银锌渣制备超细氧化铋及其基础理论研究
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摘要
我国铋资源相当丰富,铋储量和产量均居世界第一位,但铋工业落后,尤其是铋深加工产品市场竞争力仍然较低。为将我国铋资源优势转化成产业优势,本文以某公司富含铋、锌、金、银的银锌渣为原料,提取并综合回收了其中有价金属,研究了银锌渣浸出液化学沉淀法制备高纯超细氧化铋的工艺,并在制备过程中控制粉体粒径,同时还探索了水热法制备超细氧化铋工艺。
采用HCl+NaClO_3+NaCl体系浸出银锌渣,考察了浸出温度、浸出时间、液固比以及浸出液中各成分用量对铋浸出率的影响。浸出的适宜条件为液固比10:1,NaClO_3用量15g,NaCl用量60g,浓盐酸用量120mL,浸出温度80℃,浸出时间5h。在此条件下Bi的浸出率接近100%。为了还原浸出液中的少量银,可用新的银锌渣还原浸出液。在上述条件下浸出银锌渣,渣率为12%-16%,渣中银含量可达70%左右,金含量为1%。采用氨水浸银,水合肼还原制取海绵银,浸银渣再用氯酸钠加硫酸浸金,适宜条件下银、金的回收率均可达95%左右。
从各金属的Me-Cl~--H_2O体系热力学计算,得到了Me-Cl~--H_2O系E-pH图,由此可以得出,对铋而言,控制溶液电位在0-1.4V的较宽范围内,当体系酸度较高(pH＜3)时,BiOCl将溶解;pH=3-11时,BiOCl有相当大的稳定区域。对于Ag和As,只要控制电位在一定范围内,pH值从-2到12范围内Ag和As均以离子形式存在,但Cl~-浓度太高,则Ag会以AgCl形式沉淀。对于Pb,在pH＜6,E＜1.4V的整个区域内,Pb均以PbCl_2形式存在,PbO_2~-的溶解要求很高的碱液浓度,在实践中难以实现。对于Fe,在没有氧化剂存在时,只要体系E＜0.6V,Fe以Fe~(2+)形式存在,当pH＞6时才发生水解沉淀。当E为0.6-1.3V,控制pH＜1.4时,Fe可呈Fe~(3+)形式从水解液中排出。对于Sb,当体系E＜0.8V,HCl浓度较高时,Sb呈SbCl_3形式存在,随着pH值升高,生成Sb(OH)_3,甚至生成Sb_2O_4,均为固相。
提出银锌渣浸出液制备高纯三氧化二铋的工艺路线为“净化—水解—转化”。浸出液的净化工序为首先采用银锌渣除铅,控制初始pH值为0.3-0.4,银锌渣用量为100g/L,还原时间为15min,可使Pb降到3-10mg/L,过滤后在滤液中加少许NaI进一步除Ag,使Ag降到1mg/L左右后过滤得到净化后液。净化后浸出液水解制取BiOCl的适宜条件为体积比为8-10:1,中和剂为40%Na_2CO_3溶液或稀氨水,水解pH值为0.8,水解时间为20-30分钟。所得BiOCl用1 mol/L H_2SO_4溶液洗涤,再用蒸馏水或去离子水洗涤除Fe、Zn、Cu等杂质。BiOCl浓碱转化法制备三氧化二铋的适宜条件为液固比5:1,碱液浓度4mol/L,转化温度95℃,反应时间1h。所得Bi_2O_3用1mol/L NaOH溶液洗涤,再用去离子水洗涤,除去SO_4~(2-)和Cl~-等杂质离子,烘干即可得到高纯Bi_2O_3产品,在该条件下制备得到外形为四面体形或纺锤形的α-Bi_2O_3产品,产品粒径约为20μm,杂质含量很低,达到高纯三氧化二铋要求。Cu、As、Sb、Si含量都在十万分之几,Ag、Pb、Zn、Fe等金属杂质的含量都只有百万分之几。
以上述方法得到的高纯粗颗粒氧化铋为原料,采用硝酸溶解,然后用氨水作沉淀剂,用化学沉淀法通过反滴加方式制备得到超细三氧化二铋粉体,其适宜工艺条件为硝酸铋浓度0.3mol/L,滴加速度2.5mL/min,氨水浓度1:10(体积比),终点pH值9,搅拌速度600r/min。该条件下称取500g氧化铋进行放大实验,反应结束后过滤洗涤,在105℃干燥2h得到前驱体粉末,在马弗炉中于600℃下保温2h得到球状Bi_2O_3,计算表明其晶粒尺寸为28.6nm,SEM结果表明颗粒呈球形,颗粒大小比较均匀,平均粒径约为0.2μm。产品外观为橙黄色,色泽鲜艳,存在较为严重的团聚现象。
从理论和实验上对氧化铋粉体的粒径进行了分析和控制,在成核初期采取变速滴加的方式可以产生爆发性形核,将形核过程控制在较短的时间内,实现形核和长大过程的分离,可获得较细的一次粒子。加入表面活性剂聚乙烯醇-124、油酸钠及十二烷基苯磺酸钠均可抑制颗粒团聚现象,其合适的用量分别为4×10~(-3)mol/L、0.8×10~(-3)mol/L、6g/L,该条件下分别加入三种表面活性剂,均可得到粒度分布较窄、分散性好的粒子,平均粒径分别约为0.05μm、0.07μm、0.123μm。聚乙烯醇分散剂控制团聚的作用机理为空间位阻作用,油酸钠和十二烷基磺酸钠控制团聚的机理为双电层(静电)稳定作用。分析了前驱体粉末干燥过程中产生团聚的原因,通过乙醇洗涤或正丁醇共沸蒸馏可有效地脱除湿粉末中残余水分子,阻止干燥过程中团聚的发生,获得了分散性较好、平均粒径分别为0.118μm和0.116μm的超细氧化铋粒子。
分析和探索了水热法制备超细氧化铋粉体理论及工艺,研究了反应温度、时间、溶液填充度、溶液pH值以及反应介质种类等因素对晶体粒度和形貌的影响。温度越高,平均粒度越大,粒度分布越宽;反应时间较长,晶粒较粗,平均粒径较大;晶粒平均粒径随着溶液填充度的增大而减小;随着pH值增大,晶粒粒径变小;反应介质对晶粒尺寸的影响并不明显。水热法制备Bi_2O_3的适宜条件为反应温度为120℃,时间为2h,填充度为90%,溶液pH值为大于11。在适宜条件下所得Bi_2O_3的平均粒径大约为80nm,同时还发现改变反应体系pH值和反应介质可得到不同形貌和晶型的产品。
Our country is in rich of bismuth resources of which the reserves and yields are in the first rank in the world.However,our country falls behind in the bismuth industry,and particularly the market competitiveness of deep-processing bismuth products is very weak.This work aims to transform this resource advantage to industrial advantage.The valuable metals of the raw material of silver-zinc slag containing substantial bismuth,zinc,gold and silver were extracted firstly,then the technology of preparing superfine bismuth oxide powder with high purity using chemical precipitation method was studied,as well as the technology of that with hydro-thermal method was explored.The key target of this paper is to control the particle size during the whole process.
The solution containing HCl,NaClO_3 and NaCl was used to leach silver-zinc slag and the influences of liquid-to-solid ratio and the component dosage of leachate on the leaching rate of bismuth were investigated.The appropriate conditions of leaching silver-zinc slag are that the liquid-to-solid ratio is 10:1,the NaClO_3 quality is 15g,the NaCl quality is 60g,the HCl volume is 120mL,the extraction temperature is 80℃and the extraction time is 5h.The leaching rate of bismuth is 100% approximately,the slag yield is 12%-16%,the content of silver and gold of leaching residue reach 70%and 1%under these conditions.The silver was further extracted with hydrazine hydrate by reducing the residue that was leached by ammonia solution,and the gold was further extracted with NaClO_3 and H_2SO_4 solution from that leaching solution.The recovery rate of silver and gold gets up to 95%at right conditions.
The Eh-pH diagrams of Me-Cl~--H_2O system were drawn based on thermodynamic equations of that system.For Bi-Cl~--H_2O system,if the solution potential(Eh) is in 0-1.4V,BiOCl will be dissolved when the acidity of solution is high(pH＜3) and be stable when pH =3-11.For Ag-Cl~--H_2O and As-Cl~--H_2O system,as long as Eh is controlled at a certain range,arsenic and silver exist in form of ion when pH value varies from -2 to 12,while if Cl~- concentration is too high,Ag will precipitate in form of AgCl.For Pb-Cl~--H_2O system,Pb exists in the form of PbCl_2 at the region of pH＜6 and Eh＜1.4V,it's difficult for PbO2~- to dissolve because of the rigid demand of alkali concentration.For Fe-Cl~--H_2O system,Fe exists in the form of Fe~(2+) as long as Eh＜0.6V and there is no oxidizer,hydrolysis precipitation happens when pH＞6,and Fe can be removed in the form of Fe~(3+) when Eh is 0.6-1.3V and pH＜1.4.For Sb-Cl~--H_2O system,Sb exists in the form of SbCl_3 when Eh＜0.8V and HCl concentration is high,but solid Sb(OH)_3 and Sb_2O_4 form with the increase of pH value.
The process route of the preparing high-pure bismuth oxide using chemical precipitation method with the leachate from silver-zinc slag was put forward.It is "purification-hydrolysis- transformation".The purification process is that the Pb is firstly removed to 3-10mg/L by silver-zinc slag under the conditions of pH value of 0.3-0.4,slag dosage of 100g/L and reaction time of 15min,and Ag is then removed to 1mg/L by a little NaI.The appropriate conditions of preparing BiOCl with purified solution using hydrolysis method are that liquid-to-solid ratio is 8-10:1,neutralizer is 40%Na_2CO_3 solution or dilute ammonia,pH value is 0.8 and the hydrolysis time is 20-30 min.The impurities of Fe,Zn,Cu and other impurities are removed by washing the BiOCl solid using 1 mol/L H_2SO_4 and deionized water.The appropriate conditions of preparing bismuth trioxide with BiOCl are that the liquid-to-solid ratio is 5:1,the alkali concentration is 4mol/L,the reaction temperature is 95℃and the reaction time is 1h.The impurities of SO_4~(2-) and Cl~- ions are removed by washing Bi_2O_3 solid using 1mol/L NaOH solution and deionized water.The product ofα-Bi_2O_3 with diamond shape and particle size of about 20μm is obtained at these conditions above.The content of Cu,As,Sb,Fe,Si of the product is a few parts in 100,000 and that of Ag,Pb,Zn,Fe is only a few ppm,which fulfils the requirement of high-purity bismuth trioxide.
Superfine bismuth trioxide powder was prepared using chemical precipitation method by adding ammonia into Bi(NO_3)_3 solution that was prepared by HNO_3 and the coarse high-pure bismuth oxide obtained above.The appropriate conditions are that the Bi(NO_3)_3 concentration is 0.3mol/L,the feeding speed is 2.5mL/min,the ammonia concentration is 1:10(volume ratio),the end pH value is 9 and the stirring rate is 600r/min.The preparation experiment in scale-up was carried out with 500g bismuth oxide at these conditions.The precursor powder of Bi(OH) _3 is gained by drying the filter cake for 2h at 105℃.The spherical Bi_2O_3 is gained by roasting the precursor powder for 2h at 600℃.Its grain size is 28.6nm according to the calculation.SEM results show that the particles are spherical with the average size of about 0.2μm.The product has a bright orange color.The particles agglomerate seriously in the product.
The particle size of bismuth oxide powder was analyzed and controlled from the aspects of theory and experiment.In the early nucleation period,the explosive nucleation occurs by feeding at varying rate.The nucleation process is controlled in a relatively short time,and a smaller particle is achieved by separating the process of nucleation and growth.The surfactant of PVA-124,sodium oleate and sodium dodecyl benzene sulfonate can inhibit agglomeration of particles,the appropriate dosage is 4×10~(-3)mol/L,0.8×10~(-3)mol/L and 6g/L respectively.The particle with narrower size and high dispersion ability can be obtained and its average particle size is 0.05μm,0.07μm and 0.123μm,respectively.The effect mechanism of polyvinyl alcohol on the agglomeration of particle is the steric clash function,and the effect mechanism of sodium oleate and sodium dodecyl sulfate is the dual-layer(static) stability function.The possible reason of agglomeration phenomena during the drying process was analyzed.It was found that the residues of water of wet powder can be removed and the reunion phenomena can be restrained by washing the powder with ethanol or azeotropic distillating with n-butanol.The particle with high dispersion ability is obtained under these operations and its average particle size is 0.118μm and 0.116μm respectively.
The theory and technology of preparing superfine bismuth trioxide using hydro-thermal method were explored.The influences of reaction temperature,reaction time,filling degree,pH value,as well as such factors as the type of reaction medium on the crystal size and microstructure were investigated.The higher the temperature,the greater the average particle size,the wider the particle size is.The longer the reaction time,the coarser the grain,the larger average particle size is.The particle size decreases with the increase of pH value.The impact of reaction medium on grain size is not obvious.The appropriate conditions of preparing Bi_2O_3 with hydro-thermal method are that the reaction temperature is 120℃,the reaction time is 2h,filling degrees is 90%,the pH value is≥11.The average particle size obtained under these conditions is about 80nm.Meanwhile it was also found that the product with different microstructure and crystal can be obtained with the alteration of pH value and reaction medium.
采用HCl+NaClO_3+NaCl体系浸出银锌渣,考察了浸出温度、浸出时间、液固比以及浸出液中各成分用量对铋浸出率的影响。浸出的适宜条件为液固比10:1,NaClO_3用量15g,NaCl用量60g,浓盐酸用量120mL,浸出温度80℃,浸出时间5h。在此条件下Bi的浸出率接近100%。为了还原浸出液中的少量银,可用新的银锌渣还原浸出液。在上述条件下浸出银锌渣,渣率为12%-16%,渣中银含量可达70%左右,金含量为1%。采用氨水浸银,水合肼还原制取海绵银,浸银渣再用氯酸钠加硫酸浸金,适宜条件下银、金的回收率均可达95%左右。
从各金属的Me-Cl~--H_2O体系热力学计算,得到了Me-Cl~--H_2O系E-pH图,由此可以得出,对铋而言,控制溶液电位在0-1.4V的较宽范围内,当体系酸度较高(pH＜3)时,BiOCl将溶解;pH=3-11时,BiOCl有相当大的稳定区域。对于Ag和As,只要控制电位在一定范围内,pH值从-2到12范围内Ag和As均以离子形式存在,但Cl~-浓度太高,则Ag会以AgCl形式沉淀。对于Pb,在pH＜6,E＜1.4V的整个区域内,Pb均以PbCl_2形式存在,PbO_2~-的溶解要求很高的碱液浓度,在实践中难以实现。对于Fe,在没有氧化剂存在时,只要体系E＜0.6V,Fe以Fe~(2+)形式存在,当pH＞6时才发生水解沉淀。当E为0.6-1.3V,控制pH＜1.4时,Fe可呈Fe~(3+)形式从水解液中排出。对于Sb,当体系E＜0.8V,HCl浓度较高时,Sb呈SbCl_3形式存在,随着pH值升高,生成Sb(OH)_3,甚至生成Sb_2O_4,均为固相。
提出银锌渣浸出液制备高纯三氧化二铋的工艺路线为“净化—水解—转化”。浸出液的净化工序为首先采用银锌渣除铅,控制初始pH值为0.3-0.4,银锌渣用量为100g/L,还原时间为15min,可使Pb降到3-10mg/L,过滤后在滤液中加少许NaI进一步除Ag,使Ag降到1mg/L左右后过滤得到净化后液。净化后浸出液水解制取BiOCl的适宜条件为体积比为8-10:1,中和剂为40%Na_2CO_3溶液或稀氨水,水解pH值为0.8,水解时间为20-30分钟。所得BiOCl用1 mol/L H_2SO_4溶液洗涤,再用蒸馏水或去离子水洗涤除Fe、Zn、Cu等杂质。BiOCl浓碱转化法制备三氧化二铋的适宜条件为液固比5:1,碱液浓度4mol/L,转化温度95℃,反应时间1h。所得Bi_2O_3用1mol/L NaOH溶液洗涤,再用去离子水洗涤,除去SO_4~(2-)和Cl~-等杂质离子,烘干即可得到高纯Bi_2O_3产品,在该条件下制备得到外形为四面体形或纺锤形的α-Bi_2O_3产品,产品粒径约为20μm,杂质含量很低,达到高纯三氧化二铋要求。Cu、As、Sb、Si含量都在十万分之几,Ag、Pb、Zn、Fe等金属杂质的含量都只有百万分之几。
以上述方法得到的高纯粗颗粒氧化铋为原料,采用硝酸溶解,然后用氨水作沉淀剂,用化学沉淀法通过反滴加方式制备得到超细三氧化二铋粉体,其适宜工艺条件为硝酸铋浓度0.3mol/L,滴加速度2.5mL/min,氨水浓度1:10(体积比),终点pH值9,搅拌速度600r/min。该条件下称取500g氧化铋进行放大实验,反应结束后过滤洗涤,在105℃干燥2h得到前驱体粉末,在马弗炉中于600℃下保温2h得到球状Bi_2O_3,计算表明其晶粒尺寸为28.6nm,SEM结果表明颗粒呈球形,颗粒大小比较均匀,平均粒径约为0.2μm。产品外观为橙黄色,色泽鲜艳,存在较为严重的团聚现象。
从理论和实验上对氧化铋粉体的粒径进行了分析和控制,在成核初期采取变速滴加的方式可以产生爆发性形核,将形核过程控制在较短的时间内,实现形核和长大过程的分离,可获得较细的一次粒子。加入表面活性剂聚乙烯醇-124、油酸钠及十二烷基苯磺酸钠均可抑制颗粒团聚现象,其合适的用量分别为4×10~(-3)mol/L、0.8×10~(-3)mol/L、6g/L,该条件下分别加入三种表面活性剂,均可得到粒度分布较窄、分散性好的粒子,平均粒径分别约为0.05μm、0.07μm、0.123μm。聚乙烯醇分散剂控制团聚的作用机理为空间位阻作用,油酸钠和十二烷基磺酸钠控制团聚的机理为双电层(静电)稳定作用。分析了前驱体粉末干燥过程中产生团聚的原因,通过乙醇洗涤或正丁醇共沸蒸馏可有效地脱除湿粉末中残余水分子,阻止干燥过程中团聚的发生,获得了分散性较好、平均粒径分别为0.118μm和0.116μm的超细氧化铋粒子。
分析和探索了水热法制备超细氧化铋粉体理论及工艺,研究了反应温度、时间、溶液填充度、溶液pH值以及反应介质种类等因素对晶体粒度和形貌的影响。温度越高,平均粒度越大,粒度分布越宽;反应时间较长,晶粒较粗,平均粒径较大;晶粒平均粒径随着溶液填充度的增大而减小;随着pH值增大,晶粒粒径变小;反应介质对晶粒尺寸的影响并不明显。水热法制备Bi_2O_3的适宜条件为反应温度为120℃,时间为2h,填充度为90%,溶液pH值为大于11。在适宜条件下所得Bi_2O_3的平均粒径大约为80nm,同时还发现改变反应体系pH值和反应介质可得到不同形貌和晶型的产品。
Our country is in rich of bismuth resources of which the reserves and yields are in the first rank in the world.However,our country falls behind in the bismuth industry,and particularly the market competitiveness of deep-processing bismuth products is very weak.This work aims to transform this resource advantage to industrial advantage.The valuable metals of the raw material of silver-zinc slag containing substantial bismuth,zinc,gold and silver were extracted firstly,then the technology of preparing superfine bismuth oxide powder with high purity using chemical precipitation method was studied,as well as the technology of that with hydro-thermal method was explored.The key target of this paper is to control the particle size during the whole process.
The solution containing HCl,NaClO_3 and NaCl was used to leach silver-zinc slag and the influences of liquid-to-solid ratio and the component dosage of leachate on the leaching rate of bismuth were investigated.The appropriate conditions of leaching silver-zinc slag are that the liquid-to-solid ratio is 10:1,the NaClO_3 quality is 15g,the NaCl quality is 60g,the HCl volume is 120mL,the extraction temperature is 80℃and the extraction time is 5h.The leaching rate of bismuth is 100% approximately,the slag yield is 12%-16%,the content of silver and gold of leaching residue reach 70%and 1%under these conditions.The silver was further extracted with hydrazine hydrate by reducing the residue that was leached by ammonia solution,and the gold was further extracted with NaClO_3 and H_2SO_4 solution from that leaching solution.The recovery rate of silver and gold gets up to 95%at right conditions.
The Eh-pH diagrams of Me-Cl~--H_2O system were drawn based on thermodynamic equations of that system.For Bi-Cl~--H_2O system,if the solution potential(Eh) is in 0-1.4V,BiOCl will be dissolved when the acidity of solution is high(pH＜3) and be stable when pH =3-11.For Ag-Cl~--H_2O and As-Cl~--H_2O system,as long as Eh is controlled at a certain range,arsenic and silver exist in form of ion when pH value varies from -2 to 12,while if Cl~- concentration is too high,Ag will precipitate in form of AgCl.For Pb-Cl~--H_2O system,Pb exists in the form of PbCl_2 at the region of pH＜6 and Eh＜1.4V,it's difficult for PbO2~- to dissolve because of the rigid demand of alkali concentration.For Fe-Cl~--H_2O system,Fe exists in the form of Fe~(2+) as long as Eh＜0.6V and there is no oxidizer,hydrolysis precipitation happens when pH＞6,and Fe can be removed in the form of Fe~(3+) when Eh is 0.6-1.3V and pH＜1.4.For Sb-Cl~--H_2O system,Sb exists in the form of SbCl_3 when Eh＜0.8V and HCl concentration is high,but solid Sb(OH)_3 and Sb_2O_4 form with the increase of pH value.
The process route of the preparing high-pure bismuth oxide using chemical precipitation method with the leachate from silver-zinc slag was put forward.It is "purification-hydrolysis- transformation".The purification process is that the Pb is firstly removed to 3-10mg/L by silver-zinc slag under the conditions of pH value of 0.3-0.4,slag dosage of 100g/L and reaction time of 15min,and Ag is then removed to 1mg/L by a little NaI.The appropriate conditions of preparing BiOCl with purified solution using hydrolysis method are that liquid-to-solid ratio is 8-10:1,neutralizer is 40%Na_2CO_3 solution or dilute ammonia,pH value is 0.8 and the hydrolysis time is 20-30 min.The impurities of Fe,Zn,Cu and other impurities are removed by washing the BiOCl solid using 1 mol/L H_2SO_4 and deionized water.The appropriate conditions of preparing bismuth trioxide with BiOCl are that the liquid-to-solid ratio is 5:1,the alkali concentration is 4mol/L,the reaction temperature is 95℃and the reaction time is 1h.The impurities of SO_4~(2-) and Cl~- ions are removed by washing Bi_2O_3 solid using 1mol/L NaOH solution and deionized water.The product ofα-Bi_2O_3 with diamond shape and particle size of about 20μm is obtained at these conditions above.The content of Cu,As,Sb,Fe,Si of the product is a few parts in 100,000 and that of Ag,Pb,Zn,Fe is only a few ppm,which fulfils the requirement of high-purity bismuth trioxide.
Superfine bismuth trioxide powder was prepared using chemical precipitation method by adding ammonia into Bi(NO_3)_3 solution that was prepared by HNO_3 and the coarse high-pure bismuth oxide obtained above.The appropriate conditions are that the Bi(NO_3)_3 concentration is 0.3mol/L,the feeding speed is 2.5mL/min,the ammonia concentration is 1:10(volume ratio),the end pH value is 9 and the stirring rate is 600r/min.The preparation experiment in scale-up was carried out with 500g bismuth oxide at these conditions.The precursor powder of Bi(OH) _3 is gained by drying the filter cake for 2h at 105℃.The spherical Bi_2O_3 is gained by roasting the precursor powder for 2h at 600℃.Its grain size is 28.6nm according to the calculation.SEM results show that the particles are spherical with the average size of about 0.2μm.The product has a bright orange color.The particles agglomerate seriously in the product.
The particle size of bismuth oxide powder was analyzed and controlled from the aspects of theory and experiment.In the early nucleation period,the explosive nucleation occurs by feeding at varying rate.The nucleation process is controlled in a relatively short time,and a smaller particle is achieved by separating the process of nucleation and growth.The surfactant of PVA-124,sodium oleate and sodium dodecyl benzene sulfonate can inhibit agglomeration of particles,the appropriate dosage is 4×10~(-3)mol/L,0.8×10~(-3)mol/L and 6g/L respectively.The particle with narrower size and high dispersion ability can be obtained and its average particle size is 0.05μm,0.07μm and 0.123μm,respectively.The effect mechanism of polyvinyl alcohol on the agglomeration of particle is the steric clash function,and the effect mechanism of sodium oleate and sodium dodecyl sulfate is the dual-layer(static) stability function.The possible reason of agglomeration phenomena during the drying process was analyzed.It was found that the residues of water of wet powder can be removed and the reunion phenomena can be restrained by washing the powder with ethanol or azeotropic distillating with n-butanol.The particle with high dispersion ability is obtained under these operations and its average particle size is 0.118μm and 0.116μm respectively.
The theory and technology of preparing superfine bismuth trioxide using hydro-thermal method were explored.The influences of reaction temperature,reaction time,filling degree,pH value,as well as such factors as the type of reaction medium on the crystal size and microstructure were investigated.The higher the temperature,the greater the average particle size,the wider the particle size is.The longer the reaction time,the coarser the grain,the larger average particle size is.The particle size decreases with the increase of pH value.The impact of reaction medium on grain size is not obvious.The appropriate conditions of preparing Bi_2O_3 with hydro-thermal method are that the reaction temperature is 120℃,the reaction time is 2h,filling degrees is 90%,the pH value is≥11.The average particle size obtained under these conditions is about 80nm.Meanwhile it was also found that the product with different microstructure and crystal can be obtained with the alteration of pH value and reaction medium.
引文
[1]汪立果.铋冶金[M].北京:冶金工业出版社,1986
[2]中南矿冶学院,重金属冶金学(下册)[M],北京:中国工业出版社,1961
[3]化学工业部编.无机盐工业手册[M].北京:化学工业出版社,1990
[4]刘承科主编.大学化学-元素化学[M].长沙:中南工业大学出版社,1994
[5]武汉大学等编.无机化学(下)[M].北京:高等教育出版社,1991
[6]Lam L T,High N P,Lim O V,et al.Power Sources[J],1998,73:36
[7]Lam L T,High N P,Lim O V,et al.Power Sources[J],1999,78:139
[8]秦毅红,王云燕,彭文杰.铋深加工产品的应用及其发展前景[J],世界有色金属,1998年第4期:44-45
[9]刘艳.碱性电池无汞化的实现途径[J],重庆工业高等专科学校学报,2002,17(3):26
[10]冶金译丛编辑委员会,超纯金属与半导体材料(2)[M],上海市科学技术编译馆.1965
[11]简爱珠,张亚平.无汞锌粉中铋含量的测定[J],电池,2002,32(5):308-309
[12]张进孝,曹瑜强.Bi、Cu对大断而可锻铸铁的影响[J],铸造技术,2002,23(2):94
[13]A.Papworth,P.fox et al.The disruption of oxide defects within aluminum alloy castings by the addition of bismuth[J].Matedals Letters 35(1998):202-206
[14]秦小梅,赵骧,左良,等。固相法制备含铋层状结构PBN压电陶瓷[J],东北大学学报(自然科学版),2002,23(12):1147
[15]舒万银编.有色金属精细化工生产与应用[M].长沙:中南工业大学出版社,1995
[16]爱尔金斯,沃斯.钒酸铋和其它无铅色漆用颜料[J],中国涂料,2001(1):34
[17]陈玉松,张维维,于同双.含铋铅粉对铅蓄电池放电性能的影响[J],蓄电池,2002(2):55
[18]刘志宏,徐山清,黄凯,合金元素对合金锌粉析气量的影响[J],中国锰业,2001,19(2):21-24
[19]任柏峰.我国铋工业发展现状及对策[J].世界有色金属,1999,(11):10-13
[20]傅崇说,有色冶金原理[M].北京:冶金工业出版社,1984
[21]C.B.奥尔考克,火法冶金原理[M].北京:冶金工业出版社,1980
[22]北京有色冶金设计研究总院.世界有色金属工厂及公司概况[M].北京:冶金工业出版社,1982
[23]张长海,江涛宏.中国铋工业:寒流来袭[J].中国有色金属报,2006年04月03日
[24]中南矿冶学院冶金研究室,氯化冶金[M].北京:冶金工业出版社,1976
[25]金属时评编辑部.日本铋的生产与消费[J].金属时评,1993,(1481):148-150
[26]李春旺,王宝安.高银粗铋处理工艺的改进[J].有色冶炼,1995(1):20-23
[27]张传福,谭鹏夫主编.第VA族元素物理化学数据手册[M].湖南长沙:中南工业大学出版社,1995
[28]Greenwood N.N.Earnshaw A.元素化学[M].李学同,孙玲,单辉等译,北京:高等教育出版社,1996:262-263
[29]倪天增,罗冬冬,范力仁,等.纳米氧化铋的制备及应用[J].中南民族大学学报(自然科学版),2004,(3):26-29
[30]陈国华,刘心宇.氧化铋对微晶玻璃的相转变和性能的影响[J].材料科学与工艺,2004,12(5):501-505
[31]李卫,周科朝,杨华.氧化铋的应用研究进展[J].材料科学与工程学报,2004,22(1):154-156
[32]N.M.Sammes.Bismuth based oxide electrolytes structure and ionic conductivity[J].Journal of the European ceramic society,1999,19:1801-1826
[33]G.A.Tompsett,N.M.Sammes,Y.Zhang.et al.Characterization of WO_3V_2O_5 doped bismuth oxides by x-ray diffraction and romanspectoscopy[J].Solid State Ionics,1998,(113-115):631-638
[34]陈宏生.高温超导线材及其强电应用研发与产业发展状况[J].新材料产业,2002,(1):15-19
[35]毛传斌,周廉.Bi系氧化物超导体粉末制备发展及现状[J].稀有金属材料与工程,1994.12,23(6):1-7
[36]高尧来,温其标.超微粉体的制备及其在食品中的应用前景[J].食品科学,2002,23(5):157-160
[37]Hellwig H,Liebert J,Bohaty L.Linear optical properties of monoclinic bismuth borate BiB_3O_6[J].Journal of Applied Physi 2000,88:240-244
[38]Tomohiro Watanabe,Tokuro Nanba,Yoshinari Miura.X-ray neutron scattering study of the structure of lithium bismuth oxide glass[J].Journal of Non Crystalline Solids,2002,(297):73-83
[39]Sugimoto,Naoki.Ultraf stoptical switches and wave length division multi-plexing(WDM) amplifiers based on bismuth oxide glasses[J].Journal of the American Ceramic Society,2002,85(5):1083-1088
[40]S.Fujiwara,T.Suzuki,N.Sugimoto,et al.The optical switching glasses containing bismuth oxide[J].Journal of Non crystalline Solids,1999,(259):116-120
[41]Su wei-fang,Yuan Hsiao-kuan.High refractive index organic/inorganic hybrid materials prepared from polymerizable titanium bismuth ethacrylate ethoxide[J].Polymer Preprint of American Chemical Society,2000,411:574-575
[42]Golis,E.P.Lead bismuth gallium oxide glasses for optoelectronics and optical fiber technics[J].The International Society for Optical Engineering,2000,4239:23-25
[43]N.Mahhei,D.H.H.Quon,J.Aota.et al.Float-zone crystal growth of Bi_(12)GeO_(20) in a micro gravity environment[J].Journal of Crystal growth,1997,(180):105-112
[44]Hellwig H,Liebert J,Bohaty L.Linear optical properties of the monoclinic bismuth borate BiB_3O_6[J].Journal of Applied Physics,2000,88:240-244
[45]S.A.Cheng,Y.Q.Lei,Y.J.Leng,Q.D.Wang.Electrochemical performance of metal hydride negative electrode modified with bismuth oxide[J],Journal of Alloys and Compounds,1998,(264):104-106
[46]Innocenzo G.Casella,Maria Gatta,Michela Contursi,Oxidation of sugar acids on polycrystalline platinum and gold electrodes modified with adsorbed bismuth oxide adlayers[J],Journal of Electroanalytical Chemistry,2004,(561):103-111
[47]L.T.Lam,N.P.Haigh,O.V.Lim,D.A.J.Rand,J.E.Manders.Capacity and cycle-life of batteries using bismuth-bearing oxide[J],Journal of Power Sources,1999,(78):139-146
[48]L.T.Lam,H.Ceylan,N.P.Haigh,J.E.Manders,Influence of bismuth on the chargingability of negative plate in lead-acid batteries[J],Journal of Powersources,2002,(107):155-161
[49]Hellwig H,Liebert J,Bohaty L.Linear optical properties of the monoclinic bismuth borate BiB_3O_6[J].Journal of Applied Physics,2000,88:240-244
[50]韩俊鹤,欧慧灵,廖鹏,等.表面修饰的Bi_2O_3纳米微粒的光学特性[J].河南大学学报(自然科学版),2001,31(3):14-16
[51]Naixiong Jiang,Eric D.Wachsman,Su-Ho Jung et al.A higher conductivity Bi_2O_3-based electrolyte[J].Solid State Ionics 150(2002):347-353
[52]Y.Zeng,Y.S.Lin.Catalytic properties of yttria doped bismuth oxide ceramics for oxidative coupling of methane[J].Applied Catalysis A:General 159(1997)101-117
[53]郭文宇,岳振星,周济.Bi_2O_3对自燃烧法合成NiZnCu铁氧体的显微结构与性能的影响[J].压电与声光,2001(5):391-393
[54]吴锡平,吴立新.超微粉体材料的制取与应用[J],有色矿冶,1995(5):44-46
[55]O.P.Thakur,DevendraKumar,mParkash,et al.Electrical characterization of strontium titanate borosilicate glass ceramics system with bismuth oxide addition using impedance spectroscopy[J].Materials Chemistry and Physics . 2003, 78: 751-759
[56]Y.Zeng, Y.S.Lin. Stability and surface catalytic properties of fluorite structured yttria, and P_2O_5 doped bismuth oxide under reducing environment [J] .Journal of catalysis,1999,(182):30-36
[57]Vania C. De Sousa, Marcio R. Morelli, Ruth H.G. Kiminami, Combustion process in the synthesis of ZnO-Bi_2O_3 [J]. Ceramics International 2000, 26:561-564
[58]SzuhweeNg, J.M.Xue,John Wang. High temperature piezoelectric strontium bismuth titanate from mechanical activation of mixed oxides [J]. Materials Chemistry and Physics2002,75:131-135
[59]G.Fafilek. Voltammetry on BICUVOX.10 microsamples [J]. Solid State Ionics, 1998,(113-115):623-629
[60]Yanhai Du, N.M.Sammes, GA. Tompsett, et al. Phase stability of bismuth lead antimony oxide [J].Solid State Ionics 1999,(117):291-299
[61]Shaowen Zha, Jigui Cheng, YanLiu, et al. Electrical properties of pure and Sr doped bismuth Bi_2Al_4O_9 ceramics[J].Solid State Ionics,2003,(156): 197-200
[62]Jan-Dierk Grunwaldt, Manuel D.Wildberger,Tamas Mallat, and Alfons Baiker. Unusual redox properties of bismuth in Sol-Gel Bi-Mo-Ti mixed oxides [J], Journal of Catalysis, 1998,( 177):53-59
[63] Johnson, Peter K. Ultrafine powder technology[J].International Journal of Powder Metallurgy [J]. 2004,40(1): 9-11
[64]Won, H.I. Combustion synthesis of ultrafine tungsten carbide powder Journal of Materials Research[J]. 2008, 23( 9):2393-2397
[65]Sidorova, E.N. , Dzidziguri, E.L., Levina, V.V..Formation of an ultrafine nickel powder[J].Russian Metallurgy,2007,( 6): 469-472
[66]Ibaseta, Nelson , Climent, Eric, Biscans, Batrice.SFGP 2007 - Ultrafine aerosol generation from free falling nanopowders: Experiments and numerical modelling[J]. International Journal of Chemical Reactor Engineering, 2008,(6):24
[67] Song, Jae-Sung, Kim, Hyun-Ju. Photonic decomposition of ultrafine, rutile phased TiO_2 powder in aqueous 4-chlorophenol solutions[J]. Smart Materials and Structures, 2006,15(11):65-73
[68]Yakubovskaya, S.V.,Kul'bitskaya, L.V..Effect of composition of combined sensitization/activation solutions on chemical deposition of Cu-TiO_2 ultrafine-grained composite coatings on diamond powders[J].Russian Journal of Inorganic Chemistry,2008,53(12):1834-1839
[69]Wu,Songping.Preparation of fine copper powder using ascorbic acid as reducing agent and its application in MLCC Source[J].Materials Letters,2007,61(4-5):1125-1129
[70]Wu,Songping.Preparation of fine copper powder with chemical reduction method and its application in MLCC IEEE[J].Transactions on Advanced Packaging,2007,30(3):434-438
[71]张克,李良果,王洪友.超细粉体的性质、制备及其对工程学科的影响[J].中国粉体技术,1998,4(6):35-38
[72]万朴,董发勤,彭同江,等.超细粉体的应用及超细后果效应[J],非金属矿,1999年6月,22(增刊):74-76
[73]Zhang,Hui,Zhu,Jesse Ultrafine powder coatings,an innovation for the coating industry[J].2006 AIChE Spring National Meeting - 5th World Congress on Particle Technology,2006:5
[74]Mei,L.,Li,J.-T.Combustion synthesis of ultrafine magnesium nitride powder by Ar dilution[J].Scripta Materialia,2009,60(3):141-143
[75]Liu,Wenbin,Song,Xiaoyan,Zhang,Jiuxing.Preparation of ultrafine WC-Co composite powder by in situ reduction and carbonization reactions [J].International Journal of Refractory Metals and Hard Materials,2009,27(1):115-120
[76]Shi,Xiaoliang,Yang,Hua;Shao,Gangqin.Oxidation of ultrafine-cemented carbide prepared from nanocrystalline WC-10Co composite powder[J].Ceramics International,2008,34(8):2043-2049
[77]Zhan,Lu,Xu,Zhenming.Application of vacuum metallurgy to separate puremetal from mixed metallic particles of crushed waste printed circuit board scraps[J].Environmental Science and Technology,2008,42(20):7676-7681
[78]Zhao Li-Dong,Zhang Bo-Ping,Liu Wei-Shu.Enhanced thermoelectric properties of bismuth sulfide polycrystals prepared by mechanical alloying and spark plasma sintering[J].Journal of Solid State Chemistry,2008,181(12):3278-3282
[79]Kim,Daniel,Wang,Shijie.Bismuth recovery from hydrochloric acid solution [J].Canadian Metallurgical Quarterly,2008,47(3):317-326
[80]He Qiuxing,Tu Weiping;Hu Jianqing.Elimination of hard aggregation of bismuth-doped tin dioxide nanometer powders prepared by wet chemical method[J].Huagong Xuebao/Journal of Chemical Industry and Engineering,2006,57(6):1490-1495
[81]Ren Wei,Liu Xuequan,Wang Xiaolin.Thermoelectric properties of bismuth telluride based materials prepared by powder metallurgy processing[J].Key Engineering Materials,2007,336-338(Ⅰ):864-867
[82]Kondo,Masatoshi.Metallurgical analysis of a tube ruptured in the lead bismuth corrosion test facility[J].Journal of Nuclear Science and Technology,2006,43(2):174-178
[83]郑波,任志刚,童剑英,等.电化学方法制备超细氧化铋粉末[J].化学研究与应用,2004,16(3):411-412
[84]Beauchemin,S.,Chen,T.T..Behaviour of antimony and bismuth in copper electrorefining circuits[J].Canadian Metallurgical Quarterly,2008,47(1):9-25
[85]吴绍华,刘春艳,刘进,等.超细Bi_2O_3粉体的制备研究现状[J],中国粉体技术,2005年第6期:37-41
[86]何伟明,甑强,潘庆谊,等.反向滴定法制备超细氧化铋粉体的研究[J],功能材料,2003,34(6):702-703
[87]肖政伟.超细氧化铋的制备.[长沙:中南大学硕士学位论文].2004.5
[88]He Qiu-Xing.Synthesis and characterization of bismuth-doped tin dioxide nanometer powders[J].Journal of Central South University of Technology,2006,13(5):519-524
[89]Shojaie-Bahaabad,M.Economical synthesis of nano alumina powder using an aqueous sol-gel method[J].Materials Letters,2008,62(19):3364-3366
[90]Rajabi-Zamani,A.H.,Behnamghader,A.,Kazemzadeh,A.Synthesis of nanocrystalline carbonated hydroxyapatite powder via nonalkoxide sol-gel method[J].Materials Science and Engineering C,2008,28(8):1326-1329
[91]Han Yuxian,Qiu,Tai,Song Tao.Preparation of ultrafine tungsten powder by sol-gel method.Journal of Materials Science and Technology,2008,24(5,):816-818
[92]Sopyan I.Synthesis of strontium-doped hydroxyapatite powder via sol-gel method[J].Advanced Materials Research,2008:928-931
[93]Lu Zhuofei,Li Yi,Zhang Xuejian.Synthesis of Er~(3+):YAG nanopowder by sol-gel combustion method Kuei Suan Jen Hsueh Pao[J].Journal of the Chinese Ceramic Society,2008,36(10):1454-1457
[94]Fathi M.H.,Hanifi A.Evaluation and characterization of nanostructure hydroxyapatite powder prepared by simple sol-gel method[J].Materials Letters,2007,61(18):3978-3983
[95]Barati M.R.The role of surfactant in synthesis of magnetic nanocrystalline powder of NiFe_2O_4 by sol-gel auto-combustion method[J].Journal of Non-Crystalline Solids,2008,354(47-51):5184-5185
[96]Kim Won-Jeong,Kim Sang Su.Structural and electrical properties of ferroelectric Bi_(3.4)Pr_(0.6)Ti_3O_(12) prepared by a sol-gel method Integrated Ferroelectrics,2006,81(1):105-111
[97]Weidong He,Wei Qin,Xiaohong,Wu.The photocatalytic properties of bismuth oxide films prepared through the sol-gel method[J].Thin Solid Films,2007,515(13):5362-5365
[98]Xiaohong Wu,Wei Qin,Weidong He.Thin bismuth oxide films prepared through the sol-gel method as photocatalyst[J].Journal of Molecular Catalysis A:Chemical,2007,261(2):167-171
[99]Weidong He,Wei Qin,Xiaohong Wu.Thin bismuth oxide films prepared through the sol-gel method[J].Materials Letters,2007,61(19-20):4100-4102
[100]Du Xianfeng,Xu,Youlong Ma,Hanxiao.Synthesis and characterization of bismuth titanate by an aqueous sol-gel method[J].Journal of the American Ceramic Society,2007,90(5):1382-1385
[101]Roger F,Bel T.Hydrothermal ruby:Infrared spectra and X-Ray topography[J].Communications,1967,2:2688-2689
[102]ArmelaoL,ColomboP,FabrizioM.Synthesis of Bi_2O_3 and Bi_4(SiO_4)_3 thin films by the sol-gel method[J].J Sol-Gel Sci Technol,1998,13(1,2,3):213-217
[103]Sun Y.H.,Liu X.B.,Chen Min.Study on ferroelectric properties of Nd-doped Bl_4Ti_3O_(12) thin films prepared by sol-gel method[J].Key Engineering Materials,2007,336-338(Ⅰ):146-148
[104]Guo Dongyun,Li Meiya,Wang Jing.Ferroelectric properties of Bi_(3.6)Ho_(0.4)Ti_3O_(12)thin films prepared by sol-gel method[J].Applied Physics Letters,2007,91(23):232905
[105]Kao M.C.,Chen H.Z.,Young,S.L.Ferroelectfic properties and leakage current mechanisms of Bi_(3.25)La_(0.75)Ti_3O_(12) thin films with a-axis preferred orientation prepared by sol-gel method[J].Materials Letters,2008,62(4-5):629-632
[106]陈代荣,谢经雷,李博,等.Bi(OR)_3作前驱体合成Bi_2O_3微粉 (R:CH_2CH_2OCH_3,CMe_2Et)[J].山东大学学报(自然科学版),1997,32(1):88-93
[107]Moulay,Saad.Microemulsion breakdown by pervaporation technique:Effect of the alkyl chain length of n-alkanol,a cosurfactant of the microemulsion[J].Journal of Colloid and Interface Science,2007,311(2):556-561
[108]Kogan,Anna,Popov Inna.Microemulsion-facilitated ccrystallization of carbamazepine[J].Journal of Dispersion Science and Technology,2007,28(7):1008-1019
[109]Teo,Boon M.,Ashokkumar,Muthupandian.Microemulsion polymerizations via high-frequency ultrasound irradiation[J].Journal of Physical Chemistry B,2008,112(17):5265-5267
[110]Pratap Amit P.,Bhowmick D.N.Pesticides as microemulsion formulations [J].Journal of Dispersion Science and Technology,2008,29(9):1325-1330
[111]Ho Beng S.,Tan Beng H..Inverse microemulsion polymerization of sterically stabilized polyamholyte microgels[J].Langmuir,2008,24(15):7698-7703
[112]Sarraguca,J.M.G.,Pais,A.A.C.C..Structure of microemulsion -ABA triblock copolymer networks Source[J].Langmuir,2008,24(19):11153-11163
[113]Purkayastha Arup,Kim,Seongyul.Molecularly protected bismuth telluride nanoparticles:Microemulsion synthesis and thermoelectric transport properties [J].Advanced Materials,2006,18(22):2958-2963
[114]Henle J.,Kaskel S.Preparation of photochromic transparent BiOX(X=Cl,I)/PLA nanocomposite materials via microemulsion polymerization[J].Journal of Materials Chemistry,2007,17(47):4964-4971
[115]Henle J.,Simon P..Nanosized BiOX(X=Cl,Br,I) particles synthesized in reverse microemulsions[J].Chemistry of Materials,2007,19(3):366-373
[116]Stubenrauch Cosima,Wielputz Thomas,Sottmann Thomas.Microemulsions as templates for the synthesis of metallic nanoparticles Colloids and Surfaces A[J].Physicochemical and Engineering Aspects,2008,317(1-3):328-338
[117]吴晓春,汤国庆,张桂兰,等.不同制备条件对纳米Bi_2O_3发光的影响[J].化学学报,1996,54:146-151
[118]Santana C.,Mahugo.Development of a solid-phase microextraction method with micellar desorption for the determination of chlorophenols in water samples[J].Journal of Chromatography A,2007,1140(1-2):13-20
[119]Guerrero,Enrique Duran,Chinnici Fabio.Solid-phase extraction method for determination of volatile compounds in traditional balsamic vinegar[J].Journal of Separation Science,2008,31(16-17):3030-3036
[120]Vinas Pilar,Campillo Natalia.Method development and validation for strobilurin fungicides in baby foods by solid-phase microextraction gas chromatography-mass spectrometry[J].Journal of Chromatography A,2009,1216(1):140-146
[121]LI Huizhi,ZHAI Yubo.Solid-phase extraction of trace Au(Ⅲ) with SDG and determination by the catalytic spectrophotometric method[J].Rare Metals,2008,27(6):560-565
[122]Azadmard-Damirchi,Sodeif,Dutta Paresh C.A single step solid-phase extraction method for complete separation of sterol oxidation products in food lipids[J].Journal of Chromatography A,2009,1216(1):36-42
[123]Donald F,Weirauch,Robert Kong.The hydrothermal growth of Al_2O_3 in HCl solutions[J].Journal of Growth,1972,19:139-140
[124]Wang Shengwei,Yang Zhanhong.Study of calcium zincate synthesized by solid-phase synthesis method without strong alkali[J].Materials Chemistry and Physics,2008,112(2);603-606
[125]Asadov M.M.,Akhmedly K.M.Calculation of some thermodynamic parameters of non-ideal solutions Diffusion and Defect Data Pt.B Solid State Phenomena[J].Solid Phase Transformations,2008,138:331-338
[126]Miro Manuel,Hartwell Supaporn Kradtap.Recent developments in automatic solid-phase extraction with renewable surfaces exploiting flow-based approaches TrAC-Trends[J].Analytical Chemistry,2008,27(9):749-761
[127]Suvardhan K.,Kumar K.,Suresh RekhaD..Preconcentration and solid-phase extraction of beryllium,lead,nickel,and bismuth from various water samples using 2-propylpiperidine-1-carbodithioate with flame atomic absorption spectrometry(FAAS)[J].Talanta,2006,68(3):735-740
[128]Rao Mannepalli M..Determination of bismuth in natural water samples by ICP-AES after preconcentration on dithiocarbamates-coated ambedite XAD-7International[J].Journal of Environmental Analytical Chemistry,2006,86(6):443-452
[129]李青文,李娟,夏熙.纳米Bi_2O_3微粒的固相合成及其电化学性能的研究[J].化学学报,1999,29:491-495
[130]陈建龙,罗元香,刘孝恒,等.室温固相法制备纳米氧化铋[J].材料导报,2003,17(7):82-83
[131]Ahn S.H.,Choi S.K.Hydrothermally fabricated epitaxial PbTiO_3 patterns patterned lithographically by etching in hydrothermal KOH solution[J].Applied Physics Letters,2008,93(11):113-102
[132]Morimoto,Masato,Nakagawa Hiroyuki.Hydrothermal extraction and hydrothermal gasification process for brown coal conversion Fuel,[J].The 9th China-Japan Symposium on Coal and C1 Chemistry,2008:546-551
[133]German Christopher R..Hydrothermal exploration with the Autonomous Benthic Explorer Deep-Sea Research Part Ⅰ[J].Oceanographic Research Papers,2008,55(2):203-219
[134]Yuksel Asli,Diono Wahyu.Hydrothermal electrolysis of organic contaminants AIChE Annual Meeting,Conference Proceedings[J].2007 AIChE Annual Meeting,2007:7
[135]Pei L.Z.Zhao H.S.,Yu H.Y.,Tan W.Hydrothermal deposition of silicon nanochains[J],e-Journal of Surface Science and Nanotechnology,2008,6(2):171-174
[136]Wang Yanxiang,Fan Xueyun,Sun Jian.Hydrothermal synthesis of phosphate-mediated ZnO nanosheets[J].Materials Letters,2009,63(3-4):350-352
[137]Tune Mehmet Sefik,Van Heiningen Adriaan R.P.Hydrothermal dissolution of mixed southern hardwoods[J].Holzforschung,2008,62(5):539-545
[138]Kojima Takashi,Yoshida Ikue.Effect of treatment conditions and titanium source on the hydrothermal synthesis of bismuth titanate particles[J].Journal of the European Ceramic Society,2009,ⅴ29(3):431-437
[139]Hongyan Miao,Min Dong;Guoqiang Tan.Hydrothermal preparation of bismuth titanate nanopowders[J].Key Engineering Materials,2007,336-338(Ⅰ):161-164
[140]杨群保,李永祥,殷庆瑞,等.Bi_2O_3晶须的水热合成研究[J].无机材料学报,2002,17(5):979-984
[141]Yu Jimmy C,Xu Anwu,Zhang Lizhi,et al.Synthesis and characterization of porous magnesium[J].Journal of Physical Chemistry B,2004,108(1):64-70
[142]Samy El-shall M,LiShou-tian.Synthesis of nanoparticles by a laser vaporization-controlled condensation technique[A].Proc SPIE-Int Soc Opt Eng [C],1997,3123:98-109
[143]ChernenkoI M,ChasovskiiKV,KatkovUE Stabilization of the δ-phase of Bi_2O_3films at300K[J].FizikaiKhimiyaTverdogoTila,2002,3(3):531-534
[144]Gangqiang Zhu,Hongyan Miao.Hydrothermal synthesis of potassium bismuth titanate nanoparticles[J].International Journal of Nanoscience,2006,5(4-5):663-669
[145]Chen Xinxiang,Cao Yanning,Zhang,Hanhui.Hydrothermal synthesis and characteristics of 3-D hydrated bismuth oxalate coordination polymers with open-channel structure[J].Journal of Solid State Chemistry,2008,181(5):1133-1140
[146]Tooth Blake,Brugger Joel.Modeling of gold scavenging by bismuth melts coexisting with hydrothermal fluids[J].Geology,2008,36(10):815-818
[147]Paraschiv Carmen,Jurca B..Synthesis of nanosized bismuth ferrite(BiFeO_3)by a combustion method starting from Fe(NO_3)_3[Closed Circle]9H_2O-Bi(NO_3)_3[Closed Circle]9H_2O-glycine or urea systems[J].Journal of Thermal Analysis and Calorimetry,2008,94(2):411-416
[148]Andrade de Jesus,Fabiane Alexsandra.Effect of pH on the production of dispersed Bi_4Ge_3O~(12) nanoparticles by combustion synthesis[J].Journal of the European Ceramic Society,2009,29(1):125-130
[149]Bellakki,Manjunath B..Solution-combustion synthesis of Bi_(1-x)Ln_xO_(1.5)(Ln=y and La-Yb) oxide ion conductors[J].Bulletin of Materials Science,2006,29(4):339-345
[150]Li J.B.,Rao G.H..Magnetic properties of Bi(Fe_(1-x)Cr_x)O_3 synthesized by a combustion method[J].Applied Physics Letters,2007,90(16):162513
[151]Schmidt Stephan,Beyer Steffen,Mittmann Stefan.High performance LPI-C/SiC combustion chamber and nozzle extension for next generation satellite engines [J].VDI Bedchte,2028:477-478
[152]Mercadelli lisa,Galassi Carmen.Sol-gel combustion synthesis of BNBT powders [J].Journal of Sol-Gel Science and Technology,2008,46(1):39-45
[153]陈世柱,尹志民.制备金属氧化物纳米粉的液雾燃烧工艺研究[J].材料科学与工程,1998,16(3):60-63
[154]ZhouNaijun,YinZhimin,ChenShizhu.Thermochemicstry and mechanism of process for preparation of powdered Bi2O_3 by melt-atomizing-combustion method[J].Trans Nonferrous MetSocChi-na,1997,7(3):113-117
[155]尹志民,陈世柱,潘青林,等.熔体雾化-燃烧法制备高纯三氧化二铋超细粉[J].中国有色金属学报,1994,4(4):62-64
[156]Sheng Hao,Yue Zhenxing.Synthesis of BiFeO_3-PbTiO_3 powders by sol-gel auto-combustion process[J].Key Engineering Materials,2005,280-283(Ⅰ):609-612
[157]Late L.,Thelin W.,Blekkan,E.A.Selective combustion of hydrogen in the presence of hydrocarbons:Part 2.Metal oxide based catalysts[J].Applied Catalysis A,2004,262(1):63-68
[158]Zanetti S.M.,Santiago E.I.,Bulhoes,L.O.S..Preparation and characterization of nanosized SrBi_2Nb_2O_9 powder by the combustion synthesis[J].Materials Letters,2003,57(19):2812-2816
[159]Lutz M dler,Sotiris E Pratsinis.Bismuth oxide nanoparticles by flame spray pyrolysis[J].JAmCeramSoc,2002,85(7):1713-1718
[160]Zhao Li-Dong,Zhang Bo-Ping,Liu Wei-Shu.Enhanced thermoelectric properties of bismuth sulfide polycrystals prepared by mechanical alloying and spark plasma sintering[J].Journal of Solid State Chemistry,2008,181(12):3278-3282
[161]Matsumoto Akihiro,Shiozaki Tadashi.Simultaneous determination of bismuth and tellurium in steels by high power nitrogen microwave induced plasma atomic emission spectrometry coupled with the hydride generation technique[J].Analytical and Bioanalytical Chemistry,2004,379(1):90-95
[162]Hao Junjie,Wang Xiaohui.Preparation of textured bismuth titanate ceramics using spark plasma sintering[J].Journal of the American Ceramic Society,2004,87(7):1404-1406
[163]Duan Xingkai,Yang Junyou.Synthesis of Bi_2Te_3 nanopowders by vacuum arc plasma evaporation[J].Powder Technology,2007,172(2):63-66
[164]Kan Yanmei,Wang Peiling,Xu Tao.Spark plasma sintering of bismuth titanate ceramics[J].Journal of the American Ceramic Society,2005,88(6):1631-1633
[165]Wan Li,Cui Zuo-Lin,Zhang Zhi-Kun.Bi nanoparticles and Bi_2O_3 nanorods formed by thermal plasma and heat treatment[J].Surface and Coatings Technology,2007,201(9-11):5330-5332
[166]禹争光,杨邦朝,敬履伟.纳米氧化铋粉体的制备及对ZnO压敏电阻性能的影响[J].硅酸盐学报,2003,31(12):1184-1187
[167]LarinVK,Kondakov V M,Malyi E N,et al.Plasma-chemical method for preparation of nanosized of metal oxides and prospective trends in their application[J],Izvestiya Vysshikh Uchebnykh Zavedenii,Tsvetnaya Metallurgiya,2003,5:59-64
[168]JungkHO,FeldmannC.Polyol mediated synthesis of sub-micrometer Bi_2O_3 particles[J].Jmater Sci,2001,36:297-299
[169]段学臣,涂石桥.超细氧化铋的制备与结构特性[J],中南工业大学学报,1997(2):164-166
[170]孙璐薇,何永,付云德,等.纳米氧化铋研究[J],传感器技术,2000,19(1):21-22
[171]Hwang Gil-Ho,Han Won-Kyu,Park Joon-Shik.An electrochemical sensor based on the reduction of screen-printed bismuth oxide for the determination of trace lead and cadmium[J].Sensors and Actuators,2008,135(1):309-316
[172]夏兆泉,章广.矿产保护与利用[J].2000,(5):43-46
[173]许敏强.株冶铋冶炼技术的发展[J].有色冶炼,1993,(6):5-8
[174]王延岑.银锌渣提银工艺研究[J].有色冶炼,1991,(6):27-28,43
[175]汪立果.考察墨西哥托雷翁厂铋的回收[J].有色冶炼,1989,(2):39-41
[176]俞宗衡.从高铋含银渣中提取铋的试验研究[J].有色金属(冶炼),1989,(3):13-15
[177]孔繁珍.从高砷含铋物料中回铋[J].湿法冶金,2000,19(3):54-58
[178]张小红,郑文裕.从高炉烟尘提取铋的研究[J].湿法冶金,1995,(1):42-44
[179]何从行.氧化铋渣综合回收试验研究[J].湖南有色金属,1995,11(2):39-41,64
[180]赖师祥,胡传璋.从高铅铋渣中综合回收有价金属的试验研究[J].有色冶炼,1994,(3):39-42
[181]秦毅红,王云燕,彭文杰.铋深加工产品的应用及其发展前景[J].世界有色金属,1998,(4):44-45
[182]赵源泽,朱建春,李琼洁,等.制取铋盐新工艺的研究[J].广东有色金属学报,1995,5(2):126-132
[183]李学金.氯氧铋湿法直接制取铋盐新工艺研究[J].湖南有色金属,2000,16(2):18-20,30
[184]唐冠中,杨新生,许秀莲.从氯氧化铋制取高纯度铋化工产品的研究[J].有色金属(冶炼),1995,(2):9-11,27
[185]杨新生.从氯氧化铋制取高纯度铋化工产品的热力学分析与试验[J].江西冶金,1994,14(2):16-19
[186]朱建春,赵源泽,李琼洁.应用微机绘制电位-pH图分析氯氧化铋精矿提纯工艺[J].广东有色金属学报,1995,5(1):50-57
[187]康云川,粱汉贤,李月秀.氧化铋制取工艺的研究[J].云南师范大学学报,1994,14(3):58-60
[188]康云川,粱汉贤,李月秀.氧化铋制取工艺的改进[J].云南化工,1995,(4):45,71
[189]段学臣,涂石桥.超细氧化铋的制备与结构特性[J].中南工业大学学 报,1997,28(2):164-166
[190]王云燕,秦毅红.新型无机黄色颜料[J].湖南化工,1999,29(1):13-15
[191]吕尔会.高铋阳极泥提铋新工艺[J].湖南化工,199,29(4):21-23
[192]李纯旺,王宝安.高银粗铋处理工艺的改进[J].有色冶炼,1995,(1):20-22
[193]陈名瑞.三氯化铁浸出法从钨细泥硫化矿中提取铋[J].矿产综合利用,1994,(5):20-23
[194]唐谟堂,鲁君乐.由柿竹园高硅含铍含氟铋精矿直接提取铋品[J].1995,26(2):186-190
[195]孙璐薇,何永,付云德,等.纳米氧化铋研究[J].传感器技术,2000,19(1):21-22
[196]李德良,黄念东,许中坚.超细高纯氧化铋的制备研究[J].2001,33(1):15-16
[197]许秀莲,唐冠中,杨新生.从铋氯化溶液中空气氧化除铁的研究[J].1994,8(1):35-38
[198]杨新生.盐酸浸出法处理高铋银锌渣[J].1994,14(4):32-33,42
[199]钟竹前,梅光贵.化学位图在湿法冶金和废水净化中的应用[M].湖南长沙:中南工业大学出版社,1986
[200]朱元保,沈子琛,张传福,等.电化学数据手册[M].湖南长沙:湖南科学技术出版社,1984
[201]叶大伦.实用无机物热力学数据手册[M].北京:冶金工业出版社,1981
[202]杨显万.高温水溶液热力学数据计算手册[M].北京:冶金工业出版社,1983
[203]K.6雅齐米尔斯基等.络合物的不稳定常数[M].北京:化学工业出版社,1960
[204]F.巴索洛等.无机反应机理-溶液中金属络合物的研究[M].北京:化学工业出版社,1987
[205]丁绪淮,谈道.工业结晶[M].北京:高等教育出版社,1989
[206]周祖康,顾惕人,马季铭.胶体化学基础[M].北京:北京大学出版社,1996
[207]Sugimoto T.Preparation of mono-dispersed colloidal particles[M].Adv.Colloidal & Interface Sci.,1987(28):65
[208]沈钟,王果庭.胶体与表面化学[M].化学工业出版社,1997
[209]姚允斌,解涛,高英敏.物理化学手册[M].上海:上海科学技术出版社,1985
[210]秦毅红,王云燕.Bi~(3+)-NO_3-H_2O系热力学平衡研究[J].中南工业大学学报,1999,30(5):497-500
[211]罗电宏,马荣骏.对超细粉末团聚问题的探讨[J].湿法冶金,2002,21(2):57-61
[212]Randolph A.d.,Larson M.A.Theory of particulate process[M],2~(na)Edition.1988by Academic Press,INC
[213]张克从,张乐惠.晶体生长科学与技术(上册)[M].北京:科学出版社,1997.253 -271
[214]宁桂玲,吕秉玲.纳米颗粒的干燥及其研究进展[J].化工进展,1996,5:22-25
[215]刘雪莲,许煜汾,范文元.共沸蒸馏法制备ZrO_2纳米晶微粉的研究[J].合肥工业大学学报,1998,21(5):43-47
[216]仲维卓,华素坤.纳米材料及其水热法制备(上)[J],上海化工,第23卷第11期:25-27
[217]Qunbao Yang,Yongxiang Li,Qingrui Yin,et al.Hydrothermal systhesis of bismuth oxide needles[J|.Materials Letters.55(2002):46-49
[218]李汶军,施尔畏,仲维卓,等.负离子配位多面体生长基元的理论模型与晶粒形貌[J].人工晶体学报,1999,28(2):117-125
[219]梅光贵,王德润,周敬元,王辉。湿法炼锌学[M].湖南长沙;中南大学出版社
[220]博崇说.有色冶金应用基础研究[M].湖面长沙;科学出版社,1993
[221]FERNANDES C,AVELINO A,FARELO F.Crystallization of xylitol from hydro-alcoholic solutions containing arabitol and adonitol[C].14th Int Symp Industrial Crystallization Cambridge.UK,1999:12-16
[222]Ernesto Acosta Mart'inez,Marco Giulietti,Joa O Batista de Almeida e Silva,Silas Derenzo.Kinetice of the xylitol crystallization in hydro-alcoholic solution[J],Chemical Engineering and Processing.47(2008)2157-2162.
[223]崔玉民,徐立杰.用光催化剂处理含亚硝酸盐废水的研究[J]工业水处理,2000,20(8):17-19
[224]Vania C.De Sousa,Marcio R.Morelli,Ruth H.G.Kiminami,Combustion process in the synthesis of Bi_2O_3-ZnO[J].Ceramicslnternational 2000,26:561-564.
[225]Szuhwee Ng.J.M.Xue,John Wang.Hight temperature piezoelectric strontium bismuth titanate from mechanical activation of mixedoxides[J].Materials Chemistry and Physics 2002,75:131-135.
[226]O.P.Thakur,Devendra Kumar,Om Parkash,et al.Electrical characterization of strontium titanate borosilicate glass ceramics system with bismuth oxide addition using impedance spectroscopy[J].Materials Chemistry and Physics 2003,78:751-759.
[227]Y.Zeng.Y.S.Lin.Stability and surface catalytic properties of fluorite-structured yttria-,and P2O5-doped bismuth oxide under reducing environment[J].Journal of Catalysis,1999,(182):30-36.
[228]N.M.Sammes.Bismuth based oxide electrolytes-structure and ionic conductivity [J].Journal of the European ceramic society,1999,19:
[229]马挺,应锡璋.超细改性Bi_2O_3的制备及其在抗栓医用聚氨酯材料中的应用[J].上海交通大学学报1999,33(2):219-221.
[230]Malinovskaya T D,Aparnev A I.Carbon monoxide semiconductor based on SnO_2-Bi_2O_3[J].Russian Journal of Applied Chemistry,2001,74(11):1 864-1867
[231]Hyuk-Joon Y,Clive R.Dielectric relaxation and microwave dielectric properties of Bi_2O_3-ZnO-Ta_2O_5 ceramics[J].Journal of Materials Research,2002,17(6):1502-1 506
[232]戴云,刘愚,张定宇等.电子工业用氧化铋生产工艺的开发与实践[J].云南冶金,2001,30(4):22-25
[233]Xia Changrong,Zhang Yuelan,Liu Meilin.Compo-site cathode based on yttria stabilized bismuth oxide for low-temperature solid oxide fuel cells[J].Applied Physics Letters,2003,82(6):901-903
[234]Rose-Noelle V,Edouard C.Oxide ion transport in bismuth-based materials[J].Materials Research Society Symposium Proceedings,2003,756:95-103
[235]沈能斌.以高铋银锌渣为原料制取超细氧化铋的工艺研究.[长沙:中南大学硕士论文]2006.6
[2]中南矿冶学院,重金属冶金学(下册)[M],北京:中国工业出版社,1961
[3]化学工业部编.无机盐工业手册[M].北京:化学工业出版社,1990
[4]刘承科主编.大学化学-元素化学[M].长沙:中南工业大学出版社,1994
[5]武汉大学等编.无机化学(下)[M].北京:高等教育出版社,1991
[6]Lam L T,High N P,Lim O V,et al.Power Sources[J],1998,73:36
[7]Lam L T,High N P,Lim O V,et al.Power Sources[J],1999,78:139
[8]秦毅红,王云燕,彭文杰.铋深加工产品的应用及其发展前景[J],世界有色金属,1998年第4期:44-45
[9]刘艳.碱性电池无汞化的实现途径[J],重庆工业高等专科学校学报,2002,17(3):26
[10]冶金译丛编辑委员会,超纯金属与半导体材料(2)[M],上海市科学技术编译馆.1965
[11]简爱珠,张亚平.无汞锌粉中铋含量的测定[J],电池,2002,32(5):308-309
[12]张进孝,曹瑜强.Bi、Cu对大断而可锻铸铁的影响[J],铸造技术,2002,23(2):94
[13]A.Papworth,P.fox et al.The disruption of oxide defects within aluminum alloy castings by the addition of bismuth[J].Matedals Letters 35(1998):202-206
[14]秦小梅,赵骧,左良,等。固相法制备含铋层状结构PBN压电陶瓷[J],东北大学学报(自然科学版),2002,23(12):1147
[15]舒万银编.有色金属精细化工生产与应用[M].长沙:中南工业大学出版社,1995
[16]爱尔金斯,沃斯.钒酸铋和其它无铅色漆用颜料[J],中国涂料,2001(1):34
[17]陈玉松,张维维,于同双.含铋铅粉对铅蓄电池放电性能的影响[J],蓄电池,2002(2):55
[18]刘志宏,徐山清,黄凯,合金元素对合金锌粉析气量的影响[J],中国锰业,2001,19(2):21-24
[19]任柏峰.我国铋工业发展现状及对策[J].世界有色金属,1999,(11):10-13
[20]傅崇说,有色冶金原理[M].北京:冶金工业出版社,1984
[21]C.B.奥尔考克,火法冶金原理[M].北京:冶金工业出版社,1980
[22]北京有色冶金设计研究总院.世界有色金属工厂及公司概况[M].北京:冶金工业出版社,1982
[23]张长海,江涛宏.中国铋工业:寒流来袭[J].中国有色金属报,2006年04月03日
[24]中南矿冶学院冶金研究室,氯化冶金[M].北京:冶金工业出版社,1976
[25]金属时评编辑部.日本铋的生产与消费[J].金属时评,1993,(1481):148-150
[26]李春旺,王宝安.高银粗铋处理工艺的改进[J].有色冶炼,1995(1):20-23
[27]张传福,谭鹏夫主编.第VA族元素物理化学数据手册[M].湖南长沙:中南工业大学出版社,1995
[28]Greenwood N.N.Earnshaw A.元素化学[M].李学同,孙玲,单辉等译,北京:高等教育出版社,1996:262-263
[29]倪天增,罗冬冬,范力仁,等.纳米氧化铋的制备及应用[J].中南民族大学学报(自然科学版),2004,(3):26-29
[30]陈国华,刘心宇.氧化铋对微晶玻璃的相转变和性能的影响[J].材料科学与工艺,2004,12(5):501-505
[31]李卫,周科朝,杨华.氧化铋的应用研究进展[J].材料科学与工程学报,2004,22(1):154-156
[32]N.M.Sammes.Bismuth based oxide electrolytes structure and ionic conductivity[J].Journal of the European ceramic society,1999,19:1801-1826
[33]G.A.Tompsett,N.M.Sammes,Y.Zhang.et al.Characterization of WO_3V_2O_5 doped bismuth oxides by x-ray diffraction and romanspectoscopy[J].Solid State Ionics,1998,(113-115):631-638
[34]陈宏生.高温超导线材及其强电应用研发与产业发展状况[J].新材料产业,2002,(1):15-19
[35]毛传斌,周廉.Bi系氧化物超导体粉末制备发展及现状[J].稀有金属材料与工程,1994.12,23(6):1-7
[36]高尧来,温其标.超微粉体的制备及其在食品中的应用前景[J].食品科学,2002,23(5):157-160
[37]Hellwig H,Liebert J,Bohaty L.Linear optical properties of monoclinic bismuth borate BiB_3O_6[J].Journal of Applied Physi 2000,88:240-244
[38]Tomohiro Watanabe,Tokuro Nanba,Yoshinari Miura.X-ray neutron scattering study of the structure of lithium bismuth oxide glass[J].Journal of Non Crystalline Solids,2002,(297):73-83
[39]Sugimoto,Naoki.Ultraf stoptical switches and wave length division multi-plexing(WDM) amplifiers based on bismuth oxide glasses[J].Journal of the American Ceramic Society,2002,85(5):1083-1088
[40]S.Fujiwara,T.Suzuki,N.Sugimoto,et al.The optical switching glasses containing bismuth oxide[J].Journal of Non crystalline Solids,1999,(259):116-120
[41]Su wei-fang,Yuan Hsiao-kuan.High refractive index organic/inorganic hybrid materials prepared from polymerizable titanium bismuth ethacrylate ethoxide[J].Polymer Preprint of American Chemical Society,2000,411:574-575
[42]Golis,E.P.Lead bismuth gallium oxide glasses for optoelectronics and optical fiber technics[J].The International Society for Optical Engineering,2000,4239:23-25
[43]N.Mahhei,D.H.H.Quon,J.Aota.et al.Float-zone crystal growth of Bi_(12)GeO_(20) in a micro gravity environment[J].Journal of Crystal growth,1997,(180):105-112
[44]Hellwig H,Liebert J,Bohaty L.Linear optical properties of the monoclinic bismuth borate BiB_3O_6[J].Journal of Applied Physics,2000,88:240-244
[45]S.A.Cheng,Y.Q.Lei,Y.J.Leng,Q.D.Wang.Electrochemical performance of metal hydride negative electrode modified with bismuth oxide[J],Journal of Alloys and Compounds,1998,(264):104-106
[46]Innocenzo G.Casella,Maria Gatta,Michela Contursi,Oxidation of sugar acids on polycrystalline platinum and gold electrodes modified with adsorbed bismuth oxide adlayers[J],Journal of Electroanalytical Chemistry,2004,(561):103-111
[47]L.T.Lam,N.P.Haigh,O.V.Lim,D.A.J.Rand,J.E.Manders.Capacity and cycle-life of batteries using bismuth-bearing oxide[J],Journal of Power Sources,1999,(78):139-146
[48]L.T.Lam,H.Ceylan,N.P.Haigh,J.E.Manders,Influence of bismuth on the chargingability of negative plate in lead-acid batteries[J],Journal of Powersources,2002,(107):155-161
[49]Hellwig H,Liebert J,Bohaty L.Linear optical properties of the monoclinic bismuth borate BiB_3O_6[J].Journal of Applied Physics,2000,88:240-244
[50]韩俊鹤,欧慧灵,廖鹏,等.表面修饰的Bi_2O_3纳米微粒的光学特性[J].河南大学学报(自然科学版),2001,31(3):14-16
[51]Naixiong Jiang,Eric D.Wachsman,Su-Ho Jung et al.A higher conductivity Bi_2O_3-based electrolyte[J].Solid State Ionics 150(2002):347-353
[52]Y.Zeng,Y.S.Lin.Catalytic properties of yttria doped bismuth oxide ceramics for oxidative coupling of methane[J].Applied Catalysis A:General 159(1997)101-117
[53]郭文宇,岳振星,周济.Bi_2O_3对自燃烧法合成NiZnCu铁氧体的显微结构与性能的影响[J].压电与声光,2001(5):391-393
[54]吴锡平,吴立新.超微粉体材料的制取与应用[J],有色矿冶,1995(5):44-46
[55]O.P.Thakur,DevendraKumar,mParkash,et al.Electrical characterization of strontium titanate borosilicate glass ceramics system with bismuth oxide addition using impedance spectroscopy[J].Materials Chemistry and Physics . 2003, 78: 751-759
[56]Y.Zeng, Y.S.Lin. Stability and surface catalytic properties of fluorite structured yttria, and P_2O_5 doped bismuth oxide under reducing environment [J] .Journal of catalysis,1999,(182):30-36
[57]Vania C. De Sousa, Marcio R. Morelli, Ruth H.G. Kiminami, Combustion process in the synthesis of ZnO-Bi_2O_3 [J]. Ceramics International 2000, 26:561-564
[58]SzuhweeNg, J.M.Xue,John Wang. High temperature piezoelectric strontium bismuth titanate from mechanical activation of mixed oxides [J]. Materials Chemistry and Physics2002,75:131-135
[59]G.Fafilek. Voltammetry on BICUVOX.10 microsamples [J]. Solid State Ionics, 1998,(113-115):623-629
[60]Yanhai Du, N.M.Sammes, GA. Tompsett, et al. Phase stability of bismuth lead antimony oxide [J].Solid State Ionics 1999,(117):291-299
[61]Shaowen Zha, Jigui Cheng, YanLiu, et al. Electrical properties of pure and Sr doped bismuth Bi_2Al_4O_9 ceramics[J].Solid State Ionics,2003,(156): 197-200
[62]Jan-Dierk Grunwaldt, Manuel D.Wildberger,Tamas Mallat, and Alfons Baiker. Unusual redox properties of bismuth in Sol-Gel Bi-Mo-Ti mixed oxides [J], Journal of Catalysis, 1998,( 177):53-59
[63] Johnson, Peter K. Ultrafine powder technology[J].International Journal of Powder Metallurgy [J]. 2004,40(1): 9-11
[64]Won, H.I. Combustion synthesis of ultrafine tungsten carbide powder Journal of Materials Research[J]. 2008, 23( 9):2393-2397
[65]Sidorova, E.N. , Dzidziguri, E.L., Levina, V.V..Formation of an ultrafine nickel powder[J].Russian Metallurgy,2007,( 6): 469-472
[66]Ibaseta, Nelson , Climent, Eric, Biscans, Batrice.SFGP 2007 - Ultrafine aerosol generation from free falling nanopowders: Experiments and numerical modelling[J]. International Journal of Chemical Reactor Engineering, 2008,(6):24
[67] Song, Jae-Sung, Kim, Hyun-Ju. Photonic decomposition of ultrafine, rutile phased TiO_2 powder in aqueous 4-chlorophenol solutions[J]. Smart Materials and Structures, 2006,15(11):65-73
[68]Yakubovskaya, S.V.,Kul'bitskaya, L.V..Effect of composition of combined sensitization/activation solutions on chemical deposition of Cu-TiO_2 ultrafine-grained composite coatings on diamond powders[J].Russian Journal of Inorganic Chemistry,2008,53(12):1834-1839
[69]Wu,Songping.Preparation of fine copper powder using ascorbic acid as reducing agent and its application in MLCC Source[J].Materials Letters,2007,61(4-5):1125-1129
[70]Wu,Songping.Preparation of fine copper powder with chemical reduction method and its application in MLCC IEEE[J].Transactions on Advanced Packaging,2007,30(3):434-438
[71]张克,李良果,王洪友.超细粉体的性质、制备及其对工程学科的影响[J].中国粉体技术,1998,4(6):35-38
[72]万朴,董发勤,彭同江,等.超细粉体的应用及超细后果效应[J],非金属矿,1999年6月,22(增刊):74-76
[73]Zhang,Hui,Zhu,Jesse Ultrafine powder coatings,an innovation for the coating industry[J].2006 AIChE Spring National Meeting - 5th World Congress on Particle Technology,2006:5
[74]Mei,L.,Li,J.-T.Combustion synthesis of ultrafine magnesium nitride powder by Ar dilution[J].Scripta Materialia,2009,60(3):141-143
[75]Liu,Wenbin,Song,Xiaoyan,Zhang,Jiuxing.Preparation of ultrafine WC-Co composite powder by in situ reduction and carbonization reactions [J].International Journal of Refractory Metals and Hard Materials,2009,27(1):115-120
[76]Shi,Xiaoliang,Yang,Hua;Shao,Gangqin.Oxidation of ultrafine-cemented carbide prepared from nanocrystalline WC-10Co composite powder[J].Ceramics International,2008,34(8):2043-2049
[77]Zhan,Lu,Xu,Zhenming.Application of vacuum metallurgy to separate puremetal from mixed metallic particles of crushed waste printed circuit board scraps[J].Environmental Science and Technology,2008,42(20):7676-7681
[78]Zhao Li-Dong,Zhang Bo-Ping,Liu Wei-Shu.Enhanced thermoelectric properties of bismuth sulfide polycrystals prepared by mechanical alloying and spark plasma sintering[J].Journal of Solid State Chemistry,2008,181(12):3278-3282
[79]Kim,Daniel,Wang,Shijie.Bismuth recovery from hydrochloric acid solution [J].Canadian Metallurgical Quarterly,2008,47(3):317-326
[80]He Qiuxing,Tu Weiping;Hu Jianqing.Elimination of hard aggregation of bismuth-doped tin dioxide nanometer powders prepared by wet chemical method[J].Huagong Xuebao/Journal of Chemical Industry and Engineering,2006,57(6):1490-1495
[81]Ren Wei,Liu Xuequan,Wang Xiaolin.Thermoelectric properties of bismuth telluride based materials prepared by powder metallurgy processing[J].Key Engineering Materials,2007,336-338(Ⅰ):864-867
[82]Kondo,Masatoshi.Metallurgical analysis of a tube ruptured in the lead bismuth corrosion test facility[J].Journal of Nuclear Science and Technology,2006,43(2):174-178
[83]郑波,任志刚,童剑英,等.电化学方法制备超细氧化铋粉末[J].化学研究与应用,2004,16(3):411-412
[84]Beauchemin,S.,Chen,T.T..Behaviour of antimony and bismuth in copper electrorefining circuits[J].Canadian Metallurgical Quarterly,2008,47(1):9-25
[85]吴绍华,刘春艳,刘进,等.超细Bi_2O_3粉体的制备研究现状[J],中国粉体技术,2005年第6期:37-41
[86]何伟明,甑强,潘庆谊,等.反向滴定法制备超细氧化铋粉体的研究[J],功能材料,2003,34(6):702-703
[87]肖政伟.超细氧化铋的制备.[长沙:中南大学硕士学位论文].2004.5
[88]He Qiu-Xing.Synthesis and characterization of bismuth-doped tin dioxide nanometer powders[J].Journal of Central South University of Technology,2006,13(5):519-524
[89]Shojaie-Bahaabad,M.Economical synthesis of nano alumina powder using an aqueous sol-gel method[J].Materials Letters,2008,62(19):3364-3366
[90]Rajabi-Zamani,A.H.,Behnamghader,A.,Kazemzadeh,A.Synthesis of nanocrystalline carbonated hydroxyapatite powder via nonalkoxide sol-gel method[J].Materials Science and Engineering C,2008,28(8):1326-1329
[91]Han Yuxian,Qiu,Tai,Song Tao.Preparation of ultrafine tungsten powder by sol-gel method.Journal of Materials Science and Technology,2008,24(5,):816-818
[92]Sopyan I.Synthesis of strontium-doped hydroxyapatite powder via sol-gel method[J].Advanced Materials Research,2008:928-931
[93]Lu Zhuofei,Li Yi,Zhang Xuejian.Synthesis of Er~(3+):YAG nanopowder by sol-gel combustion method Kuei Suan Jen Hsueh Pao[J].Journal of the Chinese Ceramic Society,2008,36(10):1454-1457
[94]Fathi M.H.,Hanifi A.Evaluation and characterization of nanostructure hydroxyapatite powder prepared by simple sol-gel method[J].Materials Letters,2007,61(18):3978-3983
[95]Barati M.R.The role of surfactant in synthesis of magnetic nanocrystalline powder of NiFe_2O_4 by sol-gel auto-combustion method[J].Journal of Non-Crystalline Solids,2008,354(47-51):5184-5185
[96]Kim Won-Jeong,Kim Sang Su.Structural and electrical properties of ferroelectric Bi_(3.4)Pr_(0.6)Ti_3O_(12) prepared by a sol-gel method Integrated Ferroelectrics,2006,81(1):105-111
[97]Weidong He,Wei Qin,Xiaohong,Wu.The photocatalytic properties of bismuth oxide films prepared through the sol-gel method[J].Thin Solid Films,2007,515(13):5362-5365
[98]Xiaohong Wu,Wei Qin,Weidong He.Thin bismuth oxide films prepared through the sol-gel method as photocatalyst[J].Journal of Molecular Catalysis A:Chemical,2007,261(2):167-171
[99]Weidong He,Wei Qin,Xiaohong Wu.Thin bismuth oxide films prepared through the sol-gel method[J].Materials Letters,2007,61(19-20):4100-4102
[100]Du Xianfeng,Xu,Youlong Ma,Hanxiao.Synthesis and characterization of bismuth titanate by an aqueous sol-gel method[J].Journal of the American Ceramic Society,2007,90(5):1382-1385
[101]Roger F,Bel T.Hydrothermal ruby:Infrared spectra and X-Ray topography[J].Communications,1967,2:2688-2689
[102]ArmelaoL,ColomboP,FabrizioM.Synthesis of Bi_2O_3 and Bi_4(SiO_4)_3 thin films by the sol-gel method[J].J Sol-Gel Sci Technol,1998,13(1,2,3):213-217
[103]Sun Y.H.,Liu X.B.,Chen Min.Study on ferroelectric properties of Nd-doped Bl_4Ti_3O_(12) thin films prepared by sol-gel method[J].Key Engineering Materials,2007,336-338(Ⅰ):146-148
[104]Guo Dongyun,Li Meiya,Wang Jing.Ferroelectric properties of Bi_(3.6)Ho_(0.4)Ti_3O_(12)thin films prepared by sol-gel method[J].Applied Physics Letters,2007,91(23):232905
[105]Kao M.C.,Chen H.Z.,Young,S.L.Ferroelectfic properties and leakage current mechanisms of Bi_(3.25)La_(0.75)Ti_3O_(12) thin films with a-axis preferred orientation prepared by sol-gel method[J].Materials Letters,2008,62(4-5):629-632
[106]陈代荣,谢经雷,李博,等.Bi(OR)_3作前驱体合成Bi_2O_3微粉 (R:CH_2CH_2OCH_3,CMe_2Et)[J].山东大学学报(自然科学版),1997,32(1):88-93
[107]Moulay,Saad.Microemulsion breakdown by pervaporation technique:Effect of the alkyl chain length of n-alkanol,a cosurfactant of the microemulsion[J].Journal of Colloid and Interface Science,2007,311(2):556-561
[108]Kogan,Anna,Popov Inna.Microemulsion-facilitated ccrystallization of carbamazepine[J].Journal of Dispersion Science and Technology,2007,28(7):1008-1019
[109]Teo,Boon M.,Ashokkumar,Muthupandian.Microemulsion polymerizations via high-frequency ultrasound irradiation[J].Journal of Physical Chemistry B,2008,112(17):5265-5267
[110]Pratap Amit P.,Bhowmick D.N.Pesticides as microemulsion formulations [J].Journal of Dispersion Science and Technology,2008,29(9):1325-1330
[111]Ho Beng S.,Tan Beng H..Inverse microemulsion polymerization of sterically stabilized polyamholyte microgels[J].Langmuir,2008,24(15):7698-7703
[112]Sarraguca,J.M.G.,Pais,A.A.C.C..Structure of microemulsion -ABA triblock copolymer networks Source[J].Langmuir,2008,24(19):11153-11163
[113]Purkayastha Arup,Kim,Seongyul.Molecularly protected bismuth telluride nanoparticles:Microemulsion synthesis and thermoelectric transport properties [J].Advanced Materials,2006,18(22):2958-2963
[114]Henle J.,Kaskel S.Preparation of photochromic transparent BiOX(X=Cl,I)/PLA nanocomposite materials via microemulsion polymerization[J].Journal of Materials Chemistry,2007,17(47):4964-4971
[115]Henle J.,Simon P..Nanosized BiOX(X=Cl,Br,I) particles synthesized in reverse microemulsions[J].Chemistry of Materials,2007,19(3):366-373
[116]Stubenrauch Cosima,Wielputz Thomas,Sottmann Thomas.Microemulsions as templates for the synthesis of metallic nanoparticles Colloids and Surfaces A[J].Physicochemical and Engineering Aspects,2008,317(1-3):328-338
[117]吴晓春,汤国庆,张桂兰,等.不同制备条件对纳米Bi_2O_3发光的影响[J].化学学报,1996,54:146-151
[118]Santana C.,Mahugo.Development of a solid-phase microextraction method with micellar desorption for the determination of chlorophenols in water samples[J].Journal of Chromatography A,2007,1140(1-2):13-20
[119]Guerrero,Enrique Duran,Chinnici Fabio.Solid-phase extraction method for determination of volatile compounds in traditional balsamic vinegar[J].Journal of Separation Science,2008,31(16-17):3030-3036
[120]Vinas Pilar,Campillo Natalia.Method development and validation for strobilurin fungicides in baby foods by solid-phase microextraction gas chromatography-mass spectrometry[J].Journal of Chromatography A,2009,1216(1):140-146
[121]LI Huizhi,ZHAI Yubo.Solid-phase extraction of trace Au(Ⅲ) with SDG and determination by the catalytic spectrophotometric method[J].Rare Metals,2008,27(6):560-565
[122]Azadmard-Damirchi,Sodeif,Dutta Paresh C.A single step solid-phase extraction method for complete separation of sterol oxidation products in food lipids[J].Journal of Chromatography A,2009,1216(1):36-42
[123]Donald F,Weirauch,Robert Kong.The hydrothermal growth of Al_2O_3 in HCl solutions[J].Journal of Growth,1972,19:139-140
[124]Wang Shengwei,Yang Zhanhong.Study of calcium zincate synthesized by solid-phase synthesis method without strong alkali[J].Materials Chemistry and Physics,2008,112(2);603-606
[125]Asadov M.M.,Akhmedly K.M.Calculation of some thermodynamic parameters of non-ideal solutions Diffusion and Defect Data Pt.B Solid State Phenomena[J].Solid Phase Transformations,2008,138:331-338
[126]Miro Manuel,Hartwell Supaporn Kradtap.Recent developments in automatic solid-phase extraction with renewable surfaces exploiting flow-based approaches TrAC-Trends[J].Analytical Chemistry,2008,27(9):749-761
[127]Suvardhan K.,Kumar K.,Suresh RekhaD..Preconcentration and solid-phase extraction of beryllium,lead,nickel,and bismuth from various water samples using 2-propylpiperidine-1-carbodithioate with flame atomic absorption spectrometry(FAAS)[J].Talanta,2006,68(3):735-740
[128]Rao Mannepalli M..Determination of bismuth in natural water samples by ICP-AES after preconcentration on dithiocarbamates-coated ambedite XAD-7International[J].Journal of Environmental Analytical Chemistry,2006,86(6):443-452
[129]李青文,李娟,夏熙.纳米Bi_2O_3微粒的固相合成及其电化学性能的研究[J].化学学报,1999,29:491-495
[130]陈建龙,罗元香,刘孝恒,等.室温固相法制备纳米氧化铋[J].材料导报,2003,17(7):82-83
[131]Ahn S.H.,Choi S.K.Hydrothermally fabricated epitaxial PbTiO_3 patterns patterned lithographically by etching in hydrothermal KOH solution[J].Applied Physics Letters,2008,93(11):113-102
[132]Morimoto,Masato,Nakagawa Hiroyuki.Hydrothermal extraction and hydrothermal gasification process for brown coal conversion Fuel,[J].The 9th China-Japan Symposium on Coal and C1 Chemistry,2008:546-551
[133]German Christopher R..Hydrothermal exploration with the Autonomous Benthic Explorer Deep-Sea Research Part Ⅰ[J].Oceanographic Research Papers,2008,55(2):203-219
[134]Yuksel Asli,Diono Wahyu.Hydrothermal electrolysis of organic contaminants AIChE Annual Meeting,Conference Proceedings[J].2007 AIChE Annual Meeting,2007:7
[135]Pei L.Z.Zhao H.S.,Yu H.Y.,Tan W.Hydrothermal deposition of silicon nanochains[J],e-Journal of Surface Science and Nanotechnology,2008,6(2):171-174
[136]Wang Yanxiang,Fan Xueyun,Sun Jian.Hydrothermal synthesis of phosphate-mediated ZnO nanosheets[J].Materials Letters,2009,63(3-4):350-352
[137]Tune Mehmet Sefik,Van Heiningen Adriaan R.P.Hydrothermal dissolution of mixed southern hardwoods[J].Holzforschung,2008,62(5):539-545
[138]Kojima Takashi,Yoshida Ikue.Effect of treatment conditions and titanium source on the hydrothermal synthesis of bismuth titanate particles[J].Journal of the European Ceramic Society,2009,ⅴ29(3):431-437
[139]Hongyan Miao,Min Dong;Guoqiang Tan.Hydrothermal preparation of bismuth titanate nanopowders[J].Key Engineering Materials,2007,336-338(Ⅰ):161-164
[140]杨群保,李永祥,殷庆瑞,等.Bi_2O_3晶须的水热合成研究[J].无机材料学报,2002,17(5):979-984
[141]Yu Jimmy C,Xu Anwu,Zhang Lizhi,et al.Synthesis and characterization of porous magnesium[J].Journal of Physical Chemistry B,2004,108(1):64-70
[142]Samy El-shall M,LiShou-tian.Synthesis of nanoparticles by a laser vaporization-controlled condensation technique[A].Proc SPIE-Int Soc Opt Eng [C],1997,3123:98-109
[143]ChernenkoI M,ChasovskiiKV,KatkovUE Stabilization of the δ-phase of Bi_2O_3films at300K[J].FizikaiKhimiyaTverdogoTila,2002,3(3):531-534
[144]Gangqiang Zhu,Hongyan Miao.Hydrothermal synthesis of potassium bismuth titanate nanoparticles[J].International Journal of Nanoscience,2006,5(4-5):663-669
[145]Chen Xinxiang,Cao Yanning,Zhang,Hanhui.Hydrothermal synthesis and characteristics of 3-D hydrated bismuth oxalate coordination polymers with open-channel structure[J].Journal of Solid State Chemistry,2008,181(5):1133-1140
[146]Tooth Blake,Brugger Joel.Modeling of gold scavenging by bismuth melts coexisting with hydrothermal fluids[J].Geology,2008,36(10):815-818
[147]Paraschiv Carmen,Jurca B..Synthesis of nanosized bismuth ferrite(BiFeO_3)by a combustion method starting from Fe(NO_3)_3[Closed Circle]9H_2O-Bi(NO_3)_3[Closed Circle]9H_2O-glycine or urea systems[J].Journal of Thermal Analysis and Calorimetry,2008,94(2):411-416
[148]Andrade de Jesus,Fabiane Alexsandra.Effect of pH on the production of dispersed Bi_4Ge_3O~(12) nanoparticles by combustion synthesis[J].Journal of the European Ceramic Society,2009,29(1):125-130
[149]Bellakki,Manjunath B..Solution-combustion synthesis of Bi_(1-x)Ln_xO_(1.5)(Ln=y and La-Yb) oxide ion conductors[J].Bulletin of Materials Science,2006,29(4):339-345
[150]Li J.B.,Rao G.H..Magnetic properties of Bi(Fe_(1-x)Cr_x)O_3 synthesized by a combustion method[J].Applied Physics Letters,2007,90(16):162513
[151]Schmidt Stephan,Beyer Steffen,Mittmann Stefan.High performance LPI-C/SiC combustion chamber and nozzle extension for next generation satellite engines [J].VDI Bedchte,2028:477-478
[152]Mercadelli lisa,Galassi Carmen.Sol-gel combustion synthesis of BNBT powders [J].Journal of Sol-Gel Science and Technology,2008,46(1):39-45
[153]陈世柱,尹志民.制备金属氧化物纳米粉的液雾燃烧工艺研究[J].材料科学与工程,1998,16(3):60-63
[154]ZhouNaijun,YinZhimin,ChenShizhu.Thermochemicstry and mechanism of process for preparation of powdered Bi2O_3 by melt-atomizing-combustion method[J].Trans Nonferrous MetSocChi-na,1997,7(3):113-117
[155]尹志民,陈世柱,潘青林,等.熔体雾化-燃烧法制备高纯三氧化二铋超细粉[J].中国有色金属学报,1994,4(4):62-64
[156]Sheng Hao,Yue Zhenxing.Synthesis of BiFeO_3-PbTiO_3 powders by sol-gel auto-combustion process[J].Key Engineering Materials,2005,280-283(Ⅰ):609-612
[157]Late L.,Thelin W.,Blekkan,E.A.Selective combustion of hydrogen in the presence of hydrocarbons:Part 2.Metal oxide based catalysts[J].Applied Catalysis A,2004,262(1):63-68
[158]Zanetti S.M.,Santiago E.I.,Bulhoes,L.O.S..Preparation and characterization of nanosized SrBi_2Nb_2O_9 powder by the combustion synthesis[J].Materials Letters,2003,57(19):2812-2816
[159]Lutz M dler,Sotiris E Pratsinis.Bismuth oxide nanoparticles by flame spray pyrolysis[J].JAmCeramSoc,2002,85(7):1713-1718
[160]Zhao Li-Dong,Zhang Bo-Ping,Liu Wei-Shu.Enhanced thermoelectric properties of bismuth sulfide polycrystals prepared by mechanical alloying and spark plasma sintering[J].Journal of Solid State Chemistry,2008,181(12):3278-3282
[161]Matsumoto Akihiro,Shiozaki Tadashi.Simultaneous determination of bismuth and tellurium in steels by high power nitrogen microwave induced plasma atomic emission spectrometry coupled with the hydride generation technique[J].Analytical and Bioanalytical Chemistry,2004,379(1):90-95
[162]Hao Junjie,Wang Xiaohui.Preparation of textured bismuth titanate ceramics using spark plasma sintering[J].Journal of the American Ceramic Society,2004,87(7):1404-1406
[163]Duan Xingkai,Yang Junyou.Synthesis of Bi_2Te_3 nanopowders by vacuum arc plasma evaporation[J].Powder Technology,2007,172(2):63-66
[164]Kan Yanmei,Wang Peiling,Xu Tao.Spark plasma sintering of bismuth titanate ceramics[J].Journal of the American Ceramic Society,2005,88(6):1631-1633
[165]Wan Li,Cui Zuo-Lin,Zhang Zhi-Kun.Bi nanoparticles and Bi_2O_3 nanorods formed by thermal plasma and heat treatment[J].Surface and Coatings Technology,2007,201(9-11):5330-5332
[166]禹争光,杨邦朝,敬履伟.纳米氧化铋粉体的制备及对ZnO压敏电阻性能的影响[J].硅酸盐学报,2003,31(12):1184-1187
[167]LarinVK,Kondakov V M,Malyi E N,et al.Plasma-chemical method for preparation of nanosized of metal oxides and prospective trends in their application[J],Izvestiya Vysshikh Uchebnykh Zavedenii,Tsvetnaya Metallurgiya,2003,5:59-64
[168]JungkHO,FeldmannC.Polyol mediated synthesis of sub-micrometer Bi_2O_3 particles[J].Jmater Sci,2001,36:297-299
[169]段学臣,涂石桥.超细氧化铋的制备与结构特性[J],中南工业大学学报,1997(2):164-166
[170]孙璐薇,何永,付云德,等.纳米氧化铋研究[J],传感器技术,2000,19(1):21-22
[171]Hwang Gil-Ho,Han Won-Kyu,Park Joon-Shik.An electrochemical sensor based on the reduction of screen-printed bismuth oxide for the determination of trace lead and cadmium[J].Sensors and Actuators,2008,135(1):309-316
[172]夏兆泉,章广.矿产保护与利用[J].2000,(5):43-46
[173]许敏强.株冶铋冶炼技术的发展[J].有色冶炼,1993,(6):5-8
[174]王延岑.银锌渣提银工艺研究[J].有色冶炼,1991,(6):27-28,43
[175]汪立果.考察墨西哥托雷翁厂铋的回收[J].有色冶炼,1989,(2):39-41
[176]俞宗衡.从高铋含银渣中提取铋的试验研究[J].有色金属(冶炼),1989,(3):13-15
[177]孔繁珍.从高砷含铋物料中回铋[J].湿法冶金,2000,19(3):54-58
[178]张小红,郑文裕.从高炉烟尘提取铋的研究[J].湿法冶金,1995,(1):42-44
[179]何从行.氧化铋渣综合回收试验研究[J].湖南有色金属,1995,11(2):39-41,64
[180]赖师祥,胡传璋.从高铅铋渣中综合回收有价金属的试验研究[J].有色冶炼,1994,(3):39-42
[181]秦毅红,王云燕,彭文杰.铋深加工产品的应用及其发展前景[J].世界有色金属,1998,(4):44-45
[182]赵源泽,朱建春,李琼洁,等.制取铋盐新工艺的研究[J].广东有色金属学报,1995,5(2):126-132
[183]李学金.氯氧铋湿法直接制取铋盐新工艺研究[J].湖南有色金属,2000,16(2):18-20,30
[184]唐冠中,杨新生,许秀莲.从氯氧化铋制取高纯度铋化工产品的研究[J].有色金属(冶炼),1995,(2):9-11,27
[185]杨新生.从氯氧化铋制取高纯度铋化工产品的热力学分析与试验[J].江西冶金,1994,14(2):16-19
[186]朱建春,赵源泽,李琼洁.应用微机绘制电位-pH图分析氯氧化铋精矿提纯工艺[J].广东有色金属学报,1995,5(1):50-57
[187]康云川,粱汉贤,李月秀.氧化铋制取工艺的研究[J].云南师范大学学报,1994,14(3):58-60
[188]康云川,粱汉贤,李月秀.氧化铋制取工艺的改进[J].云南化工,1995,(4):45,71
[189]段学臣,涂石桥.超细氧化铋的制备与结构特性[J].中南工业大学学 报,1997,28(2):164-166
[190]王云燕,秦毅红.新型无机黄色颜料[J].湖南化工,1999,29(1):13-15
[191]吕尔会.高铋阳极泥提铋新工艺[J].湖南化工,199,29(4):21-23
[192]李纯旺,王宝安.高银粗铋处理工艺的改进[J].有色冶炼,1995,(1):20-22
[193]陈名瑞.三氯化铁浸出法从钨细泥硫化矿中提取铋[J].矿产综合利用,1994,(5):20-23
[194]唐谟堂,鲁君乐.由柿竹园高硅含铍含氟铋精矿直接提取铋品[J].1995,26(2):186-190
[195]孙璐薇,何永,付云德,等.纳米氧化铋研究[J].传感器技术,2000,19(1):21-22
[196]李德良,黄念东,许中坚.超细高纯氧化铋的制备研究[J].2001,33(1):15-16
[197]许秀莲,唐冠中,杨新生.从铋氯化溶液中空气氧化除铁的研究[J].1994,8(1):35-38
[198]杨新生.盐酸浸出法处理高铋银锌渣[J].1994,14(4):32-33,42
[199]钟竹前,梅光贵.化学位图在湿法冶金和废水净化中的应用[M].湖南长沙:中南工业大学出版社,1986
[200]朱元保,沈子琛,张传福,等.电化学数据手册[M].湖南长沙:湖南科学技术出版社,1984
[201]叶大伦.实用无机物热力学数据手册[M].北京:冶金工业出版社,1981
[202]杨显万.高温水溶液热力学数据计算手册[M].北京:冶金工业出版社,1983
[203]K.6雅齐米尔斯基等.络合物的不稳定常数[M].北京:化学工业出版社,1960
[204]F.巴索洛等.无机反应机理-溶液中金属络合物的研究[M].北京:化学工业出版社,1987
[205]丁绪淮,谈道.工业结晶[M].北京:高等教育出版社,1989
[206]周祖康,顾惕人,马季铭.胶体化学基础[M].北京:北京大学出版社,1996
[207]Sugimoto T.Preparation of mono-dispersed colloidal particles[M].Adv.Colloidal & Interface Sci.,1987(28):65
[208]沈钟,王果庭.胶体与表面化学[M].化学工业出版社,1997
[209]姚允斌,解涛,高英敏.物理化学手册[M].上海:上海科学技术出版社,1985
[210]秦毅红,王云燕.Bi~(3+)-NO_3-H_2O系热力学平衡研究[J].中南工业大学学报,1999,30(5):497-500
[211]罗电宏,马荣骏.对超细粉末团聚问题的探讨[J].湿法冶金,2002,21(2):57-61
[212]Randolph A.d.,Larson M.A.Theory of particulate process[M],2~(na)Edition.1988by Academic Press,INC
[213]张克从,张乐惠.晶体生长科学与技术(上册)[M].北京:科学出版社,1997.253 -271
[214]宁桂玲,吕秉玲.纳米颗粒的干燥及其研究进展[J].化工进展,1996,5:22-25
[215]刘雪莲,许煜汾,范文元.共沸蒸馏法制备ZrO_2纳米晶微粉的研究[J].合肥工业大学学报,1998,21(5):43-47
[216]仲维卓,华素坤.纳米材料及其水热法制备(上)[J],上海化工,第23卷第11期:25-27
[217]Qunbao Yang,Yongxiang Li,Qingrui Yin,et al.Hydrothermal systhesis of bismuth oxide needles[J|.Materials Letters.55(2002):46-49
[218]李汶军,施尔畏,仲维卓,等.负离子配位多面体生长基元的理论模型与晶粒形貌[J].人工晶体学报,1999,28(2):117-125
[219]梅光贵,王德润,周敬元,王辉。湿法炼锌学[M].湖南长沙;中南大学出版社
[220]博崇说.有色冶金应用基础研究[M].湖面长沙;科学出版社,1993
[221]FERNANDES C,AVELINO A,FARELO F.Crystallization of xylitol from hydro-alcoholic solutions containing arabitol and adonitol[C].14th Int Symp Industrial Crystallization Cambridge.UK,1999:12-16
[222]Ernesto Acosta Mart'inez,Marco Giulietti,Joa O Batista de Almeida e Silva,Silas Derenzo.Kinetice of the xylitol crystallization in hydro-alcoholic solution[J],Chemical Engineering and Processing.47(2008)2157-2162.
[223]崔玉民,徐立杰.用光催化剂处理含亚硝酸盐废水的研究[J]工业水处理,2000,20(8):17-19
[224]Vania C.De Sousa,Marcio R.Morelli,Ruth H.G.Kiminami,Combustion process in the synthesis of Bi_2O_3-ZnO[J].Ceramicslnternational 2000,26:561-564.
[225]Szuhwee Ng.J.M.Xue,John Wang.Hight temperature piezoelectric strontium bismuth titanate from mechanical activation of mixedoxides[J].Materials Chemistry and Physics 2002,75:131-135.
[226]O.P.Thakur,Devendra Kumar,Om Parkash,et al.Electrical characterization of strontium titanate borosilicate glass ceramics system with bismuth oxide addition using impedance spectroscopy[J].Materials Chemistry and Physics 2003,78:751-759.
[227]Y.Zeng.Y.S.Lin.Stability and surface catalytic properties of fluorite-structured yttria-,and P2O5-doped bismuth oxide under reducing environment[J].Journal of Catalysis,1999,(182):30-36.
[228]N.M.Sammes.Bismuth based oxide electrolytes-structure and ionic conductivity [J].Journal of the European ceramic society,1999,19:
[229]马挺,应锡璋.超细改性Bi_2O_3的制备及其在抗栓医用聚氨酯材料中的应用[J].上海交通大学学报1999,33(2):219-221.
[230]Malinovskaya T D,Aparnev A I.Carbon monoxide semiconductor based on SnO_2-Bi_2O_3[J].Russian Journal of Applied Chemistry,2001,74(11):1 864-1867
[231]Hyuk-Joon Y,Clive R.Dielectric relaxation and microwave dielectric properties of Bi_2O_3-ZnO-Ta_2O_5 ceramics[J].Journal of Materials Research,2002,17(6):1502-1 506
[232]戴云,刘愚,张定宇等.电子工业用氧化铋生产工艺的开发与实践[J].云南冶金,2001,30(4):22-25
[233]Xia Changrong,Zhang Yuelan,Liu Meilin.Compo-site cathode based on yttria stabilized bismuth oxide for low-temperature solid oxide fuel cells[J].Applied Physics Letters,2003,82(6):901-903
[234]Rose-Noelle V,Edouard C.Oxide ion transport in bismuth-based materials[J].Materials Research Society Symposium Proceedings,2003,756:95-103
[235]沈能斌.以高铋银锌渣为原料制取超细氧化铋的工艺研究.[长沙:中南大学硕士论文]2006.6