聚乙烯胺在加填CaCO_3造纸中助留助滤性能的研究
摘要
随着造纸技术的不断发展，当今世界造纸工业正经历一场由酸性造纸向中碱性造纸的变革。为了开发适应新型条件下的各种造纸化学品，进行了聚乙烯胺(PVAm)在加填CaCO_3造纸中的助留助滤性能的研究。本研究采用胶体滴定技术和紫外可见分光光度法对造纸白水组分的分析来考察两种不同电荷密度的PVAm在我国5种纸浆中的助留助滤效果。论文分析了PVAm的电荷密度受环境酸碱性变化的规律，以及纸浆组分基本性质与PVAm对纸浆的助留助滤效果之间的联系，找出PVAm对加填CaCO_3浆料中的助留助滤效果的最佳条件，为进一步开发适合我国造纸工业的各种添加剂提供理论依据。
Nowadays, with the development of papermaking technology, there is a great transformation from acidic to neutral/alkaline conditons in paper manufacture. To develop the new papermaking polymer additives, such reaserch has been done on the performance of polyvinylamine(PVAm) on retention and drainage of the pulps added with CaCO3. The present studies were conducted to investigate the effection of
PVAm with different charge densities on retention and drainage of the five pulps by means of colloid titration and ultraviolet spectrum. To better develop new polymer additives which will be adapted to China papermaking industry, we should focus our attention on analyzing the relation between the PVAm's charge densities and pH. Based on the relations between the pulp properties and the effection of PVAm on retention and drainage of the pulps, mechanims have been discussed for the retention and drainage of the pulps added with CaCO3.
Nowadays, with the development of papermaking technology, there is a great transformation from acidic to neutral/alkaline conditons in paper manufacture. To develop the new papermaking polymer additives, such reaserch has been done on the performance of polyvinylamine(PVAm) on retention and drainage of the pulps added with CaCO3. The present studies were conducted to investigate the effection of
PVAm with different charge densities on retention and drainage of the five pulps by means of colloid titration and ultraviolet spectrum. To better develop new polymer additives which will be adapted to China papermaking industry, we should focus our attention on analyzing the relation between the PVAm's charge densities and pH. Based on the relations between the pulp properties and the effection of PVAm on retention and drainage of the pulps, mechanims have been discussed for the retention and drainage of the pulps added with CaCO3.
引文
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[29] John H.Klungness, et al. Retention of calcium carbonate during recycling: direct loading versus fiber loading[J].Environmental conference & exhibit, 1997:497-503
[30] Takanori, Miyanishi. Wet end optimization for a neutral PCC filled newsprint machine[J].Tappi Journal, 1999(1): 220-225
[31] B.Alince. Cationic latex as a multifunctional papermaking wet-end additive[J]. Tappi Journal, 1999(3): 175-187
[32] 许安民．网部纸料的动电特性[J]．纸和造纸，2000(2)：19-21
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[37] Zegui Yan, Yulin Deng. Cationic microparticle based flocculation and retention
systems[J]. Chemical Engineering Journal, 2000(80)31-36
[38] Stefan suty, vlasta Luzakova. Role of surface charge in deposition of filler particles onto pulp fibres [J].Colloids and Surfaces, 1998(10): 271-278
[39] Andrea Gibbs, Robert Pelton, et al. The influence of dextran derivative on polyethylene oxide and polyacrylamide-induced calcium carbonate flocculation and floc strength[J]. Colloids and surfaces A, 1999(159): 31-45
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