of Chemical & Engineering Data, 1999,44(2):258-261
[56]Peng C, Liu H, Hu Y. Solid-liquid equilibria based on an equation of state for chain fluids[J]. Fluid Phase Equilibria,2001,180(1-2):299-311
[57]Tumkaka F, Prikhodko I V, Sadowski G. Modeling of solid-liquid equilibria for systems with solid-complex phase formation[J]. Fluid Phase Equilibria,2007,260(1): 98-104
[58]Cuevas J, Llovell F, Galindo A, et al. Solid-liquid equilibrium using the SAFT-VR equation of state:Solubility of naphthalene and acetic acid in binary mixtures and calculation of phase diagrams[J]. Fluid Phase Equilibria,2011,306(1):137-147
[59]Wilson G M. Vapor-liquid equilibrium. XI. A new expression for the excess free energy of mixing[J]. Journal of the American Chemical Society,1964,86(2):127-130
[60]Renon H, Prausnitz J M. Local compositions in thermodynamic excess functions for liquid mixtures[J].AIChE Journal,1968,14(1):135-144
[61]Jia Q Z, Ma P S, Ma S N, et al. Solid-liquid equilibria of benzoic acid derivatives in 1-Octanol[J]. Chinese Journal of Chemical Engineering,2007,15(5):710-714
[62]Wei D W, Pei Y H, Zhang C, et al. Measurement and correlation of solid-liquid equilibria of phenyl salicylate with C4 alcohols [J]. Chinese Journal of Chemical Engineering,2009,17(1):140-144
[63]Shi X H, Li M, Zhou C R. Measurement and correlation for solubility of 2-chloro-5-chloromethylpyridine in different solvents [J]. Chinese Journal of Chemical Engineering,2010,18(4):654-658
[64]Domanska U, Kozlowska M K. Solubility of imidazoles in ketones[J]. Fluid Phase Equilibria,2003,206(1-2):253-266
[65]马沛生,董奕,许文.顺丁烯二酸酐在直链二酸二乙酯类溶剂中固液平衡研究[J].化学工程,2000,28(4)：48-51
[66]李尤,马沛生,陈明鸣,等.苯甲酸和苯二元羧酸类物质在乙醇中的溶解度测定与关联[J].高校化学工程学报,2006,20(2)：282-286
[67]Domanska U, Morawski P. (Solid+liquid) equilibria of (nalkanes+ethyl 1, 1-dimethylpropyl ether)[J]. The Journal of Chemical Thermodynamics,2001,33(10): 1215-1226
[68]Zilnik L F, Jazbinsek A, Hvala A, et al. Solubility of sodium diclofenac in different solvents[J]. Fluid Phase Equilibria,2007,261(1-2):140-145
[69]Safaeefar P, Ang H M, Kuramochi H, et al. Measurement and correlation of the solubility of MnSO4·H2O in ethanol+water+MgSO4·7H2O solutions[J]. Fluid Phase Equilibria,2006,250(1-2):64-69
[70]Lin H M, Chou Y H, Wu F L, et al. Solid-liquid equilibria of closely boiling compounds of 4-methoxyphenol and catechol with p-cresol[J]. Fluid Phase Equilibria, 2004,220(1):69-74
[71]Domanska U, Morawski P, Wierzbicki R. Phase diagrams of binary systems containing n-alkanes, or cyclohexane, or 1-alkanols and 2,3-pentanedione at atmospheric and high pressure[J]. Fluid Phase Equilibria,2006,242(2):154-163
[72]Song W W, Ma P S, Fan L H, et al. Solubility of glutaric acid in cyclohexanone, cyclohexanol, their five mixtures and acetic acid[J]. Chinese Journal of Chemical Engineering,2007,15(2):228-232
[73]Kehiaian H V. Thermodynamics of binary liquid organic mixtures[J]. Pure & Applied Chemistry,1985,57(1):15-30
[74]Domanska U, Gonzalez J A. Thermodynamics of branched alcohols:Ⅱ. Solid-liquid equilibria for systems containing tert-butanol and long-chain n-alkanes. Experimental results and comparison with DISQUAC predictions [J]. Fluid Phase Equilibria,1998, 147(1-2):251-270
[75]Domanska U, Lachwa J, Gonzalez JA. Thermodynamics of binary mixtures containing N-methyl-2-pyrrolidinone:VLE measurements for systems with ethers-Comparison with the Mod. UNIFAC (Do) and DISQUAC models-Predictions for VLE, GmE, HmE, and SLE[J]. Fluid Phase Equilibria,2005,235(2):182-190
[76]Gonzalez J A, Mozo I, Garcia I, et al. Thermodynamics of 1-alkanol+cyclic ether mixtures[J]. Fluid Phase Equilibria,2006,245(2):168-184
[77]Domanska U, Gloskowska M. Experimental solid+liquid equilibria and excess molar volumes of alkanol+hexylamine mixtures:Analysis in terms of the ERAS, DISQUAC and Mod. UNIFAC models[J]. Fluid Phase Equilibria,2004,216(1):135-145
[78]Abrams D S, Prausnitz J M. Statistical thermodynamics of liquid mixtures:A new expression for the excess Gibbs energy of partly or completely miscible systems [J]. AIChE Journal,1975,21(1):116-128
[79]Gong X C, Wang S S, Qu H B. Solid-liquid equilibria of D-glucose, D-fructose and sucrose in the mixture of ethanol and water from 273.2 K to 293.2 K[J]. Chinese Journal of Chemical Engineering,2011,19(2):217-222
[80]Domanska U, Pobudkowska A, Gierycz P. Experimental solid-liquid phase equilibria of{cholesterol+binary solvent mixture:1-alcohol (C4-C10)+cyclohexane}[J]. Fluid Phase Equilibria,2010,289(1):20-31
[81]Ali S H. Measurement and prediction of pyrene solubility in pure, binary, ternary and quaternary solvent systems[J]. Fluid Phase Equilibria,2008,264(1-2):29-44
[82]Domanska U, Krolikowski M. Phase equilibrium study of the binary systems (N-hexyl-3-methylpyridinium tosylate ionic liquid+water, or organic solvent)[J]. The Journal of Chemical Thermodynamics,2011,43(10):1488-1494
[83]Fredenslund A, Jones R L, Prausnitz J M. Group-contribution estimation of activity coefficients in nonideal liquid mixtures[J]. AIChE Journal,1975,21(6):1086-1099
[84]Gmehling J G, Anderson T F, Prausnitz J M. Solid-liquid equilibria using UNIFAC[J]. Industrial & Engineering Chemistry Fundamentals,1978,17(4):269-273
[85]Ma P S, Xia Q. Determination and correlation for solubility of aromatic acids in solvents[J]. Chinese Journal of Chemical Engineering,2001,9(1):39-44
[86]Qu H M, Bai P, Yang Z C, et al. Solid-liquid equilibria of musk Ketone, musk xylene and 1,3-dimethyl-2,4-dinitro-5-tert-butyl benzene[J]. Chinese Journal of Chemical Engineering,2004,12(2):294-296
[87]Xia Q, Ma P S. Measurement and correlation for solubility of dimethyl-2,6-naphthalene dicarboxylate in organic solvents[J]. Chinese Journal of Chemical Engineering,2007,15(2):215-220
[88]Chen Y P, Tang M, Kuo J C. Solid-liquid equilibria for binary mixtures of N-phenylacetamide with 4-aminoacetophenone,3-hydroxyacetophenone and 4-hydroxyacetophenone[J]. Fluid Phase Equilibria,2005,232(1-2):182-188
[89]Zhou C R, Shi X H, Wang H F, et al. Solid-liquid equilibria of trans-1, 2-cyclohexanediol+butyl acetate+water ternary system[J]. Chinese Journal of Chemical Engineering,2007,15(003):449-452
[90]Mao Z, Sun X, Luan X, et al. Measurement and correlation of solubilities of adipic acid in different solvents[J]. Chinese Journal of Chemical Engineering,2009,17(3): 473-477
[91]Buchowski H, Ksiazczak A, Pietrzyk S. Solvent activity along a saturation line and solubility of hydrogen-bonding solids[J]. The Journal of Physical Chemistry,1980, 84(9):975-979
[92]周彩荣,石晓华,冯伟,等.新戊二醇在溶剂中溶解度的测定及关联[J].高校化学 工程学报,2010,24(3)：365-369
[93]Wang S, Wang J K, Yin Q X. Measurement and correlation of solubility of 7-aminocephalosporanic acid in aqueous acetone mixtures[J]. Industrial & Engineering Chemistry Research,2005,44(10):3783-3787
[94]Yao X D, Li Y X, Luo T L, et al. Solubilities of N-[(4-bromo-3,5-difluorine) phenyl]-acrylamide in methanol-ethanol solution[J]. Fluid Phase Equilibria,2010, 288(1-2):96-98
[95]Hu Y H, Chen X, Yang W G, et al. Measurement and correlation of the solubility of 1-(4-methyl-l-naphthyl) ethanone in an aqueous ethanol solution[J]. Fluid Phase Equilibria,2010,288(1-2):83-86
[96]Liu B S, Gong J B, Wang J K, et al. Solubility of potassium clavulanate in ethanol, 1-propanol,1-butanol,2-propanol, and 2-methyl-l-propanol between 273 K and 305 K[J]. Journal of Chemical & Engineering Data,2005,50(5):1684-1686
[97]Zhou C R, Wang H F, Jiang D G. Solubility of trans-1,2-cyclohexanediol in some solvents[J]. Chinese Journal of Chemical Engineering,2005,13(4):560-563
[98]王利生,欧阳霞,韩君,等.有机含磷化合物溶解度的测定与关联[J].化学工业与工程,2006,23(5)：420-422,452
[99]江燕斌,李凯霞,张扬,等.β-蒿甲醚在五种有机溶剂中溶解度的测定与关联[J].高校化学工程学报,2009,23(6)：911-915
[100]Apelblat A, Manzurola E. Solubilities ofo-acetylsalicylic,4-aminosalicylic, 3,5-dinitrosalicylic, andp-toluic acid, and magnesium-DL-aspartate in water from T= (278 to 348) K[J]. The Journal of Chemical Thermodynamics,1999,31(1):85-91
[101]Yang Z S, Zeng Z X, Xue W L, et al. Solubility of bis(benzoxazolyl-2-methyl) sulfide in different pure solvents and ethanol+water binary mixtures between (273.25 and 325.25) K[J]. Journal of Chemical & Engineering Data,2008,53(11):2692-2695
[102]Luan L J, Zhou Y, Wu Y J, et al. Solubility of scutellarin in methanol, water, ethanol, and ethanol+water binary mixtures from (293.2 to 333.2) K[J]. Journal of Chemical & Engineering Data,2010,55(11):5299-5301
[103]徐衡,董奕,马沛生.顺丁烯二酸酐在邻苯二甲酸酯中溶解度的研究[J].石油化工,2000,29(7)：501-504
[104]李殿卿,刘大壮,王福安.对羧基苯甲醛、对甲基苯甲酸、苯甲酸、对苯二甲酸和间苯二甲酸在N,N-二甲基甲酰胺中的溶解度[J].高校化学工程学报,2001,15(3)：258-261
[105]邹莹,刘永琼,祝宏,等.替硝唑在水溶液中溶解度的实验测定及关联[J].武汉工程大学学报,2008,3(1)：7-9
[106]沈玉芳陈,胡小安.热分析动力学处理方法现状及进展[J].中南民族大学学报(自然科学版),2002,21(3)：11-15
[107]任宁,张建军.热分析动力学数据处理方法的研究进展[J].化学进展,2006,18(4)：410-416
[108]Materazzi S, Aquili S, De Angelis Curtis S, et al. Biomimetic complexes:thermal stability, kinetic study and decomposition mechanism of Co (Ⅱ)-, Ni (Ⅱ)-and Cu (Ⅱ)-4 (5)-hydroxymethyl-5 (4)-methylimidazole complexes[J]. Thermochimica Acta,2004, 421(1-2):19-24
[109]Yu H M, Zhang Q H, Qi L J, et al. Thermal kinetic, analysis of InN by TG-MS combined with PulseTA[J]. Thermochimica Acta,2006,451(1-2):10-15
[110]Kiiciik F, Yildiz K. The decomposition kinetics of mechanically activated alunite ore in air atmosphere by thermogravimetry[J]. Thermochimica Acta,2006,448(2):107-110
[111]Leroy V, Cancellieri D, Leoni E. Thermal degradation of ligno-cellulosic fuels:DSC and TGA studies[J]. Thermochimica Acta,2006,451(1-2):131-138
[112]Bernardo da Cruz A G, Wardell J L, Rocco A M. The decomposition kinetics of [Et4N]2[M(dmit)2] (M=Ni, Pd) in a nitrogen atmosphere using thermogravimetry[J]. Thermochimica Acta,2006,443(2):217-224
[113]Starink M J. A new method for the derivation of activation energies from experiments performed at constant heating rate[J]. Thermochimica Acta,1996,288(1-2):97-104
[114]Malek J. The kinetic analysis of non-isothermal data[J]. Thermochimica Acta,1992, 200:257-269
[115]Wilburn F W, Dollimore D. Non-isothermal kinetics:a different approach[J]. Thermochimica Acta,2000,357:141-145
[116]Saha B, Ghoshal A K. Model-free kinetics analysis of waste PE sample[J]. Thermochimica Acta,2006,451(1-2):27-33
[117]Saha B, Ghoshal A K. Model-free kinetics analysis of ZSM-5 catalyzed pyrolysis of waste LDPE[J]. Thermochimica Acta,2007,453(2):120-127
[118]张健,陈栋华,袁誉洪,等.三氮唑核苷的热稳定性及其热分解动力学研究[J].药学学报,2001,36(6)：452-455
[119]张名楠,王镇江,周雪晴.热分析法研究头孢菌素类药物的热稳定性和贮存期[J].化学工程师,2011,192(9)：4-7
[120]王学杰,游金宗.司他夫定的热分解机理及动力学[J].应用化学,2011,28(6)：709-715
[121]冯伟.萘普生的工艺改进和工程数据的测定[D].郑州：郑州大学,2009
[122]钟华.脱氢极酸热力学性质测定及其分子几何结构的优化[D].南宁：广西大学,2008
[123]杨利,裴琴,曹允玲,等.碳酰肼的溶解度、溶解焓及其在溶剂中的溶解反应[J].含能材料,2007,15(3)：224-227
[124]Banerjee A, Prasad R, Venugopal V. Calorimetric studies on Rb2U4O11 (s) and Tl2U4O11 (s)[J]. Journal of Alloys and Compounds,2001,322(1-2):265-268
[125]徐芬,孙立贤,谭志诚,等.阿司匹林的热解机理及热动力学研究[J].物理化学学报,2004,20(1)：50-54
[126]祝远姣,陈小鹏,王琳琳,等.脱氢枞酸在空气中的热分解动力学[J].化工学报,2008,59(10)：2526-2530
[127]卢林刚,杨守生,张燕,等.新型磷系阻燃剂1,3,5-三(5,5-二甲基-1,3-二氧杂-2-氧代己内磷酰基-2-氧)苯的合成及热分解动力学研究[J].化学学报,2009,67(14)：1695-1699
[128]徐抗震,赵凤起,杨冉,等.GNTO的热分解动力学和比热容及绝热至爆时间研究[J].固体火箭技术,2009,32(1)：74-78
[129]李爱玲,熊金平,左禹,等.聚氨酯胶粘剂的热分解动力学[J].物理化学学报,2007,23(10)：1622-1626
[130]Yi J H, Zhao F Q, Gao H X et al. Preparation, characterization, non-isothermal reaction kinetics, thermodynamic properties, and safety performances of high nitrogen compound:Hydrazine 3-nitro-1,2,4-triazol-5-one complex[J]. Journal of Hazardous Materials,2008,153(1-2):261-268
[131]Ma H X, Yan B, Li J F et al. Molecular structure, thermal behavior and adiabatic time-to-explosion of 3,3-dinitroazetidinium picrate[J]. Journal of Molecular Structure, 2010981(1-3):103-110
[132]王韶旭,林璐,谭志诚,等.柚皮苷的热稳定性及其热分析动力学研究[J].化学学报,2010,68(21)：2156-2160
[133]祝远姣,陈小鹏,周龙昌,等.脱氢枞酸的非等温热分解动力学[J].高校化学工程学报,2009,23(3)：434-439
[134]Azimi H R, Rezaei M, Abbasi F, et al. Non-isothermal degradation kinetics of MMA-St copolymer and EPS lost foams[J]. Thermochimica Acta,2008,474(1-2): 72-77
[135]Cao X M, Li J, Yang X, et al. Nonisothermal kinetic analysis of the effect of protein concentration on BSA aggregation at high concentration by DSC[J]. Thermochimica Acta,2008,467(1-2):99-106
[136]Leng Y H, Xie L, Liao F H, et al. Kinetic and thermodynamics studies on the decompositions of Ni3C in different atmospheres[J]. Thermochimica Acta,2008, 473(1-2):14-18
[137]Ortega A. A simple and precise linear integral method for isoconversional data[J]. Thermochimica Acta,2008,474(1-2):81-86
[138]罗登林,丘泰球,卢群.超声波技术及应用(Ⅳ)—超声波技术在其他方面的应用[J].日用化学工业,2006,36(2)：120-123
[139]罗登林,丘泰球,卢群.超声波技术及应用(Ⅰ)—超声波技术[J].日用化学工业,2005,35(5)：323-326
[140]郭志超,李鸿,王静康,等.超声波对结晶过程的作用及机理[J].天津化工,2003,17(3)：1-3
[141]祝远姣,陈小鹏,陈月圆,等.超声波协同反应-结晶耦合单离脱氢枞酸[J].化工学报,2008,59(4)：920-926
[142]宋传奎,肖斌,王艳丽,等.超声波辅助提取茶多酚工艺条件的优化[J].西北农林科技大学学报(自然科学版),2011,39(5)：133-139
[143]彭川丛,孔静,游丽君,等.超声波辅助热水浸提香菇多糖响应面优化工艺及其抗氧化活性的研究[J].现代食品科技,2011,27(4)：452-456
[144]汪怀建,谭文津,丁雪杉,等.超声波辅助提取玉米芯中木聚糖条件优化研究[J].中国粮油学报,2009,24(7)：50-54
[145]靳熙茜,汪海波,王枫,等.超声波辅助提取桂花总黄酮的工艺研究[J].武汉工业学院学报,2009,28(4)：21-24
[146]耿敬章.桂树叶中类黄酮化合物的超声波辅助提取研究[J].中国食品添加剂,2009,(1)：142-145
[147]杨建斌,陈明锴,汤世华,等.超声波辅助制备微生物柴油的研究[J].武汉工业学院学报,2008,27(1)：23-27
[148]吴桐,何勇,韦嘉,等.聚乳酸-聚乙二醇嵌段共聚物结晶行为研究[J].高等学校化学学报,2006,27(11)：2193-2197
[149]陈晓蕾,邵玮,李春忠.原位聚合制备PET/ATO纳米复合材料及其结晶行为[J].高校化学工程学报,2007,21(2)：334-340
[150]王国宇,张彬,周武,等.超声波对三氯蔗糖结晶过程的影响[J].食品科技,2011,36(6)：108-111
[151]Feliciano A S, del Corral J M M, Gordaliza M, et al.13C NMR data for abieta-7,13-diene diterpenoids[J]. Magnetic Resonance in Chemistry,1993,31(9): 841-844
[152]贺近恪,李启基.林产化学工业全书[M].北京：中国林业出版社,2001.1085
[153]李华昌,符斌.实用化学手册[M].北京：化学工业出版社,2006
[154]Sandler S I. Chemical and engineering thermodynamics,3rd ed. (化学和工程热力学,第三版)[M].北京：化学工业出版社,2002
[155]陈维钧,陈建中.用DSC法测定BBO、LBO和CLBO晶体的恒压比热容[J].人工晶体学报,2003,32(2)：152-155
[156]谢宏昭,周龙昌,陈小鹏等.枞酸在四种醇类溶剂中的溶解度测定与关联[J].高校化学工程学报,2011,25(3)：385-389
[157]谢宏昭.枞酸在九种溶剂中固液相平衡研究[D].南宁：广西大学,2011
[158]Stepen H S T. Solubility of inorganic and organic compounds[M]. Oxford:Pergamon Press,1963
[159]Prausnitz J M, Lichtenthaler R N,著.陆小华,刘洪,译.Molecular thermodynamics of fluid phase equilibria(流体相平衡的分子热力学)[M].北京：化学工业出版社,2006
[160]Prausnitz J M. Molecular thermodynamics of fluid phase equilibria[M]. Englewood Cliffs, New Jersey:Prentice-Hall Inc.,1986
[161]贾青竹,马沛生,王昶,等.取代苯甲酸类在水中固液平衡的研究[J].环境化学,2006,25(2)：128-132
[162]贾青竹,马沛生,王昶,等.2,4-二氯苯酚在水中溶解度的测定及关联[J].化学工程,2006,34(8)：44-47
[163]Jia Q Z, Ma P S, Zhou H et al. The effect of temperature on the solubility of benzoic acid derivatives in water[J]. Fluid Phase Equilibria,2006,250(1-2):165-172
[164]Long B W, Yang Z R. Measurements of the solubilties of m-phthalic acid in acetone, ethanol and acetic ether[J]. Fluid Phase Equilibria,2008,266(1-2):38-41
[165]喻桂朋,佟俊,刘程,等.主链含苯基均三嗪联苯型聚芳醚的热稳定性[J].高分子材料科学与工程,2010,26(4)：75-77
[166]Ren Y L, Cheng B W, Jiang A B et al. Thermal degradation kinetics of poly (O, O-diethyl-O-allylthiophosphate-co-acrylonitrile) in nitrogen[J]. Journal of Applied Polymer Science,2010,115(6):3705-3709
[167]Rodante F, Vecchio S, Tomassetti M. Kinetic analysis of thermal decomposition for penicillin sodium salts:Model-fitting and model-free methods[J]. Journal of Pharmaceutical and Biomedical Analysis,2002,29(6):1031-1043
[168]Al-Othman A A, Al-Farhan K A, Mahfouz R M. Kinetic analysis of nonisothermal decomposition of (Mgs(CO3)4(OH)2·4H2O/5Cr2O3) crystalline mixture[J]. Journal of King Saud University (Science),2009,21(2):133-143
[169]Yi J H, Zhao F Q, Xu S Y, et al. Effects of pressure and TEGDN content on decomposition reaction mechanism and kinetics of DB gun propellant containing the mixed ester of TEGDN and NG[J]. Journal of Hazardous Materials,2009,165(1-3): 853-859
[170]Ma H X, Yan B, Li Z N, et al. Synthesis, molecular structure, non-isothermal decomposition kinetics and adiabatic time to explosion of 3,3-dinitroazetidinium 3, 5-dinitrosalicylate[J]. Journal of thermal analysis and calorimetry,2009,95(2): 437-444
[171]任元林,程博闻,张金树,等.N,N'-二(5,5-二甲基-2-磷杂-2-硫代-1,3-二噁烷-2-基)乙二胺在空气中的热分解动力学研究[J].化学学报,2008,66(9)：1123-1128
[172]胡荣祖,高胜利,赵凤起,等.热分析动力学(第二版)[M].北京：科学出版社,2008.151-155
[2]陈素文.松香松节油深度加工技术与利用[M].北京：中国林业出版社,1997.23
[3]王琳琳.松香、松节油及松脂中分子间氢转移催化反应的研究[D].南宁：广西大学,2007
[4]Ellingson E O. On abietic acid and some of its salts[J]. Journal of the American Chemical Society,1914,36(2):325-335
[5]Gubelmann I, Henke C O, Lee H R. Process of preparing abietic acid[P]. US:US 1846639 (A),1932.2.23
[6]Steele L L. Abietic acid and certain metal abietatesl[J]. Journal of the American Chemical Society,1922,44(6):1333-1341
[7]Palkin S, Harris T H. The Preparation of 1-abietic acid (Schulz) and properties of some of its salts[J]. Journal American Chemical Society,1934,56(9):1935-1937
[8]Harris G C, Sanderson T F. Resin acids. I. An improved method of isolation of resin acids; the isolation of a new abietic-type acid, neoabietic acid[J]. Journal American Chemical Society,1948,70(1):334-339
[9]王文军,戴乾圜.(-)-7,13-二烯-18-枞酸的提取与纯化及其结构鉴定[J].北京工业大学学报,2000,26(4)：77-79
[10]韩春蕊,宋湛谦,商士斌.提纯枞酸的新方法[J].林产化学与工业,2007,27(4)：42-46
[11]姚兴东,聂园梅,蓝丽红,等.一种枞酸的制备方法[P].中国：CN101020630A,2007.8.22
[12]高艺美,廖晨伊,韦小杰,等.松香树脂酸异构化反应研究[J].化学研究与应用,2009,21(11)：1533-1538
[13]高艺美,廖晨伊,韦小杰,等.超声波强化胺盐法单离枞酸的研究[J].高校化学工程学报,2009,23(4)：725-728
[14]刘红军,周永红.一种枞酸的制备方法[P]. CN101219949A,2008.7.16
[15]Jin Z M, Pan Y J, Liu J G, et al. Separation of rosin acids by molecular recognition: crystal structure of the complex of neoabietic acid with 2-amino-6-methyl-pyridine[J]. Journal of Chemical Crystallography,2000,30(3):195-198
[16]金志敏,尚四华.新枞酸与2-氨基-6-甲基-吡啶的共晶识别[J].中草药,2000,31(11)：811-812
[17]Luong J H T, Rigby T, Male K B, et al. Separation of resin acids using cyclodextrin-modified capillary electrophoresis[J]. Electrophotesis,1999,20(7): 1546-1554
[18]Osete-Cortina L, Domenech-Carbo M T, Mateo-Castro R, et al. Identification of diterpenes in canvas painting varnishes by gas chromatography-mass spectrometry with combined derivatisation[J]. Journal of Chromatography A,2004,1024(1-2): 187-194
[19]Lee B L, Koh D, Ong H Y, et al. High-performance liquid chromatographic determination of dehydroabietic and abietic acids in traditional Chinese medications[J]. Journal of Chromatography A,1997,763:221-226
[20]McMartin D W, Headley J V, Winkler M, et al. Evaluation of liquid chromatography-negative ion electrospray mass spectrometry for the determination of selected resin acids in river water[J]. Journal of Chromatography A,2002,952: 289-293
[21]Aya Y, Yoichiro E, Kohtaro M, et al. Supercritical fluid chromatography of free resin acids on an ODS-silica gel column[J]. Journal of Chromatography A,1995,709: 345-349
[22]Lin C H, Chuang H S. Use of abietic acid or derivative thereof for modulation permeability of plasma membrane[P]. US:US2004063788(A1),2004.04.01
[23]Nobuyuki T, Teruo K, Tsuyoshi G, et al. Abietic acid activates peroxisome proliferator-activated receptor-γ(PPARγ) in RAW264.7 macrophages and 3T3-L1 adipocytes to regulate gene expression involved in inflammation and lipid metabolism[J]. FEBS Lett,2003,550:190-194
[24]Morkhade D M, Nande V S, Barabde U V, et al. PEGylated rosin derivatives:Novel microencapsulating materials for sustained drug delivery[J]. AAPS PharmSciTech, 2007,8(2):E134-E142
[25]Fulzele S V, Satturwar P M, Dorle A K. Novel biopolymers as implant matrix for the delivery of ciprofloxacin:Biocompatibility, degradation, and in vitro antibiotic release[J]. Journal of pharmaceutical sciences,2007,96(1):132-144
[26]Tohoku, Kyodo, Kagakukogyo, et al. Compositions pour usages agricoles[P]. FR: FR1381645(A),1964.12.14
[27]Koushi M, Fujii R, Ishihara K, et al. Agricultural fungicide[P]. JP:JP57088102(A), 1982.06.01
[28]Yadav J S, Baishya G, Dash U. Synthesis of (+)-amberketal and its analog from 1-abietic acid[J]. Tetrahedron,2007,63:9896-9902
[29]Alvarez-Manzaneda E, Chahboun R, Cabrera E, et al. First synthesis of picealactone C. A new route toward taxodione-related terpenoids from abietic acid[J]. Tetrahedron Letters,2007,48(6):989-992
[30]Santos C D, Zukerman-Schpector J, Imamura P M. Chemical transformation of abietic acid to new chiral derivatives [J]. Journal of the Brazilian Chemical Society,2003,14: 998-1004
[31]Gigante B, Santos C, Silva A M, et al. Catechols from abietic acid:synthesis and evaluation as bioactive compounds[J]. Bioorganic & Medicinal Chemistry,2003,11(8): 1631-1638
[32]Wang H H, Liu B, Liu X Q, et al. Synthesis of biobased epoxy and curing agents using rosin and the study of cure reactions[J]. Green Chemistry,2008,10(11):1190-1196
[33]Liu X Q, Xin W B, Zhang J W. Rosin-based acid anhydrides as alternatives to petrochemical curing agents[J]. Green Chemistry,2009,11(7):1018-1025
[34]Joerg K, Hermann H, Detlef H, et al. Hair conditioner for improving the dry combability of fine hair[P]. DE:DE4438115(A1),1996.05.02
[35]Miyamoto N, Ikeuchi T. Hair cosmetic composition[P]. JP:JP60001112(A), 1985.01.07
[36]Sato K. Pigment surface-treated with abietic ester, and cosmetic containing same[P]. JP:JP2000095966(A),2000.04.04
[37]Zhang X W, Yin Q X, Gong J B, et al. Solubility of 5-Amino-N,N'-bis(2,3-dihydroxypropyl)-2,4,6-triiodobenzene-1,3-dicarboxamide in Ethanol+Water Mixtures[J]. Journal of Chemical & Engineering Data,2010,55(6): 2355-2357
[38]Li R R, Zhao H K, Jiang S N, et al. Solubility of 1,6-naphthalene disulfonic acid disodium in binary sodium chloride+water, sodium sulfate+water, and ethanol+ water solvent mixtures at elevated temperatures [J]. Journal of Chemical & Engineering Data,2011,56(5):2692-2695
[39]周彩荣.由环己烯制备1,2-环己二醇的研究[D].郑州：郑州大学,2003
[40]Domanska U, Marciniak M. Experimental (solid+liquid) phase equilibria of (alkan-1-ol+benzonitrile), (amine+benzonitrile) binary mixtures, and (decan-1-ol+decylamine+benzonitrile) ternary mixtures[J]. Fluid Phase Equilibria, 2007,251(2):161-166
[41]Liu Y, Wang J K, Wang X B, et al. Solubility of valsartan in different organic solvents and ethanol+water binary mixtures from (278.15 to 313.15) K[J]. Journal of Chemical & Engineering Data,2009,54(3):986-988
[42]高玉国.反式-1,2-环己二醇三元体系固液相平衡研究[D].郑州：郑州大学,2006
[43]孙晓波.混合二元酸综合利用工程基础研究[D].郑州：郑州大学,2007
[44]Li D Q, Liu J C, Liu D Z, et al. Solubilities of terephthalaldehydic, p-toluic, benzoic, terephthalic and isophthalic acids in N,N-dimethylformamide from 294.75 to 370.45 K[J]. Fluid Phase Equilibria,2002,200(11):69-74
[45]Hu Y H, Chen X, Yang W G, et al. Measurement and correlation of the solubility of urea 1-tartaric acid in aqueous ethanol solution[J]. Thermochimica Acta,2009, 484(1-2):38-40
[46]王静康陈慧萍,尹秋响,等.维生素C结晶物系相图的测定[J].化学工业与工程,1999,16(1)：11-14
[47]叶青,裘兆蓉,王车礼,等.DDHI-DIPP二元体系固液平衡数据的测定和关联[J].高校化学工程学报,2001,15(3)：262-265
[48]魏东炜,姜浩锡,袁继堂,等.4-羟基苯甲醛及其溴代物固液平衡数据测定与关联[J].化工学报,2003,54(10)：1459-1462
[49]Wei D W, Jin K X. (Solid+liquid) equilibria of (naphthalene+isomeric dichlorobenzenes)[J]. The Journal of Chemical Thermodynamics,2009,41(2): 145-149
[50]Carareto N D D, Costa M C, Rolemberg M P, et al. The solid-liquid phase diagrams of binary mixtures of even saturated fatty alcohols[J]. Fluid Phase Equilibria,2011, 303(2):191.el-191.e8
[51]曲红梅,周立山,杨志才,等.有机物系固-液相平衡理论研究评述[J].天然气化工,2004,29(6)：57-60
[52]黎文超,宣爱国,吴元欣,等.固液平衡的研究进展[J].石油化工,2007,36(10)：1067-1073
[53]黎文超.合成碳酸二苯酯相关体系固液平衡研究[D].武汉：武汉工程大学,2008
[54]Hino T, Prausnitz J M. Solid-liquid equilibria for solutions of binary globular-protein mixtures[J]. AIChE Journal,1999,45(3):622-632
[55]Deng T, Horiuchi S, Roy L E, et al. Solubility of anthracene in ternary 2-butoxyethanol +alkane+propanol solvent mixtures[J]. Journal of Chemical & Engineering Data, 1999,44(2):258-261
[56]Peng C, Liu H, Hu Y. Solid-liquid equilibria based on an equation of state for chain fluids[J]. Fluid Phase Equilibria,2001,180(1-2):299-311
[57]Tumkaka F, Prikhodko I V, Sadowski G. Modeling of solid-liquid equilibria for systems with solid-complex phase formation[J]. Fluid Phase Equilibria,2007,260(1): 98-104
[58]Cuevas J, Llovell F, Galindo A, et al. Solid-liquid equilibrium using the SAFT-VR equation of state:Solubility of naphthalene and acetic acid in binary mixtures and calculation of phase diagrams[J]. Fluid Phase Equilibria,2011,306(1):137-147
[59]Wilson G M. Vapor-liquid equilibrium. XI. A new expression for the excess free energy of mixing[J]. Journal of the American Chemical Society,1964,86(2):127-130
[60]Renon H, Prausnitz J M. Local compositions in thermodynamic excess functions for liquid mixtures[J].AIChE Journal,1968,14(1):135-144
[61]Jia Q Z, Ma P S, Ma S N, et al. Solid-liquid equilibria of benzoic acid derivatives in 1-Octanol[J]. Chinese Journal of Chemical Engineering,2007,15(5):710-714
[62]Wei D W, Pei Y H, Zhang C, et al. Measurement and correlation of solid-liquid equilibria of phenyl salicylate with C4 alcohols [J]. Chinese Journal of Chemical Engineering,2009,17(1):140-144
[63]Shi X H, Li M, Zhou C R. Measurement and correlation for solubility of 2-chloro-5-chloromethylpyridine in different solvents [J]. Chinese Journal of Chemical Engineering,2010,18(4):654-658
[64]Domanska U, Kozlowska M K. Solubility of imidazoles in ketones[J]. Fluid Phase Equilibria,2003,206(1-2):253-266
[65]马沛生,董奕,许文.顺丁烯二酸酐在直链二酸二乙酯类溶剂中固液平衡研究[J].化学工程,2000,28(4)：48-51
[66]李尤,马沛生,陈明鸣,等.苯甲酸和苯二元羧酸类物质在乙醇中的溶解度测定与关联[J].高校化学工程学报,2006,20(2)：282-286
[67]Domanska U, Morawski P. (Solid+liquid) equilibria of (nalkanes+ethyl 1, 1-dimethylpropyl ether)[J]. The Journal of Chemical Thermodynamics,2001,33(10): 1215-1226
[68]Zilnik L F, Jazbinsek A, Hvala A, et al. Solubility of sodium diclofenac in different solvents[J]. Fluid Phase Equilibria,2007,261(1-2):140-145
[69]Safaeefar P, Ang H M, Kuramochi H, et al. Measurement and correlation of the solubility of MnSO4·H2O in ethanol+water+MgSO4·7H2O solutions[J]. Fluid Phase Equilibria,2006,250(1-2):64-69
[70]Lin H M, Chou Y H, Wu F L, et al. Solid-liquid equilibria of closely boiling compounds of 4-methoxyphenol and catechol with p-cresol[J]. Fluid Phase Equilibria, 2004,220(1):69-74
[71]Domanska U, Morawski P, Wierzbicki R. Phase diagrams of binary systems containing n-alkanes, or cyclohexane, or 1-alkanols and 2,3-pentanedione at atmospheric and high pressure[J]. Fluid Phase Equilibria,2006,242(2):154-163
[72]Song W W, Ma P S, Fan L H, et al. Solubility of glutaric acid in cyclohexanone, cyclohexanol, their five mixtures and acetic acid[J]. Chinese Journal of Chemical Engineering,2007,15(2):228-232
[73]Kehiaian H V. Thermodynamics of binary liquid organic mixtures[J]. Pure & Applied Chemistry,1985,57(1):15-30
[74]Domanska U, Gonzalez J A. Thermodynamics of branched alcohols:Ⅱ. Solid-liquid equilibria for systems containing tert-butanol and long-chain n-alkanes. Experimental results and comparison with DISQUAC predictions [J]. Fluid Phase Equilibria,1998, 147(1-2):251-270
[75]Domanska U, Lachwa J, Gonzalez JA. Thermodynamics of binary mixtures containing N-methyl-2-pyrrolidinone:VLE measurements for systems with ethers-Comparison with the Mod. UNIFAC (Do) and DISQUAC models-Predictions for VLE, GmE, HmE, and SLE[J]. Fluid Phase Equilibria,2005,235(2):182-190
[76]Gonzalez J A, Mozo I, Garcia I, et al. Thermodynamics of 1-alkanol+cyclic ether mixtures[J]. Fluid Phase Equilibria,2006,245(2):168-184
[77]Domanska U, Gloskowska M. Experimental solid+liquid equilibria and excess molar volumes of alkanol+hexylamine mixtures:Analysis in terms of the ERAS, DISQUAC and Mod. UNIFAC models[J]. Fluid Phase Equilibria,2004,216(1):135-145
[78]Abrams D S, Prausnitz J M. Statistical thermodynamics of liquid mixtures:A new expression for the excess Gibbs energy of partly or completely miscible systems [J]. AIChE Journal,1975,21(1):116-128
[79]Gong X C, Wang S S, Qu H B. Solid-liquid equilibria of D-glucose, D-fructose and sucrose in the mixture of ethanol and water from 273.2 K to 293.2 K[J]. Chinese Journal of Chemical Engineering,2011,19(2):217-222
[80]Domanska U, Pobudkowska A, Gierycz P. Experimental solid-liquid phase equilibria of{cholesterol+binary solvent mixture:1-alcohol (C4-C10)+cyclohexane}[J]. Fluid Phase Equilibria,2010,289(1):20-31
[81]Ali S H. Measurement and prediction of pyrene solubility in pure, binary, ternary and quaternary solvent systems[J]. Fluid Phase Equilibria,2008,264(1-2):29-44
[82]Domanska U, Krolikowski M. Phase equilibrium study of the binary systems (N-hexyl-3-methylpyridinium tosylate ionic liquid+water, or organic solvent)[J]. The Journal of Chemical Thermodynamics,2011,43(10):1488-1494
[83]Fredenslund A, Jones R L, Prausnitz J M. Group-contribution estimation of activity coefficients in nonideal liquid mixtures[J]. AIChE Journal,1975,21(6):1086-1099
[84]Gmehling J G, Anderson T F, Prausnitz J M. Solid-liquid equilibria using UNIFAC[J]. Industrial & Engineering Chemistry Fundamentals,1978,17(4):269-273
[85]Ma P S, Xia Q. Determination and correlation for solubility of aromatic acids in solvents[J]. Chinese Journal of Chemical Engineering,2001,9(1):39-44
[86]Qu H M, Bai P, Yang Z C, et al. Solid-liquid equilibria of musk Ketone, musk xylene and 1,3-dimethyl-2,4-dinitro-5-tert-butyl benzene[J]. Chinese Journal of Chemical Engineering,2004,12(2):294-296
[87]Xia Q, Ma P S. Measurement and correlation for solubility of dimethyl-2,6-naphthalene dicarboxylate in organic solvents[J]. Chinese Journal of Chemical Engineering,2007,15(2):215-220
[88]Chen Y P, Tang M, Kuo J C. Solid-liquid equilibria for binary mixtures of N-phenylacetamide with 4-aminoacetophenone,3-hydroxyacetophenone and 4-hydroxyacetophenone[J]. Fluid Phase Equilibria,2005,232(1-2):182-188
[89]Zhou C R, Shi X H, Wang H F, et al. Solid-liquid equilibria of trans-1, 2-cyclohexanediol+butyl acetate+water ternary system[J]. Chinese Journal of Chemical Engineering,2007,15(003):449-452
[90]Mao Z, Sun X, Luan X, et al. Measurement and correlation of solubilities of adipic acid in different solvents[J]. Chinese Journal of Chemical Engineering,2009,17(3): 473-477
[91]Buchowski H, Ksiazczak A, Pietrzyk S. Solvent activity along a saturation line and solubility of hydrogen-bonding solids[J]. The Journal of Physical Chemistry,1980, 84(9):975-979
[92]周彩荣,石晓华,冯伟,等.新戊二醇在溶剂中溶解度的测定及关联[J].高校化学 工程学报,2010,24(3)：365-369
[93]Wang S, Wang J K, Yin Q X. Measurement and correlation of solubility of 7-aminocephalosporanic acid in aqueous acetone mixtures[J]. Industrial & Engineering Chemistry Research,2005,44(10):3783-3787
[94]Yao X D, Li Y X, Luo T L, et al. Solubilities of N-[(4-bromo-3,5-difluorine) phenyl]-acrylamide in methanol-ethanol solution[J]. Fluid Phase Equilibria,2010, 288(1-2):96-98
[95]Hu Y H, Chen X, Yang W G, et al. Measurement and correlation of the solubility of 1-(4-methyl-l-naphthyl) ethanone in an aqueous ethanol solution[J]. Fluid Phase Equilibria,2010,288(1-2):83-86
[96]Liu B S, Gong J B, Wang J K, et al. Solubility of potassium clavulanate in ethanol, 1-propanol,1-butanol,2-propanol, and 2-methyl-l-propanol between 273 K and 305 K[J]. Journal of Chemical & Engineering Data,2005,50(5):1684-1686
[97]Zhou C R, Wang H F, Jiang D G. Solubility of trans-1,2-cyclohexanediol in some solvents[J]. Chinese Journal of Chemical Engineering,2005,13(4):560-563
[98]王利生,欧阳霞,韩君,等.有机含磷化合物溶解度的测定与关联[J].化学工业与工程,2006,23(5)：420-422,452
[99]江燕斌,李凯霞,张扬,等.β-蒿甲醚在五种有机溶剂中溶解度的测定与关联[J].高校化学工程学报,2009,23(6)：911-915
[100]Apelblat A, Manzurola E. Solubilities ofo-acetylsalicylic,4-aminosalicylic, 3,5-dinitrosalicylic, andp-toluic acid, and magnesium-DL-aspartate in water from T= (278 to 348) K[J]. The Journal of Chemical Thermodynamics,1999,31(1):85-91
[101]Yang Z S, Zeng Z X, Xue W L, et al. Solubility of bis(benzoxazolyl-2-methyl) sulfide in different pure solvents and ethanol+water binary mixtures between (273.25 and 325.25) K[J]. Journal of Chemical & Engineering Data,2008,53(11):2692-2695
[102]Luan L J, Zhou Y, Wu Y J, et al. Solubility of scutellarin in methanol, water, ethanol, and ethanol+water binary mixtures from (293.2 to 333.2) K[J]. Journal of Chemical & Engineering Data,2010,55(11):5299-5301
[103]徐衡,董奕,马沛生.顺丁烯二酸酐在邻苯二甲酸酯中溶解度的研究[J].石油化工,2000,29(7)：501-504
[104]李殿卿,刘大壮,王福安.对羧基苯甲醛、对甲基苯甲酸、苯甲酸、对苯二甲酸和间苯二甲酸在N,N-二甲基甲酰胺中的溶解度[J].高校化学工程学报,2001,15(3)：258-261
[105]邹莹,刘永琼,祝宏,等.替硝唑在水溶液中溶解度的实验测定及关联[J].武汉工程大学学报,2008,3(1)：7-9
[106]沈玉芳陈,胡小安.热分析动力学处理方法现状及进展[J].中南民族大学学报(自然科学版),2002,21(3)：11-15
[107]任宁,张建军.热分析动力学数据处理方法的研究进展[J].化学进展,2006,18(4)：410-416
[108]Materazzi S, Aquili S, De Angelis Curtis S, et al. Biomimetic complexes:thermal stability, kinetic study and decomposition mechanism of Co (Ⅱ)-, Ni (Ⅱ)-and Cu (Ⅱ)-4 (5)-hydroxymethyl-5 (4)-methylimidazole complexes[J]. Thermochimica Acta,2004, 421(1-2):19-24
[109]Yu H M, Zhang Q H, Qi L J, et al. Thermal kinetic, analysis of InN by TG-MS combined with PulseTA[J]. Thermochimica Acta,2006,451(1-2):10-15
[110]Kiiciik F, Yildiz K. The decomposition kinetics of mechanically activated alunite ore in air atmosphere by thermogravimetry[J]. Thermochimica Acta,2006,448(2):107-110
[111]Leroy V, Cancellieri D, Leoni E. Thermal degradation of ligno-cellulosic fuels:DSC and TGA studies[J]. Thermochimica Acta,2006,451(1-2):131-138
[112]Bernardo da Cruz A G, Wardell J L, Rocco A M. The decomposition kinetics of [Et4N]2[M(dmit)2] (M=Ni, Pd) in a nitrogen atmosphere using thermogravimetry[J]. Thermochimica Acta,2006,443(2):217-224
[113]Starink M J. A new method for the derivation of activation energies from experiments performed at constant heating rate[J]. Thermochimica Acta,1996,288(1-2):97-104
[114]Malek J. The kinetic analysis of non-isothermal data[J]. Thermochimica Acta,1992, 200:257-269
[115]Wilburn F W, Dollimore D. Non-isothermal kinetics:a different approach[J]. Thermochimica Acta,2000,357:141-145
[116]Saha B, Ghoshal A K. Model-free kinetics analysis of waste PE sample[J]. Thermochimica Acta,2006,451(1-2):27-33
[117]Saha B, Ghoshal A K. Model-free kinetics analysis of ZSM-5 catalyzed pyrolysis of waste LDPE[J]. Thermochimica Acta,2007,453(2):120-127
[118]张健,陈栋华,袁誉洪,等.三氮唑核苷的热稳定性及其热分解动力学研究[J].药学学报,2001,36(6)：452-455
[119]张名楠,王镇江,周雪晴.热分析法研究头孢菌素类药物的热稳定性和贮存期[J].化学工程师,2011,192(9)：4-7
[120]王学杰,游金宗.司他夫定的热分解机理及动力学[J].应用化学,2011,28(6)：709-715
[121]冯伟.萘普生的工艺改进和工程数据的测定[D].郑州：郑州大学,2009
[122]钟华.脱氢极酸热力学性质测定及其分子几何结构的优化[D].南宁：广西大学,2008
[123]杨利,裴琴,曹允玲,等.碳酰肼的溶解度、溶解焓及其在溶剂中的溶解反应[J].含能材料,2007,15(3)：224-227
[124]Banerjee A, Prasad R, Venugopal V. Calorimetric studies on Rb2U4O11 (s) and Tl2U4O11 (s)[J]. Journal of Alloys and Compounds,2001,322(1-2):265-268
[125]徐芬,孙立贤,谭志诚,等.阿司匹林的热解机理及热动力学研究[J].物理化学学报,2004,20(1)：50-54
[126]祝远姣,陈小鹏,王琳琳,等.脱氢枞酸在空气中的热分解动力学[J].化工学报,2008,59(10)：2526-2530
[127]卢林刚,杨守生,张燕,等.新型磷系阻燃剂1,3,5-三(5,5-二甲基-1,3-二氧杂-2-氧代己内磷酰基-2-氧)苯的合成及热分解动力学研究[J].化学学报,2009,67(14)：1695-1699
[128]徐抗震,赵凤起,杨冉,等.GNTO的热分解动力学和比热容及绝热至爆时间研究[J].固体火箭技术,2009,32(1)：74-78
[129]李爱玲,熊金平,左禹,等.聚氨酯胶粘剂的热分解动力学[J].物理化学学报,2007,23(10)：1622-1626
[130]Yi J H, Zhao F Q, Gao H X et al. Preparation, characterization, non-isothermal reaction kinetics, thermodynamic properties, and safety performances of high nitrogen compound:Hydrazine 3-nitro-1,2,4-triazol-5-one complex[J]. Journal of Hazardous Materials,2008,153(1-2):261-268
[131]Ma H X, Yan B, Li J F et al. Molecular structure, thermal behavior and adiabatic time-to-explosion of 3,3-dinitroazetidinium picrate[J]. Journal of Molecular Structure, 2010981(1-3):103-110
[132]王韶旭,林璐,谭志诚,等.柚皮苷的热稳定性及其热分析动力学研究[J].化学学报,2010,68(21)：2156-2160
[133]祝远姣,陈小鹏,周龙昌,等.脱氢枞酸的非等温热分解动力学[J].高校化学工程学报,2009,23(3)：434-439
[134]Azimi H R, Rezaei M, Abbasi F, et al. Non-isothermal degradation kinetics of MMA-St copolymer and EPS lost foams[J]. Thermochimica Acta,2008,474(1-2): 72-77
[135]Cao X M, Li J, Yang X, et al. Nonisothermal kinetic analysis of the effect of protein concentration on BSA aggregation at high concentration by DSC[J]. Thermochimica Acta,2008,467(1-2):99-106
[136]Leng Y H, Xie L, Liao F H, et al. Kinetic and thermodynamics studies on the decompositions of Ni3C in different atmospheres[J]. Thermochimica Acta,2008, 473(1-2):14-18
[137]Ortega A. A simple and precise linear integral method for isoconversional data[J]. Thermochimica Acta,2008,474(1-2):81-86
[138]罗登林,丘泰球,卢群.超声波技术及应用(Ⅳ)—超声波技术在其他方面的应用[J].日用化学工业,2006,36(2)：120-123
[139]罗登林,丘泰球,卢群.超声波技术及应用(Ⅰ)—超声波技术[J].日用化学工业,2005,35(5)：323-326
[140]郭志超,李鸿,王静康,等.超声波对结晶过程的作用及机理[J].天津化工,2003,17(3)：1-3
[141]祝远姣,陈小鹏,陈月圆,等.超声波协同反应-结晶耦合单离脱氢枞酸[J].化工学报,2008,59(4)：920-926
[142]宋传奎,肖斌,王艳丽,等.超声波辅助提取茶多酚工艺条件的优化[J].西北农林科技大学学报(自然科学版),2011,39(5)：133-139
[143]彭川丛,孔静,游丽君,等.超声波辅助热水浸提香菇多糖响应面优化工艺及其抗氧化活性的研究[J].现代食品科技,2011,27(4)：452-456
[144]汪怀建,谭文津,丁雪杉,等.超声波辅助提取玉米芯中木聚糖条件优化研究[J].中国粮油学报,2009,24(7)：50-54
[145]靳熙茜,汪海波,王枫,等.超声波辅助提取桂花总黄酮的工艺研究[J].武汉工业学院学报,2009,28(4)：21-24
[146]耿敬章.桂树叶中类黄酮化合物的超声波辅助提取研究[J].中国食品添加剂,2009,(1)：142-145
[147]杨建斌,陈明锴,汤世华,等.超声波辅助制备微生物柴油的研究[J].武汉工业学院学报,2008,27(1)：23-27
[148]吴桐,何勇,韦嘉,等.聚乳酸-聚乙二醇嵌段共聚物结晶行为研究[J].高等学校化学学报,2006,27(11)：2193-2197
[149]陈晓蕾,邵玮,李春忠.原位聚合制备PET/ATO纳米复合材料及其结晶行为[J].高校化学工程学报,2007,21(2)：334-340
[150]王国宇,张彬,周武,等.超声波对三氯蔗糖结晶过程的影响[J].食品科技,2011,36(6)：108-111
[151]Feliciano A S, del Corral J M M, Gordaliza M, et al.13C NMR data for abieta-7,13-diene diterpenoids[J]. Magnetic Resonance in Chemistry,1993,31(9): 841-844
[152]贺近恪,李启基.林产化学工业全书[M].北京：中国林业出版社,2001.1085
[153]李华昌,符斌.实用化学手册[M].北京：化学工业出版社,2006
[154]Sandler S I. Chemical and engineering thermodynamics,3rd ed. (化学和工程热力学,第三版)[M].北京：化学工业出版社,2002
[155]陈维钧,陈建中.用DSC法测定BBO、LBO和CLBO晶体的恒压比热容[J].人工晶体学报,2003,32(2)：152-155
[156]谢宏昭,周龙昌,陈小鹏等.枞酸在四种醇类溶剂中的溶解度测定与关联[J].高校化学工程学报,2011,25(3)：385-389
[157]谢宏昭.枞酸在九种溶剂中固液相平衡研究[D].南宁：广西大学,2011
[158]Stepen H S T. Solubility of inorganic and organic compounds[M]. Oxford:Pergamon Press,1963
[159]Prausnitz J M, Lichtenthaler R N,著.陆小华,刘洪,译.Molecular thermodynamics of fluid phase equilibria(流体相平衡的分子热力学)[M].北京：化学工业出版社,2006
[160]Prausnitz J M. Molecular thermodynamics of fluid phase equilibria[M]. Englewood Cliffs, New Jersey:Prentice-Hall Inc.,1986
[161]贾青竹,马沛生,王昶,等.取代苯甲酸类在水中固液平衡的研究[J].环境化学,2006,25(2)：128-132
[162]贾青竹,马沛生,王昶,等.2,4-二氯苯酚在水中溶解度的测定及关联[J].化学工程,2006,34(8)：44-47
[163]Jia Q Z, Ma P S, Zhou H et al. The effect of temperature on the solubility of benzoic acid derivatives in water[J]. Fluid Phase Equilibria,2006,250(1-2):165-172
[164]Long B W, Yang Z R. Measurements of the solubilties of m-phthalic acid in acetone, ethanol and acetic ether[J]. Fluid Phase Equilibria,2008,266(1-2):38-41
[165]喻桂朋,佟俊,刘程,等.主链含苯基均三嗪联苯型聚芳醚的热稳定性[J].高分子材料科学与工程,2010,26(4)：75-77
[166]Ren Y L, Cheng B W, Jiang A B et al. Thermal degradation kinetics of poly (O, O-diethyl-O-allylthiophosphate-co-acrylonitrile) in nitrogen[J]. Journal of Applied Polymer Science,2010,115(6):3705-3709
[167]Rodante F, Vecchio S, Tomassetti M. Kinetic analysis of thermal decomposition for penicillin sodium salts:Model-fitting and model-free methods[J]. Journal of Pharmaceutical and Biomedical Analysis,2002,29(6):1031-1043
[168]Al-Othman A A, Al-Farhan K A, Mahfouz R M. Kinetic analysis of nonisothermal decomposition of (Mgs(CO3)4(OH)2·4H2O/5Cr2O3) crystalline mixture[J]. Journal of King Saud University (Science),2009,21(2):133-143
[169]Yi J H, Zhao F Q, Xu S Y, et al. Effects of pressure and TEGDN content on decomposition reaction mechanism and kinetics of DB gun propellant containing the mixed ester of TEGDN and NG[J]. Journal of Hazardous Materials,2009,165(1-3): 853-859
[170]Ma H X, Yan B, Li Z N, et al. Synthesis, molecular structure, non-isothermal decomposition kinetics and adiabatic time to explosion of 3,3-dinitroazetidinium 3, 5-dinitrosalicylate[J]. Journal of thermal analysis and calorimetry,2009,95(2): 437-444
[171]任元林,程博闻,张金树,等.N,N'-二(5,5-二甲基-2-磷杂-2-硫代-1,3-二噁烷-2-基)乙二胺在空气中的热分解动力学研究[J].化学学报,2008,66(9)：1123-1128
[172]胡荣祖,高胜利,赵凤起,等.热分析动力学(第二版)[M].北京：科学出版社,2008.151-155