无机层状纳米复合物的软化学法制备、结构及性能研究
|
摘要
制造新型纳米及亚微米结构材料是当今材料领域的研究热点之一。由于软化学法可以在温和的反应条件下和缓慢的反应进程中以可控制的步骤进行化学反应制备材料，被认为是目前最有前途的制备方法之一。本文以具有较高光催化活性钙钛矿型层状镧钛酸盐为研究对象，将软化学法运用到其制备及改性的有关环节，制备以K_2Ln_2Ti_3O_(10)为基础的纳米复合材料，研究其结构、形态、层间反应即交换／嵌入反应、光催化性能等，主要内容如下：
采用了两种软化学法——硬脂酸法及柠檬酸溶胶-凝胶法，在较低的温度下合成系列超细层状材料K_2Ln_2Ti_3O_(10)及K_2Ln_(2-x)Ln’_xTi_3O_(10)(Ln，Ln’=La，Pr，Nd，Sm，Eu，Gd，Dy)，系统研究了Ln对K_2Ln_2Ti_3O_(10)晶体结构的影响，证明Ln~(3+)的离子半径是能否形成钙钛矿型层状结构的决定性因素。解析了K_2Ln_2Ti_3O_(10)(Ln=Pr，Nd，Sm，Eu，Gd，Dy)系列晶体的结构，得到了未见文献报道的Ln=Pr，Sm，Eu，Gd，Dy的晶胞参数及指标化结果。对形成K_2Ln_2Ti_3O_(10)的反应历程进行了探讨，发现了由中间产物KLn_2Ti_3O_(9.5)向目标产物转变的过程。探讨了用硬脂酸法合成KLn_2Ti_3O(9.5)系列产物，产物为20nm×20nm左右的方块状小晶体，具有较大的比表面积，是一类具有层状结构新化合物。对K_2Ln_2Ti_3O_(10)的光催化活性研究结果表明：软化学法的产物活性明显高于固相反应法产物：K_2Ln_2Ti_3O_(10)的催化活性按Dy＞Gd＞Nd＞Sm＞La顺序递减，通过对其能隙的分析解释了其活性顺序；Ln位的部分掺杂有利于提高产物的光催化活性。
系统研究了K_2La_2Ti_3O_(10)的层间软化学反应——酸交换及烷基胺预撑反应，考察了原料的尺寸、酸种类等因素对酸交换及烷基胺嵌入反应的影响，并对酸交换的动力学及交换产物的拉曼活性进行了研究。发现了酸种类对酸交换反应速率、交换产物层间距及层板结构的影响规律，进而影响了烷基胺的嵌入过程；酸交换及烷基胺嵌入产物的层间距随颗粒尺寸的减小而增大；而硬脂酸法制备的超细K_2La_2Ti_3O_(10)在HNO_3交换介质中可完全剥离且剥离后的单片层自行卷曲成纳米棒，小尺寸的H_2La_2Ti_3O_(10)在正丙胺预撑过程中也出现了剥离现象。
将软化学法引入层状化合物的改性过程，采用柱撑、担载、包覆工艺制备了系列以为K_2La_2Ti_3O_(10)基的纳米复合材料，并对其光催化性能进行了研究。结果表明：改性后产物的光催化活性均得到明显提高，其中柱撑法改性产物具有最高的催化活性。
探索了K_2Ln_2Ti_3O_(10)及KLn_2Ti_3O_(9.5)系列材料在火炸药领域中的应用，发现二者对AP热分解均有一定的催化活性，而KLn_2Ti_3O_(9.5)的催化活性明显高于K_2Ln_2Ti_3O_(10)；
Recently, synthesis and creation of novel nanometer and micro-sized materials are extensively studied in material field. Soft-chemistry method is considered as one of the most outlook method in fabricating new materials because of its unique reacting characteristics, such as mild reaction condition, lower reaction speed, controllable process. In this Ph. D. dissertation, soft-chemistry law was fully used in fabricating and modifying perovskite-type layered lanthanon titanates, including synthesis of ultrafine layered K_2Ln_2Ti_3O_(10) and nanocomposites based on it. The influence of the particle size on the crystal structure, micrograph and interlayer soft reaction properties, such as exchanging/intercalating reaction and photocatalytic activity was studied. The dissertation was mainly focused on:
Two kinds of soft-chemistry method---stearic acid method (SAM) and citric acid sol-gel method were successfully adopted to fabricated ultrafine layered K_2Ln_2Ti_3O_(10) and K_2Ln_(2-x)Ln'_xTi_3O_(10) (Ln, Ln'=La, Pr, Nd, Sin, Eu, Gd, Dy) compounds under relatively lower temperature. The impact of Ln on the K_2Ln_2Ti_3O_(10) crystal structure was also systemic investigated. Results showed that the radius of Ln~(3+) determined whether the layered perovskite structure could be formed. The formation mechanism of K_2Ln_2Ti_3O_(10) was discussed. It was shown that the K_2Ln_2Ti_3O_(10) was changed from a mediate state— KLn_2Ti_3O_(9.5) for the first time. And the KLn_2Ti_3O_(9.5) series were newly synthesized by SAM. It was found that KLn_2Ti_3O_(9.5) is square-like and the average size is ca.20nm, has higher BET surface area and unique layered structure similar to the aim products. The obtained products are a new kind of perovskite-type layered compounds. The photocatalytic properties of K_2Ln_2Ti_3O_(10) and K_2Ln_(2-x)Ln'_xTi_3O_(10) were studied and results showed that the photoactivities of samples obtained by SAM are all better than those of SSR (solid state reaction), the photocatalytic activity of K_2Ln_2Ti_3O_(10) was strongly dependent on Ln, decreasing in the sequence of Dy> Gd>Nd>Sm >La by the same method and this sequence was successfully explained by analyzed the energy gap of each K_2Ln_2Ti_3O_(10). At the same time, the adulteration of Ln helps to improve its catalytic activity.
The interlayer soft reaction process, such as acid-exchanging and alkylamine intercalating process of K_2La_2Ti_3O_(10) was systemic studied. The influence of particle sizes of K_2La_2Ti_3O_(10) and the kind of acid on the products of exchanged by H+, intercalated by
采用了两种软化学法——硬脂酸法及柠檬酸溶胶-凝胶法，在较低的温度下合成系列超细层状材料K_2Ln_2Ti_3O_(10)及K_2Ln_(2-x)Ln’_xTi_3O_(10)(Ln，Ln’=La，Pr，Nd，Sm，Eu，Gd，Dy)，系统研究了Ln对K_2Ln_2Ti_3O_(10)晶体结构的影响，证明Ln~(3+)的离子半径是能否形成钙钛矿型层状结构的决定性因素。解析了K_2Ln_2Ti_3O_(10)(Ln=Pr，Nd，Sm，Eu，Gd，Dy)系列晶体的结构，得到了未见文献报道的Ln=Pr，Sm，Eu，Gd，Dy的晶胞参数及指标化结果。对形成K_2Ln_2Ti_3O_(10)的反应历程进行了探讨，发现了由中间产物KLn_2Ti_3O_(9.5)向目标产物转变的过程。探讨了用硬脂酸法合成KLn_2Ti_3O(9.5)系列产物，产物为20nm×20nm左右的方块状小晶体，具有较大的比表面积，是一类具有层状结构新化合物。对K_2Ln_2Ti_3O_(10)的光催化活性研究结果表明：软化学法的产物活性明显高于固相反应法产物：K_2Ln_2Ti_3O_(10)的催化活性按Dy＞Gd＞Nd＞Sm＞La顺序递减，通过对其能隙的分析解释了其活性顺序；Ln位的部分掺杂有利于提高产物的光催化活性。
系统研究了K_2La_2Ti_3O_(10)的层间软化学反应——酸交换及烷基胺预撑反应，考察了原料的尺寸、酸种类等因素对酸交换及烷基胺嵌入反应的影响，并对酸交换的动力学及交换产物的拉曼活性进行了研究。发现了酸种类对酸交换反应速率、交换产物层间距及层板结构的影响规律，进而影响了烷基胺的嵌入过程；酸交换及烷基胺嵌入产物的层间距随颗粒尺寸的减小而增大；而硬脂酸法制备的超细K_2La_2Ti_3O_(10)在HNO_3交换介质中可完全剥离且剥离后的单片层自行卷曲成纳米棒，小尺寸的H_2La_2Ti_3O_(10)在正丙胺预撑过程中也出现了剥离现象。
将软化学法引入层状化合物的改性过程，采用柱撑、担载、包覆工艺制备了系列以为K_2La_2Ti_3O_(10)基的纳米复合材料，并对其光催化性能进行了研究。结果表明：改性后产物的光催化活性均得到明显提高，其中柱撑法改性产物具有最高的催化活性。
探索了K_2Ln_2Ti_3O_(10)及KLn_2Ti_3O_(9.5)系列材料在火炸药领域中的应用，发现二者对AP热分解均有一定的催化活性，而KLn_2Ti_3O_(9.5)的催化活性明显高于K_2Ln_2Ti_3O_(10)；
Recently, synthesis and creation of novel nanometer and micro-sized materials are extensively studied in material field. Soft-chemistry method is considered as one of the most outlook method in fabricating new materials because of its unique reacting characteristics, such as mild reaction condition, lower reaction speed, controllable process. In this Ph. D. dissertation, soft-chemistry law was fully used in fabricating and modifying perovskite-type layered lanthanon titanates, including synthesis of ultrafine layered K_2Ln_2Ti_3O_(10) and nanocomposites based on it. The influence of the particle size on the crystal structure, micrograph and interlayer soft reaction properties, such as exchanging/intercalating reaction and photocatalytic activity was studied. The dissertation was mainly focused on:
Two kinds of soft-chemistry method---stearic acid method (SAM) and citric acid sol-gel method were successfully adopted to fabricated ultrafine layered K_2Ln_2Ti_3O_(10) and K_2Ln_(2-x)Ln'_xTi_3O_(10) (Ln, Ln'=La, Pr, Nd, Sin, Eu, Gd, Dy) compounds under relatively lower temperature. The impact of Ln on the K_2Ln_2Ti_3O_(10) crystal structure was also systemic investigated. Results showed that the radius of Ln~(3+) determined whether the layered perovskite structure could be formed. The formation mechanism of K_2Ln_2Ti_3O_(10) was discussed. It was shown that the K_2Ln_2Ti_3O_(10) was changed from a mediate state— KLn_2Ti_3O_(9.5) for the first time. And the KLn_2Ti_3O_(9.5) series were newly synthesized by SAM. It was found that KLn_2Ti_3O_(9.5) is square-like and the average size is ca.20nm, has higher BET surface area and unique layered structure similar to the aim products. The obtained products are a new kind of perovskite-type layered compounds. The photocatalytic properties of K_2Ln_2Ti_3O_(10) and K_2Ln_(2-x)Ln'_xTi_3O_(10) were studied and results showed that the photoactivities of samples obtained by SAM are all better than those of SSR (solid state reaction), the photocatalytic activity of K_2Ln_2Ti_3O_(10) was strongly dependent on Ln, decreasing in the sequence of Dy> Gd>Nd>Sm >La by the same method and this sequence was successfully explained by analyzed the energy gap of each K_2Ln_2Ti_3O_(10). At the same time, the adulteration of Ln helps to improve its catalytic activity.
The interlayer soft reaction process, such as acid-exchanging and alkylamine intercalating process of K_2La_2Ti_3O_(10) was systemic studied. The influence of particle sizes of K_2La_2Ti_3O_(10) and the kind of acid on the products of exchanged by H+, intercalated by
引文
1．张立德，牟庆美．纳米材料和纳米结构．北京：科学出版社，2001；
2. Nalwa H S. Handbook of nanostructured material and nanotechnology, Chap. 1. Academic Press. San Diego. 1999;
3．柯扬船，皮特·斯壮．聚合物-无机纳米复合材料．北京：化学工业出版社，2002．12；
4. Kazunari D, Junko N K, Michikazu H, et al. Photo- and machano- catalytic overall water splitting reactions to form H_2 and O_2 on heterogeneous catalyst. Bull Chem. Soc. Jpn., 2000, 73:1307-1331.
5．郭宪吉，侯文华，颜其洁等．层柱过渡金属氧化物．科学通报，2002，47：1681-1689．
6. Brian L. Cushing, Vladimir L. Kolesnichenko, and Charles J. O'Conner. Recent advances in the liquid-phase syntheses of inorganic nanoparticles. Chem. Rev., 2004,104:3893-3946;
7．徐如人，庞文琴．无机合成和制备化学，北京：高等教育出版社，2001；
8．汪信，陆路德．纳米金属氧化物的制备及应用研究的若干进展．无机化学学报．2000，16：213-216：
9. Chebiam R. V., Prado F., Soft chemistry synthesis and characterization of layered Li_(1-x)Ni_(1-y)Co_yO_(2-δ)(0≤x≤1 and 0≤y≤1). Chem. Mater. 2001, 13:2951-2957;
10．杨娟，李丹，吴东辉，杨绪杰，陆路德，汪信．硬脂酸法制备纳米TiO_2及其微结构控制，无机材料学报，2001，16(3)：550-554；
11．吴东辉，李丹，杨娟，杨绪杰，陆路德，汪信．硬脂酸法制备SO_4~(2-)／Fe_2O_3-SiO_2固体酸及其催化性能的初步探讨，高等学校化学学报，2001，22：1877-1880；
12．吴东辉，李丹，杨娟，杨绪杰，陆路德，汪信．微波辐射溶胶-凝胶法制备均分散纺锤形α-Fe_2O_3超细粒子，功能材料，2002，32：39-40
13. Yang Juan, Li Dan, Wang Xin, et al. Rapid synthesis of nanocrystalline TiO_2/SnO_2 binary oxides and their photoinduced decomposition of methyl orange. J. Solid State Chem., 2002, 165:193-198.
14. Li Dan, Wu Dong Hui, Wang Xin, et al. Rapid preparation of porous Fe_2O_3/SiO_2 nanocomposites via an organic precursor. Mater. Res. Bull., 2001, 36:2437-2442
15. Xiaohui Wang, Dan Li. The preparation of barium ferrite nanocrystalline powders by a stearic acid gel method. Mater. Lett. 1996, 28:203-206;
16. Xiong Gang, Zhi Zheng-liang, Yang xiujie, Lu Lude, Wang Xin, Characterization of perovskite-type LaCoO_3 nanocrystals prepared by a stearic acid sol-gel method. J. Mater. Sci. Lett. 1997, 16:1964-1968
17. Xiong Gang, Wang Xin, Yang Xujie, et al. Characterization and size-depedent magnetic properties of Ba_3Co_2Fe_(24)O_(41) nanocrystals synthesized through a sol-gel method. J. Mater. Sci. 2000, 35: 931-935;
18．沈彩，刘庆峰，刘茜．柠檬酸-硝酸盐燃烧法制备Ba_(0.5)Sr_(0.5)TiO_3介电材料，无机材料学报，2004，19：681-685：
19．宿新泰，刘瑞泉，胡云霞等．柠檬酸盐溶胶-凝胶制备Ba_3(Ca_(1.18)Nb_(1.82)O_(9-δ)纳米粉末，无机材料学报，2004，19：229-233：
20．于东生，周震涛．纳米La_(0.7)Sr_(0.3)MnO_3的制备及其电催化性能，全国第三届纳米材料和技术应用会议论文集(上)．278～290；
21．罗君，刑献然，于然波等．溶胶-凝胶法合成钛酸锌陶瓷粉体，无机化学学报，2004，20：1182-1185
22．牛新书，许亚杰，张学治等．微乳液法制备纳米TiO_2及其光催化活性，功能材料，2003，34：548-552；
23．陈宗淇，王光信，徐桂英．胶体与界面化学，北京：高等教育出版社，2201，9；
24．郭广生，顾福博，王志华等．La_2(CO_3)_3纳米线的微乳液法制备与表征，无机化学学报，2004，20(7)：860-862：
25. Tetsuy K, Guoqing G, Yuuki M, et al. Photocatalytic hydrogen production from water over a LaMnO_3/CdS nanocomposites prepared by the reverse micelle method. J. Mater. Chem., 2003,13:1186-1191
26. Junwu Zhu, Dan Li, Haiqun Chen, Xujie Yang, Lude Lu, Xin Wang, Highly dispersed CuO nanoparticales prepared by a novel quick-precipitation method, Mater. Lett. 2004,58,3324-3327
27．朱俊武，张维光，王恒志等．纳米CuO的形貌控制合成及其性质研究，无机化学学报，2004，20(7)：863-867；
28．吴涛，张希．自组装超薄膜：从纳米层状构筑到功能组装，高等学校化学学报，2001，22：1057-1065：
29．李丹．聚苯胺自组装复合膜的制备及功能特性，电子科技大学博士论文，1999；
30．沈家骢．超分子层状结构——组装与功能，北京：科学出版社，2004；
31. Panneerselvam M., Rao K. J., Microwave preparation and sintering of industrially important perovskite oxide: LaMO_3 (M=Cr, Co, Ni ), J. Mater. Chem., 2003, 13: 596-601;
32．白音孟和，纪敏，刘新等．层状K_4Ag_2Sn_3S9_2·H_2O的溶剂热合成与表征，高等学校化学学报，2004，25(8)：1391-1394；
33．上官文峰．太阳能光解水制氢的研究进展，无机化学学报，2001，17：619-626．
34．张彭义，余刚，江展彭．半导体光催化剂及其改性技术进展，环境科学进展，1997，5(3)：1-10
35．闫俊萍，张中太，唐子龙等．插层复合材料的光催化研究进展，功能材料，2003，34 (5)：482-484
36．余灯华，廖世军，江国东．几种光催化剂及其研究进展，工业催化，2003，11：48-52
37．王玲玲，吴季怀．层状光催化纳米复合材料，化工新型材料．2002(30)：6-9；
38．徐悦华，古国榜．光催化剂改性及固定的研究进展，材料导报．2001(15)：33-35；
39．章永化，龚克成．聚合物／层状无机物纳米复合材料的研究进展，材料导报．1998(12)：61-65：
40．何天白，胡汉杰．功能高分子新技术，北京：化学工业出版社，2001；
41. Tsuneo M, Udagawa M, and Kunou I. Modification of the interlayer in Lanthanum-Niobium oxide and its catalytic reactions, J. Cata., 1997,168:26-34.
42. Tsungio S, Yositaka Y, Fujishiro Y, et aI. Intercalation of Fe_2O_3 in layered H_2Ti_4O_9 and H_4Nb_6O_(17): visible-light induced photocatalytic properties. Chem. Soc. Faraday Trans., 1996, 92:5089-5092
43. Sato T, Katsuhiko M, Sato K I, et al. Photocatalytic properties of layered hydrous titanium oxide/CdS-ZnS nanocomposites incorporating CdS-ZnS into the interlayer. J. Chem. Tech. Biotechnol., 1996, 67:339-344
44. Sato T, Yamamoto Y, Fujishiro Y, Uchida S. Photochemical reduction of nitrate to ammouia using layered hydrous titanate/cadmium sulphide nanocomposites. J. Chem. Soc., Faraday Trans., 1996, 92:5089-5092
45. Fang Mingming, Kim Chy Hyung, and Mallouk Thomas E., Dielectric properties of the lamellar niobates and titnonibates AM_2Nb_3O_(10) and ATiNbO_5(A=H, K, M=Ca, Pb), and their condensation products Ca_4Nb_6O_(19) and Ti_2Nb_2O_9, Chem. Mater. 1999,11,1519-1525
46. Hou W. H., Yan Q. J., Fu X. C. Preparation of silica-pillared layered tetratitanate with a high surface area. J. Chem. Soc., Chem. Com. 1994:1371-1372
47. Li Dan, Yang Juan, Zhang LiLi, et al. Synthesis and intercalation properties of nanoscale layered tetratianate. J. Mater. Chem., 2002, 12:1796-1799
48. Raymond E. Schaak and Thomas E. Mallouk, Self-assembly of titled perovskite monolyer and multiplayer thin films, Chem. Mater. 2000,12(9): 2513-2516
49. Raymond E. Schaak and Thomas E. Mallouk, Prying apart Ruddlesden-Propper phases: Exfoliation int sheets and nanotubes for assembly of perovskite thin films, Chem. Mater. 2000,12,3427-3434
50. Nozak R., Kondo J. N., Hirose C., Domen K., and Wada A., Vibrational study of layered perovskites M_2La_2Ti_3O_(10)(M=Li, Na, K, Rb): Raman spectra and normal mode analysis, J. Phys. Chem. B 2001,105,7950-7953
51. Satoshi Uchida, yositaka Yamamoto, Yoshinobu Fujishhiro, Akiar Watanabe, Osamu Ito and Tsugio Sato, Intercalation of titanium oxide in layered H_2Ti_4O_9 and H_4Nb_6O_(17) and photocatalytic water cleavage with H_2Ti_4O_9/(TiO_2,Pt) and H_4Nb6O_(17)/(TiO2,Pt) nanocomposites, J. Chem. Faraday Trans. 1997, 93(17), 3229-3234
52. Gambarotta S., Bolhuis Van F., A_2Ln_2Ti_3O_(10)(A=K, Rb, Ln=La or rare earth): A new serried of layered perovskties exhibiting ion exchange, Inorg. Chem., 1987, 26(26):,4299-4301
53. Soofin Cheng and Tzun-Chin Wang, Pillaring of layered titanates by polyoxo cations of aluminum, Inorg. Chem. 1989,28:1283-1289
54. Byeon Song-Ho, Lee Sung-Ohk, Kim Hongdoo, Structure and Raman spectra of layered titanium oxides, J. Solid State Chem., 1997,130:110-116
55. Byeon Song-Ho, Nam Hyo-Jin, Neutron diffraction and FT-Raman study of ion-exchangeable layered titanates and niobates, Chem. Mater. 2000,12:1771-1778
56. Byeon Song-Ho, Yoon Jong-Jin and Lee Sung-Okl, Brief communication: A new family of protonated oxides HLnTiO_4 (Ln=La, Nd, Sm and Gd), J. Solid State Chem. 1996,127:119-122
57. Takayoshi Sasaki, Momoru Watanabe, Hideo Hashizume, Hirohisa Yamada, and Hiromoto Nakazawa, Macromolecule-like aspects for a colloidal suspension of an exfoliation titanate. Pairwise association of nanosheets and dynamic reassembling process, J. Am. Chem. Soc. 1996,118:8329-8335
58. Takayoshi Sasaki, Momoru Watanabe, Osmotic swelling to exfoliation. Exceptionally high degrees of hydration of a layered titanate, J. Am. Chem. Soc. 1998,120:4682-4689
59. Takata T., Shinohara K., Tanaka A., Hara M., Knodo J. N., Domen K., A highly active photocatalyst for overall water splitting with a hydrated layered perovskites structure, J. Photochem. & Photobio. A: Chem, 1997,106:45-49
60. Takayoshi Sasaki, Yasuo Ebina, Tomohiro Tanaka, Masaru Harada and Momoru Watanabe, Layer-by layer assembly of titania nanosheet/polycation composite films, Chem. Mater., 2001,13(12):4661-4667;
61. Tisugio Sato, Yositaka Yamamoto, Yoshinobu Fujishiro and Satoshi Uchida, Intercalation of iron oxide in layered H_2Ti_4O_9 and H_4Nb_6O_(17): Visible-light induced photocatalytic properties, J. Chem. Soc. Faraday Trans. 1996,92:5089-5092
62．杜以波，D．G．Evans，孙鹏，段雪．阴离子层柱材料研究进展，化学通报，2000，5：20-24：
63．肖鹏，龚克成．层状双氢氧化物的制备及改性，材料导报，1999，13：43-45；
64．路艳罗，卫敏，杨文胜等．空气条件下高温固相合成层状LiMnO_2及其离子交换规律，高等学校化学学报，2002，11：2021-2025；
65. Makoto Ogawa and Yoshinao Takizawa. Intercalation of alkylammonium cations into a layered titanates in the presence of macrocyclic compounds. Chem. Mater. 1999, 11:30-32;
66. Izawa H., Kikkawa S., Effect of intercalated alkylammonium on cation exchange properties of H_2Ti_3O_7. J. Solid State Chem. 1987,69:336-342
67．杨娟．超细层状钛酸盐和复合纳米TiO_2的制备及性质研究，南京理工大学博士论文，2002；
68. Geofferey B. Saupe,. Chad C. Waraksa. Nanoscale tubules formed by exfoloation of Potassium hexaniobate. Chem. Mater. 2000,12:1556-1562
69. Han Yang-su, Park In and Choy Jin-Ho. Exfoliation of layered perovskite, KCa_2Nb_3O_(10), into colloidal nanosheets by a novel chemical process. J. Mater. Chem. 2001,11:1577-1282
70. Takayoshi Sasaki and Mamoru Watanabe. Osmotic swellimg to exfoliation. Exceptionally high degrees of hydration of a layered titanate. J. Am. Chem. Soc. 1998,120:4682-4689;
71. Takayoshi Sasaki, Mamoru Watanabe. Macromolecule-like aspects for a colloidal suspension of an exfoliated titanae. Pairwise association of nanosheets and dynamic reassembling processinitiated from it. J. Am. Chem. Soc. 1996,118:8329-8335
72．郭宪吉，侯文华，陆春良等．高比表面TiO_2柱层状HLaNb_2O_7的制备和表征，化学学报，2003，61：1976-1979．
73. Shangguan Wenfeng, Yoshida Akria, Influence of catalyst structure and modification on the photocatalytic production of hydrogen from water on mixed metal oxides, Inter. J. Hydro. Ener., 1999,24:425-431
74. Shangguan Wenfeng, Inoue Kozo and Yoshida Akria, Synthesis of silica-pillared layered titanium niobium oxide, Chem. Commun. 1998,779-780
75. Hou Wenhua, Ma Jun, Yan Qijie, Fu Xiancai, Highly thermostable, porous, layered titanoniobate pillared by silica, at. Chem, Soc. Chem. Commun. 1993,1144-1145
76. Ogawa M, Takizawa Y. Intercalation of alkylammonium cations into a layered titanate in the presence of macrocyclic compounds. Chem. Mater., 1999, 11:30-32
77. Choy J H, Lee H C, Jung H, et al. A novel synthetic route to TiO_2-pillared layered titanate with enhanced photocatalytic activity. J. Mater. Chem., 2001, 11: 2232-2234.
78．周春晖．层间模板导向剂合成新型多孔蒙脱石材料的研究，无机材料学报，2003，18(6)：1299-1302；
79．杨刚，侯文华，郭宪吉等．无机层状纳米材料与聚苯胺的复合研究，无机化学学报，2003，19：561-568：
80. Kim Bo-Hyun, Jung Jae-Hoon, Hong Seung-Hoon, and Joo Jinsoo, Nanocomposite of PAN and Na~+-montmorillonite clay, Macromolecules, 2002,35:1419-1423;
81. Matsuo Y., Higashika S., Kimura K., et al. Synthesis of PAN-intercalated layered materials via exchange reaction, J. Mater. Chem., 2002,12:1592-1596;
82. Shah D., Fytas G., Vlassopoulos D., et al. Structure and dynamics of polymer-grafted clay suspensions, Langmuir, 2005,21:19-25;
83．张雯，王红洁，金志浩．纳米多孔材料的显微结构设计，材料导报，2003，17：43-46；
84．陈启元，兰可，尹周澜等．半导体光解水研究进展，材料导报，2005，19：20-23；
85．杨娟．无机层状化合物及其柱撑产物光解水制氢，江苏大学学报，2003，24：53-55；
86. Mikhail Sychev, V. H. J.(San) de Beer, Alexander Kodentsov, et al. Chromia and chromium sulfide pillared clays: preparation, characterization, and catalytic activity for thiophene hydrodesulfurization, J. Cata., 1997,168:245-254;
87. Masaru Yanagisawa, Satoshi Uchida, Shu Yin, and Tsugio Sato, Synthesis of titania-pillared hydrogen tetratitanate nanocomposites and control of slit width, Chem. Mater., 2001,13:174-178;
88. Fujishima A., Honda K., Electrochemical photolysis of water at a semiconductor electrode, Nature, 1972,37(1):238;
89. Bunsho Ohtani, Yoshitaka Okugawa, Nishimoto Sei-ichi, et al. Photocatalytic activity of TiO_2 powders suspended in aqueous silver nitrate solution correlation with pH-dependent surface structures, J Phys. Chem., 1987,91:3550-3555;
90．栾勇，傅平丰，戴学刚，杜竹玮．金属离子掺杂对TiO_2光催化性能的影响，化工进展，2004，16：738-746：
91．梁金生，金宗哲，王静．稀土／纳米TiO_2的表面电子结构，中国稀土学报，2002，20：74-76；
92．孙振世，陈英旭，杨晔．Pt／TiO_2膜光催化氧化降解高聚物的研究，太阳能学报，2001，22：87-89；
93．张俊平，王艳，戚慧心．Eu、Ce、Y离子对TiO_2催化剂的改性作用，中国稀土学报，2002，20：478-480：
94. Akihiko Kudo, Eichi Kaneko, Photoluminescent properties of ion-exchangeable layered oxides, Microporous and Mesoporous Mater., 1998,21:615-620;
95. Gopalakrishnan J., Vasudeva Bhat. A_2La_2Ti_3O_(10)(A=K or Rb; Ln= La or Rare earth): A new series of layered Perovskites exhibiting ion exchange. Inorg. Chem. 1987,26:4329-4301;
96. Seetharaman Uma, Addepalli R., and Jagannatha Gopalakrishnan, Bridging the Ruddlesden-Popper and the Dion-Jacobson series of layered perovskites: synthesis of the layered oxides, A_(2-x)La_2Ti_(3-x)Nb_xO_(10)(A=K,Rb), exhibiting ion exchange, J. Mater. Chem., 1993,3(7):709-713;
97. Hyum G. Kim, Dong W. Hwang. Highly donor-doped (110) layered perocskite materials as novel photocatalysts for overall water splitting. Chem. Commun. 1999,1077-1078;
98. Landis M. E., Aufdembrink B. A., Chu P., Johnson I. D., Kirker G. W., Rubin M. K., Preparation of molecular sieves form dense, layered metal oxides, J. Am. Chem. Soc., 1991,113:3189-3190;
99. Leroux F., Adachi-Pagano M., Intissar M., Charviere S., Forano C., Besse J. P., Delamination and restacking of layered double hydroxides, J. Mater., Chem., 2001,11:105-112;
100．李建宇．稀土发光材料及其应用，北京：化学工业出版社，2003．9；
101．易宪武．钪 稀土元素，无机化学丛书第七卷(第二版)，北京：科学出版社，1998．10；
102. Li Dan, Wang Xin, Xiong Gang, et al. A novel technique to prepare ultrafine Fe_2O_3 via hydrated iron (Ⅲ) nitrate, J. Mater. Sci. Lett., 1997,16:493-495;
103. Yang Juan, Li Dan, Wang Xin, et al. Synthesis and microstructural control of nanocrystalline titania powders via stearic acid method, Mater. Sci. & Engin. A, 2002,328:108-112;
104. Liu Xiaoheng, Yang Juan, Wang Ling, et al. An improvement on sol-gel method for preparing ultrafine and crystalline titania powder, Mater. Sci. & Engin. A, 2000, 289:241-245;
105．中山大学金属系编．稀土物理化学常数，冶金工业出版社(第一版)，1978；
106．褚明福，邹乐希，仲敬荣．拉曼和红外光谱在材料研究中的应用，稀有金属，2005，29：106-111
107. Byeon Song-ho, Lee Sung-ohk, and Kim Hongdoo, Structure and Raman spectra of layered titanium oxides, J. Solid State Chem., 1997,130:110-116;
108. Toda Kenji, Wtanabe Jun and Sato Mineo, Crystal structure determination of ion-exchangeable layered perovskite compound K_2La_2Ti_3O_(10) and Li_2La_2Ti_3O_(10), Mater. Res. Bull., 1996,31:1427-1435;
109．王智民，李丽，刘静波等．Li~+-Ca_xPb_(1-x)TiO_3湿敏纳米薄膜的激光拉曼光谱、晶格畸变和激光显微组织——应用“软模理论”解谱，化学学报，2005，63：81-85；
110．戴洪兴，何洪，李佩荇等．稀土钙钛矿型氧化物催化剂研究进展，吕国稀土学报，2003，21：1-15：
111．曲昭君，于春英，李文钊．掺杂钙钛矿型氧化物的固体结构及其可交换氧，物理化学学报，1994，10：796-801；
112．于洁，王华，马文全．复合掺杂钙钛矿氧化物催化剂的研究进展，昆明理工大学学报，2003，28：19-22
113．吴越．催化化学．北京：科学出版社，1998
114．陈笃慧，廖远琰，万惠霖．La_2O_3-BaO系复合氧化物的现场拉曼光谱研究，化学物理学报，1997，10：133-139
115．程传煊．表面物理化学，北京：科学技术文献出版社，1995．9
116．陈金富．固体物理学，北京：高等教育出版社，1986：
117．张光寅．晶格振动光谱学(第2版)，北京：高等教育出版社，2001
118. Milanova Maria M., Kakihana Masato, Arima Momoko, et al. A simple solution route to the synthesis of pure La_2Ti_2O_7 and Nd_2Ti_2O_7 at 700-800C by polymerized comples method, J. Alloys and Compouds, 1996,242:6-10;
119. Raymond E. S., Dawood Afzal, Joshua A. S. et al, Na_2Ln_2Ti_(3-x)Mn_xO_(10) (Ln=Sm, Eu, Gd, and Dy; 0≤x≤1):A new series of ion-exchangeable layered perovskites containing SB-site manganese, Chem. Mater., 2002,14:442-448;
120. LilianaViciu, Nicolas Liziard, Vlasimir Golub, et al. Transition-metal Dion-Jacobson layered pervskites M_(0.5)LaNb_2O_7, Mater. Res. Bull., 2004,39,2147-2154;
121. Jesus Canales-Vazuez, John T. S. Trvine, and Zhou Wuzong, Synthesis and characterization of n=5,6 members of the La_4Sr_(n-4)Ti_nO_(3n+2) series with layered structure based upon perovskite, J. Solid State Chem., 2004,177:2039-2043;
122. Liu F. S., Liu Q. L., Liang J. K., et al, A systematic study on crystal structure and magnetic properties of Ln_3GaO_6 (Ln=Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er), J. Solid State Chem., 2004,177:1796-1802;
123. Rabindra N. D., Pathak A., and Pramanik P., J Am, Ceram. Soc., 1998,81:3357
124. Asai T., Camargo E. R., Kakihana and Osada M., A novel aqueous solution route to the low-temperature synthesis of SrBi_2Nb_2O_9 by use of water-soluble Bi and Nb complexes, J. Alloys Compounds, 2000,309:113
125．甘树才，李红英，孟健，洪广言．溶胶-凝胶法合成稀土Z型铁氧体Ba_(3-x)La_xCo_2Fe_(24)O_(41)与表征，中国稀土学报，2004，22：751-754；
126. Yang Juan, Li Dan, Wang Xin, et al. Study on the synthesis and ion-exchange properties of layered titanate Na_2Ti_3O_7 powders with different sizes, J. Mater. Sci. 2003, 38:2907-2911;
127. Yang Juan, Li Dan, Wang Hengzhi, et al. Effect of particle size of staring material TiO_2 on morphology and properties of layered titanates, Mater. Lett., 2001,50:230-234;
128. Machida Masato, Yabunaka Jun-ichi, and Kijima Tsuyoshi, Synthesis and photocatalytic property of layered perovskite tantalates, RbLnTa_2O_7(Ln=La, Pr, Nd, and Sm), Chem. Mater., 2000,12,812-817;
129. Machida Masato, Yabunaka Jun-ichi, and Kijima Tsuyoshi, et al, Electronic structure of layered tantalates photocatalysts, RbLnTa_2O_7 (Ln=La, Pr, Nd, and Sm), Inter. J. Inorg. Mater., 2001,3:545-550;
130. Zhu Jun-jie, Wang Hui, Xu Shu, et al, Sonochemical method for the preparation of monodisperse spherical and rectangular lead selenide nanoparticles, Langmuir, 2002,18:3306-3310;
131．冯新．高质量低成本钛酸钾晶须的制备及其在复合材料中的应用，南京化工大学博士论文．2000；
132．谢凯，盘毅，王秀华．钛酸钾短纤维的制备工艺研究，无机盐工业，1997，1：16-17；
133. Zhu Huaiyong, Gao Xueping, Lan Ying, et al. Hydrogen titanata nanofibers cover with anatase nanocrystals: A delicate structure achieved by the wet chemistry reaction of the titanate nanofibers, J. Am. chem. Soc. 2004,126:8380-8381;
134. Nedeljkovic J. M., Micic O. I., Ahrenkiel S. P., et al. Growth of InP nanostructures via reaction of indium droplets with phosphide ions: Synthesis of InP quantum rods and InP-TiO_2 composites, J. Am. Sac., 2004,126:2632-2639;
135．曹忠良，王珍云．无机化学反应方程式手册，湖南：湖南科学出版社，1985，p260
136．武汉大学化学系等编著．稀土元素分析化学，北京：科学出版社，1983：
137. Izawa H., Kikkawa S. and Koizumi M., Ion exchange and dehydration of layered [sodium and potassium] titanates, Na_2Ti_3O_7 and K_2Ti_4O_9, J. Phys. Chem. 1982, 86: 5023-5026
138. Airold C., Nunes L. M. and Farias R. F., The intercalation of n-alkyldiamines into crystalline layered titanate, Mater. Res. Bull. 35(2000) 2081-2090
139. Takayoshi Sasaki, Mamoru Watanabe. Layered hydrous titanium dioxide: potassium ion exchange and structural characterization. Inorg. Chem. 1985(24):2265-2271;
140．中本一雄(日)．无机合配位化合物的红外和拉曼光谱(第四版)，北京：化学工业出版社，1991．2：
141．北京师范大学等编．无机化学(第三版)，高等教育出版社，1994
142．卫敏，谭娜，杨文胜等．层装钠锰氧化物的制备及离子交换反应动力学，应用化学，200320)5：437～442
143．傅献彩，沈文霞，姚天杨．物理化学(第四版)，北京：高等教育出版社，1990
144．华中师范大学等编．分析化学(第二版)，北京：高等教育出版社，1990；
145. Kwon O Y, Jeong S Y, Seo J K, Effect of organic solvents in the intercalation of octylamine into H-magadiite, J. Collid and Interface Sic., 1996,177:887-896
146．陈新，王海，侯文华等．新型中孔氧化硅柱层状锰钛酸的合成，无机化学学报，2002，18(6)：550-553；
147. Kooli F., Sasaki T., Mizukami F. et al. Characterization and acid properties of silica pillared titanates, J. Mater. Chem., 2001,11:841-845;
148．侯文华，徐林，颜其洁，陈静．具有超大通道结构的介孔氧化硅层状钛酸的合成和催化应用初探，无机化学学报，2002，18(7)：744；
149．李瑛，钟家圣．纳米TiO_2气相光催化氧化苯胺的研究(Ⅰ)，武汉大学学报，2005，51：145-148：
150．冷文华，童少平，成少安等．附载型二氧化钛光电催化降解苯胺机理，环境科学学报，2002，20(6)：781-786：
151．冷文华，成少安，刘洪等，负载型二氧化钛光催化降解苯胺，环境科学学报，2000，20：499-503：
152．李涛海，吴季怀，林建明等．酸化对层状K_2La_2Ti_3O_(10)活性的影响，感光科学与光化学，2004，22(2)120-125：
153．侯文华，汪学广，颜其洁等．具有不同层间距、比表面和孔径大小的氧化硅柱层状铌酸盐的制备，高等学校化学学报，1999，20(11)：1793；
154．朱建喜，何宏平，杨丹等．柱撑蒙脱石及其产物热处理孔性研究，无机材料学报，2004，19(2)324-328
155. Cheng S F, Wang T C. Pillaring of layered titanates by polyoxo cations of aluminum, Inorg Chem. 1989, 18(7): 1283-1289.
156．陈亚芍，侯文华，颜其洁．氧化铝柱层状镧钛酸盐的制备，无机化学学报，1995，11(4)：399：
157. Yin Shu, Sato Tsugio, Photocalatic activity of platinum loaded fibrous titania prepared by solvothermal process, J. Photochem. & Photobio. A: Chem., 2005,196:89-94;
158. Paola A. D., Garcia-Lopez E., Ikeda S., et al. Photocatalytic degradation of organic compounds in aqueous system by transition metal doped polycrystalline TiO_2, Cata. Today, 2002,75:87-93;
159. Hwang D. W., Kim H. G., Jang J. S., et al, Photocatalytic decomposition of water-methanol solution over metal-deped layered perovskite under visible light irradiation, Cata. Today, 2004,93-95:845-850;
160. Zhao Xueguo, Shi Jianlin, Hu Bin, et al, In stiu formation of silver nanoparticles inside pore channels of ordered mesoporous silica, Mater. Lett., 2004,58:2152-2156;
161. Kudo A., Sayama K., Tanaka A., et al, Nickel-loade K_4Nb_6O_(17) Photocatalyst in the decomposition of H_2O into H_2 and O_2: structure and reaction mechanism, J. Cata., 1989,120:337-352;
162. Kudo A., Tanaka A., Domen K.,, et al, Photocatalytic decomposition of water over NiOK_4Nb_6O_(17) catalyst, J. Cata., 1988,111:67-76;
163. Inoue Yasunobu, Kubokawa Toyoyuki, and Sato Kazunori, Photocatalytic activity of akli-metal titanates combined with Ru in the decomposition of water, J. Phys. Chem., 1991,95:4059-4063;
164. Wu Jihuai, Lin Jianming. Synthesis and photocatalytic properties of layered HNbWO_6/ (Pt,Cd_(0.8)Zn_(0.2)S) nanocomposites. J. Mater. Chem. 2001(11):3343-3347
165. Hwang Dong Won, Kin Hyun Gyu, Kim Jindo, et al, Photocalatic water spiltting over highly donor-doped (110) layered perovskites, J. Cata., 2000,193:43-48;
166．吴树新，马智，秦永宁等．掺杂纳米TiO_2光催化性能研究，物理化学学报，2004，20：138-143
167．刘守新，曲振平，韩秀文等．Ag担载对TiO_2光催化活性的影响，催化学报，2004，25：133-137；
168. Sadeghi M., Liu W., Zhang T-G, et al, Role of Photoinduced Charge Carrier Separation Distance in Heterogeneous Photocatalysis: Oxidative Degradation of CH_3OH Vapor in Contact with Pt/TiO_2 and Cofumed TiO_2-Fe_2O_3, J. Phys. Chem., 1996,100(50):19466;
169. Izumi I., Dunn W. W., Wilboum K. O., et al, Heterogeneous photocatalytic oxidation of hydrocarbons on platinized titanium dioxide powders, J. Phys. Chem., 1980,84(24):3207;
170．顾庆超，楼书聪，戴庆平等编．化学用表，南京：江苏教育出版社，1979，P9；
171．姚允斌，解涛，高英敏．物理化学手册，上海：上海科学技术出版社，1985，P838；
172. Schetz Peter and Caruso Frank, Semiconductor and metal nanoparticle formation on polymer spheres coated with week pilyelectrolyte multilayers, Chem. Mater., 2004,16:3066-3073;
173. Lee Daeyeon, Rubner Michael F., Cohen Robert E., Formation of nanoparticle-loaded microcapsules based on hydrogen-bonded multilayers, Chem. Mater., 2005,17:1099-1105;
174. Djerdiev Ales M., Beattie Janes K., O'brien Richard W., Coating of silica on titania pigment particles examined by electroacoustics and dielectric response, Chem. Mater., 2005,17:3844-3849;
175. Ruxandra Vidu, Pieter Stroeve, Improvement of the thermal stability of Li-ion batteries by polymer coating of LiMn_2O_4, Inter. Eng. Chem. Res., 2004,43:3314-3324;
176. Wang Zhongchun, Medforth Craig J., Schelnutt John A., Self-metallization of photocztalytic porphyrin nanotubes, J. Am. Chem. Soc., 2004,126:16720-16721;
177. Liu Mingzhao, Philippe Guyot-Sionnest, Synthesis and optical characterization of Au/Ag core/shell nanorods, J. Phys. Chem. B, 2004,108:5882-5888;
178. Santra Swadeshmukul, Tapec Rovelyn, Theodorpoulou Nikoleta, et al, Synthesis and characterization of silica-coated iron oxide nanoparticles in microemilsion: the effect of nonionic surfacents, Langmuir, 2001,17:2900-2906;
179. Drew Christopher, Liu Xin, Ziegler David, et al, Metal oxide-coated polymer nanofibers, Nano Letters, 2003,3:143-147;
180. Zeng Hao, Li Jing, Wang Z. L., et al, Bimagnetic core. shell FePt/Fe_3O_4 nanoparticles, Nano Letters, 2004,4:187-190;
181．颜秀茹，白天，霍明亮等．核-壳式纳米SnO_2-TiO_2光催化剂的制备和性能，催化学报，2004，25：120-124；
182．夏海龙，唐芳琼．SiO_2／ZnO复合纳米粒子的制备及表征，无机化学学报，2002，18：769-772；
183．张敬畅，高玲玲，曹维良．纳米TiO_2-SiO_2复合光催化剂的超临界流体干燥法制备及其光催化性能研究，无机化学学报，2003，19：934-939；
184．关凯书，尹衍升，姜秋鹏．TiO_2-SiO_2复合薄膜光催化活性与亲水性关系研究，硅酸盐学报，2003，31：219-228；
185．王宝祥，左朝阳，赵晓鹏．包覆型高岭土／二氧化钛纳米复合颗粒的电流变效应，无机材料学报，2004，19：492-496；
186. Politer P., Lane P., Energetics of ammonium perchlorate decomposition steps, J. Molecular Structure (Theochem), 1998,454:229-235;
187. Brill T. B., Brush P. J., Patil D. G., Thermal decomposition of energetic materials 60 major reaction stages of simulated burning surface of NH_4ClO_4, Combustion and Flame, 1993,94:70-76;
188. Singh G., Kapoor I. P. S., Mannan S. M., et al, Stusies on energetic compounds part 8: thermolysis of salts of HNO_3 and HClO_4, J. Hazardous Mater. A, 2000,79:1-19;
189．任务正，王泽山主编．火炸药理论与实践(第一版)，北京：中国北方化学工业总公司出版，2001；
190．刘子如，阴翠梅，孔扬辉等．高氯酸铵的热分解，含能材料，2000，8(2)：75-79；
191．罗元香．火炸药用纳米催化剂的制备及性能研究，南京理工大学博士论文，2004；
192．韩建成等著．多晶X射线结构分析，上海：华东师范大学出版社，1987；
193．刘粤惠，刘平安．X射线衍射分析原理与应用，北京：化学工业出版社，2003．10；
194. Cumming A. S, Leiper G A, Robson E. Molecular Modeling as a Tool to Aid the Design of Polymer Bonded Explosives. 24th International Annual Conference of ICT, Karlsruhe, Germany: 1993.
195．Jiang Zhenyi，Xu Xiaohong，Wu Haishun，Zhang Fuqiang，Jin Zhihao，Ad initio calculation of SiC pilytyoes。创腾科技第二届中国用户学术研讨会论文集(材料科学篇)，2002．5：71-75；
196．孟醒，徐小光，刘伟，孙源，陈岗．钙钛矿型HoNiO_3中电荷岐化的第一性原理研究，物理学报，2004，53(11)：3873-3876；
197. Zhou Danhong. Study with density functional theory method on methane dehydro-aromatization over Mo/HZSM-5 catalyst Ⅰ: optimization of active Mo species bonded to ZSM-5 zeolite, Journal of Chemical Physics, 2001, 114(20):9125-9129;
198. Lin Zheshuai. Mechanism for linear and nonolinear optical effects in monoclinic bismuth borate (BiB_3O_6) crystal, Journal of applied physics, 2001, 90(11): 5587-5590;
199. Zhou Y. C., Wang X. H., Sun Z. M., Chen S. Q. Electronic and structural properties of the layered ternary carbide Ti_3AlC_2, J. Mater. Chem., 2001,11,2335,2339
200. ZhouYanchun, Sun Zhimei, Wang Xiaohui and Chen Shengqi, Ab initio geometry optimization and ground state properties of layered ternary carbides Ti_3MC_2 (M=Al, Si, Ge), Journal of Physics Condensed Matter, 2001,13:10001-10010;
201．赵成大．固体量子化学——材料化学的理论基础，北京：高等教育出版社，1997；
202．吕世骥，范印哲．固体物理教程(第一版)，北京：北京大学出版社，1990。
2. Nalwa H S. Handbook of nanostructured material and nanotechnology, Chap. 1. Academic Press. San Diego. 1999;
3．柯扬船，皮特·斯壮．聚合物-无机纳米复合材料．北京：化学工业出版社，2002．12；
4. Kazunari D, Junko N K, Michikazu H, et al. Photo- and machano- catalytic overall water splitting reactions to form H_2 and O_2 on heterogeneous catalyst. Bull Chem. Soc. Jpn., 2000, 73:1307-1331.
5．郭宪吉，侯文华，颜其洁等．层柱过渡金属氧化物．科学通报，2002，47：1681-1689．
6. Brian L. Cushing, Vladimir L. Kolesnichenko, and Charles J. O'Conner. Recent advances in the liquid-phase syntheses of inorganic nanoparticles. Chem. Rev., 2004,104:3893-3946;
7．徐如人，庞文琴．无机合成和制备化学，北京：高等教育出版社，2001；
8．汪信，陆路德．纳米金属氧化物的制备及应用研究的若干进展．无机化学学报．2000，16：213-216：
9. Chebiam R. V., Prado F., Soft chemistry synthesis and characterization of layered Li_(1-x)Ni_(1-y)Co_yO_(2-δ)(0≤x≤1 and 0≤y≤1). Chem. Mater. 2001, 13:2951-2957;
10．杨娟，李丹，吴东辉，杨绪杰，陆路德，汪信．硬脂酸法制备纳米TiO_2及其微结构控制，无机材料学报，2001，16(3)：550-554；
11．吴东辉，李丹，杨娟，杨绪杰，陆路德，汪信．硬脂酸法制备SO_4~(2-)／Fe_2O_3-SiO_2固体酸及其催化性能的初步探讨，高等学校化学学报，2001，22：1877-1880；
12．吴东辉，李丹，杨娟，杨绪杰，陆路德，汪信．微波辐射溶胶-凝胶法制备均分散纺锤形α-Fe_2O_3超细粒子，功能材料，2002，32：39-40
13. Yang Juan, Li Dan, Wang Xin, et al. Rapid synthesis of nanocrystalline TiO_2/SnO_2 binary oxides and their photoinduced decomposition of methyl orange. J. Solid State Chem., 2002, 165:193-198.
14. Li Dan, Wu Dong Hui, Wang Xin, et al. Rapid preparation of porous Fe_2O_3/SiO_2 nanocomposites via an organic precursor. Mater. Res. Bull., 2001, 36:2437-2442
15. Xiaohui Wang, Dan Li. The preparation of barium ferrite nanocrystalline powders by a stearic acid gel method. Mater. Lett. 1996, 28:203-206;
16. Xiong Gang, Zhi Zheng-liang, Yang xiujie, Lu Lude, Wang Xin, Characterization of perovskite-type LaCoO_3 nanocrystals prepared by a stearic acid sol-gel method. J. Mater. Sci. Lett. 1997, 16:1964-1968
17. Xiong Gang, Wang Xin, Yang Xujie, et al. Characterization and size-depedent magnetic properties of Ba_3Co_2Fe_(24)O_(41) nanocrystals synthesized through a sol-gel method. J. Mater. Sci. 2000, 35: 931-935;
18．沈彩，刘庆峰，刘茜．柠檬酸-硝酸盐燃烧法制备Ba_(0.5)Sr_(0.5)TiO_3介电材料，无机材料学报，2004，19：681-685：
19．宿新泰，刘瑞泉，胡云霞等．柠檬酸盐溶胶-凝胶制备Ba_3(Ca_(1.18)Nb_(1.82)O_(9-δ)纳米粉末，无机材料学报，2004，19：229-233：
20．于东生，周震涛．纳米La_(0.7)Sr_(0.3)MnO_3的制备及其电催化性能，全国第三届纳米材料和技术应用会议论文集(上)．278～290；
21．罗君，刑献然，于然波等．溶胶-凝胶法合成钛酸锌陶瓷粉体，无机化学学报，2004，20：1182-1185
22．牛新书，许亚杰，张学治等．微乳液法制备纳米TiO_2及其光催化活性，功能材料，2003，34：548-552；
23．陈宗淇，王光信，徐桂英．胶体与界面化学，北京：高等教育出版社，2201，9；
24．郭广生，顾福博，王志华等．La_2(CO_3)_3纳米线的微乳液法制备与表征，无机化学学报，2004，20(7)：860-862：
25. Tetsuy K, Guoqing G, Yuuki M, et al. Photocatalytic hydrogen production from water over a LaMnO_3/CdS nanocomposites prepared by the reverse micelle method. J. Mater. Chem., 2003,13:1186-1191
26. Junwu Zhu, Dan Li, Haiqun Chen, Xujie Yang, Lude Lu, Xin Wang, Highly dispersed CuO nanoparticales prepared by a novel quick-precipitation method, Mater. Lett. 2004,58,3324-3327
27．朱俊武，张维光，王恒志等．纳米CuO的形貌控制合成及其性质研究，无机化学学报，2004，20(7)：863-867；
28．吴涛，张希．自组装超薄膜：从纳米层状构筑到功能组装，高等学校化学学报，2001，22：1057-1065：
29．李丹．聚苯胺自组装复合膜的制备及功能特性，电子科技大学博士论文，1999；
30．沈家骢．超分子层状结构——组装与功能，北京：科学出版社，2004；
31. Panneerselvam M., Rao K. J., Microwave preparation and sintering of industrially important perovskite oxide: LaMO_3 (M=Cr, Co, Ni ), J. Mater. Chem., 2003, 13: 596-601;
32．白音孟和，纪敏，刘新等．层状K_4Ag_2Sn_3S9_2·H_2O的溶剂热合成与表征，高等学校化学学报，2004，25(8)：1391-1394；
33．上官文峰．太阳能光解水制氢的研究进展，无机化学学报，2001，17：619-626．
34．张彭义，余刚，江展彭．半导体光催化剂及其改性技术进展，环境科学进展，1997，5(3)：1-10
35．闫俊萍，张中太，唐子龙等．插层复合材料的光催化研究进展，功能材料，2003，34 (5)：482-484
36．余灯华，廖世军，江国东．几种光催化剂及其研究进展，工业催化，2003，11：48-52
37．王玲玲，吴季怀．层状光催化纳米复合材料，化工新型材料．2002(30)：6-9；
38．徐悦华，古国榜．光催化剂改性及固定的研究进展，材料导报．2001(15)：33-35；
39．章永化，龚克成．聚合物／层状无机物纳米复合材料的研究进展，材料导报．1998(12)：61-65：
40．何天白，胡汉杰．功能高分子新技术，北京：化学工业出版社，2001；
41. Tsuneo M, Udagawa M, and Kunou I. Modification of the interlayer in Lanthanum-Niobium oxide and its catalytic reactions, J. Cata., 1997,168:26-34.
42. Tsungio S, Yositaka Y, Fujishiro Y, et aI. Intercalation of Fe_2O_3 in layered H_2Ti_4O_9 and H_4Nb_6O_(17): visible-light induced photocatalytic properties. Chem. Soc. Faraday Trans., 1996, 92:5089-5092
43. Sato T, Katsuhiko M, Sato K I, et al. Photocatalytic properties of layered hydrous titanium oxide/CdS-ZnS nanocomposites incorporating CdS-ZnS into the interlayer. J. Chem. Tech. Biotechnol., 1996, 67:339-344
44. Sato T, Yamamoto Y, Fujishiro Y, Uchida S. Photochemical reduction of nitrate to ammouia using layered hydrous titanate/cadmium sulphide nanocomposites. J. Chem. Soc., Faraday Trans., 1996, 92:5089-5092
45. Fang Mingming, Kim Chy Hyung, and Mallouk Thomas E., Dielectric properties of the lamellar niobates and titnonibates AM_2Nb_3O_(10) and ATiNbO_5(A=H, K, M=Ca, Pb), and their condensation products Ca_4Nb_6O_(19) and Ti_2Nb_2O_9, Chem. Mater. 1999,11,1519-1525
46. Hou W. H., Yan Q. J., Fu X. C. Preparation of silica-pillared layered tetratitanate with a high surface area. J. Chem. Soc., Chem. Com. 1994:1371-1372
47. Li Dan, Yang Juan, Zhang LiLi, et al. Synthesis and intercalation properties of nanoscale layered tetratianate. J. Mater. Chem., 2002, 12:1796-1799
48. Raymond E. Schaak and Thomas E. Mallouk, Self-assembly of titled perovskite monolyer and multiplayer thin films, Chem. Mater. 2000,12(9): 2513-2516
49. Raymond E. Schaak and Thomas E. Mallouk, Prying apart Ruddlesden-Propper phases: Exfoliation int sheets and nanotubes for assembly of perovskite thin films, Chem. Mater. 2000,12,3427-3434
50. Nozak R., Kondo J. N., Hirose C., Domen K., and Wada A., Vibrational study of layered perovskites M_2La_2Ti_3O_(10)(M=Li, Na, K, Rb): Raman spectra and normal mode analysis, J. Phys. Chem. B 2001,105,7950-7953
51. Satoshi Uchida, yositaka Yamamoto, Yoshinobu Fujishhiro, Akiar Watanabe, Osamu Ito and Tsugio Sato, Intercalation of titanium oxide in layered H_2Ti_4O_9 and H_4Nb_6O_(17) and photocatalytic water cleavage with H_2Ti_4O_9/(TiO_2,Pt) and H_4Nb6O_(17)/(TiO2,Pt) nanocomposites, J. Chem. Faraday Trans. 1997, 93(17), 3229-3234
52. Gambarotta S., Bolhuis Van F., A_2Ln_2Ti_3O_(10)(A=K, Rb, Ln=La or rare earth): A new serried of layered perovskties exhibiting ion exchange, Inorg. Chem., 1987, 26(26):,4299-4301
53. Soofin Cheng and Tzun-Chin Wang, Pillaring of layered titanates by polyoxo cations of aluminum, Inorg. Chem. 1989,28:1283-1289
54. Byeon Song-Ho, Lee Sung-Ohk, Kim Hongdoo, Structure and Raman spectra of layered titanium oxides, J. Solid State Chem., 1997,130:110-116
55. Byeon Song-Ho, Nam Hyo-Jin, Neutron diffraction and FT-Raman study of ion-exchangeable layered titanates and niobates, Chem. Mater. 2000,12:1771-1778
56. Byeon Song-Ho, Yoon Jong-Jin and Lee Sung-Okl, Brief communication: A new family of protonated oxides HLnTiO_4 (Ln=La, Nd, Sm and Gd), J. Solid State Chem. 1996,127:119-122
57. Takayoshi Sasaki, Momoru Watanabe, Hideo Hashizume, Hirohisa Yamada, and Hiromoto Nakazawa, Macromolecule-like aspects for a colloidal suspension of an exfoliation titanate. Pairwise association of nanosheets and dynamic reassembling process, J. Am. Chem. Soc. 1996,118:8329-8335
58. Takayoshi Sasaki, Momoru Watanabe, Osmotic swelling to exfoliation. Exceptionally high degrees of hydration of a layered titanate, J. Am. Chem. Soc. 1998,120:4682-4689
59. Takata T., Shinohara K., Tanaka A., Hara M., Knodo J. N., Domen K., A highly active photocatalyst for overall water splitting with a hydrated layered perovskites structure, J. Photochem. & Photobio. A: Chem, 1997,106:45-49
60. Takayoshi Sasaki, Yasuo Ebina, Tomohiro Tanaka, Masaru Harada and Momoru Watanabe, Layer-by layer assembly of titania nanosheet/polycation composite films, Chem. Mater., 2001,13(12):4661-4667;
61. Tisugio Sato, Yositaka Yamamoto, Yoshinobu Fujishiro and Satoshi Uchida, Intercalation of iron oxide in layered H_2Ti_4O_9 and H_4Nb_6O_(17): Visible-light induced photocatalytic properties, J. Chem. Soc. Faraday Trans. 1996,92:5089-5092
62．杜以波，D．G．Evans，孙鹏，段雪．阴离子层柱材料研究进展，化学通报，2000，5：20-24：
63．肖鹏，龚克成．层状双氢氧化物的制备及改性，材料导报，1999，13：43-45；
64．路艳罗，卫敏，杨文胜等．空气条件下高温固相合成层状LiMnO_2及其离子交换规律，高等学校化学学报，2002，11：2021-2025；
65. Makoto Ogawa and Yoshinao Takizawa. Intercalation of alkylammonium cations into a layered titanates in the presence of macrocyclic compounds. Chem. Mater. 1999, 11:30-32;
66. Izawa H., Kikkawa S., Effect of intercalated alkylammonium on cation exchange properties of H_2Ti_3O_7. J. Solid State Chem. 1987,69:336-342
67．杨娟．超细层状钛酸盐和复合纳米TiO_2的制备及性质研究，南京理工大学博士论文，2002；
68. Geofferey B. Saupe,. Chad C. Waraksa. Nanoscale tubules formed by exfoloation of Potassium hexaniobate. Chem. Mater. 2000,12:1556-1562
69. Han Yang-su, Park In and Choy Jin-Ho. Exfoliation of layered perovskite, KCa_2Nb_3O_(10), into colloidal nanosheets by a novel chemical process. J. Mater. Chem. 2001,11:1577-1282
70. Takayoshi Sasaki and Mamoru Watanabe. Osmotic swellimg to exfoliation. Exceptionally high degrees of hydration of a layered titanate. J. Am. Chem. Soc. 1998,120:4682-4689;
71. Takayoshi Sasaki, Mamoru Watanabe. Macromolecule-like aspects for a colloidal suspension of an exfoliated titanae. Pairwise association of nanosheets and dynamic reassembling processinitiated from it. J. Am. Chem. Soc. 1996,118:8329-8335
72．郭宪吉，侯文华，陆春良等．高比表面TiO_2柱层状HLaNb_2O_7的制备和表征，化学学报，2003，61：1976-1979．
73. Shangguan Wenfeng, Yoshida Akria, Influence of catalyst structure and modification on the photocatalytic production of hydrogen from water on mixed metal oxides, Inter. J. Hydro. Ener., 1999,24:425-431
74. Shangguan Wenfeng, Inoue Kozo and Yoshida Akria, Synthesis of silica-pillared layered titanium niobium oxide, Chem. Commun. 1998,779-780
75. Hou Wenhua, Ma Jun, Yan Qijie, Fu Xiancai, Highly thermostable, porous, layered titanoniobate pillared by silica, at. Chem, Soc. Chem. Commun. 1993,1144-1145
76. Ogawa M, Takizawa Y. Intercalation of alkylammonium cations into a layered titanate in the presence of macrocyclic compounds. Chem. Mater., 1999, 11:30-32
77. Choy J H, Lee H C, Jung H, et al. A novel synthetic route to TiO_2-pillared layered titanate with enhanced photocatalytic activity. J. Mater. Chem., 2001, 11: 2232-2234.
78．周春晖．层间模板导向剂合成新型多孔蒙脱石材料的研究，无机材料学报，2003，18(6)：1299-1302；
79．杨刚，侯文华，郭宪吉等．无机层状纳米材料与聚苯胺的复合研究，无机化学学报，2003，19：561-568：
80. Kim Bo-Hyun, Jung Jae-Hoon, Hong Seung-Hoon, and Joo Jinsoo, Nanocomposite of PAN and Na~+-montmorillonite clay, Macromolecules, 2002,35:1419-1423;
81. Matsuo Y., Higashika S., Kimura K., et al. Synthesis of PAN-intercalated layered materials via exchange reaction, J. Mater. Chem., 2002,12:1592-1596;
82. Shah D., Fytas G., Vlassopoulos D., et al. Structure and dynamics of polymer-grafted clay suspensions, Langmuir, 2005,21:19-25;
83．张雯，王红洁，金志浩．纳米多孔材料的显微结构设计，材料导报，2003，17：43-46；
84．陈启元，兰可，尹周澜等．半导体光解水研究进展，材料导报，2005，19：20-23；
85．杨娟．无机层状化合物及其柱撑产物光解水制氢，江苏大学学报，2003，24：53-55；
86. Mikhail Sychev, V. H. J.(San) de Beer, Alexander Kodentsov, et al. Chromia and chromium sulfide pillared clays: preparation, characterization, and catalytic activity for thiophene hydrodesulfurization, J. Cata., 1997,168:245-254;
87. Masaru Yanagisawa, Satoshi Uchida, Shu Yin, and Tsugio Sato, Synthesis of titania-pillared hydrogen tetratitanate nanocomposites and control of slit width, Chem. Mater., 2001,13:174-178;
88. Fujishima A., Honda K., Electrochemical photolysis of water at a semiconductor electrode, Nature, 1972,37(1):238;
89. Bunsho Ohtani, Yoshitaka Okugawa, Nishimoto Sei-ichi, et al. Photocatalytic activity of TiO_2 powders suspended in aqueous silver nitrate solution correlation with pH-dependent surface structures, J Phys. Chem., 1987,91:3550-3555;
90．栾勇，傅平丰，戴学刚，杜竹玮．金属离子掺杂对TiO_2光催化性能的影响，化工进展，2004，16：738-746：
91．梁金生，金宗哲，王静．稀土／纳米TiO_2的表面电子结构，中国稀土学报，2002，20：74-76；
92．孙振世，陈英旭，杨晔．Pt／TiO_2膜光催化氧化降解高聚物的研究，太阳能学报，2001，22：87-89；
93．张俊平，王艳，戚慧心．Eu、Ce、Y离子对TiO_2催化剂的改性作用，中国稀土学报，2002，20：478-480：
94. Akihiko Kudo, Eichi Kaneko, Photoluminescent properties of ion-exchangeable layered oxides, Microporous and Mesoporous Mater., 1998,21:615-620;
95. Gopalakrishnan J., Vasudeva Bhat. A_2La_2Ti_3O_(10)(A=K or Rb; Ln= La or Rare earth): A new series of layered Perovskites exhibiting ion exchange. Inorg. Chem. 1987,26:4329-4301;
96. Seetharaman Uma, Addepalli R., and Jagannatha Gopalakrishnan, Bridging the Ruddlesden-Popper and the Dion-Jacobson series of layered perovskites: synthesis of the layered oxides, A_(2-x)La_2Ti_(3-x)Nb_xO_(10)(A=K,Rb), exhibiting ion exchange, J. Mater. Chem., 1993,3(7):709-713;
97. Hyum G. Kim, Dong W. Hwang. Highly donor-doped (110) layered perocskite materials as novel photocatalysts for overall water splitting. Chem. Commun. 1999,1077-1078;
98. Landis M. E., Aufdembrink B. A., Chu P., Johnson I. D., Kirker G. W., Rubin M. K., Preparation of molecular sieves form dense, layered metal oxides, J. Am. Chem. Soc., 1991,113:3189-3190;
99. Leroux F., Adachi-Pagano M., Intissar M., Charviere S., Forano C., Besse J. P., Delamination and restacking of layered double hydroxides, J. Mater., Chem., 2001,11:105-112;
100．李建宇．稀土发光材料及其应用，北京：化学工业出版社，2003．9；
101．易宪武．钪 稀土元素，无机化学丛书第七卷(第二版)，北京：科学出版社，1998．10；
102. Li Dan, Wang Xin, Xiong Gang, et al. A novel technique to prepare ultrafine Fe_2O_3 via hydrated iron (Ⅲ) nitrate, J. Mater. Sci. Lett., 1997,16:493-495;
103. Yang Juan, Li Dan, Wang Xin, et al. Synthesis and microstructural control of nanocrystalline titania powders via stearic acid method, Mater. Sci. & Engin. A, 2002,328:108-112;
104. Liu Xiaoheng, Yang Juan, Wang Ling, et al. An improvement on sol-gel method for preparing ultrafine and crystalline titania powder, Mater. Sci. & Engin. A, 2000, 289:241-245;
105．中山大学金属系编．稀土物理化学常数，冶金工业出版社(第一版)，1978；
106．褚明福，邹乐希，仲敬荣．拉曼和红外光谱在材料研究中的应用，稀有金属，2005，29：106-111
107. Byeon Song-ho, Lee Sung-ohk, and Kim Hongdoo, Structure and Raman spectra of layered titanium oxides, J. Solid State Chem., 1997,130:110-116;
108. Toda Kenji, Wtanabe Jun and Sato Mineo, Crystal structure determination of ion-exchangeable layered perovskite compound K_2La_2Ti_3O_(10) and Li_2La_2Ti_3O_(10), Mater. Res. Bull., 1996,31:1427-1435;
109．王智民，李丽，刘静波等．Li~+-Ca_xPb_(1-x)TiO_3湿敏纳米薄膜的激光拉曼光谱、晶格畸变和激光显微组织——应用“软模理论”解谱，化学学报，2005，63：81-85；
110．戴洪兴，何洪，李佩荇等．稀土钙钛矿型氧化物催化剂研究进展，吕国稀土学报，2003，21：1-15：
111．曲昭君，于春英，李文钊．掺杂钙钛矿型氧化物的固体结构及其可交换氧，物理化学学报，1994，10：796-801；
112．于洁，王华，马文全．复合掺杂钙钛矿氧化物催化剂的研究进展，昆明理工大学学报，2003，28：19-22
113．吴越．催化化学．北京：科学出版社，1998
114．陈笃慧，廖远琰，万惠霖．La_2O_3-BaO系复合氧化物的现场拉曼光谱研究，化学物理学报，1997，10：133-139
115．程传煊．表面物理化学，北京：科学技术文献出版社，1995．9
116．陈金富．固体物理学，北京：高等教育出版社，1986：
117．张光寅．晶格振动光谱学(第2版)，北京：高等教育出版社，2001
118. Milanova Maria M., Kakihana Masato, Arima Momoko, et al. A simple solution route to the synthesis of pure La_2Ti_2O_7 and Nd_2Ti_2O_7 at 700-800C by polymerized comples method, J. Alloys and Compouds, 1996,242:6-10;
119. Raymond E. S., Dawood Afzal, Joshua A. S. et al, Na_2Ln_2Ti_(3-x)Mn_xO_(10) (Ln=Sm, Eu, Gd, and Dy; 0≤x≤1):A new series of ion-exchangeable layered perovskites containing SB-site manganese, Chem. Mater., 2002,14:442-448;
120. LilianaViciu, Nicolas Liziard, Vlasimir Golub, et al. Transition-metal Dion-Jacobson layered pervskites M_(0.5)LaNb_2O_7, Mater. Res. Bull., 2004,39,2147-2154;
121. Jesus Canales-Vazuez, John T. S. Trvine, and Zhou Wuzong, Synthesis and characterization of n=5,6 members of the La_4Sr_(n-4)Ti_nO_(3n+2) series with layered structure based upon perovskite, J. Solid State Chem., 2004,177:2039-2043;
122. Liu F. S., Liu Q. L., Liang J. K., et al, A systematic study on crystal structure and magnetic properties of Ln_3GaO_6 (Ln=Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er), J. Solid State Chem., 2004,177:1796-1802;
123. Rabindra N. D., Pathak A., and Pramanik P., J Am, Ceram. Soc., 1998,81:3357
124. Asai T., Camargo E. R., Kakihana and Osada M., A novel aqueous solution route to the low-temperature synthesis of SrBi_2Nb_2O_9 by use of water-soluble Bi and Nb complexes, J. Alloys Compounds, 2000,309:113
125．甘树才，李红英，孟健，洪广言．溶胶-凝胶法合成稀土Z型铁氧体Ba_(3-x)La_xCo_2Fe_(24)O_(41)与表征，中国稀土学报，2004，22：751-754；
126. Yang Juan, Li Dan, Wang Xin, et al. Study on the synthesis and ion-exchange properties of layered titanate Na_2Ti_3O_7 powders with different sizes, J. Mater. Sci. 2003, 38:2907-2911;
127. Yang Juan, Li Dan, Wang Hengzhi, et al. Effect of particle size of staring material TiO_2 on morphology and properties of layered titanates, Mater. Lett., 2001,50:230-234;
128. Machida Masato, Yabunaka Jun-ichi, and Kijima Tsuyoshi, Synthesis and photocatalytic property of layered perovskite tantalates, RbLnTa_2O_7(Ln=La, Pr, Nd, and Sm), Chem. Mater., 2000,12,812-817;
129. Machida Masato, Yabunaka Jun-ichi, and Kijima Tsuyoshi, et al, Electronic structure of layered tantalates photocatalysts, RbLnTa_2O_7 (Ln=La, Pr, Nd, and Sm), Inter. J. Inorg. Mater., 2001,3:545-550;
130. Zhu Jun-jie, Wang Hui, Xu Shu, et al, Sonochemical method for the preparation of monodisperse spherical and rectangular lead selenide nanoparticles, Langmuir, 2002,18:3306-3310;
131．冯新．高质量低成本钛酸钾晶须的制备及其在复合材料中的应用，南京化工大学博士论文．2000；
132．谢凯，盘毅，王秀华．钛酸钾短纤维的制备工艺研究，无机盐工业，1997，1：16-17；
133. Zhu Huaiyong, Gao Xueping, Lan Ying, et al. Hydrogen titanata nanofibers cover with anatase nanocrystals: A delicate structure achieved by the wet chemistry reaction of the titanate nanofibers, J. Am. chem. Soc. 2004,126:8380-8381;
134. Nedeljkovic J. M., Micic O. I., Ahrenkiel S. P., et al. Growth of InP nanostructures via reaction of indium droplets with phosphide ions: Synthesis of InP quantum rods and InP-TiO_2 composites, J. Am. Sac., 2004,126:2632-2639;
135．曹忠良，王珍云．无机化学反应方程式手册，湖南：湖南科学出版社，1985，p260
136．武汉大学化学系等编著．稀土元素分析化学，北京：科学出版社，1983：
137. Izawa H., Kikkawa S. and Koizumi M., Ion exchange and dehydration of layered [sodium and potassium] titanates, Na_2Ti_3O_7 and K_2Ti_4O_9, J. Phys. Chem. 1982, 86: 5023-5026
138. Airold C., Nunes L. M. and Farias R. F., The intercalation of n-alkyldiamines into crystalline layered titanate, Mater. Res. Bull. 35(2000) 2081-2090
139. Takayoshi Sasaki, Mamoru Watanabe. Layered hydrous titanium dioxide: potassium ion exchange and structural characterization. Inorg. Chem. 1985(24):2265-2271;
140．中本一雄(日)．无机合配位化合物的红外和拉曼光谱(第四版)，北京：化学工业出版社，1991．2：
141．北京师范大学等编．无机化学(第三版)，高等教育出版社，1994
142．卫敏，谭娜，杨文胜等．层装钠锰氧化物的制备及离子交换反应动力学，应用化学，200320)5：437～442
143．傅献彩，沈文霞，姚天杨．物理化学(第四版)，北京：高等教育出版社，1990
144．华中师范大学等编．分析化学(第二版)，北京：高等教育出版社，1990；
145. Kwon O Y, Jeong S Y, Seo J K, Effect of organic solvents in the intercalation of octylamine into H-magadiite, J. Collid and Interface Sic., 1996,177:887-896
146．陈新，王海，侯文华等．新型中孔氧化硅柱层状锰钛酸的合成，无机化学学报，2002，18(6)：550-553；
147. Kooli F., Sasaki T., Mizukami F. et al. Characterization and acid properties of silica pillared titanates, J. Mater. Chem., 2001,11:841-845;
148．侯文华，徐林，颜其洁，陈静．具有超大通道结构的介孔氧化硅层状钛酸的合成和催化应用初探，无机化学学报，2002，18(7)：744；
149．李瑛，钟家圣．纳米TiO_2气相光催化氧化苯胺的研究(Ⅰ)，武汉大学学报，2005，51：145-148：
150．冷文华，童少平，成少安等．附载型二氧化钛光电催化降解苯胺机理，环境科学学报，2002，20(6)：781-786：
151．冷文华，成少安，刘洪等，负载型二氧化钛光催化降解苯胺，环境科学学报，2000，20：499-503：
152．李涛海，吴季怀，林建明等．酸化对层状K_2La_2Ti_3O_(10)活性的影响，感光科学与光化学，2004，22(2)120-125：
153．侯文华，汪学广，颜其洁等．具有不同层间距、比表面和孔径大小的氧化硅柱层状铌酸盐的制备，高等学校化学学报，1999，20(11)：1793；
154．朱建喜，何宏平，杨丹等．柱撑蒙脱石及其产物热处理孔性研究，无机材料学报，2004，19(2)324-328
155. Cheng S F, Wang T C. Pillaring of layered titanates by polyoxo cations of aluminum, Inorg Chem. 1989, 18(7): 1283-1289.
156．陈亚芍，侯文华，颜其洁．氧化铝柱层状镧钛酸盐的制备，无机化学学报，1995，11(4)：399：
157. Yin Shu, Sato Tsugio, Photocalatic activity of platinum loaded fibrous titania prepared by solvothermal process, J. Photochem. & Photobio. A: Chem., 2005,196:89-94;
158. Paola A. D., Garcia-Lopez E., Ikeda S., et al. Photocatalytic degradation of organic compounds in aqueous system by transition metal doped polycrystalline TiO_2, Cata. Today, 2002,75:87-93;
159. Hwang D. W., Kim H. G., Jang J. S., et al, Photocatalytic decomposition of water-methanol solution over metal-deped layered perovskite under visible light irradiation, Cata. Today, 2004,93-95:845-850;
160. Zhao Xueguo, Shi Jianlin, Hu Bin, et al, In stiu formation of silver nanoparticles inside pore channels of ordered mesoporous silica, Mater. Lett., 2004,58:2152-2156;
161. Kudo A., Sayama K., Tanaka A., et al, Nickel-loade K_4Nb_6O_(17) Photocatalyst in the decomposition of H_2O into H_2 and O_2: structure and reaction mechanism, J. Cata., 1989,120:337-352;
162. Kudo A., Tanaka A., Domen K.,, et al, Photocatalytic decomposition of water over NiOK_4Nb_6O_(17) catalyst, J. Cata., 1988,111:67-76;
163. Inoue Yasunobu, Kubokawa Toyoyuki, and Sato Kazunori, Photocatalytic activity of akli-metal titanates combined with Ru in the decomposition of water, J. Phys. Chem., 1991,95:4059-4063;
164. Wu Jihuai, Lin Jianming. Synthesis and photocatalytic properties of layered HNbWO_6/ (Pt,Cd_(0.8)Zn_(0.2)S) nanocomposites. J. Mater. Chem. 2001(11):3343-3347
165. Hwang Dong Won, Kin Hyun Gyu, Kim Jindo, et al, Photocalatic water spiltting over highly donor-doped (110) layered perovskites, J. Cata., 2000,193:43-48;
166．吴树新，马智，秦永宁等．掺杂纳米TiO_2光催化性能研究，物理化学学报，2004，20：138-143
167．刘守新，曲振平，韩秀文等．Ag担载对TiO_2光催化活性的影响，催化学报，2004，25：133-137；
168. Sadeghi M., Liu W., Zhang T-G, et al, Role of Photoinduced Charge Carrier Separation Distance in Heterogeneous Photocatalysis: Oxidative Degradation of CH_3OH Vapor in Contact with Pt/TiO_2 and Cofumed TiO_2-Fe_2O_3, J. Phys. Chem., 1996,100(50):19466;
169. Izumi I., Dunn W. W., Wilboum K. O., et al, Heterogeneous photocatalytic oxidation of hydrocarbons on platinized titanium dioxide powders, J. Phys. Chem., 1980,84(24):3207;
170．顾庆超，楼书聪，戴庆平等编．化学用表，南京：江苏教育出版社，1979，P9；
171．姚允斌，解涛，高英敏．物理化学手册，上海：上海科学技术出版社，1985，P838；
172. Schetz Peter and Caruso Frank, Semiconductor and metal nanoparticle formation on polymer spheres coated with week pilyelectrolyte multilayers, Chem. Mater., 2004,16:3066-3073;
173. Lee Daeyeon, Rubner Michael F., Cohen Robert E., Formation of nanoparticle-loaded microcapsules based on hydrogen-bonded multilayers, Chem. Mater., 2005,17:1099-1105;
174. Djerdiev Ales M., Beattie Janes K., O'brien Richard W., Coating of silica on titania pigment particles examined by electroacoustics and dielectric response, Chem. Mater., 2005,17:3844-3849;
175. Ruxandra Vidu, Pieter Stroeve, Improvement of the thermal stability of Li-ion batteries by polymer coating of LiMn_2O_4, Inter. Eng. Chem. Res., 2004,43:3314-3324;
176. Wang Zhongchun, Medforth Craig J., Schelnutt John A., Self-metallization of photocztalytic porphyrin nanotubes, J. Am. Chem. Soc., 2004,126:16720-16721;
177. Liu Mingzhao, Philippe Guyot-Sionnest, Synthesis and optical characterization of Au/Ag core/shell nanorods, J. Phys. Chem. B, 2004,108:5882-5888;
178. Santra Swadeshmukul, Tapec Rovelyn, Theodorpoulou Nikoleta, et al, Synthesis and characterization of silica-coated iron oxide nanoparticles in microemilsion: the effect of nonionic surfacents, Langmuir, 2001,17:2900-2906;
179. Drew Christopher, Liu Xin, Ziegler David, et al, Metal oxide-coated polymer nanofibers, Nano Letters, 2003,3:143-147;
180. Zeng Hao, Li Jing, Wang Z. L., et al, Bimagnetic core. shell FePt/Fe_3O_4 nanoparticles, Nano Letters, 2004,4:187-190;
181．颜秀茹，白天，霍明亮等．核-壳式纳米SnO_2-TiO_2光催化剂的制备和性能，催化学报，2004，25：120-124；
182．夏海龙，唐芳琼．SiO_2／ZnO复合纳米粒子的制备及表征，无机化学学报，2002，18：769-772；
183．张敬畅，高玲玲，曹维良．纳米TiO_2-SiO_2复合光催化剂的超临界流体干燥法制备及其光催化性能研究，无机化学学报，2003，19：934-939；
184．关凯书，尹衍升，姜秋鹏．TiO_2-SiO_2复合薄膜光催化活性与亲水性关系研究，硅酸盐学报，2003，31：219-228；
185．王宝祥，左朝阳，赵晓鹏．包覆型高岭土／二氧化钛纳米复合颗粒的电流变效应，无机材料学报，2004，19：492-496；
186. Politer P., Lane P., Energetics of ammonium perchlorate decomposition steps, J. Molecular Structure (Theochem), 1998,454:229-235;
187. Brill T. B., Brush P. J., Patil D. G., Thermal decomposition of energetic materials 60 major reaction stages of simulated burning surface of NH_4ClO_4, Combustion and Flame, 1993,94:70-76;
188. Singh G., Kapoor I. P. S., Mannan S. M., et al, Stusies on energetic compounds part 8: thermolysis of salts of HNO_3 and HClO_4, J. Hazardous Mater. A, 2000,79:1-19;
189．任务正，王泽山主编．火炸药理论与实践(第一版)，北京：中国北方化学工业总公司出版，2001；
190．刘子如，阴翠梅，孔扬辉等．高氯酸铵的热分解，含能材料，2000，8(2)：75-79；
191．罗元香．火炸药用纳米催化剂的制备及性能研究，南京理工大学博士论文，2004；
192．韩建成等著．多晶X射线结构分析，上海：华东师范大学出版社，1987；
193．刘粤惠，刘平安．X射线衍射分析原理与应用，北京：化学工业出版社，2003．10；
194. Cumming A. S, Leiper G A, Robson E. Molecular Modeling as a Tool to Aid the Design of Polymer Bonded Explosives. 24th International Annual Conference of ICT, Karlsruhe, Germany: 1993.
195．Jiang Zhenyi，Xu Xiaohong，Wu Haishun，Zhang Fuqiang，Jin Zhihao，Ad initio calculation of SiC pilytyoes。创腾科技第二届中国用户学术研讨会论文集(材料科学篇)，2002．5：71-75；
196．孟醒，徐小光，刘伟，孙源，陈岗．钙钛矿型HoNiO_3中电荷岐化的第一性原理研究，物理学报，2004，53(11)：3873-3876；
197. Zhou Danhong. Study with density functional theory method on methane dehydro-aromatization over Mo/HZSM-5 catalyst Ⅰ: optimization of active Mo species bonded to ZSM-5 zeolite, Journal of Chemical Physics, 2001, 114(20):9125-9129;
198. Lin Zheshuai. Mechanism for linear and nonolinear optical effects in monoclinic bismuth borate (BiB_3O_6) crystal, Journal of applied physics, 2001, 90(11): 5587-5590;
199. Zhou Y. C., Wang X. H., Sun Z. M., Chen S. Q. Electronic and structural properties of the layered ternary carbide Ti_3AlC_2, J. Mater. Chem., 2001,11,2335,2339
200. ZhouYanchun, Sun Zhimei, Wang Xiaohui and Chen Shengqi, Ab initio geometry optimization and ground state properties of layered ternary carbides Ti_3MC_2 (M=Al, Si, Ge), Journal of Physics Condensed Matter, 2001,13:10001-10010;
201．赵成大．固体量子化学——材料化学的理论基础，北京：高等教育出版社，1997；
202．吕世骥，范印哲．固体物理教程(第一版)，北京：北京大学出版社，1990。