利用蓖麻秆制造人造板的机理和工艺研究
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摘要
蓖麻是大戟科,蓖麻属的唯一种,多年生或一年生木质草本;蓖麻秆各个不同部位的原料特性差异明显,木质部为散孔材,纤维形态较好、长度中等;整秆的理化性能优良,pH值呈酸性,相对结晶度63.27%,SiO2含量少,可用于造纸、人造板制造等工业应用。
     对100个不同工艺条件下,以脲醛树脂胶为胶粘剂、蓖麻整秆为原料的刨花板的性能进行了研究,在综合考虑板材生产成本、生产效率和板材性能稳定性的基础上,最终确定出了最佳热压工艺参数为:热压温度150℃,热压时间30s/mm,施胶量12%。在该工艺参数下制造的蓖麻秆刨花板添加1.44%的石蜡乳液后,各项性能均可满足国标要求,并随板材密度的增加而增加;纤维板添加1.2%的石蜡乳液后,可满足国标要求;并可与同一工艺条件下的杨木人造板的性能相媲美。在蓖麻秆刨花中添加3%的异氰酸酯胶粘剂就可制出满足国标要求的刨花板。蓖麻秆的髓部由多面体薄壁细胞组成,对刨花板性能可产生不利影响,但该材料可用于制造保温材料和包装垫块等。
     针对蓖麻秆原料的季节性、区域性分布特点提出了可行的原料收集模式和3种工业化利用模式。以蓖麻秆为原料生产人造板可降低板材生产成本、增加农民收入,节约木材资源,利用我国现有蓖麻秆资源的一半就可节约森林面积150万亩/a。
The Castor oil plant (Ricinus communis L.) is sole species of the spurge family. It is perennial or annual woody herbage. There are significant differences in characters of castor stalk and its different parts. The xylem of the castor stalk is diffuse-porous wood and has medium-length good configuration fibres. The physical-chemical properties of the castor stalk are well, the pH value is acidity, the relative crystal-degree is 63.27percent, and the SiO2 content is less. So the Castor stalk is a good woody material and can be used to make man-made board, paper and the like.
     Research on making castor stalk based particle board and comparative study of the properties of one hundred particle boards produced by corresponding different hot-press techniques. The objective of this is to choose the best techniques from the above. Considering the cost of man-made board,the properties and production efficiency of the board produced by the hot-press technique chosen, and get the hot-press temperature is 150 centigrade, the hot-press time is 30 second per millimeter and the resin added is 12 percent. Produced by it the properties of the castor stalk based particle board with 1.44 percent wax added and the castor stalk based fibre board with 1.2 percent wax added both can exceed the requirements of the PRC Standards for Particle Board and Fibre board respectively. The properties of castor stalk based board are increasing with the density increasing of the board. Besides, the results show that the properties of castor stalk based board and poplar wood based board made by the same techniques are comparable. The marrow of the castor stalk contains parenchyma cells mainly and it has disadvantage influence on the properties of the stalk based board. So it can be got rid of when the castor stalk are used in industry. But it can be used in making heat insulating material, packing pad and so on.
     It suggests one method for Collection of raw materials and three modes for castor stalk industrial use in China because castor stalk has regional and seasonal characteristics. Producing castor stalk based board can decrease the air pollution caused by stalk burning, increase the income of farmers in China, protect the forestry resources of China, and decrease the cost of man-made board. If the half of the castor stalk produced now will be used in industry, and the 100000ha forestry will be protect per year.
引文
[1]朱保葛,李文彬.蓖麻生物工程研究进展,中国生物工程杂志,2007, 27 (10) : 98~102.
    [2]山东省淄博市农业科学研究院,蓖麻深加工前景广阔[OL], http://www.bimachina.com. 2009-3-31.
    [3]陈萌蓖麻籽油的成份分析云南化工1998年第2期:73-74.
    [4]尹秀玲,徐兴友,孟宪东,张凤娟.蓖麻的开发利用,生物学杂志[J]. 1998,15(2):35.
    [5] Xiaohua He, Charlotta Turner, Grace Q. Chen, Jiann-Tsyh Lin, and Thomas A. Mckeon. (2004) Cloning and Characterization of a cDNA Encoding Diacylglycerol Acyltransferase from Castor Bean[J], Lipids, 39(4):311-318.
    [6]刘振波.种植红色蓖麻的综合效益,特种经济动植物, 2004,1:28.
    [7]黄文霞,何觉民,陆建农.国内外蓖麻杂种优势利用和蓖麻加工研究现状[J].作物研究,2006,5:541-544.
    [8]山东省淄博市农业科学研究院,利用蓖麻油制备绿色聚合物材料[OL], http://www.bimachina.com. 2009-3-31.
    [9] J. O. Metzger . U. Bornscheuer. ( 2006) Lipids as renewable resources: current state of chemical and biotechnological conversion and diversification[J], 71: 13-22.
    [10] S.Y. Mhaskar, V.V.S. Mani. (1994)Synthesis of Methyl 9,12-Epoxyoctadecanoate from Castor Oil[J],JAOCS, 71(5):543-544.
    [11] Mangesh G. Kulkarni, Sudhirprakash B. Sawant. (2003)Kinetics of the Catalytic Esterification of Castor Oil with Lauric Acid Using n-Butyl Benzene as a Water Entrainer [J]. JAOCS, 80(10): 1033-1036
    [12] Jiann-Tsyh Lin, Seiji Wani, Xiaohua He, Tasha Nguyen, Thomas A. (2005) McKeon.Incorporation of Laurate and Hydroxylaurate into Phosphatidylcholines and Acylglycerols in Castor Microsomes[J]. JAOCS, 82( 7): 495-499.
    [13] Jozef Kula, Halina Sadowska. (1993)One-Pot Synthesis of (E)-2-Nonenal from Castor Oil [J], JAOCS, 70(6):643-644.
    [14] Suresh S. Narine. Xiaohua Kong. Laziz Bouzidi ?. Peter Sporns. (2007) Physical Properties of Polyurethanes Produced from Polyols from Seed Oils: II. Foams [J]. J Amer Oil Chem Soc 84:65–72.
    [15] N. G. KULKARNI, N. KRISHNAMURTI, P. C. CHATTERJEE, J. S. AGGARWAL. (1969)Polymerizable Monomers From Castor Oil: II. Syntheses of Some Divinyl Monomers [J]. JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY, 46: 396-398.
    [16] Maria Augusta de Luca, Márcia Martinelli, Marly Maldaner Jacobi, Patrícia Luíza Becker, Marco Flores Ferr?o. (2006) Ceramer Coatings from Castor Oil Or Epoxidized Castor Oil and Tetraethoxysilane [J]. JAOCS, 83 ( 2):147-151.
    [17] A.K.Vasishtha, R.K.Trivedi, G.Das. (1990)Sebacic Acid and 2-Octanol from castor oil [J], JAOCS, 67(5):333-337.
    [18] Walter K. Sakamoto, Darcy H. F. Kanda, Francisco De Assis Andrade, D. K. Das-gupta. (2003) Dielectric relaxation of vegetable-based polyurethane[J], Journal of materials science 38: 1465-1470.
    [19]严兴初,王力军.蓖麻作为能源开发的现状与前景[J],安徽农业科,2007 ,35(34) : 11165 ,11167.
    [20]傅福勤.发挥我国南方热带地区资源优势推动蓖麻产业发展[J],农业工程学报, 1996 4:122,222.
    [21]孙福来.特用工业油源作物蓖麻[J],中国种业,2005,3:21-22.
    [22]朱国立,吴国林,赵凤春,田福东,张春华,李靖霞,郭志明.通辽市蓖麻生产现状及发展产业化对策[J],内蒙古农业科技,2001(5)1-5.
    [23]彭翠华,谭晓明,朱志文,王友平[J],蓖麻油PU/ HCAA互穿网络型聚合物的合成及其拉伸性能研究[J],聚氨酯工业, 2008. 23 (3): 29-32.
    [24]石红娥,谭晓明,胡远强,徐闫.蓖麻油TD I聚氨酯互穿网络的热降解[J],应用化学2008, 25(3):369-371.
    [25]胡国文.蓖麻油和丙烯酸醋双重改性水性聚氨醋复合乳液的研制[J],上海涂料, 2008, 46 (1): 4-7.
    [26]王洪宇,刘群元.蓖麻油及其衍生物在涂料中的应用[J],涂料工业, 2004, 34 (3):51-55.
    [27]牟科媛.蓖麻油及籽的临床应用实用[J],中西医结合临床, 2004, 4(5):58,68.
    [28]瞿金清,陈焕钦.蓖麻油聚氨酯丙烯酸酯复合乳液的研制[J],林产化学与工业, 25(1): 94-98.
    [29]朱志伟,杜文书,胡国胜.蓖麻油深加工产物—尼龙11的合成及应用[J],中国油脂, 2007, 32( 3):57-59
    [30]程国丽,杨云峰,王标兵,胡国胜.蓖麻油生物柴油组成及其燃烧性能[J].农业工程学报,2008,24(7):171-174.
    [31]周宁琳,王玉萍.蓖麻油型聚氨酯胶粘剂粘合性能的研究[J],橡胶工业, 1999, 46(5): 263-265. Zhou Ninglin, Wang Yuping. Study on Adhesion Property of Castor Oil-PU Adhesive[J], 1999, 46(5): 263-265.
    [32]李爱阳,胡波年,胡汉祥.蓖麻油制备醇酸预聚型双组分聚氨酯树脂涂料的研究[J],涂料工业, 36(1):21-23.
    [33]王赫麟,张无敌,刘士清,尹芳,官会林.蓖麻油制备生物柴油的研究能源工程[J], 2007, 3: 24-26.
    [34]尚东升.单组分蓖麻油型聚氨酯粘合剂初粘性的改进[J],聚氨酯工业, 2005, 20(5):32-34.
    [35]胡波年.改性蓖麻油制备UV光固化涂料的研究[J],涂料工业,2004, 34 (8): 24-26.
    [36]崔小明.工程塑料尼龙11的开发与应用[J],四川化工与腐蚀控制, 2000, 3(3):25-28.
    [37]王桂桂,谢洪泉,过俊石.具有良好阻尼性能的蓖麻油互穿网络弹性体[J], 2004,14 (5) :34~38
    [38]张福莲,冷春丽,田玉平,张举贤.磷酸化-马来酸蓖麻油醇酸酯-苯乙烯共聚物的合成[J],皮革化工, 2006,23(3): 33-36.
    [39]鲍利红,兰云军,张淑芬.马来酸酐改性蓖麻油制备耐光性聚氨酯复鞣剂—乳液性能研究[J],精细化工, 23(6): 145-150
    [41] Jinbo Li . High performance epoxy resin nanocomposites containing both organic montmorillonite and castor oil-polyurethane, Polymer Bulletin 56, 377–384 (2006)
    [42] R.N. MUKHERJEA, K.K. SAHA, and S.K. SANYAL, Plasticizing Effect of Acetylated Castor Oil on Castor Oil-Based, Moisture-Cured Polyurethane Film. JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY, 1978, 55:653-656
    [43] Volkhard Scholz, Jadir Nogueira da Silva. Prospects and risks of the use of castor oil as a fuel[J], Biomass and Bioenergy, 2008, 32( 2): 95-100.
    [44] P. Tongoona. Castor (Ricinus communis L.) research and production prospects in Zimbabwe[J], Industrial Crops and Products, 1992, 1(2-4): 235-239.
    [45]高一飞,黄平,王锋,肇毅,杨小冬,熊泳,赵和照.蓖麻油和聚乙二醇4000在结直肠癌术前肠道准备中的联合应用[J],结直肠肛门外科, 2007, 13 (4):225-227.
    [46] M. Maier, D. Staupendahl, H. R. Duerr, H. J. Refior. (1999) Castor oil decreases pain during extracorporeal shock wave application [J]. Arch Orthop Trauma Surg119 :423–427.
    [47]郑鹭,祁建民,陈绍军,方平平.蓖麻遗传育种进展及其在生物能源与医药综合利用潜势[J],中国农学通报, 2006, 22(9): 109-113.
    [48]李丽莉.蓖麻油炒鸡蛋对晚期妊娠引产效果的观察[J],中医药临床杂志, 2008, 20(4):366.
    [49]高昌舜,刘国喜,刘家勇,张彦,胡石强,田冬香.新型蓖麻粕脱毒生产线及其工艺的研究[J],天津农学院学报,1999,6(2):11-18.
    [50] G. FULLER, H.G. WALKER, JR., A.C. MOTTOLA, D.D. KUZMICKY, G.O. KOHLER, P. VOHRA . (1971) Potential for Detoxified Castor Meal[J]. JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY, 48:617-618.
    [51]魏兆军,周明,张世昙,林怀中.蓖麻蚕蛹的开发与利用[J],农牧产品开发, 1999, 11 :11-13。
    [52]马燕.蓖麻叶是天然的治虫剂[J],中国农村科技,2001, 7:42.
    [53]邹立波,詹金彪.蓖麻毒素的提取及其抗肿瘤作用研究[J],江大学学报(医学版), 2005, 34(3):217-219.
    [54]马青原,高宏伟,刘文森,邢丽杰,廖鹏. EDEM2对蓖麻毒素从内质网向胞浆逆向转运的影响[J].中国兽医学报,2008,28(5):557-561.
    [55]郑菁,陈华庭,黎维勇.蓖麻蛋白毒素的研究进展[J],中国医院药学杂志. 2005,25(2):164-165.
    [56]高宝岩.蓖麻毒蛋白的提取及分析[J],光谱实验室. 2001, 18(4):429-431.
    [57]曾佑炜,宋光泉,彭永宏,梁关生.蓖麻毒蛋白研究及应用进展,亚热带植物科学[J]. 2004,33(1):60-63.
    [58]罗嘉惠.蓖麻毒素的研究与应用[J],氨基酸和生物资源,1999, 21 (2) : 56~58.
    [59]葛利萍,詹金彪.蓖麻毒素在细胞内的运输和转运途径研究进展[J].浙江大学学报(医学版), 2003,32(6):538-542.
    [60]陆益民,宋光泉,贺铁山.蓖麻种子毒蛋白的高效凝胶过滤色谱分析[J],种子,2005, 24(6):89-90.
    [61]赵燕彪,侯黎伟,丁敏敏,张慧娥.聚乙二醇修饰的蓖麻毒蛋白A链的免疫原性和在小鼠体内急性毒性研究[J],食品与药品[J], 2006, 8 (12A): 41-43.
    [62]金汝城,贾超,杨晓华,谭玉玲,侯楠楠.蓖麻毒蛋白的分离纯化及其对南方根结线虫杀灭效果的研究[J],中国医药生物技术, 2008, 3 (4 ):293-296.
    [63]赵丹,谢达平.蓖麻毒蛋白研究进展[J],粮食与油脂,2005,5:3-5
    [64]阮明,贾凤兰,王福强,邢国振,张宝旭.β—七叶皂甙钠抗蓖麻毒素对小鼠腹腔渗出液及蛋白含量的影响[J],毒理学杂志, 2008, 22(3): 221-222.
    [65] S. Sharma, P. Vasudevan, M. Madan. Insecticidal value of castor (Ricinus cummunis) against termites [J], International Biodeterioration, 1991, 27(3):249-254
    [66] Peter M. L?sel, Gunter Penners, Roel P. J. Potting, Dirk Ebbinghaus, Alfred Elbert, Jürgen Scherkenbeck. (2000) Laboratory and field experiments towards the development of an attract and kill strategy for the control of the codling moth[J], Cydia pomonella, 95: 39-46.
    [67] Craig S. Tucker, Ruth Francis-Floyd, Marshall H. Beleau. (1986) Acute Toxicity of Saponified Castor Oil to channel catfish, Ictalurus punctatus, under laboratory and fied conditions[J], Bull. Environ. Contarn. Toxicol. 37:297-302
    [68]赵建兴,张树怀,佘国珍,乌云达来.蓖麻毒素粗提物杀虫作用的研究[J].内蒙古农业大学学报, 2001,22(4): 78-80.
    [69]叶锋,王德润.蓖麻毒素的毒性和毒素的分离及检测方法[J],中国油料作物学报, 2004, 26(1): 89-93.
    [70]温燕梅,冯亚非,郑明珠.蓖麻不同部位杀虫活性成分蓖麻碱的提取及含量农药[J], 2008,47(8):584-585,606.
    [71]吴雪平,单长卷,包冬蛾.蓖麻碱粗提物对麦蚜的生物活性研究[J],安徽农业科学, 2006, 34(11):2450,2495.
    [72]吴雪平,单长卷,包冬蛾(蓖麻碱粗提物对石榴棉蚜的生物活性研究[J],安徽农业科学, 2006, 34( 20) : 5293- 5294.
    [73]雷德柱,郑成,高晓明,许丽珠,周勇强,吴琼.蓖麻碱的分子修饰及其杀虫活性基团的探讨[J],化工学报, 2008, 59(5):1238-1241.
    [74]刘骁,李端.蓖麻碱的生物活性研究与应用开发前景[J],中国药理学与毒理学杂志, 20 (1) : 76– 78.
    [75]郑成,许丽珠,高晓明,胡美英,徐齐云.蓖麻碱的提取、纯化、改性及其杀虫活性研究[J],天然产物研究与开发, 2007, 19: 785-790.
    [76]高宝岩,霍建中,刘伟,刘小俊.蓖麻碱的提取及光谱研究[J],光谱实验室, 2000, 17(1):88-90
    [77]周勇强,赖春媚,张晓燕,郑成,胡美英,徐齐云.蓖麻碱的微波提取实验研究[J],广州化工, 2006, 34(4):30-35.
    [78]徐齐云,钟国华,胡美英,刘萱清,郑成.蓖麻提取物对蔬菜害虫的杀虫活性研究[J],长江蔬菜,2006,11:35-36.
    [79]王宗义,张丽英,杨文军,李冰颖,周志强.高效液相色谱法检测蓖麻粕中的蓖麻碱[J],中国饲料,2006, 8 :32-33,36.
    [80]陈兴,赵立超,贺永怀,沈倍奋.两种纯化蓖麻毒素方法的比较[J],生物化学杂志,1994,10(5):636-638
    [81]邓天福,尉吉乾,王小姣,程梦林.蓖麻乙醇粗提液对淡色库蚊幼虫的活性研究[J],中国媒介生物学及控制杂志, 2008, 19 (2):401,501,606.
    [82]申小卫,安靖靖,原国辉,罗梅浩,郭线茹.蓖麻植株不同部位粗提物对蛴螬的触杀作用研究[J],河南农业大学学报,2008. 42(4):427-429.
    [83]吴雪平,田雪亮,项志锋.蓖麻籽水提物对黄瓜褐斑病菌的生物活性研究[J],西北农业学报2006 ,15 (6) :215~216
    [84]吴雪平,邓天福,项志锋.蓖麻籽水提物对玉米小斑病菌的毒力测定[J],吉林农业科学, 2006,31( 4) : 43- 44, 52
    [85] Athanasios H. Grigoriou, Georgios A. Ntalos. The potential use of Ricinus communis L. (Castor) stalks as a lignocellulosic resource for particleboards [J], Industrial Crops and Products, 2001, 13(3): 209-218.
    [86]吕相义,李军,毕万新.国内外蓖麻生产的现状、问题及对策[J].中国农技推广,2003,6:25-26.
    [87]丁乡,蓖麻的市场走势及种植[J],特种经济动植物2008.4:28
    [88]李晓平,施静波,潘明珠.蓖麻秆制造人造板研究初探[J],林业科技开发,2008,
    [89]蔡晓鹏,发展蓖麻产业促进山区脱贫,7.
    [90]周萍祝丽香多种用途的植物———蓖麻,中国林副特产2000,2:48-49
    [91] M. Grieve. Castor Oil Plant[OL], http://www.botanical.com/botanical/mgmh/c/casoil32.html#pre. 2009,3
    [92] C. J. Wilson, formerly Weeds Branch, Darwin. (1998) Castor Oil Plant (Ricinus communis) [J], Agnote, 523(F49): 1-3.
    [93] Kenneth, Brenda Formanek. Castor-oil plant [OL], http://www.britannica.com/EBchecked/topic/98764/castor-oil-plant, 2009.03
    [94]山东省淄博市农业科学研究院,旱作高效农业的首选作物——杂交蓖麻[OL], http://www.bimachina.com. 2009-3-31.
    [95]白城市星火科技网,蓖麻产业[OL],http://www.jlsbcsp.org.cn/nation/1-1.html,2009,4,9
    [96]第六次全国森林资源清查结果发布[R].林业机械与木工设备. 2005年,第33卷第3期:27
    [97]尹思慈,木材学[M],北京:中国林业出版社,1996年10月第1版
    [98]张齐生,加快技术创新实现我国木材工业由大到强的转变[J],森林与人类,2005.11月号增刊:19-21
    [99]于海鹏刘一星刘迎涛,国内外木质环境学的研究概述[J],世界林业研究,16(6):20-26
    [100]施昆山林凤鸣,2015年我国木材供求展望[J],人造板通讯,2003年2月:27-29.
    [101]中华商务网.2003年中国木材行业与市场研究报告[R].http://www1chinaccm1com.
    [102]程宝栋等,2003年我国主要木材产品进口分析[J],林业经济问题, 2005,25(1): 53-56.
    [103]宋维明.对我国木材国际贸易战略的几点思考[J].林业经济,2000,(5):47-49.
    [104]周定国梅长彤,2000,面向21世纪的农作物秸秆工业材料[J],南京林业大学学报,25(5):1-4.
    [105]于文吉马红霞等,农作物秸秆人造板发展现状与应用前景[J],木材工业,19(4):5-8.
    [106]陈绪和. 2002.非木质人造板在中国的前景[J],国际木业,(4):4-5.
    [107]王嘉楠,查朝生,刘盛全.人工林杨树木材纤维形态特征及其变异的研究[J].安徽农业大学学报, 2006, 33 (2) : 149-154.
    [108]唐秋,蒲俊文.几种速生阔叶材纤维形态的研究[J].中华纸业,2006, 27(5):71-73.
    [109]廖声熙,李昆,杨振寅,张春华.不同年龄构树皮的纤维、化学特性与制浆性能研究[J ].林业科学研究, 2006, 19 (4) : 436- 440.
    [110]苌姗姗,刘元,胡进波,吴义强,朱林峰.人工林尾巨桉株内、株间纤维形态变异的研究[J].中南林业科技大学学报, 2007, 27(5):92-96.
    [111]王学民,应用多元分析[M],上海财经出版社,上海:2004年1月第2版
    [112]艾军,麦秸纤维特性及纤维板工艺的研究[M],东北林业大学出版社,哈尔滨:2002年6月第一版
    [113]李兰亭,胶粘剂与涂料[M],中国林业出版社,1992年2月第2版
    [114]杨淑惠.植物纤维化学[M].第3版.北京:中国轻工出版社, 2001.
    [115]李晓平,周定国.新陈稻草性能的差异研究[J].农业工程学报,2008,24(5):228-230.
    [116]唐艳军,刘秉钺,李友明等.芦苇化学成分及其化学机械浆性能研究[J].林产化学与工业, 2006, 26(2):69-73.
    [117]任海青,周海宾.三倍体毛白杨木材化学成分和纤维形态的分析[J].安徽农业大学学报, 2006, 33 (2) : 160-163.
    [118]李坚等.木材波谱学[M],北京:科学出版社,2003年3月,第一版
    [119]W.Grigsby, A.G. McDonald,A.Thumm, C.Loxton. X-ray photoelectron spectroscopy determination of urea formaldehyde resin coverage on MDF fiber[J], Holz Roh Werkst, 2004(62):358-364
    [120]Stephen S. Kelley, Timothy G. Rials, Leslie R. Groom and Chi-Leung So. Use of near infrared spectroscopy to predict the mechanical properties of six softwoods[J]. Holzforschung, Vol. 58, pp:252-260, 2004
    [121]Mari Nuopponen, Tapani Vuorinen, Saila J?ms?, and Pertti Viitaniemi. Thermal Modification in Softwood Studied by FT-IR and VU Resonance Raman Spectroscopy[J]. Holzforschung, Vol. 58, pp: 480-482, 2004
    [122]Per Hoffman, Adye Singh, Yoon Soo Kin, Seung Gon Wi, IK-Joo Kim and Uwe Schmitt. The Bremen Cog of 1380-An electron microscopic study of its degrade wood before and after stabilization with PEG. Holzforschung, Vol. 58, pp:211-218, 2004.
    [123]M.Zanetti, A. Pizzi, Dependence on the adhesive formulation of the upgrading of MUF particleboard adhesive and decrease of melamine content by buffer and additives[J]. Holz Roh Werkst (2004) 62: 445-451
    [124]Cheng Xing, Bernard Riedl, Alain Cloutier, Guangbo He. The effect of urea-formaldehyde resin pre-cure on the internal bond of medium density fiberboard[J]. Holz Roh Werkst (2004) 62: 439-444
    [125]泉美治等.李春鸿,刘振海译.仪器分析导论[M].第2版.北京:化学工业出版社,2005.
    [126]黄洛华,秦特夫. 5种不同品系相思木材的化学性质Ⅱ.pH值和酸、碱缓冲容量[J].林业科学研究, 2005,18(3):342~444
    [127]姚春丽,张求慧,段晖. 5种桦木的pH值、酸碱缓冲容量及苯醇抽出物的比较分析[J]. 2000, 22(5): 91-92
    [128]李春生,王金林,赵戈,姜惕,杜荣.杨木材性对单板胶合的影响及胶合工艺[J].木材工业,1998,12(4):13~16.
    [129]李晓平,顾凯,徐凯宏.双氧水和固化剂对稻草碎料板性能影响的比较[J].林业科技, 2006, 31(3):45-47
    [130]邢成,殷苏州,邓玉和.豆秸作为刨花板生产原料的可行性分析[J].林产工业,1999, 26(6):6-10.
    [131]吴章康,周定国.稻草原料酸碱性及稻草中密度纤维板的性能[J].林产工业, 2002, 29(3):12~14.
    [132]李阜东,吴健身,王俊先.油菜秆刨花板制造工艺研究[J].木材工业, 1998 , 12(6): 10-12.
    [133]胡云楚,2,6.二溴-4-硝基苯酚阻燃性能的热动力学研究[J],林产工业, 2002, 29(1): 30-32.
    [134]Cordero T,Rodriguez-Maroto J M,Garcia F,rodriguez J J.Thermal decomposition of wood in oxidizing atmosphere. A kinetic study from non-isothermal TG experiments[J], Thermochimica Acta,1991,191,161-178.
    [135]Zeriouh A,Belkbir L. Dilatometry analysis of Moroccan acacia wood under a nitrogen atmosphere[J]. Thermochimica Acta, 1996,287,293~298.
    [136]Kifani-Sahban F,Belkir L. Zoulalian A. Study of the slow pyrolysis of Moroccan eucalyptus by thermal anal-ysis[J]. Therm ochimica Acta,1996,284,341~349.
    [137]孙才英等,杨木热分析[J],东北林业大学学报,第26卷第1期,1998年1月:38-41
    [138]何芳,易维明,孙容峰,闸建文,柏雪源,李永军,小麦和玉米秸秆热解反应与热解动力学分析[J],农业工程学报,第18卷第4期2002年7月:10-13.
    [139]王春鹏,赵临五.木材工业用胶粘剂的现状及发展趋势(续)[J],林产工业,2001,28(3):6-8.
    [140]李晓平,高魏,周定国.稻草-木材复合空芯刨花板保温性能研究[J].中国人造板,2007,6:7-8.
    [141]周定国.关于稻秸秆人造板的几个问题[J].林产工业,2008,35(1):3-6.
    [142]阜南县经济委员会关于对全县工业经济形势的调查分析[OL],2http://www.zwgk.fy.gov.cn/XxgkNewsHtml/KH003/200903/KH003010301200903006.html,2 009-03-02
    [143]河北林业网邢台市平原林业产业发展大有可为[OL],http://www.hebly.gov.cn/showarticle.php?id=7419,2007-11-15

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