C/C复合材料的基体改性及其抗氧化研究
|
摘要
为了提高C/C复合材料的抗氧化、耐烧蚀性能，采用先驱体转化法(PIP)，以含氢聚硅氧烷为先驱体制备了C/C-SiC复合材料。本文对含氢聚硅氧烷的交联固化条件进行了研究，较佳条件为：含氢聚硅氧烷/二乙烯基苯的最佳配比为1/0.5；交联温度为250℃；裂解温度大于1550℃。裂解升温过程中链的断裂和重排主要发生300-800℃，在该温度段，升温速率较慢有利于提高陶瓷产率。密度为1.02、1.21、1.60、1.78g/cm3的C/C复合材料经4次致密化后，制得密度分别为1.24、1.36、1.69、1.84g/cm3的C/C-SiC复合材料，其SiC质量百分含量分别为15.78%、13.14%、5.28%、4.12%。
采用H2-O2焰烧蚀法测定了C/C-SiC复合材料的烧蚀率，结果显示：密度分别为1.24、1.36、1.69、1.84g/cm3的C/C-SiC复合材料的线烧蚀率分别为0.00311、0.00222、0.00167、0.00144mm/s，质量烧蚀率分别为0.87、0.58、0.56、0.16mg/s。SiC的加入明显地提高了材料的抗烧蚀性能。
对C/C-SiC复合材料在静态空气中进行了氧化实验。C/C-SiC复合材料的氧化失重率低于C/C复合材料，经800℃氧化30分钟后，1.84g/cm3的C/C-SiC复合材料的失重率是1.85g/cm3C/C复合材料的76.31%。SiC的加入明显地提高了材料的抗氧化性能。
为了在C/C复合材料基体中引入抗氧化耐烧蚀的难熔金属，本文首次采用电化学法以甲基三氯硅烷、烯丙基氯、环戊二烯和四氯化锆为原料合成合成了含有难熔金属Zr、含有双键的聚硅烷，经测定，含锆聚硅烷中Si、Zr的质量百分含量分别为48.81%、4.11%。
研究了含锆聚硅烷交联固化和裂解条件。含锆聚硅烷可以自交联，较佳的交联温度为300℃，其陶瓷产率为82.2%。热重-差热曲线分析表明，在裂解过程中，键的断裂与重排主要发生在400~800℃之间。
采用含锆聚硅烷作为浸渍剂，制备了C/C-ZrC-SiC多元陶瓷基复合材料。密度为1.28g/cm3的C/C复合材料经4次浸渍后得到为密度1.69g/cm3的C/C-ZrC-SiC复合材料，密度增加32.03%。
测定了1.69g/cm3的C/C-ZrC-SiC复合材料的烧蚀性能，其线烧蚀率为0.00211mm/s，质量烧蚀率为0.518mg/s。其线烧蚀率和质量烧蚀率分别相当于密度1.78g/cm3C/C复合材料的20.6%和31.57%。在C/C复合材料中引入ZrC-SiC复合陶瓷能明显提高C/C复合材料的抗氧化烧蚀性能。烧蚀后的形貌可明显分为烧蚀中心区、烧蚀过渡区、烧蚀边缘区，各区域的烧蚀机理不同。
C/C-ZrC-SiC复合材料在500-900℃条件下的氧化失重率低于C/C复合材料的失重率。在900℃氧化30分钟后，C/C-ZrC-SiC复合材料的氧化失重率是同密度C/C复合材料的80.73%。
从化学热力学和化学动力学方面分析了C/C-SiC复合材料和C/C-ZrC-SiC复合材料抗烧蚀、抗氧化机理：ZrC、SiC氧化的吉布斯自由能(ΔG)较低，优先于C氧化，在材料表面形成SiO2膜；另外，C/C-ZrC-SiC与C/C-SiC复合材料比C/C复合材料有更高的表观活化能。
The precursor infiltration and pyrolysis (PIP) method was used to prepareC/C-SiC composites with hydrogen-containing polysiloxane as precursor, in order toimprove the ablation resistance and oxidation resistance of the C/C composites. Thecross-linking conditions of hydrogen-containing polysiloxane were studied. The bestratio of hydrogen-containing polysiloxane and crosslinker divinylbenzene is1/0.5; thefavorable cross-linking temperature is250℃, and the pyrolysis temperature shouldbe higher than1550℃. In the pyrolysis process, the break and rearrangement of themolecular chains mainly happen at the temperature range of300-800℃. The slowheating rate is preferred to improve the ceramic yield.
C/C-SiC composites of1.24,1.36,1.69and1.84g/cm3were prepared through PIPmethod with hydrogen-containing polysiloxane as precursor, the density of the initialC/C composites was1.02,1.21,1.60and1.78g/cm3. After4times PIP process, thecontents of SiC of the above samples were15.78%,13.14%,5.28%and4.12%respectively.
The ablation rates of C/C-SiC composites and C/C composites were determinedwith H2-O2flame ablation method. The results demonstrated that: the linear ablationrates of C/C-SiC composites with density of1.24,1.36,1.69and1.84g/cm3were3.11,2.22,1.67and1.44μm/s respectively, and the mass ablation rates were0.87,0.58,0.56and0.16mg/s. The ablation rates were proved that the introduction of SiCappearently improves the ablation resistance of C/C composites.
The static air oxidation of C/C-SiC composites shows that the weight loss rates ofC/C-SiC composites with density of1.84g/cm3was76.3%that of C/C-SiCcomposites with density of1.85g/cm3. The fact proves that the addition of SiCsignificantly improves the oxidation resistance of C/C composites, Furthrmore, theanti-oxidation mechanism was analysed from the point of view of chemicalthermodynamics.
Zr-containing polysilane was synthesized for the first time throughelectrochemical method, in order to introduce the refractory metal elements into C/Ccomposites, methyl trichlorosilane allyl chloride, cyclopentadiene, and zirconiumtetrachloride was used. The product contains48.8%Si (Wt%) and4.11%Zr.
In the process, the crosslinking and pyrolysis condition of Zirconium-containingpolysilane was studied. the study of the crossling condition demonstrated that theZr-containing polysilane can cross-linked by itself, and the best cross-linkedtemperature is300℃, the highest ceramic yield is82.2%. Themogravimetrydifferential thermal curve analysis showed that the cleavage and rearrangement ofbond occur mainly between400~800℃.
The C/C-ZrC-SiC composites of1.69g/cm3were produced after PIP for4cycles,using Zr-containing polysilanes as ceramic precursor, the density of the initial C/Ccomposites was1.28g/cm3. The density was increased by32.03%.
The ablation property was measured with the H2-O2flame ablation method ofC/C-ZrC-SiC composites of1.69g/cm3, the linear ablation rate was2.11μm/s, andfor the mass ablation rate was0.518mg/s. The results showed that the addition of ZrCand SiC, to a great extent, can improve the anti-ablation properties of the C/Ccomposites. From the ablation morphology, the ablation surface can be divided into the central area, the transitional area and the rim area. The ablation mechanism indifferent regions was proposed.
The static air oxidation experiment was done to C/C-ZrC-SiC composites from500to900℃, which showed that the oxidational weight loss rate of C/C-ZrC-SiCcomposites was80.7%that of C/C composites after oxidation for30min at900℃.The additions of ZrC and SiC greatly improve the oxidation resistance of C/Ccomposites. The anti-oxidation mechanism was analyzed.
The anti-ablation and anti-oxidation mechanism of C/C-ZrC-SiC and C/C-SiCcomposites was analyzed from the perspective of chemical thermodynamics andchemical kinetics: Gibbs free energy(ΔG) of ZrC and SiC less than that of carbon, andthe oxidation of ZrC and SiC was prior to carbon, in addition, the apparent activationenergy of C/C-ZrC-SiC and C/C-SiC composites is greater than that of C/Ccomposites.
采用H2-O2焰烧蚀法测定了C/C-SiC复合材料的烧蚀率，结果显示：密度分别为1.24、1.36、1.69、1.84g/cm3的C/C-SiC复合材料的线烧蚀率分别为0.00311、0.00222、0.00167、0.00144mm/s，质量烧蚀率分别为0.87、0.58、0.56、0.16mg/s。SiC的加入明显地提高了材料的抗烧蚀性能。
对C/C-SiC复合材料在静态空气中进行了氧化实验。C/C-SiC复合材料的氧化失重率低于C/C复合材料，经800℃氧化30分钟后，1.84g/cm3的C/C-SiC复合材料的失重率是1.85g/cm3C/C复合材料的76.31%。SiC的加入明显地提高了材料的抗氧化性能。
为了在C/C复合材料基体中引入抗氧化耐烧蚀的难熔金属，本文首次采用电化学法以甲基三氯硅烷、烯丙基氯、环戊二烯和四氯化锆为原料合成合成了含有难熔金属Zr、含有双键的聚硅烷，经测定，含锆聚硅烷中Si、Zr的质量百分含量分别为48.81%、4.11%。
研究了含锆聚硅烷交联固化和裂解条件。含锆聚硅烷可以自交联，较佳的交联温度为300℃，其陶瓷产率为82.2%。热重-差热曲线分析表明，在裂解过程中，键的断裂与重排主要发生在400~800℃之间。
采用含锆聚硅烷作为浸渍剂，制备了C/C-ZrC-SiC多元陶瓷基复合材料。密度为1.28g/cm3的C/C复合材料经4次浸渍后得到为密度1.69g/cm3的C/C-ZrC-SiC复合材料，密度增加32.03%。
测定了1.69g/cm3的C/C-ZrC-SiC复合材料的烧蚀性能，其线烧蚀率为0.00211mm/s，质量烧蚀率为0.518mg/s。其线烧蚀率和质量烧蚀率分别相当于密度1.78g/cm3C/C复合材料的20.6%和31.57%。在C/C复合材料中引入ZrC-SiC复合陶瓷能明显提高C/C复合材料的抗氧化烧蚀性能。烧蚀后的形貌可明显分为烧蚀中心区、烧蚀过渡区、烧蚀边缘区，各区域的烧蚀机理不同。
C/C-ZrC-SiC复合材料在500-900℃条件下的氧化失重率低于C/C复合材料的失重率。在900℃氧化30分钟后，C/C-ZrC-SiC复合材料的氧化失重率是同密度C/C复合材料的80.73%。
从化学热力学和化学动力学方面分析了C/C-SiC复合材料和C/C-ZrC-SiC复合材料抗烧蚀、抗氧化机理：ZrC、SiC氧化的吉布斯自由能(ΔG)较低，优先于C氧化，在材料表面形成SiO2膜；另外，C/C-ZrC-SiC与C/C-SiC复合材料比C/C复合材料有更高的表观活化能。
The precursor infiltration and pyrolysis (PIP) method was used to prepareC/C-SiC composites with hydrogen-containing polysiloxane as precursor, in order toimprove the ablation resistance and oxidation resistance of the C/C composites. Thecross-linking conditions of hydrogen-containing polysiloxane were studied. The bestratio of hydrogen-containing polysiloxane and crosslinker divinylbenzene is1/0.5; thefavorable cross-linking temperature is250℃, and the pyrolysis temperature shouldbe higher than1550℃. In the pyrolysis process, the break and rearrangement of themolecular chains mainly happen at the temperature range of300-800℃. The slowheating rate is preferred to improve the ceramic yield.
C/C-SiC composites of1.24,1.36,1.69and1.84g/cm3were prepared through PIPmethod with hydrogen-containing polysiloxane as precursor, the density of the initialC/C composites was1.02,1.21,1.60and1.78g/cm3. After4times PIP process, thecontents of SiC of the above samples were15.78%,13.14%,5.28%and4.12%respectively.
The ablation rates of C/C-SiC composites and C/C composites were determinedwith H2-O2flame ablation method. The results demonstrated that: the linear ablationrates of C/C-SiC composites with density of1.24,1.36,1.69and1.84g/cm3were3.11,2.22,1.67and1.44μm/s respectively, and the mass ablation rates were0.87,0.58,0.56and0.16mg/s. The ablation rates were proved that the introduction of SiCappearently improves the ablation resistance of C/C composites.
The static air oxidation of C/C-SiC composites shows that the weight loss rates ofC/C-SiC composites with density of1.84g/cm3was76.3%that of C/C-SiCcomposites with density of1.85g/cm3. The fact proves that the addition of SiCsignificantly improves the oxidation resistance of C/C composites, Furthrmore, theanti-oxidation mechanism was analysed from the point of view of chemicalthermodynamics.
Zr-containing polysilane was synthesized for the first time throughelectrochemical method, in order to introduce the refractory metal elements into C/Ccomposites, methyl trichlorosilane allyl chloride, cyclopentadiene, and zirconiumtetrachloride was used. The product contains48.8%Si (Wt%) and4.11%Zr.
In the process, the crosslinking and pyrolysis condition of Zirconium-containingpolysilane was studied. the study of the crossling condition demonstrated that theZr-containing polysilane can cross-linked by itself, and the best cross-linkedtemperature is300℃, the highest ceramic yield is82.2%. Themogravimetrydifferential thermal curve analysis showed that the cleavage and rearrangement ofbond occur mainly between400~800℃.
The C/C-ZrC-SiC composites of1.69g/cm3were produced after PIP for4cycles,using Zr-containing polysilanes as ceramic precursor, the density of the initial C/Ccomposites was1.28g/cm3. The density was increased by32.03%.
The ablation property was measured with the H2-O2flame ablation method ofC/C-ZrC-SiC composites of1.69g/cm3, the linear ablation rate was2.11μm/s, andfor the mass ablation rate was0.518mg/s. The results showed that the addition of ZrCand SiC, to a great extent, can improve the anti-ablation properties of the C/Ccomposites. From the ablation morphology, the ablation surface can be divided into the central area, the transitional area and the rim area. The ablation mechanism indifferent regions was proposed.
The static air oxidation experiment was done to C/C-ZrC-SiC composites from500to900℃, which showed that the oxidational weight loss rate of C/C-ZrC-SiCcomposites was80.7%that of C/C composites after oxidation for30min at900℃.The additions of ZrC and SiC greatly improve the oxidation resistance of C/Ccomposites. The anti-oxidation mechanism was analyzed.
The anti-ablation and anti-oxidation mechanism of C/C-ZrC-SiC and C/C-SiCcomposites was analyzed from the perspective of chemical thermodynamics andchemical kinetics: Gibbs free energy(ΔG) of ZrC and SiC less than that of carbon, andthe oxidation of ZrC and SiC was prior to carbon, in addition, the apparent activationenergy of C/C-ZrC-SiC and C/C-SiC composites is greater than that of C/Ccomposites.
引文
[1] John D. Buckley. Carbon-Carbon, An Overview.[J]. American Ceramic SocietyBulletin,1988,67(2):364-368
[2] Brahney James H. Heat Means Stength [J]. Aerospace Engineering,1987,7(6):11-15
[3]孙晋良.纤维新材料[M].上海，上海大学出版社，2007
[4] G. Savage. Carbon-Carbon Composites,[M]. London.Chapman&Hall,1993
[5] J. E. Sheehan, K. W. Buesking, and B. J. Sullivan. Carbon-Carbon Composites[J]. Annual Review of Materials Science,1994,24:19-44
[6] Fitzer E., Lalit M. Manocha. Carbon Reinforcements and Carbon/carbonComposites [M]. Berlin, Spring,1998
[7] Stuart M. Lee. Handbook of Composite Reinforcements [M]. California. WileyVCH,1992
[8] Fitzer, E. Future of Carbon-Carbon Composites [J]. Carbon,1987,25(2):163-190
[9] John D. Buckley, Danny Dale Edie. Carbon-Carbon Materials and Composites[M]., New Jersey, Noyes Publications,1993
[10] Deborah D. L. Chung. Carbon Fiber Composites [M]. Butterworth-HeinemannPublicated,1994
[11]沈曾民.新型碳材料[M].化学工业出版社，北京，2003
[12] Colin R. Thomas. Essentials of Carbon-Carbon Composites [M]. Royal Societyof Chemistry,1993
[13] M. E. Westwood, J. D. Webster, R. J. Day, F. H. Hayes and R. Taylor.Oxidation Protection for Carbon Fibre Composites [J]. Journal of MaterialsScience1996,31(6):1389-1397
[14]罗瑞盈. C/C复合材料氧化及其防护性能研究[J].材料科学与工程，2000，8：7-10
[15] James E. Sheehan. Oxidation protection for carbon fiber composites [J].Carbon,1989,27(5):709-715
[16] T. Windhorst, G. Blount. Carbon-carbon composites: a summary of recentdevelopments and applications [J]. Materials&Design,1997,18(1):11-15
[17]宋桂明，周玉，黄玉金，雷廷权.固体火箭发动机喉衬材料[J].固体火箭技术，1998，21(2)：51-55
[18] J R Strife, J E Sheehan. Ceramic Coatings for Carbon-Carbon Composites [J].American Ceramic Society Bulletin,1988,67(2):369-374
[19] D.W. McKee. Oxidation Behavior and Protection of Carbon/Carboncomposites [J]. Carbon,1987,25(4):551-557
[20] D.W. McKee. Oxidation Behavior of Matrix-Inhibited Carbon/CarbonComposites [J]. Carbon,1988,26(5):659-664
[21] T. Sogabe, K. Nakajima and M. Inagaki. Effect Of Boron-Doping On Structureand Some Properties of Carbon-Carbon Composite J]. Journal of MaterialsScience,1996,31:6469-6476
[22] T. L. Dhami,O.P. Bahl, B.R. Awasthy. Oxidation-Resistant Carbon-CarbonComposites up to1700℃[J]. Carbon,1995,33(4):479-490
[23] S. Ragan, G. T. Emmerson. The Effect of Heat-Treatment Temperature uponthe Properties of Matrix-Inhibited Carbon-Carbon composites [J]. Carbon,1992,30(3):339-344
[24] L. Weiming, D. D. L. Chung. Oxidation Protection of Carbon Materials byAcid Phosphate Impregnation [J]. Carbon,2002,40:1249-1254
[25] L.M. Manocha, Satish M. Manocha. Studies on Solution-Derived CeramicCoatings for Oxidation Protection of Carbon-Carboncomposites.[J]. Carbon,1995,33(4):435-440
[26] Y.C. Zhu, S. Ohtani, Y. Sato, N. Iwamoto. The Improvement in OxidationResistance of CVD-SiC Coated C/C Composites by Silicon InfiltrationPretreatment [J]. Carbon,1998,36(7-8):929-935
[27] Manocha L M.. Studies on Solution-Derived Ceramic Coating for OxidationProtection of Carbon-Carbon Composites [J]. Carbon,1995,33(4):435-440.
[28] C. Friedrich, R. Gadow, M. Speicher. Protective Multilayer Coatings forCarbon-Carbon Composites [J]. Surface and Coatings Technology,2002,151-152:405-411
[29] Y. Deslandes, F-N. Sabir. Inhibition of Oxidation of Carbon Fibres by Sol-GelCoatings [J]. Journal of Materials Science Letters,1990,9:200-202
[30] YaoCan Zhu, S Ohtani, Y Sato. Formation of a functional gradient(Si3O4-SiC)/C layer for the Oxidation Protection Carbon-Carbon Composites[J]. Carbon,1999,37(9):1417-1423
[31] W. Kowbel, J. C. Withers. CVD and CVR Silicon-Based Functionally GradientCoatings on C/C Composites [J]. Carbon,1995,33(4):415-426
[32] Nathan S. Jacobson, Donald M. Curry. Oxidation Microstructure Studies ofReinforced Carbon/Carbon [J]. Carbon,2006,44(7):1142-1150
[33] Jian-Feng Huang, Qiang Yang, Ting Yang, Li-Yun Cao, Qin-Feng Zhang.Microstructure and Anti-Oxidation Property of Mullite Oxidation ProtectiveCoating Prepared by Hydrothermal Electrophoretic Deposition for SiC-C/CComposites [J]. Surface and Coatings Technology,2011,205(21-22):5077-5082
[34]. L.E. Jones, P.A. Thrower. Influence of Boron on Carbon Fiber Microstructure,Physical Properties and Oxidation Behavior [J].Carbon,1991,29:251-269
[35] Mandeep Kaur, Sandeep Kumar, P. R. Sengupta, V. Raman and G. Bhatia.Oxidation Behavior of Green Coke-Based Carbon–Ceramic CompositesIncorporating Micro-and Nano-Silicon Carbide [J]. Journal of MaterialsScience,2009,44(8):2128-2136
[36] Federico Smeacetto, Monica Ferraris, Milena Salvo. Multilayer Coating withSelf-sealing Properties for Carbon-Carbon Composites [J]. Carbon,2003,41(11):2105-2111
[37]胡兴华，吴明铂，查庆芳. C/C复合材料抗氧化研究进展[J].碳素，2006，127(3)：38-45
[38]曾燮榕，杨峥，李贺军，郑长卿.防止C/C复合材料氧化的MoSi2/SiC双相涂层系统的研究[J].航空学报，1997，18(4)：427-431
[39]成来飞,张立同.高温长寿命C/C防氧化复合梯度涂层的研究[J].高技术通讯,1996(5)：16-18
[40]李军，罗瑞盈，张仁钦.固渗+EB-PVD法制备C/C复合材料防氧化复合涂层研究[J].碳素技术，2007，26(3)：1-5
[41] N. I. Baklanova, T. M. Zima, A. V. Utkin and A. T. Titov. Microstructure ofTaC Coatings on Carbon Fibers [J]. Inorganic Materials,2011,47(7):728-732
[42] Erica L. Corral, Luke S. Walker. Improved Ablation Resistance of C-CComposites Using Zirconium Diboride and Boron Carbide [J]. Journal of theEuropean Ceramic Society,2010,30(11):2357–2364
[43]何捍卫，周科朝，熊翔. C/C复合材料抗烧蚀TaC涂层的制备[J].稀有金属材料与工程，2004，33(5)：490-493
[44] NELoBiondo, LE Jones, AG Clare. Halogenated glass systems for theProtection of structural carbon-carbon composites [J]. Carbon,1995,33(4):499-508
[45]李建军，陈来，孙晋良，周春节，张家宝，任慕苏. C/C和C/C-SiC复合材料的氧化及烧蚀性能[J].上海大学学报（自然科学版），2005，11(1)：74-79
[46] N. I. Baklanova, V. N. Kulyukin, V. G. Kostrovsky, N. Z. Lyakhov, V. V.Terskikh, G. Yu Turkina, L. V. Zhilitskaya, O. G. Yarosh and M. G. Voronkov.High-Temperature Evolution of SiC/C Products Derived from PreceramicPolymers [J]. Journal of Materials Synthesis and Processing,1999,7(5):289-296
[47] J. M. Staehler and L.P. Zawada. Performance of Four Ceramic-MatrixComposite Divergent Flap Inserts Following Ground Testing on an F110Turbofan Engine [J]. Journal of the American Ceramic Society,2000,83(7):1727-1738
[48] R. John, L. P. Zawada, and J. L. Kroupa. Stresses due to TemperatureGradients in Ceramic-Matrix-Composite Aerospace Components [J]. Journalof the American Ceramic Society,1999,82(1):161-168
[49]郭伟明，肖汉宁，聂昆.碳毡/碳复合材料的氧化防护[J].碳素，2007，131(3)：29-32
[50] S. M. Gee, J. A. Little. Oxidation Behaviour and Protection of Carbon/CarbonComposites [J]. Journal of Materials Science,1991,26:1093-1100
[51] H. Hannache, J. M. Quenisset, R. Naslain and L. Heraud. Composite MaterialsMade From a Porous2D Carbon-Carbon Preform Densified with BoronNitride by Chemical Vapour Infiltration [J]. Journal of Materials Science,1984,19：202-212
[52] T. Sogabe, K. Nakajima, M. Inagaki. Effect of Boron-Doping on Structure andSome Properties of Carbon-Carbon Composite [J]. Journal of Materials Science,1996,31:6469-6476
[53]崔红，李瑞珍，苏君明，李贺军，康沫狂.多元基体抗烧蚀C/C复合材料的微观结构分析[J].固体火箭技术，2001，24(3)：63-67
[54]闫桂沈，王俊，苏君明，李贺军，郝志彪.难熔金属碳化物改性基体对C/C复合材料抗氧化性能的影响[J].碳素，2003，114(2)：3-6
[55]王俊山，李仲平，敖明，许正辉，刘朗，胡子君，彭维周.掺杂难熔金属碳化物对C/C复合材料烧蚀机理的影响[J].新型碳材料，2005：21(2)：9-13
[56] N. I. Baklanova, T. M. Zima, A. T. Titov, T. M. Naimushina and V. P.Berveno.Microstructure and Strength of Carbon Fibers Surface-Modified withTitanium Carbide[J]. Inorganic Materials,2008,44(2):121-128
[57]邓景屹，刘文川，杜海峰，成会明，李依依. C/C-SiC梯度基复合材料氧化行为研究[J].硅酸盐学报，1999，27(3)：357-361
[58] F Lamouroux, X. Bourrat, R. Naslain and J. Thebault Silicon CarbideInfiltration of Porous C-C Composites for Improving Oxidation Resistance [J].Carbon,1995,33(4):525-535
[59] W. Krenkel, F. Berndt. C/C–SiC Composites for Space Applications andAdvanced Friction Systems [J]. Materials Science and Engineering: A,2005,412(1–2):177–181
[60]崔红，李瑞珍，苏君明，李贺军，康沫狂.添加难熔金属碳化物提高C/C复合材料抗烧蚀性能的研究[J].西北工业大学学报，2000，18（4）：669-673
[61]赵磊.添加碳化钽炭_炭复合材料的制备及其性能研究[D].长沙.中南大学硕士论文，2007
[62]罗瑞盈，金志浩.添加剂对快速CVD抗氧化C/C复合材料力学性能影响[J].无机材料学报，1997，12(4)：627-631
[63]王毅，徐永东，张立同，成来飞.液相先驱体制备C/C-TaC复合材料[J].固体火箭技术，2007,30(6)：541-543
[64]闫联生，崔红，李克智，李贺军，王涛，宋麦丽.碳纤维针刺预制体增强复合材料的制备与性能研究[J].无机材料学报，2008,23(2)：223-228
[65]王林山，熊翔，肖鹏，任芸芸.反应熔渗法制备C/C-SiC复合材料及其影响因素的研究进展[J].粉末冶金材料科学与工程，2002,21(1)：37-41
[66]孙万昌，李贺军，陈三平，张守阳. C/C复合材料快速CVI致密化技术研究进展[J].材料导报,2001,15(12)：43-45
[67] Walter Krenkel. Ceramic Matrix Composites: Fiber Reinforced Ceramics andTheir Applications [M]. Wiley VCH, weinheim,2008
[68]韩秀峰.碳改性C/SiC复合材料的结构与性能[D].西安.西北工业大学硕士论文，2006
[69]陈曼华. PIP工艺制备陶瓷基复合材料中先驱体的交联固化研究[D].长沙.国防科学技术大学博士学位论文，2005
[70]马青松.聚硅氧烷先驱体转化制备陶瓷基复合材料研究[D].长沙.国防科学技术大学博士学位论文，2003
[71]杜红娜.先驱体转化法制备C/C-SiC复合材料的研究[D].西安.西北工业大学硕士论文，2006
[72] Fitzer, E. The Future of Carbon-Carbon Composites [J]. Carbon.,1987,25(2):163-190
[73]王毅，徐永东，张立同，成来飞.液相先驱体制备C/C-TaC复合材料[J].固体火箭技术，2007，21（6）：541-543
[74]石岳，刘辉，迟伟东，沈曾民.液相先驱体转化法制备锆掺杂C-C复合材料的研究[J].耐火材料，2010，44(5)：345-350
[75]李淑萍，李克智，郭领军，和永岗. HfC改性C/C复合材料整体喉衬的烧蚀性能研究[J].无机材料学报，2008，23(6)：1155-1158
[76]益小苏，杜善义，张立同主编.中国材料工程大典-复合材料卷[M].北京:化学工业出版社,2006
[77] Hasegawa T., Iwasa Y., Koda T., Kishida H., Tokura Y., Wada S., Tashiro H.,Tachibana H., Matsumoto M., Miller R. D. Nonlinear Optical Spectroscopyon Polysilanes: Dependence of Exciton States on Polymer BackboneConformations [J]. Synthetic Metals,1995,71:1679-1680
[78]楚增勇.聚硅烷的奇异特性及其应用[J].有机硅材料,2000,14(4):25-28
[79]李光亮.有机硅高分子化学[M].科学出版社，北京，1999
[80]幸松民，王一璐编著.有机硅合成工艺及产品应用[M].北京，化学工业出版社，北京，2000
[81]李建军，陈来，孙晋良，周春节，张家宝，任慕苏. C/C和C/C-SiC复合材料的氧化及烧蚀性能[J].上海大学学报(自然科学版)，2003，11(1)：74-79
[82]王光信，张积树.有机电合成导论[M].化学工业出版社，北京，1997
[83] Shigenori Kashimura, Manabu Ishifune, Natsuki Yamashita, Hang-Bom Bu,Masakatsu Takebayashi, Satsuki Kitajima, Daisuke Yoshiwara, Yasuki Kataoka,Ryoichi Nishida, Shin-ichi Kawasaki, Hiroaki Murase, and Tatsuya Sho.Electroreductive Synthesis of Polysilanes, Polygermanes and Related Polymerswith Magnesium Electrodes [J]. Journal of Organic Chemistry,1999,64(18):6615-6621
[84] Atsutaka Kunai, Takafumi Ueda, Eiji Toyoda and Mitsuo Ishikawa.Electrochemical Reduction of Dichlorosilanes in the Presence of2,3-Dimethylbutadiene [J]. Bulletin of the Chemical Society of Japan,1994,67(1):287-289.
[85] Lori A. Vermeulen, Kevin Smith and Jiabin Wang. ElectrochemicalPolymerization of Alkyltri-chlorosilane monomers to Form Branched SiBackbone Polymers [J]. Electrochimica Acta,1999,45(7):1007-1014
[86] Mitsutoshi Okano, Hirokuni Fukai, Makoto Arakawa and Hiroshi Hamano.Electrochemical Synthesis of Network Polygermanes and Polysilanes [J].Electrochemistry Communications,1999,1(6):223-226
[87] Mitsutoshi Okano, Ken-ichi Takeda, Takeshi Toriumi and Hiroshi Hamano.Electrochemical Synthesis of Polygermanes [J]. Electrochimica Acta,1998,44(4):659-666
[88] Mitsutoshi Okano, Takeshi Toriumi, Hiroshi Hamano. Electrochemicalsynthesis of Germane-Germane and Germane-Silane Copolymers [J].Electrochimica Acta,1999,44(20):3475-3482
[89] Shigenori Kashimura, Manabu Ishifune, Hang-Bom Bu, MasakatsuTakebayashi, Satsuki Kitajima, Daisuke Yoshihara, Ryoichi Nishida, Shin-ichiKawasaki, Hiroaki Murase and Tatsuya Shono. Electroreductive Synthesis ofsome Functionalized polysilanes and Related Polymers [J]. TetrahedronLetters,1997,38(26):4607-4610
[90] Tanik Y.日本公开特许.08,255,484.1993
[91] Carole Moreau, Francüoise Serein-Spirau, Michel Bordeau. ElectrochemicalSynthesis of Functional Aryl-and Heteroarylchlorosilanes. Application to thePreparation of Donor-Acceptor or Donor-Donor OrganosiliconMolecules [J].Organometallics2001,20:1910-1917
[92] Amberger E, Salazar R W G. Mixed Organometallic Compounds of Group VI:Synthese, Properties and Addition Reaction [J]. Macromolecule,1985,18:2349-2354
[93]郭爱青.含Sb聚硅烷合成及性能研究[D].长沙：湖南师范大学硕士学位论文，2004
[94]邢欣，刘琳，李效东，王海哲.侧链含锑聚硅烷的合成与性能研究[J].国防科技大学学报，2008,30(3)：15-20
[95] M. Elangovan, A. Muthukumaran, M. Anbu Kulandainathan. NovelElectrochemical Synthesis and Characterisation of poly(methyl vinylsilane) andits co-polymers [J]. European Polymer Journal,2005,41:2450-2460
[96]郭玉明，冯志海，王金明.高性能PAN基碳纤维及其复合材料在航天领域的应用[J].高科技纤维与应用,2007,32(5):1-7
[97]西田亮一，村濑裕明.聚硅烷及其制造方法[P].中国专利号98801634.6
[98]西田亮一，川崎真一，村濑裕明.聚硅烷类的制造方法[P].中国专利号97180726.
[99]吴市，陈来，张峰君，范雪骐，任慕苏，孙晋良.电化学合成的含双键聚硅烷[J].高分子材料科学与工程，2007，23(5)：64-66
[100]吴市，陈来，钱林，张家宝，潘健峰，周春节，任慕苏，孙晋良.先驱体浸渗裂解法制备C/C-SiC复合材料的烧蚀性能[J].硅酸盐学报，2008，37(7)：973-977
[1] R. W. Rice. Ceramics from Polymer Pyrolysis, Opportunities and Needs-A MaterialsPerspective [J]. American Ceramic Society Bulletin,1983,62:889-892
[2] P. Colombo, G. Mera, R. Riedel, G.D. Sorarù. Polymer-Derived Ceramics:40Years ofResearch and Innovation in Advanced Ceramics [J]. Journal of the American CeramicSociety,2010,93:1805-1837
[3] K. J. Wynne, R.W. Rice. Ceramics via Polymer Pyrolysis [J]. Annual Review ofMaterials Research,1984,14:297-334
[4] Dong Mei Zhu, Hong Na Du, Fa Luo, Wan Cheng Zhou. Fabrication andCharacteristics of Carbon Fiber Reinforced C–SiC Dual Matrix Composites [J].Advances in Composite Materials and Structures,2007,334-335:145-148
[5] R. M. Rocha, C. A. A. Cairo, M.L.A. Gra a. Formation of Carbon Fiber-ReinforcedCeramic Matrix Composites with Polysiloxane/Silicon Derived Matrix [J]. MaterialsScience and Engineering: A.2006,437(2):268-273
[6] A. G. Odeshi, H. Mucha, B. Wielage. Manufacture and Characterisation of A Low CostCarbon Fibre Reinforced C/SiC Dual Matrix Composite [J].Carbon,2006,44(10):1994-2001
[7]幸松民，王一璐.有机硅合成工艺及产品应用[M].北京，化学工业出版社，2000[8] Yuxi Yu, Jinhua Tai, Xueyuan Tang, Yadi Guo, Ming Tang, Xiaodong Li. ContinuousSi–C–O–Al Fiber Derived from Aluminum-Containing Polycarbosilane Precursor [J].Composites: Part A,2008,39:1101-1105
[9] Schiavon, M. A., Radovanovic E. and Yoshida, I. V. P. Microstructural Characterizationof Monolithic Ceramic Matrix Composites from Polysiloxane and SiC Powder [J].Powder Technol.,2002,123:232-241
[10] Wei, Q., Pippel, E. Woltersdorf J., Scheffler M. and Greil P. Interfacial SiC Formationin Polysiloxane-Derived Si–O–C Ceramics [J]. Mater. Chem. Phys.,2002,73:281-289
[11] Hourlier D. B., Latournerie J. and Dempsey P. Reaction Pathways during the ThermalConversion of Polysiloxane Precursors into Oxycarbide Ceramics [J]. Journal of theEuropean Ceramic Society,2005,25:979-985
[12] Kleebe H. J., Turquat C. and Sorarù G. D. Phase-separation in an SiCO Glass Studiedby Transmission Electron Microscopy and Electron Energy-Loss Spectroscopy [J].Journal of the American Ceramic Society,2001,84:1073-1080
[13] C. Laffon, A. M. Flank, P. Lagarde, M. Laridjan, R. Hagege, P. Olry, J. Cotteret,J.L.Miquel, H. Hommel and A. P. Lagrand. Study of Nicalon-based Ceramic Fibresand Powders by EXAFS Spectrometry, X-Ray Diffractometry and Some AdditionalMethods.[J]. Journal of Materials Science,1989,24:1503-1512
[14] Kenji Kaneko, Ken-Ichi Kakimoto. HRTEM and ELNES Analysis of PolycarbosilaneDerived Si-C-O bulk Ceramics [J]. Journal of Non-Crystalline Solids,2000，270:181-190
[15] O. Delverdier, M. Monthioux, D. Mocaer, R. Pailler.Thermal behavior of polymer-derived ceramics. I. Si-C and Si-C-O Systems from both Commercial and NewPolycarbosilane (PCS) precursors [J]. Journal of the European Ceramic Society,1993,12:27-41
[16] E. Bouillon, F. Langlais, R. Pailler, R. Naslain, F. Cruege,J.C. Sarthou, A. Delpuech, C.La.on, P. Lagarde, M.Monthioux, A. Oberlin. Conversion Mechanisms of a Poly-carbosilane Precursor into an SiC-based Ceramic Material [J]. Journal of MaterialsScience,1991,26:1333-1345.
[17] T. Shimoo, K. Okamura M. Ito and Takeda M. High-Temperature Stability ofLow-Oxygen Silicon Carbide Fiber Heat-Treated under Different Atmosphere [J].Journal of Materials Science,2000,35(15):3733-3739
[18]马青松，陈朝晖，郑文伟，胡海峰.聚硅氧烷-二乙烯基苯的交联与裂解[J].国防科技大学学报，2001，23(5)：40-44
[19] Gregori G., Kleebe H.J., Blum Y. D. and Babonneaun F. Evolution of C-rich SiOCCeramics. Part II. Characterization by High Lateral Resolution Techniques: ElectronEnergy-Loss Spectroscopy, High-Resolution TEM and Energy-Filtered TEM [J].International Journal of Materials Research,2006,97:710-720
[20] Shimoo T., Tsukada I., Seguchi T., Okamura K. Effect of Firing Temperature on theThermal Stability of Low-Oxygen Silicon Carbide Fibers [J]. Journal of the AmericanCeramic Society,1998,81(8):2109-2115
[21]叶大伦.实用无机物热力学数据手册[M].冶金工业出版社，北京，1981
[1] John B. Wachtman Jr.J. R. Strife, J. J. Brennan, K. M. Prewo. Status of ContinuousFiber-Reinforced Ceramic Matrix Composite Processing Technology [J]. CeramicEngineering and Science Proceedings,1990,11(7-8):871-919
[2]郑春满，李效东，余煜玺，曹峰. SiC陶瓷纤维先驱体设计原则及合成研究进展[J].高分子材料科学与工程，2005,21(6):6-10
[3] A. Centeno, R. Santamaría, M. Granda, R. Menéndez, C. Blanco. Thermal Curing ofMesophase Pitch: an Alternative to Oxidative Stabilisation for The Development ofCarbon-Carboncomposites [J]. Journal of Analytical and Applied Pyrolysis,2009,86(1):28-32
[4] Dileep Singh, Dongming Zhu, Yanchun Zhou, Mrityunjay Singh,S. Le Ber, M.-A.Dourges, L. Maillé, R. Pailler, A. Guette. Ceramic Matrix Composites Densification byActive Filler Impregnation Followed by a P.I.P. Process [J]. Ceramic Transactions,2010,215:113-123
[5] R. M. Rocha, C. A. A. Cairo, M.L.A. Gra a. Formation of carbon fiber-reinforcedceramic matrix composites with polysiloxane/silicon derived matrix [J]. MaterialsScience and Engineering: A,2006,437(2):268-273.
[6] Dan Zhao, Haifeng Hu, Changrui Zhang, Yudi Zhang and Jun Wang. A Simple Way toPrepare Precursors for Zirconium Carbide [J]. Journal of Materials Science,2010,45(23):6401-6405
[7] Schiavon, M. A., K. J. Ciuffi, Yoshida V. P. Glasses in the SiOCN System Produced byPyrolysis of Polycyclic Silazane/Siloxane Networks [J]. Journal of Non-CrystallineSolids,2007,353(22-23):2280-2288
[8]薛宁娟，郝志彪，李瑞珍，谢瑞广.炭/炭复合材料抗氧化研究进展[J].材料导报，2003,17:229-232
[9] Yongsheng Liu, Litong Zhang, Laifei Cheng, Xin’gang Luan, Wenbin Yang, WeihuaZhang, Yongdong Xu, Qingfeng Zeng. Preparation and Oxidation Resistance of2DC/SiC Composites Modified by Partial Boron Carbide Self-Sealing Matrix [J].Materials Science and Engineering: A,2008,498(1-2):430-436
[10]实用化学手册编写组.实用化学手册[M].科学出版社，北京，2001
[11] GBT6730.9-2006铁矿石硅含量的测定硫酸亚铁铵还原-硅钼蓝分光光度
[12] Marco Antonio Schiavon, Eduardo Radovanovic, Inez Valeria Pagotto Yoshida.Microstructural Characterisation of Monolithic Ceramic Matrix Composites fromPolysiloxane and SiC Powder [J]. Powder Technology,2002,123:232–241
[13]马青松，陈朝晖，郑文伟，胡海峰.聚硅氧烷-二乙烯基苯的交联与裂解[J].国防科技大学学报，2001，23(5):40-44
[14] Marco Antonio Schiavon. Crystallization Behavior of Novel Silicon Boron OxycarbideGlasses [J]. Journal of the American Ceramic Society,2004,87(2):203-208
[15] Yuxi Yu, Jinhua Tai, Xueyuan Tang, Yadi Guo, Ming Tang, Xiaodong Li. ContinuousSi–C–O–Al Fiber Derived from Aluminum-Containing Polycarbosilane Precursor[J].Composites: Part A,2008,39:1101–1105
[1]闫联生,崔红,李克智,李贺军,王涛,宋麦丽.炭纤维针刺预制体增强C/SiC复合材料的制备与性能研究[J].无机材料学报，2008,23(2):223-228
[2]郭全贵，宋进仁，刘朗，张碧江. B4C-SiC/C复合材料高温自愈合抗氧化性能研究，Ⅱ.复合材料结构变化与其自愈合抗氧化相关性研究[J].新型碳材料，1998,13(2):5-10
[3]曹学强.热障涂层材料[M].科学出版社，北京，2001
[4]潘育松，徐永东，陈照峰，成来飞，张立同，熊党生.2D C/SiC复合材料烧蚀性能分析[J].兵器材料科学与工程，2006,29(1):17-20
[5]胡秀颖,王成国,王启芬,卢文博,王延相.聚丙烯腈基碳纤维皮芯结构的形成与演变[J].材料导报,2010,24(9):71-74
[6]李照谦,李贺军,曹翠微,李克智,张守阳,赵华. C/C复合材料ZrC/SiC抗烧蚀涂层性能研究,固体火箭技术，2011,34(1):105-108
[7]黄海明,杜善义,吴林志，王建新. C/C复合材料烧蚀性能分析[J].复合材料学报,2001,18(3):76–80
[8] Shen Xuetao, Li Kezhi, Li Hejun, Du Hongying, Cao Weifeng, Lan Fengtao.Microstructure and Ablation Properties of Zirconium Carbidedoped Carbon/CarbonComposites [J].Carbon,2010,48:344–351
[9]叶大伦.实用无机物热力学数据手册[M].冶金工业出版社，北京，1981
[10]实用化学手册编写组.实用化学手册[M].科学出版社，北京，2001
[11]傅献彩，沈文霞，姚天扬.物理化学[M].高等教育出版社，北京，1990
[12] J.Szekely，J.W.Evans， H.Y.Sohn.Gas-solidreactions [M].胡道和译.北京:中国建筑工业出版社，1986,12:8-34
[13] F. Lamouroux and R. Naslain. Kinetics and Mechanisms of Oxidation of2D WovenC/SiC ComPosite: Ⅱ: Theoretical Approach [J]. Journal of the American CeramicSociety，1994,77(8):2058-2068
[1] Gabriela Sacarescu, Rodinel Ardeleanu, Liviu Sacarescu, Mihaela Simionescu.Synthesis of polysilane-bis(salicyliden)ethylenediamine Ni(II) complex [J]. Journalof Organometallic Chemistry,2003,685:202-206
[2] Venkatasubbaiah Krishnan, Ravindranathan Bindu, Vadapalli Chandrasekhar andVaranasi S. R. Murthy. Single-Step Synthesis of Chemically Cross-LinkedPolysilastyrene and Its Conversion to_-Silicon Carbide [J]. Journal of the AmericanCeramic Society,2002,85(2):504–506
[3] Smith, T. L. US. Patent4,631,179, Dec.1986
[4] Hui Jung Wu, Leonard V. Interrante. Preparation of poly(dichlorosilaethylene) andpoly(silaethylene) via Ring-opening polymerization [J]. Macromolecules,1992,25(6):1840–1841
[5]钱林,陈来,田玲,吴市,张家宝,任慕苏,孙晋良.含双键聚硅烷的电化学合成[J].高分子材料科学与工程,2009,25(9):4-7
[6]洛阳耐火材料研究所.耐火材料化学分析[M].冶金工业出版社,1984
[7]幸松民，王一璐.有机硅合成工艺及产品应用[M].北京，化学工业出版社，,2000:211-212,818-823
[8]邓建平，史保川，廖学巍.聚甲基环戊二烯基硅烷及其共聚物的合成与表征[J].有机硅材料，2001，15(6)：1-5
[9]曾昭琼.有机化学[M].北京:高等教育出版社，1993:189-193
[10] Yutaka M, Yasushi K, Yoshihiko N. Polysilane Spherulites and their HighPhotolurninesence quantum Yields [J]. Journal of Polymer Science Part A: PolymerChemistry,1997,35:427-430
[11]邢欣，刘琳，李效东，王海哲.侧链含锑聚硅烷的合成与性能研究[J].国防科技大学学报,2008,30(3):15~20
[12]杨刚，高升，谷秋菊，徐南平.柱层析法纯化烯丙基硅烷[J].南京工业大学学报(自然科学版),2010,32(1):19-22
[13] Brian J. Grimmond, Nigam P. Rath, and Joyce Y. Corey. Enantiopure Siloxy-Functionalized Group4Metallocene Dichlorides. Synthesis, Characterization, andCatalytic Dehydropolymerization of PhSiH3[J]. Organometallics,2000,19,2975-2984
[14] Braunschweig J H, Koblinski C, Wang R M. Synthesis and Structure of the First [1]Boratitanocenophanes [J]. European Journal of Inorganic Chemistry,1999,69-73
[15] Bajgur C S, Tikkanen W, Petersen J L. Synthesis, Structural Characterization, andElectrochemistry of [1]Metallocenophane Complexes,[Si(alkyl)2(C5H4)2]MCl2, M=Ti,Zr [J] Inorganic Chemistry,1985,24:2539-2546
[16]张友杰，李念平.有机波普学教程[M].上海,华中师范大学出版社,1990:80-88
[17] Okano M, Takeda K, Toriumi T, Hamano H. Electrochemical Synthesis ofPolygermanes [J]. Electrochimica Acta,1998,44:659-666
[1] Kagawa, Y. and Goto, K. Notch. Sensitivity Of Two-Dimensional Woven SiC Fibre-Reinforced SiC Matrix Composite Fabricated by the Polymer Conversion Process [J].Journal of Materials Science Letters,1997,16:850-854
[2] Takeda, M., Kagawa, Y., Mitsuno, S., Imai, Y., and Ichikawa, J. Strength of aHi-NicalonTM/Silicon Carbide Matrix Composite Fabricated by the Multiple PolymerInfiltration Pyrolysis Process [J]. Journal of the American Ceramic Society,1999,82(6):1579-1581
[3] Mamiya, T., Kagawa, Y., Shioji, Y., Sato, M. and Yamamura, T. Tensile FractureBehavior and Strength of Surface-Modified SiTiCO Fiber Sic-Matrix MinicompositesFabricated by The PIP Process [J]. Journal of the American Ceramic Society,2000,83(2):433-435
[4] Takemi Yamamura, Toshihiro Ishikawa, Masaki Shibuya, Terumi Hisayuki andKiyohito Okamura. Development of a New Continuous Si-Ti-C-O Fibre Using anOrganometallic Polymer Precursor [J]. Journal of Materials Science,1988,23(7):2589-2594
[5] F. Babonneau and G. D. Soraru. Synthesis and Characterization of Si-Zr-C-O Ceramicsfrom Polymer Precursors [J]. Journal of the European Ceramic Society,1991,8:29-34
[6] K Suzuki, K Kumagawa, T Kamiyama, M. Shibuya. Characterization of theMedium-Range Structure of Si-Al-C-O, Si-Zr-C-O and Si-Al-C Tyranno Fibers bySmall Angle X-Ray Scattering [J]. Journal of Materials Science,2002,37:949-953
[7] E. Radovanovic, M.F. Gozzi, M.C. Gon alves, I.V.P. Yoshida. Silicon OxycarbideGlasses from Silicone Networks [J]. Journal of Non-Crystalline Solids,1999,248(1):37–48
[8] Robert Frind, Martin Oschatz and Stefan Kaskel. Polymerization of Polycarbosilanes inHigh Internal Phase Emulsions for the Synthesis of Macroporous Silicon CarbideCatalysts (polyHIPE-SiC)[J]. Journal of Materials Chemistry,2011,21:11936-11940
[9] G. D. Soraru, Florence Babonneau and J. D. Mackenzie. Structural Evolutions fromPolycarbosilane to SiC Ceramic [J]. Journal of Materials Science,1990,25(9):3886-3893
[10] Yuxi Yu, Jinhua Tai, Xueyuan Tang, Yadi Guo, Ming Tang, Xiaodong Li. ContinuousSi–C–O–Al Fiber Derived from Aluminum-Containing Polycarbosilane Precursor [J].Composites: Part A,2008,39:1101–1105
[11]李照谦,李贺军,曹翠微,李克智,张守阳,赵华. C/C复合材料ZrC/SiC抗烧蚀涂层性能研究[J].固体火箭技术,2011,34(1):105-108
[12]石岳,刘辉,迟伟东,沈曾民.锆掺杂C/C复合材料的制备及微观结构研究[J].热加工工艺,2010,39(20):83-90
[13]刘军，冯春祥，宋永才,薛金根.先驱体转化法制备碳化硅纤维[J].现代化工,2000,20(10):58-62
[14] T. Iseki, M. Narisawa, Y. Katase, K. Oka, T. Dohmaru, K. Okamura. An EfficientProcess of Cross-Linking Poly(Methylsilane) for SiC Ceramics [J]. Chemistry ofMaterials,2001,13(11):4163-4169
[1] James E. Sheehan. Oxidation protection for carbon fiber composites [J]. Carbon,1989,27(5):709-715
[2] C.G. Papakonstantinou， P. Balaguru， R.E. Lyon. Comparative Study of HighTemperature Composites [J]. Composites Part B: Engineering,2001,32(8):637-649
[3] J. S. Fischedick, J. Schmidt, R. Tamme, U. Kroner, J. Arnold, B. Zeiffer. OxidationBehaviour of C/C–SiC Coated with SiC-B4C-SiC-Cordierite Oxidation ProtectionSystem,[J]. Materials Science and Engineering A,2004,386:428-434
[4] X. Wu, L.R. Radovic. Inhibition of catalytic oxidation of carbon/carboncomposites byboron-doping [J]. Carbon,2005,43:1768-1777
[5] Yulei Zhang, Hejun Li, Xinfa Qiang, Kezhi Li. Oxidation Protective C/SiC/Si-SiCMultilayer Coating for Carbon/Carbon Composites Applying at1873K [J]. Journal ofMaterials Science&Technology,2010,26(12):1139-1142
[6] Feng Tao, Li He-Jun, Fu Qian-Gang, Zhang Yu-Lei, Shi Xiao-Hong. Microstructureand Anti-Oxidation Properties of Multi-Composition Ceramic Coatings forCarbon/Carbon Composites [J]. Ceramics International,2011,37(1):79-84
[7] Fu Qian-Gang, Li He-Jun, Shi Xiao-Hong, Li Ke-Zhi, Zhang Wei, Huang Min. A SiCWhisker-Toughened SiC-CrSi2Oxidation Protective Coating for Carbon/CarbonComposites [J]. Applied Surface Science,2007,253(8):3757-3760
[8] P. Lespade, N. Richet, P. Goursat. Oxidation resistance of HfB2–SiC Composites forProtection of Carbon-Based Materials [J]. Acta Astronautica,2007,60(10-11):858-864
[9] Tong Qingfeng, Shi Jingli, Song Yongzhong，Quangui Guo, Lang Liu. Resistance toAblation of Pitch-Derived ZrC/C composites [J]． Carbon，2004，42(12-13):2495-2500．
[10]宋桂明,武英,白厚善. TiC颗粒增强钨基复合材料的烧蚀性能[J].中国有色金属学报,2000,10(3):313-3l7
[11] J. F. Huang, B. Wang, H.J. Li, M. Liu, L.Y. Cao, C.Y. Yao. A MoSi2/SiC OxidationProtective Coating for Carbon/Carbon Composites [J]. Corrosion Science,2011,53:834-839.
[12] Wang C. R., Yang J.M., Hoffman W. Thermal Stability of Refractory Carbide/BorideComposites [J]. Materials Chemistry and Physics,2002,74:272-281
[13] GBT6730.9-2006铁矿石硅含量的测定硫酸亚铁铵还原-硅钼蓝分光光度
[14]叶大伦.实用无机物热力学数据手册[M].冶金工业出版社，北京，1981
[15] Penvecost J L. High Temperature Inorganic coatings [M]. New York: ReinholdPublishing Corp,1963
[16] Wu Shi, Chen Lai, Qian Lin, Zhang Jiabao, Pan Jianfeng, Zhou Chunjie, Ren Musu,Sun Jinliang. Ablation Properties of C/C-SiC Composite by the Precursor InfiltrationPyrolysis [J]. Journal of Chinese Ceramic society,2008,36(7):973-977
[17]宋桂明，王玉金，周玉，郭英奎，温广武. ZrCp/W复合材料的烧蚀性能.稀有金属材料与工程[J].2001,30（2）:101-104
[2] Brahney James H. Heat Means Stength [J]. Aerospace Engineering,1987,7(6):11-15
[3]孙晋良.纤维新材料[M].上海，上海大学出版社，2007
[4] G. Savage. Carbon-Carbon Composites,[M]. London.Chapman&Hall,1993
[5] J. E. Sheehan, K. W. Buesking, and B. J. Sullivan. Carbon-Carbon Composites[J]. Annual Review of Materials Science,1994,24:19-44
[6] Fitzer E., Lalit M. Manocha. Carbon Reinforcements and Carbon/carbonComposites [M]. Berlin, Spring,1998
[7] Stuart M. Lee. Handbook of Composite Reinforcements [M]. California. WileyVCH,1992
[8] Fitzer, E. Future of Carbon-Carbon Composites [J]. Carbon,1987,25(2):163-190
[9] John D. Buckley, Danny Dale Edie. Carbon-Carbon Materials and Composites[M]., New Jersey, Noyes Publications,1993
[10] Deborah D. L. Chung. Carbon Fiber Composites [M]. Butterworth-HeinemannPublicated,1994
[11]沈曾民.新型碳材料[M].化学工业出版社，北京，2003
[12] Colin R. Thomas. Essentials of Carbon-Carbon Composites [M]. Royal Societyof Chemistry,1993
[13] M. E. Westwood, J. D. Webster, R. J. Day, F. H. Hayes and R. Taylor.Oxidation Protection for Carbon Fibre Composites [J]. Journal of MaterialsScience1996,31(6):1389-1397
[14]罗瑞盈. C/C复合材料氧化及其防护性能研究[J].材料科学与工程，2000，8：7-10
[15] James E. Sheehan. Oxidation protection for carbon fiber composites [J].Carbon,1989,27(5):709-715
[16] T. Windhorst, G. Blount. Carbon-carbon composites: a summary of recentdevelopments and applications [J]. Materials&Design,1997,18(1):11-15
[17]宋桂明，周玉，黄玉金，雷廷权.固体火箭发动机喉衬材料[J].固体火箭技术，1998，21(2)：51-55
[18] J R Strife, J E Sheehan. Ceramic Coatings for Carbon-Carbon Composites [J].American Ceramic Society Bulletin,1988,67(2):369-374
[19] D.W. McKee. Oxidation Behavior and Protection of Carbon/Carboncomposites [J]. Carbon,1987,25(4):551-557
[20] D.W. McKee. Oxidation Behavior of Matrix-Inhibited Carbon/CarbonComposites [J]. Carbon,1988,26(5):659-664
[21] T. Sogabe, K. Nakajima and M. Inagaki. Effect Of Boron-Doping On Structureand Some Properties of Carbon-Carbon Composite J]. Journal of MaterialsScience,1996,31:6469-6476
[22] T. L. Dhami,O.P. Bahl, B.R. Awasthy. Oxidation-Resistant Carbon-CarbonComposites up to1700℃[J]. Carbon,1995,33(4):479-490
[23] S. Ragan, G. T. Emmerson. The Effect of Heat-Treatment Temperature uponthe Properties of Matrix-Inhibited Carbon-Carbon composites [J]. Carbon,1992,30(3):339-344
[24] L. Weiming, D. D. L. Chung. Oxidation Protection of Carbon Materials byAcid Phosphate Impregnation [J]. Carbon,2002,40:1249-1254
[25] L.M. Manocha, Satish M. Manocha. Studies on Solution-Derived CeramicCoatings for Oxidation Protection of Carbon-Carboncomposites.[J]. Carbon,1995,33(4):435-440
[26] Y.C. Zhu, S. Ohtani, Y. Sato, N. Iwamoto. The Improvement in OxidationResistance of CVD-SiC Coated C/C Composites by Silicon InfiltrationPretreatment [J]. Carbon,1998,36(7-8):929-935
[27] Manocha L M.. Studies on Solution-Derived Ceramic Coating for OxidationProtection of Carbon-Carbon Composites [J]. Carbon,1995,33(4):435-440.
[28] C. Friedrich, R. Gadow, M. Speicher. Protective Multilayer Coatings forCarbon-Carbon Composites [J]. Surface and Coatings Technology,2002,151-152:405-411
[29] Y. Deslandes, F-N. Sabir. Inhibition of Oxidation of Carbon Fibres by Sol-GelCoatings [J]. Journal of Materials Science Letters,1990,9:200-202
[30] YaoCan Zhu, S Ohtani, Y Sato. Formation of a functional gradient(Si3O4-SiC)/C layer for the Oxidation Protection Carbon-Carbon Composites[J]. Carbon,1999,37(9):1417-1423
[31] W. Kowbel, J. C. Withers. CVD and CVR Silicon-Based Functionally GradientCoatings on C/C Composites [J]. Carbon,1995,33(4):415-426
[32] Nathan S. Jacobson, Donald M. Curry. Oxidation Microstructure Studies ofReinforced Carbon/Carbon [J]. Carbon,2006,44(7):1142-1150
[33] Jian-Feng Huang, Qiang Yang, Ting Yang, Li-Yun Cao, Qin-Feng Zhang.Microstructure and Anti-Oxidation Property of Mullite Oxidation ProtectiveCoating Prepared by Hydrothermal Electrophoretic Deposition for SiC-C/CComposites [J]. Surface and Coatings Technology,2011,205(21-22):5077-5082
[34]. L.E. Jones, P.A. Thrower. Influence of Boron on Carbon Fiber Microstructure,Physical Properties and Oxidation Behavior [J].Carbon,1991,29:251-269
[35] Mandeep Kaur, Sandeep Kumar, P. R. Sengupta, V. Raman and G. Bhatia.Oxidation Behavior of Green Coke-Based Carbon–Ceramic CompositesIncorporating Micro-and Nano-Silicon Carbide [J]. Journal of MaterialsScience,2009,44(8):2128-2136
[36] Federico Smeacetto, Monica Ferraris, Milena Salvo. Multilayer Coating withSelf-sealing Properties for Carbon-Carbon Composites [J]. Carbon,2003,41(11):2105-2111
[37]胡兴华，吴明铂，查庆芳. C/C复合材料抗氧化研究进展[J].碳素，2006，127(3)：38-45
[38]曾燮榕，杨峥，李贺军，郑长卿.防止C/C复合材料氧化的MoSi2/SiC双相涂层系统的研究[J].航空学报，1997，18(4)：427-431
[39]成来飞,张立同.高温长寿命C/C防氧化复合梯度涂层的研究[J].高技术通讯,1996(5)：16-18
[40]李军，罗瑞盈，张仁钦.固渗+EB-PVD法制备C/C复合材料防氧化复合涂层研究[J].碳素技术，2007，26(3)：1-5
[41] N. I. Baklanova, T. M. Zima, A. V. Utkin and A. T. Titov. Microstructure ofTaC Coatings on Carbon Fibers [J]. Inorganic Materials,2011,47(7):728-732
[42] Erica L. Corral, Luke S. Walker. Improved Ablation Resistance of C-CComposites Using Zirconium Diboride and Boron Carbide [J]. Journal of theEuropean Ceramic Society,2010,30(11):2357–2364
[43]何捍卫，周科朝，熊翔. C/C复合材料抗烧蚀TaC涂层的制备[J].稀有金属材料与工程，2004，33(5)：490-493
[44] NELoBiondo, LE Jones, AG Clare. Halogenated glass systems for theProtection of structural carbon-carbon composites [J]. Carbon,1995,33(4):499-508
[45]李建军，陈来，孙晋良，周春节，张家宝，任慕苏. C/C和C/C-SiC复合材料的氧化及烧蚀性能[J].上海大学学报（自然科学版），2005，11(1)：74-79
[46] N. I. Baklanova, V. N. Kulyukin, V. G. Kostrovsky, N. Z. Lyakhov, V. V.Terskikh, G. Yu Turkina, L. V. Zhilitskaya, O. G. Yarosh and M. G. Voronkov.High-Temperature Evolution of SiC/C Products Derived from PreceramicPolymers [J]. Journal of Materials Synthesis and Processing,1999,7(5):289-296
[47] J. M. Staehler and L.P. Zawada. Performance of Four Ceramic-MatrixComposite Divergent Flap Inserts Following Ground Testing on an F110Turbofan Engine [J]. Journal of the American Ceramic Society,2000,83(7):1727-1738
[48] R. John, L. P. Zawada, and J. L. Kroupa. Stresses due to TemperatureGradients in Ceramic-Matrix-Composite Aerospace Components [J]. Journalof the American Ceramic Society,1999,82(1):161-168
[49]郭伟明，肖汉宁，聂昆.碳毡/碳复合材料的氧化防护[J].碳素，2007，131(3)：29-32
[50] S. M. Gee, J. A. Little. Oxidation Behaviour and Protection of Carbon/CarbonComposites [J]. Journal of Materials Science,1991,26:1093-1100
[51] H. Hannache, J. M. Quenisset, R. Naslain and L. Heraud. Composite MaterialsMade From a Porous2D Carbon-Carbon Preform Densified with BoronNitride by Chemical Vapour Infiltration [J]. Journal of Materials Science,1984,19：202-212
[52] T. Sogabe, K. Nakajima, M. Inagaki. Effect of Boron-Doping on Structure andSome Properties of Carbon-Carbon Composite [J]. Journal of Materials Science,1996,31:6469-6476
[53]崔红，李瑞珍，苏君明，李贺军，康沫狂.多元基体抗烧蚀C/C复合材料的微观结构分析[J].固体火箭技术，2001，24(3)：63-67
[54]闫桂沈，王俊，苏君明，李贺军，郝志彪.难熔金属碳化物改性基体对C/C复合材料抗氧化性能的影响[J].碳素，2003，114(2)：3-6
[55]王俊山，李仲平，敖明，许正辉，刘朗，胡子君，彭维周.掺杂难熔金属碳化物对C/C复合材料烧蚀机理的影响[J].新型碳材料，2005：21(2)：9-13
[56] N. I. Baklanova, T. M. Zima, A. T. Titov, T. M. Naimushina and V. P.Berveno.Microstructure and Strength of Carbon Fibers Surface-Modified withTitanium Carbide[J]. Inorganic Materials,2008,44(2):121-128
[57]邓景屹，刘文川，杜海峰，成会明，李依依. C/C-SiC梯度基复合材料氧化行为研究[J].硅酸盐学报，1999，27(3)：357-361
[58] F Lamouroux, X. Bourrat, R. Naslain and J. Thebault Silicon CarbideInfiltration of Porous C-C Composites for Improving Oxidation Resistance [J].Carbon,1995,33(4):525-535
[59] W. Krenkel, F. Berndt. C/C–SiC Composites for Space Applications andAdvanced Friction Systems [J]. Materials Science and Engineering: A,2005,412(1–2):177–181
[60]崔红，李瑞珍，苏君明，李贺军，康沫狂.添加难熔金属碳化物提高C/C复合材料抗烧蚀性能的研究[J].西北工业大学学报，2000，18（4）：669-673
[61]赵磊.添加碳化钽炭_炭复合材料的制备及其性能研究[D].长沙.中南大学硕士论文，2007
[62]罗瑞盈，金志浩.添加剂对快速CVD抗氧化C/C复合材料力学性能影响[J].无机材料学报，1997，12(4)：627-631
[63]王毅，徐永东，张立同，成来飞.液相先驱体制备C/C-TaC复合材料[J].固体火箭技术，2007,30(6)：541-543
[64]闫联生，崔红，李克智，李贺军，王涛，宋麦丽.碳纤维针刺预制体增强复合材料的制备与性能研究[J].无机材料学报，2008,23(2)：223-228
[65]王林山，熊翔，肖鹏，任芸芸.反应熔渗法制备C/C-SiC复合材料及其影响因素的研究进展[J].粉末冶金材料科学与工程，2002,21(1)：37-41
[66]孙万昌，李贺军，陈三平，张守阳. C/C复合材料快速CVI致密化技术研究进展[J].材料导报,2001,15(12)：43-45
[67] Walter Krenkel. Ceramic Matrix Composites: Fiber Reinforced Ceramics andTheir Applications [M]. Wiley VCH, weinheim,2008
[68]韩秀峰.碳改性C/SiC复合材料的结构与性能[D].西安.西北工业大学硕士论文，2006
[69]陈曼华. PIP工艺制备陶瓷基复合材料中先驱体的交联固化研究[D].长沙.国防科学技术大学博士学位论文，2005
[70]马青松.聚硅氧烷先驱体转化制备陶瓷基复合材料研究[D].长沙.国防科学技术大学博士学位论文，2003
[71]杜红娜.先驱体转化法制备C/C-SiC复合材料的研究[D].西安.西北工业大学硕士论文，2006
[72] Fitzer, E. The Future of Carbon-Carbon Composites [J]. Carbon.,1987,25(2):163-190
[73]王毅，徐永东，张立同，成来飞.液相先驱体制备C/C-TaC复合材料[J].固体火箭技术，2007，21（6）：541-543
[74]石岳，刘辉，迟伟东，沈曾民.液相先驱体转化法制备锆掺杂C-C复合材料的研究[J].耐火材料，2010，44(5)：345-350
[75]李淑萍，李克智，郭领军，和永岗. HfC改性C/C复合材料整体喉衬的烧蚀性能研究[J].无机材料学报，2008，23(6)：1155-1158
[76]益小苏，杜善义，张立同主编.中国材料工程大典-复合材料卷[M].北京:化学工业出版社,2006
[77] Hasegawa T., Iwasa Y., Koda T., Kishida H., Tokura Y., Wada S., Tashiro H.,Tachibana H., Matsumoto M., Miller R. D. Nonlinear Optical Spectroscopyon Polysilanes: Dependence of Exciton States on Polymer BackboneConformations [J]. Synthetic Metals,1995,71:1679-1680
[78]楚增勇.聚硅烷的奇异特性及其应用[J].有机硅材料,2000,14(4):25-28
[79]李光亮.有机硅高分子化学[M].科学出版社，北京，1999
[80]幸松民，王一璐编著.有机硅合成工艺及产品应用[M].北京，化学工业出版社，北京，2000
[81]李建军，陈来，孙晋良，周春节，张家宝，任慕苏. C/C和C/C-SiC复合材料的氧化及烧蚀性能[J].上海大学学报(自然科学版)，2003，11(1)：74-79
[82]王光信，张积树.有机电合成导论[M].化学工业出版社，北京，1997
[83] Shigenori Kashimura, Manabu Ishifune, Natsuki Yamashita, Hang-Bom Bu,Masakatsu Takebayashi, Satsuki Kitajima, Daisuke Yoshiwara, Yasuki Kataoka,Ryoichi Nishida, Shin-ichi Kawasaki, Hiroaki Murase, and Tatsuya Sho.Electroreductive Synthesis of Polysilanes, Polygermanes and Related Polymerswith Magnesium Electrodes [J]. Journal of Organic Chemistry,1999,64(18):6615-6621
[84] Atsutaka Kunai, Takafumi Ueda, Eiji Toyoda and Mitsuo Ishikawa.Electrochemical Reduction of Dichlorosilanes in the Presence of2,3-Dimethylbutadiene [J]. Bulletin of the Chemical Society of Japan,1994,67(1):287-289.
[85] Lori A. Vermeulen, Kevin Smith and Jiabin Wang. ElectrochemicalPolymerization of Alkyltri-chlorosilane monomers to Form Branched SiBackbone Polymers [J]. Electrochimica Acta,1999,45(7):1007-1014
[86] Mitsutoshi Okano, Hirokuni Fukai, Makoto Arakawa and Hiroshi Hamano.Electrochemical Synthesis of Network Polygermanes and Polysilanes [J].Electrochemistry Communications,1999,1(6):223-226
[87] Mitsutoshi Okano, Ken-ichi Takeda, Takeshi Toriumi and Hiroshi Hamano.Electrochemical Synthesis of Polygermanes [J]. Electrochimica Acta,1998,44(4):659-666
[88] Mitsutoshi Okano, Takeshi Toriumi, Hiroshi Hamano. Electrochemicalsynthesis of Germane-Germane and Germane-Silane Copolymers [J].Electrochimica Acta,1999,44(20):3475-3482
[89] Shigenori Kashimura, Manabu Ishifune, Hang-Bom Bu, MasakatsuTakebayashi, Satsuki Kitajima, Daisuke Yoshihara, Ryoichi Nishida, Shin-ichiKawasaki, Hiroaki Murase and Tatsuya Shono. Electroreductive Synthesis ofsome Functionalized polysilanes and Related Polymers [J]. TetrahedronLetters,1997,38(26):4607-4610
[90] Tanik Y.日本公开特许.08,255,484.1993
[91] Carole Moreau, Francüoise Serein-Spirau, Michel Bordeau. ElectrochemicalSynthesis of Functional Aryl-and Heteroarylchlorosilanes. Application to thePreparation of Donor-Acceptor or Donor-Donor OrganosiliconMolecules [J].Organometallics2001,20:1910-1917
[92] Amberger E, Salazar R W G. Mixed Organometallic Compounds of Group VI:Synthese, Properties and Addition Reaction [J]. Macromolecule,1985,18:2349-2354
[93]郭爱青.含Sb聚硅烷合成及性能研究[D].长沙：湖南师范大学硕士学位论文，2004
[94]邢欣，刘琳，李效东，王海哲.侧链含锑聚硅烷的合成与性能研究[J].国防科技大学学报，2008,30(3)：15-20
[95] M. Elangovan, A. Muthukumaran, M. Anbu Kulandainathan. NovelElectrochemical Synthesis and Characterisation of poly(methyl vinylsilane) andits co-polymers [J]. European Polymer Journal,2005,41:2450-2460
[96]郭玉明，冯志海，王金明.高性能PAN基碳纤维及其复合材料在航天领域的应用[J].高科技纤维与应用,2007,32(5):1-7
[97]西田亮一，村濑裕明.聚硅烷及其制造方法[P].中国专利号98801634.6
[98]西田亮一，川崎真一，村濑裕明.聚硅烷类的制造方法[P].中国专利号97180726.
[99]吴市，陈来，张峰君，范雪骐，任慕苏，孙晋良.电化学合成的含双键聚硅烷[J].高分子材料科学与工程，2007，23(5)：64-66
[100]吴市，陈来，钱林，张家宝，潘健峰，周春节，任慕苏，孙晋良.先驱体浸渗裂解法制备C/C-SiC复合材料的烧蚀性能[J].硅酸盐学报，2008，37(7)：973-977
[1] R. W. Rice. Ceramics from Polymer Pyrolysis, Opportunities and Needs-A MaterialsPerspective [J]. American Ceramic Society Bulletin,1983,62:889-892
[2] P. Colombo, G. Mera, R. Riedel, G.D. Sorarù. Polymer-Derived Ceramics:40Years ofResearch and Innovation in Advanced Ceramics [J]. Journal of the American CeramicSociety,2010,93:1805-1837
[3] K. J. Wynne, R.W. Rice. Ceramics via Polymer Pyrolysis [J]. Annual Review ofMaterials Research,1984,14:297-334
[4] Dong Mei Zhu, Hong Na Du, Fa Luo, Wan Cheng Zhou. Fabrication andCharacteristics of Carbon Fiber Reinforced C–SiC Dual Matrix Composites [J].Advances in Composite Materials and Structures,2007,334-335:145-148
[5] R. M. Rocha, C. A. A. Cairo, M.L.A. Gra a. Formation of Carbon Fiber-ReinforcedCeramic Matrix Composites with Polysiloxane/Silicon Derived Matrix [J]. MaterialsScience and Engineering: A.2006,437(2):268-273
[6] A. G. Odeshi, H. Mucha, B. Wielage. Manufacture and Characterisation of A Low CostCarbon Fibre Reinforced C/SiC Dual Matrix Composite [J].Carbon,2006,44(10):1994-2001
[7]幸松民，王一璐.有机硅合成工艺及产品应用[M].北京，化学工业出版社，2000[8] Yuxi Yu, Jinhua Tai, Xueyuan Tang, Yadi Guo, Ming Tang, Xiaodong Li. ContinuousSi–C–O–Al Fiber Derived from Aluminum-Containing Polycarbosilane Precursor [J].Composites: Part A,2008,39:1101-1105
[9] Schiavon, M. A., Radovanovic E. and Yoshida, I. V. P. Microstructural Characterizationof Monolithic Ceramic Matrix Composites from Polysiloxane and SiC Powder [J].Powder Technol.,2002,123:232-241
[10] Wei, Q., Pippel, E. Woltersdorf J., Scheffler M. and Greil P. Interfacial SiC Formationin Polysiloxane-Derived Si–O–C Ceramics [J]. Mater. Chem. Phys.,2002,73:281-289
[11] Hourlier D. B., Latournerie J. and Dempsey P. Reaction Pathways during the ThermalConversion of Polysiloxane Precursors into Oxycarbide Ceramics [J]. Journal of theEuropean Ceramic Society,2005,25:979-985
[12] Kleebe H. J., Turquat C. and Sorarù G. D. Phase-separation in an SiCO Glass Studiedby Transmission Electron Microscopy and Electron Energy-Loss Spectroscopy [J].Journal of the American Ceramic Society,2001,84:1073-1080
[13] C. Laffon, A. M. Flank, P. Lagarde, M. Laridjan, R. Hagege, P. Olry, J. Cotteret,J.L.Miquel, H. Hommel and A. P. Lagrand. Study of Nicalon-based Ceramic Fibresand Powders by EXAFS Spectrometry, X-Ray Diffractometry and Some AdditionalMethods.[J]. Journal of Materials Science,1989,24:1503-1512
[14] Kenji Kaneko, Ken-Ichi Kakimoto. HRTEM and ELNES Analysis of PolycarbosilaneDerived Si-C-O bulk Ceramics [J]. Journal of Non-Crystalline Solids,2000，270:181-190
[15] O. Delverdier, M. Monthioux, D. Mocaer, R. Pailler.Thermal behavior of polymer-derived ceramics. I. Si-C and Si-C-O Systems from both Commercial and NewPolycarbosilane (PCS) precursors [J]. Journal of the European Ceramic Society,1993,12:27-41
[16] E. Bouillon, F. Langlais, R. Pailler, R. Naslain, F. Cruege,J.C. Sarthou, A. Delpuech, C.La.on, P. Lagarde, M.Monthioux, A. Oberlin. Conversion Mechanisms of a Poly-carbosilane Precursor into an SiC-based Ceramic Material [J]. Journal of MaterialsScience,1991,26:1333-1345.
[17] T. Shimoo, K. Okamura M. Ito and Takeda M. High-Temperature Stability ofLow-Oxygen Silicon Carbide Fiber Heat-Treated under Different Atmosphere [J].Journal of Materials Science,2000,35(15):3733-3739
[18]马青松，陈朝晖，郑文伟，胡海峰.聚硅氧烷-二乙烯基苯的交联与裂解[J].国防科技大学学报，2001，23(5)：40-44
[19] Gregori G., Kleebe H.J., Blum Y. D. and Babonneaun F. Evolution of C-rich SiOCCeramics. Part II. Characterization by High Lateral Resolution Techniques: ElectronEnergy-Loss Spectroscopy, High-Resolution TEM and Energy-Filtered TEM [J].International Journal of Materials Research,2006,97:710-720
[20] Shimoo T., Tsukada I., Seguchi T., Okamura K. Effect of Firing Temperature on theThermal Stability of Low-Oxygen Silicon Carbide Fibers [J]. Journal of the AmericanCeramic Society,1998,81(8):2109-2115
[21]叶大伦.实用无机物热力学数据手册[M].冶金工业出版社，北京，1981
[1] John B. Wachtman Jr.J. R. Strife, J. J. Brennan, K. M. Prewo. Status of ContinuousFiber-Reinforced Ceramic Matrix Composite Processing Technology [J]. CeramicEngineering and Science Proceedings,1990,11(7-8):871-919
[2]郑春满，李效东，余煜玺，曹峰. SiC陶瓷纤维先驱体设计原则及合成研究进展[J].高分子材料科学与工程，2005,21(6):6-10
[3] A. Centeno, R. Santamaría, M. Granda, R. Menéndez, C. Blanco. Thermal Curing ofMesophase Pitch: an Alternative to Oxidative Stabilisation for The Development ofCarbon-Carboncomposites [J]. Journal of Analytical and Applied Pyrolysis,2009,86(1):28-32
[4] Dileep Singh, Dongming Zhu, Yanchun Zhou, Mrityunjay Singh,S. Le Ber, M.-A.Dourges, L. Maillé, R. Pailler, A. Guette. Ceramic Matrix Composites Densification byActive Filler Impregnation Followed by a P.I.P. Process [J]. Ceramic Transactions,2010,215:113-123
[5] R. M. Rocha, C. A. A. Cairo, M.L.A. Gra a. Formation of carbon fiber-reinforcedceramic matrix composites with polysiloxane/silicon derived matrix [J]. MaterialsScience and Engineering: A,2006,437(2):268-273.
[6] Dan Zhao, Haifeng Hu, Changrui Zhang, Yudi Zhang and Jun Wang. A Simple Way toPrepare Precursors for Zirconium Carbide [J]. Journal of Materials Science,2010,45(23):6401-6405
[7] Schiavon, M. A., K. J. Ciuffi, Yoshida V. P. Glasses in the SiOCN System Produced byPyrolysis of Polycyclic Silazane/Siloxane Networks [J]. Journal of Non-CrystallineSolids,2007,353(22-23):2280-2288
[8]薛宁娟，郝志彪，李瑞珍，谢瑞广.炭/炭复合材料抗氧化研究进展[J].材料导报，2003,17:229-232
[9] Yongsheng Liu, Litong Zhang, Laifei Cheng, Xin’gang Luan, Wenbin Yang, WeihuaZhang, Yongdong Xu, Qingfeng Zeng. Preparation and Oxidation Resistance of2DC/SiC Composites Modified by Partial Boron Carbide Self-Sealing Matrix [J].Materials Science and Engineering: A,2008,498(1-2):430-436
[10]实用化学手册编写组.实用化学手册[M].科学出版社，北京，2001
[11] GBT6730.9-2006铁矿石硅含量的测定硫酸亚铁铵还原-硅钼蓝分光光度
[12] Marco Antonio Schiavon, Eduardo Radovanovic, Inez Valeria Pagotto Yoshida.Microstructural Characterisation of Monolithic Ceramic Matrix Composites fromPolysiloxane and SiC Powder [J]. Powder Technology,2002,123:232–241
[13]马青松，陈朝晖，郑文伟，胡海峰.聚硅氧烷-二乙烯基苯的交联与裂解[J].国防科技大学学报，2001，23(5):40-44
[14] Marco Antonio Schiavon. Crystallization Behavior of Novel Silicon Boron OxycarbideGlasses [J]. Journal of the American Ceramic Society,2004,87(2):203-208
[15] Yuxi Yu, Jinhua Tai, Xueyuan Tang, Yadi Guo, Ming Tang, Xiaodong Li. ContinuousSi–C–O–Al Fiber Derived from Aluminum-Containing Polycarbosilane Precursor[J].Composites: Part A,2008,39:1101–1105
[1]闫联生,崔红,李克智,李贺军,王涛,宋麦丽.炭纤维针刺预制体增强C/SiC复合材料的制备与性能研究[J].无机材料学报，2008,23(2):223-228
[2]郭全贵，宋进仁，刘朗，张碧江. B4C-SiC/C复合材料高温自愈合抗氧化性能研究，Ⅱ.复合材料结构变化与其自愈合抗氧化相关性研究[J].新型碳材料，1998,13(2):5-10
[3]曹学强.热障涂层材料[M].科学出版社，北京，2001
[4]潘育松，徐永东，陈照峰，成来飞，张立同，熊党生.2D C/SiC复合材料烧蚀性能分析[J].兵器材料科学与工程，2006,29(1):17-20
[5]胡秀颖,王成国,王启芬,卢文博,王延相.聚丙烯腈基碳纤维皮芯结构的形成与演变[J].材料导报,2010,24(9):71-74
[6]李照谦,李贺军,曹翠微,李克智,张守阳,赵华. C/C复合材料ZrC/SiC抗烧蚀涂层性能研究,固体火箭技术，2011,34(1):105-108
[7]黄海明,杜善义,吴林志，王建新. C/C复合材料烧蚀性能分析[J].复合材料学报,2001,18(3):76–80
[8] Shen Xuetao, Li Kezhi, Li Hejun, Du Hongying, Cao Weifeng, Lan Fengtao.Microstructure and Ablation Properties of Zirconium Carbidedoped Carbon/CarbonComposites [J].Carbon,2010,48:344–351
[9]叶大伦.实用无机物热力学数据手册[M].冶金工业出版社，北京，1981
[10]实用化学手册编写组.实用化学手册[M].科学出版社，北京，2001
[11]傅献彩，沈文霞，姚天扬.物理化学[M].高等教育出版社，北京，1990
[12] J.Szekely，J.W.Evans， H.Y.Sohn.Gas-solidreactions [M].胡道和译.北京:中国建筑工业出版社，1986,12:8-34
[13] F. Lamouroux and R. Naslain. Kinetics and Mechanisms of Oxidation of2D WovenC/SiC ComPosite: Ⅱ: Theoretical Approach [J]. Journal of the American CeramicSociety，1994,77(8):2058-2068
[1] Gabriela Sacarescu, Rodinel Ardeleanu, Liviu Sacarescu, Mihaela Simionescu.Synthesis of polysilane-bis(salicyliden)ethylenediamine Ni(II) complex [J]. Journalof Organometallic Chemistry,2003,685:202-206
[2] Venkatasubbaiah Krishnan, Ravindranathan Bindu, Vadapalli Chandrasekhar andVaranasi S. R. Murthy. Single-Step Synthesis of Chemically Cross-LinkedPolysilastyrene and Its Conversion to_-Silicon Carbide [J]. Journal of the AmericanCeramic Society,2002,85(2):504–506
[3] Smith, T. L. US. Patent4,631,179, Dec.1986
[4] Hui Jung Wu, Leonard V. Interrante. Preparation of poly(dichlorosilaethylene) andpoly(silaethylene) via Ring-opening polymerization [J]. Macromolecules,1992,25(6):1840–1841
[5]钱林,陈来,田玲,吴市,张家宝,任慕苏,孙晋良.含双键聚硅烷的电化学合成[J].高分子材料科学与工程,2009,25(9):4-7
[6]洛阳耐火材料研究所.耐火材料化学分析[M].冶金工业出版社,1984
[7]幸松民，王一璐.有机硅合成工艺及产品应用[M].北京，化学工业出版社，,2000:211-212,818-823
[8]邓建平，史保川，廖学巍.聚甲基环戊二烯基硅烷及其共聚物的合成与表征[J].有机硅材料，2001，15(6)：1-5
[9]曾昭琼.有机化学[M].北京:高等教育出版社，1993:189-193
[10] Yutaka M, Yasushi K, Yoshihiko N. Polysilane Spherulites and their HighPhotolurninesence quantum Yields [J]. Journal of Polymer Science Part A: PolymerChemistry,1997,35:427-430
[11]邢欣，刘琳，李效东，王海哲.侧链含锑聚硅烷的合成与性能研究[J].国防科技大学学报,2008,30(3):15~20
[12]杨刚，高升，谷秋菊，徐南平.柱层析法纯化烯丙基硅烷[J].南京工业大学学报(自然科学版),2010,32(1):19-22
[13] Brian J. Grimmond, Nigam P. Rath, and Joyce Y. Corey. Enantiopure Siloxy-Functionalized Group4Metallocene Dichlorides. Synthesis, Characterization, andCatalytic Dehydropolymerization of PhSiH3[J]. Organometallics,2000,19,2975-2984
[14] Braunschweig J H, Koblinski C, Wang R M. Synthesis and Structure of the First [1]Boratitanocenophanes [J]. European Journal of Inorganic Chemistry,1999,69-73
[15] Bajgur C S, Tikkanen W, Petersen J L. Synthesis, Structural Characterization, andElectrochemistry of [1]Metallocenophane Complexes,[Si(alkyl)2(C5H4)2]MCl2, M=Ti,Zr [J] Inorganic Chemistry,1985,24:2539-2546
[16]张友杰，李念平.有机波普学教程[M].上海,华中师范大学出版社,1990:80-88
[17] Okano M, Takeda K, Toriumi T, Hamano H. Electrochemical Synthesis ofPolygermanes [J]. Electrochimica Acta,1998,44:659-666
[1] Kagawa, Y. and Goto, K. Notch. Sensitivity Of Two-Dimensional Woven SiC Fibre-Reinforced SiC Matrix Composite Fabricated by the Polymer Conversion Process [J].Journal of Materials Science Letters,1997,16:850-854
[2] Takeda, M., Kagawa, Y., Mitsuno, S., Imai, Y., and Ichikawa, J. Strength of aHi-NicalonTM/Silicon Carbide Matrix Composite Fabricated by the Multiple PolymerInfiltration Pyrolysis Process [J]. Journal of the American Ceramic Society,1999,82(6):1579-1581
[3] Mamiya, T., Kagawa, Y., Shioji, Y., Sato, M. and Yamamura, T. Tensile FractureBehavior and Strength of Surface-Modified SiTiCO Fiber Sic-Matrix MinicompositesFabricated by The PIP Process [J]. Journal of the American Ceramic Society,2000,83(2):433-435
[4] Takemi Yamamura, Toshihiro Ishikawa, Masaki Shibuya, Terumi Hisayuki andKiyohito Okamura. Development of a New Continuous Si-Ti-C-O Fibre Using anOrganometallic Polymer Precursor [J]. Journal of Materials Science,1988,23(7):2589-2594
[5] F. Babonneau and G. D. Soraru. Synthesis and Characterization of Si-Zr-C-O Ceramicsfrom Polymer Precursors [J]. Journal of the European Ceramic Society,1991,8:29-34
[6] K Suzuki, K Kumagawa, T Kamiyama, M. Shibuya. Characterization of theMedium-Range Structure of Si-Al-C-O, Si-Zr-C-O and Si-Al-C Tyranno Fibers bySmall Angle X-Ray Scattering [J]. Journal of Materials Science,2002,37:949-953
[7] E. Radovanovic, M.F. Gozzi, M.C. Gon alves, I.V.P. Yoshida. Silicon OxycarbideGlasses from Silicone Networks [J]. Journal of Non-Crystalline Solids,1999,248(1):37–48
[8] Robert Frind, Martin Oschatz and Stefan Kaskel. Polymerization of Polycarbosilanes inHigh Internal Phase Emulsions for the Synthesis of Macroporous Silicon CarbideCatalysts (polyHIPE-SiC)[J]. Journal of Materials Chemistry,2011,21:11936-11940
[9] G. D. Soraru, Florence Babonneau and J. D. Mackenzie. Structural Evolutions fromPolycarbosilane to SiC Ceramic [J]. Journal of Materials Science,1990,25(9):3886-3893
[10] Yuxi Yu, Jinhua Tai, Xueyuan Tang, Yadi Guo, Ming Tang, Xiaodong Li. ContinuousSi–C–O–Al Fiber Derived from Aluminum-Containing Polycarbosilane Precursor [J].Composites: Part A,2008,39:1101–1105
[11]李照谦,李贺军,曹翠微,李克智,张守阳,赵华. C/C复合材料ZrC/SiC抗烧蚀涂层性能研究[J].固体火箭技术,2011,34(1):105-108
[12]石岳,刘辉,迟伟东,沈曾民.锆掺杂C/C复合材料的制备及微观结构研究[J].热加工工艺,2010,39(20):83-90
[13]刘军，冯春祥，宋永才,薛金根.先驱体转化法制备碳化硅纤维[J].现代化工,2000,20(10):58-62
[14] T. Iseki, M. Narisawa, Y. Katase, K. Oka, T. Dohmaru, K. Okamura. An EfficientProcess of Cross-Linking Poly(Methylsilane) for SiC Ceramics [J]. Chemistry ofMaterials,2001,13(11):4163-4169
[1] James E. Sheehan. Oxidation protection for carbon fiber composites [J]. Carbon,1989,27(5):709-715
[2] C.G. Papakonstantinou， P. Balaguru， R.E. Lyon. Comparative Study of HighTemperature Composites [J]. Composites Part B: Engineering,2001,32(8):637-649
[3] J. S. Fischedick, J. Schmidt, R. Tamme, U. Kroner, J. Arnold, B. Zeiffer. OxidationBehaviour of C/C–SiC Coated with SiC-B4C-SiC-Cordierite Oxidation ProtectionSystem,[J]. Materials Science and Engineering A,2004,386:428-434
[4] X. Wu, L.R. Radovic. Inhibition of catalytic oxidation of carbon/carboncomposites byboron-doping [J]. Carbon,2005,43:1768-1777
[5] Yulei Zhang, Hejun Li, Xinfa Qiang, Kezhi Li. Oxidation Protective C/SiC/Si-SiCMultilayer Coating for Carbon/Carbon Composites Applying at1873K [J]. Journal ofMaterials Science&Technology,2010,26(12):1139-1142
[6] Feng Tao, Li He-Jun, Fu Qian-Gang, Zhang Yu-Lei, Shi Xiao-Hong. Microstructureand Anti-Oxidation Properties of Multi-Composition Ceramic Coatings forCarbon/Carbon Composites [J]. Ceramics International,2011,37(1):79-84
[7] Fu Qian-Gang, Li He-Jun, Shi Xiao-Hong, Li Ke-Zhi, Zhang Wei, Huang Min. A SiCWhisker-Toughened SiC-CrSi2Oxidation Protective Coating for Carbon/CarbonComposites [J]. Applied Surface Science,2007,253(8):3757-3760
[8] P. Lespade, N. Richet, P. Goursat. Oxidation resistance of HfB2–SiC Composites forProtection of Carbon-Based Materials [J]. Acta Astronautica,2007,60(10-11):858-864
[9] Tong Qingfeng, Shi Jingli, Song Yongzhong，Quangui Guo, Lang Liu. Resistance toAblation of Pitch-Derived ZrC/C composites [J]． Carbon，2004，42(12-13):2495-2500．
[10]宋桂明,武英,白厚善. TiC颗粒增强钨基复合材料的烧蚀性能[J].中国有色金属学报,2000,10(3):313-3l7
[11] J. F. Huang, B. Wang, H.J. Li, M. Liu, L.Y. Cao, C.Y. Yao. A MoSi2/SiC OxidationProtective Coating for Carbon/Carbon Composites [J]. Corrosion Science,2011,53:834-839.
[12] Wang C. R., Yang J.M., Hoffman W. Thermal Stability of Refractory Carbide/BorideComposites [J]. Materials Chemistry and Physics,2002,74:272-281
[13] GBT6730.9-2006铁矿石硅含量的测定硫酸亚铁铵还原-硅钼蓝分光光度
[14]叶大伦.实用无机物热力学数据手册[M].冶金工业出版社，北京，1981
[15] Penvecost J L. High Temperature Inorganic coatings [M]. New York: ReinholdPublishing Corp,1963
[16] Wu Shi, Chen Lai, Qian Lin, Zhang Jiabao, Pan Jianfeng, Zhou Chunjie, Ren Musu,Sun Jinliang. Ablation Properties of C/C-SiC Composite by the Precursor InfiltrationPyrolysis [J]. Journal of Chinese Ceramic society,2008,36(7):973-977
[17]宋桂明，王玉金，周玉，郭英奎，温广武. ZrCp/W复合材料的烧蚀性能.稀有金属材料与工程[J].2001,30（2）:101-104