聚酯类纤维性能研究及其产品开发
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摘要
PTT/PET双组分复合纤维的自卷曲特性使其在弹性及膨松类织物开发上独具优势,市场前景广阔,但目前还没有关于该类纤维及其织物的系统报道。本论文以PTT、PET纤维及PTT/PET双组分复合纤维为研究对象,主要从以下四个方面着手研究。
首先利用科视达观察了PTT/PET双组分复合纤维的外观形态,发现PTT/PET双组分复合纤维中PTT、PET两种组分呈双边分布,横截面呈不对称的哑铃状,PTT和PET两组分分居在横截面两侧,单丝经热处理呈现出三维立体卷曲,在无张力条件下卷曲数最多,在一定的张力范围内,随着所加负荷的增加,PTT/PET双组分复合纤维热处理后的蓬松性及卷曲性均下降显著。当超过一定张力范围时,卷曲性能及蓬松性反而会增大。
其次在大量实验基础上,分析了加热介质、时间、温度及张力四个因素对聚酯类纤维热收缩性能的影响,结果发现,在干热加热介质、张力不变的条件下,随着处理时间或处理温度的增加,PTT、PET纤维及PTT/PET双组分复合纤维的卷曲收缩率均呈增大趋势,PTT/PET双组分复合纤维在140～160℃时卷曲收缩率基本稳定。在湿热为加热介质、张力不变的条件下,随着处理时间或处理温度的增加,PTT、PET纤维及PTT/PET双组分复合纤维卷曲收缩率基本呈增加趋势,PTT/PET双组分复合纤维湿热收缩率与处理时间呈非线性变化,在加热的起始阶段,卷曲收缩率迅速增加,随之变缓,约20min后收缩趋于稳定。在干热或湿热为加热介质、温度及时间不变的情况下,PTT、PET纤维的卷曲收缩率随负荷的增加略微减小,而PTT/PET双组分复合纤维的卷曲收缩率呈双曲线形状,在张力<11.5mg/D时,随张力增加而卷曲收缩率减小的情况很明显,但在张力>11.5mg/D时,随张力的增加卷曲收缩率变化不大。
再次测试分析了聚酯类纤维机械性能特征,发现PTT/PET双组分复合纤维典型的应力-应变特征曲线可划分为6个不同的拉伸阶段,具有与PET纤维显著不同的两个弹性区域及两个塑性区域。在PTT/PET双组分复合纤维中,随PTT组分含量增加,卷曲伸长率逐渐增大,模量逐渐下降。
在干热、1mg/D张力条件下,温度从100℃逐渐升到200℃时,PET、PTT和PTT/PET三种纤维的断裂伸长率及PTT/PET的卷曲伸长率都大于未热处理的原丝纤维;PTT、PET纤维的断裂强力大于未经热处理的原丝,而PTT/PET双组分复合纤维的断裂强力比原丝小很多;模量方面,PTT纤维随温度增加而增大,PET纤维随温度增加而明显下降,PTT/PET复合纤维随温度增加有微小增加。在干热无张力条件下,温度从100℃逐渐上升到200℃时,PTT、PTT/PET双组分复合纤维的卷曲伸长率、断裂伸长率随着温度增加而增大,且都好于原丝纤维;PTT纤维的断裂强力和模量随着温度的增大而上升,但较未处理的原丝纤维有所下降;PTT/PET双组分复合纤维的断裂强力及模量随温度升高而下降,且比未处理的原丝纤维下降显著。
在湿热无张力的条件下,处理时间不变,PTT/PET双组分复合纤维的断裂伸长率及卷曲伸长率随温度增加而增大,且比未经热处理的原丝好,其断裂强力和模量比未经热处理的原丝纤维下降很多。温度从50℃升到100℃时,三种纤维的断裂伸长率逐渐增大且都好于未经热处理的原丝纤维。PTT/PET双组分复合纤维的卷曲伸长率随温度提高而逐渐下降,但较未经热处理原丝纤维提高。三种纤维的模量随温度增加而降低,并且比未经热处理的原丝纤维下降显著,PTT、PET断裂强力大于未经热处理的原丝,而PTT/PET双组分复合纤维的断裂强力较未经过热处理的原丝纤维下降很多,三种纤维的断裂强力均随着温度增加呈下降趋势。
在热处理条件下,PTT/PET双组分复合纤维的卷曲伸长率和断裂伸长率随张力的增加均呈一阶指数形式下降,在小张力下的模量及断裂伸长率变化显著,一旦超过某一值后,模量及断裂伸长率基本处于恒定,不再变化。两种单组分纤维的模量都比未经过热处理的原丝纤维有所下降,并且随张力增加而增加。
最后探讨了PTT/PET双组分复合纤维与毛混纤织物的性能,对影响织物弹性的各种因素进行了分析,结果发现,织物中PTT/PET双组分复合纤维随PTT组分比例增大织物弹性略微有所增大,PTT/PET复合纤维采用适中的捻度能提高织物的弹性,织物的断裂负荷及断裂伸长率随捻度的增大而增大,不同织造方式对织物的弹性并无较大影响。PTT/PET原液着色织物和白丝织物力学性能及弹性没有太大的差异,染色织物的弹性要好于原液及白丝织物;经过无张力定型处理的织物其织物的弹性变形能力要好于经过拉幅定型的织物。随着PTT/PET纤维细度增大,织物断裂负荷和模量增大,细度较大时织物在小外力作用下不容易变形,但回复性能好于细度较小的织物。
The PTT/PET bicomponent fiber has the unique advantages such as bulkiness and elasticity due to the self-crimp determining the good application on the textiles. However, there exist many problems about this fiber and fabric made by the fiber. So in the paper, we study the fiber of PET、PTT and PTT/PET bicomponent fiber. The main work is as followings:
First, we use KE SI DA microscope for observing the appearance and configuration of bicomponent fiber. It was found in the bicomponent fiber it is a bilateral array for the PET and PTT. The cross section is anisomerous with PTT and PET side by side. After heat treating the shape of single filament becomes three dimensional curly and the number of crimp is biggest in the condition of relaxation. In the range of some tention, the bulkiness and crimpness fall obviously after the bicomponent fiber is treated with heat. When it exceeds the range of extension, the bulkiness and crimpness become high.
Secondly, in the base of experiments, it is analyzed the affect of heating media、time、temperature and tension to the contractility of Polyester fibers. It is found that in the condition of the same tension and dry media, the contractility of PET、PTT and bicomponent fiber increases with the increasing of treating time and temperature. The bicomponent fibre has a steady contractility when the temperature is 140～160℃. In the condition of same tension and wet media, the contractility of PET、PTT and bicomponent fiber increases with the treating time and temperature. The contractility of bicomponent fiber has a nonlinear relation with the treating time. In the initial phase, the contraction increase rapidly and then slowly, after some time, about 10 minutes, it is near to steady. In the condition of the same wetting media or drying media、time and temperature, the contractility of PTT、PET decreases with the falling load. The curve of ratio of contractility presents hyperbola. When the tension<11.5mg/D, the decreasing is obviously as the tension increases. But when it is put in the opposite condition, the changing is not obviously.
Thirdly, testing and analyzing the characteristics of the mechanical properties of polyester fibre and finding the typical stress - strain characteristic curve of PTT / PET composite fibre can be divided into six different tensile stages. The two flexible region and two plastic region in the curve are significantly different from PET fibres. In PTT / PET fibre with the increase of PTT component ,the curly elongate rate increased while the modulus declined gradually.
In the conditions of hot air and 1 mg / D tension, with the temperature gradually rose from 100℃to 200℃, the rupture elongation rate of PET, PTT and PTT/PET fibres and the curly elongation rate of PTT / PET fibre are better than their original fibres, the fracture strength of PTT and PET fibre are better than their the original fibre, while the fracture strength of PTT / PET composite fibre is less than its original fibre. The modulus of PTT fibre increased with the increasing temperature while the modulus of PET fibre dropped significantly, and the modulus of PTT / PET fibre slightly increased with the increaseing temperature. On the conditions of hot air, no strain and the temperature gradually rose from 100℃to 200℃, the crimp elongation rate and breaking elongation rate of PTT, PTT / PET composite fibre increased with the increasing temperature, and are better than the original fibre. The fracture strength and modulus of PTT fibre increased with the increasing temperature, but they are less than the original fibre's. The fracture strength and modulus of PTT / PET composite fibre decreased with increasing temperature and they decreased significantly than the original fibre.
In the conditions of hot water and no strain, at the same time, the breaking elongation rate and curly elongation rate of PTT / PET fibre increases with increasing temperature and better than the original fibre. The fracture strength and modulus of PTT/PET fibre decreased more than the original fibre without heat treatment. Temperature rose from 50°C 100°C, the breaking elongation rate of the three fibres are gradually increased and are better than the original fiber without heat treatment. The curly elongation rate of PTT / PET composite fibre decreased gradually with the increasing temperature, but better than the original fibre without heat treatment. The modulus of the three fibres decreased with increasing temperature, it decreased significantly compare to the original fibres, and the fracture strength of PTT/PET decreased more than the original fibre without heat treatment, the fracture strength of the three fibres showed downtrend while the temperature increased
Under hot air treatment condition, the crimp elongation rate and rupture elongation rate of bicomponent PTT/PET fibre all declined exponentially with increasing tension. The modulus under small tension and fracture strength all changed significantly and when the tension was larger than a critical value, the modulus and elongation at break were nearly constant. Besides, compared with the untreated fibres, the modulus of the two single-component fibres were decreased to some extent and they all increased with increasing tension.
At last, it is discussed the property of PTT/PET biocomponent fiber/wool fiber blended fabric. It is analyzed the different factors affecting the elasticity. It is found the elasticity of fabric increases with the ratio of bicomponent fiber to PTT. In the proper twist, the elasticity can be promoted. The breading load and elongation at break increase with the twist, and the way of weaving has no affect to the elasticity. The mechanic property of PTT/PET bicomponent fabric with Dope dyeing and fabric with no dyeing has no differences. After relaxation, the elasticity of dyeing fabric is better than the fabric with Dope dyeing and fabric with no dyeing; the elasticity of fabric treated with relaxation is better than the fabric treated with framing setting. The modulus and breading load increase with size of fiber. When the size of fiber is big, the fabric is not transformed easily, but the restoration is better than the fabric with small size of fiber.
首先利用科视达观察了PTT/PET双组分复合纤维的外观形态,发现PTT/PET双组分复合纤维中PTT、PET两种组分呈双边分布,横截面呈不对称的哑铃状,PTT和PET两组分分居在横截面两侧,单丝经热处理呈现出三维立体卷曲,在无张力条件下卷曲数最多,在一定的张力范围内,随着所加负荷的增加,PTT/PET双组分复合纤维热处理后的蓬松性及卷曲性均下降显著。当超过一定张力范围时,卷曲性能及蓬松性反而会增大。
其次在大量实验基础上,分析了加热介质、时间、温度及张力四个因素对聚酯类纤维热收缩性能的影响,结果发现,在干热加热介质、张力不变的条件下,随着处理时间或处理温度的增加,PTT、PET纤维及PTT/PET双组分复合纤维的卷曲收缩率均呈增大趋势,PTT/PET双组分复合纤维在140～160℃时卷曲收缩率基本稳定。在湿热为加热介质、张力不变的条件下,随着处理时间或处理温度的增加,PTT、PET纤维及PTT/PET双组分复合纤维卷曲收缩率基本呈增加趋势,PTT/PET双组分复合纤维湿热收缩率与处理时间呈非线性变化,在加热的起始阶段,卷曲收缩率迅速增加,随之变缓,约20min后收缩趋于稳定。在干热或湿热为加热介质、温度及时间不变的情况下,PTT、PET纤维的卷曲收缩率随负荷的增加略微减小,而PTT/PET双组分复合纤维的卷曲收缩率呈双曲线形状,在张力<11.5mg/D时,随张力增加而卷曲收缩率减小的情况很明显,但在张力>11.5mg/D时,随张力的增加卷曲收缩率变化不大。
再次测试分析了聚酯类纤维机械性能特征,发现PTT/PET双组分复合纤维典型的应力-应变特征曲线可划分为6个不同的拉伸阶段,具有与PET纤维显著不同的两个弹性区域及两个塑性区域。在PTT/PET双组分复合纤维中,随PTT组分含量增加,卷曲伸长率逐渐增大,模量逐渐下降。
在干热、1mg/D张力条件下,温度从100℃逐渐升到200℃时,PET、PTT和PTT/PET三种纤维的断裂伸长率及PTT/PET的卷曲伸长率都大于未热处理的原丝纤维;PTT、PET纤维的断裂强力大于未经热处理的原丝,而PTT/PET双组分复合纤维的断裂强力比原丝小很多;模量方面,PTT纤维随温度增加而增大,PET纤维随温度增加而明显下降,PTT/PET复合纤维随温度增加有微小增加。在干热无张力条件下,温度从100℃逐渐上升到200℃时,PTT、PTT/PET双组分复合纤维的卷曲伸长率、断裂伸长率随着温度增加而增大,且都好于原丝纤维;PTT纤维的断裂强力和模量随着温度的增大而上升,但较未处理的原丝纤维有所下降;PTT/PET双组分复合纤维的断裂强力及模量随温度升高而下降,且比未处理的原丝纤维下降显著。
在湿热无张力的条件下,处理时间不变,PTT/PET双组分复合纤维的断裂伸长率及卷曲伸长率随温度增加而增大,且比未经热处理的原丝好,其断裂强力和模量比未经热处理的原丝纤维下降很多。温度从50℃升到100℃时,三种纤维的断裂伸长率逐渐增大且都好于未经热处理的原丝纤维。PTT/PET双组分复合纤维的卷曲伸长率随温度提高而逐渐下降,但较未经热处理原丝纤维提高。三种纤维的模量随温度增加而降低,并且比未经热处理的原丝纤维下降显著,PTT、PET断裂强力大于未经热处理的原丝,而PTT/PET双组分复合纤维的断裂强力较未经过热处理的原丝纤维下降很多,三种纤维的断裂强力均随着温度增加呈下降趋势。
在热处理条件下,PTT/PET双组分复合纤维的卷曲伸长率和断裂伸长率随张力的增加均呈一阶指数形式下降,在小张力下的模量及断裂伸长率变化显著,一旦超过某一值后,模量及断裂伸长率基本处于恒定,不再变化。两种单组分纤维的模量都比未经过热处理的原丝纤维有所下降,并且随张力增加而增加。
最后探讨了PTT/PET双组分复合纤维与毛混纤织物的性能,对影响织物弹性的各种因素进行了分析,结果发现,织物中PTT/PET双组分复合纤维随PTT组分比例增大织物弹性略微有所增大,PTT/PET复合纤维采用适中的捻度能提高织物的弹性,织物的断裂负荷及断裂伸长率随捻度的增大而增大,不同织造方式对织物的弹性并无较大影响。PTT/PET原液着色织物和白丝织物力学性能及弹性没有太大的差异,染色织物的弹性要好于原液及白丝织物;经过无张力定型处理的织物其织物的弹性变形能力要好于经过拉幅定型的织物。随着PTT/PET纤维细度增大,织物断裂负荷和模量增大,细度较大时织物在小外力作用下不容易变形,但回复性能好于细度较小的织物。
The PTT/PET bicomponent fiber has the unique advantages such as bulkiness and elasticity due to the self-crimp determining the good application on the textiles. However, there exist many problems about this fiber and fabric made by the fiber. So in the paper, we study the fiber of PET、PTT and PTT/PET bicomponent fiber. The main work is as followings:
First, we use KE SI DA microscope for observing the appearance and configuration of bicomponent fiber. It was found in the bicomponent fiber it is a bilateral array for the PET and PTT. The cross section is anisomerous with PTT and PET side by side. After heat treating the shape of single filament becomes three dimensional curly and the number of crimp is biggest in the condition of relaxation. In the range of some tention, the bulkiness and crimpness fall obviously after the bicomponent fiber is treated with heat. When it exceeds the range of extension, the bulkiness and crimpness become high.
Secondly, in the base of experiments, it is analyzed the affect of heating media、time、temperature and tension to the contractility of Polyester fibers. It is found that in the condition of the same tension and dry media, the contractility of PET、PTT and bicomponent fiber increases with the increasing of treating time and temperature. The bicomponent fibre has a steady contractility when the temperature is 140～160℃. In the condition of same tension and wet media, the contractility of PET、PTT and bicomponent fiber increases with the treating time and temperature. The contractility of bicomponent fiber has a nonlinear relation with the treating time. In the initial phase, the contraction increase rapidly and then slowly, after some time, about 10 minutes, it is near to steady. In the condition of the same wetting media or drying media、time and temperature, the contractility of PTT、PET decreases with the falling load. The curve of ratio of contractility presents hyperbola. When the tension<11.5mg/D, the decreasing is obviously as the tension increases. But when it is put in the opposite condition, the changing is not obviously.
Thirdly, testing and analyzing the characteristics of the mechanical properties of polyester fibre and finding the typical stress - strain characteristic curve of PTT / PET composite fibre can be divided into six different tensile stages. The two flexible region and two plastic region in the curve are significantly different from PET fibres. In PTT / PET fibre with the increase of PTT component ,the curly elongate rate increased while the modulus declined gradually.
In the conditions of hot air and 1 mg / D tension, with the temperature gradually rose from 100℃to 200℃, the rupture elongation rate of PET, PTT and PTT/PET fibres and the curly elongation rate of PTT / PET fibre are better than their original fibres, the fracture strength of PTT and PET fibre are better than their the original fibre, while the fracture strength of PTT / PET composite fibre is less than its original fibre. The modulus of PTT fibre increased with the increasing temperature while the modulus of PET fibre dropped significantly, and the modulus of PTT / PET fibre slightly increased with the increaseing temperature. On the conditions of hot air, no strain and the temperature gradually rose from 100℃to 200℃, the crimp elongation rate and breaking elongation rate of PTT, PTT / PET composite fibre increased with the increasing temperature, and are better than the original fibre. The fracture strength and modulus of PTT fibre increased with the increasing temperature, but they are less than the original fibre's. The fracture strength and modulus of PTT / PET composite fibre decreased with increasing temperature and they decreased significantly than the original fibre.
In the conditions of hot water and no strain, at the same time, the breaking elongation rate and curly elongation rate of PTT / PET fibre increases with increasing temperature and better than the original fibre. The fracture strength and modulus of PTT/PET fibre decreased more than the original fibre without heat treatment. Temperature rose from 50°C 100°C, the breaking elongation rate of the three fibres are gradually increased and are better than the original fiber without heat treatment. The curly elongation rate of PTT / PET composite fibre decreased gradually with the increasing temperature, but better than the original fibre without heat treatment. The modulus of the three fibres decreased with increasing temperature, it decreased significantly compare to the original fibres, and the fracture strength of PTT/PET decreased more than the original fibre without heat treatment, the fracture strength of the three fibres showed downtrend while the temperature increased
Under hot air treatment condition, the crimp elongation rate and rupture elongation rate of bicomponent PTT/PET fibre all declined exponentially with increasing tension. The modulus under small tension and fracture strength all changed significantly and when the tension was larger than a critical value, the modulus and elongation at break were nearly constant. Besides, compared with the untreated fibres, the modulus of the two single-component fibres were decreased to some extent and they all increased with increasing tension.
At last, it is discussed the property of PTT/PET biocomponent fiber/wool fiber blended fabric. It is analyzed the different factors affecting the elasticity. It is found the elasticity of fabric increases with the ratio of bicomponent fiber to PTT. In the proper twist, the elasticity can be promoted. The breading load and elongation at break increase with the twist, and the way of weaving has no affect to the elasticity. The mechanic property of PTT/PET bicomponent fabric with Dope dyeing and fabric with no dyeing has no differences. After relaxation, the elasticity of dyeing fabric is better than the fabric with Dope dyeing and fabric with no dyeing; the elasticity of fabric treated with relaxation is better than the fabric treated with framing setting. The modulus and breading load increase with size of fiber. When the size of fiber is big, the fabric is not transformed easily, but the restoration is better than the fabric with small size of fiber.
引文
[1]Hoe,H.Corterra;Anew polyesterfibre,Textiles.Magazine,1998,1;12-14
[2]陈克权,段菊兰,PTT纤维研究历史及市场前景分析,金山油石化,2004,1;18-23
[3]黄立新,PTT纤维及其产品的开发与应用,上海纺织科技,2002,2;16-17
[4]任永花,俞建勇,张一心,PTT纤维及其制品的应用特性分析,棉纺织技术,2005,11;1-4
[5]杨佳庆,顾利霞,PTT纤维的发展及其性能和应用,纺织导报,1998,3;13-14
[6]MBuscemi,KDangayach,KKiibler,HKormelink,F Schnitzeler,Shell Chemical Ltd.,Amersham,Bucks/UK.Challenges and opportunites for Corterra PTT in textile fibers.Chemical Fibers International,2002,2;34-35.
[7]Dr.H.S.Brown,H.H.Chuah,Shell Chemical Company,Houston,Texas/ USA.Texturing of textile filament yarns based on polytrimethylene terephthalate.Chemical Fibers International,1997,1;72-74
[8]Ma Moerman,Shell Coordination Center,S.A.and Gary Hess,Rhodia Filtec.Corterra Polymers Value Proposition in Textile Apparel Application.www.shellchemicals.com.
[9]Yiqi Yang and Shiqi Li,Houston Brown and Paul casey.Dyeing Behavior of 100%Poly(trimethylene terephthalate)(PTT)Textiles.Chemist and Colorist&American Dyestuff Repor,1999,3;50-54.
[10]何中琴译,PTT/PET混纺物染色,国外丝绸,2003,1;31-37
[11]林诗钦译,新聚酯(PTT)/棉混纺物的染色,上海染料,2002,4;43-45.
[12]Ch.Hwo,H.Brown,P.Casey,H.Chuah,K.Dangayach,Th.Forschner,M.Moer-man and L.oliveri,Shell Chemical Company,Westhollow Technology Center,Houston,Texas/USA.Opportunites of Corterra PTT fibers in textiles.Chemical Fibers International,2000,2;53-56.
[13]林玲,PTT短纤维可纺性研究及产品开发,[硕士学位论文],上海,东华大学,2004.
[14]蔡平平,赵俐,新型弹性纤维在针织物应用上的性能研究,针织工业,2003,3;50.52
[15]曹利敏,PTT纤维圆纬机产品的开发及性能研究,[硕士学位论文],上海,东华大学,2004.
[16]李慧,PTT产品的弹性开发研究,[硕士学位论文[,上海,东华大学,2004.
[17]殷苏晨,PTT梭织物的开发技术研究,[硕士学位论文[,上海,东华大学,2005
[18[罗益锋,世界环保型化纤的新进展,纺织导报,2003,6;82-87
[19]陈克权,PTT纤维的结构与性能,合成纤维工业,2001,6;37-40
[20]Dandurand S P,Perez S,Revol J F,et al.The Crystal Structure of Poly(tetra-methyleneterephalate)by X-ray and Electron Diffraction[J].Polymer,1979,4;419-426.
[21]罗抚英,徐冉丹,唐人成,新型聚酯PTT纤维的染色,国外丝绸,2002,5;23-26
[22]杨栋梁,PTT纤维的染整加工(一),印染,2006,1;45-49
[23]刘玉莉,杨宝武,新型纺织用PTT纤维的特性及其染色工艺探讨,当代石油化工,2002,2;39-41
[24]钱以厷等,PTT纤维与产品开发,北京;中国纺织出版社,2006;85-86
[25]Rave H,Schemken M,Beck A.State of the art of bicomponent staple fiberproduction[J].Chemical Fiber International,2002,4;52
[26]高善荣译,双组分纤维引论,国外纺织技术,2000,1;8-10
[27]王府梅编著,服装面料的性能设计,上海;中国纺织大学出版社,2000;39-42
[28]张黎,双组分纤维的开发及应用,合成技术及应用,2004,1;38-41
[29]郭春花,张文,陈玉顺,PET与PTT共聚酯的合成及其性能研究,聚酯工业,2004,6;30-32
[30]李桂娟,代国兴,李玮等,PTTPPET共混体系晶体形态与结晶性能的研究,高分子学报,2005,5;736-739.
[31]梁浩,吴唯,钱琦,PET/PTT共混体系在无定形区的相容性,中国塑料,2006,1;31-35
[32]孙宏,来侃,孙润军,PTT/PET复合长丝仿毛织物服用性能研究,毛纺科技,2006,10;57-59
[33]孙宏,来侃,孙润军,PET/PTT复合纤维工艺性能研究,西安工程科技学院学报,2006,6;706-709
[34]宋燕菲,赵俐,PTT/PET双组分长丝在针织无缝内衣上的应用及产品性能,上海纺织科技,2006,11;66-69
[35]曹秋玲,王府梅,新型聚酯长丝纱的弹性比较,丝绸,2006,7;51-52
[36]杨兆湘,复合纤维的开发与应用,上海纺织科技,1997,4;4-5
[37]程贞娟,凌荣根,复合纤维的成型原理及性能探讨,纺织学报,1999,4;47-49
[38]K.Bender,W.Stibal(德),骆为林译,双组分纤维.不仅是一种市场适销的产品,国际纺织导报,2000,2;34-38
[39]姚穆编,纺织材料学,北京;中国纺织出版社,1988;120-126
[40]宋心远,弹性纤维的结构、弹性及其纺织品染整(一),印染,2006,8;44-46
[41]宋心远等,新型纤维及织物染整[M],北京;中国纺织出版社,2006;86-92
[42]薛元等,伸缩性弹力素材及其在弹力织物中的应用[J],纺织导报,2005,11;65-71.
[43]王家昭等,氨纶弹力丝生产及其应用,北京;纺织工业出版社,1989;33-36
[44]尹继亮,刘俊卿,弹性纤维及其在服用织物中的应用,纺织导报,1999,6;8-12
[45]牛家祥,刘兴富,张组文,聚氨酯弹性纤维发展趋势及其熔融纺丝工艺简述,广东纤维,2002,4;19-24
[46]马新敏,于伟东.弹性聚酯纤维的弹性机制与应用研究,纺织导报,2003,6;88-92
[47]廖镜华,新型聚酯纤维;PTT,广西化纤通讯,1999,2;2-6
[48]王善元主编,变形纱,上海;上海科学技术出版社,1992;11-18
[49]姚穆主编,纺织材料学,中国纺织出版社,2003,第二版;99-103
[50]大卫R.萨利姆著,高绪珊,吴大成等译,聚合物纤维结构的形成,北京;化学工业出版社,2004;338-349
[51]Heuvel,H.M,Lucaas,L.J.,van den Heuvel,C.J.M and de Weijer,A.P.J.Appl.polym.Sci.,1992,45;1649
[52]颜冬梅,李淑华,并列复合纤维及其生产讨论,北京化纤,2000,2;9-13
[53]韩嘉坤,李俊,PTT/毛混纺织物的回弹性能.纺织导报,2005,5;57-59
[54]尹继亮等,弹性纤维及其在服用织物中的应用,纺织导报,1999,6;8-12
[2]陈克权,段菊兰,PTT纤维研究历史及市场前景分析,金山油石化,2004,1;18-23
[3]黄立新,PTT纤维及其产品的开发与应用,上海纺织科技,2002,2;16-17
[4]任永花,俞建勇,张一心,PTT纤维及其制品的应用特性分析,棉纺织技术,2005,11;1-4
[5]杨佳庆,顾利霞,PTT纤维的发展及其性能和应用,纺织导报,1998,3;13-14
[6]MBuscemi,KDangayach,KKiibler,HKormelink,F Schnitzeler,Shell Chemical Ltd.,Amersham,Bucks/UK.Challenges and opportunites for Corterra PTT in textile fibers.Chemical Fibers International,2002,2;34-35.
[7]Dr.H.S.Brown,H.H.Chuah,Shell Chemical Company,Houston,Texas/ USA.Texturing of textile filament yarns based on polytrimethylene terephthalate.Chemical Fibers International,1997,1;72-74
[8]Ma Moerman,Shell Coordination Center,S.A.and Gary Hess,Rhodia Filtec.Corterra Polymers Value Proposition in Textile Apparel Application.www.shellchemicals.com.
[9]Yiqi Yang and Shiqi Li,Houston Brown and Paul casey.Dyeing Behavior of 100%Poly(trimethylene terephthalate)(PTT)Textiles.Chemist and Colorist&American Dyestuff Repor,1999,3;50-54.
[10]何中琴译,PTT/PET混纺物染色,国外丝绸,2003,1;31-37
[11]林诗钦译,新聚酯(PTT)/棉混纺物的染色,上海染料,2002,4;43-45.
[12]Ch.Hwo,H.Brown,P.Casey,H.Chuah,K.Dangayach,Th.Forschner,M.Moer-man and L.oliveri,Shell Chemical Company,Westhollow Technology Center,Houston,Texas/USA.Opportunites of Corterra PTT fibers in textiles.Chemical Fibers International,2000,2;53-56.
[13]林玲,PTT短纤维可纺性研究及产品开发,[硕士学位论文],上海,东华大学,2004.
[14]蔡平平,赵俐,新型弹性纤维在针织物应用上的性能研究,针织工业,2003,3;50.52
[15]曹利敏,PTT纤维圆纬机产品的开发及性能研究,[硕士学位论文],上海,东华大学,2004.
[16]李慧,PTT产品的弹性开发研究,[硕士学位论文[,上海,东华大学,2004.
[17]殷苏晨,PTT梭织物的开发技术研究,[硕士学位论文[,上海,东华大学,2005
[18[罗益锋,世界环保型化纤的新进展,纺织导报,2003,6;82-87
[19]陈克权,PTT纤维的结构与性能,合成纤维工业,2001,6;37-40
[20]Dandurand S P,Perez S,Revol J F,et al.The Crystal Structure of Poly(tetra-methyleneterephalate)by X-ray and Electron Diffraction[J].Polymer,1979,4;419-426.
[21]罗抚英,徐冉丹,唐人成,新型聚酯PTT纤维的染色,国外丝绸,2002,5;23-26
[22]杨栋梁,PTT纤维的染整加工(一),印染,2006,1;45-49
[23]刘玉莉,杨宝武,新型纺织用PTT纤维的特性及其染色工艺探讨,当代石油化工,2002,2;39-41
[24]钱以厷等,PTT纤维与产品开发,北京;中国纺织出版社,2006;85-86
[25]Rave H,Schemken M,Beck A.State of the art of bicomponent staple fiberproduction[J].Chemical Fiber International,2002,4;52
[26]高善荣译,双组分纤维引论,国外纺织技术,2000,1;8-10
[27]王府梅编著,服装面料的性能设计,上海;中国纺织大学出版社,2000;39-42
[28]张黎,双组分纤维的开发及应用,合成技术及应用,2004,1;38-41
[29]郭春花,张文,陈玉顺,PET与PTT共聚酯的合成及其性能研究,聚酯工业,2004,6;30-32
[30]李桂娟,代国兴,李玮等,PTTPPET共混体系晶体形态与结晶性能的研究,高分子学报,2005,5;736-739.
[31]梁浩,吴唯,钱琦,PET/PTT共混体系在无定形区的相容性,中国塑料,2006,1;31-35
[32]孙宏,来侃,孙润军,PTT/PET复合长丝仿毛织物服用性能研究,毛纺科技,2006,10;57-59
[33]孙宏,来侃,孙润军,PET/PTT复合纤维工艺性能研究,西安工程科技学院学报,2006,6;706-709
[34]宋燕菲,赵俐,PTT/PET双组分长丝在针织无缝内衣上的应用及产品性能,上海纺织科技,2006,11;66-69
[35]曹秋玲,王府梅,新型聚酯长丝纱的弹性比较,丝绸,2006,7;51-52
[36]杨兆湘,复合纤维的开发与应用,上海纺织科技,1997,4;4-5
[37]程贞娟,凌荣根,复合纤维的成型原理及性能探讨,纺织学报,1999,4;47-49
[38]K.Bender,W.Stibal(德),骆为林译,双组分纤维.不仅是一种市场适销的产品,国际纺织导报,2000,2;34-38
[39]姚穆编,纺织材料学,北京;中国纺织出版社,1988;120-126
[40]宋心远,弹性纤维的结构、弹性及其纺织品染整(一),印染,2006,8;44-46
[41]宋心远等,新型纤维及织物染整[M],北京;中国纺织出版社,2006;86-92
[42]薛元等,伸缩性弹力素材及其在弹力织物中的应用[J],纺织导报,2005,11;65-71.
[43]王家昭等,氨纶弹力丝生产及其应用,北京;纺织工业出版社,1989;33-36
[44]尹继亮,刘俊卿,弹性纤维及其在服用织物中的应用,纺织导报,1999,6;8-12
[45]牛家祥,刘兴富,张组文,聚氨酯弹性纤维发展趋势及其熔融纺丝工艺简述,广东纤维,2002,4;19-24
[46]马新敏,于伟东.弹性聚酯纤维的弹性机制与应用研究,纺织导报,2003,6;88-92
[47]廖镜华,新型聚酯纤维;PTT,广西化纤通讯,1999,2;2-6
[48]王善元主编,变形纱,上海;上海科学技术出版社,1992;11-18
[49]姚穆主编,纺织材料学,中国纺织出版社,2003,第二版;99-103
[50]大卫R.萨利姆著,高绪珊,吴大成等译,聚合物纤维结构的形成,北京;化学工业出版社,2004;338-349
[51]Heuvel,H.M,Lucaas,L.J.,van den Heuvel,C.J.M and de Weijer,A.P.J.Appl.polym.Sci.,1992,45;1649
[52]颜冬梅,李淑华,并列复合纤维及其生产讨论,北京化纤,2000,2;9-13
[53]韩嘉坤,李俊,PTT/毛混纺织物的回弹性能.纺织导报,2005,5;57-59
[54]尹继亮等,弹性纤维及其在服用织物中的应用,纺织导报,1999,6;8-12