双头型氨基酸衍生物在制备手性纳米材料中的应用
摘要
从2004年开始,手性介孔材料和螺旋材料由于其在手性催化,手性拆分以及手性光学材料等领域具有的潜在应用价值引起了越来越多的关注和研究。同时,模板法是合成有序纳米结构材料的重要方法,可以用来制备颗粒、线、管、棒等不同维度的纳米结构。为了得到理想的纳米结构,本文从以下方面进行了研究,首先,研究了两亲手性小分子在不同溶剂中的自组装形态;其次使用氯亚铂酸钾、有机硅烷、钛酸四异丙酯等为前躯体,利用三种不同类型的模板,分别用来合成铂的颗粒、管以及螺旋结构;合成氧化硅的螺旋纤维材料;合成二氧化钛的管状和螺旋结构。
Since 2004, chiral mesoporous materials and helical materials attract more and more attention because of their potential application in the fields of chiral catalysis、chiral separation and chiral optial materials. In the mean time, template method is one of the most important ways to synthesize ordered nanostructured materials, so that it can be used to prepare nanoparticles、nanospoints、nanowires、nanotubes and nanorods in different dimension. In order to gain ideal nanostructure, this thesis carried on the research from follow aspects, first, self-assembly behaviors of amphiphitic chiral micromolecule in different solvents were studies in this thesis. Then, using K2PtCl4, organosilane and titanium tetraisopropanolate as precursor and utilizing three different kinds of template to synthesize platonic particles, tubes and helical structure, prepare helical-fiber materials of silica and manufacture tubes and helical structure of titanium dioxide.
Since 2004, chiral mesoporous materials and helical materials attract more and more attention because of their potential application in the fields of chiral catalysis、chiral separation and chiral optial materials. In the mean time, template method is one of the most important ways to synthesize ordered nanostructured materials, so that it can be used to prepare nanoparticles、nanospoints、nanowires、nanotubes and nanorods in different dimension. In order to gain ideal nanostructure, this thesis carried on the research from follow aspects, first, self-assembly behaviors of amphiphitic chiral micromolecule in different solvents were studies in this thesis. Then, using K2PtCl4, organosilane and titanium tetraisopropanolate as precursor and utilizing three different kinds of template to synthesize platonic particles, tubes and helical structure, prepare helical-fiber materials of silica and manufacture tubes and helical structure of titanium dioxide.
引文
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